Photochemically induced electron transfer between sulfur dioxide and tin (IV) mono-and di-phthalocyanines
- Nensala, Ngudiankama, Nzimande, Ayanda, Nyokong, Tebello
- Authors: Nensala, Ngudiankama , Nzimande, Ayanda , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293402 , vital:57082 , xlink:href="https://doi.org/10.1016/1010-6030(96)04344-4"
- Description: Photolysis, using radiation from a tungsten lamp, of tin diphthalocyanine (Pc2Sn(IV)) in dichloromethane containing SO2 results in the one-electron oxidation of this species to [Pc(−2)Sn(IV)Pc(−1)]+. The relative quantum yields for the formation of the oxidized species were in the order of 10−3. The one-electron oxidized complex was also formed when Pc2Sn was photolysed in an acetonitrile/dichloromethane solvent mixture. Photolysis of the monomeric (L)2Sn(IV)Pc(LOH−, Cl−, Br− and F−) in pyridine and in the presence of SO2 resulted in the reduction of these species to (L)2Sn(IV)Pc(−3)]− with quantum yields in the order of 10−2.
- Full Text:
- Authors: Nensala, Ngudiankama , Nzimande, Ayanda , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293402 , vital:57082 , xlink:href="https://doi.org/10.1016/1010-6030(96)04344-4"
- Description: Photolysis, using radiation from a tungsten lamp, of tin diphthalocyanine (Pc2Sn(IV)) in dichloromethane containing SO2 results in the one-electron oxidation of this species to [Pc(−2)Sn(IV)Pc(−1)]+. The relative quantum yields for the formation of the oxidized species were in the order of 10−3. The one-electron oxidized complex was also formed when Pc2Sn was photolysed in an acetonitrile/dichloromethane solvent mixture. Photolysis of the monomeric (L)2Sn(IV)Pc(LOH−, Cl−, Br− and F−) in pyridine and in the presence of SO2 resulted in the reduction of these species to (L)2Sn(IV)Pc(−3)]− with quantum yields in the order of 10−2.
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Routing MIDI messages over Ethernet
- Foss, Richard, Mosala, Thabo
- Authors: Foss, Richard , Mosala, Thabo
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427486 , vital:72442 , https://www.aes.org/e-lib/browse.cfm?elib=7898
- Description: A system known as the MIDINet system has been created,which routes MIDI messages between MIDI-compatible source and destination devices. These devices are attached to nodes which in turn are linked into an Ethernet network. Message routing is facilitated by the MIDINet protocol, which is a layer above standard Ethernet. The performance of the system has been measured and documented. In order to address the nondeterminism of Ethernet, a token bus protocol layer has been introduced between the Ethernet and MIDINet layers. The MIDINet system is being used to enhance MIDI routing in a music studio network where studio resources are shared between remote music stations.
- Full Text:
- Authors: Foss, Richard , Mosala, Thabo
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427486 , vital:72442 , https://www.aes.org/e-lib/browse.cfm?elib=7898
- Description: A system known as the MIDINet system has been created,which routes MIDI messages between MIDI-compatible source and destination devices. These devices are attached to nodes which in turn are linked into an Ethernet network. Message routing is facilitated by the MIDINet protocol, which is a layer above standard Ethernet. The performance of the system has been measured and documented. In order to address the nondeterminism of Ethernet, a token bus protocol layer has been introduced between the Ethernet and MIDINet layers. The MIDINet system is being used to enhance MIDI routing in a music studio network where studio resources are shared between remote music stations.
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Spectroelectrochemical studies of tin (IV) diphthalocyanine
- Nensala, Ngudiankama, Nyokong, Tebello
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293436 , vital:57085 , xlink:href="https://doi.org/10.1016/0277-5387(95)00325-1"
- Description: Cyclic voltammetry of tin(IV) diphthalocyanine (Pc2Sn) in dichloromethane containing TEAP shows two reduction couples at −0.56 and −0.89 versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE; all were quasireversible one-electron couples. The oxidation couple corresponds to [Pc(−1)SnIVPc(−2)+/Pc(−2)SnIVPc(−2) and the reduction couples to Pc(−2)SnIVPc(−2)/[Pc(−3)SnIVPc(−2)]− and [Pc(−3)SnIVPc(−2)]−/[Pc(−3)SnIVPc(−3)]2−, respectively. The electronic absorption spectra of the various reduced or oxidized tin(IV) diphthalocyanine species are reported.
- Full Text:
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293436 , vital:57085 , xlink:href="https://doi.org/10.1016/0277-5387(95)00325-1"
- Description: Cyclic voltammetry of tin(IV) diphthalocyanine (Pc2Sn) in dichloromethane containing TEAP shows two reduction couples at −0.56 and −0.89 versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE; all were quasireversible one-electron couples. The oxidation couple corresponds to [Pc(−1)SnIVPc(−2)+/Pc(−2)SnIVPc(−2) and the reduction couples to Pc(−2)SnIVPc(−2)/[Pc(−3)SnIVPc(−2)]− and [Pc(−3)SnIVPc(−2)]−/[Pc(−3)SnIVPc(−3)]2−, respectively. The electronic absorption spectra of the various reduced or oxidized tin(IV) diphthalocyanine species are reported.
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Stars to Buses to Stars-The Evolution of Remote Studio Access Topologies
- Authors: Foss, Richard
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427444 , vital:72439 , https://www.aes.org/e-lib/browse.cfm?elib=7428
- Description: This paper describes an ongoing investigation into the use of networking technology to provide access to shared music studio resources. The goal of the investigation is to see whether it is possible to provide remote, shared, and centralized access to studio resources. The investigation has followed an evolutionary path along which three configurations have been identified and completely or partially implemented. The configurations provide various paths for the flow of MIDI, audio, and studio control data.
- Full Text:
- Authors: Foss, Richard
- Date: 1996
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427444 , vital:72439 , https://www.aes.org/e-lib/browse.cfm?elib=7428
- Description: This paper describes an ongoing investigation into the use of networking technology to provide access to shared music studio resources. The goal of the investigation is to see whether it is possible to provide remote, shared, and centralized access to studio resources. The investigation has followed an evolutionary path along which three configurations have been identified and completely or partially implemented. The configurations provide various paths for the flow of MIDI, audio, and studio control data.
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Suppositories: An underutilized dosage form
- Webster, Jessica A, Dowse, Roslind, Walker, Roderick B
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184697 , vital:44264 , xlink:href="https://hdl.handle.net/10520/AJA16836707_911"
- Description: The rectal route is useful for the delivery of both local acting and systemic drugs. In certain cases suppositories are the best form of therapy, or else they are an effective alternative when oral therapy is not possible. However; doctors rarely prescribe them and patients are often reluctant to use them. Understanding how suppositories work, and their numerous uses, can overcome the aversion to this particular dosage form. Pharmacists are in an ideal position to educate doctors, other health care providers, and patients, on the benefits of using suppositories and their correct use, and to offer advice on any problems associated with their use.
- Full Text:
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184697 , vital:44264 , xlink:href="https://hdl.handle.net/10520/AJA16836707_911"
- Description: The rectal route is useful for the delivery of both local acting and systemic drugs. In certain cases suppositories are the best form of therapy, or else they are an effective alternative when oral therapy is not possible. However; doctors rarely prescribe them and patients are often reluctant to use them. Understanding how suppositories work, and their numerous uses, can overcome the aversion to this particular dosage form. Pharmacists are in an ideal position to educate doctors, other health care providers, and patients, on the benefits of using suppositories and their correct use, and to offer advice on any problems associated with their use.
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Addendum to the paper Landcare: New directions in professional development for environmental education
- Authors: Lotz-Sisitka, Heila
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438672 , vital:73488 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137475"
- Description: During 1994-1995, we received correspondence from Tania Sadler of the University of Tasmania and from Debbie Heck, about the latter's paper published in volume 14. In response we publish the following addendum, which includes a list of references inadvertently left out of her paper. Ms Heck did supply these references to the SAJEE originally, and we apologise for any inconvenience to readers as a result of the mistake. (Ed.)
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- Authors: Lotz-Sisitka, Heila
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438672 , vital:73488 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137475"
- Description: During 1994-1995, we received correspondence from Tania Sadler of the University of Tasmania and from Debbie Heck, about the latter's paper published in volume 14. In response we publish the following addendum, which includes a list of references inadvertently left out of her paper. Ms Heck did supply these references to the SAJEE originally, and we apologise for any inconvenience to readers as a result of the mistake. (Ed.)
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Editorial
- Authors: Janse van Rensburg, Eureta
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438706 , vital:73493 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137460"
- Description: This edition of the SAJEE focuses on EEASA' s conference-and-workshops held in July 1995, at Kearsney College in Kwazulu Natal, South Africa. ln the 1994 issue we invited readers to explore Progress and Paradox, as a conference theme reflecting a new perspective on education and environment. We received a very positive response and the conference featured an excellent range of papers. From amongst the many worthy contributions the reviewers selected those papers that addressed the theme most directly, for publication in this, arguably EEASA' s best journal yet.
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- Authors: Janse van Rensburg, Eureta
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438706 , vital:73493 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137460"
- Description: This edition of the SAJEE focuses on EEASA' s conference-and-workshops held in July 1995, at Kearsney College in Kwazulu Natal, South Africa. ln the 1994 issue we invited readers to explore Progress and Paradox, as a conference theme reflecting a new perspective on education and environment. We received a very positive response and the conference featured an excellent range of papers. From amongst the many worthy contributions the reviewers selected those papers that addressed the theme most directly, for publication in this, arguably EEASA' s best journal yet.
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Equilibrium and kinetic studies of the reaction between pyridine and cobalt (II) phthalocyanine in DMSO
- Authors: Nyokong, Tebello
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293380 , vital:57080 , xlink:href="https://doi.org/10.1016/0277-5387(95)00090-F"
- Description: Kinetics and equilibria for the reaction between pyridine and cobalt(II) phthalocyanine [CoPc] (H2Pc = phthalocyanine) in dimethyl sulphoxide (DMSO) were studied at 25°C. The complex, CoPc(py)2, is formed in two consecutive steps. The formation of the mono-substituted CoPc(py)(DMSO) occurs first with a pseudo-first-order rate constant of k1f = 7.7 ± 0.3 × 10−3 dm3 mol−1 s−1. The final disubstituted CoPc(py)2 complex is formed with k2f= 1.1 ± 0.1 × 10−4dm3mol−1−1. The equilibrium constants were found to be K1 = 160 ± 20dm3 mol−1 and K2 = 15 ± 3 dm3mol−1 for the formation of CoPc(py)(DMSO) and CoPc(py)2, respectively.
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- Authors: Nyokong, Tebello
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293380 , vital:57080 , xlink:href="https://doi.org/10.1016/0277-5387(95)00090-F"
- Description: Kinetics and equilibria for the reaction between pyridine and cobalt(II) phthalocyanine [CoPc] (H2Pc = phthalocyanine) in dimethyl sulphoxide (DMSO) were studied at 25°C. The complex, CoPc(py)2, is formed in two consecutive steps. The formation of the mono-substituted CoPc(py)(DMSO) occurs first with a pseudo-first-order rate constant of k1f = 7.7 ± 0.3 × 10−3 dm3 mol−1 s−1. The final disubstituted CoPc(py)2 complex is formed with k2f= 1.1 ± 0.1 × 10−4dm3mol−1−1. The equilibrium constants were found to be K1 = 160 ± 20dm3 mol−1 and K2 = 15 ± 3 dm3mol−1 for the formation of CoPc(py)(DMSO) and CoPc(py)2, respectively.
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Resource materials development in environmental education : Exploring some of the myths and tensions in participatory resource development in the We Care Primary Project
- Authors: Lotz-Sisitka, Heila
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438792 , vital:73500 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137472"
- Description: This paper on environmental education resource materials development represents some of my 'lived experience' (Malone, 1994:20) as a researcher involved in clarifying the processes of materials development for junior primary classrooms. The sites of inquiry, action and reflection have been focussed around the development of the We Care Primary materials, shifts in orientations to environmental education and current educational change.
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- Authors: Lotz-Sisitka, Heila
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438792 , vital:73500 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137472"
- Description: This paper on environmental education resource materials development represents some of my 'lived experience' (Malone, 1994:20) as a researcher involved in clarifying the processes of materials development for junior primary classrooms. The sites of inquiry, action and reflection have been focussed around the development of the We Care Primary materials, shifts in orientations to environmental education and current educational change.
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The reaction of cyanide with iron (II) hexadecachlorophthalocyanine
- Authors: Nyokong, Tebello
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293447 , vital:57086 , xlink:href="https://doi.org/10.1016/0277-5387(94)00291-L"
- Description: Kinetics and equilibria for the reaction between cyanide and iron(II) hexadecachlorophthalocyanine ((Cl)16PcFe(DMSO)2, where Pc(−2) = phthalocyanine dianion) in dimethyl sulphoxide (DMSO) are reported. Only the spectrophotometric changes due to the formation of the dicyano, [(Cl)16PcFe(CN)2]2−, complex were observed. This complex is formed with the equilibrium constant, K3 = 1.6 × 103 dm3 mol−1 and a rate constant of k3f = 4.2 × 10−3 dm3 mol−1 s−1. The K2[(Cl)16PcFe(CN)2] complex dissolves in DMSO and dimethyl formamide (DMF) with ϵ = 110 000 and 92 000 dm3 mol−1 cm−1, respectively.
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- Authors: Nyokong, Tebello
- Date: 1995
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293447 , vital:57086 , xlink:href="https://doi.org/10.1016/0277-5387(94)00291-L"
- Description: Kinetics and equilibria for the reaction between cyanide and iron(II) hexadecachlorophthalocyanine ((Cl)16PcFe(DMSO)2, where Pc(−2) = phthalocyanine dianion) in dimethyl sulphoxide (DMSO) are reported. Only the spectrophotometric changes due to the formation of the dicyano, [(Cl)16PcFe(CN)2]2−, complex were observed. This complex is formed with the equilibrium constant, K3 = 1.6 × 103 dm3 mol−1 and a rate constant of k3f = 4.2 × 10−3 dm3 mol−1 s−1. The K2[(Cl)16PcFe(CN)2] complex dissolves in DMSO and dimethyl formamide (DMF) with ϵ = 110 000 and 92 000 dm3 mol−1 cm−1, respectively.
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Cyclic voltammetry and photooxidation of molybdenum (V) phthalocyanine
- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295475 , vital:57344 , xlink:href="https://doi.org/10.1016/S0277-5387(00)86594-8"
- Description: Cyclic voltammetry of OMoV(OH)Pc in chloronaphthalene shows two quasi-reversible oxidation couples at 0.38 and 1.22 V and three quasi-reversible reduction couples at −0.74, −1.15 and −1.85 V vs S.C.E. Bulk electrolysis of OMoV(OH)Pc (Pc2 = phthalocyanine dianion) shows that the first oxidation couple is due to the oxidation of the central MoV metal to MoVI and the first reduction couple due to reduction to OMoIVPc. Cyclic voltammetry and spectroelectrochemistry in DMSO also showed redox activity at the metal. Further reductions or oxidations in OMoVPc complexes occur at the phthalocyanine ring. OMoV(OH)Pc is readily photooxidized at the metal in the presence dichloromethane or dichlorobenzene, with the formation of OMoVIPc species.
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- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295475 , vital:57344 , xlink:href="https://doi.org/10.1016/S0277-5387(00)86594-8"
- Description: Cyclic voltammetry of OMoV(OH)Pc in chloronaphthalene shows two quasi-reversible oxidation couples at 0.38 and 1.22 V and three quasi-reversible reduction couples at −0.74, −1.15 and −1.85 V vs S.C.E. Bulk electrolysis of OMoV(OH)Pc (Pc2 = phthalocyanine dianion) shows that the first oxidation couple is due to the oxidation of the central MoV metal to MoVI and the first reduction couple due to reduction to OMoIVPc. Cyclic voltammetry and spectroelectrochemistry in DMSO also showed redox activity at the metal. Further reductions or oxidations in OMoVPc complexes occur at the phthalocyanine ring. OMoV(OH)Pc is readily photooxidized at the metal in the presence dichloromethane or dichlorobenzene, with the formation of OMoVIPc species.
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Cyclic voltammetry and spectroelectrochemistry of rhodium phthalocyanines
- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295486 , vital:57346 , xlink:href="https://doi.org/10.1039/DT9940001359"
- Description: The electrochemistry of RhIII(pc)(pc = phthalocyanine dianion) complexes containing chloride, pyridine, dimethyl sulfoxide (dmso) and cyanide as axial ligands was investigated by cyclic voltammetry and UV/VIS spectroelectrochemistry. The compounds were K[Rh(pc)(CN)2], [Rh(pc)(Cl)(py)] and [Rh(pc)Cl(dmso)]. For all of these the first oxidation occurs at the phthalocyanine ligand with the formation of a π-cation radical species. The addition of one electron to the complexes leads to one of two different reduction products depending on the nature of the axial ligands. The first reduction of [Rh(pc)Cl(py)] and [Rh(pc)Cl(dmso)] occurs at the metal, followed by rapid dimerization of the reduced species. The first and subsequent reductions of K[Rh(pc)(CN)2] occur at the ring.
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- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295486 , vital:57346 , xlink:href="https://doi.org/10.1039/DT9940001359"
- Description: The electrochemistry of RhIII(pc)(pc = phthalocyanine dianion) complexes containing chloride, pyridine, dimethyl sulfoxide (dmso) and cyanide as axial ligands was investigated by cyclic voltammetry and UV/VIS spectroelectrochemistry. The compounds were K[Rh(pc)(CN)2], [Rh(pc)(Cl)(py)] and [Rh(pc)Cl(dmso)]. For all of these the first oxidation occurs at the phthalocyanine ligand with the formation of a π-cation radical species. The addition of one electron to the complexes leads to one of two different reduction products depending on the nature of the axial ligands. The first reduction of [Rh(pc)Cl(py)] and [Rh(pc)Cl(dmso)] occurs at the metal, followed by rapid dimerization of the reduced species. The first and subsequent reductions of K[Rh(pc)(CN)2] occur at the ring.
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Editorial
- Janse van Rensburg, Eureta, Irwin, Pat
- Authors: Janse van Rensburg, Eureta , Irwin, Pat
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438694 , vital:73491 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137493"
- Description: In 1993 environmental education was looking forward to the first democratic election in South Africa - now it is in the midst of 'reconstructionand-development'. For many local environmental educators, this means a contrihution, in one way or another, to the new national curriculum. But the challenges of 1993 continue: processes of participative curriculum development are forcing us to clarify different orientations to environmental education in our efforts to shape a curriculum based on the best of our various visions.
- Full Text:
- Authors: Janse van Rensburg, Eureta , Irwin, Pat
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438694 , vital:73491 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137493"
- Description: In 1993 environmental education was looking forward to the first democratic election in South Africa - now it is in the midst of 'reconstructionand-development'. For many local environmental educators, this means a contrihution, in one way or another, to the new national curriculum. But the challenges of 1993 continue: processes of participative curriculum development are forcing us to clarify different orientations to environmental education in our efforts to shape a curriculum based on the best of our various visions.
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Local government and coloured residential segregation in Port Elizabeth, 1964-1976
- Authors: Taylor, Beverley J
- Date: 1994
- Language: English
- Type: text , article
- Identifier: vital:7108 , https://doi.org/10.1080/03736245.1994.9713566 , http://hdl.handle.net/10962/d1010736
- Description: preprint , Studies of racial territorial segregation affecting the coloured population in Port Elizabeth tend to perceive it as an outcome of a power struggle between central and local government over the implementation of apartheid legislation. This paper explores the underlying economic forces on the local government to bring about residential segregation and address the coloured housing crisis in the city. It is proposed that whereas central government motives for segregation were primarily political, local government was influenced largely by economic considerations. Local government objectives were severely compromised through both local industrial interests and the implementation of central government Group Areas policies.
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- Authors: Taylor, Beverley J
- Date: 1994
- Language: English
- Type: text , article
- Identifier: vital:7108 , https://doi.org/10.1080/03736245.1994.9713566 , http://hdl.handle.net/10962/d1010736
- Description: preprint , Studies of racial territorial segregation affecting the coloured population in Port Elizabeth tend to perceive it as an outcome of a power struggle between central and local government over the implementation of apartheid legislation. This paper explores the underlying economic forces on the local government to bring about residential segregation and address the coloured housing crisis in the city. It is proposed that whereas central government motives for segregation were primarily political, local government was influenced largely by economic considerations. Local government objectives were severely compromised through both local industrial interests and the implementation of central government Group Areas policies.
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Photoassisted electron transfer between sulfur dioxide and tin (IV) phthalocyanines
- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295520 , vital:57349 , xlink:href="https://doi.org/10.1039/C39940001983"
- Description: Photolysis of tin(IV) phthalocyanine complexes in the presence of sulfur dioxide shows a first-order kinetic dependence on sulfur dioxide, and a one-electron reduction of SnPc to an anion radical species.
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- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295520 , vital:57349 , xlink:href="https://doi.org/10.1039/C39940001983"
- Description: Photolysis of tin(IV) phthalocyanine complexes in the presence of sulfur dioxide shows a first-order kinetic dependence on sulfur dioxide, and a one-electron reduction of SnPc to an anion radical species.
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Photoreduction of tin (IV) phthalocyanines
- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293413 , vital:57083 , xlink:href="https://doi.org/10.1016/S0277-5387(00)83491-9"
- Description: Photolysis of Sn(IV)Pc(OH)2 (Pc = phthalocyanine dianion) and Sn(IV)Pc(Cl)2 using a tungsten lamp, and in the presence of SnCl2·2H2O as an electron donor results in the reduction of these complexes of π anion radical species. The reduction shows second order dependence on the concentration of the Sn(IV)Pc complexes and a first order dependence on SnCl2·H2O.
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- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293413 , vital:57083 , xlink:href="https://doi.org/10.1016/S0277-5387(00)83491-9"
- Description: Photolysis of Sn(IV)Pc(OH)2 (Pc = phthalocyanine dianion) and Sn(IV)Pc(Cl)2 using a tungsten lamp, and in the presence of SnCl2·2H2O as an electron donor results in the reduction of these complexes of π anion radical species. The reduction shows second order dependence on the concentration of the Sn(IV)Pc complexes and a first order dependence on SnCl2·H2O.
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Promotion of the Etendeka Formation to Group status: a new integrated stratigraphy
- Milner, Simon C, Duncan, Andrew R, Ewart, A, Marsh, Julian S
- Authors: Milner, Simon C , Duncan, Andrew R , Ewart, A , Marsh, Julian S
- Date: 1994
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145482 , vital:38442
- Description: The Etendeka volcanic rocks of northwestem Namibia are currently defined as the upper part of the Karoo Sequence in Namibia and have thus been represented as stratigraphically equivalent to the volcanic rocks of the Karoo Sequence in South Africa, Botswana, Lesotho, Swaziland and Zimbabwe. However, the Etendeka volcanic rocks (130-135 Ma) are considerably younger than those of the Karoo Sequence (180-190 Ma) in the areas mentioned above. They are compositionally distinct from Karoo volcanic rocks, and constitute an eastern portion of the Parana Igneous Province of Brazil. Stratigraphic studies have shown the Etendeka Formation to be made up of several definable volcanic successions and it is suggested that these successions now be formally recognized as Formations within an Etendeka Group which itself should no longer be part of the Karoo Sequence. Prominent quartz latite units and sequences of basalt flows are defined as Members within the new Formations.
- Full Text:
- Authors: Milner, Simon C , Duncan, Andrew R , Ewart, A , Marsh, Julian S
- Date: 1994
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145482 , vital:38442
- Description: The Etendeka volcanic rocks of northwestem Namibia are currently defined as the upper part of the Karoo Sequence in Namibia and have thus been represented as stratigraphically equivalent to the volcanic rocks of the Karoo Sequence in South Africa, Botswana, Lesotho, Swaziland and Zimbabwe. However, the Etendeka volcanic rocks (130-135 Ma) are considerably younger than those of the Karoo Sequence (180-190 Ma) in the areas mentioned above. They are compositionally distinct from Karoo volcanic rocks, and constitute an eastern portion of the Parana Igneous Province of Brazil. Stratigraphic studies have shown the Etendeka Formation to be made up of several definable volcanic successions and it is suggested that these successions now be formally recognized as Formations within an Etendeka Group which itself should no longer be part of the Karoo Sequence. Prominent quartz latite units and sequences of basalt flows are defined as Members within the new Formations.
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Redox reactions of an Mo (V) tetrasulfophthalocyanine
- Ferraudi, Guillermo, Nyokong, Tebello, Feliz, Mario, Perkovic, Marc, Rillema, D Paul
- Authors: Ferraudi, Guillermo , Nyokong, Tebello , Feliz, Mario , Perkovic, Marc , Rillema, D Paul
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295530 , vital:57351 , xlink:href="https://doi.org/10.1016/0020-1693(93)03664-V"
- Description: The preparation of an Mo(V) tetrasulfophthalocyanine and some of its thermal and photochemical reactions have been investigated in this work. Electrochemical processes have been followed by means of the UVVis spectral changes and compared with those observed in flash photolysis. Mo(IV) and Mo(V)-ligand-radical species are common intermediates of the electrochemical and photochemical reactions. In 254 nm irradiations of the Mo(V) tetrasulfophthalocyanine in aqueous solutions of 2-propanol, the macrocycle can be photohydrogenated and the product of the photolysis can be reoxidized with O2 back to the parent complex.
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- Authors: Ferraudi, Guillermo , Nyokong, Tebello , Feliz, Mario , Perkovic, Marc , Rillema, D Paul
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295530 , vital:57351 , xlink:href="https://doi.org/10.1016/0020-1693(93)03664-V"
- Description: The preparation of an Mo(V) tetrasulfophthalocyanine and some of its thermal and photochemical reactions have been investigated in this work. Electrochemical processes have been followed by means of the UVVis spectral changes and compared with those observed in flash photolysis. Mo(IV) and Mo(V)-ligand-radical species are common intermediates of the electrochemical and photochemical reactions. In 254 nm irradiations of the Mo(V) tetrasulfophthalocyanine in aqueous solutions of 2-propanol, the macrocycle can be photohydrogenated and the product of the photolysis can be reoxidized with O2 back to the parent complex.
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Research priorities for environmental education in southern Africa: Preliminary report
- Authors: Janse van Rensburg, Eureta
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438781 , vital:73499 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137480"
- Description: In this preliminary research report I introduce initial interpretations of the results of a recently completed study on research priorities in southern Africa. The study has been sponsored by Murray and Roberts, Rhodes University and the HNRE (Human and Natural Resources in the Environment) Programme of the Human Sciences Research Council.
- Full Text:
- Authors: Janse van Rensburg, Eureta
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438781 , vital:73499 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137480"
- Description: In this preliminary research report I introduce initial interpretations of the results of a recently completed study on research priorities in southern Africa. The study has been sponsored by Murray and Roberts, Rhodes University and the HNRE (Human and Natural Resources in the Environment) Programme of the Human Sciences Research Council.
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The first Bothriolepsis-associated Devonian fish fauna from Africa
- Anderson, M Eric, Hiller, Norton, Gess, Robert W
- Authors: Anderson, M Eric , Hiller, Norton , Gess, Robert W
- Date: 1994
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/73852 , vital:30235 , https://journals.co.za/content/sajsci/90/7/AJA00382353_5900
- Description: An advanced diplacanthid (Climatiiformes) is described from a Famennian estuarine environment of South Africa. It is characterized by having exceptionally long thin fin spines and a deep body form. Unusual details of the fins and fin spine insertions are preserved. This is the first record of a diplacanthid from the Southern Hemisphere.
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- Authors: Anderson, M Eric , Hiller, Norton , Gess, Robert W
- Date: 1994
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/73852 , vital:30235 , https://journals.co.za/content/sajsci/90/7/AJA00382353_5900
- Description: An advanced diplacanthid (Climatiiformes) is described from a Famennian estuarine environment of South Africa. It is characterized by having exceptionally long thin fin spines and a deep body form. Unusual details of the fins and fin spine insertions are preserved. This is the first record of a diplacanthid from the Southern Hemisphere.
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