- Title
- Excited state dynamics of zinc and aluminum phthalocyanine carboxylates
- Creator
- Idowu, Mopelola A I, Ogunsipe, Abimbola, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2007
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/271228
- Identifier
- vital:54523
- Identifier
- xlink:href="https://doi.org/10.1016/j.saa.2007.01.025"
- Description
- Photophysical parameters for zinc and aluminium tetracarboxylphthalocyanines (ZnTCPc and AlTCPc, respectively) and their octacarboxy substituted counterparts (ZnOCPc and AlOCPc) were studied. Data for the fluorescence quenching of the complexes by benzoquinone (BQ) were treated using the Stern–Volmer analysis, and the quenching was found to follow a diffusion-controlled (dynamic) bimolecular mechanism. Theoretical values of bimolecular rate constant for complex-BQ interactions were determined using the Stokes–Einstein–Smoluchowski model; and the values, together with the Stern–Volmer quenching constants were used in calculating the fluorescence lifetimes of the complexes. The thermodynamics of the MPc-BQ interaction, in terms of solvent reorientation energy is also discussed.
- Format
- computer, online resource, application/pdf, 1 online resource (5 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Idowu, M., Ogunsipe, A. and Nyokong, T., 2007. Excited state dynamics of zinc and aluminum phthalocyanine carboxylates. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 68(3), pp.995-999, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy volume 68 number 3 p. 995 2007 1386-1425
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | Excited state dynamics of zinc and aluminum phthalocyanine carboxylates.pdf | 639 KB | Adobe Acrobat PDF | View Details |