The structure of aliphatic amine adducts of uranyl acetylacetonate. III. Dioxobis(2,4-pentanedionato)mono (2-N-isopropylaminopentan-4-one)uranium(VI)
- Rodgers, A L, Nassimbeni, L R, Haigh, John M
- Authors: Rodgers, A L , Nassimbeni, L R , Haigh, John M
- Date: 1977
- Language: English
- Type: text , Article
- Identifier: vital:6419 , http://hdl.handle.net/10962/d1006552
- Description: Introduction: In two earlier structural determinations of compounds of this type we have shown that the conformation of the adduct moiety is dependent on the formation of intramolecular N-H...0 hydrogen bonds (part I: Haigh, Nassimbeni, Pauptit, Rodgers & Sheldrick, 1976; part II: Nassimbeni, Orpen, Pauptit, Rodgers & Haigh, 1977). We have carried out the present analysis to study the conformational effects on the ligand brought about by the steric influence of an isopropyl substituent at N.
- Full Text:
- Authors: Rodgers, A L , Nassimbeni, L R , Haigh, John M
- Date: 1977
- Language: English
- Type: text , Article
- Identifier: vital:6419 , http://hdl.handle.net/10962/d1006552
- Description: Introduction: In two earlier structural determinations of compounds of this type we have shown that the conformation of the adduct moiety is dependent on the formation of intramolecular N-H...0 hydrogen bonds (part I: Haigh, Nassimbeni, Pauptit, Rodgers & Sheldrick, 1976; part II: Nassimbeni, Orpen, Pauptit, Rodgers & Haigh, 1977). We have carried out the present analysis to study the conformational effects on the ligand brought about by the steric influence of an isopropyl substituent at N.
- Full Text:
The structure of aliphatic amine adducts of uranyl acetylacetonate. IV. Dioxobis(2,4-pentanedionato) mono(2-aminopentan-4-one)uranium(VI)
- Rodgers, A L, Nassimbeni, L R, Pauptit, R A, Orpen, G, Haigh, John M
- Authors: Rodgers, A L , Nassimbeni, L R , Pauptit, R A , Orpen, G , Haigh, John M
- Date: 1977
- Language: English
- Type: text , Article
- Identifier: vital:6420 , http://hdl.handle.net/10962/d1006555
- Description: Introduction: We have shown in three earlier determinations of aliphatic amine adducts of U02(AA)2 (part I: Haigh, Nassimbeni, Pauptit, Rodgers & Sheldrick, 1976; part II: Nassimbeni, Orpen, Pauptit, Rodgers & Haigh, 1977; part III: Rodgers, Nassimbeni & Haigh, 1977) that the conformation of the adduct is dependent on its ability to form hydrogen bonds. The present compound has two H atoms available for hydrogen bonding and may be regarded as the parent of the series.
- Full Text:
- Authors: Rodgers, A L , Nassimbeni, L R , Pauptit, R A , Orpen, G , Haigh, John M
- Date: 1977
- Language: English
- Type: text , Article
- Identifier: vital:6420 , http://hdl.handle.net/10962/d1006555
- Description: Introduction: We have shown in three earlier determinations of aliphatic amine adducts of U02(AA)2 (part I: Haigh, Nassimbeni, Pauptit, Rodgers & Sheldrick, 1976; part II: Nassimbeni, Orpen, Pauptit, Rodgers & Haigh, 1977; part III: Rodgers, Nassimbeni & Haigh, 1977) that the conformation of the adduct is dependent on its ability to form hydrogen bonds. The present compound has two H atoms available for hydrogen bonding and may be regarded as the parent of the series.
- Full Text:
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