Retracted COVID-19 Papers and the level of 'citation pollution': a preliminary analysis and directions for future research
- Authors: Van der Walt, Wynand , Willems, Kris A , Friedrich, Wernher , Hatsu, Sylvester , Krauss, Kirstin
- Date: 2020
- Subjects: Retraction watch , Research -- Evaluation , Bibliographical citations -- Evaluation , Science publishing -- Corrupt practices , Scholarly publishing -- Corrupt practices , Learning and scholarship -- Corrupt practices , Medical publishing -- Corrupt practices , COVID-19 (Disease) -- Publishing
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/167732 , vital:41508 , https://www.abd-bvd.be/nl/bladen-voor-documentatie/2020-3-4/
- Description: Retraction Watch maintains a "running list" of retracted papers on Covid-19 related research. By the end of September 2020, thirty-three retracted Covid-19 papers were listed. We analysed these retracted papers, focusing specifically on how they have been cited by review papers, and subsequently how they have penetrated and potentially distorted public discourse and legitimate research on Covid-19. The study demonstrates the need for more in-depth studies that focus on the phenomenon of citation pollution. We show that the "Covid-19 publication race", amplified by a pressure-to-publish research culture, distorted published science on Covid-19. We highlight the urgency to engage popular media and critical decision makers on how to distinguish between questionable and legitimate science. We also emphasise the importance of dealing with illegitimate research in a timely manner, both from a scholarly communications and research quality perspective. , Retraction Watch maintient une "liste courante" des articles rétractés sur les recherches liées au Covid-19. Fin septembre 2020, trente-trois articles rétractés sur le Covid-19 étaient répertoriés. Nous avons analysé ces articles rétractés, en nous concentrant spécifiquement sur la façon dont ils ont été cités par d'autres articles, et ensuite sur la façon dont ils ont pénétré et potentiellement faussé le discours public et la recherche légitime sur le Covid-19. L'étude démontre le besoin d'études plus approfondies qui se concentrent sur le phénomène de la pollution des citations. Nous montrons que la "course à la publication sur le Covid-19", amplifiée par une culture de la pression à la publication de la recherche, a déformé l'information scientifique publiée sur le Covid-19. Nous soulignons l'urgence d'engager les médias populaires et les décideurs critiques sur la manière de distinguer la science douteuse de la science légitime. Nous soulignons également l'importance de traiter rapidement les recherches illégitimes, tant du point de vue de la communication scientifique que de la qualité de la recherche. , Retraction Watch houdt een "lopende lijst" bij van ingetrokken papieren over Covid-19-gerelateerd onderzoek. Eind september 2020 waren drieëndertig ingetrokken Covid-19 papieren op de lijst geplaatst. We hebben deze ingetrokken papieren geanalyseerd, waarbij we ons specifiek hebben gericht op de manier waarop ze zijn geciteerd door review papers, en vervolgens op de manier waarop ze zijn doorgedrongen en mogelijk vervormd in het publieke discours en het legitieme onderzoek naar Covid-19. De studie toont aan dat er behoefte is aan meer diepgaande studies die zich richten op het fenomeen van de citatievervuiling. We tonen aan dat de "Covid-19-publicatierace", versterkt door een druk om te publiceren onderzoekscultuur, de gepubliceerde wetenschap over Covid-19 vertekend heeft. We benadrukken de urgentie om de populaire media en kritische besluitvormers te betrekken bij het maken van een onderscheid tussen twijfelachtige en legitieme wetenschap. We benadrukken ook het belang van het tijdig aanpakken van onrechtmatig onderzoek, zowel vanuit het oogpunt van wetenschappelijke communicatie als vanuit het oogpunt van de kwaliteit van het onderzoek.
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Optical limiting and singlet oxygen generation properties of phosphorus triazatetrabenzcorroles
- Authors: Mkhize, Colin , Britton, Jonathan , Mack, John , Nyokong, Tebello
- Date: 2015
- Language: English
- Type: Article
- Identifier: vital:7257 , http://hdl.handle.net/10962/d1020266
- Description: Novel phosphorus triazatetrabenzcorrole (TBC) tetrasubstituted at the α- and β-positions of the peripheral fused benzene rings with t-butylphenoxy substituents have been prepared and characterized. The effect of the substituents on the electronic structures and optical properties is investigated with TD-DFT calculations and MCD spectroscopy. The optical limiting properties have been investigated to examine whether the lower symmetry that results from the direct pyrrole–pyrrole bond and hence the permanent dipole moment that is introduced result in higher safety thresholds, relative to the values that have been reported for phthalocyanines. The suitability of the compounds for singlet oxygen applications has also been examined. , Original publication is available at http://dx.doi.org/10.1142/S1088424614501065
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Contrasting habitat associations of imperilled endemic stream fishes from a global biodiversity hot spot
- Authors: Chakona, Albert , Swartz, Ernst R
- Date: 2012
- Language: English
- Type: Article
- Identifier: vital:7148 , http://hdl.handle.net/10962/d1011850 , http://www.biomedcentral.com/1472-6785/12/19
- Description: Knowledge of the factors that drive species distributions provides a fundamental baseline for several areas of research including biogeography, phylogeography and biodiversity conservation. Data from 148 minimally disturbed sites across a large drainage system in the Cape Floristic Region of South Africa were used to test the hypothesis that stream fishes have similar responses to environmental determinants of species distribution. Two complementary statistical approaches, boosted regression trees and hierarchical partitioning, were used to model the responses of four fish species to 11 environmental predictors, and to quantify the independent explanatory power of each predictor.
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The distribution, abundance and composition of street trees in selected towns of the Eastern Cape, South Africa
- Authors: Kuruneri-Chitepo, C , Shackleton, Charlie M
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6639 , http://hdl.handle.net/10962/d1006865
- Description: Street trees are an important component of the urban forest as they provide critical ecosystem services which contribute to human health and environmental quality. However, little is known about the distribution, diversity and density of street trees, particularly in the developing world where urbanisation is most rapid. Thus, the aim of this paper was to assess the distribution, composition and abundance of street trees across three towns along an environmental gradient in the Eastern Cape of South Africa, and identify the key challenges faced by local officials concerned with the provision of street trees. In each town, streets were randomly sampled in the commercial, affluent residential, township settlement and low cost housing areas under the Reconstruction and Development Program (RDP). Attributes recorded per tree were species, circumference, height and health, while semi-structured interviews were conducted with the municipal officials involved in the establishment and maintenance of street trees. A total of 1,485 trees were encountered, comprising 61 species. The majority (56%) of trees were alien species. Noticeable differences in tree density and species richness were evident across suburbs, being highest in the more affluent suburbs and poorly represented in the low income township and RDP areas. There was a decreasing mean tree height and health score along the environmental gradient from the coastal town to the inland town. Although awareness of the benefits of street trees was high, as was the need to reduce the proportion of alien species, the primary constraint to establishment and maintenance of street trees in the three towns was limited budget and human resources.
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Compactification of lattice-valued convergence spaces
- Authors: Jäger, Gunter
- Date: 2010
- Language: English
- Type: text , Article
- Identifier: vital:6828 , http://hdl.handle.net/10962/d1012339
- Description: We define compactness for stratified lattice-valued convergence spaces and show that a Tychonoff theorem is true. Further a generalization of the classical Richardson compactification is given. This compactification has a universal property.
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A test for Allee effects in the self-incompatible wasp-pollinated milkweed Gomphocarpus physocarpus
- Authors: Coombs, Gareth , Peter, Craig I , Johnson, Steven D
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6511 , http://hdl.handle.net/10962/d1005938 , http://dx.doi.org/10.1111/j.1442-9993.2009.01976.x
- Description: It has been suggested that plants which are good colonizers will generally have either an ability to self-fertilize or a generalist pollination system. This prediction is based on the idea that these reproductive traits should confer resistance to Allee effects in founder populations and was tested using Gomphocarpus physocarpus (Asclepiadoideae; Apocynaceae), a species native to South Africa that is invasive in other parts of the world. We found no significant relationships between the size of G. physocarpus populations and various measures of pollination success (pollen deposition, pollen removal, and pollen transfer efficiency) and fruit set. A breeding system experiment showed that plants in a South African population are genetically self-incompatible and thus obligate outcrossers. Out-crossing is further enhanced by mechanical reconfiguration of removed pollinaria before the pollinia can be deposited. Selfpollination is reduced when such reconfiguration exceeds the average duration of pollinator visits to a plant. Observations suggest that a wide variety of wasp species in the genera Belonogaster and Polistes (Vespidae) are the primary pollinators. We conclude that efficient pollination of plants in small founding populations, resulting from their generalist wasp-pollination system, contributes in part to the colonizing success of G. physocarpus. The presence of similar wasps in other parts of the world has evidently facilitated the expansion of the range of this milkweed.
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Investigating how the attributes of live theatre productions influence consumption choices using conjoint analysis : the example of the National Arts Festival, South Africa
- Authors: Willis, K G , Snowball, Jeanette D
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6075 , http://hdl.handle.net/10962/d1003825 , http://dx.doi.org/10.1007/s10824-009-9097-z
- Description: While there is a fair amount of work on determinants of demand for the live performing arts, results have often been contradictory with little explanatory power. This may be because of the difficulty in describing the attributes of a performance, particularly in terms of its quality, and the heterogeneity of consumer preferences. This article uses conjoint analysis, also called choice experiments, to investigate the impact of the attributes of live theatre performances on demand, using data collected from 483 randomly chosen attenders at live theatre performances at the 2008 South African National Arts Festival. Attributes include the type of cast (professional, semi-professional or amateur), reputation of the producer/director, the context or setting, production type and ticket price of the show. Results largely support the a priori expectations based on the results of other demand studies. For example, it is found that the age of consumers affects the type of show chosen, that utility and willingness to pay increase for shows with professional and semi-professional casts and that 93% of the potential audience prefer shows with a South African context. It is concluded that the method could prove useful to both event organisers and policy makers, especially where the goal is to broaden access to the arts.
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Pointfree pseudocompactness revisited
- Authors: Dube, T , Matutu, Phethiwe P
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6781 , http://hdl.handle.net/10962/d1006924
- Description: We give several internal and external characterizations of pseudocompactness in frames which extend (and transcend) analogous characterizations in topological spaces. In the case of internal characterizations we do not make reference (explicitly or implicitly) to the reals.
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Predicting geographic distribution of seven blowfly species (Diptera: Calliphoridae) in South Africa
- Authors: Richards, Cameron S , Williams, Kirstin A , Villet, Martin H
- Date: 2009
- Language: English
- Type: text , Article
- Identifier: vital:6854 , http://hdl.handle.net/10962/d1011135
- Description: The predicted geographic distributions of seven forensically important blowfly species are modelled using the computer program Maxent, based on selected climatic variables for South Africa, a country with large climatic and environmental gradients. It is shown that although temperature was hypothesized to most influence the distributions of these ectotherms, moisture, and particularly humidity, was in fact usually paramount. Chrysomya albiceps (Wiedemann) and C. marginalis (Robineau-Desvoidy) had the most widespread geographic and climatic distribution, while the forest-associated C. inclinata(Walker) was the least widespread. Chrysomya putoria (Wiedemann) and C. megacephala (Fabricius) had very similar predicted distributions that were restricted mainly to Limpopo, Mpumalanga, KwaZulu-Natal and the coast of the Eastern Cape. Chrysomya chloropyga (Wiedemann) and Calliphora croceipalpis (Jaennicke) were the only species predicted to occur at high altitudes. Blowfly distributions restricted to part of the map area were predicted better than those that were more widespread in the region, presumably because species with extremely widespread distributions in a study area occupy nearly the whole range of variation of most predictor variables, leaving little variation with which themaximumentropy modelling method can discriminate between presence and absence of the organism.
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Topographic thresholds in gully development on the hillslopes of communal areas in Ngqushwa Local Municipality, Eastern Cape, South Africa
- Authors: Kakembo, V , Xanga, W W , Rowntree, Kate M
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6691 , http://hdl.handle.net/10962/d1006726
- Description: The relationships between the spatial distribution of gully erosion and topographic thresholds in the form of slope angle, position and configuration, as well as land use change in the form of abandoned lands were examined in several affected catchments of the Eastern Cape Province, South Africa. Land use and permanent gullies were mapped, digitized from orthophoto maps in Arc/info 3.5.2 GIS and converted to shapefiles using ArcView 3.2 GIS. Relationships between the mapped phenomena and topographic variables were sought using a Digital Elevation Model (DEM) in Idrisi Kilimanjaro GIS. A comparison between areas with a high potential for gullying and actual gully erosion was made using the Stream Power Index (SPI) as a surrogate for critical flow shear stress. Field surveys were also conducted to assess the present condition of the gullied sites as well as to validate DEM derivations. Seventy five percent of the gullied area was noted to lie on abandoned lands. A predominance of gullying in concave bottom lands was also identified. The SPI values highlighted a distinct preferential topographic zone for gully location. A conceptual model depicting the interaction between land use and topographic parameters to induce gully erosion was developed. This should assist local authorities to develop a policy regarding management of abandoned lands.
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Handling multiple levels of data and multiple research questions in an embedded case study : methodological challenges
- Authors: Edwards, David J A
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:6247 , http://hdl.handle.net/10962/d1007865
- Description: Hougaard et al. report an embedded case study in which nine socially phobic clients were treated as part of a therapy program, which incorporated individual and group therapy and which was largely delivered by trainee clinicians. An important focus of the report is on the effectiveness of their treatment model. This commentary draws attention to the size and complexity of the available data, and it suggests ways in which the use of a more explicitly interpretative methodology can draw out additional dimensions of the data and allow a more systematic contribution to be made to the development of clinical theory.
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The effects of load and gradient on hand force responses during dynamic pushing and pulling tasks
- Authors: Bennett, Anthea I , Desai, Sheena D , Todd, Andrew I , Freeland, H
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:6757 , http://hdl.handle.net/10962/d1009459
- Description: The limited attention afforded to push/pull activities and the motion phases (initial, sustained and ending) characteristic of these tasks has prompted a research focus in this area. The present study examined biomechanical responses in the form of hand forces during dynamic submaximal trolley pushing and pulling. Participants pushed/pulled loads of 100, 200 and 300 kg on the level (determining impact of load) or pushed 100 kg along a 12° ramp (uphill and downhill- determining impact of gradient). During level exertions significant differences (p<0.05) in hand forces occurred between loads of 100 and 200 kg, and 100 and 300 kg for initial and sustained forces but not ending forces. Values were similar for pushing and pulling at respective loads and motion phases. Strong correlations indicate that initial forces can be used to accurately estimate sustained and ending forces. Importantly, correct technique is essential in force reduction. Forces were highest during uphill initial and sustained phases and the downhill sustained phase. For the initial phase, the forces were highest during uphill pushing (86.5 ± 25.73 N); for the sustained phase, there was no difference between uphill and downhill forces but level forces were significantly lower (18.19 ± 8.09 N) than either of the other two conditions; for the ending phase, the highest forces were produced during downhill pushing (-53.34 ± 13.65N). As sustained forces equaled or exceeded initial forces for uphill and downhill efforts, consideration of sustained forces may be appropriate in determining the inherent potential risk of graded pushing.
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A stability-indicating high performance liquid chromatographic (HPLC) assay for the simultaneous determination of atorvastatin and amlodipine in commercial tablets
- Authors: Mohammadi, Ali , Rezanour, N , Ansari Dogaheh, M , Ghorbani Bidkorbeh, F , Hashem, M , Walker, Roderick B
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6403 , http://hdl.handle.net/10962/d1006340
- Description: A simple, rapid, precise and accurate isocratic reversed-phase stability-indicating HPLC method was developed and validated for the simultaneous determination of atorvastatin (AT) and amlodipine (AM) in commercial tablets. The method has shown adequate separation for AM, AT from their associated main impurities and their degradation products. Separation was achieved on a Perfectsil® Target ODS-3, 5 μm, 250 mm × 4.6 mm i.d. column using a mobile phase consisting of acetonitrile–0.025 M NaH2PO4 buffer (pH 4.5) (55:45, v/v) at a flow rate of 1 ml/min and UV detection at 237 nm. The drugs were subjected to oxidation, hydrolysis, photolysis and heat to apply stress conditions. The linearity of the proposed method was investigated in the range of 2–30 μg/ml (r = 0.9994) for AT and 1–20 μg/ml (r = 0.9993) for AM. The limits of detection were 0.65 μg/ml and 0.35 μg/ml for AT and AM, respectively. The limits of quantitation were 2 μg/ml and 1 μg/ml for AT and AM, respectively. Degradation products produced as a result of stress studies did not interfere with the detection of AT and AM and the assay can thus be considered stability-indicating.
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Quality of life in South Africa: the first ten years of democracy
- Authors: Moller, Valerie
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:7110 , http://hdl.handle.net/10962/d1010741
- Description: South Africa celebrated ten years of democracy in 2004. This special issue of Social Indicators Research (SIR) reviews developments that have impacted on the quality of life of ordinary South Africans during the transition period. The issue updates an earlier volume of SIR (Volume 41) published in 1997 and as a stand-alone volume. The earlier volume was initiated following SIR editor Alex Michalos’ first visit to South Africa. This update on quality of life in South Africa follows on his return visit to the country in 2004 to see firsthand the changes that had occured in the meantime. This introductory article outlines major achievements of and setbacks for the new democracy and the challenges facing it in future. It provides the backround for the evaluations of a range of quality of life domains and issues including poverty and inequality, crime, the HIV/AIDS epidemic, migration and housing, religiosity, reconciliation, and optimism for the future which are covered in the eleven articles that follow. The introduction divides the articles under the headings of challenges, achievements, monitoring quality of life, and social capital for the future. The overview article concludes that improvements in quality of life have been uneven but goodwill and a positive outlook bode well for South African quality of life in future.
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Spermiogenesis in three species of cicadas (Hemiptera: Cicadidae)
- Authors: Chawanji, A S , Hodgson, Alan N , Villet, Martin H , Sanborn, Allen F , Phillips, Polly K F
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6865 , http://hdl.handle.net/10962/d1011207
- Description: Spermiogenesis in three species of cicadas representing one cicadettine (Monomatapa matoposa Boulard) and two cicadines (Diceroprocta biconica [Walker] and Kongota punctigera [Walker]) was investigated by light and electron microscopy. Although spermiogenesis was occurring in the testis of adult males of all species, earlier spermiogenic stages were observed in D. biconica only. While spermiogenesis was similar to that described for other insects, some differences were noted. For example granular material did not assemble around the centriole to form a centriolar adjunct but did accumulate in the cytoplasm of early spermatids adjacent to a region of the nuclear membrane where nuclear pores were aggregated. In late spermatids this material accumulated anterior to the mitochondrial derivatives in a developing postero-lateral nuclear groove. While this material has been named the ‘centriolar adjunct’ by previous authors, its formation away from the centriole raises questions about its true identity. Second, during acrosome maturation an ante-acrosomal region of cytoplasm develops. Although present in later spermatids, this region is lost in spermatozoa. Interspecific variations in chromatin condensation patterns and the number of microtubule layers encircling the spermatid nucleus during spermiogenesis were noted.
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A stability-indicating high performance liquid chromatographic assay for the determination of orlistat in capsules
- Authors: Mohammadi, Ali , Haririan, I , Rezanour, I , Ghiasi, L , Walker, Roderick B
- Date: 2006
- Language: English
- Type: Article , text
- Identifier: vital:6407 , http://hdl.handle.net/10962/d1006480
- Description: A stability-indicating HPLC method was developed and validated for the quantitative determination of orlistat in capsule dosage forms. An isocratic separation was achieved using a Perfectsil® target ODS-3, 250 mm × 4.6 mm i.d., 5 µm particle size column with a flow rate of 0.7 ml/min and using a UV detector to monitor the eluate at 210 nm. The mobile phase consisted of methanol:acetonitrile:trifluoroacetic acid (82.5:17.5:0.01, v/v/v). The drug was subjected oxidation, hydrolysis, photolysis and heat to apply stress conditions. Complete separation was achieved for the parent compound and all degradation products in an overall analytical run time of approximately 15 min with the parent compound orlistat eluting at approximately 9 min. The method was linear over the concentration range of 0.02–0.75 mg/ml (r = 0.9998) with a limit of detection and quantitation 0.006 and 0.02 mg/ml, respectively. The method has the requisite accuracy, selectivity, sensitivity and precision to assay orlistat in capsules. Degradation products resulting from the stress studies did not interfere with the detection of orlistat and the assay is thus stability-indicating.
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Academic Library Consortia in South Africa : where we come from and where we are heading
- Authors: Thomas, G M E , Fourie, I
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6987 , http://hdl.handle.net/10962/d1012410
- Description: The purpose of this article is to give an overview of the establishment of the five academic library consortia in South Africa, their status quo, and a summary of their successes and plans for the future. Although useful information can be found from the consortia Web sites, much of it is no longer current. Similarly, there is limited published literature on the academic library consortia in South Africa. Apart from the sources referenced, the authors therefore relied heavily on an unpublished conference paper by Thomas[reference 1], which included findings gathered during a short survey among the five academic library consortia. In addition, Rowley and Slack[reference 2] and Sekabembe[reference 3] provide useful overviews of the library consortia in South Africa at the time of publication. Further information is available in published and unpublished sources.
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Application of reverse-flow micellar electrokinetic chromatography for the simultaneous determination of flavonols and terpene trilactones in Ginkgo biloba dosage forms
- Authors: Dubber, Mary-Jean , Kanfer, Isadore
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:6357 , http://hdl.handle.net/10962/d1006049
- Description:
A reverse-flow micellar electrokinetic chromatographic (RF-MEKC) method was developed for the simultaneous qualitative determination of 10 components consisting of the flavonol glycosides, rutin and quercitrin, the flavonol aglycones, isorhamnetin, kaempferol and quercetin, the terpene trilactones, ginkgolides A, B, C and J and the sesquiterpene, bilobalide. This method was used to fingerprint Ginkgo biloba solid oral dosage forms and validated for the quantitation of the marker compounds, rutin and quercetin in some commercial products. In addition to the usual variables, the influence of some essential background electrolyte (BGE) components such as sodium dodecyl sulphate (SDS) and
-cyclodextrin concentrations were investigated. A polyimide fused-silica square capillary column (75 μm I.D. × 360 μm O.D.) with a total length of 60.0 cm and effective length of 45.0 cm was used for the separation. The final BGE consisted of 20 mM phosphoric acid, 40 mM SDS and 12 mM -cyclodextrin (pH 2.2) using reverse polarity with a voltage of −17.5 kV. Samples were injected electrokinetically at −5 kV for 3 s for the qualitative analysis and hydrodynamically at 20 mbar for 0.6 s for the quantitative assay. The total run time was 22 min and the limits of detection were 3.13 μg/ml and 1.88 μg/ml for rutin and quercetin, respectively. Fingerprint profiles of the solid oral dosage forms and the results of the quantitative analysis indicated that there were major discrepancies in the marker content between products and illustrates the value of this method for use as a procedure to assess product quality of commercially available Ginkgo biloba products. - Full Text:
Effects of ring substituents on electrocatalytic activity of manganese phthalocyanines towards the reduction of molecular oxygen
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6594 , http://hdl.handle.net/10962/d1004343
- Description: Reduction of oxygen electrocatalyzed by adsorbed films of manganese phthalocyanine complexes is reported. The complexes studied were: manganese phthalocyanine (MnPc, 1); manganese tetraamino phthalocyanine (MnTAPc, 2); manganese tetrapentoxy pyrrole phthalocyanine (MnTPePyrPc, 3); manganese tetra phenoxy pyrrole phthalocyanine (MnTPPyrPc, 4); manganese tetra mercaptopyrimidine phthalocyanine (MnTMPyPc, 5) and manganese tetra ethoxy thiophene phthalocyanine (MnTETPc, 6). The reaction was conducted in buffer solutions of pH range 1–12. Rotating disk electrode voltammetry revealed two electron reduction in acidic and slightly alkaline media due to the formation of hydrogen peroxide. In highly basic media, water is the major product formed via four electron transfer. The reaction was found to be first order in the diffusing analyte oxygen.
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Estimation of small reservoir storage capacities in Limpopo River Basin using geographical information systems (GIS) and remotely sensed surface areas: case of Mzingwane catchment
- Authors: Sawunyama, Tendai , Senzanje, J , Mhizha, A
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:7077 , http://hdl.handle.net/10962/d1009741
- Description: The current interest in small reservoirs stems mainly from their utilization for domestic use, livestock watering, fishing and irrigation. Rarely were small reservoirs considered in the water resources system even though they are important in water resource planning and management. The main limitation being lack of knowledge on small reservoir capacities, for the methodologies used to quantify physical parameters of reservoirs are costly, time consuming and laborious. To address this challenge an attempt has been made in this study to estimate small reservoir storage capacities using remotely sensed surface areas. A field study on 12 small reservoirs was carried out in Mzingwane catchment in Limpopo River Basin; Zimbabwe. The depths of water accompanied with their coordinates were measured; from which area and capacity were calculated for each reservoir using geographical information system based on data acquired from the field and that from satellite images. The output data was compared and a linear regression analysis was carried out to establish a power relationship between surface area and storage capacity of small reservoirs. The Pearson correlation analysis at 95% confidence interval indicated that the variances of the two surface areas (field area and image area) were not significantly different (p < 0.05). The findings from linear regression analysis (log capacity–log area) show that there exist a power relationship between remotely sensed surface areas (m^2) and storage capacities of reservoirs (m^3), with 95% variation of the storage capacity being explained by surface areas. The relationship can be used as a tool in decision-making processes in integrated water resources planning and management in the river basin. The applicability of the relationship to other catchments requires further research as well as investigating the impacts of small reservoirs in water resources available in the river basin by carrying out a hydrological modelling of the catchment.
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