Trophic importance of kelp-derived suspended particulate matter in a through-flow sub-Antarctic system
- Authors: Kaehler, Sven , Pakhomov, Evgeny A , Kalin, R M , Davis, S
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6876 , http://hdl.handle.net/10962/d1011624
- Description: Spatial dynamics of surface chlorophyll concentrations, diatom abundance and carbon and nitrogen stable isotope signatures of surface suspended particulate matter (SPM) were investigated during a bloom event observed in March 2003 in the vicinity of the sub-Antarctic Prince Edward Islands. The surface water composition was studied to estimate the overall importance and spatial extent of kelp derived SPM in the water column of the islands. It was observed that high chlorophyll concentrations (up to 2 mg m–3) between and downstream of the islands could not be explained by the development of the diatom bloom. Instead, microscopic and stable isotope analyses suggested that the chlorophyll signal was largely derived from the residual chlorophyll in fresh and decaying particles of small fragments of the kelp Macrocystis laevis, an endemic kelp species abundant along the shoreline of the islands. The findings of this study suggest that the dietary subsidy of kelp-derived carbon and nitrogen to benthic communities and possibly the plankton is not limited to the vicinity of kelp beds, but rather is a widespread phenomenon between the islands. Due to the dominating unidirectional Antarctic Circumpolar Current, large quantities of kelp-derived SPM may be transported and utilised tens of kilometres downstream of the islands.
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U Dzhenelela Kha Vhulanguli Ha Zwiko Zwa Madi
- Authors: Burt, Jane C , du Toit, Derick , Neves, David , Pollard, Sharon , Berold, Robert , Stanford, Mindy
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437657 , vital:73400 , ISBN 1-77005-504-5 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/TT291-06.pdf
- Description: Mulayo wa Lushakawa Madi (1998) u vulela ndila vhathu zwavho uri vha kone u dzhenelela kha Ndangulo ya Zwiko zwa Madi (WRM). Bugu iyi i amba nga uri u shela mulennzhe kana u dzhenelela ndi mini kha nyito. Thodisiso ya bugu iyi yo yo itwa nga tshigwada tsha vho gudelaho Ndangulo ya Zwiko zwa Madi (WRM) vhukati ha 2003 na 2005. Vhatodisisi vho da na themendelo mbili dza ndeme: 1. Kupfesesele kwashu kwa ipfi “u dzhenelela” zwi tou vha na vhukwamani thwii na uri ri langa hani zwiko zwa madi. Zwenezwo ri tea u khwathisedza ndivho yashu na tshenzhemo kha u dzhenelela kha WRM.( Ndangulo ya Zwiko zwa Madi) 2. Ri toda tsivhudzo yo teaho musi ri tshi pulana u dzhenelela kha zwa zwa WRM, hone tsivhudzo iyi i tea u kona u shandukisea uri maitele a u dzhenelela avhe o teaho kha nyimele inwe nainwe kana dzothe. Bugu iyi yo khethekanywa nga kha zwipida zwivhili: Tshipida, thoho U dzhenelela kha Ndangulo ya Zwiko zwa Madi kha la Afrika Tshipembe , zwi sumbedza uri mihumbulo yo fhambanho ya vhathu na zwi anganyelwaho zwa tu-tuwedza uri vha nga langa hani zwiko zwa madi.
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U Ho Ba Le Seabo Taolong Ya Mehlodi Ya Metsi Afrika Borwa
- Authors: Burt, Jane C , du Toit, Derick , Neves, David , Pollard, Sharon , Berold, Robert , Stanford, Mindy
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437625 , vital:73398 , ISBN 1-77005-503-7 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/TT290-06.pdf
- Description: Molao wa Naha wa Metsi (1998) o neha batho monyetla wa ho ba le seabo Taolong ya Mehlodi ya Metsi. Buka ena e bua ka se bolelwang ke ho ba le seabo. Diphuputso tsa buka ena di entswe ke sehlopha sa basebetsi ba diprofeshenale tsa Taolo ya Mehlodi ya Metsi mahareng a 2003 le 2005. Bafuputsi ba ile ba fihlela diqeto tsa bohlokwa tse pedi: 1. Kutlwisiso ya rona ya mohopolo wa “ho ba le seabo” e ama ka ho toba tsela eo re laolang mehlodi ya rona ya metsi. Ka hoo re lokela ho tebisa tsebo ya rona le boiphihlelo ba ho ba le seabo Taolong ya Mehlodi ya Metsi. 2. Re hloka tataiso e sebetsang ha re rera ho ba le seabo Taolong ya Mehlodi ya Metsi, empa tataiso ena e tshwanela ho kgona ho fetoha le mabaka hore mofuta wa ho ba le seabo o tshwanelehe bakeng sa boemo kapa ketsahalo ka nngwe.
- Full Text:
Ukuthabatha Inxaxheba Kulawulo Lwemithombo Yamanzi Emzantsi Afrika
- Authors: Burt, Jane C , du Toit, Derick , Neves, David , Pollard, Sharon , Berold, Robert , Stanford, Mindy
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437670 , vital:73401 , ISBN 1-77005-505-3 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/TT292-06.pdf
- Description: UmThetho weSizwe waManzi (National Water Act) (1998) uvula indlela yokuba abantu nje abaqhelekileyo bathabathe inxaxheba kuLawulo lwemiThombo yaManzi (Water Resource Management) (WRM). Le ncwadi ixoxa ngokuba ukuthabatha inxaxheba kuthetha ntoni na xa kusenziwa. Uphando lwale ncwadi lwenziwe nga-magcisa angabasebenzi eqela le-WRM phakathi kuka-2003 no-2005. Abaphathi baf-ikelela kwizigqibo zemiba emibini ebalulekileyo: 1. Ukuqonda kwethu “ukuthabatha inxaxheba” kuchaphazela ngqo ukuba siyiphatha njani imithombo yamanzi. Ngoko ke kufuneka sense nzulu ulwazi lwethu kunye namava okuthabatha inxaxheba kwi-WRM. 2. Sifuna ukhokelo olusebenzayo xa sicebela uthabatho nxaxheba lwe-WRM, kodwa olu khokelo kufuneka lube nokuguquka ukwenzela ukuba ubunjani bothabatho nxaxheba lufaneleke kwisimo okanye kumxholo ngamnye.
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Understanding educator-mediated conflict resolution in a preschool environment: the experiences and feelings of preschool educators
- Authors: Cakwe, Mandisa
- Date: 2006
- Subjects: Education, Preschool , Early childhood education , Preschool children , Conflict management
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2943 , http://hdl.handle.net/10962/d1002452 , Education, Preschool , Early childhood education , Preschool children , Conflict management
- Description: This thesis discusses the experiences and feelings of preschool educators when resolving situations of conflict between preschool children. Data was collected by means of semistructured individual interviews with preschool educators and a video recorder recording conflict situations among preschool children focusing on educator resolution strategies. Grounded theory was used as a data analysis technique to analyse the data collected. The analysis revealed that the preschool educators under study do not use mediation as a conflict resolution strategy but use various strategies that include, prevention, directive approach, arbitration, myths and threats and rules. Data analysis also revealed that these preschool educators encounter experiences and feelings before, while and after intervening in the conflict situations of children. These findings imply that preschool educators lack the professional skill of conflict resolution. This suggests an urgent need of restructuring of the preschool educator’s training to include conflict resolution training as one of their important component. Educators and parents also need to be consulted or involved in the process of restructuring the training.
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Understanding workplace-based learning contexts to inform curriculum development: the case of a Level 5 Environmental Education, Training and Development Practice Qualification
- Authors: Wigley, Jonathan James
- Date: 2006
- Subjects: South African Qualifications Authority National Qualifications Framework (South Africa) Environmental education -- Study and teaching -- South Africa Curriculum planning -- South Africa Competency-based education -- South Africa Vocational qualifications -- South Africa Education and state -- South Africa Education -- Standards -- South Africa Education, Higher -- South Africa -- Standards
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1808 , http://hdl.handle.net/10962/d1003694
- Description: This is an interpretive case study that explores the workplace epistemologies and institutional structures of two nested cases within the broader context of the Environmental Education, Training and Development Practices - Level 5 qualification (EETDP qualification) that is registered on the South African National Qualifications Framework. The study provides insights to inform EETDP curriculum development that is enabling of reflexive environmental education and training processes. The study develops an understanding of workplace epistemologies related to environment and education, the structural factors that enable and constrain agency of environmental educators and the role of reflexivity in practice and in education in two nested cases: the agricultural and local government sectors. It draws on findings from workshops, semistructured interviews and document analysis of education materials in these two nested cases. The study notes that there are diverse and seemingly ambiguous understandings of both environment/sustainability and education processes in the two nested cases. This ambiguity seems to relate to environmental education practitioners drawing on different forms of knowledge, including differentiated or theoretical knowledge, and 'common-sense' ways of knowing, in their education practice. The understandings related to theoretical knowledge are, in both nested cases, dominated by scientific or technical understandings where environment is understood in the terms of the natural sciences and education is seen in instrumentalist terms as the transfer of mainly technical environmental knowledge to learners in order to effect behaviour change. The study opens up deeper understandings of the epistemological, socio-cultural and structural features of context, in the two nested cases, that have a bearing on environmental educators. It provides insights into workplace structures that can be both enabling and constraining of agency and notes that the causal power of structures to enable or constrain does not lie only in the structures but also in relation to the intentionality of the environmental education practitioners/agents. The study then examines reflexivity as one of the means through which environmental educators in the nested cases are able to consider appropriate actions or responses to structural constraints or enablements. Based on the insights offered by the research findings, the study makes recommendations for the EETDP curriculum development. It frames these recommendations within an understanding of curriculum as a contextualised social process that involves structural aspects of curriculum such as materials, as well as socio-cultural processes such as learning on the course and in the workplace.
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Unique electrochemical behavior of tantalum (V) phthalocyanine
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/286139 , vital:56243 , xlink:href="https://doi.org/10.1142/S1088424606000090"
- Description: The electrochemical and spectroscopic behavior of tantalum(V) phthalocyanine are presented. The NMR spectra is consistent with the lack of symmetry of the complex. Cyclic (CV) and square wave (SWV) voltammetries, and spectroelectrochemistry, were employed in the study of the complex. Two one-electron reductions and a simultaneous 4-electron reduction were observed. Reduction occurs first at the metal to form a Ta(IV) species, followed by ring based processes.
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Unstable ironies: narrative instability in Herman Charles Bosman's "Oom Schalk Lourens" series
- Authors: Davis, Rebecca
- Date: 2006
- Subjects: Bosman, Herman Charles, 1905-1951 -- Criticism and interpretation , Irony in literature , Narration (Rhetoric)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2215 , http://hdl.handle.net/10962/d1002258 , Bosman, Herman Charles, 1905-1951 -- Criticism and interpretation , Irony in literature , Narration (Rhetoric)
- Description: This thesis examines the narrative situation within Herman Charles Bosman’s “Oom Schalk Lourens” series of stories, focussing on the nature of the relationship between author and narrator. In particular, it seeks to trace the source of the multiple ironies at work in the texts. It has been customary for critics in the past to claim that the irony within the stories stems from Bosman, operating authorially ‘above’ Oom Schalk. In terms of this theory, Oom Schalk is read as being largely unaware of the inconsistencies and contradictions within his narrative. It is the claim of this thesis, however, that Oom Schalk is the self-aware creator of the texts’ ironies much of the time. Chapter 1 commences with an attempt at defining irony, and provides a brief overview of the history of its deployment within South African literature before discussing the literary genre which Bosman was to exploit as his ironic vehicle: the “oral-style” short story. Chapter 2 examines Wayne C. Booth’s notions of “stable” and “unstable” irony: the irony of the Oom Schalk stories has, in the past, been classified as belonging to the former category, but this thesis attempts to show that its inconsistent deployment within the stories consigns it more accurately to the latter. Chapter 3 offers an assessment of the extrinsic contexts relevant to the analysis: the context of the stories’ publication, and the likely composition of Bosman’s reading public. Chapter 4 begins to examine the distance between implied author and implied narrator in the stories. Chapters 5, 6 and 7 subject stories dealing with the themes of art, race and land to detailed analysis in order to examine the shifting – and progressively, though unevenly, diminishing – distance between Bosman and Oom Schalk. The thesis concludes that the degree to which the ironic distance between author and narrator fluctuates within, and between, the stories, results in a narrative situation which must be classified as fundamentally unstable.
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Urban forestry–A cinderella science in South Africa?
- Authors: Shackleton, Charlie M
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183092 , vital:43911 , xlink:href="https://doi.org/10.2989/10295920609505255"
- Description: The benefits of forests (in their broadest sense) and of trees to the natural environment and rural communities are well known throughout the world, including in South Africa (e.g. see chapters in Lawes et al. 2004). The presence of these benefits has also been extrapolated to urban situations, where natural forests and veld might be left in situ, or trees planted in public spaces, or in private gardens. These benefits span the social, aesthetic, health, environmental and economic spheres.
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Urban fuelwood demand and markets in a small town in South Africa: Livelihood vulnerability and alien plant control
- Authors: Shackleton, Charlie M , McConnachie, Matthew M , Chauke, Maphambe I , Mentz, J , Sutherland, F , Gambiza, James , Jones, R
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181224 , vital:43710 , xlink:href="https://doi.org/10.1080/13504500609469697"
- Description: Fuelwood is the primary energy for most households throughout the developing world. With increasing urbanization and declining local availability of fuelwood, a growing proportion of households obtain their fuelwood by purchasing it. These fuelwood markets are the key nexus in supply and demand scenarios and can be potentially significant points for intervention to address energy security amongst the urban poor. This paper reports on the fuelwood demand and marketing in a small town in South Africa. Despite the availability of more modern fuels and state subsidization of electricity, fuelwood was still used by half the households. Annual demand was 1.2 t per household. Over half of the households bought their fuelwood requirements because local stocks were limited. Those households that did collect their own fuelwood were significantly poorer than households that purchased fuelwood, as well as households that did not use fuelwood at all. Fuelwood markets operated through 45-60 vendors who transported fuelwood from further afield. Income from the fuelwood trade was low, but was strongly linked to hours worked. Thus, vendors working a full week did earn a meaningful income, especially in the context of high unemployment in the area. Fuelwood vendors also provided casual employment opportunities for unskilled labour. Most vendors harvested fuelwood from commonage lands, with most of the wood being from alien species. Local stocks of wood are declining in the face of constant transformation of commonage to residential areas, and a national water and biodiversity conservation programme to eradicate alien plants. This decline poses a threat to the financial viability of fuelwood markets. Yet, an opportunity exists to incorporate the vendors into the alien plant clearing programme, since they already perform such a function.
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Urban-rural contrasts in Arbor Week in South Africa
- Authors: Guthrie, G , Shackleton, Charlie M
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6631 , http://hdl.handle.net/10962/d1006823
- Description: Trees provide people with environmental benefits. Greening projects have been implemented worldwide, but many of them have frustratingly low participation levels. In South Africa, tree-planting campaigns such as the national Arbor Week are generally aimed at schools. Because of the remoteness of rural schools, there are urban / rural disparities in standards of education, infrastructure and support provided at schools, and hence we hypothesized that these disparities would be mirrored in tree-planting activities associated with national Arbor Week. In the study reported here, 236 urban and rural schools were assessed by means of postal surveys and subsampled via direct interviews, as to their participation in Arbor Week activities, the provision of trees, constraints to participation, and the perceived benefits of planting trees. Very few urban schools had never participated in any Arbor Week activities, whereas one-fifth of rural ones had never participated in any way. Urban schools participated in a greater number of Arbor Week activities than rural schools, including tree-planting, displaying posters and having speeches. Thus, overall information about Arbor Week is lacking in rural areas compared to urban ones. Rural schools derived more benefits from planting trees, with shade and education being the primary benefits overall. Rural schools were supplied with trees by NGOs, whereas urban schools received trees from individual or company donations. The major constraints to tree-planting are livestock damage, water shortages, vandalism and theft. These obstacles need to be addressed in a holistic fashion in order to improve the participation and success of National Arbor Week as a vehicle for tree-planting and environmental awareness.
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Using experiential learning to facilitate pharmacy students' understanding of patients' medication practice in chronic illness
- Authors: Williams, Kevin F
- Date: 2006
- Subjects: Chronic diseases -- Chemotherapy Chronically ill -- Care Pharmacy -- Study and teaching Pharmacy -- Practice Social medicine Health -- Sociological aspects Diseases -- Sociological aspects Health -- Psychological aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1322 , http://hdl.handle.net/10962/d1003955
- Description: This study originates from experiences which led me to question the way pharmacists are equipped to advise and support the medicine-taking practice of patients using chronic medication. The study offers a critical theoretical consideration of underlying perspectives informing pharmacy education. I propose following a critical realist ontological perspective, a social realist understanding of social structure and human agency, and a sociocultural epistemology. Based on these perspectives, I consider a sociological critique of ‘health’, ‘disease’, ‘illness’ and ‘sickness’ perspectives on medicine-taking, and of pharmacy as a profession. I then propose an experiential learning approach, with an emphasis on developing reflexivity through affective learning. I follow this with an illustrative case study. Following a critical discourse analysis of student texts from the case study, I conclude that there is evidence that experiential learning may prove useful in developing pharmacy students’ reflexive competency to support the provision of pharmaceutical care to patients using chronic medications.
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UV-Visible and Electrochemical Monitoring of Carbon Monoxide Release by Donor Complexes to Myoglobin Solutions and to Electrodes Modified with Films Containing Hemin
- Authors: Obirai, Joseph C , Hamadi, Sara , Ithurbide, Aurélie , Wartelle, Corinne , Nyokong, Tebello , Zagal, José H , Top, Siden , Bedioui, Fethi
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283906 , vital:56001 , xlink:href="https://doi.org/10.1002/elan.200603571"
- Description: This study reports on the evaluation of the CO donating behavior of tricarbonyl dichloro ruthenium(II) dimer ([Ru(CO)3Cl2]2) and 1,3-dimethoxyphenyl tricarbonyl chromium (C6H3(MeO)2Cr(CO)3) complex by UV-visible technique and electrochemical technique. The CO release was monitored by following the modifications of the UV-visible features of MbFe(II) in phosphate buffer solution and the redox features of reduced Hemin, HmFe(II), confined at the surface of a vitreous carbon electrode. In the latter case, the interaction between the hemin-modified electrode and the released CO was seen through the observation of an increase of the reduction current related to the FeIII/FeII redox process of the immobilized porphyrin. While the ruthenium-based complex, ([Ru(CO)3Cl2]2), depended on the presence of Fe(II) species to release CO, it was found that the chromium-based complex released spontaneously CO. This was facilitated by illuminating and/or simple stirring of the solution containing the complex.
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Valuation of communal area livestock benefits, rural livelihoods and related policy issues
- Authors: Dovie, Delali B K , Shackleton, Charlie M , Witkowski, Ed T F
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6627 , http://hdl.handle.net/10962/d1006819
- Description: The multiple benefits from livestock production to rural households are evaluated in Thorndale, a communal area of the Limpopo Province South Africa. Monetary values of livestock products are presented. Values from most previous studies are static (and thus outdated), as a result of conceptual and methodological shifts. The net monetary value of the direct benefits from livestock was estimated as $656 per household/annum, excluding the holding of cattle for savings. The net value is equivalent to 22.7% of the value of the other livelihood sources that were considered, and inclusive of cash income streams, crops, and secondary woodland resources. A net 168% herd increase in livestock was recorded between 1993 and 1999. More households owned goats compared to cattle, and cattle were important for use as draught power, and for milk. Households without livestock benefited through gifts and services, valued at $33 per household/annum. Policy concerns are the provision of adequate market and pricing mechanisms for communal area livestock, tailored savings, investment support, credit schemes, and infrastructure. An appropriate multipurpose benefit production model, other than a commercialised model is suggested for the sector.
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Variation in the timing of reproduction of the four-striped field mouse, Rhabdomys pumilio, in the Eastern Cape Province, South Africa
- Authors: Jackson, Claire , Bernard, Ric T F
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/447101 , vital:74584 , https://doi.org/10.1080/15627020.2006.11407367
- Description: We used the four-striped field mouse, Rhabdomys pumilio (Sparrmann, 1784), to test the hypothesis that reproduction in a small, short-lived mammal will be opportunistic, characterized by temporal and spatial variation in the timing of events, and only be inhibited under harsh and predictable winter conditions. Field mice were trapped for three years in two regions of the Eastern Cape Province of South Africa, one that experienced a predictable and harsh winter (Mountain Zebra National Park; MZNP) and the other which experienced a milder winter (Thomas Baines Nature Reserve; TBNR). There was no winter inhibition of reproduction at TBNR, while at MZNP female reproductive activity was inhibited but males continued to produce spermatozoa in winter. We interpret this flexibility in the timing of reproduction as supporting an opportunistic reproductive strategy which may be an adaptation to the seasonal and often unpredictable climate of the region.
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Verb agreement and the syntax of ciNsenga relative clauses
- Authors: Simango, Silvester R
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/469278 , vital:77228 , https://doi.org/10.2989/16073610609486421
- Description: Relativisation of a non-subject NP in ciNsenga (Bantu) results in the inversion of the subject and the appearance on the verb of a prefix which agrees with the relativised noun. Recent studies on Bantu relative constructions (for example, Demuth and Harford, 1999; Ngonyani, 1999; 2001) have shown that subject inversion results from the verb raising from I to C, and that this occurs only when the relative pronoun is a prosodic clitic and not a phonological word. When the relative pronoun has the status of a phonological word it blocks verb raising and thus subject inversion does not occur. In ciNsenga, however, subject inversion occurs despite the fact that the relative pronoun constitutes a phonological word. Drawing on the insights of Kayne (1994) this paper argues that the relative pronoun does not occupy the C position as is generally assumed, but that it occupies the head position of the moved DP, which itself occupies the Spec position of CP (which equates to Topic Phrase in the current study). This leaves the C position available for the inflected verb to move into.
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Vice Chancellor New staff welcome address, 2006
- Authors: Badat, Saleem
- Date: 2006
- Subjects: Rhodes University
- Language: English
- Type: text
- Identifier: vital:7645 , http://hdl.handle.net/10962/d1015773
- Full Text:
Virginity testing in South Africa: re-traditioning the postcolony
- Authors: Vincent, Louise
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141511 , vital:37981 , DOI: 10.1080/13691050500404225
- Description: Umhlanga is a ceremony celebrating virginity. In South Africa, it is practiced, among others, by the Zulu ethnic group who live mainly in the province of KwaZulu Natal. After falling into relative disuse in the Zulu community, the practice of virginity testing made a comeback some 10 years ago at around the time of the country's first democratic election and coinciding with the period when the HIV pandemic began to take hold. In July 2005 the South African Parliament passed a new Children's Bill which will prohibit virginity testing of children. The Bill has been met with outrage and public protest on the part of Zulu citizens. Traditional circumcision rites are also addressed in the new bill but are not banned. Instead, male children are given the right to refuse to participate in traditional initiation ceremonies which include circumcision. This paper asks why the practice of virginity testing is regarded as so troubling to the new democratic order that the state has chosen to take the heavy‐handed route of banning it. The paper further asks why the state's approach to traditional male circumcision has been so different to its approach to virginity testing. Finally, the paper asks what these two challenging cases in the country's new democracy tell us about the nature of liberal democratic citizenship in South Africa 10 years after apartheid's formal demise.
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Voltammetric analysis of pesticides and their degradation: A case study of Amitraz and its degradants
- Authors: Brimecombe, Rory Dennis
- Date: 2006
- Subjects: Hydrolysis , Biodegradation , Voltammetry , Pesticides -- Biodegradation , Pesticides -- Environmental aspects , Acaricides , Acaricides -- Physiological effect
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4131 , http://hdl.handle.net/10962/d1015724
- Description: Amitraz is a formamide acaricide used predominantly in the control of ectoparasites in livestock and honeybees. Amitraz hydrolysis is rapid and occurs under acidic conditions, exposure to sunlight and biodegradation by microorganisms. The main hydrolysis product of amitraz, 2,4-dimethylaniline, is recalcitrant in the environment and toxic to humans. An electrochemical method for the determination of total amitraz residues and its final breakdown product, 2,4-dimethylaniline, in spent cattle dip, is presented. Cyclic voltammetry at a glassy carbon electrode showed the irreversible oxidation of amitraz and 2,4-dimethylaniline. A limit of detection in the range of 8.5 x 10⁻⁸ M for amitraz and 2 x 10⁻⁸ M for 2,4-dimethylaniline was determined using differential pulse voltammetry. Feasibility studies in which the effect of supporting electrolyte type and pH had on electroanalysis of amitraz and its degradants, showed that pH affects current response as well as the potential at which amitraz and its degradants are oxidised. Britton-Robinson buffer was found to be the most suitable supporting electrolyte for detection of amitraz and its degradants in terms of sensitivity and reproducibility. Studies performed using environmental samples showed that the sensitivity and reproducibility of amitraz and 2,4-dimethylaniline analyses in spent cattle dip were comparable to analyses of amitraz and 2,4-dimethylaniline performed in Britton-Robinson buffer. In addition, the feasibility qf measuring amitraz and 2,4-dimethylaniline in environmental samples was assessed and compared to amitraz and 2,4-dimethylaniline analyses in Britton-Robinson buffer. Amitraz and 2,4-dimethylaniline were readily detectable in milk and honey. Furthermore, it was elucidated that 2,4-dimethylaniline can be metabolised to 3-methylcatechol by Pseudomonas species and the proposed breakdown pathway is presented. The biological degradation of amitraz and subsequent formation of 2,4-dimethylaniline was readily monitored in spent cattle dip. The breakdown of amitraz to 2,4-dimethylaniline and then to 3-MC was monitored using cyclic voltammetry.
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What does the movement of the Phloem-mobile symplastic tracer, 5,6-carboxyfluorescein in shoots of Pisum Sativum L. Indicate - the existence of a symplastic transport system? - a bid to answer some puzzling questions
- Authors: Ade-Ademilua, Omobolanle Elizabeth , Botha, Christiaan E J
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6492 , http://hdl.handle.net/10962/d1004475 , http://dx.doi.org/10.3923/ajpp.2006.127.131
- Description: Like other members of the Fabaceae, the minor veins of Pisum are categorized as a closed system termed type 2 minor vein configuration due to the presence of few or no plasmodesmal connections between the sieve element-transfer cell complex (SE-TCC) and the adjacent cells (Gamalei, 1989; van Bel and Gamalei, 1991) Pisum is classified further into the category of type 2 b minor vein configuration due to the presence of transfer cells with the characteristic wall ingrowths in the minor vein phloem (Gamalei, 1989). According to van Bel et al. (1992), there is a correlation between minor vein configuration and phloem loading. However, by reason of low plasmodesmal frequency, the pathway of the flow of assimilates in plants with type 2 minor vein configuration is considered to be apoplasmic (Gamalei, 1989; van Bel and Gamalei, 1991). Therefore, present reports on the movement of phloem-mobile 5,6-carboxyfluorescein, a known symplamically transported compound between pea leaflets raises some doubts on the accession that transport within the phloem in pea is strictly apoplasmic. In this study we look at different points of arguments and try to offer our explanation and conclusions on the transport pathways that are likely to exist in Pisum.
- Full Text: false