The characterization of and formulation development using a novel tyre devulcanizate
- von Berg, Stuart, Hlangothi, Percy
- Authors: von Berg, Stuart , Hlangothi, Percy
- Date: 2016
- Subjects: Rubber, Reclaimed Rubber chemicals Tires -- Recycling
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/13149 , vital:27156
- Description: The amount of waste tyres being dumped is fast becoming a problem. These stockpiles take up valuable land and are an environmental and health problem. While incineration is the simplest way to recycle the used tyres it isn’t an efficient way to dispose of tyres. This research looks at developing a method for characterizing the New Reclamation Group (NRG) reclaim with the main focus on Hi-Res™ thermogravimetric analysis. Good quantification was possible using this technique. A trade off was established between resolution, sensitivity and time. While increasing the resolution allowed greater separation to be achieved the time for each experiment increased rapidly. Although kinetic models do exist for quantifying rubber components in vulcanized sample, they were not suitable for this study. When devulcanization causes significant molecular changes, such as with NRG reclaim, the decomposition profiles no longer match those of virgin materials. Formulations developed focused on mixing, rheometry, crosslink density and tensile properties. The NRG reclaim acted as a processing aid which lowered the maximum torque. This provides mixing safety as the temperature is decreased as a result of the lower torque. This effect was not seen with conventional reclaim. Rheometry tests indicated that the addition of the devulcanizates decreased the extent of cure. It was demonstrated that this could be linked to crosslink density. Testing of the 100%, 200%, 300% moduli correlated the crosslink density to the maximum torque. Although the addition of NRG reclaim reduced the tensile strength of the formulation, a link between crosslink density and ultimate tensile strength (UTS) couldn’t be made. The decrease in the UTS and increase in extension at break is possibly caused by an increase in low molecular weight material present in the formulations and decrease in crosslink density. This could possibly increase the mobility of polymer chains which could increases flexibility.
- Full Text:
- Date Issued: 2016
- Authors: von Berg, Stuart , Hlangothi, Percy
- Date: 2016
- Subjects: Rubber, Reclaimed Rubber chemicals Tires -- Recycling
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/13149 , vital:27156
- Description: The amount of waste tyres being dumped is fast becoming a problem. These stockpiles take up valuable land and are an environmental and health problem. While incineration is the simplest way to recycle the used tyres it isn’t an efficient way to dispose of tyres. This research looks at developing a method for characterizing the New Reclamation Group (NRG) reclaim with the main focus on Hi-Res™ thermogravimetric analysis. Good quantification was possible using this technique. A trade off was established between resolution, sensitivity and time. While increasing the resolution allowed greater separation to be achieved the time for each experiment increased rapidly. Although kinetic models do exist for quantifying rubber components in vulcanized sample, they were not suitable for this study. When devulcanization causes significant molecular changes, such as with NRG reclaim, the decomposition profiles no longer match those of virgin materials. Formulations developed focused on mixing, rheometry, crosslink density and tensile properties. The NRG reclaim acted as a processing aid which lowered the maximum torque. This provides mixing safety as the temperature is decreased as a result of the lower torque. This effect was not seen with conventional reclaim. Rheometry tests indicated that the addition of the devulcanizates decreased the extent of cure. It was demonstrated that this could be linked to crosslink density. Testing of the 100%, 200%, 300% moduli correlated the crosslink density to the maximum torque. Although the addition of NRG reclaim reduced the tensile strength of the formulation, a link between crosslink density and ultimate tensile strength (UTS) couldn’t be made. The decrease in the UTS and increase in extension at break is possibly caused by an increase in low molecular weight material present in the formulations and decrease in crosslink density. This could possibly increase the mobility of polymer chains which could increases flexibility.
- Full Text:
- Date Issued: 2016
Catalytic oxidation of thioanisole using oxovanadium (IV)‐functionalized electrospun polybenzimidazole nanofibers
- Walmsley, Ryan S, Hlangothi, Percy, Litwinski, Christian, Nyokong, Tebello, Torto, Nelson, Tshentu, Zenixole R
- Authors: Walmsley, Ryan S , Hlangothi, Percy , Litwinski, Christian , Nyokong, Tebello , Torto, Nelson , Tshentu, Zenixole R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242083 , vital:51000 , xlink:href="https://doi.org/10.1002/app.38067"
- Description: Polybenzimidazole fibers, with an average diameter of 262 nm, were produced by the process of electrospinning. These fibers were used as a solid support material for the immobilization of oxovanadium(IV) which was achieved via a reaction with vanadyl sulfate. The oxovanadium(IV)-functionalized nanofibers were used as heterogeneous catalysts for the oxidation of thioanisole under both batch and pseudo-continuous flow conditions with great success. Under batch conditions near quantitative oxidation of thioanisole was achieved in under 90 min, even after four successive catalytic reactions. Under continuous conditions, excellent conversion of thioanisole was maintained throughout the period studied at flow rates of up to 2 mLh−1. This study, therefore, proposes that electrospun polybenzimidazole nanofibers, with their small diameters, impressive chemical and thermal stability, as well as coordinating benzimidazole group, may be a desirable support material for immobilization of homogeneous catalysts.
- Full Text:
- Date Issued: 2013
- Authors: Walmsley, Ryan S , Hlangothi, Percy , Litwinski, Christian , Nyokong, Tebello , Torto, Nelson , Tshentu, Zenixole R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/242083 , vital:51000 , xlink:href="https://doi.org/10.1002/app.38067"
- Description: Polybenzimidazole fibers, with an average diameter of 262 nm, were produced by the process of electrospinning. These fibers were used as a solid support material for the immobilization of oxovanadium(IV) which was achieved via a reaction with vanadyl sulfate. The oxovanadium(IV)-functionalized nanofibers were used as heterogeneous catalysts for the oxidation of thioanisole under both batch and pseudo-continuous flow conditions with great success. Under batch conditions near quantitative oxidation of thioanisole was achieved in under 90 min, even after four successive catalytic reactions. Under continuous conditions, excellent conversion of thioanisole was maintained throughout the period studied at flow rates of up to 2 mLh−1. This study, therefore, proposes that electrospun polybenzimidazole nanofibers, with their small diameters, impressive chemical and thermal stability, as well as coordinating benzimidazole group, may be a desirable support material for immobilization of homogeneous catalysts.
- Full Text:
- Date Issued: 2013
Oxovanadium (IV)-containing poly (styrene-co-4′-ethenyl-2-hydroxyphenylimidazole) electrospun nanofibers for the catalytic oxidation of thioanisole
- Walmsley, Ryan S, Litwinski, Christian, Antunes, Edith M, Hlangothi, Percy, Hosten, Eric C, McCleland, Cedric, Nyokong, Tebello, Torto, Nelson, Tshentu, Zenixole R
- Authors: Walmsley, Ryan S , Litwinski, Christian , Antunes, Edith M , Hlangothi, Percy , Hosten, Eric C , McCleland, Cedric , Nyokong, Tebello , Torto, Nelson , Tshentu, Zenixole R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241665 , vital:50959 , xlink:href="https://doi.org/10.1016/j.molcata.2013.07.018"
- Description: The catalytic fibers have been fabricated by the electrospinning of a copolymer of styrene and 2-(2′-hydroxy-4′-ethenylphenyl)imidazole {p(ST-co-VPIM)} followed by a reaction with a methanolic vanadyl solution to afford the oxovanadium(IV)-containing poly(styrene-co-4′-ethenyl-2-hydroxyphenylimidazole) fibers {p(ST-co-VPIM)-VO fibers}. The relationship between polymer concentration and fiber diameter was investigated, and at high concentration (20 wt%) the fibers were quite large (average diameter of 3.8 μm) but as the concentration was reduced fibers of much lower diameter were produced (0.6 μm using 8 wt%). The BET surface area for p(ST-co-VPIM) fibers (0.6 μm diameter) was 47.9 m2 g−1 and functionalization of p(ST-co-VPIM) with vanadyl resulted in an increase in surface area to 60.7 m2 g−1 for p(ST-co-VPIM)-VO. The presence of vanadyl was confirmed by XPS and EPR. The EPR spectral analyses depicted complex speciation of vanadium within these polymer supports. These catalytic fibers were applied under batch and continuous flow conditions for the catalytic oxidation of thioanisole using hydrogen peroxide. The continuous flow method gave excellent and constant conversion throughout the 10 h period studied. The leaching of vanadium from the fiber support was 4% over the 10 h period indicating a significant stability of the material.
- Full Text:
- Date Issued: 2013
- Authors: Walmsley, Ryan S , Litwinski, Christian , Antunes, Edith M , Hlangothi, Percy , Hosten, Eric C , McCleland, Cedric , Nyokong, Tebello , Torto, Nelson , Tshentu, Zenixole R
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241665 , vital:50959 , xlink:href="https://doi.org/10.1016/j.molcata.2013.07.018"
- Description: The catalytic fibers have been fabricated by the electrospinning of a copolymer of styrene and 2-(2′-hydroxy-4′-ethenylphenyl)imidazole {p(ST-co-VPIM)} followed by a reaction with a methanolic vanadyl solution to afford the oxovanadium(IV)-containing poly(styrene-co-4′-ethenyl-2-hydroxyphenylimidazole) fibers {p(ST-co-VPIM)-VO fibers}. The relationship between polymer concentration and fiber diameter was investigated, and at high concentration (20 wt%) the fibers were quite large (average diameter of 3.8 μm) but as the concentration was reduced fibers of much lower diameter were produced (0.6 μm using 8 wt%). The BET surface area for p(ST-co-VPIM) fibers (0.6 μm diameter) was 47.9 m2 g−1 and functionalization of p(ST-co-VPIM) with vanadyl resulted in an increase in surface area to 60.7 m2 g−1 for p(ST-co-VPIM)-VO. The presence of vanadyl was confirmed by XPS and EPR. The EPR spectral analyses depicted complex speciation of vanadium within these polymer supports. These catalytic fibers were applied under batch and continuous flow conditions for the catalytic oxidation of thioanisole using hydrogen peroxide. The continuous flow method gave excellent and constant conversion throughout the 10 h period studied. The leaching of vanadium from the fiber support was 4% over the 10 h period indicating a significant stability of the material.
- Full Text:
- Date Issued: 2013
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