Analysis of saprolite-hosted Rutile-Graphite deposit: a case study of Malingunde saprolite-hosted Rutile-Graphite project in Central Malawi
- Authors: Zabula, Ansel Aliko
- Date: 2024-10-11
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/464970 , vital:76562
- Description: The Malingunde graphite project, owned by Sovereign Metals Ltd (SML), has revealed significant potential for rutile and high-grade graphite in saprolite. This study addresses the complexity of mineral assemblages in the Malingunde area, emphasizing the coexistence of graphite and rutile. SML's exploration activities, including extensive drilling and soil sampling, have uncovered variations in associated minerals, such as muscovite, kyanite, garnets, and ilmenite. Rutile, initially discovered incidentally, has prompted further investigation, impacting the financial model of the project. This research aims to analyse the Malingunde deposit, focusing on understanding its mineralogy, formation, and potential for elements like vanadium. Geological surveys reveal the distribution of graphite in the Precambrian to lower Palaeozoic age basement complex, hosted in saprolite resulting from tropical weathering of graphitic gneisses. Exploration techniques, including remote sensing, and geophysics, are crucial in targeting graphite and rutile deposits. Ground electromagnetic surveys, airborne electromagnetic data, and GIS applications aid in identifying and quantifying mineralised areas. Geochemical analysis and metallurgical tests further contribute to understanding the ore body and processing methods. Results indicate an inverse relationship between graphite and rutile concentrations, influencing the economic viability of different regions within the project area. Correlation matrices and regression analyses reveal distinct geological conditions influencing the association of vanadium and graphite in Lifidzi and Malingunde. The study concludes with exploration potential outside the Malingunde project, highlighting regional prospects and potential byproducts like vanadium pentoxide. The ongoing metallurgical tests and pilot plant design signify the project's evolution toward production. Additionally, neighbouring licenses show potential, emphasizing the need for comprehensive research to define and quantify resources in the region. This research provides valuable insights for the mining industry, informing strategies for exploration, resource assessment, and potential byproduct utilization in similar geological settings. , Thesis (MSc) -- Faculty of Science, Geology, 2024
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- Date Issued: 2024-10-11
Regulation of sexual harassment at the workplace in Namibia
- Authors: Kayama, Ohms Moven
- Date: 2024-04
- Subjects: Workplace Sexual Harassments , Labour Law , Sex discrimination in employment
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/64695 , vital:73862
- Description: Many Namibians are driven by the need for income and economic sustainability, pushing them to seek employment and make a living for themselves. However, what appears to be just participating in economic activities can be a risky and traumatic experience for some workers. For years, many have had to balance their job responsibilities while enduring discrimination, bullying, violence, and harassment in the workplace. Sexual harassment has been a major problem in the workplace, with women being the primary targets and victims. Studies have shown that gender inequality is one of the leading causes of sexual harassment in the workplace. Within the above context, this treatise aimed at answering to what extent Namibia's legislative framework regulates sexual harassment in the workplace. Namibia's legal framework was tested against the global instruments to answer the question. It was found that Namibia's legislative framework does regulate sexual harassment. However, some several gaps were identified. First, there is ambiguity and scope of legal definitions as the current definition of sexual harassment in section 5(7)(b) of the LA is not comprehensive enough. It fails to explicitly include both "quid pro quo" and "hostile environment" sexual harassment. This ambiguity could hinder victims' ability to seek justice and the legal system to prosecute offenders effectively. Second, there is an inefficacy of reporting structures, which is a significant barrier. Victims often face unclear and inefficient procedures, contributing to underreporting and unresolved cases. Developing straightforward, accessible, and efficient reporting mechanisms is crucial. Third, the absence of comprehensive workplace policies against sexual harassment exacerbates the issue. While developing a Code of Good Practice is positive, its implementation status and effectiveness remain uncertain. Another gap relates to the protection for whistleblowers and victims, as a lack of adequate legal protection for whistleblowers and witnesses discourages reporting. Strengthening legal protections can empower more individuals to come forward. The gaps identified were developed while comparing Namibia’s legislative framework to South Africa to determine whether lessons can be learned as it was found that lessons could be learned. Further recommendations is that Namibia should establish a single OHS legislation to address workplace sexual harassment by standardising policies and procedures across various industries, improving reporting standards to measure the occurrence of sexual harassment incidents, and developing a Code of Good Practice regulating sexual harassment. Lastly, it is acknowledged that Namibia's ratification of the Violence and Harassment Convention, 2019 (No. 190) is a welcomed development and shows a positive commitment in its intention to curb sexual violence in the workplace. , Thesis (LLM) -- Faculty of Law, 2024
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- Date Issued: 2024-04
Kant and the experience of skepticism: rranscendental arguments, skepticism, and a version of the problem of the justification of foundational assumptions
- Authors: Grecia, Hadley
- Date: 2023-10-13
- Subjects: Kant, Immanuel, 1724-1804 , Transcendental argument , Deductive reasoning , Skepticism , Foundationalism (Theory of knowledge)
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/425078 , vital:72207
- Description: Immanuel Kant is a key thinker in the History of Western Philosophy whose ideas continue to fascinate contemporary English-speaking academic philosophers. One such idea is Kant's conception of transcendental arguments. Although these arguments do not originate in Kant's philosophy, Kant's conception of them occupies a special place in the English-speaking literature on the topic. A growing trend in this literature is to claim that Kant's transcendental arguments are unique because they aim to achieve an anti-skeptical end through deductive means. I call the basic assumption behind readings of transcendental arguments like these the deductive/anti-skeptical assumption. This assumption claims that deduction is the best means to achieve an anti-skeptical end. In this thesis, I argue that accepting this assumption is one way to misinterpret transcendental arguments because—even though it seems compelling at first blush—it must be false. The resultant twist is that transcendental arguments cannot be deductive, which, in turn, means that understanding that Kant's transcendental arguments are not deductive in nature is itself no small detail for understanding the version of Kant's 'not-deductive' solution to skepticism developed here. , Thesis (MA) -- Faculty of Humanities, Philosophy, 2023
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- Date Issued: 2023-10-13
Isolation, characterization and functionalization of cellulose fibres derived from the waste pineapple leaf fibres by hydrolysis to produce cellulose acetate
- Authors: Seyisi, Thulethu
- Date: 2023-04
- Subjects: Nonwoven fabrics -- Technological innovations , Pineapple fiber -- South Africa , Fibrous composites
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/61248 , vital:69844
- Description: This thesis forms part of the Nelson Mandela University biomass and nanotechnology project, which aims at using agricultural waste for many applications, including biomedical applications, water treatment, and agricultural films. Pineapple leaf fiber (PALF) is one of the natural fibers with the highest cellulose content (about 80%), and they produce about 2.5–3.3% of the weight of green leaves. However, the other parts of the pineapple fruit, such as the leaves and crown, are still treated as waste due to a lack of understanding of the benefits and risks of these parts of the pineapple fruit. The transformation of PALF as a renewable and abundantly available natural residue into cellulose fibers (CFs) will reduce the waste accumulated in the atmosphere, and it will add value to the cultivation of pineapple. In the biomedical industry, CF is very promising in terms of drug delivery. Cellulose acetate is a remarkable biomaterial extensively used in biomedical applications due to its properties such as being non-toxic, non-irritant, biodegradable, heat resistant, and less hygroscopic. In this research, the isolation, functionalization, and characterization of cellulose from PALFs were conducted. The PALFs were dried and ground into small particles before being alkali treated with sodium hydroxide to remove the non-cellulosic components. Moreover, the remaining lignin in the residue was removed using sodium chlorite and acetic acid; this process is known as the bleaching process. The bleaching process resulted in white CFs, which was an indication of the successful removal of the non-cellulosic material. The obtained CFs were further functionalized using acetic acid, acetic anhydride, and sulfuric acid, and this reaction is known as the acetylation reaction. Subsequently, both treated, untreated, and functionalized CFs were characterised using the following instruments: FTIR, SEM, SPM, TGA, XRD, and XPS. In the FTIR data of raw PALFs, the following functional groups were more pronounced: C-O, C=C-O, and C=O, whereas peak C-O-C disappeared and peak CH2, C-O, were less pronounced. These FTIR results confirmed the successful removal of non-cellulosic components. The SEM and SPM images visually suggested the partial removal of hemicellulose and lignin from the raw PALFs after the chemical treatment, which are the cementing materials around the fiber bundles. The TGA studies revealed good thermal stability for the isolated CFs from PALFs. The XRD diffractograms of the PALFs showed a cellulose I crystal pattern where the peaks were located at angular positions (2θ) of around 18°, 26°, and 41°. Lastly, after the functionalization of CFs, the cellulose structure remained intact (not damaged); instead, the newly ix introduced functional groups (the acetyl group) were attached at the ends of the cellulose structure. These results are therefore confirmation of the successful removal of non-cellulose material from the PALFs after the chemical treatment. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Science and Management, 2023
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- Date Issued: 2023-04
Growth performance of three F1 Hybrid tomato (Solanum lycopersicum L.) Cultivars grown in Peat moss and Sawdust
- Authors: Mondile, Landile
- Date: 2022-12
- Subjects: Agricultural development projects -- South Africa -- Eastern Cape , Tomatoes – Irrigation – Management
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/59853 , vital:62450
- Description: The tomato is one of the most important and commonly grown vegetable crops cultivated by subsistence as well as commercial farmers in South Africa. Even though hydroponic tomato production has gained popularity, tomato production in South Africa is mostly practised open field. This is because most South African households in rural communities depend on agriculture for their livelihoods. Tomatoes are one of the “cash crops” − meaning cash in hand for many farmers. As a staple food for many rural communities and households, tomatoes are prepared as relish daily. Including tomatoes in the human diet provides the benefit of various important nutrients, such as Vitamin C, amongst others. The main aim of this study was to evaluate the growth performance − by assessing the number of leaves, stem diameter, plant height and number of flowers per plant − in three Solanum lycopersicum L. cultivars, namely: F1 hybrids Star9006, TF4009 and TF4011, grown in peat moss and sawdust respectively. In addition, the research aimed at investigating how peat moss and sawdust, as growing media, influenced the growth performance of the tomato cultivars under study. The study was conducted at the Döhne Agricultural Development Institute near Stutterheim in the Eastern Cape. The experiment was laid out in a split randomized complete block design (RCBD) in which the growing media, namely: sawdust and peat moss, were assigned as main plots and the tomato cultivars to sub-plots, with three replicates. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2022
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- Date Issued: 2022-12
In a novel landscape, in the Eastern Cape, South Africa, what are the key vegetation resources that support livestock production?
- Authors: Liversage-Quinlan, William Peter
- Date: 2021-10
- Subjects: Mzimvubu River Watershed (South Africa) , Livestock productivity South Africa Mzimvubu River Watershed , Range ecology South Africa Mzimvubu River Watershed , Land degradation South Africa Mzimvubu River Watershed , Vegetation dynamics South Africa Mzimvubu River Watershed , Novel landscapes
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/190053 , vital:44959
- Description: The Tsitsa River is the largest remaining river that is without a dam in South Africa, and so the government has pledged to install two major dams for irrigation and hydroelectricity, under the Mzimvubu Water Project. These dams are intended to supply water and electricity to surrounding communities as well as the large neighbouring urban areas of Mthatha and Tsolo. However, large areas of the Tsitsa Catchment (~494 000 ha) are degraded, posing the possibility that if these dams were to be created, they would inevitably fill with sediment and silt within a few decades. To address these issues, the Tsitsa Project was established in 2014 to co-ordinate actions by government, developers and local communities in order to restore the landscape condition and prevent soil erosion, as well as to improve the livelihoods of the people who live there (Fabricius, Biggs, & Powell, 2016). Research into the landscape condition as well and the environmental interactions with local communities are therefore highly necessary in order to guide restoration practices to their best effect. The economic necessity for livestock production in the catchment indicates its urgent need for a better understanding of its current effects on the catchment landscape and vegetation. The overall goal of this study is to contribute to the knowledge needed to manage the area in a sustainable way. This paper will therefore examine the key vegetation resources that support livestock production in an area of the Tsitsa River Catchment, by describing the various types that exist, and by determining their relative production levels of usable livestock forage. , Thesis (MSc) -- Faculty of Science, Institute for Water Research, 2021
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- Date Issued: 2021-10
The relationship between work engagement and psychological meaningfulness
- Authors: Faro, Gillian Rochelle
- Date: 2021-04
- Subjects: Employee motivation , Organizational behavior , Psychology, Industrial
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/51360 , vital:43267
- Description: Work engagement is a positive psychological construct that according to research predicts positive organisational outcomes. The overarching objective of this study is to investigate the relationship between work engagement and psychological meaningfulness and to determine whether work engagement can be predicted by means of psychological meaningfulness. This study took on the form of a cross-sectional design, using a questionnaire to measure work engagement and psychological meaningfulness. The Utrecht Work Engagement Scale (UWES) and the Psychological Meaningfulness Scale (PMS) are instruments that have been widely used in research and were both found to be reliable and valid. The questionnaire was administered in the form of a paper and pencil self-administered questionnaire. This study was conducted at a mining/manufacturing company based in the Eastern Cape for employees across all occupational levels (N=202) and the sample was selected using non-probability convenience sampling as participation in the study was voluntary. Descriptive statistic methods were used to analyse the data, as well as an analysis of variance (ANOVA). Correlation data analysis methods were utilised to measure the relationship between variables. The study found a strong positive relationship between work engagement and psychological meaningfulness and that a large portion of the respondents scored moderate to high on work engagement and high on psychological meaningfulness. The study also found that there is a positive relationship between work engagement and age in that older employees are more engaged than younger employees. Male respondents were found to have higher levels of psychological meaningfulness. Lastly, the study revealed that psychological meaningfulness predicts work engagement. Research and organisational recommendations based on the research are discussed. , Thesis (MA) -- Faculty of Business and Economic Sciences, Labour Relations and Human Resources, 2021
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- Date Issued: 2021-04
A study of the manifestations of the death instinct as evidenced in the case of a pathological organization
- Authors: De Villiers, Jeanine
- Date: 1991-04
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191691 , vital:45148
- Description: The case study method was used to investigate the manifestations of the death instinct as evidenced in a pathological organization. Work of Kleinian analysts in this area was employed as a basis for interrogating the material that emerged in a five month psychotherapy with a borderline disordered patient. It was demonstrated how the pathological organization was employed as a means of evading paranoid- schizoid fears and depressive position anxieties. Two ways in which defences were assembled into the pathological organization could be traced, both leading to resistance in the therapy. The one set of defences would entail a complete withdrawal from contact, where the patient would hold herself aloof from experience through a solitary invulnerability. The other set of defences involved an active attack on the vulnerable, libidinal self. Identified with the bad, anti-libidinal self, the patient would attempt to annihilate the libidinal self in various ways. Fragmentation of her thoughts and memories, self-destructive behaviour and phantasized and actual attacks on the objects in her world which called forth her neediness were all evidenced. In conclusion, the issue of whether a more active interpretation of the manifestations of the death instinct or a less interpretative, more holding therapeutic stance should be adopted in the therapy with patients exhibiting a pathological organization was raised. , Thesis (MA) -- Faculty of Humanities, Psychology, 1991
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- Date Issued: 1991-04