Distribution of heavy minerals sand in Namalope deposit, Moma district, Mozambique
- Authors: Assane, Ali Ossufo
- Date: 2014
- Subjects: Heavy minerals -- Mozambique -- Moma District , Prospecting -- Mozambique -- Moma District , Mines and mineral resources -- Mozambique -- Moma District , Ilmenite -- Research , Zircon -- Research , Rutile -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5056 , http://hdl.handle.net/10962/d1012169 , Heavy minerals -- Mozambique -- Moma District , Prospecting -- Mozambique -- Moma District , Mines and mineral resources -- Mozambique -- Moma District , Ilmenite -- Research , Zircon -- Research , Rutile -- Research
- Description: The spatial distribution of heavy minerals along the mine paths 2014 and 2015 at the wet concentrate plant B shows an increase of heavy minerals sand concentration northwards and slime contents southwards, and it is commonly associated with depth and grain sorting; the increase of heavy minerals concentration with depth is considered to be from the surface formed by Unit 6 to the bottom of Unit 7. The Unit 82 is characterized by low heavy minerals concentrations and high slime contents declining northwards. The mineral proportion estimation suggests that ilmenite is the most abundant heavy mineral in the entire area followed by zircon, rutile and mozanite, and some accessory minerals such as chromite, kyanite, staurolite, tourmaline, epidote, spinel and quartz. The ilmenite occurrence is divided into ilmenite low (< 53% TiO₂) and high (> 53% TiO₂); the ilmenite high with zircon and rutile shows tendency to increase northwards while ilmenite low increase southwards. Zircon, monazite, rutile, chromite, kyanite and staurolite show low variability, which is probably associated with high resistance of minerals for abrasion during transportation and diagenesis. The depositional model of the Namalope deposit, in the flat area and wet concentrate plant B in particular, suggests deposition in a shallow marine environment associated with regression for deposition of Unit 6, 7 and 9 and transgression during deposition of Unit 82. The spatial distribution of heavy minerals in the Namalope deposit and its environment of deposition are the key points for discovery of new deposits around the Namalope with the same characteristic of mineral assemblage and they are used for mine strategic plans such as update block model and mine design.
- Full Text:
- Date Issued: 2014
Geotectonic controls on primary diamond deposits : a review of exploration criteria
- Authors: Hannon, Camille
- Date: 2013-05-23
- Subjects: Diamonds , Geology, Structural , Diamond deposits , Kimberlite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5047 , http://hdl.handle.net/10962/d1007810 , Diamonds , Geology, Structural , Diamond deposits , Kimberlite
- Description: The origin of diamonds, their preservation and transport to the surface have been important issues over the last decades after the acknowledgement that diamonds are xenocrysts in the host kimberlites and after the discovery of new transport media such as lamproites. Different types of diamonds -E-type diamonds, P-type diamonds- and different types of hosts - Eclogites, Peridotites- have been distinguished. Each type corresponds to particular formation criteria. Ecogitic Diamonds are mostly related to subduction processes, whereas more uncertainties remain regarding the formation of Peridotitic Diamonds. Komatiite extraction and subduction of graphite-bearing serpentinites have been proposed as the more likely processes involved in their formation. A typical mantle signature for diamonds implies a thick, cool, reduced lithosphere. The keel-shape model is the most popular. Archaean cratons are therefore the most promising exploration target and area selection will expect to follow the Clifford's Rule. However, the evidence of cratonic areas hidden under younger formations · through seismic profiles and the discovery of diamond structurally trapped outside their stability field, have increased the potential of diamondiferous areas. Preservation of diamonds inside the lithosphere requires that the mantleroot remains insulated against excessive reheating and tectonic reworking. Mantle-root friendly and mantle-root destructive structures are distinguished. Small-size cratons are usually the most promising exploration targets. Transport of diamonds to the surface is dependant on' the same criteria of preservation. Only kimberlites and lamproites have been recognized as efficient transport media. Their ascent to the surface is conditioned by a multitude of parameters, amongst them the nature of the magma, the speed of ascent, the presence of pre-existing structures in the crust and the availability of ground water in the near-surface environment. The origin of kimberlite magma probably lies near the transition zone. Mixtures of depleted asthenospheric · sources and metasomatically enriched and possibly subducted materials are likely to be at the origin of the different kimberlite magmas. Kimberlite magmatism correlates generally in time with global tectonic events, triggered by either plume activity or by subduction processes, depending of the tectonic school of thought. Kimberlite alignments have been interpreted as hotspot tracks, and kimberlite magmas as volatile-rich melts issued from the remaining plume tail. The plume head produces flood-basalts in an adjacent "thinspot" of the lithosphere, generally on the edges of the cratons. Kimberlite and lamproite ascent to the surface are unconditionally influenced by regional structures. Rift structures, ring structures, transform faults, suture zones and deep-seated faults have been mentioned as controlling or accompanying features of kimberlite magmatism. Nearsurface emplacement constraints are better understood and the ultimate shape of the intrusion(s) depends on the nature of the country rocks, the availability of ground water and the near-surface faulting pattern. The recent discovery of "fissure" kimberlites is one of the more important breakthroughs of the last decade. With a better understanding of the processes involved in diamond formation, preservation and of kimberlite emplacement, major diamond discoveries have recently increased on all the continents. Successful diamond exploration requires today an integration of all geophysical, petrologic, geochemical and structural information available. The particular study of the northwestern Australian lamproite and kimberlite fields, the Brazilian kimberlites, the easternNorth American kimberlite fields, the Lac de Gras kimberlite field, the South African rich kimberlite provinces, and the Yakutian kimberlite fields provide concrete examples of the geotectonic controls on primary diamond deposits. Area selection criteria based on the previous models and examples, are expected to yield to many more discoveries in the coming years. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
Photophysical properties of zinc carboxy phthalocyanine-quantum dot conjugates
- Authors: Sekhosana, Kutloano Edward
- Date: 2013 , 2013-03-27
- Subjects: Phthalocyanines , Quantum dots , Zinc , Photochemistry , Atomic force microscopy , Transmission electron microscopy , Raman spectroscopy , Infrared spectroscopy , X-ray photoelectron spectroscopy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4276 , http://hdl.handle.net/10962/d1001652 , Phthalocyanines , Quantum dots , Zinc , Photochemistry , Atomic force microscopy , Transmission electron microscopy , Raman spectroscopy , Infrared spectroscopy , X-ray photoelectron spectroscopy
- Description: This thesis presents work based on the interactions of water soluble caboxylated zinc phthalocyanines (Pcs) and coreshell quantum dots (QDs). The Pcs are ZnPc(COOH)₈ and ZnPc(COOH)₄ and coreshell QDs are CdTe@ZnS-GSH. GSH = L-glutathione. Characterization and photophysical studies of conjugates were carried out. The approach of coordinating Pcs to QDs was achieved using an organic cross linker, N-N’-dicyclohexylcarbodiimide (DCC) at pH 10 at room temperature. Employing atomic force microscopy (AFM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman, infrared and X-ray photoelectron spectroscopies, the formation of the conjugates was confirmed. Upon conjugation with Pc derivatives, the fluorescence quantum yield of CdTe@ZnS-GSH decreased due to energy transfer from the QDs to the Pc. The average fluorescence lifetime of the CdTe@ZnS-GSH QD also decreased upon conjugation. The föster resonance energy transfer (FRET) behaviour of CdTe@ZnS-GSH-ZnPc(COOH)₄ conjugates was compared to that of CdTe@ZnS-GSH-ZnPc(COOH)₈. Higher FRET efficiencies were observed for CdTe@ZnS-GSH-ZnPc(COOH)₄-mixed or CdTe@ZnS-GSH-ZnPc(COOH)₄-linked compared to the corresponding CdTe@ZnS-GSH-ZnPc(COOH)₈-mixed or CdTe@ZnS-GSH-ZnPc(COOH)₈-linked. Triplet quantum yield (ΦT) and lifetime (ΤT) of ZnPc(COOH)₈ were found to increase in the presence of coreshell QDs. Though the singlet quantum yield (ΦΔ) value of ZnPc(COOH)8 was lower than ΦT , there was a slight upsurge in the ΦT in the presence of QDs. , Microsoft� Word 2010 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
Synthesis of novel coumarin derivatives as potential inhibitors of HIV-1 protease
- Authors: Rose, Nathan Rolf
- Date: 2007 , 2013-07-01
- Subjects: Coumarins , Protease Inhibitors , Heterocyclic compounds -- Derivatives , HIV infections -- Treatment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4430 , http://hdl.handle.net/10962/d1007220 , Coumarins , Protease Inhibitors , Heterocyclic compounds -- Derivatives , HIV infections -- Treatment
- Description: This research has focused on the development of novel coumann derivatives containing peptide-like side chains as potential HIV-1 protease inhibitors. The reaction of various salicylaldehyde derivatives with tert-butyl acrylate In the presence of 1,4- diazabicyclo[2.2.2]octane (DABCO) has afforded a series of Baylis-Hillman adducts in moderate yield. Cyclisation of the adducts in the presence of HCI afforded the corresponding 3-(chloromethyl)coumarin derivatives, which have been reacted with various amine hydrochlorides in the presence of Proton Sponge® to afford a series of novel 3- (aminomethyl)coumarin derivatives, which were fully characterised by NMR and HRMS methods. Various approaches to the introduction of hydroxyl or amino groups at the C-4 position of coumarin and the 3-(chloromethyl)coumarin derivatives have been explored; these have included dihydroxylation of the coumarin double bond, and the synthesis of 4- benzylaminocoumarin derivatives as potential intermediates. The Vilsmeier-Haack and Mannich reactions have also been investigated as possible methods of introducing the desired peptide-like functionality. Computer modelling of selected structures has indicated that some of the novel 3- (aminomethyl)coumarin derivatives may exhibit activity as inhibitors of HIV-1 protease. The planned enzyme inhibition assays were unfortunately precluded by the aqueous insolubility of the selected compounds. Three ¹³C NMR chemical shift algorithms, viz., Modgraph Neural Network, Modgraph HOSE and Chern Window, have been applied to selected compounds prepared in this study. The Modgraph Neural Network algorithm was found, in all cases, to provide the most accurate correlations with the experimentally-determined chemical shifts. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2007
A remote interactive music keyboard tuition system
- Authors: Newton, Mark Brian
- Date: 2005
- Subjects: Computer-assisted instruction , Keyboard instrument music -- Instruction and study , Music -- Computer assisted instruction , Music in education
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4603 , http://hdl.handle.net/10962/d1004860 , Computer-assisted instruction , Keyboard instrument music -- Instruction and study , Music -- Computer assisted instruction , Music in education
- Description: A networked multimedia system to assist teaching music keyboard skills to a class is described. Teaching practical music lessons requires a large amount of interaction between the teacher and student and is thus teacher intensive. Although there is a range of computer software available for learning how to play the keyboard, these programs cannot replace the guidance of a music teacher. The possibility of combining the music applications with video conferencing technology for use in a keyboard class is discussed. An ideal system is described that incorporates the benefits of video conferencing and music applications for use in a classroom. A design of the ideal system is described and implemented. Certain design and implementation decisions are explained and the performance of the implementation examined. The system would enable a music teacher to effectively teach a music class keyboard skills.
- Full Text:
- Date Issued: 2005
Designing and implementing a virtual reality interaction framework
- Authors: Rorke, Michael
- Date: 2000
- Subjects: Virtual reality , Computer simulation , Human-computer interaction , Computer graphics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4623 , http://hdl.handle.net/10962/d1006491 , Virtual reality , Computer simulation , Human-computer interaction , Computer graphics
- Description: Virtual Reality offers the possibility for humans to interact in a more natural way with the computer and its applications. Currently, Virtual Reality is used mainly in the field of visualisation where 3D graphics allow users to more easily view complex sets of data or structures. The field of interaction in Virtual Reality has been largely neglected due mainly to problems with input devices and equipment costs. Recent research has aimed to overcome these interaction problems, thereby creating a usable interaction platform for Virtual Reality. This thesis presents a background into the field of interaction in Virtual Reality. It goes on to propose a generic framework for the implementation of common interaction techniques into a homogeneous application development environment. This framework adds a new layer to the standard Virtual Reality toolkit – the interaction abstraction layer, or interactor layer. This separation is in line with current HCI practices. The interactor layer is further divided into specific sections – input component, interaction component, system component, intermediaries, entities and widgets. Each of these performs a specific function, with clearly defined interfaces between the different components to promote easy objectoriented implementation of the framework. The validity of the framework is shown in comparison with accepted taxonomies in the area of Virtual Reality interaction. Thus demonstrating that the framework covers all the relevant factors involved in the field. Furthermore, the thesis describes an implementation of this framework. The implementation was completed using the Rhodes University CoRgi Virtual Reality toolkit. Several postgraduate students in the Rhodes University Computer Science Department utilised the framework implementation to develop a set of case studies. These case studies demonstrate the practical use of the framework to create useful Virtual Reality applications, as well as demonstrating the generic nature of the framework and its extensibility to be able to handle new interaction techniques. Finally, the generic nature of the framework is further demonstrated by moving it from the standard CoRgi Virtual Reality toolkit, to a distributed version of this toolkit. The distributed implementation of the framework utilises the Common Object Request Broker Architecture (CORBA) to implement the distribution of the objects in the system. Using this distributed implementation, we are able to ascertain that CORBA is useful in the field of distributed real-time Virtual Reality, even taking into account the extra overhead introduced by the additional abstraction layer. We conclude from this thesis that it is important to abstract the interaction layer from the other layers of a Virtual Reality toolkit in order to provide a consistent interface to developers. We have shown that our framework is implementable and useful in the field, making it easier for developers to include interaction in their Virtual Reality applications. Our framework is able to handle all the current aspects of interaction in Virtual Reality, as well as being general enough to implement future interaction techniques. The framework is also applicable to different Virtual Reality toolkits and development platforms, making it ideal for developing general, cross-platform interactive Virtual Reality applications.
- Full Text:
- Date Issued: 2000
Aspects of the ecology of the shrimp Palaemon pacificus (Stimpson) (Decapoda,Palaemonidae) in the Bushmans river estuary
- Authors: Robertson, Wendy Daryl
- Date: 1984
- Subjects: Shrimps -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5815 , http://hdl.handle.net/10962/d1007184 , Shrimps -- South Africa
- Description: The recruitment of Palaemon pacificus to the Bushmans River estuary was studied over a 12 month period. The dynamics of a population of shrimps in a small, tidal channel in the lower reaches of the estuary was investigated over a similar time span. Temperature and salinity tolerances of various stages and sizes of shrimps were compared in controlled experiments and are discussed in the light of the distribution and general ecology of the shrimp. Stage 6 zoeae and post-larvae entered the estuary on nocturnal flood tides throughout the year with peak recruitment occurring in March/April. The population of shrimps in the study site was predominantly juvenile for most of the year, with peak sub-adult numbers occurring in midsummer. The sex ratio was female-biased throughout the year except for short bursts of male predominance in February and April. Average growth rate was 0,043 mm carapace length per day. Maximum residence time in the study site was estimated to be four months and in the estuary at least six months. Flooding of the estuary resulted in a considerable reduction in juvenile numbers in the study site and some loss of sub-adults. Shrimps tolerated a temperature range of 4,3 to 30,9⁰C for 144 hours. Their long term tolerance range is probably narrower (10 to 28⁰C) because of the effects of temperature related factors such as starvation and disease. Their distribution in South Africa (Olifants River to Kosi Bay ) is consistent with this tolerance range. Sub-adults tolerated salinities of 1 to 79 ‰ and post-larvae 2 to 60 ‰ at 15⁰C for 144 hours. Low moulting success (low and high salinities ) and starvation (high salinities) would probably reduce these tolerance ranges to 2 to 56 ‰ (sub-adults) and 4 to 56 ‰ (post-larvae). Higher and lower temperatures (10 and 20⁰C) reduced the tolerance of post-larvae to low salinities, but sub-adults were only affected at 30⁰C. Stages 4 and 5 and stage 6 zoeae were intolerant of salinities below 14 ‰. The development of salinity tolerance with age is consistent with the retention of a marine breeding phase. It also explains the high loss of juveniles from the study site following the flood. It is postulated that recovery of the population after a flood would be fairly rapid except in extreme cases when estuarine vegetation is severely affected.
- Full Text:
- Date Issued: 1984