- Title
- 1H NMR-based kinetic and mechanistic study of unusual skeletal rearrangements of a spirobornyl tosylate derivative
- Creator
- Lobb, Kevin A, Kaye, Perry T
- Subject
- To be catalogued
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/448858
- Identifier
- vital:74766
- Identifier
- xlink:href="https://doi.org/10.1002/poc.1699"
- Description
- 1H NMR analysis of the kinetics of skeletal rearrangement of optically pure 3,3-xylyl-2-exo-bornyl tosylate in CDCl3 indicates the operation of tandem autocatalytic and pseudo-first-order transformations, leading sequentially to a pairof isomeric camphene derivatives and involving partial racemization. Changing the solvent system has been shown topermit the chemoselective isolation of either of the isomeric camphenes.
- Format
- computer, online resource, application/pdf, 1 online resource (7 pages), pdf
- Publisher
- Wiley
- Language
- English
- Relation
- Journal of Physical Organic Chemistry, Lobb, K.A. and Kaye, P.T., 2011. 1H NMR-based kinetic and mechanistic study of unusual skeletal rearrangements of a spirobornyl tosylate derivative. Journal of Physical Organic Chemistry, 24(1), pp.38-44, Journal of Physical Organic Chemistry volume 24 number 1 p. 38 2011 1099-1395
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Wiley Library Online Terms of Use Statement (https://onlinelibrary.wiley.com/terms-and-conditions)
- Rights
- Closed Access
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- Visitors: 85
- Downloads: 7
Collections
Lobb, Kevin Allan (Assoc Prof)
Kaye, Perry T (Distinguished Fellow Emeritus Professor)
RU Department of Chemistry
SDG 03. Good Health and Well-Being
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details | SOURCE1 | 1H NMR‐based kinetic and mechanistic study of unusual skeletal rearrangements of a spirobornyl tosylate derivative.pdf | 633 KB | Adobe Acrobat PDF | View Details |