Development of manganese phthalocyanine decorated with silver nanoparticles nanocomposite for improved electrocatalytic oxidation of hydrazine:
- Mpeta, Lekhetho S, Sen, Pinar, Nyokong, Tebello
- Authors: Mpeta, Lekhetho S , Sen, Pinar , Nyokong, Tebello
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148472 , vital:38742 , https://doi.org/10.1016/j.jelechem.2020.114173
- Description: In this study we report on the synthesis of tetrakis [4-(4-(5-chloro-1H-benzo [d]imidazol-2-yl) phenoxy phthalocyaninato] manganese (III) chloride (MnPc). The MnPc was first used to modify a glassy carbon electrode, followed by the growth of silver nanoparticles (AgNPs) onto the MnPc modified electrode to form MnPc-AgNPs modified electrode. The modified electrode was characterized using cydic voltammetry, chronoamperometry, scanning electrochemical microscopy and electrochemical impedance spectroscopy. The modified MnPc-AgNPs electrode was employed for the detection of hydrazine. The MnPc-AgNPs gave better current responses for electrooxidation of hydrazine relative to MnPc and AgNPs, individually. The catalytic rate constant was 1.90 x 10(5 )M(-1) S-1, with the detection limit (LoD) of 2.42 pM (using 3 sigma notation), and sensitivity of 61.56 mu A mM(-1), for MnPc-AgNPs. (C) 2020 Elsevier B.V. All rights reserved.
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- Authors: Mpeta, Lekhetho S , Sen, Pinar , Nyokong, Tebello
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148472 , vital:38742 , https://doi.org/10.1016/j.jelechem.2020.114173
- Description: In this study we report on the synthesis of tetrakis [4-(4-(5-chloro-1H-benzo [d]imidazol-2-yl) phenoxy phthalocyaninato] manganese (III) chloride (MnPc). The MnPc was first used to modify a glassy carbon electrode, followed by the growth of silver nanoparticles (AgNPs) onto the MnPc modified electrode to form MnPc-AgNPs modified electrode. The modified electrode was characterized using cydic voltammetry, chronoamperometry, scanning electrochemical microscopy and electrochemical impedance spectroscopy. The modified MnPc-AgNPs electrode was employed for the detection of hydrazine. The MnPc-AgNPs gave better current responses for electrooxidation of hydrazine relative to MnPc and AgNPs, individually. The catalytic rate constant was 1.90 x 10(5 )M(-1) S-1, with the detection limit (LoD) of 2.42 pM (using 3 sigma notation), and sensitivity of 61.56 mu A mM(-1), for MnPc-AgNPs. (C) 2020 Elsevier B.V. All rights reserved.
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New difluoroboron complexes based on N, O-chelated Schiff base ligands: Synthesis, characterization, DFT calculations and photophysical and electrochemical properties
- Sen, Pinar, Mpeta, Lekhetho S, Mack, John, Nyokong, Tebello
- Authors: Sen, Pinar , Mpeta, Lekhetho S , Mack, John , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186207 , vital:44473 , xlink:href="https://doi.org/10.1016/j.jlumin.2020.117262"
- Description: The synthesis of new Schiff bases and their dinuclear boron complexes is described, along with their characterization by 1H and 13C NMR, FT-IR, and UV–visible absorption spectroscopy, mass spectrometry, and EDX for elemental analysis. The optical and photophysical properties were examined in terms of their absorption and emission behavior, fluorescence quantum yields and fluorescence lifetimes. The flexible dinuclear boron complexes that are linked by a flexible carbon chain exhibited large Stokes shifts in the range from 92 nm to 115 nm in contrast to BODIPY dyes. Those properties make these complexes precious for applications in fluorescence materials. And also theoretical calculations were obtained by using Density Functional Theory (DFT) methods.
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- Authors: Sen, Pinar , Mpeta, Lekhetho S , Mack, John , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186207 , vital:44473 , xlink:href="https://doi.org/10.1016/j.jlumin.2020.117262"
- Description: The synthesis of new Schiff bases and their dinuclear boron complexes is described, along with their characterization by 1H and 13C NMR, FT-IR, and UV–visible absorption spectroscopy, mass spectrometry, and EDX for elemental analysis. The optical and photophysical properties were examined in terms of their absorption and emission behavior, fluorescence quantum yields and fluorescence lifetimes. The flexible dinuclear boron complexes that are linked by a flexible carbon chain exhibited large Stokes shifts in the range from 92 nm to 115 nm in contrast to BODIPY dyes. Those properties make these complexes precious for applications in fluorescence materials. And also theoretical calculations were obtained by using Density Functional Theory (DFT) methods.
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Nonlinear optical response and electrocatalytic activity of cobalt phthalocyanine clicked zinc oxide nanoparticles
- Mpeta, Lekhetho S, Sekhosana, Kutloano E, Nyokong, Tebello
- Authors: Mpeta, Lekhetho S , Sekhosana, Kutloano E , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186179 , vital:44471 , xlink:href="https://doi.org/10.1016/j.ica.2020.119661"
- Description: In this article, we report on the linking of cobalt tetrakis (4-pentyn-oxy) phthalocyanine (CoTPPc) to ZnO nanoparticles via click chemistry. Subsequently, electrocatalytic activity and nonlinear optical properties were investigated (the latter using an open Z-scan technique at 532 nm). The linking of CoTPPc with ZnO resulted in the lowest limiting intensity value of 0.27 J.Cm−2, the βeff (cmW−1) values were found to be 1.51 × 10-8 and 7.10 × 104 for ZnO and CoTPPc-ZnO respectively. The catalytic rate constants (M−1s−1) (and limits of detection) were 4.1 × 104 (12.87 µM), 5.7 × 104 (8.62 µM) and 7.36 × 104 (4.35 µM) for ZnO, CoTPPc and CoTPPc-ZnO. Hence linking ZnO nanoparticles to CoTPPc result in the enhancement of both nonlinear optical behaviour and catalytic activity.
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- Authors: Mpeta, Lekhetho S , Sekhosana, Kutloano E , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186179 , vital:44471 , xlink:href="https://doi.org/10.1016/j.ica.2020.119661"
- Description: In this article, we report on the linking of cobalt tetrakis (4-pentyn-oxy) phthalocyanine (CoTPPc) to ZnO nanoparticles via click chemistry. Subsequently, electrocatalytic activity and nonlinear optical properties were investigated (the latter using an open Z-scan technique at 532 nm). The linking of CoTPPc with ZnO resulted in the lowest limiting intensity value of 0.27 J.Cm−2, the βeff (cmW−1) values were found to be 1.51 × 10-8 and 7.10 × 104 for ZnO and CoTPPc-ZnO respectively. The catalytic rate constants (M−1s−1) (and limits of detection) were 4.1 × 104 (12.87 µM), 5.7 × 104 (8.62 µM) and 7.36 × 104 (4.35 µM) for ZnO, CoTPPc and CoTPPc-ZnO. Hence linking ZnO nanoparticles to CoTPPc result in the enhancement of both nonlinear optical behaviour and catalytic activity.
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The effects of asymmetry in combination with reduced graphene oxide nanosheets on hydrazine electrocatalytic detection on cobalt phthalocyanines
- Mpeta, Lekhetho S, Sen, Pinar, Nyokong, Tebello
- Authors: Mpeta, Lekhetho S , Sen, Pinar , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186023 , vital:44456 , xlink:href="https://doi.org/10.1002/elan.202060094"
- Description: New symmetric {tetrakis [4-(4-(5-chloro-1Hbenzo[d]imidazol-2-yl) phenoxy phthalocyaninato] Co (II) (CoTPc)} and low symmetry {tris tert butyl phenoxy mono [4-(4-(5-chloro-1H-benzo[d]imidazol-2-yl) phenoxy phthalocyaninato]} Co (II) (CoMPc) were successfully synthesised and combined with reduced graphene oxide nanosheets (rGONS) for electrocatalytic detection of hydrazine. Prior to electrocatalysis, the probes were characterised using cyclic voltammetry and electrochemical impedance spectroscopy. Chronoamperometry was used to determine catalytic rate constant and the limit of detection (LOD). CoMPc-rGONS gave catalytic rate constant and LOD of 1.37×106 M 1 s 1 and 0.82 μM respectively, rendering it a more suitable probe for hydrazine, due to low symmetry.
- Full Text:
- Authors: Mpeta, Lekhetho S , Sen, Pinar , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186023 , vital:44456 , xlink:href="https://doi.org/10.1002/elan.202060094"
- Description: New symmetric {tetrakis [4-(4-(5-chloro-1Hbenzo[d]imidazol-2-yl) phenoxy phthalocyaninato] Co (II) (CoTPc)} and low symmetry {tris tert butyl phenoxy mono [4-(4-(5-chloro-1H-benzo[d]imidazol-2-yl) phenoxy phthalocyaninato]} Co (II) (CoMPc) were successfully synthesised and combined with reduced graphene oxide nanosheets (rGONS) for electrocatalytic detection of hydrazine. Prior to electrocatalysis, the probes were characterised using cyclic voltammetry and electrochemical impedance spectroscopy. Chronoamperometry was used to determine catalytic rate constant and the limit of detection (LOD). CoMPc-rGONS gave catalytic rate constant and LOD of 1.37×106 M 1 s 1 and 0.82 μM respectively, rendering it a more suitable probe for hydrazine, due to low symmetry.
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