Performance evaluation and cost analysis of subsurface flow constructed wetlands designed for ammonium-nitrogen removal
- Authors: Tebitendwa, Sylvie Muwanga
- Date: 2018
- Subjects: Sewage Purification Nitrogen removal , Constructed wetlands , Bioremediation , Sewage lagoons , Coal mine waste
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/61808 , vital:28062
- Description: Subsurface flow constructed wetlands (SSF CWs) is a low-cost, environmentally friendly sanitation technology for on-site treatment of domestic/municipal sewage. However, these systems are apparently unable to produce treated water of a quality suitable for discharge particularly in terms of nitrogen concentration, which has been attributed to design and operation based on biological oxygen demand as the parameter of choice. The aim of this study was to evaluate the performance, support medium, and techno-economics of a vertical- horizontal (V-H) SSF hybrid CW designed and operated using ammonium-nitrogen (NH4+-N) as the major parameter. Two pilot scale V-H SSF hybrid CWs were designed, constructed, and the performance of each monitored over two seasons and under two phases i.e. an initiation phase, and an optimization phase. Laboratory-scale horizontal SSF CWs were used to evaluate the support medium while the techno-economic study was framed to determine the cost effectiveness of V-H SSF hybrid CWs relative to high rate algal oxidation pond (HRAOP) systems to increase capacity of overloaded and/or under-performing waste stabilization pond (WSP) sewage treatment plants. Results revealed that under optimal operating conditions of hydraulic loading rate, hydraulic retention, and influent NH4+-N loading rate, treated water from the V-H SSF hybrid CWs achieved a quality commensurate with current South African standards for discharge into a surface water resource for all parameters except chemical oxygen demand and faecal coliforms. This suggests that NH4+-N is an important design and operational parameter for SSF CWs treating municipal sewage that is characterised as weak in terms of NH4+-N with a requirement of only simple disinfection such as chlorination to eliminate faecal coliforms. Use of discard coal to replace gravel as support medium in horizontal SSF CWs revealed an overall reduction in elemental composition of the discard coal support medium but without compromising water quality. This result strongly supports use of discard coal as an appropriate substrate for SSF CWs to achieve acceptable water quality. Furthermore, simultaneous degradation of discard coal during wastewater treatment demonstrates the versatility of SSF CWs for use in bio-remediation and pollution control. Finally, a technoeconomic assessment of V-H SSF hybrid CWs and a HRAOP series was carried out to determine the suitability of each process to increase capacity by mitigating dysfunctional and/or overloaded WSP sewage treatment plants. Analysis revealed that the quality of treated water from both systems was within the South African General Authorization standards for discharge to a surface water resource. Even so, each technology system presented its own set of limitations including; the inability to satisfactorily remove NH4+-N and chemical oxygen demand (i.e. for V-H SSF hybrid CWs) and total suspended solids and faecal coliforms (i.e. for HRAOPs), and a requirement for substantial land footprint while, HRAOPs required significantly less capital than V-H SSF hybrid CWs for implementation. The latter suggests that HRAOPs could be preferred over V-H SSF hybrid CWs as a technology of choice to increase the capacity of overloaded WSP sewage treatment plants especially where financial resources are limited. Overall, the results of this thesis indicate the potential to use NH4+-N as a design parameter in constructing SSF CWs treating weak strength municipal sewage (i.e. in terms of NH4+-N concentration) and to supplant gravel as the treatment media with industrial waste material like discard coal to achieve wastewater treatment, bio-remediation, and pollution control. The results of this work are discussed in terms of using SSF CWs as a passive and resilient technology for the treatment of domestic sewage in sub-Saharan Africa.
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Empirical modelling of the solar wind influence on Pc3 pulsation activity
- Authors: Lotz, Stefanus Ignatius
- Date: 2012
- Subjects: Solar wind -- Research Solar activity -- Research Stellar oscillations -- Research , Magnetospheric radio wave propagation , Interplanetary magnetic fields
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5464 , http://hdl.handle.net/10962/d1005249
- Description: Geomagnetic pulsations are ultra-low frequency (ULF) oscillations of the geomagnetic field that have been observed in the magnetosphere and on the Earth since the 1800’s. In the 1960’s in situ observations of the solar wind suggested that the source of pulsation activity must lie beyond the magnetosphere. In this work the influence of several solar wind plasma and interplanetary magnetic field (IMF) parameters on Pc3 pulsations are studied. Pc3 pulsations are a class of geomagnetic pulsations with frequency ranging between 22 and 100 mHz. A large dataset of solar wind and pulsation measurements is employed to develop two empirical models capable of predicting the Pc3 index (an indication of Pc3 intensity) at one hour and five minute time resolution, respectively. The models are based on artificial neural networks, due to their ability to model highly non-linear interactions between dependent and independent variables. A robust, iterative process is followed to find and rank the set of solar wind input parameters that optimally predict Pc3 activity. According to the parameter selection process the input parameters to the low resolution model (1 hour data) are, in order of importance, solar wind speed, a pair of time-based parameters, dynamic solar wind pressure, and the IMF orientation with respect to the Sun-Earth line (i.e. the cone angle). Input parameters to the high resolution model (5 minute data) are solar wind speed, cone angle, solar wind density and a pair of time-based parameters. Both models accurately predict Pc3 intensity from unseen solar wind data. It is observed that Pc3 activity ceases when the density in the solar wind is very low, even while other conditions are favourable for the generation and propagation of ULF waves. The influence that solar wind density has on Pc3 activity is studied by analysing six years of solar wind and Pc3 measurements at one minute resolution. It is suggested that the pause in Pc3 activity occurs due to two reasons: Firstly, the ULF waves that are generated in the region upstream of the bow shock does not grow efficiently if the solar wind density is very low; and secondly, waves that are generated cannot be convected into the magnetosphere because of the low Mach number of the solar wind plasma due to the decreased density.
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Equilibrium, expectations and information : a study of the general theory, the neo-classical synthesis and modern classical macroeconomics
- Authors: Torr, Christopher
- Date: 1984
- Subjects: Macroeconomics Equilibrium (Economics) Economics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1035 , http://hdl.handle.net/10962/d1004515
- Description: From Introduction: It is now nearly 50 years since the appearance of Keynes's General Theory of Employment, Interest and Money and the stream of articles and books on what Keynes really meant or didn't mean shows no sign of abating. In part, this dissertation is a contribution to this voluminous literature, but what follows is hardly an attempt to provide an exhaustive interpretation. Instead the General Theory is examined from a certain angle, with the title "Equilibrium, Expectations and Information" providing the framework for the investigation. That the title has been borrowed from G.B. Richdrdson's 1959 Economic Journal article is no accident. Richardson's work has been unduly neglected and his trichotomy serves as a convenient platform from which to analyse Keynes's method and those of his interpreters, in particular the approaches stemming from the work of Clower and Leijonhufvud. The information structure of the Walrasian type of general equilibrium model is also examined as the latter forms the basis of both the neo-classical interpretation of Keynes's contribution and the rational expectations approach that will be discussed. Finally Richardson's framework is applied in an analysis of two modern classical schools of thought, namely the rational expectations approach headed by Lucas, and the neoRicardian school amongst which Garegnani, Eatwell and Milgate, for example, are prominent. In a sentence, therefore, what follows is an examination of the General Theory and certain interpretations thereof as well as an analysis of modern classical macroeconomics, with the equilibrium-expectations-information framework providing the unifying theme. As will become apparent, the framework does not consist of three watertight compartments. For example, whether a system is in equilibrium or not will depend on whether the expectations of those who have the ablility to effect change are realised. The specification of which agents have this power will depend on the information with which the model builder endows the agents in the model. In discussing this, attention is drawn to Keynes's important distinction between an entrepreneur economy and a cooperative economy. The distinction between the information available to the model builder and that with which he endows the agents in the model is also emphasized.
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