An investigative case study of the introduction of democratic decision-making within an East London secondary school
- Authors: Carelse, Garth Craig
- Date: 2000
- Subjects: School management and organization -- South Africa Decision making -- Cast studies Education and state Ebenezer Majombozi High
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1920 , http://hdl.handle.net/10962/d1007404
- Description: The move towards greater democracy and participation in our education system is legislated quite succinctly in our South African Schools Act. The Act furthermore, and more importantly for this case study, posits that decision-making should be democratic in nature and our schools should eventually become governed in a collaborative and co-operative manner. Other policy texts such as the Labour Relations Act and the South African Constitution canonise the demand for a democratic South African society. This study investigates how democratic decision-making practices are taking place in an East London Secondary School namely Ebenezer Majombozi High. Even though distinct links exist between management and governance arms of schools, this study concentrates predominantly on decision-making within the school governing body and touches briefly on management thinking trends as a theoretical background to the kind of management at the school. What makes the school interesting as a case study is its rich history and its location in a deprived and impoverished township environment. The school was also part of the ex-Department of Education and Training, the black educational department of the past apartheid state. The kind of research undertaken was in the form of unstructured personal interviews with influential stakeholders at the school. Some of these stakeholders fonn part of the school governing body and the questions asked probed forms of governance at the school and how decision-making impacted on the overall school governance. The research findings acknowledges that decision-making does occur democratically at the school but that the practical implementation of positive consensual decisions are rarely realized. The school governing body only meets to deal with crises underpinned by a lack of learning and teaching and has not even debated the policies within the South African Schools Act. The study also argues that only by building capacity within the school and empowering the stakeholders, can constructive participation by all become a reality.
- Full Text:
- Authors: Carelse, Garth Craig
- Date: 2000
- Subjects: School management and organization -- South Africa Decision making -- Cast studies Education and state Ebenezer Majombozi High
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1920 , http://hdl.handle.net/10962/d1007404
- Description: The move towards greater democracy and participation in our education system is legislated quite succinctly in our South African Schools Act. The Act furthermore, and more importantly for this case study, posits that decision-making should be democratic in nature and our schools should eventually become governed in a collaborative and co-operative manner. Other policy texts such as the Labour Relations Act and the South African Constitution canonise the demand for a democratic South African society. This study investigates how democratic decision-making practices are taking place in an East London Secondary School namely Ebenezer Majombozi High. Even though distinct links exist between management and governance arms of schools, this study concentrates predominantly on decision-making within the school governing body and touches briefly on management thinking trends as a theoretical background to the kind of management at the school. What makes the school interesting as a case study is its rich history and its location in a deprived and impoverished township environment. The school was also part of the ex-Department of Education and Training, the black educational department of the past apartheid state. The kind of research undertaken was in the form of unstructured personal interviews with influential stakeholders at the school. Some of these stakeholders fonn part of the school governing body and the questions asked probed forms of governance at the school and how decision-making impacted on the overall school governance. The research findings acknowledges that decision-making does occur democratically at the school but that the practical implementation of positive consensual decisions are rarely realized. The school governing body only meets to deal with crises underpinned by a lack of learning and teaching and has not even debated the policies within the South African Schools Act. The study also argues that only by building capacity within the school and empowering the stakeholders, can constructive participation by all become a reality.
- Full Text:
Application of the Minolta chromameter to the assessment of corticosteroid-induced skin blanching
- Walker, Roderick B, Haigh, John M, Smith, Eric W
- Authors: Walker, Roderick B , Haigh, John M , Smith, Eric W
- Date: 2000
- Language: English
- Type: Book chapter , text
- Identifier: vital:6451 , http://hdl.handle.net/10962/d1006639
- Full Text:
- Authors: Walker, Roderick B , Haigh, John M , Smith, Eric W
- Date: 2000
- Language: English
- Type: Book chapter , text
- Identifier: vital:6451 , http://hdl.handle.net/10962/d1006639
- Full Text:
Aspects of reproduction in the four-striped field mouse, Rhabdomys pumilio
- Authors: Jackson, Claire
- Date: 2000
- Subjects: Microtus , Mice , Mice -- Reproduction
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5637 , http://hdl.handle.net/10962/d1005319 , Microtus , Mice , Mice -- Reproduction
- Description: Rhabdomys pumilio, in the Eastern Cape of South Africa, does not use short day length as an inhibitory cue for reproductive activity, and, despite previous records indicating that these mice are strictly seasonal in their reproduction, litters have been found during the winters of some years,both in the Eastern Cape and in the Western Cape. This led me to believe that the reproductive activity of Rhabdomys pumilio is more opportunistic and that the cue or cues used to control reproduction are less predictable and, or more variable than the photoperiod cue used by many seasonally reproducing rodents. Two experiments were conducted, investigating the influence of low ambient temperature (15⁰C)and reduced food availability on the reproductive activity of both male and female four striped field mice. Mice were maintained in one of four conditions (food restricted at 15⁰C, food restricted at 26⁰C, ad lib. food at 15⁰C, and ad lib. food at 26⁰C) for 4 (males) and 8 weeks (females)(photoperiod 12L:12D, humidity 40%). Results indicated that the males reduced their reproductive activity slightly when exposed to either low temperature or low food availability and that maximum inhibition of reproduction occurred when mice were exposed to both low temperature and low food availability. However, female reproductive activity was inhibited when exposed to low food availability, irrespective of the temperature. Both sexes of mice showed varying abilities to resist fat loss and, in the males, the size of the fat store had a significant effect on reproduction. This varying ability to resist fat loss could be related to levels of activity and in the females (where activity was quantified), high activity scores were significantly associated with reproductive inhibition. These results support the hypothesis that reproduction in Rhabdomys pumilio is opportunistic and controlled by the availability of energy. I propose that the females will be more sensitive to reproductive inhibition due to their far greater post-fertilization responsibilities, where the reproductive activity of the females is rapidly inhibited by a reduction in food availability, while the males are less readily inhibited by low food availability or low temperature, unless the change in the controlling factors is severe enough, or prolonged, at which stage their reproductive activity will cease. The significance of opportunistic reproduction in the seasonal but unpredictable climate of the study area is discussed.
- Full Text:
- Authors: Jackson, Claire
- Date: 2000
- Subjects: Microtus , Mice , Mice -- Reproduction
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5637 , http://hdl.handle.net/10962/d1005319 , Microtus , Mice , Mice -- Reproduction
- Description: Rhabdomys pumilio, in the Eastern Cape of South Africa, does not use short day length as an inhibitory cue for reproductive activity, and, despite previous records indicating that these mice are strictly seasonal in their reproduction, litters have been found during the winters of some years,both in the Eastern Cape and in the Western Cape. This led me to believe that the reproductive activity of Rhabdomys pumilio is more opportunistic and that the cue or cues used to control reproduction are less predictable and, or more variable than the photoperiod cue used by many seasonally reproducing rodents. Two experiments were conducted, investigating the influence of low ambient temperature (15⁰C)and reduced food availability on the reproductive activity of both male and female four striped field mice. Mice were maintained in one of four conditions (food restricted at 15⁰C, food restricted at 26⁰C, ad lib. food at 15⁰C, and ad lib. food at 26⁰C) for 4 (males) and 8 weeks (females)(photoperiod 12L:12D, humidity 40%). Results indicated that the males reduced their reproductive activity slightly when exposed to either low temperature or low food availability and that maximum inhibition of reproduction occurred when mice were exposed to both low temperature and low food availability. However, female reproductive activity was inhibited when exposed to low food availability, irrespective of the temperature. Both sexes of mice showed varying abilities to resist fat loss and, in the males, the size of the fat store had a significant effect on reproduction. This varying ability to resist fat loss could be related to levels of activity and in the females (where activity was quantified), high activity scores were significantly associated with reproductive inhibition. These results support the hypothesis that reproduction in Rhabdomys pumilio is opportunistic and controlled by the availability of energy. I propose that the females will be more sensitive to reproductive inhibition due to their far greater post-fertilization responsibilities, where the reproductive activity of the females is rapidly inhibited by a reduction in food availability, while the males are less readily inhibited by low food availability or low temperature, unless the change in the controlling factors is severe enough, or prolonged, at which stage their reproductive activity will cease. The significance of opportunistic reproduction in the seasonal but unpredictable climate of the study area is discussed.
- Full Text:
Aspects of the ecology and reproductive biology of the limpet, Helcion pruinosus (Gastropoda : prosobranchia)
- Authors: Henninger, Tony Oskar
- Date: 2000
- Subjects: Prosobranchia , Limpets -- Reproduction , Limpets -- Ecology , Prosobranchia -- Ecology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5641 , http://hdl.handle.net/10962/d1005323 , Prosobranchia , Limpets -- Reproduction , Limpets -- Ecology , Prosobranchia -- Ecology
- Description: Helcion pruinosus, the rayed limpet, is found in the midshore region of the intertidal zone, (i.e. the Balanoid zone) of rocky shores, from Saldanha Bay to Sodwana Bay along the coast of South Africa. At Gonubie (32°57'S/25°01'E) this species of limpet was found under boulders, (when not feeding), and could reach average densities of 85/ m². The limpets prefer smooth boulders, avoiding those encrusted by coralline algae or boulders with a rough texture. There was no habitat segregation between adult and juvenile H. pruinosus, i.e. there was no sign of up-shore migration by larger individuals. Males out-numbered females by, on average 1.4 : 1, which was a similar sex ratio to that of the congeneric species, H. pectunculus (Gray, 996). Unlike H. pectunculus, there were no differences in shell lengths between males and females (p = 0.946 at Gonubie, south-east coast and p = 0.961 at Kommetjie, south-west coast; t-test). Shell height could also not be used as a criterion to differentiate between the sexes. The average maximum shell length of H. pruinosus at Gonubie and Kommetjie was 25 mm, but the maximum shell lengths found were 30 mm, (one individual in each case), on both the southeast coast and west coast. Growth occurred most rapidly in the first year of life, with individuals reaching 15 mm after 1 year. In the second year limpet growth slowed to only 7 mm. Sexual maturity was reached at a shell length of between 11 to 14 mm (at an age of 8 months to 1 year). The life-span of H. pruinosus was determined at 2.55 years on the south-east coast and 2.9 years on the south-west coast. Micro-growth bands were produced tidally. Growth occurred allometrically, i.e. shell length increased at a faster rate than shell height. The limpets foraged during low tide, at night, presumably feeding on epilithic algae on the boulders. A second smaller peak of limpet activity was often recorded during the day, when low tide coincided with dawn). More limpets (up to ten times more) were active at spring tides compared to neap tides. Limpet activity was greatest during the spring tides of autumn. During all seasons limpet activity peaked 30 minutes before low water, after which numbers decreased rapidly. All limpets had retreated beneath the boulders before being covered by the flooding tide. It was concluded that the limpets were responding to both endogenous and exogenous cues, but the actual stimulus for retreat could not be determined. The limpets did not return to a fixed scar nor did they return rigidly to a home site. H. pruinosus was found to be gonochoristic. Sexes could be separated, on dissection, according to the colour of their gonads (males had white gonads, whilst that of the females was olive-green). Gonads were present throughout the year in most individuals, i.e. totally spent animals were never observed. Reproductive seasonality was similar in west coast and south-east coast animals. The gonad indices of the west coast limpets were higher, (maximum of 35%), compared to that on the southeast coast, (25%). The animals were probably trickle spawners, with some individuals liberating gametes throughout the year. There was however synchrony in gametogenesis between male and female limpets on both the west coast and south-east coast lines. Gonad indices peaked in the summer months (October to December) with a second minor peak in April/May. These peaks occurred before the release of the gametes in spawning events. The gonad index was lowest in winter, (July). The ovaries were full of mature eggs (oocytes having a diameter of 200 to 250 ~) prior to spawning. The acinal wall thickness had been decreasing prior to spawning. After spawning there was an increase in previtellogenic eggs « 100 μm) in females, and an increase in the acinal wall thickness to indicate spermatogenesis. The two populations are subjected to different environmental conditions and the actual cue for stimulating the release of gametes could not be determined. Finally, a table of differences between H pruinosus and its sister species, H pectunculus was created to show the life-style of H pruinosus.
- Full Text:
- Authors: Henninger, Tony Oskar
- Date: 2000
- Subjects: Prosobranchia , Limpets -- Reproduction , Limpets -- Ecology , Prosobranchia -- Ecology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5641 , http://hdl.handle.net/10962/d1005323 , Prosobranchia , Limpets -- Reproduction , Limpets -- Ecology , Prosobranchia -- Ecology
- Description: Helcion pruinosus, the rayed limpet, is found in the midshore region of the intertidal zone, (i.e. the Balanoid zone) of rocky shores, from Saldanha Bay to Sodwana Bay along the coast of South Africa. At Gonubie (32°57'S/25°01'E) this species of limpet was found under boulders, (when not feeding), and could reach average densities of 85/ m². The limpets prefer smooth boulders, avoiding those encrusted by coralline algae or boulders with a rough texture. There was no habitat segregation between adult and juvenile H. pruinosus, i.e. there was no sign of up-shore migration by larger individuals. Males out-numbered females by, on average 1.4 : 1, which was a similar sex ratio to that of the congeneric species, H. pectunculus (Gray, 996). Unlike H. pectunculus, there were no differences in shell lengths between males and females (p = 0.946 at Gonubie, south-east coast and p = 0.961 at Kommetjie, south-west coast; t-test). Shell height could also not be used as a criterion to differentiate between the sexes. The average maximum shell length of H. pruinosus at Gonubie and Kommetjie was 25 mm, but the maximum shell lengths found were 30 mm, (one individual in each case), on both the southeast coast and west coast. Growth occurred most rapidly in the first year of life, with individuals reaching 15 mm after 1 year. In the second year limpet growth slowed to only 7 mm. Sexual maturity was reached at a shell length of between 11 to 14 mm (at an age of 8 months to 1 year). The life-span of H. pruinosus was determined at 2.55 years on the south-east coast and 2.9 years on the south-west coast. Micro-growth bands were produced tidally. Growth occurred allometrically, i.e. shell length increased at a faster rate than shell height. The limpets foraged during low tide, at night, presumably feeding on epilithic algae on the boulders. A second smaller peak of limpet activity was often recorded during the day, when low tide coincided with dawn). More limpets (up to ten times more) were active at spring tides compared to neap tides. Limpet activity was greatest during the spring tides of autumn. During all seasons limpet activity peaked 30 minutes before low water, after which numbers decreased rapidly. All limpets had retreated beneath the boulders before being covered by the flooding tide. It was concluded that the limpets were responding to both endogenous and exogenous cues, but the actual stimulus for retreat could not be determined. The limpets did not return to a fixed scar nor did they return rigidly to a home site. H. pruinosus was found to be gonochoristic. Sexes could be separated, on dissection, according to the colour of their gonads (males had white gonads, whilst that of the females was olive-green). Gonads were present throughout the year in most individuals, i.e. totally spent animals were never observed. Reproductive seasonality was similar in west coast and south-east coast animals. The gonad indices of the west coast limpets were higher, (maximum of 35%), compared to that on the southeast coast, (25%). The animals were probably trickle spawners, with some individuals liberating gametes throughout the year. There was however synchrony in gametogenesis between male and female limpets on both the west coast and south-east coast lines. Gonad indices peaked in the summer months (October to December) with a second minor peak in April/May. These peaks occurred before the release of the gametes in spawning events. The gonad index was lowest in winter, (July). The ovaries were full of mature eggs (oocytes having a diameter of 200 to 250 ~) prior to spawning. The acinal wall thickness had been decreasing prior to spawning. After spawning there was an increase in previtellogenic eggs « 100 μm) in females, and an increase in the acinal wall thickness to indicate spermatogenesis. The two populations are subjected to different environmental conditions and the actual cue for stimulating the release of gametes could not be determined. Finally, a table of differences between H pruinosus and its sister species, H pectunculus was created to show the life-style of H pruinosus.
- Full Text:
Assessing alternative assessment: students' experiences of the different forms of assessment in a Bachelor of Education course
- Authors: Hendricks, Monica
- Date: 2000
- Subjects: Education, Higher -- South Africa -- Evaluation Educational tests and measurements -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1424 , http://hdl.handle.net/10962/d1003305
- Description: In this study I examine the current alternative forms of assessment that were employed in the foundation year of the Bachelor of Education course at Rhodes University in 1998. Since assessment is concerned with ascertaining the amount, and kind, of learning that has taken place, it links learning and teaching. As my role in the course was academic development, I was interested in the nature ofthe development that the course promoted, for lecturers and students. My main intention was to gain insight into students' experiences of the assessment practices. To this end I selected six students, photocopied all their academic writing for the year and interviewed them. In addition, to provide a holistic picture of assessment and marking, I interviewed the six lecturers who team-taught the course. The data thus included the course assignments of the six students and an interview with each student as well as with the course lecturers. The findings show that though policy documents advocate alternative forms of assessment, implementing such assessment is a complex matter for both teachers and students.
- Full Text:
- Authors: Hendricks, Monica
- Date: 2000
- Subjects: Education, Higher -- South Africa -- Evaluation Educational tests and measurements -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1424 , http://hdl.handle.net/10962/d1003305
- Description: In this study I examine the current alternative forms of assessment that were employed in the foundation year of the Bachelor of Education course at Rhodes University in 1998. Since assessment is concerned with ascertaining the amount, and kind, of learning that has taken place, it links learning and teaching. As my role in the course was academic development, I was interested in the nature ofthe development that the course promoted, for lecturers and students. My main intention was to gain insight into students' experiences of the assessment practices. To this end I selected six students, photocopied all their academic writing for the year and interviewed them. In addition, to provide a holistic picture of assessment and marking, I interviewed the six lecturers who team-taught the course. The data thus included the course assignments of the six students and an interview with each student as well as with the course lecturers. The findings show that though policy documents advocate alternative forms of assessment, implementing such assessment is a complex matter for both teachers and students.
- Full Text:
Assessing the potential for biological invasion - the case of Ammophila arenaria in South Africa
- Hertling, Ursula M, Lubke, Roy
- Authors: Hertling, Ursula M , Lubke, Roy
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6518 , http://hdl.handle.net/10962/d1005947
- Description: Many plants, especially woody species, introduced into South Africa for ornamental or commercial purposes, have become invasive in a number of habitats. Because of the risk of an invasion of coastal dunes by yet another species, the European dune grass Ammophila arenaria, used as a dune stabilizer, is assessed using lists of attributes of invasive species and invasible ecosystems. It is impossible to predict plant invasions, but both invasive species as well as invaded ecosystems are often characterized by certain attributes which facilitate invasions. Many of the species attributes connected with invasion appear to apply to A. arenaria. Above all, the grass is characterized by ecological tolerance and vigorous rhizomatous reproduction. An important site attribute connected with invasion is an evolutionary history with isolation patterns, which applies to the South African Cape coast. We conclude also on the basis of the overseas experience, that the potential for A. arenaria to become invasive needs urgent investigation in the South African context.
- Full Text: false
- Authors: Hertling, Ursula M , Lubke, Roy
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6518 , http://hdl.handle.net/10962/d1005947
- Description: Many plants, especially woody species, introduced into South Africa for ornamental or commercial purposes, have become invasive in a number of habitats. Because of the risk of an invasion of coastal dunes by yet another species, the European dune grass Ammophila arenaria, used as a dune stabilizer, is assessed using lists of attributes of invasive species and invasible ecosystems. It is impossible to predict plant invasions, but both invasive species as well as invaded ecosystems are often characterized by certain attributes which facilitate invasions. Many of the species attributes connected with invasion appear to apply to A. arenaria. Above all, the grass is characterized by ecological tolerance and vigorous rhizomatous reproduction. An important site attribute connected with invasion is an evolutionary history with isolation patterns, which applies to the South African Cape coast. We conclude also on the basis of the overseas experience, that the potential for A. arenaria to become invasive needs urgent investigation in the South African context.
- Full Text: false
Asymmetric α-alkylation reactions
- Authors: Klein, Rosalyn
- Date: 2000
- Subjects: Asymmetric synthesis , Alkylation , Chemical reactions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4405 , http://hdl.handle.net/10962/d1006710 , Asymmetric synthesis , Alkylation , Chemical reactions
- Description: A novel camphor-derived hydroxy ketal 138 has been developed as a crural auxiliary, and used to prepare a series of six carboxylic esters of increasing steric bulk. The α-benzylation of this series of esters was achieved with diastereoselectivities of 59 - 83％ d. e. and in 39 - 48％ material yield. These results compared very favourably with those obtained in earlier studies using a regioisomeric analogue as the chiral auxiliary. Computer.modelling studies of the putative enolate intermediate has provided some insight into the possible mode of electrophilic attack at the α-carbon and the roles of the ketal protecting group and the lithium cation in these asymmetric transformations. In a related investigation, based on earlier work, a camphor-derived imino lactone has provided convenient access to α-alkyl α-amino acids, the imino lactone serving as a masked glycine equivalent. Using straight chain primary alkyl iodides [RI; R = Me, Et, Pr, Bu, CH₃(CH₂)₄ and CH₃(CH₄)₅], alkylation of the potassium enolate of the camphor-derived imino lactone was effected with 54 - 89％ d.e. and in 54 - 87％ material yield. Four novel alkylated derivatives were synthesised using isopropyl iodide, sec-butyl iodide and allyl iodide, the latter reagent resulting in both the monoallylated and diallylated products. While very good diastereoselectivities were achieved (83 - 88％ d. e.) in these reactions, the material yields from reaction with the secondary alkyl iodides were low (31- 35％) due, presumably, to their decreased electrophilicity. Computer modelling studies of the enolate were carried out and support the hypothesis of endo attack by the electrophile on the enolate intermediate. These studies also indicate the possibility of coordination of the postassium cation to the endocyclic ester oxygen, thus effectively anchoring the bulky cation away from the reaction site.
- Full Text:
- Authors: Klein, Rosalyn
- Date: 2000
- Subjects: Asymmetric synthesis , Alkylation , Chemical reactions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4405 , http://hdl.handle.net/10962/d1006710 , Asymmetric synthesis , Alkylation , Chemical reactions
- Description: A novel camphor-derived hydroxy ketal 138 has been developed as a crural auxiliary, and used to prepare a series of six carboxylic esters of increasing steric bulk. The α-benzylation of this series of esters was achieved with diastereoselectivities of 59 - 83％ d. e. and in 39 - 48％ material yield. These results compared very favourably with those obtained in earlier studies using a regioisomeric analogue as the chiral auxiliary. Computer.modelling studies of the putative enolate intermediate has provided some insight into the possible mode of electrophilic attack at the α-carbon and the roles of the ketal protecting group and the lithium cation in these asymmetric transformations. In a related investigation, based on earlier work, a camphor-derived imino lactone has provided convenient access to α-alkyl α-amino acids, the imino lactone serving as a masked glycine equivalent. Using straight chain primary alkyl iodides [RI; R = Me, Et, Pr, Bu, CH₃(CH₂)₄ and CH₃(CH₄)₅], alkylation of the potassium enolate of the camphor-derived imino lactone was effected with 54 - 89％ d.e. and in 54 - 87％ material yield. Four novel alkylated derivatives were synthesised using isopropyl iodide, sec-butyl iodide and allyl iodide, the latter reagent resulting in both the monoallylated and diallylated products. While very good diastereoselectivities were achieved (83 - 88％ d. e.) in these reactions, the material yields from reaction with the secondary alkyl iodides were low (31- 35％) due, presumably, to their decreased electrophilicity. Computer modelling studies of the enolate were carried out and support the hypothesis of endo attack by the electrophile on the enolate intermediate. These studies also indicate the possibility of coordination of the postassium cation to the endocyclic ester oxygen, thus effectively anchoring the bulky cation away from the reaction site.
- Full Text:
Bread and honour: white working class women and Afrikaner Nationalism in the 1930s
- Authors: Vincent, Louise
- Date: 2000
- Language: English
- Type: text , Article
- Identifier: vital:6205 , http://hdl.handle.net/10962/d1008575
- Description: Women have occupied a central place in the ideological formulations of nationalist movements. In particular, the figure of woman as mother recurs throughout the history of nationalist political mobilizations. In Afrikaner nationalism, this symbolic female identity takes the form of the volksmoeder (mother of the nation) icon, commonly assumed to describe a highly circumscribed set of women's social roles, created for women by men. The academic orthodoxy holds that middle-class Afrikaner women submitted to the volksmoeder ideology early on in the development of Afrikaner nationalism but that the working class Afrikaner women of the Garment Workers' Union (GWU) represented an enclave of resistance to dominant definitions of ethnic identity. They chose instead to ally themselves with militant, class-conscious trade unionism. This paper argues that Afrikaner women of different classes helped to shape the contours of the volksmoeder icon. Whilst middle class Afrikaner women questioned the idea that their social contribution should remain restricted to narrow familial and charitable concerns, prominent working class women laid claim to their own entitlement to the volksmoeder heritage. In doing so, the latter contributed to the popularization and reinterpretation of an ideology that was at this time seeking a wider audience. The paper argues that the incorporation of Afrikaner women into the socialist milieu of the GWU did not result in these women simply discarding the ethnic components of their identity. Rather their self-awareness as Afrikaner women with a recent rural past was grafted onto their new experience as urban factory workers. The way in which leading working class Afrikaner women articulated this potent combination of 'derived' and 'inherent' ideology cannot be excluded from the complex process whereby Afrikaner nationalism achieved success as a movement appealing to its imagined community across boundaries of class and gender.
- Full Text:
- Authors: Vincent, Louise
- Date: 2000
- Language: English
- Type: text , Article
- Identifier: vital:6205 , http://hdl.handle.net/10962/d1008575
- Description: Women have occupied a central place in the ideological formulations of nationalist movements. In particular, the figure of woman as mother recurs throughout the history of nationalist political mobilizations. In Afrikaner nationalism, this symbolic female identity takes the form of the volksmoeder (mother of the nation) icon, commonly assumed to describe a highly circumscribed set of women's social roles, created for women by men. The academic orthodoxy holds that middle-class Afrikaner women submitted to the volksmoeder ideology early on in the development of Afrikaner nationalism but that the working class Afrikaner women of the Garment Workers' Union (GWU) represented an enclave of resistance to dominant definitions of ethnic identity. They chose instead to ally themselves with militant, class-conscious trade unionism. This paper argues that Afrikaner women of different classes helped to shape the contours of the volksmoeder icon. Whilst middle class Afrikaner women questioned the idea that their social contribution should remain restricted to narrow familial and charitable concerns, prominent working class women laid claim to their own entitlement to the volksmoeder heritage. In doing so, the latter contributed to the popularization and reinterpretation of an ideology that was at this time seeking a wider audience. The paper argues that the incorporation of Afrikaner women into the socialist milieu of the GWU did not result in these women simply discarding the ethnic components of their identity. Rather their self-awareness as Afrikaner women with a recent rural past was grafted onto their new experience as urban factory workers. The way in which leading working class Afrikaner women articulated this potent combination of 'derived' and 'inherent' ideology cannot be excluded from the complex process whereby Afrikaner nationalism achieved success as a movement appealing to its imagined community across boundaries of class and gender.
- Full Text:
Cape Town talks about sex workers
- Sex Workers’ Education & Advocacy Taskforce (SWEAT)
- Authors: Sex Workers’ Education & Advocacy Taskforce (SWEAT)
- Date: 2000
- Subjects: SWEAT
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/168829 , vital:41651
- Description: On Monday 25 September,, as- part of the One City Festival, the Black Arts Collective hosted a debate about sex work. Natasha from SWEAT spoke about the why the government should decriminalize sex work. Khadija Magardie, a journalist from the Mail and Guardian newspaper, sent a speech talking about how sex work should be abolished by changing the law to make the clients criminals, so they can be arrested for buying sex from sex workers. Members of the public came to the debate, and talked about their feelings about sex work, and asked questions and gave comments. Generally most people were supportive of the fact that sex workers deserve human rights, even if they didn’t like the idea that people sell sex for a living. The city is starting to talk about sex work and sex workers, which is very exciting. It is a chance for SWEAT to talk about the realities of the industry, and to break down some of the stereotypes that many members of the public have about sex workers and sex work. One element that is missing from these discussions is the voices of sex workers themselves. SWEAT points out that it is very difficult for sex workers to talk publicly because of the stigmatization they suffer, and because sex work is still illegal. If you are interested in talking to the public about your experiences and opinions, please contact SWEAT and let us know, so that next time there is a chance to speak to the public we can invite you along.
- Full Text:
- Authors: Sex Workers’ Education & Advocacy Taskforce (SWEAT)
- Date: 2000
- Subjects: SWEAT
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10962/168829 , vital:41651
- Description: On Monday 25 September,, as- part of the One City Festival, the Black Arts Collective hosted a debate about sex work. Natasha from SWEAT spoke about the why the government should decriminalize sex work. Khadija Magardie, a journalist from the Mail and Guardian newspaper, sent a speech talking about how sex work should be abolished by changing the law to make the clients criminals, so they can be arrested for buying sex from sex workers. Members of the public came to the debate, and talked about their feelings about sex work, and asked questions and gave comments. Generally most people were supportive of the fact that sex workers deserve human rights, even if they didn’t like the idea that people sell sex for a living. The city is starting to talk about sex work and sex workers, which is very exciting. It is a chance for SWEAT to talk about the realities of the industry, and to break down some of the stereotypes that many members of the public have about sex workers and sex work. One element that is missing from these discussions is the voices of sex workers themselves. SWEAT points out that it is very difficult for sex workers to talk publicly because of the stigmatization they suffer, and because sex work is still illegal. If you are interested in talking to the public about your experiences and opinions, please contact SWEAT and let us know, so that next time there is a chance to speak to the public we can invite you along.
- Full Text:
Cardiac responses under diverse combinations of marching speed and backpack load
- Scott, Patricia A, Christie, Candice J
- Authors: Scott, Patricia A , Christie, Candice J
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6755 , http://hdl.handle.net/10962/d1009457
- Description: Thirty seasoned foot-soldiers were exposed to a total of 16 combinations of marching speed and backpack load, each soldier experiencing 8 of the combinations between 3.5km.h-1 with a 20kg load and 6.5km.h-1 with a 65kg load. Detailed physiological analyses were conducted, of which the heart rate responses are reported here. Steady state was achieved with all combinations under 5.5km.h-1 speed and 35kg load. Excessively elevated heart rates were elicited by all loads over 20kg at 6.5km.h-1 marching speed; by loads over 35kg at 5.5km.h-1 marching speed and by the 65kg load even at 4.5km.h-1 marching speed.
- Full Text:
- Authors: Scott, Patricia A , Christie, Candice J
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6755 , http://hdl.handle.net/10962/d1009457
- Description: Thirty seasoned foot-soldiers were exposed to a total of 16 combinations of marching speed and backpack load, each soldier experiencing 8 of the combinations between 3.5km.h-1 with a 20kg load and 6.5km.h-1 with a 65kg load. Detailed physiological analyses were conducted, of which the heart rate responses are reported here. Steady state was achieved with all combinations under 5.5km.h-1 speed and 35kg load. Excessively elevated heart rates were elicited by all loads over 20kg at 6.5km.h-1 marching speed; by loads over 35kg at 5.5km.h-1 marching speed and by the 65kg load even at 4.5km.h-1 marching speed.
- Full Text:
Characterization of amide bond hydrolysis in novel hydantoinase-producing bacteria
- Authors: Skepu, Zoleka G
- Date: 2000
- Subjects: Amides , Hydrolysis , Hydantoin , Imides
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3911 , http://hdl.handle.net/10962/d1003970 , Amides , Hydrolysis , Hydantoin , Imides
- Description: This thesis describes a series of investigations into the amide bond-hydrolyzing activity of bacterial strains RU-KM1, RU-KM3L, RU-KM3S, and RU-OR, which were previously isolated for their ability to hydrolyze hydantoins to amino acids. The main aim of the study was to develop biotransformations with potential application in the production of enantiomerically pure amino acids and related compounds. Several compounds may be used as substrates by biocatalysts for the production of amino acids, such as hydantoins, amino nitriles, and amides. These compounds are not only important for amino acid production, but they may be used for production of other industrially important compounds, such as 2- arylpropionic acids, which are non-steroidal anti-inflammatory drugs. Thus, the ability of the above-mentioned strains to hydrolyze these substrates was investigated, with the view to utilizing the maximum potential of these biocatalysts. The compounds used as substrates in the investigation are all essentially amides. Thus, the ability of the strains to hydrolyze imides, hydantoins, and amides, was investigated. In particular, imides have a structure which is very similar to that of hydantoins, and thus it was an objective of the study to determine whether these strains could hydrolyze imides. Imidehydrolyzing activity has only recently been discovered in microorganisms. Hydantoin conversion involves a two-step hydrolysis reaction which yields, initially, an Ncarbamylamino acid intermediate, and subsequently, an "-amino acid. The hydantoinhydrolyzing enzymes of a Pseudomonas putida strain, RU-KM3S, were characterized in a crude extract preparation and reaction conditions for its biocatalytic application were optimized. The optimum conditions for conversion of 5-methylhydantoin were found to be 3 hours at 40°C, with conversion yields greater than 50% achieved. The enzymes of RU-KM3S demonstrated considerable stability, retaining 80% of their activity after incubation at 40°C for 3 hours. The activities of the enzymes were increased by the addition of a detergent to the extraction medium, suggesting that the enzymes might be membrane-bound. The results of the determination of the metal-dependence of the hydantoinase and N-carbamylase of RUKM3S suggested that these enzymes required metal ions for activity, with metal ions such as Mg²⁺, Mn²⁺, Zn²⁺, and Co²⁺ resulting in activation of the enzymes. However, Cu²⁺ and Fe²⁺ caused inactivation of these enzymes. The stereoselectivity of the enzymes was investigated, and the results suggested that the hydantoinase was non-selective, whereas the N-carbamylase was L-selective. The hydantoin substrate selectivity of RU-KM3S was compared to that of three other hydantoinase-producing bacteria, RU-KM1, RU-KM3L, and RU-OR. The four strains were able to hydrolyze all of the seven substrates tested. However, there was a difference in activity levels between crude extract preparations and whole cells, with crude extracts generally showing higher activity than whole cells, except in the case of RU-KM1. Some difference was also observed in the order of preference of substrates between whole cells and crude extracts. The preferred substrate for RU-KM1 whole cells was isopropylhydantoin, whereas the crude extract preparation preferentially hydrolyzed p-hydroxyphenylhydantoin. RU-KM3L whole cells achieved a higher conversion yield with isobutylhydantoin, whereas the crude extract achieved a higher yield with 5-t-butylhydantoin. RU-KM3S whole cells and crude extract preferentially hydrolyzed 5-n-butylhydantoin, although the yield was greater with the crude extract. The highest conversion yields were observed with RU-KM3S crude extract, with conversion yields of 71.6% and 100% for n-butylhydantoin and phydroxyphenylhydantoin, respectively.The ability of RU-KM1, RU-KM3L, and RU-KM3S to hydrolyze nitriles, initially to amides and subsequently to carboxylic acids, was investigated. These strains were demonstrated to be unable to utilize acrylonitrile, propionitrile and benzonitrile as nitrogen sources, but were able to hydrolyze acrylonitrile, propionitrile and acetonitrile, in resting cell reactions. Nitrile hydrolysis was demonstrated to be inducible in all three strains, and the enzyme system responsible for nitrile hydrolysis was proposed to be a nitrile hydratase-amidase system. Amidase activity in the four bacterial strains was investigated. The ability of RU-KM1, RUKM3L, RU-KM3S, and RU-OR to utilize amides as a nitrogen source was investigated, and the results showed that propionamide was a good nitrogen source for all four of the strains. Amide-hydrolyzing activity, by resting cells, was shown to be inducible by propionamide in all four strains. RU-KM3S demonstrated superior amide-hydrolyzing ability in that it hydrolyzed propionamide, acetamide, and acrylamide to a greater extent than the other strains. Resting cells of RU-KM1 and RU-OR were demonstrated to have the ability to hydrolyze the imide substrate, succinimide, and this imidase activity was found to be inducible. These strains were also able to utilize this imide as the sole source of nitrogen for growth, which is a novel finding, as to date, bacteria have only be reported to utilize imides as a carbon source. The identity of the enzyme system responsible for succinimide hydrolysis is not yet clear. In conclusion, the hydantoin-hydrolyzing enzymes of RU-KM3S have been shown to be possibly membrane associated, which is a novel finding that has also been proposed in three other hydantoinase-producing strains in our laboratory. This study has shown that the Ncarbamylase of RU-KM3S is L-stereoselective, which, to our knowledge, is the first report of an L-stereospecific N-carbamylase in a Pseudomonas putida. Publication of these findings is already in progress. This is the first report on the study of imide hydrolysis in either an Agrobacterium tumefaciens or a Pseudomonas sp., and publications reporting these results are in preparation.
- Full Text:
- Authors: Skepu, Zoleka G
- Date: 2000
- Subjects: Amides , Hydrolysis , Hydantoin , Imides
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3911 , http://hdl.handle.net/10962/d1003970 , Amides , Hydrolysis , Hydantoin , Imides
- Description: This thesis describes a series of investigations into the amide bond-hydrolyzing activity of bacterial strains RU-KM1, RU-KM3L, RU-KM3S, and RU-OR, which were previously isolated for their ability to hydrolyze hydantoins to amino acids. The main aim of the study was to develop biotransformations with potential application in the production of enantiomerically pure amino acids and related compounds. Several compounds may be used as substrates by biocatalysts for the production of amino acids, such as hydantoins, amino nitriles, and amides. These compounds are not only important for amino acid production, but they may be used for production of other industrially important compounds, such as 2- arylpropionic acids, which are non-steroidal anti-inflammatory drugs. Thus, the ability of the above-mentioned strains to hydrolyze these substrates was investigated, with the view to utilizing the maximum potential of these biocatalysts. The compounds used as substrates in the investigation are all essentially amides. Thus, the ability of the strains to hydrolyze imides, hydantoins, and amides, was investigated. In particular, imides have a structure which is very similar to that of hydantoins, and thus it was an objective of the study to determine whether these strains could hydrolyze imides. Imidehydrolyzing activity has only recently been discovered in microorganisms. Hydantoin conversion involves a two-step hydrolysis reaction which yields, initially, an Ncarbamylamino acid intermediate, and subsequently, an "-amino acid. The hydantoinhydrolyzing enzymes of a Pseudomonas putida strain, RU-KM3S, were characterized in a crude extract preparation and reaction conditions for its biocatalytic application were optimized. The optimum conditions for conversion of 5-methylhydantoin were found to be 3 hours at 40°C, with conversion yields greater than 50% achieved. The enzymes of RU-KM3S demonstrated considerable stability, retaining 80% of their activity after incubation at 40°C for 3 hours. The activities of the enzymes were increased by the addition of a detergent to the extraction medium, suggesting that the enzymes might be membrane-bound. The results of the determination of the metal-dependence of the hydantoinase and N-carbamylase of RUKM3S suggested that these enzymes required metal ions for activity, with metal ions such as Mg²⁺, Mn²⁺, Zn²⁺, and Co²⁺ resulting in activation of the enzymes. However, Cu²⁺ and Fe²⁺ caused inactivation of these enzymes. The stereoselectivity of the enzymes was investigated, and the results suggested that the hydantoinase was non-selective, whereas the N-carbamylase was L-selective. The hydantoin substrate selectivity of RU-KM3S was compared to that of three other hydantoinase-producing bacteria, RU-KM1, RU-KM3L, and RU-OR. The four strains were able to hydrolyze all of the seven substrates tested. However, there was a difference in activity levels between crude extract preparations and whole cells, with crude extracts generally showing higher activity than whole cells, except in the case of RU-KM1. Some difference was also observed in the order of preference of substrates between whole cells and crude extracts. The preferred substrate for RU-KM1 whole cells was isopropylhydantoin, whereas the crude extract preparation preferentially hydrolyzed p-hydroxyphenylhydantoin. RU-KM3L whole cells achieved a higher conversion yield with isobutylhydantoin, whereas the crude extract achieved a higher yield with 5-t-butylhydantoin. RU-KM3S whole cells and crude extract preferentially hydrolyzed 5-n-butylhydantoin, although the yield was greater with the crude extract. The highest conversion yields were observed with RU-KM3S crude extract, with conversion yields of 71.6% and 100% for n-butylhydantoin and phydroxyphenylhydantoin, respectively.The ability of RU-KM1, RU-KM3L, and RU-KM3S to hydrolyze nitriles, initially to amides and subsequently to carboxylic acids, was investigated. These strains were demonstrated to be unable to utilize acrylonitrile, propionitrile and benzonitrile as nitrogen sources, but were able to hydrolyze acrylonitrile, propionitrile and acetonitrile, in resting cell reactions. Nitrile hydrolysis was demonstrated to be inducible in all three strains, and the enzyme system responsible for nitrile hydrolysis was proposed to be a nitrile hydratase-amidase system. Amidase activity in the four bacterial strains was investigated. The ability of RU-KM1, RUKM3L, RU-KM3S, and RU-OR to utilize amides as a nitrogen source was investigated, and the results showed that propionamide was a good nitrogen source for all four of the strains. Amide-hydrolyzing activity, by resting cells, was shown to be inducible by propionamide in all four strains. RU-KM3S demonstrated superior amide-hydrolyzing ability in that it hydrolyzed propionamide, acetamide, and acrylamide to a greater extent than the other strains. Resting cells of RU-KM1 and RU-OR were demonstrated to have the ability to hydrolyze the imide substrate, succinimide, and this imidase activity was found to be inducible. These strains were also able to utilize this imide as the sole source of nitrogen for growth, which is a novel finding, as to date, bacteria have only be reported to utilize imides as a carbon source. The identity of the enzyme system responsible for succinimide hydrolysis is not yet clear. In conclusion, the hydantoin-hydrolyzing enzymes of RU-KM3S have been shown to be possibly membrane associated, which is a novel finding that has also been proposed in three other hydantoinase-producing strains in our laboratory. This study has shown that the Ncarbamylase of RU-KM3S is L-stereoselective, which, to our knowledge, is the first report of an L-stereospecific N-carbamylase in a Pseudomonas putida. Publication of these findings is already in progress. This is the first report on the study of imide hydrolysis in either an Agrobacterium tumefaciens or a Pseudomonas sp., and publications reporting these results are in preparation.
- Full Text:
Colonial photography in nineteenth century Grahamstown: an analysis of the Dr W.G. Atherstone Bequest
- Authors: Waters, Hywell George
- Date: 2000
- Subjects: Atherstone, W. G. (William Guybon), 1814-1898 Art and photography Photography -- Technique
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2426 , http://hdl.handle.net/10962/d1002222
- Description: The research for this degree comprises of a theoretical dissertationand a practicalcomponent of exhibited photographs. The theoretical research investigates the original photographic prints and glass-plate negatives taken betweenthe 1840's and 1890's, by the late Dr. W.G. Atherstone - an enthusiastic, Grahamstown amateur photographer. Dr W. G Atherstone's prints and negatives were examined by the author to deduce and establish his photographic abilities, his numerous techniques, diverse subject matter and the pictorialconstructionof his images. Selected works will be examined in order to interpret and illustrate his diverse interests and approaches towards photography. The selection of these photographs was determined by their pertinence to subject matter, and to the pictorial and historical considerations of the candidate. These issues are finally examined in relation to the candidates's own approach to photography today.
- Full Text:
- Authors: Waters, Hywell George
- Date: 2000
- Subjects: Atherstone, W. G. (William Guybon), 1814-1898 Art and photography Photography -- Technique
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2426 , http://hdl.handle.net/10962/d1002222
- Description: The research for this degree comprises of a theoretical dissertationand a practicalcomponent of exhibited photographs. The theoretical research investigates the original photographic prints and glass-plate negatives taken betweenthe 1840's and 1890's, by the late Dr. W.G. Atherstone - an enthusiastic, Grahamstown amateur photographer. Dr W. G Atherstone's prints and negatives were examined by the author to deduce and establish his photographic abilities, his numerous techniques, diverse subject matter and the pictorialconstructionof his images. Selected works will be examined in order to interpret and illustrate his diverse interests and approaches towards photography. The selection of these photographs was determined by their pertinence to subject matter, and to the pictorial and historical considerations of the candidate. These issues are finally examined in relation to the candidates's own approach to photography today.
- Full Text:
Comparative Spectroscopic and Electrochemical Properties of Bis (octakis (dodecylthio) naphthalocyaninato) europium (III) and Bis (tetra-tert-butylnaphthalocyaninato) europium (III) Complexes
- Nyokong, Tebello, Furuya, Fumio, Kobayashi, Nagao, Du, Daming, Liu, Wei, Jiang, Jianzhuang
- Authors: Nyokong, Tebello , Furuya, Fumio , Kobayashi, Nagao , Du, Daming , Liu, Wei , Jiang, Jianzhuang
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293174 , vital:57062 , xlink:href="https://doi.org/10.1021/ic990483b"
- Description: Bis(substituted-2,3-naphthalocyaninato)europium(III) complexes: bis(octakis(dodecylthio)-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(SC12H25)8]2, 1} and bis(tetra-tert-butyl-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(t-Bu)4]2, 2} have been synthesized by cyclic tetramerization of naphthalonitriles with Eu(acac)3·H2O in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in refluxing n-octanol. These compounds were characterized by UV−visible, magnetic circular dichroism (MCD), near-IR, IR, EPR, and mass spectroscopies. The absorption and MCD spectra of 1 showed splitting of the Q band, with peaks at 700 and 784 nm, red shifted from the Q band of 2 at 763 nm. The absorption and MCD spectral band deconvolution calculations of complex 1 gave two A terms in the Q-band region. The A terms are assigned to 2A2 → 2E1 transitions. Cyclic voltammograms of 1 and 2 showed reversible oxidation couples at E1/2 = −0.28 V (for 2) and −0.25 V (for 1) vs ferrocenium/ferrocene (Fc+/Fc). The second oxidation exhibited a complicated behavior for both complexes. The reduction couples for 2 were observed at E1/2 = −0.61, −1.64, −1.97, and −2.42 V, and for 1 they were observed at E1/2 = −0.62, −1.60, −1.86, and −2.27 V vs Fc+/Fc. Spectral changes observed on chemical oxidation and reduction of the complexes are presented, and the behaviors of 1 and 2 are compared.
- Full Text:
- Authors: Nyokong, Tebello , Furuya, Fumio , Kobayashi, Nagao , Du, Daming , Liu, Wei , Jiang, Jianzhuang
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293174 , vital:57062 , xlink:href="https://doi.org/10.1021/ic990483b"
- Description: Bis(substituted-2,3-naphthalocyaninato)europium(III) complexes: bis(octakis(dodecylthio)-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(SC12H25)8]2, 1} and bis(tetra-tert-butyl-2,3-naphthalocyaninato)europium(III) {Eu[2,3-Nc(t-Bu)4]2, 2} have been synthesized by cyclic tetramerization of naphthalonitriles with Eu(acac)3·H2O in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in refluxing n-octanol. These compounds were characterized by UV−visible, magnetic circular dichroism (MCD), near-IR, IR, EPR, and mass spectroscopies. The absorption and MCD spectra of 1 showed splitting of the Q band, with peaks at 700 and 784 nm, red shifted from the Q band of 2 at 763 nm. The absorption and MCD spectral band deconvolution calculations of complex 1 gave two A terms in the Q-band region. The A terms are assigned to 2A2 → 2E1 transitions. Cyclic voltammograms of 1 and 2 showed reversible oxidation couples at E1/2 = −0.28 V (for 2) and −0.25 V (for 1) vs ferrocenium/ferrocene (Fc+/Fc). The second oxidation exhibited a complicated behavior for both complexes. The reduction couples for 2 were observed at E1/2 = −0.61, −1.64, −1.97, and −2.42 V, and for 1 they were observed at E1/2 = −0.62, −1.60, −1.86, and −2.27 V vs Fc+/Fc. Spectral changes observed on chemical oxidation and reduction of the complexes are presented, and the behaviors of 1 and 2 are compared.
- Full Text:
Comparison of plant diversity in protected and communal lands in the Bushbuckridge lowveld savanna, South Africa
- Authors: Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181885 , vital:43777 , xlink:href="https://doi.org/10.1016/S0006-3207(00)00001-X"
- Description: Patterns of higher plant species richness and beta diversity were assessed using standard Modified-Whittaker plots in relation to land use, slope position and mean annual rainfall across a rainfall gradient in the savanna areas of the Bushbuckridge lowveld, South Africa. In particular, comparison of communal areas with adjacent protected areas was important in showing the impacts of potential changes in land use within an overarching catchment management plan. Although most of the protected areas considered preservation of biodiversity as their primary goal, they were characterised by significantly fewer plant species than the adjacent, highly utilised, communal lands, at both the plot and point scale. Slope position also had a significant effect on plant species richness, with eutrophic bottomlands having c. 30% more species than the dystrophic toplands. This adds weight to the need for greater public awareness for the judicious use and management of the sensitive bottomlands, which fringe the primary drainage lines that are vital for sustained supplies of good quality surface water in this semi-arid environment. The total number of species increased with increasing mean annual rainfall across the rainfall gradient. This suggests that, if the catchment management plan aims to identify additional areas for conservation, the higher rainfall areas should be the first to be assessed. Species turnover was greater along the rainfall gradient than the catenal gradient between toplands and bottomlands.
- Full Text:
- Authors: Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181885 , vital:43777 , xlink:href="https://doi.org/10.1016/S0006-3207(00)00001-X"
- Description: Patterns of higher plant species richness and beta diversity were assessed using standard Modified-Whittaker plots in relation to land use, slope position and mean annual rainfall across a rainfall gradient in the savanna areas of the Bushbuckridge lowveld, South Africa. In particular, comparison of communal areas with adjacent protected areas was important in showing the impacts of potential changes in land use within an overarching catchment management plan. Although most of the protected areas considered preservation of biodiversity as their primary goal, they were characterised by significantly fewer plant species than the adjacent, highly utilised, communal lands, at both the plot and point scale. Slope position also had a significant effect on plant species richness, with eutrophic bottomlands having c. 30% more species than the dystrophic toplands. This adds weight to the need for greater public awareness for the judicious use and management of the sensitive bottomlands, which fringe the primary drainage lines that are vital for sustained supplies of good quality surface water in this semi-arid environment. The total number of species increased with increasing mean annual rainfall across the rainfall gradient. This suggests that, if the catchment management plan aims to identify additional areas for conservation, the higher rainfall areas should be the first to be assessed. Species turnover was greater along the rainfall gradient than the catenal gradient between toplands and bottomlands.
- Full Text:
Computers in science teaching: a reality or dream; The role of computers in effective science education: a case of using a computer to teach colour mixing; Career oriented science education for the next millennium
- Authors: Nadarajah, Kumaravel
- Date: 2000
- Subjects: Science -- Study and teaching Computer-assisted instruction Education -- Data processing
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1460 , http://hdl.handle.net/10962/d1003341
- Description: Science education in South Africa is not improving much. Many science educators do not have appropriate science qualifications. Majority of the learners have limited facilities to learn science. In this dilemma the move to OBE may result in further substantial deterioration of science education. A possible way out is to use computers in science education to facilitate the learning process. This study was designed to investigate how computers contribute to learners’ skills development in a physics course. A series of interactive computer simulations of colour mixing and a number of closely related traditional practical activities are aimed to promote learners’ understanding of colour. It was concluded that while computer environments have greater potentialas learning tools, they also limit interactions in significant ways.
- Full Text:
- Authors: Nadarajah, Kumaravel
- Date: 2000
- Subjects: Science -- Study and teaching Computer-assisted instruction Education -- Data processing
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1460 , http://hdl.handle.net/10962/d1003341
- Description: Science education in South Africa is not improving much. Many science educators do not have appropriate science qualifications. Majority of the learners have limited facilities to learn science. In this dilemma the move to OBE may result in further substantial deterioration of science education. A possible way out is to use computers in science education to facilitate the learning process. This study was designed to investigate how computers contribute to learners’ skills development in a physics course. A series of interactive computer simulations of colour mixing and a number of closely related traditional practical activities are aimed to promote learners’ understanding of colour. It was concluded that while computer environments have greater potentialas learning tools, they also limit interactions in significant ways.
- Full Text:
Constitutional frameworks and democratization in Africa since independence
- Authors: Neirynck, Karim
- Date: 2000
- Subjects: Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2816 , http://hdl.handle.net/10962/d1003026 , Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Description: The subject of this thesis is international studies, specifically a study of constitutional frameworks in Africa in the second half of the 20th century, focussing on a statistical correlation between constitutional frameworks, party systems, electoral systems and the Index of Democracy. The struggle to consolidate new democracies - especially those in Eastern Europe, Latin America and Asia - has given rise to a wide-ranging debate about the hard choices concerning democratic political institutions and political markets. According to Stepan and Skach " this literature has produced provocative hypotheses about the effects of institutions on democracy" (Stepan and Skach, 1993 : 1). It forms part of the' new institutionalism I literature in comparative politics that'holds as a premise that political democracy depends not only on economic and social conditions but also on the design of political institutions (Koelble, 1995 : 231-243). " One fundamental political-institutional question that has only received serious scholarly attention concerns the impact of different constitutional frameworks on democratic consolidation. Although the topic has been increasingly debated and discussed, little systematic cross-regional evidence [especially for our field of research: Africa] has been brought to bear on it " (Stepan and Skach, 1993 : 1-2). So far, only the book"on regime transitions in Africa written by Bratton and Van De Walle seeks to fill this empirical gap (Bratton and Van De Walle, 1997, preface xiii). In this thesis, we paid particular attention to the dichotomy between (pure) parliamentarism and (pure) presidentialism. Each type has fundamental characteristics, and for the purposes of classification these characteristics are necessary and sufficient. It was not our purpose to weigh the benefits and drawbacks of parliamentarism and presidentialism. Our intention was to report and analyse different sources of data, and we based our case exclusively on statistic correlatiohs between regime type and the record of democratic success and failure. We collected a data set about constitutional frameworks (matrix1), democracy indices (matrix2), party systems (matrix3) and election systems (matrix4). The basis for matrix 1 was the constitutions of the African countries (over time) and relevant literature. The basis for matrix 2 was the annual Freedom House ratings made by Raymond D. Gastil and others. The basis for matrix 3 and 4 was relevant literature. Once these matrices had been composed, we compared them and calculated statistic correlations. This long-dyration model allowed us to estimate whether African constitutional frameworks, party systems and electoral systems exhibit positive or negative correlation with the index of democracy.
- Full Text:
- Authors: Neirynck, Karim
- Date: 2000
- Subjects: Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2816 , http://hdl.handle.net/10962/d1003026 , Democracy -- Africa , Constitutions -- Africa , Africa -- Politics and government -- 1960-
- Description: The subject of this thesis is international studies, specifically a study of constitutional frameworks in Africa in the second half of the 20th century, focussing on a statistical correlation between constitutional frameworks, party systems, electoral systems and the Index of Democracy. The struggle to consolidate new democracies - especially those in Eastern Europe, Latin America and Asia - has given rise to a wide-ranging debate about the hard choices concerning democratic political institutions and political markets. According to Stepan and Skach " this literature has produced provocative hypotheses about the effects of institutions on democracy" (Stepan and Skach, 1993 : 1). It forms part of the' new institutionalism I literature in comparative politics that'holds as a premise that political democracy depends not only on economic and social conditions but also on the design of political institutions (Koelble, 1995 : 231-243). " One fundamental political-institutional question that has only received serious scholarly attention concerns the impact of different constitutional frameworks on democratic consolidation. Although the topic has been increasingly debated and discussed, little systematic cross-regional evidence [especially for our field of research: Africa] has been brought to bear on it " (Stepan and Skach, 1993 : 1-2). So far, only the book"on regime transitions in Africa written by Bratton and Van De Walle seeks to fill this empirical gap (Bratton and Van De Walle, 1997, preface xiii). In this thesis, we paid particular attention to the dichotomy between (pure) parliamentarism and (pure) presidentialism. Each type has fundamental characteristics, and for the purposes of classification these characteristics are necessary and sufficient. It was not our purpose to weigh the benefits and drawbacks of parliamentarism and presidentialism. Our intention was to report and analyse different sources of data, and we based our case exclusively on statistic correlatiohs between regime type and the record of democratic success and failure. We collected a data set about constitutional frameworks (matrix1), democracy indices (matrix2), party systems (matrix3) and election systems (matrix4). The basis for matrix 1 was the constitutions of the African countries (over time) and relevant literature. The basis for matrix 2 was the annual Freedom House ratings made by Raymond D. Gastil and others. The basis for matrix 3 and 4 was relevant literature. Once these matrices had been composed, we compared them and calculated statistic correlations. This long-dyration model allowed us to estimate whether African constitutional frameworks, party systems and electoral systems exhibit positive or negative correlation with the index of democracy.
- Full Text:
Criteria social workers employ in making child custody recommendations
- Authors: Froneman, Anna Petronella
- Date: 2000
- Subjects: Custody of children -- South Africa Social work with children -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:696 , http://hdl.handle.net/10962/d1006414
- Description: During this study, an attempt was made to investigate the process employed by social workers in conducting child custody evaluations and making decisions related to the process, as well as to provide insight into which criteria are currently being used. The goal was to explore the perceived usefulness of these criteria from the perspective of social work, and to assess the adequacy of the requirements of the custody report in reflecting the above process and decision-making. In order to meet this goal, literature and empirical studies were conducted. The literature study focuses on the history of child custody matters, custody decision-making and legislation, types of custody arrangements, criteria social workers employ in making child custody recommendations, evaluator bias and custody evaluation reports. During the empirical research phase, a non-probability purposive sampling procedure was adopted. Five family counsellors from the office of the family advocate serving the Eastern Cape were selected. After an interview schedule was compiled to cover certain topics and their sequence, semi-structured interviews were conducted with the family counsellors. In order to compare the criteria stated in the interviews with the criteria applied in the custody reports, three cases from each family counsellor were selected and the final custody report and recommendation were studied. This study has revealed the following: some of the family counsellors experience proqlems with the process of custody evaluations; certain aspects regarding the process are not in line with some ofthe literature; some of the criteria used by the family counsellors are not evident in the custody reports and are not discussed in detail; a lack of training exists for the family counsellors; and the family counsellors experience some form of bias. Finally, based on the research findings, recommendations were made regarding the process of custody evaluation, the criteria social workers employ when conducting child custody evaluations, training and bias of family counsellors, the role of the family advocate and possible future research.
- Full Text:
- Authors: Froneman, Anna Petronella
- Date: 2000
- Subjects: Custody of children -- South Africa Social work with children -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:696 , http://hdl.handle.net/10962/d1006414
- Description: During this study, an attempt was made to investigate the process employed by social workers in conducting child custody evaluations and making decisions related to the process, as well as to provide insight into which criteria are currently being used. The goal was to explore the perceived usefulness of these criteria from the perspective of social work, and to assess the adequacy of the requirements of the custody report in reflecting the above process and decision-making. In order to meet this goal, literature and empirical studies were conducted. The literature study focuses on the history of child custody matters, custody decision-making and legislation, types of custody arrangements, criteria social workers employ in making child custody recommendations, evaluator bias and custody evaluation reports. During the empirical research phase, a non-probability purposive sampling procedure was adopted. Five family counsellors from the office of the family advocate serving the Eastern Cape were selected. After an interview schedule was compiled to cover certain topics and their sequence, semi-structured interviews were conducted with the family counsellors. In order to compare the criteria stated in the interviews with the criteria applied in the custody reports, three cases from each family counsellor were selected and the final custody report and recommendation were studied. This study has revealed the following: some of the family counsellors experience proqlems with the process of custody evaluations; certain aspects regarding the process are not in line with some ofthe literature; some of the criteria used by the family counsellors are not evident in the custody reports and are not discussed in detail; a lack of training exists for the family counsellors; and the family counsellors experience some form of bias. Finally, based on the research findings, recommendations were made regarding the process of custody evaluation, the criteria social workers employ when conducting child custody evaluations, training and bias of family counsellors, the role of the family advocate and possible future research.
- Full Text:
Cuba's revolutionist and anti-imperialist foreign policy in Southern Africa: the case of Angola and Namibia
- Authors: Othieno, Timothy
- Date: 2000
- Subjects: Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2819 , http://hdl.handle.net/10962/d1003029 , Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Description: This study examines Cuba’s role in the two southern African countries of Angola and Namibia during the Cold War period. It argues that Cuba’s ideological motivations have been embodied in the mutually reinforcing concepts of proletarian internationalism and anti-imperialism. These conceptual perspectives constitute some of the central variables that influence Cuba’s foreign policy behaviour in international relations. It is within this context that one can understand Cuba’s involvement in Southern Africa. This study also attempts to explain that Cuban foreign policy towards Africa was based on two complementary and contextual objectives namely, promoting nationalism at home and nurturing revolutionary Marxist-Leninist governments, as well as supporting anti-colonial and anti-imperialist movements abroad. For the purpose of achieving these foreign policy objectives, Cuba not only engaged in state-to-state relations with Angola and Namibia; but had cordial relations with the rest of the continent and in particular Southern Africa, which also became a direct military testing ground for Cuba’s commitment to an anti-colonial and anti-imperialist revolutionary stance. Furthermore, the thesis shows that Cuba’s relentless hatred of imperialism is rooted in its historical relationship with the United States because from the turn of the century till 1958, the Americans interfered in Cuba’s internal affairs by supporting corrupt administrations and exploited the country. These practices by the United States laid the foundation for Cuba’s anti-colonialism and antiimperialism abroad. Ultimately, this thesis shows that Cuban involvement in Angola and Namibia can be conceptualised within these contexts (anti-imperialism, anti-colonialism, proletarian internationalism and revolutionary Marxism-Leninism). The role of Cuban nationalism in the realisation of these objectives and ideals, as well as its role in perpetuating and consolidating her foreign policy is assessed in this study. This nationalism and ideals of internationalism constitutes the central idea in the Cuban revolution. Finally, this thesis asserts that Cuban motives for getting involved in the politics of Southern Africa were not motivated by economic or imperialistic reasons. Rather, the historical similarity and colonial experiences between Africa and Cuba were some of the central causal factors.
- Full Text:
- Authors: Othieno, Timothy
- Date: 2000
- Subjects: Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2819 , http://hdl.handle.net/10962/d1003029 , Cuba -- Foreign Relations -- Africa, Southern , Cuba -- Dependency on foreign countries -- History , Cuba -- Foreign relations -- Angola , Cuba -- Foreign relations -- Namibia , Cuba -- Politics and government
- Description: This study examines Cuba’s role in the two southern African countries of Angola and Namibia during the Cold War period. It argues that Cuba’s ideological motivations have been embodied in the mutually reinforcing concepts of proletarian internationalism and anti-imperialism. These conceptual perspectives constitute some of the central variables that influence Cuba’s foreign policy behaviour in international relations. It is within this context that one can understand Cuba’s involvement in Southern Africa. This study also attempts to explain that Cuban foreign policy towards Africa was based on two complementary and contextual objectives namely, promoting nationalism at home and nurturing revolutionary Marxist-Leninist governments, as well as supporting anti-colonial and anti-imperialist movements abroad. For the purpose of achieving these foreign policy objectives, Cuba not only engaged in state-to-state relations with Angola and Namibia; but had cordial relations with the rest of the continent and in particular Southern Africa, which also became a direct military testing ground for Cuba’s commitment to an anti-colonial and anti-imperialist revolutionary stance. Furthermore, the thesis shows that Cuba’s relentless hatred of imperialism is rooted in its historical relationship with the United States because from the turn of the century till 1958, the Americans interfered in Cuba’s internal affairs by supporting corrupt administrations and exploited the country. These practices by the United States laid the foundation for Cuba’s anti-colonialism and antiimperialism abroad. Ultimately, this thesis shows that Cuban involvement in Angola and Namibia can be conceptualised within these contexts (anti-imperialism, anti-colonialism, proletarian internationalism and revolutionary Marxism-Leninism). The role of Cuban nationalism in the realisation of these objectives and ideals, as well as its role in perpetuating and consolidating her foreign policy is assessed in this study. This nationalism and ideals of internationalism constitutes the central idea in the Cuban revolution. Finally, this thesis asserts that Cuban motives for getting involved in the politics of Southern Africa were not motivated by economic or imperialistic reasons. Rather, the historical similarity and colonial experiences between Africa and Cuba were some of the central causal factors.
- Full Text:
Cumulative mild head injury in contact sport: a comparison of the cognitive profiles of rugby players and non-contact sport controls with normative data
- Authors: Bold, Lisa Clare
- Date: 2000
- Subjects: Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2935 , http://hdl.handle.net/10962/d1002444 , Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Description: This study investigates the effects of cumulative mild head injury on the cognitive functioning of elite rugby players. A comprehensive battery of neuropsychological tests was administered to top national (Springbok) rugby players (n=26), national Under 21 rugby players (n= 19), and a non-contact sport control group of national hockey players (n=21). The test results of the Total Rugby group (Springbok Rugby and Under 21 Rugby players), the Under 21 Rugby group, the hockey controls, and the Total Rugby and Under 21 Rugby forward and backline players respectively, were each compared with established normative data. Results showed significant differences in the direction of a poorer performance relative to the norms for the Total Rugby and Under 21 Rugby groups, and for the Total Rugby Forwards and Under 21 Rugby Forwards, on tests sensitive to the effects of diffuse brain damage. On the other hand, the Hockey Control group and the Total Rugby Backs and Under 21 Rugby Backs tended to perform within the normal range or better than the norm on some tests. These results confirm the hypothesis that rugby players, and the forward players in particular, are at risk of adverse cognitive effects consequent on cumulative mild head injury. The theoretical implications are that the aggregate effects of multiple exposures to mild head injuries in the rugby players served to reduce their brain reserve capacities and acted as a threshold-lowering influence associated with symptom onset.
- Full Text:
- Authors: Bold, Lisa Clare
- Date: 2000
- Subjects: Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2935 , http://hdl.handle.net/10962/d1002444 , Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Description: This study investigates the effects of cumulative mild head injury on the cognitive functioning of elite rugby players. A comprehensive battery of neuropsychological tests was administered to top national (Springbok) rugby players (n=26), national Under 21 rugby players (n= 19), and a non-contact sport control group of national hockey players (n=21). The test results of the Total Rugby group (Springbok Rugby and Under 21 Rugby players), the Under 21 Rugby group, the hockey controls, and the Total Rugby and Under 21 Rugby forward and backline players respectively, were each compared with established normative data. Results showed significant differences in the direction of a poorer performance relative to the norms for the Total Rugby and Under 21 Rugby groups, and for the Total Rugby Forwards and Under 21 Rugby Forwards, on tests sensitive to the effects of diffuse brain damage. On the other hand, the Hockey Control group and the Total Rugby Backs and Under 21 Rugby Backs tended to perform within the normal range or better than the norm on some tests. These results confirm the hypothesis that rugby players, and the forward players in particular, are at risk of adverse cognitive effects consequent on cumulative mild head injury. The theoretical implications are that the aggregate effects of multiple exposures to mild head injuries in the rugby players served to reduce their brain reserve capacities and acted as a threshold-lowering influence associated with symptom onset.
- Full Text: