Phase equilibria in three component systems alcohol-hydrocarbon-water
- Authors: Siswana, Msimelelo Patrick
- Date: 1992
- Subjects: Chemical equilibrium , Liquid-liquid equilibrium , Alcohol as fuel , Hydrocarbons , Water chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4327 , http://hdl.handle.net/10962/d1004988 , Chemical equilibrium , Liquid-liquid equilibrium , Alcohol as fuel , Hydrocarbons , Water chemistry
- Description: The fuel industry in many parts of the world is blending alcohols with motor fuel either to extend the fuel or to improve its octane rating or both. Unfortunately alcohols are hygroscopic and as a result, water becomes a component of the fuel. This can lead to phase separation and the formation of a water-rich layer which could have serious corrosion consequences. In an attempt to understand the phase-splitting in alcohol-petrol-water blends, phase equilibria in ternary systems (alcohol-hydrocarbon-water) have been determined by experiment. The phase equilibria in these ternary systems are also discussed in terms of modern theories of liquid mixtures and the UNIQUAC theory is applied to the "ethanol + benzene + water" ternary system. The alcohols are all the C₁, C₂, C₃ and C₄ alcohols, and the hydrocarbons include those typically found in petrol, e.g. cyclohexane, benzene and substituted benzenes.
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The hydrogeology and hydrogeochemisty of the aquifers of the Hex River Valley, Cape Province
- Authors: Rosewarne, Peter Nigel
- Date: 1984 , 2013-04-11
- Subjects: Hydrogeology , Aquifers , Water chemistry , Hydrogeology -- South Africa -- Cape Colony
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4863 , http://hdl.handle.net/10962/d1007224 , Hydrogeology , Aquifers , Water chemistry , Hydrogeology -- South Africa -- Cape Colony
- Description: The Hex River Valley is one of the main centres in South Africa for cultivation of table grapes of export quality. The vines require irrigation water, which must be low in dissolved solids. Approximately two thirds of the annual irrigation requirement is obtained from boreholes and the balance from surface water sources. During the early 1960s a deterioration in the quality of the groundwater was noticed, becoming critical in some areas, and borehole yields also declined. The main objectives of this study were therefore to obtain an understanding of the hydrogeological and hydrogeochemical processes operating in the valley to explain the derogation of the groundwater resource and enable optimum utilisation and management of the resource in the future. To achieve these objectives, field work involving exploration drilling, aquifer tests, hydrocensus, long-term monitoring of groundwater levels and surfacewater flows and extensive sampling of the ground and surface waters was carried out. Analysis of these data gave quantitative information on groundwater occurrence, aquifer hydraulic properties, groundwater recharge and storage, chemical characteristics of the ground and surfacewaters and sources of dissolved species. , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
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