- Title
- Synthesis, photophysical and nonlinear optical behavior of neodymium based trisphthalocyanine
- Creator
- Sekhosana, Kutloana E, Amuhaya, Edith K, Khene, Samson M, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2015
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/241412
- Identifier
- vital:50937
- Identifier
- xlink:href="https://doi.org/10.1016/j.ica.2014.11.029"
- Description
- Tris-{1(4),8(11),15(18),22(25)-tetra(4-tertbutylphenoxy) phthalocyaninato} dineodymium (III) was synthesised and its nonlinear optical and fluorescence behavior was studied. Low fluorescence quantum yield (ФF = 0.03) was obtained with a fluorescence lifetime τF = 4.31 ns for this complex. Nonlinear optical parameters for the complex were determined using the Z-scan technique and the values of Im[χ(3)] and γ were of the order of 10−10 and 10−28 esu, respectively. Square wave voltammetry revealed three reduction and two oxidation couples for the complex.
- Format
- computer, online resource, application/pdf, 1 online resource (6 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Inorganica Chimica, Sekhosana, K.E., Amuhaya, E., Khene, S. and Nyokong, T., 2015. Synthesis, photophysical and nonlinear optical behavior of neodymium based trisphthalocyanine. Inorganica Chimica Acta, 426, pp.221-226, Inorganica Chimica volume 426 p. 221 2015 1873-3255
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Khene, Samson Mielie (Assoc Prof)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
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