Labouring to love: romantic love and power in the construction of middle-class femininity
- Vincent, Louise, McEwen, Caryn
- Authors: Vincent, Louise , McEwen, Caryn
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141783 , vital:38004 , DOI: 10.1177/097152150501300102
- Description: South Africa is 10 years into its new democratic order. An aspect of the country's political transformation has been an official political commitment to gender trans-formation. While great strides have been made towards greater gender equality at the institutional and legal level of society, the present article suggests that highly unequal power relations between men and women continue to be perpetuated in unexpected ways among those whom we would most expect to be capable of resistance. This paper is about how subtle yet deeply embedded ideologies and practices within heterosexual relationships serve to keep highly educated, apparently empowered and liberated women ‘in their place’, ensuring that they do not fulfil their potential. Traditionally women were socialised into assuming their positions in the home as caregivers and unpaid household labourers. The hope of feminism was that education, economic empowerment and an ideology of ‘can do’ independence would liberate women. However, for many women, it is in the most intimate aspects of their lives—in their sexual relationships with men—that this hope continues to be thwarted.
- Full Text:
- Authors: Vincent, Louise , McEwen, Caryn
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141783 , vital:38004 , DOI: 10.1177/097152150501300102
- Description: South Africa is 10 years into its new democratic order. An aspect of the country's political transformation has been an official political commitment to gender trans-formation. While great strides have been made towards greater gender equality at the institutional and legal level of society, the present article suggests that highly unequal power relations between men and women continue to be perpetuated in unexpected ways among those whom we would most expect to be capable of resistance. This paper is about how subtle yet deeply embedded ideologies and practices within heterosexual relationships serve to keep highly educated, apparently empowered and liberated women ‘in their place’, ensuring that they do not fulfil their potential. Traditionally women were socialised into assuming their positions in the home as caregivers and unpaid household labourers. The hope of feminism was that education, economic empowerment and an ideology of ‘can do’ independence would liberate women. However, for many women, it is in the most intimate aspects of their lives—in their sexual relationships with men—that this hope continues to be thwarted.
- Full Text:
Language and learning science in South Africa
- Authors: Probyn, Margie J
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:7023 , http://hdl.handle.net/10962/d1007204 , http://dx.doi.org/10.2167/le554.0
- Description: South Africa is a multilingual country with 11 official languages. However, English dominates as the language of access and power and although the Language-in- Education Policy (1997) recommends school language policies that will promote additive bilingualism and the use of learners' home languages as languages of learning and teaching, there has been little implementation of these recommendations by schools. This is despite the fact that the majority of learners do not have the necessary English language proficiency to successfully engage with the curriculum and that teachers frequently are obliged to resort to using the learners' home language to mediate understanding. This research investigates the classroom language practices of six Grade 8 science teachers, teaching science through the medium of English where they and their learners share a common home language, Xhosa. Teachers' lessons were videotaped, transcribed and analysed for the opportunities they offered learners for language development and conceptual challenge. The purpose of the research is to better understand the teachers' perceptions and problems and to be able to draw on examples of good practice, to inform teacher training and to develop a coherent bilingual approach for teaching science through the medium of English as an additional language.
- Full Text:
- Authors: Probyn, Margie J
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:7023 , http://hdl.handle.net/10962/d1007204 , http://dx.doi.org/10.2167/le554.0
- Description: South Africa is a multilingual country with 11 official languages. However, English dominates as the language of access and power and although the Language-in- Education Policy (1997) recommends school language policies that will promote additive bilingualism and the use of learners' home languages as languages of learning and teaching, there has been little implementation of these recommendations by schools. This is despite the fact that the majority of learners do not have the necessary English language proficiency to successfully engage with the curriculum and that teachers frequently are obliged to resort to using the learners' home language to mediate understanding. This research investigates the classroom language practices of six Grade 8 science teachers, teaching science through the medium of English where they and their learners share a common home language, Xhosa. Teachers' lessons were videotaped, transcribed and analysed for the opportunities they offered learners for language development and conceptual challenge. The purpose of the research is to better understand the teachers' perceptions and problems and to be able to draw on examples of good practice, to inform teacher training and to develop a coherent bilingual approach for teaching science through the medium of English as an additional language.
- Full Text:
Larval development of the carrion-breeding flesh fly, Sarcophaga (Liosarcophaga) tibialis Macquart (Diptera: Sarcophagidae), at constant temperatures
- Villet, Martin H, MacKenzie, B, Muller, Wilhelmine J
- Authors: Villet, Martin H , MacKenzie, B , Muller, Wilhelmine J
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:7091 , http://hdl.handle.net/10962/d1012422
- Description: Larvae of Sarcophaga (Liosarcophaga) tibialis Macquart were raised on chicken liver under six different constant temperatures. Maximum survival indicated an optimal developmental temperature of near 20°C, while trends in mortality, larval length and larval mass implied that the thermal window for successful development lay between 15°C and 30°C. Using a recently described method to estimate a simple thermal summation model, it was found that the timing of the end of the feeding phase could be estimated by a developmental zero (D0) of 5.2°C (S.E. = 1.21) and a thermal summation constant (K) of 106.4 d°C (S.E. = 8.31) and of the end of the wandering phase by D0 = 4.1°C (S.E. = 0.39) and K = 126.7 d°C (S.E. = 3.28). Published development times at constant temperatures were compiled for 19 other species of flesh flies, and the developmental constants were calculated for six species for which sufficient data were accumulated.
- Full Text:
- Authors: Villet, Martin H , MacKenzie, B , Muller, Wilhelmine J
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:7091 , http://hdl.handle.net/10962/d1012422
- Description: Larvae of Sarcophaga (Liosarcophaga) tibialis Macquart were raised on chicken liver under six different constant temperatures. Maximum survival indicated an optimal developmental temperature of near 20°C, while trends in mortality, larval length and larval mass implied that the thermal window for successful development lay between 15°C and 30°C. Using a recently described method to estimate a simple thermal summation model, it was found that the timing of the end of the feeding phase could be estimated by a developmental zero (D0) of 5.2°C (S.E. = 1.21) and a thermal summation constant (K) of 106.4 d°C (S.E. = 8.31) and of the end of the wandering phase by D0 = 4.1°C (S.E. = 0.39) and K = 126.7 d°C (S.E. = 3.28). Published development times at constant temperatures were compiled for 19 other species of flesh flies, and the developmental constants were calculated for six species for which sufficient data were accumulated.
- Full Text:
Lattice-valued continuous convergence is induced by a lattice-valued uniform convergence structure
- Authors: Jäger, Gunter
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:6824 , http://hdl.handle.net/10962/d1012332
- Description: We define a stratified L-uniform convergence structure on the set of all continuous mappings from a stratified L-limit space to a stratified L-uniform convergence space. This structure induces L-continuous convergence. This shows that the category of all L-limit-uniformizable spaces is cartesian closed.
- Full Text:
- Authors: Jäger, Gunter
- Date: 2006
- Language: English
- Type: text , Article
- Identifier: vital:6824 , http://hdl.handle.net/10962/d1012332
- Description: We define a stratified L-uniform convergence structure on the set of all continuous mappings from a stratified L-limit space to a stratified L-uniform convergence space. This structure induces L-continuous convergence. This shows that the category of all L-limit-uniformizable spaces is cartesian closed.
- Full Text:
Launch of 'Popular Music and Censorship in Africa'
- Authors: Badat, Saleem
- Date: 2006 , 2014-06-12
- Language: English
- Type: Text
- Identifier: vital:7613 , http://hdl.handle.net/10962/d1011814
- Description: Address at the launch of 'Popular Music and Censorship in Africa', edited by Drewett, M and Cloonan, M.
- Full Text:
- Authors: Badat, Saleem
- Date: 2006 , 2014-06-12
- Language: English
- Type: Text
- Identifier: vital:7613 , http://hdl.handle.net/10962/d1011814
- Description: Address at the launch of 'Popular Music and Censorship in Africa', edited by Drewett, M and Cloonan, M.
- Full Text:
Leading strategic change: driving the transformation in the provision of legal services to the Eastern Cape Provincial government
- Authors: Beningfield, Perry Guy
- Date: 2006
- Subjects: Eastern Cape (South Africa) -- Politics and government Legal services -- South Africa -- Eastern Cape Organizational change Strategic planning Leadership
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:755 , http://hdl.handle.net/10962/d1003876
- Description: Effective change leadership is important to any organisation undergoing fundamental transformation. In particular, the ability of senior public sector leaders to successfully drive strategic change is crucial to meeting the developmental and service delivery challenges faced by the Province of the Eastern Cape in ensuring the effective, efficient and innovative government demanded by all its various stakeholders. The creation on 3 October of a Shared Legal Service situated in the Office of the Premier provided a unique opportunity to examine the leadership of this change initiative in the context of the organisational culture that existed in the provincial public service. This thesis consequently probes the phenomenon of effective change leadership by means of an examination of the understandings of the three change agents involved in driving the transformation of the provision of legal advisory services to the provincial administration and its constituent departments. The picture which emerges from the insights of the participants is one that casts a shadow over the validity of the contemporary theory of transformational leadership. Furthermore, the research conducted has identified the need to view the nature of effective change leadership through a more nuanced, situation-specific lens: one that appreciates the role of relationships and emotions, and that recognises the importance of culture and its impact on the success of organisational transformation. The case study of the Shared Legal Service change initiative provides useful insights into the many and varied challenges faced by public sector leaders in driving strategic transformation in the provincial administration. It offers an example of successful change leadership and demonstrates the need for change agents within the public service to harness more emotionally resonant and relational forms of leadership if they are to soar to new heights in meeting the service delivery expectations of all who look to provincial government to deliver the fruits of democracy.
- Full Text:
- Authors: Beningfield, Perry Guy
- Date: 2006
- Subjects: Eastern Cape (South Africa) -- Politics and government Legal services -- South Africa -- Eastern Cape Organizational change Strategic planning Leadership
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:755 , http://hdl.handle.net/10962/d1003876
- Description: Effective change leadership is important to any organisation undergoing fundamental transformation. In particular, the ability of senior public sector leaders to successfully drive strategic change is crucial to meeting the developmental and service delivery challenges faced by the Province of the Eastern Cape in ensuring the effective, efficient and innovative government demanded by all its various stakeholders. The creation on 3 October of a Shared Legal Service situated in the Office of the Premier provided a unique opportunity to examine the leadership of this change initiative in the context of the organisational culture that existed in the provincial public service. This thesis consequently probes the phenomenon of effective change leadership by means of an examination of the understandings of the three change agents involved in driving the transformation of the provision of legal advisory services to the provincial administration and its constituent departments. The picture which emerges from the insights of the participants is one that casts a shadow over the validity of the contemporary theory of transformational leadership. Furthermore, the research conducted has identified the need to view the nature of effective change leadership through a more nuanced, situation-specific lens: one that appreciates the role of relationships and emotions, and that recognises the importance of culture and its impact on the success of organisational transformation. The case study of the Shared Legal Service change initiative provides useful insights into the many and varied challenges faced by public sector leaders in driving strategic transformation in the provincial administration. It offers an example of successful change leadership and demonstrates the need for change agents within the public service to harness more emotionally resonant and relational forms of leadership if they are to soar to new heights in meeting the service delivery expectations of all who look to provincial government to deliver the fruits of democracy.
- Full Text:
Learning (dis)advantage in matriculation language classrooms
- Authors: Prinsloo, J
- Date: 2006
- Language: English
- Type: Book chapter
- Identifier: vital:529 , http://hdl.handle.net/10962/d1008479
- Description: During the first decade of democracy in South Africa formal education has been characterised by sweeping policy shifts and consequent curriculum revision. In many instances, curricular revisions are criticised for failing to effect desired or anticipated changes. In this chapter the focus is on the language curriculum and the associated practices, or what I refer to as the literacy practices that have become naturalised over decades and persist in the present. The argument that is presented here contends that to enable effective change, it is essential to understand better what has historically constituted literacy practices and to recognise their social, cultural and economic implications.
- Full Text:
- Authors: Prinsloo, J
- Date: 2006
- Language: English
- Type: Book chapter
- Identifier: vital:529 , http://hdl.handle.net/10962/d1008479
- Description: During the first decade of democracy in South Africa formal education has been characterised by sweeping policy shifts and consequent curriculum revision. In many instances, curricular revisions are criticised for failing to effect desired or anticipated changes. In this chapter the focus is on the language curriculum and the associated practices, or what I refer to as the literacy practices that have become naturalised over decades and persist in the present. The argument that is presented here contends that to enable effective change, it is essential to understand better what has historically constituted literacy practices and to recognise their social, cultural and economic implications.
- Full Text:
Learning about participation in integrated water resources management: A South African review
- Burt, Jane, du Toit, Derick, Neves, David, Pollard, Sharon
- Authors: Burt, Jane , du Toit, Derick , Neves, David , Pollard, Sharon
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433025 , vital:72924 , xlink:href="https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/TT293-06.pdf"
- Description: The National Water Act (1998) opens the way for ordinary people to take part in water resource management (WRM). This is a significant move towards a more social orientation and away from an approach that focused almost exclusively on the technical aspects of WRM. This set of two books asks what a social orientation means in practice. Since the National Water Act became law in 1998, how have WRM practitioners involved people in the process of managing water? What have we learnt so far? And how can we use these lessons to move forward? The content of the books is based on research that looked in some depth at national and local participatory practice in South Africa, and also broadly at international trends. The research was conducted by three WRM practitioners and two researchers in the field of participatory approaches.
- Full Text:
- Authors: Burt, Jane , du Toit, Derick , Neves, David , Pollard, Sharon
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433025 , vital:72924 , xlink:href="https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/TT293-06.pdf"
- Description: The National Water Act (1998) opens the way for ordinary people to take part in water resource management (WRM). This is a significant move towards a more social orientation and away from an approach that focused almost exclusively on the technical aspects of WRM. This set of two books asks what a social orientation means in practice. Since the National Water Act became law in 1998, how have WRM practitioners involved people in the process of managing water? What have we learnt so far? And how can we use these lessons to move forward? The content of the books is based on research that looked in some depth at national and local participatory practice in South Africa, and also broadly at international trends. The research was conducted by three WRM practitioners and two researchers in the field of participatory approaches.
- Full Text:
LibQUAL+™ at Rhodes University Library: an overview of the first South African implementation
- Authors: Moon, A E
- Date: 2006
- Language: English
- Type: Text
- Identifier: vital:6979 , http://hdl.handle.net/10962/d1012407
- Description: When Rhodes University Library closed its LibQUAL+™ survey on 29 August 2005, it became the first of seven university libraries in South Africa to complete this Web-based survey, which measures library users’ perceptions of service quality and identifies gaps between desired, perceived, and minimum expectations of service. This paper focuses on the Rhodes Library’s implementation of the 2005 LibQUAL+™ survey. Results are looked at within the broader context of aggregate scores and score norms from the South African cohort. The library’s first efforts to address areas where perceptions of service quality differed from users’ expectations are described and plans for future efforts are indicated. The paper also details some lessons learnt by other LibQUAL+™ participants, as documented in published case studies.
- Full Text:
- Authors: Moon, A E
- Date: 2006
- Language: English
- Type: Text
- Identifier: vital:6979 , http://hdl.handle.net/10962/d1012407
- Description: When Rhodes University Library closed its LibQUAL+™ survey on 29 August 2005, it became the first of seven university libraries in South Africa to complete this Web-based survey, which measures library users’ perceptions of service quality and identifies gaps between desired, perceived, and minimum expectations of service. This paper focuses on the Rhodes Library’s implementation of the 2005 LibQUAL+™ survey. Results are looked at within the broader context of aggregate scores and score norms from the South African cohort. The library’s first efforts to address areas where perceptions of service quality differed from users’ expectations are described and plans for future efforts are indicated. The paper also details some lessons learnt by other LibQUAL+™ participants, as documented in published case studies.
- Full Text:
Making sense of Men's Health: an investigation into the meanings men and women make of Men's Health
- Authors: McCance-Price, Maris
- Date: 2006
- Subjects: Men's Health (South Africa) , Men's magazines -- South Africa , Men in mass media , Women in mass media , Sex role in mass media , Men in popular culture , Women in popular culture , Mass media -- Social aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3464 , http://hdl.handle.net/10962/d1002919 , Men's Health (South Africa) , Men's magazines -- South Africa , Men in mass media , Women in mass media , Sex role in mass media , Men in popular culture , Women in popular culture , Mass media -- Social aspects
- Description: This study investigates the popular pleasures produced by readers of men's magazines, focusing primarily on the publication, Men's Health, which represents a new type of magazine catering for men. Using qualitative research methods such as textual analysis and reception analysis, the study explores the pleasures produced by both men and women from the consumption of such texts. The theoretical perspective of cultural studies informs this project, an approach that focuses on the generation and circulation of meanings in society. Focusing on the notion of the active audience and Hall's encoding/decoding model, this study examines readers' interpretations of the Men's Health text, focusing on the moment of consumption in the circuit of culture. Reception theory proposes the existence of "clustered readings" produced by interpretive communities that are socially rather than individually constructed. As a critical ethnography, the study interrogates these meanings with particular reference to questions of gender relations and power in society. Access to different discourses is structured by the social position of readers within relations of power and this study takes gender as a structuring principle. Therefore, this study also explores the particular discursive practices through which masculine and feminine imagery is produced by the Men's Health text and by its readers. The research findings support the more limited notion of the active audience espoused by theorists such as Hall (1980) offering further evidence to suggest that readers produce readings other than those preferred by the text and that therein lies the pleasure of the text for male and female readers. The research concludes that the popularity of Men's Health derives from the capacity of its readers to make multiple meanings of the text.
- Full Text:
- Authors: McCance-Price, Maris
- Date: 2006
- Subjects: Men's Health (South Africa) , Men's magazines -- South Africa , Men in mass media , Women in mass media , Sex role in mass media , Men in popular culture , Women in popular culture , Mass media -- Social aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3464 , http://hdl.handle.net/10962/d1002919 , Men's Health (South Africa) , Men's magazines -- South Africa , Men in mass media , Women in mass media , Sex role in mass media , Men in popular culture , Women in popular culture , Mass media -- Social aspects
- Description: This study investigates the popular pleasures produced by readers of men's magazines, focusing primarily on the publication, Men's Health, which represents a new type of magazine catering for men. Using qualitative research methods such as textual analysis and reception analysis, the study explores the pleasures produced by both men and women from the consumption of such texts. The theoretical perspective of cultural studies informs this project, an approach that focuses on the generation and circulation of meanings in society. Focusing on the notion of the active audience and Hall's encoding/decoding model, this study examines readers' interpretations of the Men's Health text, focusing on the moment of consumption in the circuit of culture. Reception theory proposes the existence of "clustered readings" produced by interpretive communities that are socially rather than individually constructed. As a critical ethnography, the study interrogates these meanings with particular reference to questions of gender relations and power in society. Access to different discourses is structured by the social position of readers within relations of power and this study takes gender as a structuring principle. Therefore, this study also explores the particular discursive practices through which masculine and feminine imagery is produced by the Men's Health text and by its readers. The research findings support the more limited notion of the active audience espoused by theorists such as Hall (1980) offering further evidence to suggest that readers produce readings other than those preferred by the text and that therein lies the pleasure of the text for male and female readers. The research concludes that the popularity of Men's Health derives from the capacity of its readers to make multiple meanings of the text.
- Full Text:
Managing South Africa's trawl bycatch
- Walmsley, Sarah A, Leslie, Rob W, Sauer, Warwick H H
- Authors: Walmsley, Sarah A , Leslie, Rob W , Sauer, Warwick H H
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124954 , vital:35713 , https://doi.10.1093/icesjms/fsl022
- Description: Over the past few decades, it has become widely recognized that the management strategies of world fisheries must ensure sustainability of bycatch as well as of target species. South Africa implemented a pilot observer programme from 1995 to 2000 to collect data on the levels and patterns of bycatch and discards in the demersal trawl fishery. Here, the results of that programme are used in conjunction with information on bycatch value and compliance to assess the issues and problems regarding bycatch and discarding in the fishery. In general, bycatch components can be placed into one of three categories (discarded bycatch, retained bycatch, and processing waste), each of which present different management problems and require different management approaches. The results were used to formulate a bycatch management plan for the demersal trawl fishery in South Africa. Given the need to continue monitoring bycatch, the performance of the pilot observer programme is reviewed, and the levels of sampling effort required for a national programme are discussed.
- Full Text:
- Authors: Walmsley, Sarah A , Leslie, Rob W , Sauer, Warwick H H
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124954 , vital:35713 , https://doi.10.1093/icesjms/fsl022
- Description: Over the past few decades, it has become widely recognized that the management strategies of world fisheries must ensure sustainability of bycatch as well as of target species. South Africa implemented a pilot observer programme from 1995 to 2000 to collect data on the levels and patterns of bycatch and discards in the demersal trawl fishery. Here, the results of that programme are used in conjunction with information on bycatch value and compliance to assess the issues and problems regarding bycatch and discarding in the fishery. In general, bycatch components can be placed into one of three categories (discarded bycatch, retained bycatch, and processing waste), each of which present different management problems and require different management approaches. The results were used to formulate a bycatch management plan for the demersal trawl fishery in South Africa. Given the need to continue monitoring bycatch, the performance of the pilot observer programme is reviewed, and the levels of sampling effort required for a national programme are discussed.
- Full Text:
Mapping Grahamstown's security governance network : prospects and problems for democratic policing
- Brereton, Catherine Margaret
- Authors: Brereton, Catherine Margaret
- Date: 2006
- Subjects: Democracy -- South Africa , Police -- South Africa , Police administration -- South Africa -- Grahamstown , Police-community relations -- South Africa -- Grahamstown , Crime prevention -- South Africa -- Grahamstown , Police patrol -- South Africa -- Grahamstown , Private security services -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2851 , http://hdl.handle.net/10962/d1006323 , Democracy -- South Africa , Police -- South Africa , Police administration -- South Africa -- Grahamstown , Police-community relations -- South Africa -- Grahamstown , Crime prevention -- South Africa -- Grahamstown , Police patrol -- South Africa -- Grahamstown , Private security services -- South Africa -- Eastern Cape
- Description: The security of its citizens is often regarded as the democratic state's primary raison d'etre. However, with increasing crime and perceptions of insecurity among citizens, along with actual and perceived state policing inadequacies, citizens around the world have sought to make alternative arrangements for their security. The explosion of private alternatives to state policing has resulted in the need for the replacement of former static definitions of policing by more fluid understandings of what policing entails. Policing is no longer an activity undertaken exclusively by the 'state police.' Policing needs to be understood within a framework which recognises the existence of a variety of state, commercial, community groups and individuals which exist within loose and sometimes informal, sometimes formal, networks to provide for the security of citizens. Preceding the country's transition to democracy in 1994 'state' policing in South Africa was aimed at monitoring and suppressing the black population and as a result it conducted itself in a largely militaristic way. When the government of national unity assumed power in 1994 it was indisputable that the South African Police had to undergo major reform if it was to play an effective, co-operative and accountable role in a democratic South Africa. While state policing has unquestionably undergone enormous changes since the advent of democracy in 1994, so too has non-state policing. It is widely accepted that the dividing line between state and non-state policing in South Africa is increasingly blurred. Policing, by its very nature, holds the potential to threaten democracy. Consequently it is important that policing is democratically controlled. According to the Law Commission of Canada four values and principles - justice, equality, accountability, and efficiency - should support policing in a democracy. This thesis is a case study of policing in Grahamstown, a small city in South Africa's Eastern Cape province. It will be shown that the policing problem that currently plagues Grahamstown, and by extension South Africa, is not simply the result of a shortage of providers but rather a problem of co-coordinating and monitoring security governance to ensure that the city does not further develop into a society where the wealthy have greater access to security than the poor.
- Full Text:
- Authors: Brereton, Catherine Margaret
- Date: 2006
- Subjects: Democracy -- South Africa , Police -- South Africa , Police administration -- South Africa -- Grahamstown , Police-community relations -- South Africa -- Grahamstown , Crime prevention -- South Africa -- Grahamstown , Police patrol -- South Africa -- Grahamstown , Private security services -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2851 , http://hdl.handle.net/10962/d1006323 , Democracy -- South Africa , Police -- South Africa , Police administration -- South Africa -- Grahamstown , Police-community relations -- South Africa -- Grahamstown , Crime prevention -- South Africa -- Grahamstown , Police patrol -- South Africa -- Grahamstown , Private security services -- South Africa -- Eastern Cape
- Description: The security of its citizens is often regarded as the democratic state's primary raison d'etre. However, with increasing crime and perceptions of insecurity among citizens, along with actual and perceived state policing inadequacies, citizens around the world have sought to make alternative arrangements for their security. The explosion of private alternatives to state policing has resulted in the need for the replacement of former static definitions of policing by more fluid understandings of what policing entails. Policing is no longer an activity undertaken exclusively by the 'state police.' Policing needs to be understood within a framework which recognises the existence of a variety of state, commercial, community groups and individuals which exist within loose and sometimes informal, sometimes formal, networks to provide for the security of citizens. Preceding the country's transition to democracy in 1994 'state' policing in South Africa was aimed at monitoring and suppressing the black population and as a result it conducted itself in a largely militaristic way. When the government of national unity assumed power in 1994 it was indisputable that the South African Police had to undergo major reform if it was to play an effective, co-operative and accountable role in a democratic South Africa. While state policing has unquestionably undergone enormous changes since the advent of democracy in 1994, so too has non-state policing. It is widely accepted that the dividing line between state and non-state policing in South Africa is increasingly blurred. Policing, by its very nature, holds the potential to threaten democracy. Consequently it is important that policing is democratically controlled. According to the Law Commission of Canada four values and principles - justice, equality, accountability, and efficiency - should support policing in a democracy. This thesis is a case study of policing in Grahamstown, a small city in South Africa's Eastern Cape province. It will be shown that the policing problem that currently plagues Grahamstown, and by extension South Africa, is not simply the result of a shortage of providers but rather a problem of co-coordinating and monitoring security governance to ensure that the city does not further develop into a society where the wealthy have greater access to security than the poor.
- Full Text:
Master of Education research portfolio
- Authors: Iitula, Helena
- Date: 2006
- Subjects: Education -- Namibia Curriculum planning -- Namibia Education and state -- Namibia Competency-based education -- Namibia Teachers -- Training of -- Namibia Education, Secondary -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1948 , http://hdl.handle.net/10962/d1008196
- Description: This Portfolio was submitted in 2005 to Rhodes University as a Research Portfolio presented in partial fulfilment of the requirements for the degree of Master of Education in General Education Theory and Practice. The Portfolio consists of seven (7) key parts. The reader of this Portfolio is courteously informed that the structure of this portfolio is to some extent differ from the thesis structure. Thus, the reader should be attentive not to weigh against the two. Further more, I hereby declare that this portfolio is my own work and that all the sources that I have used or quoted have been indicated and acknowledged by means of references indicated at the end of each part. Part 2 and 6 are the core parts of the portfolio. The focal point of part 2 is the contextual curriculum analysis of Grade 8-10 Oshindonga Curriculum in order to investigate its implementation in four educational circuits: Oshigambo, Onathinge, Onyaanya and Omuthiya in Oshikoto Region. Based on the findings of this analysis, lack of critical inquiry and reflective practice among Oshindonga teachers was identified as one of the major obstacles that preventing the effective implementation of the curriculum. Most of these teachers are Basic Education Teacher Diploma (BETD) postgraduates. Thus, part 3 and 4 were developed as supplements to inform the main research paper (part 6) which is related to teacher's professionalism in the classroom. The focus of part 3 (literature review) was on the teacher as a reflective practitioner. This is in line with the Namibian Education Policy, which identifies reflective practice as the heart of teacher professionalism. In this part, I explored a variety of views related to the notion of professionalism in teaching. I have also focused on views related to teacher's professional development both on macro and micro levels. These views provided a clarification and an underpinning framework on which to base my analysis of reflective practice as professionalism in education. Part 4 (education theories) focused on the digging of understanding of knowledge as an important theoretical domain of behaviourist and constructivist theories. I have tried to establish how the two theories (Behaviourist and Constructivist) view knowledge and its acquisition and to gain an understanding of how the two theories have been informing the practice. Subsequently, part 6 meant to investigate and assess the extent to which Basic Education Teacher Diploma postgraduate teachers are autonomously applying the theory of critical inquiry and reflective practice in the classroom. Both part 2 and 6 have findings. There is much correlation between the issues and problems in the implementation of the curriculum as identified in part 2 and the findings of the main research paper (part 6). Though critical inquiry and reflective practice is the key journey towards a high level of reflectivity and one of the significant characters of teacher professionalism in the classroom, most issues and problems identified were related to the insufficient practice of critical inquiry and reflective practices. Low correlation was found between critical inquiry and reflective practice theory and teachers' practices in the classroom. Despite to the fact that various rationales were mentioned as to why critical inquiry and reflective practice successful implementation is not taking place, the study positioned an emphasis on team working at school, cluster and circuit base that could contributed to a great extend to making teachers more competent and supporting themselves in mastering the applicable critical inquiry and reflective practice skills.
- Full Text:
- Authors: Iitula, Helena
- Date: 2006
- Subjects: Education -- Namibia Curriculum planning -- Namibia Education and state -- Namibia Competency-based education -- Namibia Teachers -- Training of -- Namibia Education, Secondary -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1948 , http://hdl.handle.net/10962/d1008196
- Description: This Portfolio was submitted in 2005 to Rhodes University as a Research Portfolio presented in partial fulfilment of the requirements for the degree of Master of Education in General Education Theory and Practice. The Portfolio consists of seven (7) key parts. The reader of this Portfolio is courteously informed that the structure of this portfolio is to some extent differ from the thesis structure. Thus, the reader should be attentive not to weigh against the two. Further more, I hereby declare that this portfolio is my own work and that all the sources that I have used or quoted have been indicated and acknowledged by means of references indicated at the end of each part. Part 2 and 6 are the core parts of the portfolio. The focal point of part 2 is the contextual curriculum analysis of Grade 8-10 Oshindonga Curriculum in order to investigate its implementation in four educational circuits: Oshigambo, Onathinge, Onyaanya and Omuthiya in Oshikoto Region. Based on the findings of this analysis, lack of critical inquiry and reflective practice among Oshindonga teachers was identified as one of the major obstacles that preventing the effective implementation of the curriculum. Most of these teachers are Basic Education Teacher Diploma (BETD) postgraduates. Thus, part 3 and 4 were developed as supplements to inform the main research paper (part 6) which is related to teacher's professionalism in the classroom. The focus of part 3 (literature review) was on the teacher as a reflective practitioner. This is in line with the Namibian Education Policy, which identifies reflective practice as the heart of teacher professionalism. In this part, I explored a variety of views related to the notion of professionalism in teaching. I have also focused on views related to teacher's professional development both on macro and micro levels. These views provided a clarification and an underpinning framework on which to base my analysis of reflective practice as professionalism in education. Part 4 (education theories) focused on the digging of understanding of knowledge as an important theoretical domain of behaviourist and constructivist theories. I have tried to establish how the two theories (Behaviourist and Constructivist) view knowledge and its acquisition and to gain an understanding of how the two theories have been informing the practice. Subsequently, part 6 meant to investigate and assess the extent to which Basic Education Teacher Diploma postgraduate teachers are autonomously applying the theory of critical inquiry and reflective practice in the classroom. Both part 2 and 6 have findings. There is much correlation between the issues and problems in the implementation of the curriculum as identified in part 2 and the findings of the main research paper (part 6). Though critical inquiry and reflective practice is the key journey towards a high level of reflectivity and one of the significant characters of teacher professionalism in the classroom, most issues and problems identified were related to the insufficient practice of critical inquiry and reflective practices. Low correlation was found between critical inquiry and reflective practice theory and teachers' practices in the classroom. Despite to the fact that various rationales were mentioned as to why critical inquiry and reflective practice successful implementation is not taking place, the study positioned an emphasis on team working at school, cluster and circuit base that could contributed to a great extend to making teachers more competent and supporting themselves in mastering the applicable critical inquiry and reflective practice skills.
- Full Text:
Maximum likelihood and Bayesian approaches to stock assessment when data are questionable
- Booth, Anthony J, Quinn II, T J
- Authors: Booth, Anthony J , Quinn II, T J
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6764 , http://hdl.handle.net/10962/d1007962
- Description: This study examines the use of age-structured maximum likelihood and Bayesian approaches for stock assessment of the Namibian monkfish, Lophius vomerinus, resource with questionable data, in which time series are short, abundance indices are variable, and research data conflict with commercial data. Bayesian approaches with both noninformative and informative priors are investigated to determine if they enhance estimation stability. Three data scenarios are assessed: commercial and research survey data, research survey data only, and commercial data only. Both statistical approaches show that resource abundance has decreased with exploitable biomass estimated at approximately 44% of pristine levels. The maximum likelihood and the Bayesian approach with noninformative priors result in similar estimates. As the abundance data contained little information pertaining to possible density dependence within the stock–recruit relationship, only a Bayesian approach with informative priors reduces uncertainty in the steepness parameter h. Estimated management quantities are sensitive both to the set of data sources and whether prior information was informative or not. The strengths of the Bayesian approach include the integration of prior information with uncertain data, the exploration of data conflicts, and the ability to show the uncertainty in estimates of management parameters. Its weakness is that estimation stability is dependent on the choice of priors, which alters some posterior distributions of management quantities.
- Full Text:
- Authors: Booth, Anthony J , Quinn II, T J
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6764 , http://hdl.handle.net/10962/d1007962
- Description: This study examines the use of age-structured maximum likelihood and Bayesian approaches for stock assessment of the Namibian monkfish, Lophius vomerinus, resource with questionable data, in which time series are short, abundance indices are variable, and research data conflict with commercial data. Bayesian approaches with both noninformative and informative priors are investigated to determine if they enhance estimation stability. Three data scenarios are assessed: commercial and research survey data, research survey data only, and commercial data only. Both statistical approaches show that resource abundance has decreased with exploitable biomass estimated at approximately 44% of pristine levels. The maximum likelihood and the Bayesian approach with noninformative priors result in similar estimates. As the abundance data contained little information pertaining to possible density dependence within the stock–recruit relationship, only a Bayesian approach with informative priors reduces uncertainty in the steepness parameter h. Estimated management quantities are sensitive both to the set of data sources and whether prior information was informative or not. The strengths of the Bayesian approach include the integration of prior information with uncertain data, the exploration of data conflicts, and the ability to show the uncertainty in estimates of management parameters. Its weakness is that estimation stability is dependent on the choice of priors, which alters some posterior distributions of management quantities.
- Full Text:
Media and cyber-democracy in Africa: an introduction
- Authors: Banda, Fackson
- Date: 2006
- Language: English
- Type: Conference paper
- Identifier: vital:6323 , http://hdl.handle.net/10962/d1008549
- Description: The paper provides a sketch of the discourse of media and ‘cyber-democracy’ in and out of Africa. Firstly, it discusses the characteristic features of new media technology. Secondly, it attempts a ‘theorising’ of cyber-democracy, within the context of general democratic theory. Thirdly, it sets out a vision of cyber-democracy for Africa. In delineating this vision, it highlights six features characteristic of the democratic potential of new media technology and gives examples of how Africa has appropriated them. Finally, it outlines a ‘new media’ research agenda for Africa.
- Full Text:
- Authors: Banda, Fackson
- Date: 2006
- Language: English
- Type: Conference paper
- Identifier: vital:6323 , http://hdl.handle.net/10962/d1008549
- Description: The paper provides a sketch of the discourse of media and ‘cyber-democracy’ in and out of Africa. Firstly, it discusses the characteristic features of new media technology. Secondly, it attempts a ‘theorising’ of cyber-democracy, within the context of general democratic theory. Thirdly, it sets out a vision of cyber-democracy for Africa. In delineating this vision, it highlights six features characteristic of the democratic potential of new media technology and gives examples of how Africa has appropriated them. Finally, it outlines a ‘new media’ research agenda for Africa.
- Full Text:
Media in the service of citizens
- Authors: Banda, Fackson
- Date: 2006
- Language: English
- Type: Conference paper
- Identifier: vital:6321 , http://hdl.handle.net/10962/d1008547
- Description: This lecture looks at the role of the media in promoting an enhanced citizenship, locating the debate within the discourse of development and freedom. It identifies threats to what can be characterised as a 'media-citizens compact', such as media over-commercialisation. It concludes that public-service media are cardinal to the enjoyment of citizenship rights and freedoms.
- Full Text:
- Authors: Banda, Fackson
- Date: 2006
- Language: English
- Type: Conference paper
- Identifier: vital:6321 , http://hdl.handle.net/10962/d1008547
- Description: This lecture looks at the role of the media in promoting an enhanced citizenship, locating the debate within the discourse of development and freedom. It identifies threats to what can be characterised as a 'media-citizens compact', such as media over-commercialisation. It concludes that public-service media are cardinal to the enjoyment of citizenship rights and freedoms.
- Full Text:
Media management training needs assessment within the SADC region : a qualitative study
- Milne, Claire, du Toit, Peter, Rau, Asta, Mdlongwa, Francis
- Authors: Milne, Claire , du Toit, Peter , Rau, Asta , Mdlongwa, Francis
- Date: 2006
- Language: English
- Type: Text
- Identifier: vital:7119 , http://hdl.handle.net/10962/d1012462
- Description: By exploring the views of editorial and business leaders in the media industry, the Sol Plaatje Institute for Media Leadership (SPI) aims to reach a comprehensive understanding of management training issues that are regarded as priorities by leaders in the SADC region. The Institute also aims to create a space for media organisations to share their experiences of management capacity building and explore avenues for future collaboration. It is envisaged that this report will form part of an ongoing dialogue on the needs of media leaders in the region. Representatives from the SPI, the Southern Africa Institute for Media Entrepreneurship Development (SAIMED), the Southern Africa Media Development Fund (SAMDEF) and the Southern African Media Training Trust (NSJ) met to advise the SPI on the industry’s key information needs. The research was then designed to focus on the identified needs. The research was conducted in three phases. In the first phase approximately 75 interviews were conducted with people holding diverse positions in a broad range of print and broadcast media institutions in Botswana, Malawi, Swaziland, Tanzania and Zambia. The second research phase comprised a workshop held for training providers and media professionals from the SADC region. Findings from the initial phase of the research were presented to workshop delegates for comment and debate. This allowed for the testing and triangulation of initial research findings. In response to comments by delegates, who thought that the research ought to have included countries where the lingua franca of business is not predominantly English, the study was extended to a second set of countries: Angola, Mozambique and the Democratic Republic of Congo. Interviews with 64 informants from this second set of countries constitutes the final phase of the research, Translators were used in this third phase, but other than that, there was a high degree of standardisation across all eight countries with the same methodological approach - including the selection of participants - being used in the first and third phases. As the research is predominantly qualitative, findings are context-specific and not generalisable. The overall impression portrayed by the study is a sense that media managers throughout the SADC region are struggling to overcome the constraints of having received little training other than that acquired in the workplace. There is also a sense that media leaders and managers thirst for the knowledge and skills that will enable them to continually improve and steer their organisations to success. The political and economic contexts of the research countries are, to differing extents, all problematic. Mozambique has the most liberal media climate out of all the countries researched and the Democratic Republic of Congo has the most repressed. But all of the countries suffer some degree of media repression, whether blatant or subtle. It is widely accepted that media plays a vital role in the development and mediation of democracy. With empowerment central to the democratic ethos, it is vital that media leaders and managers are themselves empowered to steer their organisations fairly, freely and effectively. This study contributes to the process by asking media professionals about their perceptions on what kinds of training their leaders and managers need and prefer so that training interventions can be appropriately targeted and designed. And so this research process serves to initiate what the Sol Plaatje Institute for Media Leadership foresees will be an ongoing collaboration with media industry leaders and managers in the SADC region: a cooperate effort to shape solutions to the considerable range of training and management capacity building needs revealed in this study. , Funded by the Netherlands Institute for Southern Africa (NIZA)
- Full Text:
- Authors: Milne, Claire , du Toit, Peter , Rau, Asta , Mdlongwa, Francis
- Date: 2006
- Language: English
- Type: Text
- Identifier: vital:7119 , http://hdl.handle.net/10962/d1012462
- Description: By exploring the views of editorial and business leaders in the media industry, the Sol Plaatje Institute for Media Leadership (SPI) aims to reach a comprehensive understanding of management training issues that are regarded as priorities by leaders in the SADC region. The Institute also aims to create a space for media organisations to share their experiences of management capacity building and explore avenues for future collaboration. It is envisaged that this report will form part of an ongoing dialogue on the needs of media leaders in the region. Representatives from the SPI, the Southern Africa Institute for Media Entrepreneurship Development (SAIMED), the Southern Africa Media Development Fund (SAMDEF) and the Southern African Media Training Trust (NSJ) met to advise the SPI on the industry’s key information needs. The research was then designed to focus on the identified needs. The research was conducted in three phases. In the first phase approximately 75 interviews were conducted with people holding diverse positions in a broad range of print and broadcast media institutions in Botswana, Malawi, Swaziland, Tanzania and Zambia. The second research phase comprised a workshop held for training providers and media professionals from the SADC region. Findings from the initial phase of the research were presented to workshop delegates for comment and debate. This allowed for the testing and triangulation of initial research findings. In response to comments by delegates, who thought that the research ought to have included countries where the lingua franca of business is not predominantly English, the study was extended to a second set of countries: Angola, Mozambique and the Democratic Republic of Congo. Interviews with 64 informants from this second set of countries constitutes the final phase of the research, Translators were used in this third phase, but other than that, there was a high degree of standardisation across all eight countries with the same methodological approach - including the selection of participants - being used in the first and third phases. As the research is predominantly qualitative, findings are context-specific and not generalisable. The overall impression portrayed by the study is a sense that media managers throughout the SADC region are struggling to overcome the constraints of having received little training other than that acquired in the workplace. There is also a sense that media leaders and managers thirst for the knowledge and skills that will enable them to continually improve and steer their organisations to success. The political and economic contexts of the research countries are, to differing extents, all problematic. Mozambique has the most liberal media climate out of all the countries researched and the Democratic Republic of Congo has the most repressed. But all of the countries suffer some degree of media repression, whether blatant or subtle. It is widely accepted that media plays a vital role in the development and mediation of democracy. With empowerment central to the democratic ethos, it is vital that media leaders and managers are themselves empowered to steer their organisations fairly, freely and effectively. This study contributes to the process by asking media professionals about their perceptions on what kinds of training their leaders and managers need and prefer so that training interventions can be appropriately targeted and designed. And so this research process serves to initiate what the Sol Plaatje Institute for Media Leadership foresees will be an ongoing collaboration with media industry leaders and managers in the SADC region: a cooperate effort to shape solutions to the considerable range of training and management capacity building needs revealed in this study. , Funded by the Netherlands Institute for Southern Africa (NIZA)
- Full Text:
Medicines information and adherence in HIV/AIDS patients
- Mansoor, Leila E, Dowse, Roslind
- Authors: Mansoor, Leila E , Dowse, Roslind
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6395 , http://hdl.handle.net/10962/d1006319
- Description: Background: Providing written medicines information is being legislated in an increasing number of countries worldwide, with the patient information leaflet (PIL) being the most widely used method for conveying health information. The impact of providing such information on adherence to therapy is reportedly unpredictable. Therapy for human immunodeficiency virus/acquired immune deficiency syndrome (HIV/AIDS) and related opportunistic infections usually involves polytherapy and complex regimens, both of which are risk factors for non-adherence. The objective of this study was to assess the impact of medicines information on adherence to chronic co-trimoxazole therapy in low-literate HIV/AIDS patients. Methods: Two different PILs were designed for co-trimoxazole tablets and were available in both English and isiXhosa. Participants were randomly allocated to a control group (receiving no PIL), group A (receiving a 'complex PIL') and group B (receiving a 'simple PIL' incorporating pictograms). At the first interview, demographic data were collected and the time, date and day that the participant would take his/her first tablet of the month's course was also documented. In a follow-up interview adherence to therapy was assessed using two methods; self-report and tablet count. Results: The medicines information materials incorporating simple text and pictograms resulted in significantly improved adherence to therapy in the short term, whereas a non-significant increase in adherence was associated with the availability of the more complex information. This was shown by both the self-reported assessment as well as the tablet count. Conclusion: This research suggests that appropriately designed written material can have a positive impact in improving adherence and, together with verbal consultation, are essential for enabling patients to make appropriate decisions about their medicine taking.
- Full Text:
- Authors: Mansoor, Leila E , Dowse, Roslind
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6395 , http://hdl.handle.net/10962/d1006319
- Description: Background: Providing written medicines information is being legislated in an increasing number of countries worldwide, with the patient information leaflet (PIL) being the most widely used method for conveying health information. The impact of providing such information on adherence to therapy is reportedly unpredictable. Therapy for human immunodeficiency virus/acquired immune deficiency syndrome (HIV/AIDS) and related opportunistic infections usually involves polytherapy and complex regimens, both of which are risk factors for non-adherence. The objective of this study was to assess the impact of medicines information on adherence to chronic co-trimoxazole therapy in low-literate HIV/AIDS patients. Methods: Two different PILs were designed for co-trimoxazole tablets and were available in both English and isiXhosa. Participants were randomly allocated to a control group (receiving no PIL), group A (receiving a 'complex PIL') and group B (receiving a 'simple PIL' incorporating pictograms). At the first interview, demographic data were collected and the time, date and day that the participant would take his/her first tablet of the month's course was also documented. In a follow-up interview adherence to therapy was assessed using two methods; self-report and tablet count. Results: The medicines information materials incorporating simple text and pictograms resulted in significantly improved adherence to therapy in the short term, whereas a non-significant increase in adherence was associated with the availability of the more complex information. This was shown by both the self-reported assessment as well as the tablet count. Conclusion: This research suggests that appropriately designed written material can have a positive impact in improving adherence and, together with verbal consultation, are essential for enabling patients to make appropriate decisions about their medicine taking.
- Full Text:
Message to Goedgedacht Forum
- Authors: Badat, Saleem
- Date: 2006 , 2014-06-12
- Subjects: Goedgedact Forum for Social Reflection
- Language: English
- Type: Text
- Identifier: vital:7605 , http://hdl.handle.net/10962/d1011800
- Description: Message from Dr Saleem Badat to the Goedgedacht Forum for Social Development in regards to the forum's 10th annivisary celebrations.
- Full Text:
- Authors: Badat, Saleem
- Date: 2006 , 2014-06-12
- Subjects: Goedgedact Forum for Social Reflection
- Language: English
- Type: Text
- Identifier: vital:7605 , http://hdl.handle.net/10962/d1011800
- Description: Message from Dr Saleem Badat to the Goedgedacht Forum for Social Development in regards to the forum's 10th annivisary celebrations.
- Full Text:
Metathesis catalysts : an integrated computational, mechanistic and synthetic study
- Authors: Sabbagh, Ingrid Theresa
- Date: 2006
- Subjects: Metathesis (Chemistry) Catalysis Metal catalysts Chemical kinetics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4397 , http://hdl.handle.net/10962/d1006208
- Description: An integrated approach to the design of potential rutheniun-based metathesis catalysts is described, in which closely defined synthetic forays provide the focus and rationale for detailed computational and mechanistic studies. The ground-state geometry of a 1st-generation Grubbs catalyst has been explored at the molecular mechanics, semi-empirical and DFT levels, and the resulting structures have been shown to compare favourably with literature data and with the structure of a known crystalline analogue. The DMol³ DFT code has also been shown to represent accurately both the geometry of the corresponding co-ordinatively unsaturated monophosphine derivative, and the ligand dissociation energy associated with its formation. A DFT free-energy profile of the degenerate metathesis of ethylene has been generated, using a truncated model of the 1st-generation Grubbs catalyst, permitting location, for the first time, of the three expected transition states and providing new information regarding the rate-determining step. DFT methods have been used to facilitate the design of a tridentate camphor-derived ligand for use in the construction of a novel Grubbs-type catalyst. The phosphine ligand dissociation energy of the putative catalyst and the ethylene metathesis energy profile of a truncated model have also been studies at the DFT level. The attempted synthesis of the proposed ligand proceeded via a novel 8-bromocamphoric anhydride intermediate and afforded several unexpected and novel products, including a cisfused γ-Iactone, and a bromo camphoric acid derivative. Single crystal X-ray analysis of the latter reveals a chiral, polymeric H-bonded packing arrangement, rendering it suitable for chiral inclusion studies. Computational methods, including the GAUSSIAN-based GIAO NMR prediction technique, were used to support the structural characterisation of the novel camphor derivatives. DFT-Ievel computational analysis of the C-8- and C-9 bromination of camphor has afforded theoretical insights which permit the reconciliation of two earlier empirical explanations regarding the regioselectivity of these transformations; moreover, the theoretical results suggest that a third, previously disregarded factor, plays a significant role. A coset analysis, in conjunction with DFT-Ievel energy profiling, has also been used to resolve conflicting opinions regarding the origin of the major byproduct. Computed electronic parameters (CEP's) have been calculated for the anionic ligands involved in a series of 2nd-generation Grubbs-Hoveyda-type catalysts, and used to explain some apparently anomalous trends in catalyst activity. A linear relationship between ligand CEP's and selected ¹H NMR chemical shifts has also been demonstrated and used to identify a transient ruthenium complex in solution. The ability of the malonate di-anion to bind to ruthenium in a bidentate manner has been explored and demonstrated, under suitable conditions. DFT methods have been used to design and assess the ruthenium-chelating potential of a novel tridentate malonate derivative. A synthetic pathway to this ligand has been designed and several novel heterocyclic intermediates have been isolated and characterised. An NMR-based kinetic study of the Grubbs-catalysed self-metathesis of l-octene has been completed, and the effects of temperature, concentration and solvent variations on the kinetic parameters have been studied. Application of the Guggenheim method and a simplified mechanistic model has permitted the accurate calculation of pseudorate constants for the initiation and, for the first time, the propagation phase of the reaction. Theoretical studies of this reaction at the DFT and molecular mechanics levels have been shown to support previous assumptions regarding the selectivity and temperature-dependence of metallacycle formation.
- Full Text:
- Authors: Sabbagh, Ingrid Theresa
- Date: 2006
- Subjects: Metathesis (Chemistry) Catalysis Metal catalysts Chemical kinetics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4397 , http://hdl.handle.net/10962/d1006208
- Description: An integrated approach to the design of potential rutheniun-based metathesis catalysts is described, in which closely defined synthetic forays provide the focus and rationale for detailed computational and mechanistic studies. The ground-state geometry of a 1st-generation Grubbs catalyst has been explored at the molecular mechanics, semi-empirical and DFT levels, and the resulting structures have been shown to compare favourably with literature data and with the structure of a known crystalline analogue. The DMol³ DFT code has also been shown to represent accurately both the geometry of the corresponding co-ordinatively unsaturated monophosphine derivative, and the ligand dissociation energy associated with its formation. A DFT free-energy profile of the degenerate metathesis of ethylene has been generated, using a truncated model of the 1st-generation Grubbs catalyst, permitting location, for the first time, of the three expected transition states and providing new information regarding the rate-determining step. DFT methods have been used to facilitate the design of a tridentate camphor-derived ligand for use in the construction of a novel Grubbs-type catalyst. The phosphine ligand dissociation energy of the putative catalyst and the ethylene metathesis energy profile of a truncated model have also been studies at the DFT level. The attempted synthesis of the proposed ligand proceeded via a novel 8-bromocamphoric anhydride intermediate and afforded several unexpected and novel products, including a cisfused γ-Iactone, and a bromo camphoric acid derivative. Single crystal X-ray analysis of the latter reveals a chiral, polymeric H-bonded packing arrangement, rendering it suitable for chiral inclusion studies. Computational methods, including the GAUSSIAN-based GIAO NMR prediction technique, were used to support the structural characterisation of the novel camphor derivatives. DFT-Ievel computational analysis of the C-8- and C-9 bromination of camphor has afforded theoretical insights which permit the reconciliation of two earlier empirical explanations regarding the regioselectivity of these transformations; moreover, the theoretical results suggest that a third, previously disregarded factor, plays a significant role. A coset analysis, in conjunction with DFT-Ievel energy profiling, has also been used to resolve conflicting opinions regarding the origin of the major byproduct. Computed electronic parameters (CEP's) have been calculated for the anionic ligands involved in a series of 2nd-generation Grubbs-Hoveyda-type catalysts, and used to explain some apparently anomalous trends in catalyst activity. A linear relationship between ligand CEP's and selected ¹H NMR chemical shifts has also been demonstrated and used to identify a transient ruthenium complex in solution. The ability of the malonate di-anion to bind to ruthenium in a bidentate manner has been explored and demonstrated, under suitable conditions. DFT methods have been used to design and assess the ruthenium-chelating potential of a novel tridentate malonate derivative. A synthetic pathway to this ligand has been designed and several novel heterocyclic intermediates have been isolated and characterised. An NMR-based kinetic study of the Grubbs-catalysed self-metathesis of l-octene has been completed, and the effects of temperature, concentration and solvent variations on the kinetic parameters have been studied. Application of the Guggenheim method and a simplified mechanistic model has permitted the accurate calculation of pseudorate constants for the initiation and, for the first time, the propagation phase of the reaction. Theoretical studies of this reaction at the DFT and molecular mechanics levels have been shown to support previous assumptions regarding the selectivity and temperature-dependence of metallacycle formation.
- Full Text: