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The photophysicochemical properties and photodynamic therapy activity of In and Zn phthalocyanines when incorporated into individual or mixed Pluronic® micelles

- Motloung, Banele M, Babu, Balaji, Prinsloo, Earl, Nyokong, Tebello

  • Authors: Motloung, Banele M , Babu, Balaji , Prinsloo, Earl , Nyokong, Tebello
  • Date: 2020
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/186124 , vital:44465 , xlink:href="https://doi.org/10.1016/j.poly.2020.114683"
  • Description: The synthesis, photophysicochemical properties and photodynamic activity (PDT) of tetra-pyridyloxy (1,2) and benzothiazole (3, 4) substituted indium (III) (1,3) and zinc (2, 4) phthalocyanines (Pcs) and their incorporation into Pluronic® F127 and Pluronic L121/F127 mixed micelles (the latter for 3 and 4 only) are presented in this study. The InPcs exhibited higher singlet oxygen (ΦΔ) at 0.76 and 0.68 compared to the ZnPc’s at 0.47 and 0.44 in dimethyl sulfoxide. The ΦΔ values in the presence of Pluronic® F127 and in water, were 0.39 and 0.42 for InPcs and 0.23 and 0.37 for ZnPc. The ΦΔ values in the presence of Pluronic F127/L121 mixed micelles for complex 3 and 4 were 0.51 and 0.29 in water. The Kp was determined using the water and octanol system. InPcs had larger Kp values suggesting that they are more likely to be taken up by the cancer cells hence they showed better PDT activity
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The political ecological economics of coal mining and water resources: a participatory economic valuation approach in Carolina, Mpumalanga

- Nzimande, Nqobile

The political promise of choreography in performance and/as research: First Physical Theatre Company’s manifesto and repertory, 1993-2015

- Finestone-Praeg, Juanita

  • Authors: Finestone-Praeg, Juanita
  • Date: 2020
  • Subjects: Choreography -- Political aspects , Dance -- South Africa -- Makhanda , Dance -- Political aspects , Performance art -- South Africa -- Makhanda , Performance art -- History and criticism , Performance art -- Research , Performance art -- Study and teaching , Performance art -- Philosophy , Experimental theater -- South Africa -- Makhanda , Experimental theater -- History and criticism , Political art -- South Africa -- Makhanda , First Physical Theatre Company , First Physical Theatre Company -- History and criticism
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: http://hdl.handle.net/10962/149373 , vital:38844
  • Description: This study redefines the political in dance by drawing on the scholarly concept of the “choreopolitical” (André Lepecki) and extending it into analysing related concepts such as the “postdramatic” (Hans-Thies Lehmann), performance and/as research, among others from Performance Studies scholarship as well as from First Physical Theatre Company’s pioneering legacy of production, pedagogy and research in making Phyical Theatre performance. Following from the notion that performance is both a site and a method of study/knowing, the research invites a rethinking of the relationship between art (performance), epistemology and the political, in the sense that performance becomes a way, not of simply re-presenting the political but, as its own way of knowing, actively questioning the very categories on which the political is premised. The argument for Physical Theatre as having nascent potential to invoke what I call “the power of the small” is analysed as a choreopolitical method and community of practice that has a generative capacity to produce the “intimate revolts” (Julia Kristeva) or body of questions that can perform the imaginative curiosities/forms required to create provocative, subversive, ethical, reflexive and charged performance. My argument is supported by critical commentary, insight, choreological analysis and reflection on the dramaturgical strategies and choreopolitics of selected commissioned choreographers and dance forms that extended FPTC’s manifesto and production between 1993 and 2015. My project has the following three goals: (i) to contextualise, conceptualise and identify key issues in the identity, pedagogy and performance ethos of Physical Theatre as a performance philosophy and form; (ii) to engage critically with the praxis of Physical Theatre within the contextual, cultural, historical and political relationships between Physical Theatre and other performance practices in South Africa; and (iii) to document, analyse and interpret selected claims, works and performance processes from the archive of FPTC’s repertory and training manifesto from 1993 to 2015. The research evaluates the political significance and consequence of FPTC’s heritage and legacy problematising constraints, possibilities, tensions, failures and proposing the hope of imaginative entanglements with practising freedoms.
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The political thought of Thomas Sankara and its contemporary relevance

- Kabwato, Levison M

  • Authors: Kabwato, Levison M
  • Date: 2020
  • Subjects: Sankara, Thomas , Sankara, Thomas -- Influence , Burkina Faso -- Politics and government -- 1960-1987 , Cabral, Amílcar, 1924-1973 , Fanon, Frantz, 1925-1961 , Nkrumah, Kwame, 1909-1972
  • Language: English
  • Type: text , Thesis , Masters , MA
  • Identifier: http://hdl.handle.net/10962/146556 , vital:38536
  • Description: On 4 August 1983, a thirty-three year-old army captain seized power in Burkina Faso and embarked on what can be described a revolutionary journey. Over the next four years, until his assassination in 1987 the government, led by Captain Thomas Sankara, attempted to redeem Burkina Faso from the clutches of neo-colonialism. Through popular mobilisation and organisation, infrastructure (schools, hospitals, bridges) was built, millions of children were vaccinated and diseases such as river blindness were eliminated. Women, long-subjugated by patriarchal systems took up space and led their own initiatives in freedom, including holding senior roles in the public service. On the international stage, practical solidarity was extended to countries either fighting or threatened by neo-colonialism despite the fact that Burkina Faso was poor and was itself threatened by France and her lackeys. What Sankara inherited in August 1983, twenty-three years after Burkina Faso’s independence, was a fragile neo-colonial state which was not allowed by dominant imperialist interests to set an example of what true independence means. So, in just four years, it was all over. Sankara was assassinated by his comrades and the revolutionary project he had led came to a halt. The tragedy of Sankara was the tragedy of all those attempts at revolution which occur before mass movements have had the opportunity to develop and organise themselves independently of the state. Despite this, it is apparent today that Sankara has been influential on current political movements and parties in Africa, from Burkina Faso to South Africa. One of these political movements is the Economic Freedom Fighters (EFF) in South Africa. This half-thesis is an investigation of Sankara’s political thought. It also examines the extent to which his answers to questions of nationalism and pan-Africanism both matched and differed from his predecessors. To accomplish the latter, a brief but critical analysis of the writings of Amílcar Cabral, Frantz Fanon, Kwame Nkrumah is made.
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The potential for biological control on cryptic plant invasions

- Canavan, Kim N, Canavan, Susan, Harms, Nathan E, Lambertini, Carla, Paterson, Iain D, Thum, Ryan A

  • Authors: Canavan, Kim N , Canavan, Susan , Harms, Nathan E , Lambertini, Carla , Paterson, Iain D , Thum, Ryan A
  • Date: 2020
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/423562 , vital:72072 , xlink:href="https://doi.org/10.1016/j.biocontrol.2020.104243"
  • Description: Cryptic invasions can be defined as ‘the occurrence of an invasive species or genotype that was not previously recognised as alien in origin or not distinguished from other aliens’. Such invasions can result in negative impacts on the recipient ecosystems and disturb the evolutionary history of native plant populations. Many cryptic invasions have become so problematic that there is a need to implement control measures. This paper explores the potential for biological control to be implemented as a means of managing cryptic invasions. Firstly, the paper defines the different forms of cryptic invasion, differentiating between interspecific and intraspecific invasions; this hierarchy influences how to detect, study and ultimately implement biological control when cryptic invasions occur. Secondly, unique challenges associated with biological control programmes for cryptic invasions are addressed, including: the need for intraspecific level host specificity in agents, the occurrence of hybridisation between native species/lineages and the target weed, the role of enemy release in cryptic invasions in the presence of closely related native plant species/lineages, and a review of potential stakeholder conflicts of interest and legislation. Biological control of cryptic invasions has been shown to be possible, however the process will be more difficult and complex than controlling traditional targets and will likely take up more time and resources. If these challenges are overcome, then biological control programmes against cryptic invasions should be able to proceed and maintain the same standards as traditional biological control programmes.
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The potential of Geography fieldwork projects to develop action competence in response to social-ecological concerns: a case study of two Grade 10 Geography classes in Northern Namibia

- Mwiila, Modestus

  • Authors: Mwiila, Modestus
  • Date: 2020
  • Subjects: Geography -- Study and teaching (Secondary) -- Namibia
  • Language: English
  • Type: text , Thesis , Masters , MEd
  • Identifier: http://hdl.handle.net/10962/126563 , vital:35901
  • Description: The study explored the potential of Geography fieldwork projects to develop learners’ action competence in response to social-ecological problems in two schools in the Omusati and Oshana Education Regions. The study investigates ways in which learners’ activities create an opportunity for them to act for the environment. That is, to investigate ways in which learners can be shaped into environmentally literate citizens who act for the environment. A total of 43 grade 10 learners and two grade 10 Geography teachers participated in this qualitative, interpretive case study. Data was generated through document analysis, focus group interview with learners, semi-structured interviews with educators, and participant observations. Such data were analysed into three phases, first inductively and then abductively using Jensen’s (2004) Investigations, Visions, Actions and Change (IVAC) model to produce analytic statements that form the basis of the research findings. The study found that Geography fieldwork projects foster understandings of environmental problems in a local area. Through fieldwork projects, schools initiate indirect environmental actions, however, some environmental problems are too large or complex to be resolved by the actions initiated by learners. Based on these findings, the study identifies Geography fieldwork as an opportunity to create a community of practice in effort to address socioecological concerns. The study further recommends that learners should be allowed to engage with both social investigative actions and technical, scientific investigative actions when doing project work.
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The precarious ‘good mother’ position: a psychosocial reading of maternal subjectivity of working mothers in scarcely-resourced South African communities

- Kinahan-Sweeney, Siobhan

  • Authors: Kinahan-Sweeney, Siobhan
  • Date: 2020
  • Subjects: Motherhood -- Psychological aspects -- South Africa , Working mothers -- South Africa -- Attitudes , Working mothers -- South Africa -- Psychology
  • Language: English
  • Type: text , Thesis , Doctoral , PhD
  • Identifier: http://hdl.handle.net/10962/142464 , vital:38082
  • Description: This psychosocial study investigates the maternal subjectivities of mothers returning to work after maternity leave, who are living in scarcely-resourced Cape Town communities in South Africa. Engaging with interview texts and listening to mothers’ talk, I explore how and why maternal subjectivity is constructed discursively and defensively in our talk. This thesis claims that these particular mothers predominately employ instrumental mothering discourse. The traditional subject position of the intensive mother – which is typically assumed to be the ‘good mother’ – is not a position available to these mothers due to their social circumstances and working role. Subsequently, material provision, the baby’s thriving and surviving body, finding substitute carers and maternal preoccupation are constructed as qualities of ‘good mothering’ in their talk. This ‘good mother’ position, however, is a precarious position that both these mothers and I invest in to defend against feelings towards their babies and themselves as well as to deny (maternal) ambivalence in a problematic social system. In a combined analysis drawing on discursive theory and psychoanalysis, more specifically contemporary attachment theory and intersubjectivity theory, I illustrate how both these mothers and I – as emotional, social and political subjects – co-construct maternal subjectivity. Based on the findings, recommendations for parent-infant interventions are discussed. Arguing that a purely psychoanalytic reading of investment perpetuates notions of individual blame and pathology, I advocate for a psychosocial reading that does not neglect failing social systems but rather pursues an open and reflective, yet critical, mindfulness when listening to talk.
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The predictive ability of the yield spread in timing the stock exchange: a South African case

- Cook, Jenna

  • Authors: Cook, Jenna
  • Date: 2020
  • Subjects: Stocks -- Mathematical models , Probits , Johannesburg Stock Exchange
  • Language: English
  • Type: Thesis , Masters , MCom
  • Identifier: http://hdl.handle.net/10962/147025 , vital:38586
  • Description: The use of the yield curve in forecasting economic recessions is well established in the literature. A new avenue of use for the yield curve has emerged in the form of using it to forecast bull and bear stock markets. This has the potential to change how investors manage portfolios. A dynamic market-timing strategy would allow investors to shift out of or in to stock markets based on the probability of bear stock market in the future. The relationship between the yield curve and the stock market is tested using an adapted probit model. This has proven positive with encouraging results for the US, India and Spain. This is tested for South Africa using the adapted probit model and the SA yield spread. Bear stock markets are identified on the JSE and forms part of the probit modelling process. Bear markets are identified using a six- and four-month criteria. As South Africa is a small, open and developing economy, the probit is also modelled using the US yield spread. The three probit models do not appear to track bear markets well. This is substantiated through the Henriksson-Merton parametric model test which tests for market timing ability. The results for the SA yield spread using both bear market criteria do not show market timing ability, however, the SA and US yield spread model does show potential market timing ability.
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The primacy of illicit financial flows (IFFs) in developing countries: a comparative study analysis of South Africa and China

- Mahlaba, Asande Cikizwa

  • Authors: Mahlaba, Asande Cikizwa
  • Date: 2020
  • Subjects: Money -- Developing countries , Transfer pricing -- South Africa , Developing countries -- Economic conditions , Tax evasion -- China , Tax evasion -- South Africa
  • Language: English
  • Type: text , Thesis , Masters , MCom
  • Identifier: http://hdl.handle.net/10962/147435 , vital:38636
  • Description: The main objective of this study was to question and investigate the primacy of illicit financial flows (IFFs) in developing countries, specifically focused on two countries namely China and South Africa. Africa is estimated to have lost approximately $1 trillion to IFFs over the last 50 years, which exceeds the financial assistance that these nations needed over the same period. For years. Africa has been the feeding ground for exploitation and resource plunder, and the narrative has always been Africa is underdeveloped because of this crime. Although this statement holds true in most African countries, what this paper seeks to do is to question whether capital flight, IFFs and more specifically tax evasion and tax haven activity are the reason for the deterioration of African economies or are IFFs perpetuated by economies with unsustainable growth paths. IFFs are an important factor when it comes to obstacles of economic growth. But are they the cause or effect? A very strong case can be made that they are the latter however, it is beyond the scope of this article to resolve this question. Its purpose is merely to assert that the question is a valid one and that presuming the answer could divert attention from the real question of economic development. This study contextualized the way in which IFFs are currently viewed in the world economic system according to the two approaches to development finance, and discussed modern monetary theory as an extension off these theories. Due to the nature of the study, the methodology employed is a case study approach between China and South Africa by means of extensive numerical and document analysis. Upon conducting this analysis on the primacy of illicit financial flows in developing countries there was difficulty in measuring IFFs. The reason for this is because IFFs have a range of estimates so it was very difficult to produce precise and accurate results. The key findings of this paper were that there seems to be some kind of parallel between developing countries with large volumes of illicit financial outflows, and a dependency these countries have on external debt. This means it seems that weak economies, that are highly dependent on external debt and have large amounts of this debt, seem to have the largest volumes of illicit financial outflows. Weak regulation, high levels of debt and liberalised trade markets seem to be contributing factors to the degree to which companies evade taxes and partake in tax haven activity in these regions. Another key finding was that in 2012, despite China being ranked number one in the the countries which have the largest amounts of outflows on average, it still managed to achieve large amounts growth in the last 20 years. Indicating that there is some form of indication that IFFs could be viewed as symptomatic of weak financial systems and weak economies, instead of IFFs being the core of the problem.
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The privacy paradox applies to IoT devices too: a Saudi Arabian study

- Aleisa, Noura, Renaud, Karen, Bongiovanni, Ivano

  • Authors: Aleisa, Noura , Renaud, Karen , Bongiovanni, Ivano
  • Date: 2020
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/150252 , vital:38953 , https://doi.org/10.1016/j.cose.2020.101897
  • Description: The “privacy paradox” is the term used to describe the disconnect between self-reported privacy value attributions and actions actually taken to protect and preserve personal privacy. This phenomenon has been investigated in a number of domains and we extend the body of research with an investigation in the IoT domain. We presented participants with evidence of a specific IoT device’s (smart plug) privacy violations and then measured changes in privacy concerns and trust, as well as uptake of a range of behavioural responses. Our Saudi Arabian participants, despite expressing high levels of privacy concerns, generally chose not to respond to this evidence with preventative action.
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The Privacy Paradox applies to IoT devices too: a Saudi Arabian study

- Aleisa, Noura, Renaud, Karen, Bongiovanni, Ivano

  • Authors: Aleisa, Noura , Renaud, Karen , Bongiovanni, Ivano
  • Date: 2020
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/158350 , vital:40176 , https://doi.org/10.1016/j.cose.2020.101897
  • Description: The “privacy paradox” is the term used to describe the disconnect between self-reported privacy value attributions and actions actually taken to protect and preserve personal privacy. This phenomenon has been investigated in a number of domains and we extend the body of research with an investigation in the IoT domain. We presented participants with evidence of a specific IoT device’s (smart plug) privacy violations and then measured changes in privacy concerns and trust, as well as uptake of a range of behavioural responses.
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The relationship between childhood trauma and schizophrenia in the Genomics of Schizophrenia in the Xhosa people (SAX) study in South Africa

- Mall, Sumaya, Platt, Jonathan M, Temmingh, Henk, Musenge, Eustasius, Campbell, Megan M, Susser, Ezra, Stein, Dan J

  • Authors: Mall, Sumaya , Platt, Jonathan M , Temmingh, Henk , Musenge, Eustasius , Campbell, Megan M , Susser, Ezra , Stein, Dan J
  • Date: 2020
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/302567 , vital:58208 , xlink:href="https://doi.org/10.1017/S0033291719001703"
  • Description: Background. Evidence from high-income countries suggests that childhood trauma is associated with schizophrenia. Studies of childhood trauma and schizophrenia in low and middle income (LMIC) countries are limited. This study examined the prevalence of childhood traumatic experiences among cases and controls and the relationship between specific and cumulative childhood traumatic experiences and schizophrenia in a sample in South Africa. Methods. Data were from the Genomics of Schizophrenia in the South African Xhosa people study. Cases with schizophrenia and matched controls were recruited from provincial hospitals and clinics in the Western and Eastern Cape regions in South Africa. Childhood traumatic experiences were measured using the Childhood Trauma Questionnaire (CTQ). Adjusted logistic regression models estimated associations between individual and cumulative childhood traumatic experiences and schizophrenia. Results. Traumatic experiences were more prevalent among cases than controls. The odds of schizophrenia were 2.44 times higher among those who experienced any trauma than those who reported no traumatic experiences (95% CI 1.77–3.37). The odds of schizophrenia were elevated among those who experienced physical/emotional abuse (OR 1.59, CI 1.28–1.97), neglect (OR 1.39, CI 1.16–1.68), and sexual abuse (OR 1.22, CI 1.03–1.45) compared to those who did not. Cumulative physical/emotional abuse and neglect experiences increased the odds of schizophrenia as a dose–response relationship. Conclusion. Childhood trauma is common in this population. Among many other benefits, interventions to prevent childhood trauma may contribute to a decreasing occurrence of schizophrenia.
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The relevance of industrial/organisational psychology research in “post” colonial/apartheid South Africa : exploring the views of academics

- Christison, Michael Alan

  • Authors: Christison, Michael Alan
  • Date: 2020
  • Subjects: Psychology, Industrial -- Research -- South Africa
  • Language: English
  • Type: text , Thesis , Masters , MA
  • Identifier: http://hdl.handle.net/10962/140331 , vital:37880
  • Description: This dissertation explored the views of academics who teach and research in the area of Industrial/Organisational Psychology in South Africa about the utility of the field in engaging with the post-1994 South African workplace, thereby remaining relevant. When it emerged as a field of study and practice, Industrial/Organisational Psychology research’s aim was to inform workplace practice and contribute to the betterment of society. It appears as if today this research is deemed irrelevant to the workplace and society, with many practitioners relying on their own knowledge and irrelevant repetitive one size-fit-all Euro-American developed theoretical framework and research evidence to solve the challenges of the post-1994 South African workplace, and to serve its society. The latter propelled the researcher to ask broadly the question of relevancy of the discipline in meeting the demands of the post-1994 South African workplace. Face-to-face, semi-structured interviews were employed to collect data on 8 senior and younger generations of academics in 3 different universities. The collected data was analysed using Braun and Clarke’s 6 steps of thematic analysis. The data and study as a whole was approached with a ‘post’-colonial lens and a Contexualist paradigm in order to contextualise in the present time the past nuances that arose in our country during the colonial and apartheid eras. Themes discussed seemed to indicate a lack of research focus by academics and their students due to limited time and stringent bureaucratic publication structures present both within their universities and outside. When it came to the discipline as seen through the lens of the data and what this suggested in terms of speaking to post-1994 workplace organisational psychological problems, the study found that the findings arising out of the research in I/O psychology appear to be of little relevance to whom they are currently aimed, leading to the idea of these studies acting as a change agent in the workplace and society to fall to the wayside.
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The Rise of the Executive Dean and the Slide into Managerialism

- McKenna, Sioux

  • Authors: McKenna, Sioux
  • Date: 2020
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/187139 , vital:44573 , xlink:href="http://dx.doi.org/10.17159/2221-4070/2020/v9i0a6"
  • Description: Universities have long been characterised by hierarchical and paternalistic management structures and institutional cultures. Change is therefore to be welcomed but, in contexts where social change is urgently needed, it is possible to mistake a change in any direction as being worthwhile. Around the world, recent shifts in university leadership and management have been towards managerialist approaches that work against a shared responsibility for the academic project. Accusations of managerialism often refer to a general sense that institutions are becoming bureaucratic, or that it is the logic of the market that drives decision-making. But beyond vague complaints, these accusations fail to identify the exact processes whereby managerialism takes hold of the institution. This article hones in on one specific example of institutional change in order to argue that it is implicated in the move towards managerialism: most universities in South Africa have changed from having elected deans, selected by faculty, to executive deans, appointed by selection committee. Crudely distinguished, it can be said that elected deans represent the interests of their faculty up into various institutional structures whereas executive deans are tasked with implementing the decisions of top management down into faculty. This paper tracks the differences between the two forms of deanship through reflections on discussions about such a change at one South African institution, Rhodes University. It analyses the literature to argue that we do not have to choose between patriarchal management and compliance-based managerialism. Instead, we can choose shared responsibility for the academic project.
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The role of assessment in preparing academic developers for professional practice

- Quinn, Lynn

  • Authors: Quinn, Lynn
  • Date: 2020
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/445865 , vital:74438 , ISBN 9781003028215 , https://www.taylorfrancis.com/chapters/edit/10.4324/9781003028215-15/role-assessment-preparing-academic-developers-professional-practice-lynn-quinn
  • Description: Academic developers are tasked with supporting institutions in times of change. Essential for preparing academic developers for professional practice is enabling them to engage with and integrate existing knowledge with new knowledge, and apply their understandings to new contexts. Focusing on the summative assessment processes and products of a course specifically for academic developers, this chapter shows how cumulative knowledge-building can be achieved in both course design and pedagogy. Drawing on LCT concepts of ‘semantic gravity’ and ‘semantic density’, two high-achieving portfolios were analysed. The analysis indicates that movements between knowledge that is relatively abstract, decontextualized and complex to knowledge that is relatively concrete, context-dependent and simpler, represents a key characteristic of cumulative learning for professional practice courses. The chapter demonstrates how LCT can reveal the tacit ‘rules’ for success in the course, as well as how pedagogic strategies can be designed to achieve the desired outcome.
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The role of expansive learning in the potential development of rural youth as value creators: a case study of youth farming activity in the Amahlathi Local Municipality in the Eastern Cape

- Matiwane, Lwazi Mandilive

  • Authors: Matiwane, Lwazi Mandilive
  • Date: 2020
  • Subjects: Environmental education -- South Africa -- Lenye , Rural development -- South Africa -- Lenye , Unemployed youth -- South Africa -- Lenye , Social learning -- South Africa -- Lenye , Educational change -- South Africa -- Lenye , Youth in development -- South Africa -- Lenye , Sustainable development -- South Africa -- Lenye , Agriculture -- Study and teaching -- Activity programs , Active learning -- South Africa -- Lenye , Cultural Historical Activity Theory
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: http://hdl.handle.net/10962/146034 , vital:38489
  • Description: Environmental sustainability and agriculture are key development and transformational concerns in South Africa while rural development and youth unemployment are key national issues pertinent in the Eastern Cape which ranks in the top three provinces for both concerns. As a formative interventionist researcher, working in a singular case study with youth in Lenye village located in the Eastern Cape Province of South Africa, I sought to investigate the following: Can, and if so, how can expansive learning facilitated by a change laboratory intervention contribute to the development of youth as potential value creators for rural development? This was investigated through the following sub questions: 1) What value is created at each point of the expansive learning process of the change laboratory process and for who? 2) What value can still be created at each point of the expansive learning process of the change laboratory? 3) How is that value created via an expansive learning process? I collected data as I participated as a youth member through: extended contextual profiling via a focus group interview, individual interviews, note taking and document analysis. Furthermore, I attended village meetings, youth meetings and emergent youth development/youth in agriculture/agriculture opportunities. Additionally, change laboratory workshops were conducted and I used audio recordings and notes to capture data. The data collected was then analysed through second generation Cultural Historical Activity Theory using the concepts of immediate, potential, applied, realised and reframing value. In conclusion, the expansive learning process may contribute to the development of rural youth as value creators for sustainable development through youth development, agriculture and community development. All forms of value were created along the expansive learning process for the formative interventionist researcher, the Lenye youth and the greater Lenye youth community. All forms of value may still be created for the Lenye youth, the formative interventionist researcher and the greater Lenye youth community.
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The role of flexible working in achieving a work-life balance: a case study of information technology consultants of Kestrel Business Solutions – London, United Kingdom

- Nyamujara, Tinashe

  • Authors: Nyamujara, Tinashe
  • Date: 2020
  • Subjects: Kestrel Business Solutions , Flexible work arrangement -- Case studies , Work-life balance , Flexitime , Telecommunting , Telecommunting -- Case studies
  • Language: English
  • Type: text , Thesis , Masters , MBA
  • Identifier: http://hdl.handle.net/10962/167245 , vital:41459
  • Description: This research was a Case Study on the role of Flexible Working in achieving a Work – Life Balance, based on the Information Technology Consultants of Kestrel Business Solutions – a company based in London, the United Kingdom. The study set out to determine what aspects of flexible working can reduce work - related stress; home - related stress; improve personal wellbeing; identify the pitfalls of flexible working, and to recommend mitigating actions. The literature review identified five different, but complimentary theories that included: The Spill over Theory; Balanced Theory; Resource Based Theory; Compensation Theory and the Wellness Theory to unpack and explore the concept of Work - Life Balance. The study followed a predominantly qualitative methodology approach and used thematic analysis to identify key ideas from the data. Interviews and questionnaires were used to obtain data from the respondents, in addition to being a data triangulation exercise. From a population of 10 subjects - purposeful sampling was used to select a sample of 10 respondents - made up of 3 males and 7 females. All respondents were employees of Kestrel Business Solutions. 6 respondents were interviewed and given questionnaires to fill out. 6 face to face interviews were conducted, and 6 questionnaires completed until saturation was achieved - indicating a survey response rate of 100%. The results from the data collection generally showed how aspects of flexible working like telecommuting, flexitime and homeworking ultimately helped the employees to achieve a Work-Life Balance - by primarily influencing how they balanced their work, home, and personal commitments. Importantly, the study also identified pitfalls of flexible working; like employees feeling isolated and the pressure to perform. Potential mitigating efforts identified in the study included, providing more company support and education for flexible working initiatives. The study concluded by acknowledging the limitations of the study, which included time constraints and the small population, and sample size of the study. In its conclusion, the study identified recommendations for future studies like: increasing the population and sample size, and devoting more time to the study, for more generalized and conclusive findings.
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The Role of HSP70/HSP90 Organizing Protein (Hop) in the Heat Shock Factor 1 (HSF1)-mediated Stress Response

- Chakraborty, Abantika

  • Authors: Chakraborty, Abantika
  • Date: 2020
  • Subjects: Uncatalogued
  • Language: English
  • Type: Doctoral theses , text
  • Identifier: http://hdl.handle.net/10962/163204 , vital:41018 , doi:10.21504/10962/163204
  • Description: Molecular chaperones regulate cellular proteostasis. They control protein conformation and prevent misfolding and aggregation under both normal and stressful environments, ultimately resulting in cell survival. The project aimed to understand the role of the HSP70 – HSP90 Organizing Protein (Hop/STIP1) in the survival of stressed cells and the function of the stress-responsive transcription factor, Heat Shock Factor 1 (HSF1). HSF1 protein levels were significantly reduced in Hop-depleted HEK293T cells compared to controls by ELISA, western blot, and mass spectrometry. HSF1 transcriptional activity at the HSP70 promoter, and binding of a biotinylated HSE oligonucleotide under basal conditions were significantly reduced, consistent with the reduced levels of HSF1. In response to heat shock, HSF1 levels in Hop-depleted cells increased to that of controls, but there was still significantly lowerHSF1 transcriptional activity and HSE binding. Hop-depleted HEK293T cells were more sensitive than controls to the HSF1 inhibitor KRIBB11 and showed reduced short-term and long-term proliferation. Unlike the HSP90 inhibitor 17-DMAG, which had no effect, the HSP70 inhibitor JG98, further decreased the levels of HSF1 in Hop-depleted cells, suggesting a role for HSP70 in the Hop-mediated effects. There was punctate nuclear staining for HSF1 in Hop-depleted cells under both basal and heat shock conditions, as well as reduced nuclear localization and increased cytoplasmic accumulation of HSF1 in response to heat shock. Hop and HSF1 colocalized in cells, and HSF1 could be isolated in complex with Hop and HSP70. Loss of Hop reduced HSF1 in HSP70complexes but did not affect HSF1 abundance in HSP90 complexes. Hop-depleted cells showed reduced short-term and long-term survival compared to controls, an effect that was potentiated by the JG98 HSP70 inhibitor. Taken together, these data suggest that Hop regulation of HSF1activity is via a mechanism involving reductions in HSP70 interaction, as well as reduced nuclear localization, and DNA binding, and is consistent with reduced cellular fitness under basal and stress conditions. , Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2020
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The role of microhabitats within mangroves: an invertebrate and fish larval perspective

- Vorsatz, Lyle Dennis

  • Authors: Vorsatz, Lyle Dennis
  • Date: 2020
  • Subjects: Mangrove ecology -- South Africa , Mangrove forests -- South Africa , Niche (Ecology) , Rhizophora mucronata , Acanthaceae , Rhizophoraceae , Fishes -- Larvae -- South Africa , Aquatic ecology -- South Africa
  • Language: English
  • Type: text , Thesis , Doctoral , PhD
  • Identifier: http://hdl.handle.net/10962/167644 , vital:41499
  • Description: Microhabitats provided through structural complexity are central for the diversity, productivity, connectivity and niche differentiation within and among ecosystems. Mangrove forests afford juvenile fish and invertebrates with nursery and recruitment habitats, facilitated by the fine scale configuration of their specialised root systems. Although the importance of mangroves for resident and transient juveniles is well recognised, the roles that mangrove microhabitats play for larvae is not yet comprehensively understood. This study aimed to determine how microhabitats with varying degrees of complexity influence the composition, abundance and distribution of larval communities that inhabit mangrove forests and the physiological responses of larvae to acute temperature variations in relation to ontogenetic stage and microenvironment exposure. Two relatively pristine study sites were selected to represent a warm temperate and subtropical mangrove system in the Eastern Cape and KwaZulu-Natal on the east coast of South Africa, respectively. The differences in complexity among the root systems of Rhizophora mucronata, Avicennia marina and Bruguiera gymnorhiza were assessed using 3D scanning and the computed 3D models were then analysed using four complexity metrics. Results indicated that A. marina is the most complex in terms of surface-volume ratio, R. mucronata has the most interstitial space among its roots and B. gymnorhiza and R. mucronata differ in their fractal dimensions. Larvae collected in each microhabitat at each site using light traps showed that, despite temperature and salinity homogeneity across microenvironments, spatio-temporal differences occurred in both fish and invertebrate assemblages. This trend suggests that microhabitat structural complexity exerts an influence on larval community composition by acting as a microscape of available habitat, which ensures ecological linkages within and among the mangrove forest and adjacent ecosystems. In addition, the oxygen consumption rates of mangrove-associated brachyuran larvae varied according to mangrove microhabitat, whereby larvae collected at less complex environments had the highest metabolic rates at increased temperatures. Moreover, ontogenetic shifts in physiology were prevalent as older brachyuran larvae were more eurythermal than earlier stages, suggesting that thermally stressful events will have a greater impact on recently spawned larvae. Overall, the interstitial spaces within individual root systems are the most important complexity measure, as utilisation of these mangrove microhabitats is scale-dependent, and larvae will most likely occupy spaces inaccessible to large predators. Likewise, microscale variation in the environmental conditions and ontogenetic stage of brachyuran larvae within the mangrove microscape, can amplify the physiological responses to rapid temperature variations. Results suggest that early stage larvae are the most vulnerable to mass-mortality, and if thermally stressful events increase in frequency, duration and magnitude, the larval supply for the successful recruitment into adult populations could be under threat. Through linking how mangrove microhabitat complexity influences larvae in terms of community metrics and physiology, this study paves the way for further advancement of our understanding of how microscale processes emerge into meso- and macroscale patterns and influence the stability and functioning of highly productive ecosystems.
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The role of northwest striking structures in controlling highgrade ore shoots at the Syama Gold Mine, Mali, West Africa

- Soro, Ali

  • Authors: Soro, Ali
  • Date: 2020
  • Subjects: Syama Gold Mine , Gold ores -- Geology -- Mali , Veins (Geology) -- Mali
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: http://hdl.handle.net/10962/145209 , vital:38418
  • Description: This study intended to investigate the relationship between the NW striking structures and the high-grade ore shoots at the Syama gold mine in Mali, West Africa. All structural data collected since 1987 from drill core have been integrated to allow the interpretation and modelling of these NW-SE structures. The structures collected were grouped into three main groups; foliations/shears/faults, veins and joints/contacts/fractures. Micromine software was used to plot the structures, printed out on A3 paper and interpreted manually using tracing paper. Analysis and interpretation of stereographic plots has shown that the majority of the high-grade zones are generally located at the intersection of the NNE structures and the NW structures. The observed cross-cutting relationship between the NNE and the NW structures suggests two different generation of faults. It is suggested that the NW structures were active during the D4 deformation event (Standing, 2007) and have played a role in reactivating earlier (D3) NNE structures, allowing greater fluid flow and enhancing the gold grade. These zones are mainly defined by brecciation and stockwork veining. The E-W structures are believed to be the latest and are attributed to the D5 event. Although gold mineralisation is grossly controlled by the NNE structures, the NW structures need to be considered as major gold enrichment upgrading factors at Syama. It is therefore strongly recommended that ongoing exploration at Syama specifically target the intersection of the NW and NNE structures as favourable zones for high-grade mineralisation.
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