Three's a crowd: the process of triadic translation in a South African psychiatric institution
- Authors: Slabbert, Meggan
- Date: 2010
- Subjects: Mental health services -- South Africa -- Eastern Cape , Psychiatric hospitals -- South Africa -- Eastern Cape , Translating and interpreting -- Psychological aspects , Translating and interpreting -- Social aspects , Content analysis (Communication) , South Africa -- Languages -- Translating and interpreting , Intercultural communication -- South Africa -- Eastern Cape , Culture conflict -- South Africa -- Eastern Cape , Communication and culture -- South Africa -- Eastern Cape , Physician and patient -- South Africa -- Eastern Cape , Communication in medicine -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3056 , http://hdl.handle.net/10962/d1002565 , Mental health services -- South Africa -- Eastern Cape , Psychiatric hospitals -- South Africa -- Eastern Cape , Translating and interpreting -- Psychological aspects , Translating and interpreting -- Social aspects , Content analysis (Communication) , South Africa -- Languages -- Translating and interpreting , Intercultural communication -- South Africa -- Eastern Cape , Culture conflict -- South Africa -- Eastern Cape , Communication and culture -- South Africa -- Eastern Cape , Physician and patient -- South Africa -- Eastern Cape , Communication in medicine -- South Africa -- Eastern Cape
- Description: Mental health care in South Africa has long been governed by inequalities (Foster & Swartz, 1997). During apartheid, those who did not speak English and Afrikaans could not access mental health services in the same way as those who did (Foster & Swartz, 1997). One main reason for this is the majority of mental health practitioners could not, and were not required to speak languages other than English and Afrikaans (Swartz, 1991). The South African mental health literature suggests that language and communication must be prioritised if there is to be an improvement in mental health care services for those individuals who do not speak English and Afrikaans (Bantjes, 1999; Drennan & Swartz, 1999; Swartz & Drennan, 2000; Swartz & MacGregor, 2002). Drawing on Prasad's (2002) interpretation of Gadamer's critical hermeneutic theory and utilising thematic networks analysis (Attride-Stirling, 2001), this study investigated the process of translated clinical assessment interviews within a psychiatric hospital in the Eastern Cape Province within South Africa. Results of the study revealed that contextual factors, issues concerning linguistic and cultural heritage, clinicians' role expectations regarding translators' role performance, as well as relational dynamics regarding individual levels of control and influence within the translation triad, all impacted on the effectiveness of communication, translation and service provision. These fmdings are supported by literature on the theory and practice of translation that identifies these issues as prominent (Robinson, 2003). Specific recommendations regarding the formalisation of translation practices within the hospital setting, as well as the familiari~ation of clinical practitioners and psychiatric nurses with the intricacies of translation processes are offered.
- Full Text:
- Date Issued: 2010
- Authors: Slabbert, Meggan
- Date: 2010
- Subjects: Mental health services -- South Africa -- Eastern Cape , Psychiatric hospitals -- South Africa -- Eastern Cape , Translating and interpreting -- Psychological aspects , Translating and interpreting -- Social aspects , Content analysis (Communication) , South Africa -- Languages -- Translating and interpreting , Intercultural communication -- South Africa -- Eastern Cape , Culture conflict -- South Africa -- Eastern Cape , Communication and culture -- South Africa -- Eastern Cape , Physician and patient -- South Africa -- Eastern Cape , Communication in medicine -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3056 , http://hdl.handle.net/10962/d1002565 , Mental health services -- South Africa -- Eastern Cape , Psychiatric hospitals -- South Africa -- Eastern Cape , Translating and interpreting -- Psychological aspects , Translating and interpreting -- Social aspects , Content analysis (Communication) , South Africa -- Languages -- Translating and interpreting , Intercultural communication -- South Africa -- Eastern Cape , Culture conflict -- South Africa -- Eastern Cape , Communication and culture -- South Africa -- Eastern Cape , Physician and patient -- South Africa -- Eastern Cape , Communication in medicine -- South Africa -- Eastern Cape
- Description: Mental health care in South Africa has long been governed by inequalities (Foster & Swartz, 1997). During apartheid, those who did not speak English and Afrikaans could not access mental health services in the same way as those who did (Foster & Swartz, 1997). One main reason for this is the majority of mental health practitioners could not, and were not required to speak languages other than English and Afrikaans (Swartz, 1991). The South African mental health literature suggests that language and communication must be prioritised if there is to be an improvement in mental health care services for those individuals who do not speak English and Afrikaans (Bantjes, 1999; Drennan & Swartz, 1999; Swartz & Drennan, 2000; Swartz & MacGregor, 2002). Drawing on Prasad's (2002) interpretation of Gadamer's critical hermeneutic theory and utilising thematic networks analysis (Attride-Stirling, 2001), this study investigated the process of translated clinical assessment interviews within a psychiatric hospital in the Eastern Cape Province within South Africa. Results of the study revealed that contextual factors, issues concerning linguistic and cultural heritage, clinicians' role expectations regarding translators' role performance, as well as relational dynamics regarding individual levels of control and influence within the translation triad, all impacted on the effectiveness of communication, translation and service provision. These fmdings are supported by literature on the theory and practice of translation that identifies these issues as prominent (Robinson, 2003). Specific recommendations regarding the formalisation of translation practices within the hospital setting, as well as the familiari~ation of clinical practitioners and psychiatric nurses with the intricacies of translation processes are offered.
- Full Text:
- Date Issued: 2010
Tillage and crop rotation impacts on soil, quality parameters and maize yield in Zanyokwe Irrigation Scheme, South Africa
- Authors: Njaimwe, Arnold Ngare
- Date: 2010
- Subjects: No-tillage , Soil mechanics , Soils -- Quality , Cover crops , Corn -- Irrigation
- Language: English
- Type: Thesis , Doctoral , PhD (Soil Science)
- Identifier: vital:11962 , http://hdl.handle.net/10353/460 , No-tillage , Soil mechanics , Soils -- Quality , Cover crops , Corn -- Irrigation
- Description: Intensive tillage and monoculture cropping practices reduce soil C accumulation hence increasing soil vulnerability to chemical, physical and biological degradation. This study focussed on enhancing biomass production of wheat and oat winter cover crops as a means of increasing C sequestration in the low organic C soils of the central part of Eastern Cape Province. The specific objectives were (i) to evaluate the short-term effects of no till and cereal-fallow based crop rotations on; soil organic matter related parameters, pH and electrical conductivity, (ii) soil bulk density, water retention and aggregate stability, (iii) soil microbial biomass C and N, mineralizable N, soil respiration, and dehydrogenase enzyme activity, (iv) grain yield, soil nutrient concentration (N, P and K) and their uptake by maize, and (v) to identify soil parameters with high sensitivity to tillage under maize-fallow-maize, maize-wheat-maize and maize-oat-maize rotational cover cropping practices. The experiment was laid out as a split-plot arrangement in a randomized complete block design with 4 replicates. Tillage treatments (CT and NT) were applied on the main plots which measured 8 × 18 m while crop rotation treatments were applied in the subplots which measured 8 × 6 m. The rotation treatments were maize-fallow-maize (MFM), maize-wheat-maize (MWM) and maize-oat-maize (MOM). Weed control in NT plots involved preplant application of glyphosate to control mainly the grass weeds while post emergence weed management was done using Atrazine (485 atrazine and 15 g l-1 triazines). Initial weed control in CT plots was achieved through ploughing to a depth of 20 cm followed by disking while post emergence weed iii management was done by hand hoeing. Soil parameters measured were; (i) particulate organic matter (POM), soil organic carbon (SOC), total nitrogen (TN), pH and electrical conductivity (EC), (ii) soil bulk density (b), moisture at field capacity (FC), aggregate mean weight diameter (MWD) determined by fast wetting (FW), slow wetting (SW), mechanical breakdown by shaking (MB) and the stability index (SI), (iii) soil microbial biomass C (MBC) and N (MBN), mineralizable N (MN), soil respiration (SR), and dehydrogenase enzyme activity (DHEA). No-till increased POM and TN compared to CT in Lenye and Burnshill, respectively. The MWM and the MOM rotations increased TN relative to the MFM rotation in Lenye. The MWM and MOM rotations enhanced SOC relative to MFM in all sampled soil depths at Burnshill and similar observations were made under MOM rotation in the 5-20 cm depth in Lenye. The MWM and MOM rotations tended to depress soil pH relative to the MFM rotation in both sampled soil depths in Lenye while NT reduced soil pH relative to CT on the surface soil layer in Burnshill. Soil EC and pH varied with depth across tillage practices but both parameters remained within the ideal range for successful crop production over the study period. Soil stability index (SI) and aggregate MWD determined by FW, SW and MB were higher in Lenye compared to Burnshill. The MOM rotation enhanced the SI relative to MFM and MWM rotations at both sites. Scanning electron microscope (SEM) showed that more organic C was incorporated into the soil under NT and MOM rotation compared to CT and MFM rotation which had few organic coatings on the soil particles. Microbial properties varied with plant biomass input as influenced by tillage and type of rotational cover crop at both sites. Like in other past studies, NT showed higher levels of MBC, MBN, NM and SR at the soil surface layer compared to CT in Burnshill. No till increased MN iv relative to CT in both sampled soil depths in Lenye and resulted in higher DHEA compared to CT in Burnshill. The MOM rotation increased MBC, MBN, MN relative to MFM rotation especially within surface soil layer. Similar observations were made with respect to MN and SR in both sampled soil layers at Lenye. By contrast, the DHEA was higher under the MFM relative to the MWM and MOM rotations in Lenye but similar under the MFM and MOM rotations in Burnshill. Maize grain yield was not affected by both tillage and crop rotations but varied with cropping season. Comparable grain yields observed under the two tillage practices with similar fertilizer application rates indicated the advantage of NT over CT in saving on labour costs in maize production without compromising yields. High plant biomass retention under NT relative to CT contributed to high soil N and P levels under the former compared to the latter tillage practice especially on soil surface layer at both study sites. Principal component analysis (PCA) revealed that soil chemical and biological parameters closely linked to organic matter, namely SOC, MN, MBC and MBN showed the highest sensitivity to tillage and crop rotation treatments. Soil aggregate MWD determined by SW and b were the physical parameters which were highly altered by agronomic management practice. The MWM and MOM rotations were clustered together and clearly separated from the MFM rotation and this observed trend only applied to the 0-5 and 5-20 cm depths in Lenye site only. No till, MWM and MOM rotations enhanced POM, SOC and TN relative to CT and MFM rotation suggesting these practices have greater potential to improve soil chemical properties compared to intensive tillage and maize monoculture based production practices. Reduced soil b under MOM rotation and improved SI under NT compared to MFM and CT, respectively v indicate that these practices have the potential to improve degraded soils. Although not significantly different, NT values for MBC, MBN, MN, SR and DHEA were higher compared to CT indicating the potential of the practice to improve soil biotic activity relative to conventional tillage practices. No till enhanced surface soil nitrate N and extractable P compared to CT at both sites revealing the long-term potential of NT in improving the supply of these essential plant nutrients compared to CT. Principal component analysis showed that SOC, MN, K, P, MBC, MBN, soil aggregate MWD determined by SW and b were the most sensitive parameters to tillage and crop rotations. Therefore, these parameters could constitute the minimum data set for assessments of the impact of selected CA practices on soil quality attributes.
- Full Text:
- Date Issued: 2010
- Authors: Njaimwe, Arnold Ngare
- Date: 2010
- Subjects: No-tillage , Soil mechanics , Soils -- Quality , Cover crops , Corn -- Irrigation
- Language: English
- Type: Thesis , Doctoral , PhD (Soil Science)
- Identifier: vital:11962 , http://hdl.handle.net/10353/460 , No-tillage , Soil mechanics , Soils -- Quality , Cover crops , Corn -- Irrigation
- Description: Intensive tillage and monoculture cropping practices reduce soil C accumulation hence increasing soil vulnerability to chemical, physical and biological degradation. This study focussed on enhancing biomass production of wheat and oat winter cover crops as a means of increasing C sequestration in the low organic C soils of the central part of Eastern Cape Province. The specific objectives were (i) to evaluate the short-term effects of no till and cereal-fallow based crop rotations on; soil organic matter related parameters, pH and electrical conductivity, (ii) soil bulk density, water retention and aggregate stability, (iii) soil microbial biomass C and N, mineralizable N, soil respiration, and dehydrogenase enzyme activity, (iv) grain yield, soil nutrient concentration (N, P and K) and their uptake by maize, and (v) to identify soil parameters with high sensitivity to tillage under maize-fallow-maize, maize-wheat-maize and maize-oat-maize rotational cover cropping practices. The experiment was laid out as a split-plot arrangement in a randomized complete block design with 4 replicates. Tillage treatments (CT and NT) were applied on the main plots which measured 8 × 18 m while crop rotation treatments were applied in the subplots which measured 8 × 6 m. The rotation treatments were maize-fallow-maize (MFM), maize-wheat-maize (MWM) and maize-oat-maize (MOM). Weed control in NT plots involved preplant application of glyphosate to control mainly the grass weeds while post emergence weed management was done using Atrazine (485 atrazine and 15 g l-1 triazines). Initial weed control in CT plots was achieved through ploughing to a depth of 20 cm followed by disking while post emergence weed iii management was done by hand hoeing. Soil parameters measured were; (i) particulate organic matter (POM), soil organic carbon (SOC), total nitrogen (TN), pH and electrical conductivity (EC), (ii) soil bulk density (b), moisture at field capacity (FC), aggregate mean weight diameter (MWD) determined by fast wetting (FW), slow wetting (SW), mechanical breakdown by shaking (MB) and the stability index (SI), (iii) soil microbial biomass C (MBC) and N (MBN), mineralizable N (MN), soil respiration (SR), and dehydrogenase enzyme activity (DHEA). No-till increased POM and TN compared to CT in Lenye and Burnshill, respectively. The MWM and the MOM rotations increased TN relative to the MFM rotation in Lenye. The MWM and MOM rotations enhanced SOC relative to MFM in all sampled soil depths at Burnshill and similar observations were made under MOM rotation in the 5-20 cm depth in Lenye. The MWM and MOM rotations tended to depress soil pH relative to the MFM rotation in both sampled soil depths in Lenye while NT reduced soil pH relative to CT on the surface soil layer in Burnshill. Soil EC and pH varied with depth across tillage practices but both parameters remained within the ideal range for successful crop production over the study period. Soil stability index (SI) and aggregate MWD determined by FW, SW and MB were higher in Lenye compared to Burnshill. The MOM rotation enhanced the SI relative to MFM and MWM rotations at both sites. Scanning electron microscope (SEM) showed that more organic C was incorporated into the soil under NT and MOM rotation compared to CT and MFM rotation which had few organic coatings on the soil particles. Microbial properties varied with plant biomass input as influenced by tillage and type of rotational cover crop at both sites. Like in other past studies, NT showed higher levels of MBC, MBN, NM and SR at the soil surface layer compared to CT in Burnshill. No till increased MN iv relative to CT in both sampled soil depths in Lenye and resulted in higher DHEA compared to CT in Burnshill. The MOM rotation increased MBC, MBN, MN relative to MFM rotation especially within surface soil layer. Similar observations were made with respect to MN and SR in both sampled soil layers at Lenye. By contrast, the DHEA was higher under the MFM relative to the MWM and MOM rotations in Lenye but similar under the MFM and MOM rotations in Burnshill. Maize grain yield was not affected by both tillage and crop rotations but varied with cropping season. Comparable grain yields observed under the two tillage practices with similar fertilizer application rates indicated the advantage of NT over CT in saving on labour costs in maize production without compromising yields. High plant biomass retention under NT relative to CT contributed to high soil N and P levels under the former compared to the latter tillage practice especially on soil surface layer at both study sites. Principal component analysis (PCA) revealed that soil chemical and biological parameters closely linked to organic matter, namely SOC, MN, MBC and MBN showed the highest sensitivity to tillage and crop rotation treatments. Soil aggregate MWD determined by SW and b were the physical parameters which were highly altered by agronomic management practice. The MWM and MOM rotations were clustered together and clearly separated from the MFM rotation and this observed trend only applied to the 0-5 and 5-20 cm depths in Lenye site only. No till, MWM and MOM rotations enhanced POM, SOC and TN relative to CT and MFM rotation suggesting these practices have greater potential to improve soil chemical properties compared to intensive tillage and maize monoculture based production practices. Reduced soil b under MOM rotation and improved SI under NT compared to MFM and CT, respectively v indicate that these practices have the potential to improve degraded soils. Although not significantly different, NT values for MBC, MBN, MN, SR and DHEA were higher compared to CT indicating the potential of the practice to improve soil biotic activity relative to conventional tillage practices. No till enhanced surface soil nitrate N and extractable P compared to CT at both sites revealing the long-term potential of NT in improving the supply of these essential plant nutrients compared to CT. Principal component analysis showed that SOC, MN, K, P, MBC, MBN, soil aggregate MWD determined by SW and b were the most sensitive parameters to tillage and crop rotations. Therefore, these parameters could constitute the minimum data set for assessments of the impact of selected CA practices on soil quality attributes.
- Full Text:
- Date Issued: 2010
Time budgets, avoidance distance scores-related behaviour and milk yield of pasture-based Jersey, Friesland and cross bred cows
- Authors: Dodzi, Madodana Sunson
- Date: 2010
- Subjects: Dairy products -- Analysis , Jersey cattle , Milk yield , Dairy cattle -- Feed utilization efficiency , Dairy farming
- Language: English
- Type: Thesis , Masters , MSc Agric (Animal Science)
- Identifier: vital:11817 , http://hdl.handle.net/10353/474 , Dairy products -- Analysis , Jersey cattle , Milk yield , Dairy cattle -- Feed utilization efficiency , Dairy farming
- Description: Time budgets, avoidance distance scores-related behaviour and milk yield of pasture-based Jersey, Friesland and crossbred cows. by Madodana Sunson Dodzi The study was conducted at the University of Fort Hare farm to determine the time budgets, the avoidance-related behaviour variables and their relationship with milk yield in three pasturebased dairy genotypes: Jersey, Friesland and crossbreed. Twenty one clinically health dairy cows aged between 52 and 55 months, in mid lactation and comprising of seven cows from each genotype were used in the study. The time spent on different activities (grazing, lying down, standing and others) at pasture was recorded using stop watches across four seasons. The behavioural responses of the three genotypes to humans were determined by recording their avoidance distance scores (AD), exit speed (ES), pen scores (PS), pen behaviour scores (PBS), plat form scores (PLS) and the occurrence of kicking (KCK) and stepping (SPG) during milking on four consecutive days in four seasons. Time spent standing was higher (P < 0.05) for Friesland compared to Jersey and crossbred during the hot-wet season. In the cool-dry season the Jersey spent more time (P < 0.05) grazing than the other breeds. The Friesland and crossbred on the other hand devoted most of their time lying down compared to Jersey in the cool- dry season (P < 0.05). There were season differences in time spent on all activities (P < 0.05). Time spent on grazing was longest in post-rainy seasonal and lowest in hot- wet season (P < 0.05). The longest lying down period was observed in the hot-dry season and lowest in hot-wet season (P < 0.05). iii Daily milk yield Varied (P < 0.05) with genotype with the Friesland and Jersey producing higher yield than the crossbred. The highest amount was produced in hot-dry and the least in hot-wet season. Milk yield was positively correlated (P < 0.05) with lying down. Standing was negatively correlated with milk yield (P < 0.05). The Friesland had the highest avoidance distance scores (P < 0.05) and the Jersey had the lowest avoidance distance scores in all seasons. There was an association (P < 0.05) between genotype and exit speed scores, pen scores and stepping behaviour scores. The Friesland exhibited the highest exit speed scores than the other breeds. The Jersey had the lowest (P < 0.05) kicking behaviour scores. There was a relationship (r = 0.64) between avoidance distance scores and exit speed. Exit speed scores were correlated with pen score(r= 0.23). Milk yield was significant related (r= 0.17) to the occurrence of kicking behaviour. The genotypes showed different levels of sensitivity to season and milk yield was influenced by breed and season. It can be concluded that time budgets vary with season and farmers need to adopt measures that buffer the effect of season on welfare of dairy cows. It can also be concluded that avoidance distance scores differs according to genotype with Jersey being more confident to humans than other two breeds. It is therefore recommended that provision of shades or cooling mechanism should be adopted to buffer the effects of hot-wet season. Improving quality of feed during the cool-dry season may be critical for Jersey cows. Finally positive handling of the dairy cows is recommended in order to improve the welfare and milk yield of pasture based dairy cows.
- Full Text:
- Date Issued: 2010
- Authors: Dodzi, Madodana Sunson
- Date: 2010
- Subjects: Dairy products -- Analysis , Jersey cattle , Milk yield , Dairy cattle -- Feed utilization efficiency , Dairy farming
- Language: English
- Type: Thesis , Masters , MSc Agric (Animal Science)
- Identifier: vital:11817 , http://hdl.handle.net/10353/474 , Dairy products -- Analysis , Jersey cattle , Milk yield , Dairy cattle -- Feed utilization efficiency , Dairy farming
- Description: Time budgets, avoidance distance scores-related behaviour and milk yield of pasture-based Jersey, Friesland and crossbred cows. by Madodana Sunson Dodzi The study was conducted at the University of Fort Hare farm to determine the time budgets, the avoidance-related behaviour variables and their relationship with milk yield in three pasturebased dairy genotypes: Jersey, Friesland and crossbreed. Twenty one clinically health dairy cows aged between 52 and 55 months, in mid lactation and comprising of seven cows from each genotype were used in the study. The time spent on different activities (grazing, lying down, standing and others) at pasture was recorded using stop watches across four seasons. The behavioural responses of the three genotypes to humans were determined by recording their avoidance distance scores (AD), exit speed (ES), pen scores (PS), pen behaviour scores (PBS), plat form scores (PLS) and the occurrence of kicking (KCK) and stepping (SPG) during milking on four consecutive days in four seasons. Time spent standing was higher (P < 0.05) for Friesland compared to Jersey and crossbred during the hot-wet season. In the cool-dry season the Jersey spent more time (P < 0.05) grazing than the other breeds. The Friesland and crossbred on the other hand devoted most of their time lying down compared to Jersey in the cool- dry season (P < 0.05). There were season differences in time spent on all activities (P < 0.05). Time spent on grazing was longest in post-rainy seasonal and lowest in hot- wet season (P < 0.05). The longest lying down period was observed in the hot-dry season and lowest in hot-wet season (P < 0.05). iii Daily milk yield Varied (P < 0.05) with genotype with the Friesland and Jersey producing higher yield than the crossbred. The highest amount was produced in hot-dry and the least in hot-wet season. Milk yield was positively correlated (P < 0.05) with lying down. Standing was negatively correlated with milk yield (P < 0.05). The Friesland had the highest avoidance distance scores (P < 0.05) and the Jersey had the lowest avoidance distance scores in all seasons. There was an association (P < 0.05) between genotype and exit speed scores, pen scores and stepping behaviour scores. The Friesland exhibited the highest exit speed scores than the other breeds. The Jersey had the lowest (P < 0.05) kicking behaviour scores. There was a relationship (r = 0.64) between avoidance distance scores and exit speed. Exit speed scores were correlated with pen score(r= 0.23). Milk yield was significant related (r= 0.17) to the occurrence of kicking behaviour. The genotypes showed different levels of sensitivity to season and milk yield was influenced by breed and season. It can be concluded that time budgets vary with season and farmers need to adopt measures that buffer the effect of season on welfare of dairy cows. It can also be concluded that avoidance distance scores differs according to genotype with Jersey being more confident to humans than other two breeds. It is therefore recommended that provision of shades or cooling mechanism should be adopted to buffer the effects of hot-wet season. Improving quality of feed during the cool-dry season may be critical for Jersey cows. Finally positive handling of the dairy cows is recommended in order to improve the welfare and milk yield of pasture based dairy cows.
- Full Text:
- Date Issued: 2010
Time course of performance changes and fatigue markers during training for the ironman triathlon
- Authors: Joiner, Alexander Jason
- Date: 2010
- Subjects: Ironman triathlons -- Training , Physical education and training -- Physiological aspects , Endurance sports -- Training , Sports -- Physiological aspects , Fatigue
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5133 , http://hdl.handle.net/10962/d1005212 , Ironman triathlons -- Training , Physical education and training -- Physiological aspects , Endurance sports -- Training , Sports -- Physiological aspects , Fatigue
- Description:
Suboptimal preparation for the Ironman triathlon can have detrimental effects on mental and physical condition. The purpose of this longitudinal investigation was to examine the relationship between a number of performance changes and fatigue markers during training for an Ironman as well as immediately after the event, in an attempt to better understand the effects of ultraendurance training. Eighteen athletes training for the Ironman; South Africa, 2009 were recruited for the study. Over the 6 month data collection period body mass, training load (TRIMP and Session x RPE methods), physiological responses (waking heart rate, postural dizziness, sleep ratings), changes in psychological state (profile of mood states - POMS), reported immunological responses (symptoms of illness), biochemical changes (salivary cortisol and alpha amylase) and performance (8 km submaximal running time trial (TT) and race day performance) were measured. These responses were compared to a control sample (n=15). Results show a significant increase (p<0.05) in training load (3899.4 ± 2517.8) four weeks prior to the event. Fatigue scores significantly increased (p<0.05) concurrently with this significant increase (p<0.05) in training. TT performance did not significantly (p<0.05) alter during the time course of training. It was however strongly correlated to training load (R2=0.85) and modestly related to race performance (R2=0.65). The signs and symptoms of upper respiratory tract infections (URTI) were prevalent during the training period, decreasing during the taper and race period. Large standard deviations were found within the majority of the responses. During the final two weeks of preparation, tension scores were significantly increased (p<0.05) while training load significantly decreased (p<0.05) during the final week of preparation. Cortisol increased significantly (p<0.05) immediately post race (0.507±0.15
- Full Text:
- Date Issued: 2010
- Authors: Joiner, Alexander Jason
- Date: 2010
- Subjects: Ironman triathlons -- Training , Physical education and training -- Physiological aspects , Endurance sports -- Training , Sports -- Physiological aspects , Fatigue
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5133 , http://hdl.handle.net/10962/d1005212 , Ironman triathlons -- Training , Physical education and training -- Physiological aspects , Endurance sports -- Training , Sports -- Physiological aspects , Fatigue
- Description:
Suboptimal preparation for the Ironman triathlon can have detrimental effects on mental and physical condition. The purpose of this longitudinal investigation was to examine the relationship between a number of performance changes and fatigue markers during training for an Ironman as well as immediately after the event, in an attempt to better understand the effects of ultraendurance training. Eighteen athletes training for the Ironman; South Africa, 2009 were recruited for the study. Over the 6 month data collection period body mass, training load (TRIMP and Session x RPE methods), physiological responses (waking heart rate, postural dizziness, sleep ratings), changes in psychological state (profile of mood states - POMS), reported immunological responses (symptoms of illness), biochemical changes (salivary cortisol and alpha amylase) and performance (8 km submaximal running time trial (TT) and race day performance) were measured. These responses were compared to a control sample (n=15). Results show a significant increase (p<0.05) in training load (3899.4 ± 2517.8) four weeks prior to the event. Fatigue scores significantly increased (p<0.05) concurrently with this significant increase (p<0.05) in training. TT performance did not significantly (p<0.05) alter during the time course of training. It was however strongly correlated to training load (R2=0.85) and modestly related to race performance (R2=0.65). The signs and symptoms of upper respiratory tract infections (URTI) were prevalent during the training period, decreasing during the taper and race period. Large standard deviations were found within the majority of the responses. During the final two weeks of preparation, tension scores were significantly increased (p<0.05) while training load significantly decreased (p<0.05) during the final week of preparation. Cortisol increased significantly (p<0.05) immediately post race (0.507±0.15
- Full Text:
- Date Issued: 2010
Timing of primary wing moult in sexually dimorphic passerines from the Western Cape, South Africa
- Bonnevie, Bo T, Oschadleus, Hans-Dieter
- Authors: Bonnevie, Bo T , Oschadleus, Hans-Dieter
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448355 , vital:74724 , https://doi.org/10.2989/00306525.2010.455821
- Description: SAFRING ringing data was used to investigate the differences in the timing and duration of primary wing moult between males and females of sexually dimorphic passerines from the Western Cape, South Africa. In the sunbirds, weavers and canaries that were considered, the males generally started moult before the females, whereas this was not so for other species. In the species where males started moult before the females, the standard deviation of the start of moult was generally smaller in the males and the males generally took longer to moult. These differences in the patterns of moult are discussed in the context of differences in parental care between males and females of each species and within their taxonomic groups.
- Full Text:
- Date Issued: 2010
- Authors: Bonnevie, Bo T , Oschadleus, Hans-Dieter
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448355 , vital:74724 , https://doi.org/10.2989/00306525.2010.455821
- Description: SAFRING ringing data was used to investigate the differences in the timing and duration of primary wing moult between males and females of sexually dimorphic passerines from the Western Cape, South Africa. In the sunbirds, weavers and canaries that were considered, the males generally started moult before the females, whereas this was not so for other species. In the species where males started moult before the females, the standard deviation of the start of moult was generally smaller in the males and the males generally took longer to moult. These differences in the patterns of moult are discussed in the context of differences in parental care between males and females of each species and within their taxonomic groups.
- Full Text:
- Date Issued: 2010
To be Xhosa or not to be Xhosa… that is the question:
- Authors: De Klerk, Vivian A
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158096 , vital:40148 , https://doi.org/10.1080/01434630008666401
- Description: It has long been recognised that indigenous languages are endangered because of powerful social, political and economic pressures. In South Africa, the legacy of apartheid has left its indigenous languages particularly vulnerable, and since 1994 huge efforts have been made to reverse the situation. Despite the new language policy and accompanying legislation, it would seem that many Xhosa speakers themselves want English, and not Xhosa,for their children. This paper reports on a multi-faceted quantitative and qualitative survey in and around Grahamstown in the Eastern Cape Province, which focused on the steady trickle of speakers of Xhosa into English-medium schools in thearea, and examined the reasons underlying decisions to send Xhosa children to these schools and the subsequent linguistic and psycho-social effects of the move on the children.
- Full Text:
- Date Issued: 2010
- Authors: De Klerk, Vivian A
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158096 , vital:40148 , https://doi.org/10.1080/01434630008666401
- Description: It has long been recognised that indigenous languages are endangered because of powerful social, political and economic pressures. In South Africa, the legacy of apartheid has left its indigenous languages particularly vulnerable, and since 1994 huge efforts have been made to reverse the situation. Despite the new language policy and accompanying legislation, it would seem that many Xhosa speakers themselves want English, and not Xhosa,for their children. This paper reports on a multi-faceted quantitative and qualitative survey in and around Grahamstown in the Eastern Cape Province, which focused on the steady trickle of speakers of Xhosa into English-medium schools in thearea, and examined the reasons underlying decisions to send Xhosa children to these schools and the subsequent linguistic and psycho-social effects of the move on the children.
- Full Text:
- Date Issued: 2010
Towards creating a legally literate WSU community for today and tomorrow
- Authors: Mammen, Kuttickattu John
- Date: 2010
- Subjects: Legal literacy -- South Africa Law -- Literacy
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/790 , vital:29777
- Description: Legal literacy has been gaining significance in literature in recent years as can be seen from several publications, for example, amongst others, Van Wyk (1983), White (1983), Barrell and Partington (1985), Kawatoko (1995), Andretta (2001), Fischer, Schimmel and Stellman (2003), Oosthuizen (2003), Barry (2006), Hasl-Kelchner (2006), and Schimmel and Militello (2007). In 1948, the world community spoke through the United Nations by establishing a framework for human rights awareness and protection with the Universal Declaration of Human Rights (UDHR). In 1987, several Commonwealth associations founded the Commonwealth Human Rights Initiative (CHRI) to promote human rights issues. CHRI’s International Right to Information (RTI) Program focuses on monitoring and supporting the push for recognition and implementation of the right to information throughout the 53 states of the Commonwealth and the institutions of the Commonwealth itself. Generally, legal literacy efforts focus on human rights. It was originally used in a context where citizens, particularly from the marginalized or underprivileged groups, were made to know what the law had to offer them so that they could recognise and challenge injustices much more forcefully. The first step towards that knowledge of the law, which can transform people’s lives, is legal literacy. Legal literacy puts one in the driver’s seat of risk management. Generally, legal literacy efforts focus on human rights.
- Full Text:
- Date Issued: 2010
- Authors: Mammen, Kuttickattu John
- Date: 2010
- Subjects: Legal literacy -- South Africa Law -- Literacy
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/790 , vital:29777
- Description: Legal literacy has been gaining significance in literature in recent years as can be seen from several publications, for example, amongst others, Van Wyk (1983), White (1983), Barrell and Partington (1985), Kawatoko (1995), Andretta (2001), Fischer, Schimmel and Stellman (2003), Oosthuizen (2003), Barry (2006), Hasl-Kelchner (2006), and Schimmel and Militello (2007). In 1948, the world community spoke through the United Nations by establishing a framework for human rights awareness and protection with the Universal Declaration of Human Rights (UDHR). In 1987, several Commonwealth associations founded the Commonwealth Human Rights Initiative (CHRI) to promote human rights issues. CHRI’s International Right to Information (RTI) Program focuses on monitoring and supporting the push for recognition and implementation of the right to information throughout the 53 states of the Commonwealth and the institutions of the Commonwealth itself. Generally, legal literacy efforts focus on human rights. It was originally used in a context where citizens, particularly from the marginalized or underprivileged groups, were made to know what the law had to offer them so that they could recognise and challenge injustices much more forcefully. The first step towards that knowledge of the law, which can transform people’s lives, is legal literacy. Legal literacy puts one in the driver’s seat of risk management. Generally, legal literacy efforts focus on human rights.
- Full Text:
- Date Issued: 2010
Towards enhancing indigenous language acquisition skills through MMORPGs
- Kaschula, Russell H, Mostert, André M
- Authors: Kaschula, Russell H , Mostert, André M
- Date: 2010
- Subjects: Indigenous peoples -- Languages -- Study and teaching -- South Africa , Language and languags -- Computer-assisted instruction , Language and languags -- Study and teaching -- Technological innovation , Language acquisition , Computer games
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59343 , vital:27559 , http://alternation.ukzn.ac.za/Files/docs/17.1/08 Kas FIN.pdf
- Description: The growing interest and access to massively multiplayer online role-playing games (MMORPG) has opened up significant new scope for educational methodologies, from standard language teaching options through to formalising the skills that a ‘player’ develops through their quests and other activities. This scope is extensive and has created numerous opportunities for innovation both within education and the world of work. This is evidenced by the increasing presence of educational establishments in the virtual world, with Second Life being the most popular for conventional educational purposes. In Second Life and many other realms participants are earning some income and in some cases enjoying a reasonable living from online activities, while developing their skills base. These MMORPGs may open opportunities for promoting language acquisition provided this is located within a suitably attractive realm; ‘players’ would then engage in activities that would contribute to their abilities to use the indigenous languages in everyday life. This article explores how such a system could be developed and the likely contribution it could make to promote a multilingual environment at school and post school levels. Further, it will identify the implications for the future of teaching and learning through the harnessing of MMORPGs.
- Full Text:
- Date Issued: 2010
- Authors: Kaschula, Russell H , Mostert, André M
- Date: 2010
- Subjects: Indigenous peoples -- Languages -- Study and teaching -- South Africa , Language and languags -- Computer-assisted instruction , Language and languags -- Study and teaching -- Technological innovation , Language acquisition , Computer games
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59343 , vital:27559 , http://alternation.ukzn.ac.za/Files/docs/17.1/08 Kas FIN.pdf
- Description: The growing interest and access to massively multiplayer online role-playing games (MMORPG) has opened up significant new scope for educational methodologies, from standard language teaching options through to formalising the skills that a ‘player’ develops through their quests and other activities. This scope is extensive and has created numerous opportunities for innovation both within education and the world of work. This is evidenced by the increasing presence of educational establishments in the virtual world, with Second Life being the most popular for conventional educational purposes. In Second Life and many other realms participants are earning some income and in some cases enjoying a reasonable living from online activities, while developing their skills base. These MMORPGs may open opportunities for promoting language acquisition provided this is located within a suitably attractive realm; ‘players’ would then engage in activities that would contribute to their abilities to use the indigenous languages in everyday life. This article explores how such a system could be developed and the likely contribution it could make to promote a multilingual environment at school and post school levels. Further, it will identify the implications for the future of teaching and learning through the harnessing of MMORPGs.
- Full Text:
- Date Issued: 2010
Towards expediting land claims: a case study of Fairview, Port Elizabeth
- Authors: Tyala, Sindiswa
- Date: 2010
- Subjects: Land tenure -- South Africa -- Port Elizabeth , Right of property -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9081 , http://hdl.handle.net/10948/1127 , Land tenure -- South Africa -- Port Elizabeth , Right of property -- South Africa -- Port Elizabeth
- Description: In 1994, South Africa’s political dispensation changed when the African National Congress (ANC) came into power. For most people, that meant that their aspirations and wishes would be fulfilled. The main objective of the new government was to redress past imbalances. The land question was one item on their agenda. In South Africa, land ownership has long been a source of conflict. The South African history of dispossession and forced removals and racially–skewed distribution of land resources has left Africans with a complex and difficult legacy (Christopher,1987).The issue of land had been an emotional issue affecting many people in South Africa. The struggle for land and access to land in South African history gave rise to many conflicts and loss of lives. The restitution of land rights in South Africa has been a highly contentious and emotive issue. The pain, anger and frustration of those affected by the implementation of racially based discriminatory measures of the past, cannot be denied. Confronting and redressing the anguish of the past has proven to be central to the process of reconciliation within a transformed political dispensation in South Africa (South African White Paper on Land, 1991a). The Constitution of South Africa and The Restitution of Land Rights Act (Act No. 22 of 1994) have firmly established the rights to claim restitution in accordance with the provision of justice and equity for all South Africans. During such a long process, it has been noticed in the suburb of Fairview, Port Elizabeth that some claimants ultimately received their land and compensation, some died before they received absolutely nothing and some old, poor and illiterate claimants are still struggling to claim their land or compensation. Fairview was formerly known as Baakens River Farm in 1810. It was situated far from the city centre and formed part of the Walmer Municipality. Initially, it was owned by John James Besny. In 1826 the farmer was bought by John Parkin and he later sold half 2 of it to Robert Newcombe before 1849. Robbert Newcombe named his half of the farm Fairview (Harradene, 2000). In 1933, Fairview became part of the Walmer Municipality. In 1967 Walmer became part of the Port Elizabeth Municipality. Fairview developed as a township of low density and became increasingly heterogeneous in nature. Davies (1971:10) claimed that the largest concentration of properties were owned and occupied by Coloured people, followed by Chinese, Blacks and Indians. The majority of the residents were Coloured. According to Sampson (1994), the plot sizes in Fairview were relatively large, either 0,8 ha or 0,2ha. Sampson also claimed that no business sites were distinguished, but businesses were established by the Chinese on residential plots. During the apartheid era, Fairview was one of the lands declared as a “Controlled Area”. The Group Areas Act also affected Fairview, even though the removal of the people in Fairview was not as pressing as it was to other suburbs due to its location at a relative distance from the city (Davies, 1970). As a result an increase in the Coloured population in Fairview was noticed between 1960 and 1970 as people faced eviction from central city areas such as South End. The people moved to Fairview with the hope that the area would be proclaimed a Coloured area. Unfortunately for those who ran to Fairview, people in Fairview were also removed from 1970s to other areas like New Brighton Location and other areas in Korsten. The last removal of people in Fairview took place in 1984 (Eastern Province Herald, 26 October 1996). After 1994, the introduction of the Restitution of Land Rights Act made provision for the establishment of a Commission on the Restitution of Land Rights and a Land Claims Court to adjudicate all claims lodged with the Commission as from 1 May 1998 (Land Info., 1996). Disputes with land owners over prices, validity of the claims and resistance to give away land, led to referral of some claims to the Land Claims Court. Although some research has been undertaken on Fairview, there is a vacuum of research into the problems faced by claimants in this area. The problems faced by claimants meant that some died while they were still busy with the process and some are still struggling to make a claim, and recently some were successful. 3 The focus of this study is to examine the process of the Fairview land claim, and as a recommendation, I wish to come up with suggestions for making the process easier for claimants.
- Full Text:
- Date Issued: 2010
- Authors: Tyala, Sindiswa
- Date: 2010
- Subjects: Land tenure -- South Africa -- Port Elizabeth , Right of property -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9081 , http://hdl.handle.net/10948/1127 , Land tenure -- South Africa -- Port Elizabeth , Right of property -- South Africa -- Port Elizabeth
- Description: In 1994, South Africa’s political dispensation changed when the African National Congress (ANC) came into power. For most people, that meant that their aspirations and wishes would be fulfilled. The main objective of the new government was to redress past imbalances. The land question was one item on their agenda. In South Africa, land ownership has long been a source of conflict. The South African history of dispossession and forced removals and racially–skewed distribution of land resources has left Africans with a complex and difficult legacy (Christopher,1987).The issue of land had been an emotional issue affecting many people in South Africa. The struggle for land and access to land in South African history gave rise to many conflicts and loss of lives. The restitution of land rights in South Africa has been a highly contentious and emotive issue. The pain, anger and frustration of those affected by the implementation of racially based discriminatory measures of the past, cannot be denied. Confronting and redressing the anguish of the past has proven to be central to the process of reconciliation within a transformed political dispensation in South Africa (South African White Paper on Land, 1991a). The Constitution of South Africa and The Restitution of Land Rights Act (Act No. 22 of 1994) have firmly established the rights to claim restitution in accordance with the provision of justice and equity for all South Africans. During such a long process, it has been noticed in the suburb of Fairview, Port Elizabeth that some claimants ultimately received their land and compensation, some died before they received absolutely nothing and some old, poor and illiterate claimants are still struggling to claim their land or compensation. Fairview was formerly known as Baakens River Farm in 1810. It was situated far from the city centre and formed part of the Walmer Municipality. Initially, it was owned by John James Besny. In 1826 the farmer was bought by John Parkin and he later sold half 2 of it to Robert Newcombe before 1849. Robbert Newcombe named his half of the farm Fairview (Harradene, 2000). In 1933, Fairview became part of the Walmer Municipality. In 1967 Walmer became part of the Port Elizabeth Municipality. Fairview developed as a township of low density and became increasingly heterogeneous in nature. Davies (1971:10) claimed that the largest concentration of properties were owned and occupied by Coloured people, followed by Chinese, Blacks and Indians. The majority of the residents were Coloured. According to Sampson (1994), the plot sizes in Fairview were relatively large, either 0,8 ha or 0,2ha. Sampson also claimed that no business sites were distinguished, but businesses were established by the Chinese on residential plots. During the apartheid era, Fairview was one of the lands declared as a “Controlled Area”. The Group Areas Act also affected Fairview, even though the removal of the people in Fairview was not as pressing as it was to other suburbs due to its location at a relative distance from the city (Davies, 1970). As a result an increase in the Coloured population in Fairview was noticed between 1960 and 1970 as people faced eviction from central city areas such as South End. The people moved to Fairview with the hope that the area would be proclaimed a Coloured area. Unfortunately for those who ran to Fairview, people in Fairview were also removed from 1970s to other areas like New Brighton Location and other areas in Korsten. The last removal of people in Fairview took place in 1984 (Eastern Province Herald, 26 October 1996). After 1994, the introduction of the Restitution of Land Rights Act made provision for the establishment of a Commission on the Restitution of Land Rights and a Land Claims Court to adjudicate all claims lodged with the Commission as from 1 May 1998 (Land Info., 1996). Disputes with land owners over prices, validity of the claims and resistance to give away land, led to referral of some claims to the Land Claims Court. Although some research has been undertaken on Fairview, there is a vacuum of research into the problems faced by claimants in this area. The problems faced by claimants meant that some died while they were still busy with the process and some are still struggling to make a claim, and recently some were successful. 3 The focus of this study is to examine the process of the Fairview land claim, and as a recommendation, I wish to come up with suggestions for making the process easier for claimants.
- Full Text:
- Date Issued: 2010
Towards IPTV service discovery and selection in an IMS environment
- Tsietsi, Mosiuoa, Musvibe, Ray, Terzoli, Alfredo, Wells, George C
- Authors: Tsietsi, Mosiuoa , Musvibe, Ray , Terzoli, Alfredo , Wells, George C
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430795 , vital:72716 , 10.1109/ICUMT.2010.5676637
- Description: The IP Multimedia Subsystem (IMS) is a telecommunication middleware architecture that behaves as a docking station for a wide range of mul-timedia services. Several so-called killer applications have been envi-sioned for this platform such as multimedia group communications and location based services (LBS), but one of the most common business cases for IMS remains IPTV (Internet Protocol TV). Several IMS stand-ards development bodies and non-IMS players have contributed knowledge to the topic of IPTV, and the mechanisms needed to support various IPTV services are well understood. In addition, there are exam-ples of researchers who have implemented IPTV services in their net-work testbeds. However, many of them do not make use of the full power of the specifications which describe the mechanisms of service discovery and service selection. These processes define support for customer device configuration, service personalisation and service se-lection in a multi-service provider ecosystem. This position paper pro-poses solutions to some of the open questions in this area and pro-vides an architecture for a testbed that properly supports service dis-covery and selection. An initial implementation addressing the topic of auto-configuration of IMS terminals for service discovery is also pre-sented.
- Full Text:
- Date Issued: 2010
- Authors: Tsietsi, Mosiuoa , Musvibe, Ray , Terzoli, Alfredo , Wells, George C
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430795 , vital:72716 , 10.1109/ICUMT.2010.5676637
- Description: The IP Multimedia Subsystem (IMS) is a telecommunication middleware architecture that behaves as a docking station for a wide range of mul-timedia services. Several so-called killer applications have been envi-sioned for this platform such as multimedia group communications and location based services (LBS), but one of the most common business cases for IMS remains IPTV (Internet Protocol TV). Several IMS stand-ards development bodies and non-IMS players have contributed knowledge to the topic of IPTV, and the mechanisms needed to support various IPTV services are well understood. In addition, there are exam-ples of researchers who have implemented IPTV services in their net-work testbeds. However, many of them do not make use of the full power of the specifications which describe the mechanisms of service discovery and service selection. These processes define support for customer device configuration, service personalisation and service se-lection in a multi-service provider ecosystem. This position paper pro-poses solutions to some of the open questions in this area and pro-vides an architecture for a testbed that properly supports service dis-covery and selection. An initial implementation addressing the topic of auto-configuration of IMS terminals for service discovery is also pre-sented.
- Full Text:
- Date Issued: 2010
Towards Medical Education that is Responsive to Community Needs, while Recognising Community Assets and Capabilities
- Authors: Mfenyana, Khaya
- Date: 2010
- Subjects: Medical education -- South Africa Clinical medicine -- Teaching and learning Problem-based learning -- South Africa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/780 , vital:29753
- Description: Medical education today is under severe tension between “maintenance of standards” and “relevance to the needs of the population served”. A standard is a level of excellence and conventional schools tend to separate “standards” from “relevance” whereas innovative schools do not. This battle has been going on for sometime and in many places including South Africa. de Klerk (1979) warns that South African doctors should not allow the medical standards they have set for themselves to deteriorate because of the pragmatic problems encountered in attempting to attain the primary health care ideal. Daubenton (1990), on the other hand, states that one is excellent only if one is relevant. According to Daubenton, medical education can only be considered excellent if it is responsive and relevant to local needs.
- Full Text:
- Date Issued: 2010
- Authors: Mfenyana, Khaya
- Date: 2010
- Subjects: Medical education -- South Africa Clinical medicine -- Teaching and learning Problem-based learning -- South Africa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/780 , vital:29753
- Description: Medical education today is under severe tension between “maintenance of standards” and “relevance to the needs of the population served”. A standard is a level of excellence and conventional schools tend to separate “standards” from “relevance” whereas innovative schools do not. This battle has been going on for sometime and in many places including South Africa. de Klerk (1979) warns that South African doctors should not allow the medical standards they have set for themselves to deteriorate because of the pragmatic problems encountered in attempting to attain the primary health care ideal. Daubenton (1990), on the other hand, states that one is excellent only if one is relevant. According to Daubenton, medical education can only be considered excellent if it is responsive and relevant to local needs.
- Full Text:
- Date Issued: 2010
Towards social impact assessment of copper-nickel mining in Botswana
- Authors: Mengwe, Moses Seargent
- Date: 2010
- Subjects: Copper mines and mining -- Environmental aspects -- Botswana , Nickel mines and mining -- Environmental aspects -- Botswana , Mineral industry -- Botswana , Mines and mineral resources -- Botswana
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10644 , http://hdl.handle.net/10948/1443 , Copper mines and mining -- Environmental aspects -- Botswana , Nickel mines and mining -- Environmental aspects -- Botswana , Mineral industry -- Botswana , Mines and mineral resources -- Botswana
- Description: This research study is more of an initiative towards Social Impact Assessment of copper-nickel mining in Botswana. The specific objectives of the study were centred on the assessment of the social impacts of copper-nickel mining in Botswana from the initial mining stage of exploration, surveying and mine site development to mine closure. The study was carried out under the broad hypotheses that mining influences population movement that impact on areas of mining; mining activities have both economic benefits and deleterious social impacts on the local communities found in the areas where mining is taking place; and mine closure has far reaching socio-economic, investment and developmental implications over and above the obvious interests of project owners. To achieve the broad aim as summarised above, the research study used a multi-disciplinary methodology and approach that required several kinds of expertise and sources of information. Hence it used both primary and secondary sources centred on interactive informative interviews, site visits and observations, questionnaires, census data records, mining companies’ publications, published textbooks and journal articles. The research study comprised of three different mines operated by three different mining companies in three varied socio-cultural and ethnic regions of Botswana. First was a detailed Social Impact Assessment of the initial phase of exploration, surveying and mine site development represented by Mowana mine project operated by African Copper in the rural areas of Dugwi and Mosetse. This case study yielded results showing that the social impacts of mining in the area are diverse and extensive. The findings suggest that the impacts relate not only to the possible economic benefits of foreign exchange, employment, the optimal use of available mineral resources and the possible development of Dugwi and Mosetse villages, but extends to the deleterious social impacts. The results also indicated that the social impacts have just begun in the two communities. Hence they point towards a possible disruption within the socio-cultural system of the local people if serious mitigation measures are not put in place; thus suggesting that the early stages of exploration and mine site development results in the most conflict between the mine and the local people. Second was a comprehensive Social Impact Assessment of Tati-Nickel Phoenix mining project in the peri-urban areas of Matshelagabedi and Matsiloje areas representing the mining stage of mine production and expansion. The results from this case study suggest that during vi mine production and expansion, many people were relocated. However, the overriding impression gained from the case study was Tati-Nickel Mining Company’s elaborate corporate policies that suggested good corporate governance and best practices that promote sustainable development. A notable milestone on good corporate governance and best practice that the other two case studies (mining company) could benchmark on is Tati-Nickel’s corporate social responsibility programme that has been designed to ensure that the communities within a fifty kilometre mine radius benefit from the mine. The results from the case study also distinguished the mining stage of production and expansion from the other two because it is associated with the deep entrenchment of the social impacts into the communities near to mining areas. Third was a detailed Social Impact Assessment on Bamangwato Concession Limited mine in the industrial town of Selebi-Phikwe. The case study represented the stage of mine closure. Through the findings of this case study, it became apparent that the economic dependence of Selebi-Phikwe on mining has seen the town developing into a mining town, increasing its vulnerability at mine closure. The results from the case study further suggest that mine closure will degrade the socio-economic sector of the town with ever far reaching socio-economic implications as many people lose their gainful employment, hence suggesting that a possible complete mine closure will be the most traumatic phase leading to major social conflict within the area. Thus the results suggest that at mine closure, the deleterious social impacts will overspill to other areas in Botswana with disastrous effects for the economy of the country. The results yielded through this study established in clear and passionate language that copper-nickel mining in Botswana influences population movements that lead to positive and negative impacts on the communities found in mining areas. Another major finding of the study is that copper-nickel mining activities have both economic benefits and deleterious social impacts on the local communities, hence the recommendation that the copper-nickel mining companies should embrace the concept of sustainable mining for sustainable development to avoid most of the negative impacts of their operations on the local communities.
- Full Text:
- Date Issued: 2010
- Authors: Mengwe, Moses Seargent
- Date: 2010
- Subjects: Copper mines and mining -- Environmental aspects -- Botswana , Nickel mines and mining -- Environmental aspects -- Botswana , Mineral industry -- Botswana , Mines and mineral resources -- Botswana
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10644 , http://hdl.handle.net/10948/1443 , Copper mines and mining -- Environmental aspects -- Botswana , Nickel mines and mining -- Environmental aspects -- Botswana , Mineral industry -- Botswana , Mines and mineral resources -- Botswana
- Description: This research study is more of an initiative towards Social Impact Assessment of copper-nickel mining in Botswana. The specific objectives of the study were centred on the assessment of the social impacts of copper-nickel mining in Botswana from the initial mining stage of exploration, surveying and mine site development to mine closure. The study was carried out under the broad hypotheses that mining influences population movement that impact on areas of mining; mining activities have both economic benefits and deleterious social impacts on the local communities found in the areas where mining is taking place; and mine closure has far reaching socio-economic, investment and developmental implications over and above the obvious interests of project owners. To achieve the broad aim as summarised above, the research study used a multi-disciplinary methodology and approach that required several kinds of expertise and sources of information. Hence it used both primary and secondary sources centred on interactive informative interviews, site visits and observations, questionnaires, census data records, mining companies’ publications, published textbooks and journal articles. The research study comprised of three different mines operated by three different mining companies in three varied socio-cultural and ethnic regions of Botswana. First was a detailed Social Impact Assessment of the initial phase of exploration, surveying and mine site development represented by Mowana mine project operated by African Copper in the rural areas of Dugwi and Mosetse. This case study yielded results showing that the social impacts of mining in the area are diverse and extensive. The findings suggest that the impacts relate not only to the possible economic benefits of foreign exchange, employment, the optimal use of available mineral resources and the possible development of Dugwi and Mosetse villages, but extends to the deleterious social impacts. The results also indicated that the social impacts have just begun in the two communities. Hence they point towards a possible disruption within the socio-cultural system of the local people if serious mitigation measures are not put in place; thus suggesting that the early stages of exploration and mine site development results in the most conflict between the mine and the local people. Second was a comprehensive Social Impact Assessment of Tati-Nickel Phoenix mining project in the peri-urban areas of Matshelagabedi and Matsiloje areas representing the mining stage of mine production and expansion. The results from this case study suggest that during vi mine production and expansion, many people were relocated. However, the overriding impression gained from the case study was Tati-Nickel Mining Company’s elaborate corporate policies that suggested good corporate governance and best practices that promote sustainable development. A notable milestone on good corporate governance and best practice that the other two case studies (mining company) could benchmark on is Tati-Nickel’s corporate social responsibility programme that has been designed to ensure that the communities within a fifty kilometre mine radius benefit from the mine. The results from the case study also distinguished the mining stage of production and expansion from the other two because it is associated with the deep entrenchment of the social impacts into the communities near to mining areas. Third was a detailed Social Impact Assessment on Bamangwato Concession Limited mine in the industrial town of Selebi-Phikwe. The case study represented the stage of mine closure. Through the findings of this case study, it became apparent that the economic dependence of Selebi-Phikwe on mining has seen the town developing into a mining town, increasing its vulnerability at mine closure. The results from the case study further suggest that mine closure will degrade the socio-economic sector of the town with ever far reaching socio-economic implications as many people lose their gainful employment, hence suggesting that a possible complete mine closure will be the most traumatic phase leading to major social conflict within the area. Thus the results suggest that at mine closure, the deleterious social impacts will overspill to other areas in Botswana with disastrous effects for the economy of the country. The results yielded through this study established in clear and passionate language that copper-nickel mining in Botswana influences population movements that lead to positive and negative impacts on the communities found in mining areas. Another major finding of the study is that copper-nickel mining activities have both economic benefits and deleterious social impacts on the local communities, hence the recommendation that the copper-nickel mining companies should embrace the concept of sustainable mining for sustainable development to avoid most of the negative impacts of their operations on the local communities.
- Full Text:
- Date Issued: 2010
Towards the synthesis of coumarin derivatives as potential dual-action HIV-1 protease and reverse transcriptase inhibitors
- Olomola, Temitope O, Klein, Rosalyn, Lobb, Kevin A, Sayed, Yasien, Kaye, Perry T
- Authors: Olomola, Temitope O , Klein, Rosalyn , Lobb, Kevin A , Sayed, Yasien , Kaye, Perry T
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448963 , vital:74774 , xlink:href="https://doi.org/10.1016/j.tetlet.2010.09.121"
- Description: 3-(Chloromethyl)coumarins, obtained via acid-catalysed cyclisation of salicylaldehyde-derived Baylis– Hillman adducts, have been treated with propargylamine; reaction of the resulting 3-alkynylmethylcoumarins with azidothymidine (AZT) in the presence of a Cu(I) catalyst has afforded a series of cycloaddition products for evaluation, in their own right, as potential dual-action HIV-1 protease and non-nucleoside reverse transcriptase inhibitors, and as scaffolds for further structural elaboration.
- Full Text:
- Date Issued: 2010
- Authors: Olomola, Temitope O , Klein, Rosalyn , Lobb, Kevin A , Sayed, Yasien , Kaye, Perry T
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448963 , vital:74774 , xlink:href="https://doi.org/10.1016/j.tetlet.2010.09.121"
- Description: 3-(Chloromethyl)coumarins, obtained via acid-catalysed cyclisation of salicylaldehyde-derived Baylis– Hillman adducts, have been treated with propargylamine; reaction of the resulting 3-alkynylmethylcoumarins with azidothymidine (AZT) in the presence of a Cu(I) catalyst has afforded a series of cycloaddition products for evaluation, in their own right, as potential dual-action HIV-1 protease and non-nucleoside reverse transcriptase inhibitors, and as scaffolds for further structural elaboration.
- Full Text:
- Date Issued: 2010
Trade union investment schemes: a blemish on the social movement unionism outlook of South African unions?
- Authors: Rubushe, Melikaya
- Date: 2010
- Subjects: Labor unions -- South Africa , Labor unions and communism , Cosatu , Economic development -- South Africa , National Union of Mineworkers (South Africa) , Labor unions -- Finance , Business enterprises, Black -- South Africa , Investments -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3331 , http://hdl.handle.net/10962/d1003119 , Labor unions -- South Africa , Labor unions and communism , Cosatu , Economic development -- South Africa , National Union of Mineworkers (South Africa) , Labor unions -- Finance , Business enterprises, Black -- South Africa , Investments -- South Africa
- Description: South African trade unions affiliated to Congress of South African Trade Unions (COSATU) have taken advantage of the arrival of democracy and newly found opportunities available through Black Economic Empowerment to venture into the world of business by setting up their own investment companies. The declared desire behind these ventures was to break the stranglehold of white capital on the economy and to extend participation in the economic activities of the country to previously disadvantaged communities. Using the National Union of Mineworkers and the Mineworkers’ Investment Company as case studies, this dissertation seeks to determine whether unions affiliated to the Congress of South African Trade Unions (COSATU) are advancing the struggle for socialism through their investment schemes. Secondly, the dissertation determines whether, in the activities of the schemes, internal democracy is preserved and strengthened. The theoretical framework of this dissertation emerges from arguments advanced by Lenin and Gramsci on the limitations of trade unions in terms of their role in the struggle against capitalism. In addition, the argument draws on the assertions by Michels regarding the proneness of trade union leadership to adopt oligarchic tendencies in their approach to leadership. Of interest is how, according to Gramsci, trade unions are prone to accepting concessions from the capitalist system that renders them ameliorative rather than transformative. Drawing from Michels’ ‘iron law of oligarchy’, the thesis examines whether there is space for ordinary members of the unions to express views on the working of the union investment companies. By looking at the extent to which the investment initiatives of the companies mirror the preferences of the ordinary members of the unions, one can determine the level of disjuncture between the two. The study relies on data collected through interviews and documentary material. Interviews provide first-hand knowledge of how respondents experience the impact of the investment schemes. This provides a balanced analysis given that documents reflect policy stances whereas interviews provide data on whether these have the stated impact. What the study shows is a clear absence of space for ordinary members to directly influence the workings of union investment companies. It is also established that, in their current form, the schemes operate more as a perpetuation of the capitalist logic than offering an alternative system.
- Full Text:
- Date Issued: 2010
- Authors: Rubushe, Melikaya
- Date: 2010
- Subjects: Labor unions -- South Africa , Labor unions and communism , Cosatu , Economic development -- South Africa , National Union of Mineworkers (South Africa) , Labor unions -- Finance , Business enterprises, Black -- South Africa , Investments -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3331 , http://hdl.handle.net/10962/d1003119 , Labor unions -- South Africa , Labor unions and communism , Cosatu , Economic development -- South Africa , National Union of Mineworkers (South Africa) , Labor unions -- Finance , Business enterprises, Black -- South Africa , Investments -- South Africa
- Description: South African trade unions affiliated to Congress of South African Trade Unions (COSATU) have taken advantage of the arrival of democracy and newly found opportunities available through Black Economic Empowerment to venture into the world of business by setting up their own investment companies. The declared desire behind these ventures was to break the stranglehold of white capital on the economy and to extend participation in the economic activities of the country to previously disadvantaged communities. Using the National Union of Mineworkers and the Mineworkers’ Investment Company as case studies, this dissertation seeks to determine whether unions affiliated to the Congress of South African Trade Unions (COSATU) are advancing the struggle for socialism through their investment schemes. Secondly, the dissertation determines whether, in the activities of the schemes, internal democracy is preserved and strengthened. The theoretical framework of this dissertation emerges from arguments advanced by Lenin and Gramsci on the limitations of trade unions in terms of their role in the struggle against capitalism. In addition, the argument draws on the assertions by Michels regarding the proneness of trade union leadership to adopt oligarchic tendencies in their approach to leadership. Of interest is how, according to Gramsci, trade unions are prone to accepting concessions from the capitalist system that renders them ameliorative rather than transformative. Drawing from Michels’ ‘iron law of oligarchy’, the thesis examines whether there is space for ordinary members of the unions to express views on the working of the union investment companies. By looking at the extent to which the investment initiatives of the companies mirror the preferences of the ordinary members of the unions, one can determine the level of disjuncture between the two. The study relies on data collected through interviews and documentary material. Interviews provide first-hand knowledge of how respondents experience the impact of the investment schemes. This provides a balanced analysis given that documents reflect policy stances whereas interviews provide data on whether these have the stated impact. What the study shows is a clear absence of space for ordinary members to directly influence the workings of union investment companies. It is also established that, in their current form, the schemes operate more as a perpetuation of the capitalist logic than offering an alternative system.
- Full Text:
- Date Issued: 2010
Transcending objectifications and dualisms: farm workers and civil society in contemporary Zimbabwe
- Sadomba, Zvakanyorwa W, Helliker, Kirk D
- Authors: Sadomba, Zvakanyorwa W , Helliker, Kirk D
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71242 , vital:29822 , https://doi.org/10.1177/0021909609357417
- Description: In the academic literature, civil society is often conceptualized in terms of objectifications and subject—object dichotomies. This is the case with regard to both social movements and non-governmental organizations. This article seeks to transcend such argumentation by providing ‘thick descriptions’ of the agency of farm workers and civil society in the context of land reform in contemporary Zimbabwe. We examine a land-based social movement (and the role of farm workers within it) and the involvement of a particular non-governmental organization in farm worker livelihoods. On this basis, we offer a re-formulation of civil society as a social field marked by ambivalences and tensions.
- Full Text: false
- Date Issued: 2010
- Authors: Sadomba, Zvakanyorwa W , Helliker, Kirk D
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71242 , vital:29822 , https://doi.org/10.1177/0021909609357417
- Description: In the academic literature, civil society is often conceptualized in terms of objectifications and subject—object dichotomies. This is the case with regard to both social movements and non-governmental organizations. This article seeks to transcend such argumentation by providing ‘thick descriptions’ of the agency of farm workers and civil society in the context of land reform in contemporary Zimbabwe. We examine a land-based social movement (and the role of farm workers within it) and the involvement of a particular non-governmental organization in farm worker livelihoods. On this basis, we offer a re-formulation of civil society as a social field marked by ambivalences and tensions.
- Full Text: false
- Date Issued: 2010
Transformativity: recognising melancholic power, and renegotiating vulnerability
- Authors: Knowles, Corinne Ruth
- Date: 2010
- Subjects: Transformational leadership -- South Africa Educational change -- South Africa Universities and colleges -- South Africa Sex discrimination in higher education -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2789 , http://hdl.handle.net/10962/d1002999
- Description: South African universities are embedded in an unequal society. Transformation strategies and interventions in the sector attempt to address this, but arguably, the policies and practices which aim to bring about transformation are merely platforms for potential change and do not guarantee the achievement of their aspirations. This study engages with the notion of transformation in one university, looking at how an organisation for women has contributed to transformation in individuals and in the institution. It explores the idea that vulnerability is the starting point of transformation, and must be recognized and incorporated into how an organisation, institution or individual regards vulnerable groups, in order to build a more equitable society. The reframing of vulnerability is a process of acknowledging the way power works, and arguably, power’s melancholic nature and expression in society and in universities has particular challenges with regard to how vulnerable groups experience their vulnerability. If the framing of an individual as vulnerable does not also provide that individual with the conditions that shelter the vulnerability they experience, leading to a renegotiation of whom they can become, their “vulnerable” status is entrenched. The study explores ways in which an organisation for women uses its legitimized platform for renegotiating subjectivities, norms and performances, and the potential this has for transformativity.
- Full Text:
- Date Issued: 2010
- Authors: Knowles, Corinne Ruth
- Date: 2010
- Subjects: Transformational leadership -- South Africa Educational change -- South Africa Universities and colleges -- South Africa Sex discrimination in higher education -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2789 , http://hdl.handle.net/10962/d1002999
- Description: South African universities are embedded in an unequal society. Transformation strategies and interventions in the sector attempt to address this, but arguably, the policies and practices which aim to bring about transformation are merely platforms for potential change and do not guarantee the achievement of their aspirations. This study engages with the notion of transformation in one university, looking at how an organisation for women has contributed to transformation in individuals and in the institution. It explores the idea that vulnerability is the starting point of transformation, and must be recognized and incorporated into how an organisation, institution or individual regards vulnerable groups, in order to build a more equitable society. The reframing of vulnerability is a process of acknowledging the way power works, and arguably, power’s melancholic nature and expression in society and in universities has particular challenges with regard to how vulnerable groups experience their vulnerability. If the framing of an individual as vulnerable does not also provide that individual with the conditions that shelter the vulnerability they experience, leading to a renegotiation of whom they can become, their “vulnerable” status is entrenched. The study explores ways in which an organisation for women uses its legitimized platform for renegotiating subjectivities, norms and performances, and the potential this has for transformativity.
- Full Text:
- Date Issued: 2010
Trophic ecology of grey-headed albatrosses from Marion Island, Southern Ocean: insights from stomach contents and diet tracers
- Richoux, Nicole B, Jaquemet, Se´bastien, Bonnevie, Bo T, Cherel, Yves, McQuaid, Christopher D
- Authors: Richoux, Nicole B , Jaquemet, Se´bastien , Bonnevie, Bo T , Cherel, Yves , McQuaid, Christopher D
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/458019 , vital:75710 , xlink:href="https://doi.org/10.1007/s00227-010-1448-y"
- Description: During chick-rearing, albatrosses can alternate between long foraging trips that provide the main source of food for the adults and short foraging trips that they use to feed their young. This flexibility in foraging behaviour can lead to differences in diet composition between adults and chicks and implies that they may be vulnerable in different ways to food shortages. The trophic ecology of the Grey-headed albatross Thalassarche chrysostoma was investigated at the sub-Antarctic Prince Edward Islands during the chick-rearing period in April 2006 using a combination of approaches. Diets of adults and chicks were assessed using stable isotope ratios and fatty acid (FA) profiles of blood and/or stomach oils, in addition to stomach contents analysis. Fish from the family Macrouridae and cephalopods (particularly the onychoteuthid Kondakovia longimana) were the primary prey, whereas crustaceans (krill Euphausia superba) represented a smaller proportion of the stomach contents. Stomach oil FA profiles contained more monounsaturated FA than the profiles of plasma, which were richer in saturated FA and arachidonic acid (20:4n-6). There was also a distinct separation of adults from chicks, with higher levels of monounsaturates in chick plasma, and higher saturated FA levels (particularly 16:0) in the adult plasma. Stable carbon isotope ratios of whole blood were similar in adults and chicks, whereas stable nitrogen isotope ratios showed significant enrichment by >1‰ in chicks. The combined FA, stable isotopes and stomach contents analyses suggest clear differences in diet quality between adults and chicks, with chicks feeding at a higher trophic position through feeding more on highly nutritious fish and adults keeping much of the less nutritious zooplankton for themselves.
- Full Text:
- Date Issued: 2010
- Authors: Richoux, Nicole B , Jaquemet, Se´bastien , Bonnevie, Bo T , Cherel, Yves , McQuaid, Christopher D
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/458019 , vital:75710 , xlink:href="https://doi.org/10.1007/s00227-010-1448-y"
- Description: During chick-rearing, albatrosses can alternate between long foraging trips that provide the main source of food for the adults and short foraging trips that they use to feed their young. This flexibility in foraging behaviour can lead to differences in diet composition between adults and chicks and implies that they may be vulnerable in different ways to food shortages. The trophic ecology of the Grey-headed albatross Thalassarche chrysostoma was investigated at the sub-Antarctic Prince Edward Islands during the chick-rearing period in April 2006 using a combination of approaches. Diets of adults and chicks were assessed using stable isotope ratios and fatty acid (FA) profiles of blood and/or stomach oils, in addition to stomach contents analysis. Fish from the family Macrouridae and cephalopods (particularly the onychoteuthid Kondakovia longimana) were the primary prey, whereas crustaceans (krill Euphausia superba) represented a smaller proportion of the stomach contents. Stomach oil FA profiles contained more monounsaturated FA than the profiles of plasma, which were richer in saturated FA and arachidonic acid (20:4n-6). There was also a distinct separation of adults from chicks, with higher levels of monounsaturates in chick plasma, and higher saturated FA levels (particularly 16:0) in the adult plasma. Stable carbon isotope ratios of whole blood were similar in adults and chicks, whereas stable nitrogen isotope ratios showed significant enrichment by >1‰ in chicks. The combined FA, stable isotopes and stomach contents analyses suggest clear differences in diet quality between adults and chicks, with chicks feeding at a higher trophic position through feeding more on highly nutritious fish and adults keeping much of the less nutritious zooplankton for themselves.
- Full Text:
- Date Issued: 2010
Tuning the physico-electrochemical properties of novel cobalt (II) octa [(3, 5-biscarboxylate)-phenoxy] phthalocyanine complex using phenylamine-functionalised SWCNTs
- Agboola, Bolade O, Ozoemena, Kenneth I, Nyokong, Tebello, Fukuda, Takamitsu, Kobayashi, Nagao
- Authors: Agboola, Bolade O , Ozoemena, Kenneth I , Nyokong, Tebello , Fukuda, Takamitsu , Kobayashi, Nagao
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261692 , vital:53435 , xlink:href="https://doi.org/10.1016/j.carbon.2009.10.023"
- Description: The integration of phenylamine-functionalised SWCNTs (SWCNT-phenylamine) with a novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine (CoOBPPc) complex has been described. The physical and electrochemical properties of the CoOBPPc-SWCNT-phenylamine hybrid were evaluated using spectroscopy (IR and UV–vis), field emission scanning electron microscopy and electrochemistry (cyclic voltammetry and electrochemical impedance spectroscopy). Integration of SWCNT-phenylamine resulted in the physical transformation of the CoOBCPPc from the usually bluish colour of cobalt phthalocyanine complexes to a beautiful bright green colour. In addition, the heterogeneous electron transfer kinetics and electrocatalytic properties of the CoOBCPPc were greatly enhanced following the attachment of the SWCNT-phenylamine. The potential electrocatalytic application of the hybrid was tested using β-nicotinamide adenine dinucleotide (NADH) as a model biological analyte. Interestingly, the onset oxidation potential of this analyte was significantly reduced (300 mV) by this hybrid compared to the bare electrode.
- Full Text:
- Date Issued: 2010
- Authors: Agboola, Bolade O , Ozoemena, Kenneth I , Nyokong, Tebello , Fukuda, Takamitsu , Kobayashi, Nagao
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261692 , vital:53435 , xlink:href="https://doi.org/10.1016/j.carbon.2009.10.023"
- Description: The integration of phenylamine-functionalised SWCNTs (SWCNT-phenylamine) with a novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine (CoOBPPc) complex has been described. The physical and electrochemical properties of the CoOBPPc-SWCNT-phenylamine hybrid were evaluated using spectroscopy (IR and UV–vis), field emission scanning electron microscopy and electrochemistry (cyclic voltammetry and electrochemical impedance spectroscopy). Integration of SWCNT-phenylamine resulted in the physical transformation of the CoOBCPPc from the usually bluish colour of cobalt phthalocyanine complexes to a beautiful bright green colour. In addition, the heterogeneous electron transfer kinetics and electrocatalytic properties of the CoOBCPPc were greatly enhanced following the attachment of the SWCNT-phenylamine. The potential electrocatalytic application of the hybrid was tested using β-nicotinamide adenine dinucleotide (NADH) as a model biological analyte. Interestingly, the onset oxidation potential of this analyte was significantly reduced (300 mV) by this hybrid compared to the bare electrode.
- Full Text:
- Date Issued: 2010
Two new species of Prosopistomatidae (Ephemeroptera) from South Africa and Swaziland
- Authors: Barber-James, Helen M
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452385 , vital:75124 , https://hdl.handle.net/10520/EJC32841
- Description: Three species of Prosopistoma Latreille, 1833 are currently described from Africa. The immature nymph of Prosopistoma deguernei Vayssière, 1893 was described from Senegal, and the nymph and winged stages of Prosopistoma africanum Gillies, 1954 are known from Tanzania. The southern African species Prosopistoma crassi Gillies, 1954, initially described as a nymph from KwaZulu-Natal, South Africa, has subsequently been collected in a number of South African rivers. Two further species from South Africa are described here, the nymph of Prosopistoma amanzamnyama sp. n., and the nymph and female subimago of Prosopistoma mccaffertyi sp. n.
- Full Text:
- Date Issued: 2010
- Authors: Barber-James, Helen M
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/452385 , vital:75124 , https://hdl.handle.net/10520/EJC32841
- Description: Three species of Prosopistoma Latreille, 1833 are currently described from Africa. The immature nymph of Prosopistoma deguernei Vayssière, 1893 was described from Senegal, and the nymph and winged stages of Prosopistoma africanum Gillies, 1954 are known from Tanzania. The southern African species Prosopistoma crassi Gillies, 1954, initially described as a nymph from KwaZulu-Natal, South Africa, has subsequently been collected in a number of South African rivers. Two further species from South Africa are described here, the nymph of Prosopistoma amanzamnyama sp. n., and the nymph and female subimago of Prosopistoma mccaffertyi sp. n.
- Full Text:
- Date Issued: 2010
Unethical decision-making and behaviour in the life insurance sector of South Africa
- Authors: Van Greunen, Conrad
- Date: 2010
- Subjects: Insurance companies -- Corrupt pratices -- South Africa , Business ethics -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:9282 , http://hdl.handle.net/10948/1364 , Insurance companies -- Corrupt pratices -- South Africa , Business ethics -- South Africa
- Description: The public is regularly shocked by revelations of new business scandals. Nearly every sector of society is tainted by incidents of unethical behaviour. In this regard, the South African financial services industry has attracted a lot of attention, as some of the biggest scandals in recent years have occurred in this industry. With the world economy still experiencing the effects of the global recession, the last thing that institutions in the financial arena must do is engage in unethical behaviour. Immoral behaviour could damage a company's repution and lead to further financial losses. The purpose of this study was thus two-fold: firstly, to investigae the factors that influence unethical decision-making and behaviour in the local life insurance sector, and secondly to evaluate how business ethics are institutionalised at a sample of life insurance companies.
- Full Text:
- Date Issued: 2010
- Authors: Van Greunen, Conrad
- Date: 2010
- Subjects: Insurance companies -- Corrupt pratices -- South Africa , Business ethics -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:9282 , http://hdl.handle.net/10948/1364 , Insurance companies -- Corrupt pratices -- South Africa , Business ethics -- South Africa
- Description: The public is regularly shocked by revelations of new business scandals. Nearly every sector of society is tainted by incidents of unethical behaviour. In this regard, the South African financial services industry has attracted a lot of attention, as some of the biggest scandals in recent years have occurred in this industry. With the world economy still experiencing the effects of the global recession, the last thing that institutions in the financial arena must do is engage in unethical behaviour. Immoral behaviour could damage a company's repution and lead to further financial losses. The purpose of this study was thus two-fold: firstly, to investigae the factors that influence unethical decision-making and behaviour in the local life insurance sector, and secondly to evaluate how business ethics are institutionalised at a sample of life insurance companies.
- Full Text:
- Date Issued: 2010