- Title
- Enhanced Optical Limiting Behavior of an Indium Phthalocyanine–Single-Walled Carbon Nanotube Composite
- Creator
- Sanusi, Kayode, Amuhaya, Edith K, Nyokong, Tebello
- Subject
- To be catalogued
- Date
- 2014
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/193871
- Identifier
- vital:45401
- Identifier
- xlink:href="https://doi.org/10.1021/jp501469e "
- Description
- The nonlinear optical behavior of 2(3),9(10),16(17),23(24)-tetrakis-(4-aminophenoxy) phthalocyaninato indium (III) chloride (2) and its carbon nanotube composite in dimethylsulfoxide (DMSO) and dimethylformamide (DMF) solutions is described. The nonlinear third-order susceptibility and second-order hyperpolarizability values are also reported. A large nonlinear absorption that increased on covalent linking with single-walled carbon nanotubes (SWCNTs) was observed for the compound in DMSO. The nanosecond nonlinear absorption and the optical limiting behavior of this complex are shown to be dominated by a strong excited state absorption from a two-photon pumped state. The optical limiter using the new nanocomposite material (SWCNT-2) in the appropriate solvent showed a much lower threshold for optical limiting together with a much lower transmission at high fluences than previously reported nanocomposite limiters. The optical properties of the phthalocyanine and its conjugate were found to show high sensitivity toward the change of solvent matrix.
- Format
- computer, online resource, application/pdf, 1 online resource (13 pages), pdf
- Publisher
- ACS Publications
- Language
- English
- Relation
- The Journal of Chemistry C, Sanusi, K., Amuhaya, E.K. and Nyokong, T., 2014. Enhanced Optical Limiting Behavior of an Indium Phthalocyanine–Single-Walled Carbon Nanotube Composite: An Investigation of the Effects of Solvents. The Journal of Physical Chemistry C, 118(13), pp.7057-7069, The Journal of Chemistry C volume 118 number 13 p. 7057 2014 1932-7455
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the ACS Publications Terms of Use Statement (https://0-www.acs.org.wam.seals.ac.za/content/acs/en/terms.html)
- Rights
- Closed Access
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Collections
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
Nyokong, Tebello (Distinguished Professor)
RU Department of Chemistry
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|---|---|---|---|---|---|---|---|
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