- Title
- Photophysical, photochemical and electrochemical properties of water soluble silicon, titanium and zinc phthalocyanines
- Creator
- Masilela, Nkosiphile, Idowu, Mopelola, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2009
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/264496
- Identifier
- vital:53739
- Identifier
- xlink:href="https://doi.org/10.1016/j.jphotochem.2008.10.009"
- Description
- The photophysical, and photochemical properties of titanium, silicon and zinc octacarboxy phthalocyanine (OTiOCPc, (OH)2SiOCPc and ZnOCPc) and their tetrasulfonated counterparts (OTiTSPc, (OH)2SiTSPc and ZnTSPc) in phosphate-buffer solution (PBS), pH 10 were studied. The tetrasulfonated derivatives were also studied in the presence of a surfactant, cremophore EL (CEL) due to their high aggregation tendency in aqueous solutions. Triplet quantum yields ranged from 0.20 to 0.48 for MOCPcs and 0.32–0.65 for MTSPcs in the presence of CEL and in pH 10. High triplet lifetimes were observed for ZnTSPc (270 μs, in the presence of CEL) or ZnOCPc (130 μs) compared to values ranging from 50 to 70 μs for the rest of the complexes.
- Format
- computer, online resource, application/pdf, 1 online resource (7 pages), pdf
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Photochemistry and Photobiology A: Chemistry, Masilela, N., Idowu, M. and Nyokong, T., 2009. Photophysical, photochemical and electrochemical properties of water soluble silicon, titanium and zinc phthalocyanines. Journal of Photochemistry and Photobiology A: Chemistry, 201(2-3), pp.91-97, Journal of Photochemistry and Photobiology A: Chemistry volume 201 number 2 - 3 p. 91 2009 1010-6030
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Photophysical, photochemical and electrochemical properties of water soluble silicon, titanium and zinc phthalocyanines.pdf | 659 KB | Adobe Acrobat PDF | View Details Download |