- Title
- Optical properties and electronic structures of axially-ligated group 9 porphyrins
- Creator
- Wang, Bei-Bei, Zuo, Huiping, Mack, John, Majumdar, Poulomi, Nyokong, Tebello, Chan, Kin Shing, Shen, Zhen
- Type
- Article
- Identifier
- vital:7295
- Identifier
- http://hdl.handle.net/10962/d1020358
- Description
- A series of group 9 metal tetra-(p-tolyl)-porphyrin (M(ttp), M = Co(II), Rh(III), Ir(III)) complexes with axial phenyl substituents have been synthesized and characterized. An aryl bromide cleavage reaction of transition metal complexes was used to prepare the complexes from Co(ttp), Rh(ttp)Cl and Ir(ttp)COCl, respectively. Magnetic circular dichroism (MCD) spectroscopy and TD-DFT calculations have been used to study trends in the optical spectra and electronic structures. The effect of introducing different para-substituents on the phenyl substituents was examined. During fluorescence emission studies, phosphorescence was observed for the Ir(III) complexes in the near infrared (NIR) region.
- Description
- Original publication is available at http://dx.doi.org/10.1142/S108842461550073X
- Format
- 10 p., pdf
- Publisher
- World Scientific Publishing
- Language
- English
- Relation
- Wang, B., Zuo, H., Mack, J., Majumdar, P., Nyokong, T., Chan, K. S. & Shen, Z. 2015. Optical properties and electronic structures of axially-ligated group 9 porphyrins. Journal of Porphyrins and Phthalocyanines, 19(8):973–982. Available: http://dx.doi.org/ 10.1142/S108842461550073X.
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Mack, John (Associate Prof)
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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