Maintenance management systems of on-campus student hostels at Nigerian universities
- Authors: Adamu, Anita Dzikwi
- Date: 2015
- Subjects: School buildings -- Maintenance and repair , Dormitories -- Nigeria , Nigeria -- Student housing
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9710 , http://hdl.handle.net/10948/d1020168
- Description: Most universities have long recognised the importance and contribution of on-campus hostels to the learning process. In so doing, most of these institutions have provided and maintained building facilities for academic purposes (teaching and research). Hostels are integral components of most campuses of Nigerian universities, and they are part of the built assets of the institutions in terms of both administration and maintenance management. Currently, there is little understanding of the maintenance management systems of on-campus hostel buildings in both the public and the private universities. Moreover, there is a dearth of research evidence demonstrating that there is an appreciable difference in the maintenance management systems of the Federal, State and private universities in Nigeria. This research aimed at establishing an understanding of maintenance management systems of on-campus hostel buildings at Nigerian universities owned by the Federal and State governments and the Private Sector, relative to stipulated criteria for best practice.The qualitative method of research inquiry that is rooted in the phenomenological paradigm was employed in the investigations. The research activities included a comprehensive review of the related literature and study of selected cases. The North-central geopolitical zone of Nigeria was the selected geographical scope of this research. Ten universities were purposefully selected for the study, and they include three Federal, four state and three private universities. The nature and differences in the research questions necessitated generating different forms of data. The questions that were related to the maintenance management systems for the hostels in place at the universities were addressed with the outcomes of interviews with the hostel managers. The questions that were about the structures and current conditions of the hostel buildings at the three categories of universities were addressed with data that were generated from condition assessments of the facilities and physical observations with the aid of cameras. The study reveals apparent deteriorated and unhealthy conditions of most of the on-campus hostels at the public universities, while those of the private universities are satisfactory. The research also found that the maintenance management systems in use at all the universities are reactive and lack proper planning and coordination of maintenance activities. There is no significant difference in the maintenance management systems of hostels at the public and the private universities and the systems have major negative impact on the conditions of the buildings and their performances. The research has developed a conceptual model for the study of maintenance management informed by the theoretical framework. The model considered the impact of the external environmental factors on the management and maintenance of the hostels. Secondly, the interrelationships of strategic and performance management with maintenance management in developing an effective maintenance management system were established. The study has achieved its aim of establishing an understanding of maintenance management systems of on-campus hostel buildings at Nigerian universities owned by the Federal and, State governments and the Private Sector. The maintenance management model developed in the study is recommended to maintenance management departments as a guide for effective maintenance of the built facilities in their institutions.
- Full Text:
- Date Issued: 2015
- Authors: Adamu, Anita Dzikwi
- Date: 2015
- Subjects: School buildings -- Maintenance and repair , Dormitories -- Nigeria , Nigeria -- Student housing
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9710 , http://hdl.handle.net/10948/d1020168
- Description: Most universities have long recognised the importance and contribution of on-campus hostels to the learning process. In so doing, most of these institutions have provided and maintained building facilities for academic purposes (teaching and research). Hostels are integral components of most campuses of Nigerian universities, and they are part of the built assets of the institutions in terms of both administration and maintenance management. Currently, there is little understanding of the maintenance management systems of on-campus hostel buildings in both the public and the private universities. Moreover, there is a dearth of research evidence demonstrating that there is an appreciable difference in the maintenance management systems of the Federal, State and private universities in Nigeria. This research aimed at establishing an understanding of maintenance management systems of on-campus hostel buildings at Nigerian universities owned by the Federal and State governments and the Private Sector, relative to stipulated criteria for best practice.The qualitative method of research inquiry that is rooted in the phenomenological paradigm was employed in the investigations. The research activities included a comprehensive review of the related literature and study of selected cases. The North-central geopolitical zone of Nigeria was the selected geographical scope of this research. Ten universities were purposefully selected for the study, and they include three Federal, four state and three private universities. The nature and differences in the research questions necessitated generating different forms of data. The questions that were related to the maintenance management systems for the hostels in place at the universities were addressed with the outcomes of interviews with the hostel managers. The questions that were about the structures and current conditions of the hostel buildings at the three categories of universities were addressed with data that were generated from condition assessments of the facilities and physical observations with the aid of cameras. The study reveals apparent deteriorated and unhealthy conditions of most of the on-campus hostels at the public universities, while those of the private universities are satisfactory. The research also found that the maintenance management systems in use at all the universities are reactive and lack proper planning and coordination of maintenance activities. There is no significant difference in the maintenance management systems of hostels at the public and the private universities and the systems have major negative impact on the conditions of the buildings and their performances. The research has developed a conceptual model for the study of maintenance management informed by the theoretical framework. The model considered the impact of the external environmental factors on the management and maintenance of the hostels. Secondly, the interrelationships of strategic and performance management with maintenance management in developing an effective maintenance management system were established. The study has achieved its aim of establishing an understanding of maintenance management systems of on-campus hostel buildings at Nigerian universities owned by the Federal and, State governments and the Private Sector. The maintenance management model developed in the study is recommended to maintenance management departments as a guide for effective maintenance of the built facilities in their institutions.
- Full Text:
- Date Issued: 2015
Metallophthalocyanine-gold nanoparticle conjugates for photodynamic antimicrobial chemotherapy
- Mthethwa, Thandekile Phakamisiwe
- Authors: Mthethwa, Thandekile Phakamisiwe
- Date: 2015
- Subjects: Nanochemistry , Phthalocyanines , Photochemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4543 , http://hdl.handle.net/10962/d1017923
- Description: This thesis presents the synthesis of neutral and cationic metallophthalocyanines and their gold nanoparticles conjugates. The spectroscopic characterization of these compounds is presented herein. The studies presented in this work shows that the conjugation of gold nanoparticles influenced both photophysical and photochemical properties. Gold nanoparticles were found to enhance the singlet oxygen quantum yield while lowering the fluorescence quantum yields. This work also looks at the effect of anisotropic gold nanoparticles such as nanorods and bipyramids on the photophysical behaviour of the metallophthalocyanines. The effect of the size of the gold nanorods was investigated herein. The results show that photophysical and photochemical properties can be influenced by both size and shape of the nanoparticles. Physical characterization about the loading of nanoparticles was also looked into. Parameters such as the surface area, the number of surface atoms, the number of atoms as well as the number of nanoparticles loaded on the surface of the phthalocyanines were studied. The self-assembled monolayers formed by phthalocyanines on gold surfaces were studied using the X-ray photoelectron spectroscopy (XPS). The gold nanoparticles synthesized herein include both organic and water soluble, different capping agents (citrate, tetraammonium bromide (TAOBr) and cetrimethylammonium bromide (CTAB). The concentration of the gold nanoparticles was measured on the inductively coupled plasma (ICP) and their size and shape were obtained from the transmission electron microscopy (TEM) images. A cationic aluminium phthalocyanine and its conjugates were used for photoinactivation of bacteria and fungi. The results show significant reduction and higher activity in the presence of gold nanoparticles, especially nanorods. A small chapter in this work presents an attempted work on the binding of metallothionein protein with protophorphyrin (IX). The pH and concentration dependent binding studies were investigated
- Full Text:
- Date Issued: 2015
- Authors: Mthethwa, Thandekile Phakamisiwe
- Date: 2015
- Subjects: Nanochemistry , Phthalocyanines , Photochemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4543 , http://hdl.handle.net/10962/d1017923
- Description: This thesis presents the synthesis of neutral and cationic metallophthalocyanines and their gold nanoparticles conjugates. The spectroscopic characterization of these compounds is presented herein. The studies presented in this work shows that the conjugation of gold nanoparticles influenced both photophysical and photochemical properties. Gold nanoparticles were found to enhance the singlet oxygen quantum yield while lowering the fluorescence quantum yields. This work also looks at the effect of anisotropic gold nanoparticles such as nanorods and bipyramids on the photophysical behaviour of the metallophthalocyanines. The effect of the size of the gold nanorods was investigated herein. The results show that photophysical and photochemical properties can be influenced by both size and shape of the nanoparticles. Physical characterization about the loading of nanoparticles was also looked into. Parameters such as the surface area, the number of surface atoms, the number of atoms as well as the number of nanoparticles loaded on the surface of the phthalocyanines were studied. The self-assembled monolayers formed by phthalocyanines on gold surfaces were studied using the X-ray photoelectron spectroscopy (XPS). The gold nanoparticles synthesized herein include both organic and water soluble, different capping agents (citrate, tetraammonium bromide (TAOBr) and cetrimethylammonium bromide (CTAB). The concentration of the gold nanoparticles was measured on the inductively coupled plasma (ICP) and their size and shape were obtained from the transmission electron microscopy (TEM) images. A cationic aluminium phthalocyanine and its conjugates were used for photoinactivation of bacteria and fungi. The results show significant reduction and higher activity in the presence of gold nanoparticles, especially nanorods. A small chapter in this work presents an attempted work on the binding of metallothionein protein with protophorphyrin (IX). The pH and concentration dependent binding studies were investigated
- Full Text:
- Date Issued: 2015
Methods to improve the effective implementation of organisational codes of conduct
- Robinson, Bryan Michael Kenneth
- Authors: Robinson, Bryan Michael Kenneth
- Date: 2015
- Subjects: Business ethics , Organizational behavior -- Moral and ethical aspects
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/6541 , vital:21105
- Description: This research explores methods to improve code of conduct effectiveness. Misconduct is a common phenomenon in the business environment, even in the face of increased regulation, and the adoption of codes of conduct by organisations. This impacts negatively on organisations’ reputations, results in financial loss, and has a negative impact on the sustainability of businesses. While researchers suggest that codes of conduct should reduce misconduct and improve the ethical culture of organisations, mixed research results suggest codes of conduct are not always effective. While research into code of conduct effectiveness proliferates, seldom does such research take a holistic approach to understanding effectiveness of codes of conduct. Models proposed to better research code of conduct effectiveness, such as Kaptein and Schwartz’ (2008) integrated research model, do not present guidelines for better developing and implementing codes of conduct. Therefore the primary research objective was to develop a benchmarking framework which could provide insight into factors that could influence code of conduct effectiveness, and provide guidelines on how these factors should be influenced and accounted for to improve code of conduct effectiveness. Content of codes of conduct can play an important part in code of conduct effectiveness, yet they vary enormously in terms of provisions, language, tone, style, design. Some are directional or rules based, others aspirational, or values based. Bettcher, Deshpandé, Margolis and Paine (2005) developed the Global Business Standards Codex that depicted the most commonly found provisions in organisations they surveyed. A secondary research objective was therefore to apply this codex to the evaluation of participating organisations codes of conduct, and in so doing, evaluate the suitability of the codex as a benchmarking framework for the content of the code of conduct. Adopting a grounded theory methodological approach and code of conduct content analysis, the researcher investigated nine of South Africa’s largest multinational organisations in order to understand the factors influencing their code of conduct effectiveness better. The research makes a significant contribution to the understanding of codes of conduct, their effectiveness, and provides practical guidelines on improving their effectiveness. This is achieved by 1) presenting nine formulae for an effective code of conduct; 2) detailing a multi-dimensional model that can facilitate the effectiveness of codes of conduct; and 3) improving the codex developed by Bettcher et al. (2005) on the content of codes of conduct with the proposed code of conduct architecture criterion.
- Full Text:
- Date Issued: 2015
- Authors: Robinson, Bryan Michael Kenneth
- Date: 2015
- Subjects: Business ethics , Organizational behavior -- Moral and ethical aspects
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/6541 , vital:21105
- Description: This research explores methods to improve code of conduct effectiveness. Misconduct is a common phenomenon in the business environment, even in the face of increased regulation, and the adoption of codes of conduct by organisations. This impacts negatively on organisations’ reputations, results in financial loss, and has a negative impact on the sustainability of businesses. While researchers suggest that codes of conduct should reduce misconduct and improve the ethical culture of organisations, mixed research results suggest codes of conduct are not always effective. While research into code of conduct effectiveness proliferates, seldom does such research take a holistic approach to understanding effectiveness of codes of conduct. Models proposed to better research code of conduct effectiveness, such as Kaptein and Schwartz’ (2008) integrated research model, do not present guidelines for better developing and implementing codes of conduct. Therefore the primary research objective was to develop a benchmarking framework which could provide insight into factors that could influence code of conduct effectiveness, and provide guidelines on how these factors should be influenced and accounted for to improve code of conduct effectiveness. Content of codes of conduct can play an important part in code of conduct effectiveness, yet they vary enormously in terms of provisions, language, tone, style, design. Some are directional or rules based, others aspirational, or values based. Bettcher, Deshpandé, Margolis and Paine (2005) developed the Global Business Standards Codex that depicted the most commonly found provisions in organisations they surveyed. A secondary research objective was therefore to apply this codex to the evaluation of participating organisations codes of conduct, and in so doing, evaluate the suitability of the codex as a benchmarking framework for the content of the code of conduct. Adopting a grounded theory methodological approach and code of conduct content analysis, the researcher investigated nine of South Africa’s largest multinational organisations in order to understand the factors influencing their code of conduct effectiveness better. The research makes a significant contribution to the understanding of codes of conduct, their effectiveness, and provides practical guidelines on improving their effectiveness. This is achieved by 1) presenting nine formulae for an effective code of conduct; 2) detailing a multi-dimensional model that can facilitate the effectiveness of codes of conduct; and 3) improving the codex developed by Bettcher et al. (2005) on the content of codes of conduct with the proposed code of conduct architecture criterion.
- Full Text:
- Date Issued: 2015
Minding your own game : self-regulation and psychological momentum among golfers
- Authors: Kingma, Graham
- Date: 2015
- Subjects: Golf -- Strategic aspects , Golf -- Psychological aspects , Athletes , Self-control , Golfers -- Conduct of life
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3260 , http://hdl.handle.net/10962/d1017883
- Description: Psychological momentum (PM) is often regarded as an important phenomenon that influences athlete performance. Nevertheless, conceptualisations of PM are criticised for being speculative, vague and impractical for scientific inquiry. In contrast, self-regulation is a long-standing, well researched concept used to explain performance outcomes, yet not clearly integrated in current PM conceptualisations. Hence, this thesis explores self-regulation relative to PM. Golf was considered to be an appropriate context for the empirical inquiries on the basis that it serves as a metaphor for managing life’s challenges. Three studies were conducted. The first study entailed a systematic conceptual analysis of PM based on previous conceptualisations and studies in relevant scientific literature. Self-regulatory processes were identified among the key psychological mechanisms and moderators related to PM. The second study aimed to identify key self-regulation strategies in PM experiences among 16 golfers. A mixed method approach including novel “walk-along” and “think aloud” data collection techniques was used. An inductive thematic analysis yielded a comprehensive typology golfing strategies. Nevertheless, the study did not find consistent strategy patterns in positive or negative PM phases. The third study explored the self-regulation of identity (ego-regulation) in relation to PM phases. A staggered multiple-baseline single-case research methodology was used with five golfers (three professionals and two amateurs). Ego-regulation was manipulated through a mindfulness-based schema mode program tailored to golf (Mindfulness for Golf; MFG). Pre-, mid- and post-intervention data showed positive changes among the participants on two dimensions of PM as well as performance outcomes. Overall the results suggest that golfers use idiosyncratic self-regulation processes to facilitate performance, but these are not directly linked to PM phases. Nonetheless, there are promising indications that enhancing ego-regulation through the MFG program facilitates positive momentum among golfers. Based on the results of the studies in this thesis, and for the sake of scientific parsimony and pragmatism, it is recommended that self-regulation models incorporating motivation are used to explain momentum in athletic activity. In this view, PM has the function of describing, not influencing, goal-driven performance
- Full Text:
- Date Issued: 2015
- Authors: Kingma, Graham
- Date: 2015
- Subjects: Golf -- Strategic aspects , Golf -- Psychological aspects , Athletes , Self-control , Golfers -- Conduct of life
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3260 , http://hdl.handle.net/10962/d1017883
- Description: Psychological momentum (PM) is often regarded as an important phenomenon that influences athlete performance. Nevertheless, conceptualisations of PM are criticised for being speculative, vague and impractical for scientific inquiry. In contrast, self-regulation is a long-standing, well researched concept used to explain performance outcomes, yet not clearly integrated in current PM conceptualisations. Hence, this thesis explores self-regulation relative to PM. Golf was considered to be an appropriate context for the empirical inquiries on the basis that it serves as a metaphor for managing life’s challenges. Three studies were conducted. The first study entailed a systematic conceptual analysis of PM based on previous conceptualisations and studies in relevant scientific literature. Self-regulatory processes were identified among the key psychological mechanisms and moderators related to PM. The second study aimed to identify key self-regulation strategies in PM experiences among 16 golfers. A mixed method approach including novel “walk-along” and “think aloud” data collection techniques was used. An inductive thematic analysis yielded a comprehensive typology golfing strategies. Nevertheless, the study did not find consistent strategy patterns in positive or negative PM phases. The third study explored the self-regulation of identity (ego-regulation) in relation to PM phases. A staggered multiple-baseline single-case research methodology was used with five golfers (three professionals and two amateurs). Ego-regulation was manipulated through a mindfulness-based schema mode program tailored to golf (Mindfulness for Golf; MFG). Pre-, mid- and post-intervention data showed positive changes among the participants on two dimensions of PM as well as performance outcomes. Overall the results suggest that golfers use idiosyncratic self-regulation processes to facilitate performance, but these are not directly linked to PM phases. Nonetheless, there are promising indications that enhancing ego-regulation through the MFG program facilitates positive momentum among golfers. Based on the results of the studies in this thesis, and for the sake of scientific parsimony and pragmatism, it is recommended that self-regulation models incorporating motivation are used to explain momentum in athletic activity. In this view, PM has the function of describing, not influencing, goal-driven performance
- Full Text:
- Date Issued: 2015
Modification and application of the decentralised wastewater treatment technology for greywater treatment to reduce water needs
- Authors: Ngqwala, Nosiphiwe P
- Date: 2015
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/103714 , vital:32290
- Description: Expected release date-April 2017
- Full Text: false
- Date Issued: 2015
- Authors: Ngqwala, Nosiphiwe P
- Date: 2015
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/103714 , vital:32290
- Description: Expected release date-April 2017
- Full Text: false
- Date Issued: 2015
Molecular systematics and biology of two closely related blowflies : Lucilia sericata and Lucilia cuprina
- Authors: Williams, Kirstin Alexa
- Date: 2015
- Subjects: Lucilia sericata , Lucilia cuprina
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5934 , http://hdl.handle.net/10962/d1017812
- Description: The greenbottle blowflies, Lucilia sericata (Meigen, 1826) and Lucilia cuprina (Wiedemann, 1830) (Diptera: Calliphoridae) are very difficult to distinguish on the basis of their external morphology. The literature suggests that these two species may be interbreeding. Sequencing two nuclear (28S rRNA and Period) and one mitochondrial (COI) gene indicated that there has been an ancient hybridization event and that mtDNA of L. sericata has become fixed in a lineage of L. cuprina through mtDNA introgression, possibly involving Wolbachia infection. This has implications for identifications of these species based on mtDNA alone. No study has shown explicitly that hybrids of L. sericata and L. cuprina can be identified morphologically. Morphological characters used to identify L. sericata and L. cuprina were scored and tested using specimens of both species and known hybrids. Discriminant function analysis of the characters successfully separated the specimens into three unambiguous groups – L. sericata, L. cuprina and hybrids. This is the first evidence that hybrids of these two species can be identified from physical characteristics.Lucilia sericata and L. cuprina have medical, veterinary and forensic importance. Knowing their distribution in South Africa would allow more effective management and utilisation of these flies. Their predicted geographic distributions in South Africa were modelled using maximum entropy analysis of selected climatic variables. The most important environmental variables in modelling their distributions were magnitude of monthly rainfall and the magnitude of the monthly maximum temperature for L. sericata, and the seasonal variation in monthly mean humidity and magnitude of monthly rainfall for L. cuprina. Both species have a widespread distribution in South Africa and one therefore cannot identify specimens of these flies by locality of capture alone.Luciliinae is a diverse and geographically widespread subfamily containing four genera - Hemipyrellia, Lucilia, Dyscritomyia and Hypopygiopsis – that all contain parasitic species ranging from saprophages to obligate parasites. The phylogenetic relationships between these genera are unclear. The 28S rRNA, COI and Period genes of 14 species of Lucilia and Hemipyrellia were partially sequenced and analysed together with 11sequences from GenBank and the Barcode of Life Database (BOLD). Lucilia sericata and L. cuprina were shown to be sister-species. Three cases of paraphylly were identified within Lucilia that affects identification of these species using mtDNA alone. Hemipyrellia consistently caused Lucilia to be paraphyletic when it was included in analyses, so Hemipyrellia should be synonymized with Lucilia. The relationships of Dyscritomyia and Hypopygiopsis to Lucilia are unclear and further studies are required. No geographic pattern was found within the different forms of parasitism within this group, but the different degrees of parasitism were phylogenetically clustered.
- Full Text:
- Date Issued: 2015
- Authors: Williams, Kirstin Alexa
- Date: 2015
- Subjects: Lucilia sericata , Lucilia cuprina
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5934 , http://hdl.handle.net/10962/d1017812
- Description: The greenbottle blowflies, Lucilia sericata (Meigen, 1826) and Lucilia cuprina (Wiedemann, 1830) (Diptera: Calliphoridae) are very difficult to distinguish on the basis of their external morphology. The literature suggests that these two species may be interbreeding. Sequencing two nuclear (28S rRNA and Period) and one mitochondrial (COI) gene indicated that there has been an ancient hybridization event and that mtDNA of L. sericata has become fixed in a lineage of L. cuprina through mtDNA introgression, possibly involving Wolbachia infection. This has implications for identifications of these species based on mtDNA alone. No study has shown explicitly that hybrids of L. sericata and L. cuprina can be identified morphologically. Morphological characters used to identify L. sericata and L. cuprina were scored and tested using specimens of both species and known hybrids. Discriminant function analysis of the characters successfully separated the specimens into three unambiguous groups – L. sericata, L. cuprina and hybrids. This is the first evidence that hybrids of these two species can be identified from physical characteristics.Lucilia sericata and L. cuprina have medical, veterinary and forensic importance. Knowing their distribution in South Africa would allow more effective management and utilisation of these flies. Their predicted geographic distributions in South Africa were modelled using maximum entropy analysis of selected climatic variables. The most important environmental variables in modelling their distributions were magnitude of monthly rainfall and the magnitude of the monthly maximum temperature for L. sericata, and the seasonal variation in monthly mean humidity and magnitude of monthly rainfall for L. cuprina. Both species have a widespread distribution in South Africa and one therefore cannot identify specimens of these flies by locality of capture alone.Luciliinae is a diverse and geographically widespread subfamily containing four genera - Hemipyrellia, Lucilia, Dyscritomyia and Hypopygiopsis – that all contain parasitic species ranging from saprophages to obligate parasites. The phylogenetic relationships between these genera are unclear. The 28S rRNA, COI and Period genes of 14 species of Lucilia and Hemipyrellia were partially sequenced and analysed together with 11sequences from GenBank and the Barcode of Life Database (BOLD). Lucilia sericata and L. cuprina were shown to be sister-species. Three cases of paraphylly were identified within Lucilia that affects identification of these species using mtDNA alone. Hemipyrellia consistently caused Lucilia to be paraphyletic when it was included in analyses, so Hemipyrellia should be synonymized with Lucilia. The relationships of Dyscritomyia and Hypopygiopsis to Lucilia are unclear and further studies are required. No geographic pattern was found within the different forms of parasitism within this group, but the different degrees of parasitism were phylogenetically clustered.
- Full Text:
- Date Issued: 2015
Monetary policy transparency in Sub-Saharan Africa evidence and lessons
- Nhavira, John Davison Gondwe
- Authors: Nhavira, John Davison Gondwe
- Date: 2015
- Subjects: Monetary policy -- Africa, Sub-Saharan , Banks and banking, Central -- Africa, Sub-Saharan
- Language: English
- Type: Thesis , Doctoral , DCom
- Identifier: http://hdl.handle.net/10948/5262 , vital:20827
- Description: This research deals with achieving and maintaining price stability in Sub-Saharan Africa (SSA) through the practice of monetary-policy transparency (MPT). On the one hand, MPT refers to a monetary strategy whereby the central bank is insulated from political influence and made accountable to society through disclosure of its policies, procedures, economic models, data and forecasts, operations and political practices (such as objectives, personnel independence, and the like). On the other hand, price stability refers to achieving and maintaining low and stable levels of inflation conducive for long-term planning and poverty alleviation. The primary objective of this research was to investigate MPT in SSA as it represents a powerful means whereby economic agents’ expectations may be coordinated and managed by the central bank to achieve its societal, objective function of low inflation. The empirical evidence shows that, first, a dependent central bank is more likely to slip into hyperinflation. Second, a SADC (2008) model central bank law is not independent enough to be used as a benchmark for any central bank or as a charter for a regional central bank. Third, the degree of central bank independence in SSA is relatively lower than that in industrialised economies. Fourth, the determinants of MPT in SSA are trade openness, and financial depth that are important factors influencing policy-makers to adopt monetary-policy transparency. Fifth, MPT is associated with a decline in the inflation rate. Sixth, MPT had no significant effect on economic output, whilst trade openness was positively associated with real GDP.
- Full Text:
- Date Issued: 2015
- Authors: Nhavira, John Davison Gondwe
- Date: 2015
- Subjects: Monetary policy -- Africa, Sub-Saharan , Banks and banking, Central -- Africa, Sub-Saharan
- Language: English
- Type: Thesis , Doctoral , DCom
- Identifier: http://hdl.handle.net/10948/5262 , vital:20827
- Description: This research deals with achieving and maintaining price stability in Sub-Saharan Africa (SSA) through the practice of monetary-policy transparency (MPT). On the one hand, MPT refers to a monetary strategy whereby the central bank is insulated from political influence and made accountable to society through disclosure of its policies, procedures, economic models, data and forecasts, operations and political practices (such as objectives, personnel independence, and the like). On the other hand, price stability refers to achieving and maintaining low and stable levels of inflation conducive for long-term planning and poverty alleviation. The primary objective of this research was to investigate MPT in SSA as it represents a powerful means whereby economic agents’ expectations may be coordinated and managed by the central bank to achieve its societal, objective function of low inflation. The empirical evidence shows that, first, a dependent central bank is more likely to slip into hyperinflation. Second, a SADC (2008) model central bank law is not independent enough to be used as a benchmark for any central bank or as a charter for a regional central bank. Third, the degree of central bank independence in SSA is relatively lower than that in industrialised economies. Fourth, the determinants of MPT in SSA are trade openness, and financial depth that are important factors influencing policy-makers to adopt monetary-policy transparency. Fifth, MPT is associated with a decline in the inflation rate. Sixth, MPT had no significant effect on economic output, whilst trade openness was positively associated with real GDP.
- Full Text:
- Date Issued: 2015
My living theory of the transformational potential of my educational leadership
- Authors: Johannes, Arnold Marius
- Date: 2015
- Subjects: Educational change -- South Africa , School management and organization , Leadership
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/4079 , vital:20510
- Description: In democratic South Africa, policies place much emphasis on the need for transformational leadership. This challenges school leaders to ensure that their practice is in line with the democratic and inclusive values espoused therein. This thesis is an account of my journey of learning about educational leadership and how I attempted to influence transformation at my own school. The development of my living theory of educational management is grounded in my desire to make a positive change to the quality of teaching and learning at my school, by embodying and exemplifying such values in my leadership. My learning as an educational leader comprises my living theory on improving my educational leadership within a socially challenged context. I explain the context and problems experienced at my school and provide evidence of the need to move from the hierarchic, autocratic form of leadership, still prevailing at many South African schools. I adopted the theoretical framework of servant leadership to enable me to develop a more contextually sensitive and visionary style of leadership through critical reflection on my own practice. My stimulus for this journey of learning stemmed from the perceived contradiction between my espoused beliefs about leadership and my actual practice. My own autocratic leadership style was one of the main barriers that prevented teachers from attaining autonomy and taking on leadership roles within the school. My leadership style was more in alignment with the values of accountability, discipline and efficiency than those of care, trust and the development of the potential of others. This interrogation of my ontological values informed my subsequent interventions to improve my practice. Following an action research design, I investigated the quality of my leadership to determine which areas I needed to improve, took action to improve these and evaluated the change against the values inherent in the notion of servant-leadership. I embarked on a journey that helped me to shift my practice from being based on previously held authoritarian professional values towards values that underpin a more transformational leadership, such as care and trust. My journey of learning was guided by the tenets of self-study action research, which required critical self-reflection and holding myself accountable for my own actions The practical knowledge I gained through this self-reflection on my practice enabled me to make professional judgements, which then became conceptual knowledge in the form of a living theory generated by my research. This was made possible through a continuous process of data generation to extract evidence to test the validity of the claims to knowledge I made. Multiple sources of data (written, graphic and multimedia) were used to better understand the scope of happenings throughout the research and to monitor my practice over time. I explain how I used my improved understanding of leadership to promote collegiality for building quality relationships to promote teacher leadership for school improvement and how I subjected these claims to social and personal validation procedures. The significance of this study is that it contributes to new forms of practice and theory in terms of showing how a values-based approach to school leadership can influence positive change in teacher practice. While this study is a narrative of my practice, it is also a narrative of theorising about how my colleagues and I have come to know and how our thinking has changed about our work and ourselves. Although I had to indicate a cut-off point in this action research enquiry, the knowledge gained will continue to develop and influence my practice in the future and hopefully will be judged as useful by others in positions of leadership. The thesis is thus an original contribution to educational knowledge in the field of self-study action research. It demonstrates how sociohistorical and sociocultural insights from Apartheid to Post-Apartheid South Africa can be integrated within a living theory of transformational leadership.
- Full Text:
- Date Issued: 2015
- Authors: Johannes, Arnold Marius
- Date: 2015
- Subjects: Educational change -- South Africa , School management and organization , Leadership
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/4079 , vital:20510
- Description: In democratic South Africa, policies place much emphasis on the need for transformational leadership. This challenges school leaders to ensure that their practice is in line with the democratic and inclusive values espoused therein. This thesis is an account of my journey of learning about educational leadership and how I attempted to influence transformation at my own school. The development of my living theory of educational management is grounded in my desire to make a positive change to the quality of teaching and learning at my school, by embodying and exemplifying such values in my leadership. My learning as an educational leader comprises my living theory on improving my educational leadership within a socially challenged context. I explain the context and problems experienced at my school and provide evidence of the need to move from the hierarchic, autocratic form of leadership, still prevailing at many South African schools. I adopted the theoretical framework of servant leadership to enable me to develop a more contextually sensitive and visionary style of leadership through critical reflection on my own practice. My stimulus for this journey of learning stemmed from the perceived contradiction between my espoused beliefs about leadership and my actual practice. My own autocratic leadership style was one of the main barriers that prevented teachers from attaining autonomy and taking on leadership roles within the school. My leadership style was more in alignment with the values of accountability, discipline and efficiency than those of care, trust and the development of the potential of others. This interrogation of my ontological values informed my subsequent interventions to improve my practice. Following an action research design, I investigated the quality of my leadership to determine which areas I needed to improve, took action to improve these and evaluated the change against the values inherent in the notion of servant-leadership. I embarked on a journey that helped me to shift my practice from being based on previously held authoritarian professional values towards values that underpin a more transformational leadership, such as care and trust. My journey of learning was guided by the tenets of self-study action research, which required critical self-reflection and holding myself accountable for my own actions The practical knowledge I gained through this self-reflection on my practice enabled me to make professional judgements, which then became conceptual knowledge in the form of a living theory generated by my research. This was made possible through a continuous process of data generation to extract evidence to test the validity of the claims to knowledge I made. Multiple sources of data (written, graphic and multimedia) were used to better understand the scope of happenings throughout the research and to monitor my practice over time. I explain how I used my improved understanding of leadership to promote collegiality for building quality relationships to promote teacher leadership for school improvement and how I subjected these claims to social and personal validation procedures. The significance of this study is that it contributes to new forms of practice and theory in terms of showing how a values-based approach to school leadership can influence positive change in teacher practice. While this study is a narrative of my practice, it is also a narrative of theorising about how my colleagues and I have come to know and how our thinking has changed about our work and ourselves. Although I had to indicate a cut-off point in this action research enquiry, the knowledge gained will continue to develop and influence my practice in the future and hopefully will be judged as useful by others in positions of leadership. The thesis is thus an original contribution to educational knowledge in the field of self-study action research. It demonstrates how sociohistorical and sociocultural insights from Apartheid to Post-Apartheid South Africa can be integrated within a living theory of transformational leadership.
- Full Text:
- Date Issued: 2015
Negotiating historical continuities in contested terrain : a narrative-based reflection on the post-apartheid psychosocial legacies of conscription into the South African Defence Force
- Authors: Edlmann, Tessa Margaret
- Date: 2015
- Subjects: South Africa. National Defence Force , Draft -- South Africa -- History -- 20th century , Draft -- Psychological aspects , Masculinity -- South Africa , Sociology, Military -- South Africa , Whites -- Race identity -- South Africa , South Africa -- Politics and government -- 1948-1994 , Narrative inquiry (Research method)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2608 , http://hdl.handle.net/10962/d1012811
- Description: For a 25-year period during the apartheid era in South Africa, all school-leaving white men were issued with a compulsory call-up to national military service in the South African Defence Force. It is estimated that 600 000 men were conscripted between 1968 and 1993, undergoing military training and being deployed in Namibia, Angola and South Africa. The purpose of this system of military conscription was to support both the apartheid state’s role in the “Border War” in Namibia and Angola and the suppression of anti-apartheid resistance within South Africa. It formed part of the National Party’s strategy of a “total response” to what it perceived as the “total onslaught” of communism and African nationalism. While recruiting and training young white men was the focus of the apartheid government’s strategy, all of white South African society was caught up in supporting, contesting, avoiding and resisting this system in one way or another. Rather than being a purely military endeavour, conscription into the SADF therefore comprised a social and political system with wide-ranging ramifications. The 1994 democratic elections in South Africa heralded the advent of a very different political, social and economic system to what had gone before. The focus of this research is SADF conscripts’ narrations of identity in the contested narrative terrain of post-apartheid South Africa. The thesis begins with a contextual framing of the historical, social and political systems of which conscription was a part. Drawing on narrative psychology as a theoretical framework, the thesis explores discursive resources of whiteness, masculinities and perceptions of threat in conscripts’ narrations of identity, the construction of memory fields in narrating memories of war and possible trauma, and the notions of moral injury and moral repair in dealing with legacies of war. Using a narrative discursive approach, the thesis then reflects on historical temporal threads, and narrative patterns that emerge when analysing a range of texts about the psychosocial legacies of conscription, including interviews, research, memoirs, plays, media reports, video documentaries, blogs and photographic exhibitions. Throughout the thesis, conscripts’ and others’ accounts of conscription and its legacies are regarded as cultural texts. This serves as a means to highlight both contextual narrative negotiations and the narrative-discursive patterns of conscripts’ personal accounts of their identities in the post-apartheid narrative terrain. The original contribution of this research is the development of conceptual and theoretical framings of the post-apartheid legacies of conscription. Key to this has been the use of narrative-based approaches to highlight the narrative-discursive patterns, memory fields and negotiations of narrative terrains at work in texts that focus on various aspects of conscription and its ongoing aftereffects. The concept of temporal threads has been developed to account for the emergence and shifts in these patterns over time. Existing narrative-discursive theory has formed the basis for conscripts’ negotiations of identity being identified as acts of narrative reinforcement and narrative repair. The thesis concludes with reflections on the future possibilities for articulating and supporting narrative repair that enables a shift away from historical discursive laagers and a reconfiguration of the narrative terrain within which conscripts narrate their identities. , Also known as: Edlmann, Theresa
- Full Text:
- Date Issued: 2015
- Authors: Edlmann, Tessa Margaret
- Date: 2015
- Subjects: South Africa. National Defence Force , Draft -- South Africa -- History -- 20th century , Draft -- Psychological aspects , Masculinity -- South Africa , Sociology, Military -- South Africa , Whites -- Race identity -- South Africa , South Africa -- Politics and government -- 1948-1994 , Narrative inquiry (Research method)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2608 , http://hdl.handle.net/10962/d1012811
- Description: For a 25-year period during the apartheid era in South Africa, all school-leaving white men were issued with a compulsory call-up to national military service in the South African Defence Force. It is estimated that 600 000 men were conscripted between 1968 and 1993, undergoing military training and being deployed in Namibia, Angola and South Africa. The purpose of this system of military conscription was to support both the apartheid state’s role in the “Border War” in Namibia and Angola and the suppression of anti-apartheid resistance within South Africa. It formed part of the National Party’s strategy of a “total response” to what it perceived as the “total onslaught” of communism and African nationalism. While recruiting and training young white men was the focus of the apartheid government’s strategy, all of white South African society was caught up in supporting, contesting, avoiding and resisting this system in one way or another. Rather than being a purely military endeavour, conscription into the SADF therefore comprised a social and political system with wide-ranging ramifications. The 1994 democratic elections in South Africa heralded the advent of a very different political, social and economic system to what had gone before. The focus of this research is SADF conscripts’ narrations of identity in the contested narrative terrain of post-apartheid South Africa. The thesis begins with a contextual framing of the historical, social and political systems of which conscription was a part. Drawing on narrative psychology as a theoretical framework, the thesis explores discursive resources of whiteness, masculinities and perceptions of threat in conscripts’ narrations of identity, the construction of memory fields in narrating memories of war and possible trauma, and the notions of moral injury and moral repair in dealing with legacies of war. Using a narrative discursive approach, the thesis then reflects on historical temporal threads, and narrative patterns that emerge when analysing a range of texts about the psychosocial legacies of conscription, including interviews, research, memoirs, plays, media reports, video documentaries, blogs and photographic exhibitions. Throughout the thesis, conscripts’ and others’ accounts of conscription and its legacies are regarded as cultural texts. This serves as a means to highlight both contextual narrative negotiations and the narrative-discursive patterns of conscripts’ personal accounts of their identities in the post-apartheid narrative terrain. The original contribution of this research is the development of conceptual and theoretical framings of the post-apartheid legacies of conscription. Key to this has been the use of narrative-based approaches to highlight the narrative-discursive patterns, memory fields and negotiations of narrative terrains at work in texts that focus on various aspects of conscription and its ongoing aftereffects. The concept of temporal threads has been developed to account for the emergence and shifts in these patterns over time. Existing narrative-discursive theory has formed the basis for conscripts’ negotiations of identity being identified as acts of narrative reinforcement and narrative repair. The thesis concludes with reflections on the future possibilities for articulating and supporting narrative repair that enables a shift away from historical discursive laagers and a reconfiguration of the narrative terrain within which conscripts narrate their identities. , Also known as: Edlmann, Theresa
- Full Text:
- Date Issued: 2015
Network simulation for professional audio networks
- Authors: Otten, Fred
- Date: 2015
- Subjects: Sound engineers , Ethernet (Local area network system) , Computer networks , Computer simulation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4713 , http://hdl.handle.net/10962/d1017935
- Description: Audio Engineers are required to design and deploy large multi-channel sound systems which meet a set of requirements and use networking technologies such as Firewire and Ethernet AVB. Bandwidth utilisation and parameter groupings are among the factors which need to be considered in these designs. An implementation of an extensible, generic simulation framework would allow audio engineers to easily compare protocols and networking technologies and get near real time responses with regards to bandwidth utilisation. Our hypothesis is that an application-level capability can be developed which uses a network simulation framework to enable this process and enhances the audio engineer’s experience of designing and configuring a network. This thesis presents a new, extensible simulation framework which can be utilised to simulate professional audio networks. This framework is utilised to develop an application - AudioNetSim - based on the requirements of an audio engineer. The thesis describes the AudioNetSim models and implementations for Ethernet AVB, Firewire and the AES- 64 control protocol. AudioNetSim enables bandwidth usage determination for any network configuration and connection scenario and is used to compare Firewire and Ethernet AVB bandwidth utilisation. It also applies graph theory to the circular join problem and provides a solution to detect circular joins.
- Full Text:
- Date Issued: 2015
- Authors: Otten, Fred
- Date: 2015
- Subjects: Sound engineers , Ethernet (Local area network system) , Computer networks , Computer simulation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4713 , http://hdl.handle.net/10962/d1017935
- Description: Audio Engineers are required to design and deploy large multi-channel sound systems which meet a set of requirements and use networking technologies such as Firewire and Ethernet AVB. Bandwidth utilisation and parameter groupings are among the factors which need to be considered in these designs. An implementation of an extensible, generic simulation framework would allow audio engineers to easily compare protocols and networking technologies and get near real time responses with regards to bandwidth utilisation. Our hypothesis is that an application-level capability can be developed which uses a network simulation framework to enable this process and enhances the audio engineer’s experience of designing and configuring a network. This thesis presents a new, extensible simulation framework which can be utilised to simulate professional audio networks. This framework is utilised to develop an application - AudioNetSim - based on the requirements of an audio engineer. The thesis describes the AudioNetSim models and implementations for Ethernet AVB, Firewire and the AES- 64 control protocol. AudioNetSim enables bandwidth usage determination for any network configuration and connection scenario and is used to compare Firewire and Ethernet AVB bandwidth utilisation. It also applies graph theory to the circular join problem and provides a solution to detect circular joins.
- Full Text:
- Date Issued: 2015
Neurocognitive effects of head and body collisions on club level rugby union players
- Authors: Zoccola, Diana
- Date: 2015
- Subjects: Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3257 , http://hdl.handle.net/10962/d1016397
- Description: The objective of the study was to investigate the cumulative neurocognitive effects of repetitive concussive and subconcussive events in club level Rugby Union (hereafter rugby) during the course of one rugby season, in a combined group and individualized case-based approach. Amateur adult club level rugby players (n = 20) were compared with a non-contact control group (n = 22) of equivalent age, years of education and estimated IQ (p = > .05, in all instances), although the two groups were clearly differentiated on the basis of a history of reported concussions (p = < .05). Video analyses documented the tackling maneuvers observed amongst the players during all matches across the rugby season revealing a sobering average of more than a thousand tackles per player, excluding any contact practice sessions. Five rugby players (n = 5) who were observed to have a head jarring event were also isolated for individualized postconcussive follow-up analysis of their neurocognitive profiles. Measures included the ImPACT Verbal and Visual Memory, Visual Motor Speed and Reaction Time composites and the Purdue Pegboard. Independent and dependent statistical analyses were employed to compare the rugby versus control group neurocognitive test profiles at and between the three test intervals. Correlational analyses explored the association between concussion, tackling and neurocognitive test outcomes. Descriptive comparisons of individual neurocognitive test scores with normative data were employed for the case analyses. Taken together, the results implicated vulnerability amongst club rugby players on the motor and speeded tasks, with less robust indications on the memory tasks. While limited in terms of its small sample size, it is considered that the outcome of the study was rendered more robust by virtue of being methodologically multifaceted with heuristic implications for future research studies in the area. The novel inclusion of tackling data as well as fine-tuned case analyses, were of particular relevance in that regard. The results add to a growing body of literature that implicates deleterious neurocognitive effects in participants of a sport such as rugby due to repetitive head jarring incidents that are intrinsic to the game.
- Full Text:
- Date Issued: 2015
- Authors: Zoccola, Diana
- Date: 2015
- Subjects: Head -- Wounds and injuries -- Psychology , Neuropsychological tests , Head -- Wounds and injuries , Sports injuries -- Psychological aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3257 , http://hdl.handle.net/10962/d1016397
- Description: The objective of the study was to investigate the cumulative neurocognitive effects of repetitive concussive and subconcussive events in club level Rugby Union (hereafter rugby) during the course of one rugby season, in a combined group and individualized case-based approach. Amateur adult club level rugby players (n = 20) were compared with a non-contact control group (n = 22) of equivalent age, years of education and estimated IQ (p = > .05, in all instances), although the two groups were clearly differentiated on the basis of a history of reported concussions (p = < .05). Video analyses documented the tackling maneuvers observed amongst the players during all matches across the rugby season revealing a sobering average of more than a thousand tackles per player, excluding any contact practice sessions. Five rugby players (n = 5) who were observed to have a head jarring event were also isolated for individualized postconcussive follow-up analysis of their neurocognitive profiles. Measures included the ImPACT Verbal and Visual Memory, Visual Motor Speed and Reaction Time composites and the Purdue Pegboard. Independent and dependent statistical analyses were employed to compare the rugby versus control group neurocognitive test profiles at and between the three test intervals. Correlational analyses explored the association between concussion, tackling and neurocognitive test outcomes. Descriptive comparisons of individual neurocognitive test scores with normative data were employed for the case analyses. Taken together, the results implicated vulnerability amongst club rugby players on the motor and speeded tasks, with less robust indications on the memory tasks. While limited in terms of its small sample size, it is considered that the outcome of the study was rendered more robust by virtue of being methodologically multifaceted with heuristic implications for future research studies in the area. The novel inclusion of tackling data as well as fine-tuned case analyses, were of particular relevance in that regard. The results add to a growing body of literature that implicates deleterious neurocognitive effects in participants of a sport such as rugby due to repetitive head jarring incidents that are intrinsic to the game.
- Full Text:
- Date Issued: 2015
Nonlinear optical studies of phthalocyanines and their conjugates with nanomaterials
- Authors: Sanusi, Sikiru Olukayode
- Date: 2015
- Subjects: Phthalocyanines , Nonlinear optics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4545 , http://hdl.handle.net/10962/d1017925
- Description: A number of metallophthalocyanines (MPcs) and metal-free phthalocyanines (H₂Pcs) have been synthesized and characterized using various characterization tools such as ¹H-NMR, TOF mass spectrometry, FT-IR, UV-visible spectrophotometry and CHNS elemental analysis. Some of the MPcs were covalently linked to nanomaterials such as silica nanoparticles (SiNPs), single-walled carbon nanotubes (SWCNTs), magnetite nanoparticles (MNPs) and quantum dots (QDs), or embedded in polymer thin-films using poly(methyl methacrylate) (PMMA) and poly(acrylic acid) (PAA) as the polymer sources. The phthalocyanine-nanomaterial composites (Pc-NMCs) were characterized with FT-IR, UV-visible spectrophotometry, transmission electron microscopy (TEM), thermogravimetry analysis and X-ray diffractometry. The nonlinear optical (NLO) properties (using the open-aperture Z-scan technique) of the MPcs and the Pc-NMCs were investigated. In general, most of the investigated MPcs showed good optical limiting behaviors, except for a few, like the non-peripherally-substituted 2-pyridyloxy phthalocyanines, which showed inhibited NLO response as a result of the ring-strain effects. The absence of a metal center was found to greatly reduce the inherent high nonlinearities expected of some of the phthalocyanine complexes. The octaphenoxy derivatives (61a – 61e) were found to exhibit reverse saturable absorption (RSA) that depends on the singlet-singlet transitions, hence making them less reliable optical limiters. The optical limiting properties of the MPcs were improved in the presence of nanomaterials such as the QDs, MNPs and SWCNTs, with MPc-QDs showing the best optical limiting behavior of the three. SiNPs have no significant effect on the optical limiting behavior of the MPcs. The optical limiting properties of the MPcs were greatly enhanced in the presence of PMMA or PAA polymers. The PAA polymer showed better optical limiting behavior compared to PMMA
- Full Text:
- Date Issued: 2015
- Authors: Sanusi, Sikiru Olukayode
- Date: 2015
- Subjects: Phthalocyanines , Nonlinear optics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4545 , http://hdl.handle.net/10962/d1017925
- Description: A number of metallophthalocyanines (MPcs) and metal-free phthalocyanines (H₂Pcs) have been synthesized and characterized using various characterization tools such as ¹H-NMR, TOF mass spectrometry, FT-IR, UV-visible spectrophotometry and CHNS elemental analysis. Some of the MPcs were covalently linked to nanomaterials such as silica nanoparticles (SiNPs), single-walled carbon nanotubes (SWCNTs), magnetite nanoparticles (MNPs) and quantum dots (QDs), or embedded in polymer thin-films using poly(methyl methacrylate) (PMMA) and poly(acrylic acid) (PAA) as the polymer sources. The phthalocyanine-nanomaterial composites (Pc-NMCs) were characterized with FT-IR, UV-visible spectrophotometry, transmission electron microscopy (TEM), thermogravimetry analysis and X-ray diffractometry. The nonlinear optical (NLO) properties (using the open-aperture Z-scan technique) of the MPcs and the Pc-NMCs were investigated. In general, most of the investigated MPcs showed good optical limiting behaviors, except for a few, like the non-peripherally-substituted 2-pyridyloxy phthalocyanines, which showed inhibited NLO response as a result of the ring-strain effects. The absence of a metal center was found to greatly reduce the inherent high nonlinearities expected of some of the phthalocyanine complexes. The octaphenoxy derivatives (61a – 61e) were found to exhibit reverse saturable absorption (RSA) that depends on the singlet-singlet transitions, hence making them less reliable optical limiters. The optical limiting properties of the MPcs were improved in the presence of nanomaterials such as the QDs, MNPs and SWCNTs, with MPc-QDs showing the best optical limiting behavior of the three. SiNPs have no significant effect on the optical limiting behavior of the MPcs. The optical limiting properties of the MPcs were greatly enhanced in the presence of PMMA or PAA polymers. The PAA polymer showed better optical limiting behavior compared to PMMA
- Full Text:
- Date Issued: 2015
Nutritional value and cultivation requirements of Cleome Gynandra: a wild vegetable growing in the Eastern Cape Province, South Africa
- Sowunmi, Linda Ifeanyichukwu
- Authors: Sowunmi, Linda Ifeanyichukwu
- Date: 2015
- Subjects: Ethnobotany -- South Africa -- Eastern Cape Vegetables -- South Africa -- Eastern Cape Nutrition -- South Africa -- Evaluation
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/2600 , vital:27907
- Description: South Africa has wide ranges of plants among which are leafy vegetables growing in the wild. These wild vegetables have been reported to have high nutritive and medicinal potentials. Yet, there is still high prevalence of malnutrition and micronutrients deficiencies among the low income bracket of the population. Effective utilization of wild vegetables has been proposed as part of the solutions to address the problem of dietary deficiencies among the populace. Their importance is mainly as relish to accompany and complement starch based diets. They are also known to serve as supplements for food which have the potential to improve the health status of its consumers in many rural communities. Cleome gynandra L. (Capparaceae) is one of the underutilized species mentioned during asurvey conducted in Nkonkobe municipality of the Eastern Cape Province, South Africa. The plant is an erect annual herb with alternate, palmately compound leaves and its petals are white, pink or lilac. It grows as a weed in this part of the Province and is usually gathered from the wild for food and medicine. It is commonly found on wastes land, road sides and on grass lands. Therefore, this research work was designed to contribute to the possible domestication of this wild vegetable in order to explore the nutritive and therapeutic potentials which would broaden the food base in the Eastern Cape Province. The ultra-micromorphological features of plants have become an essential tool in proper identification and authentication of several plant species. In the light of this, the micromorphology of Cleome gynandra was examined to reveal the micro-morphological characters of the plantand to determine if micro and macro mineral elements are present using energy dispersive x-rays. The present study revealed the epidermal cells of the leaves to be asymmetric in shape with undulating cell walls having four subsidiary cells around the stomata. The leaves have anomocyctic stomata which are more distributed in the abaxial surface than the adaxial surface. The mean length and width of the guard cells in the abaxial surface are 0.09 ± 0.01 mm and 0.08 ± 0.01 mm respectively while that of adaxial surface are 0.1± 0.01 mm and 0.07 ± 0.01 mm respectively. The energy dispersive x-rays (EDXS) micro-analysis of the leaf revealed the presence of phosphorus, manganese, iron, calcium, sodium, magnesium, potassium and zinc as the major constituents of the crystal deposits present in the stomata pores and the mesophyll. C. gynandra was collected from the wild and analysed for its mineral and proximatecomposition using standard analytical methods. The plant showed high levels of sodium, iron, zinc, calcium and potassium while many other macro and micro minerals were moderately present. Amongst the proximate factors investigated, moisture content was found to be 82.1% while crude fibre and protein contents were 39.9 percent and 31.03 percent respectively. Vitamin C was also high (345.3 mg/100g). The anti-nutrients compositions revealed low concentrations of oxalate (7.4 ± 0.4) and phytate (0.6 ± 0.0) mg/100g. The study revealed high nutritive value of the species growing naturally from the wild. Interest in the phenolic compounds has greatly increased recently because these compounds have been implicated in suppressing the risk of degenerative diseases in humans. The pharmacological properties of plants may be related to their antioxidant capacities and hence there was need to investigate the antioxidant potential using aqueous, ethanolic and acetone extracts of different parts of C. gynandra. The quantities of phenols, flavonoids and flavonols were significantly higher (p < 0.05) in both aqueous and ethanol extracts of the leaf while the concentration of proanthocyanidins was higher in the aqueous stem extract compared to other plant parts. The aqueous extract of the different parts exhibited better ABTS, reducing power and NO radical scavenging abilities than ethanol extract.
- Full Text:
- Date Issued: 2015
- Authors: Sowunmi, Linda Ifeanyichukwu
- Date: 2015
- Subjects: Ethnobotany -- South Africa -- Eastern Cape Vegetables -- South Africa -- Eastern Cape Nutrition -- South Africa -- Evaluation
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/2600 , vital:27907
- Description: South Africa has wide ranges of plants among which are leafy vegetables growing in the wild. These wild vegetables have been reported to have high nutritive and medicinal potentials. Yet, there is still high prevalence of malnutrition and micronutrients deficiencies among the low income bracket of the population. Effective utilization of wild vegetables has been proposed as part of the solutions to address the problem of dietary deficiencies among the populace. Their importance is mainly as relish to accompany and complement starch based diets. They are also known to serve as supplements for food which have the potential to improve the health status of its consumers in many rural communities. Cleome gynandra L. (Capparaceae) is one of the underutilized species mentioned during asurvey conducted in Nkonkobe municipality of the Eastern Cape Province, South Africa. The plant is an erect annual herb with alternate, palmately compound leaves and its petals are white, pink or lilac. It grows as a weed in this part of the Province and is usually gathered from the wild for food and medicine. It is commonly found on wastes land, road sides and on grass lands. Therefore, this research work was designed to contribute to the possible domestication of this wild vegetable in order to explore the nutritive and therapeutic potentials which would broaden the food base in the Eastern Cape Province. The ultra-micromorphological features of plants have become an essential tool in proper identification and authentication of several plant species. In the light of this, the micromorphology of Cleome gynandra was examined to reveal the micro-morphological characters of the plantand to determine if micro and macro mineral elements are present using energy dispersive x-rays. The present study revealed the epidermal cells of the leaves to be asymmetric in shape with undulating cell walls having four subsidiary cells around the stomata. The leaves have anomocyctic stomata which are more distributed in the abaxial surface than the adaxial surface. The mean length and width of the guard cells in the abaxial surface are 0.09 ± 0.01 mm and 0.08 ± 0.01 mm respectively while that of adaxial surface are 0.1± 0.01 mm and 0.07 ± 0.01 mm respectively. The energy dispersive x-rays (EDXS) micro-analysis of the leaf revealed the presence of phosphorus, manganese, iron, calcium, sodium, magnesium, potassium and zinc as the major constituents of the crystal deposits present in the stomata pores and the mesophyll. C. gynandra was collected from the wild and analysed for its mineral and proximatecomposition using standard analytical methods. The plant showed high levels of sodium, iron, zinc, calcium and potassium while many other macro and micro minerals were moderately present. Amongst the proximate factors investigated, moisture content was found to be 82.1% while crude fibre and protein contents were 39.9 percent and 31.03 percent respectively. Vitamin C was also high (345.3 mg/100g). The anti-nutrients compositions revealed low concentrations of oxalate (7.4 ± 0.4) and phytate (0.6 ± 0.0) mg/100g. The study revealed high nutritive value of the species growing naturally from the wild. Interest in the phenolic compounds has greatly increased recently because these compounds have been implicated in suppressing the risk of degenerative diseases in humans. The pharmacological properties of plants may be related to their antioxidant capacities and hence there was need to investigate the antioxidant potential using aqueous, ethanolic and acetone extracts of different parts of C. gynandra. The quantities of phenols, flavonoids and flavonols were significantly higher (p < 0.05) in both aqueous and ethanol extracts of the leaf while the concentration of proanthocyanidins was higher in the aqueous stem extract compared to other plant parts. The aqueous extract of the different parts exhibited better ABTS, reducing power and NO radical scavenging abilities than ethanol extract.
- Full Text:
- Date Issued: 2015
On the characterisation of diffused light and optical elements in high concentrator photovoltaic modules
- Authors: Schultz, Ross Dane
- Date: 2015
- Subjects: Photovoltaic cells , Solar concentrators , Optical materials
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/5170 , vital:20817
- Description: High Concentrated Photovoltaics (H-CPV) promise a more efficient, higher power output than traditional photovoltaic modules. This is achieved by concentrating sunlight onto a small triple junction (CTJ) InGaP/InGaAs/Ge cell (ranging from 3.14 mm2 to 1 cm2) by using precision optical systems. These systems utilise non-imaging optics to concentrate and distribute the incident solar flux uniformly onto the CTJ device receiver to achieve maximum performance and power output from an H-CPV module. However, the performance of the device can be reduced due to the partial or complete absorption of a range of wavelengths present in the solar spectrum by the optical materials that are used for concentration. An investigation to determine the current density topographies of each subcell in a CTJ cell by multiple raster scans of an optical fibre receiver of a spectrometer in the plane of the aperture of the secondary’s optical element was conducted. Results showed that the physical properties of the optical elements’ material absorbed different amounts of the spectral content with respect to the subcell photosensitive wavelength regions. The facet properties of the primary optical Fresnel lens showed that the more rounded the Fresnel facets were, the lower the concentration of sunlight incident onto the CTJ cell. The increase in facet numbers showed an increase in scattering of the incident sunlight and chromatic aberrations. Chromatic aberration created by the refractive optics showed a variation in the amount of concentration on each individual subcell as well as the difference in intensity profiles across for the different subcells. Based on these results and the development of new multi-junction devices by industry, the performance of a four and six-junction device with the optical materials was investigated by simulations. The simulations showed that the careful integration of an additional subcell in a multi-junction device could rectify current mismatch between the subcells in the device. Based on the simulations, the best performing multi-junction cell was identified as the four-junction device that showed a cell and module efficiency under operation of 42.5 % and 35.5 %, respectively. Additionally, based on the performance results observed from the H-CPV module, the development of an HCPV module that would attempt to harness the incident tracked diffuse sunlight available to a concentrator photovoltaic (CPV) module for additional energy yield was undertaken. The part of the study comprised of measurements of the solar source, design of a prototype Hybrid High Concentrator Photovoltaic (HH-CPV) module. Results showed that power generation from the H-CPV system was highly dependent on the DNI levels and fluctuates greatly with variation in the DNI. The irradiance levels within the diffuse regions of the H-CPV module showed that the baseplate and vertical sides had an average irradiance range of 140-450 and 50-225 W.m-2, respectively. Irradiance topographic raster scans revealed that the baseplate and vertical sides had a relatively uniform intensity distribution and was identified as favourable sites for diffuse cell population. Simulations of various PV technologies showed the most suitable technology for the placement within the cavity of the HH-CPV module. The developed HH-CPV module was finalized with the utilization of CIS modules to harness the diffuse irradiance. During a 3 month power monitoring of the HH-CPV system, it was determined that the major power generation for the HH-CPV module come from the CPV component, while the CIS modules showed a minor power contribution. The total energy yield for the monitoring period was 45.99, 3.89 and 1.76 kW.h for the CPV, four-vertical sides and baseplate components, respectively. The increase in energy yield of the HH-CPV module when compared to the standard H-CPV module was determined to be 12.35 % for the monitoring period. The incorporation of the CIS modules into the H-CPV module to create the HH-CPV module did increase the energy yield of the module during high DNI conditions and did offset the almost zero power generation during low DNI conditions.
- Full Text:
- Date Issued: 2015
- Authors: Schultz, Ross Dane
- Date: 2015
- Subjects: Photovoltaic cells , Solar concentrators , Optical materials
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/5170 , vital:20817
- Description: High Concentrated Photovoltaics (H-CPV) promise a more efficient, higher power output than traditional photovoltaic modules. This is achieved by concentrating sunlight onto a small triple junction (CTJ) InGaP/InGaAs/Ge cell (ranging from 3.14 mm2 to 1 cm2) by using precision optical systems. These systems utilise non-imaging optics to concentrate and distribute the incident solar flux uniformly onto the CTJ device receiver to achieve maximum performance and power output from an H-CPV module. However, the performance of the device can be reduced due to the partial or complete absorption of a range of wavelengths present in the solar spectrum by the optical materials that are used for concentration. An investigation to determine the current density topographies of each subcell in a CTJ cell by multiple raster scans of an optical fibre receiver of a spectrometer in the plane of the aperture of the secondary’s optical element was conducted. Results showed that the physical properties of the optical elements’ material absorbed different amounts of the spectral content with respect to the subcell photosensitive wavelength regions. The facet properties of the primary optical Fresnel lens showed that the more rounded the Fresnel facets were, the lower the concentration of sunlight incident onto the CTJ cell. The increase in facet numbers showed an increase in scattering of the incident sunlight and chromatic aberrations. Chromatic aberration created by the refractive optics showed a variation in the amount of concentration on each individual subcell as well as the difference in intensity profiles across for the different subcells. Based on these results and the development of new multi-junction devices by industry, the performance of a four and six-junction device with the optical materials was investigated by simulations. The simulations showed that the careful integration of an additional subcell in a multi-junction device could rectify current mismatch between the subcells in the device. Based on the simulations, the best performing multi-junction cell was identified as the four-junction device that showed a cell and module efficiency under operation of 42.5 % and 35.5 %, respectively. Additionally, based on the performance results observed from the H-CPV module, the development of an HCPV module that would attempt to harness the incident tracked diffuse sunlight available to a concentrator photovoltaic (CPV) module for additional energy yield was undertaken. The part of the study comprised of measurements of the solar source, design of a prototype Hybrid High Concentrator Photovoltaic (HH-CPV) module. Results showed that power generation from the H-CPV system was highly dependent on the DNI levels and fluctuates greatly with variation in the DNI. The irradiance levels within the diffuse regions of the H-CPV module showed that the baseplate and vertical sides had an average irradiance range of 140-450 and 50-225 W.m-2, respectively. Irradiance topographic raster scans revealed that the baseplate and vertical sides had a relatively uniform intensity distribution and was identified as favourable sites for diffuse cell population. Simulations of various PV technologies showed the most suitable technology for the placement within the cavity of the HH-CPV module. The developed HH-CPV module was finalized with the utilization of CIS modules to harness the diffuse irradiance. During a 3 month power monitoring of the HH-CPV system, it was determined that the major power generation for the HH-CPV module come from the CPV component, while the CIS modules showed a minor power contribution. The total energy yield for the monitoring period was 45.99, 3.89 and 1.76 kW.h for the CPV, four-vertical sides and baseplate components, respectively. The increase in energy yield of the HH-CPV module when compared to the standard H-CPV module was determined to be 12.35 % for the monitoring period. The incorporation of the CIS modules into the H-CPV module to create the HH-CPV module did increase the energy yield of the module during high DNI conditions and did offset the almost zero power generation during low DNI conditions.
- Full Text:
- Date Issued: 2015
On the characterisation of solar cells using light beam induced current measurements
- Authors: Kwarikunda, Nicholas
- Date: 2015
- Subjects: Solor cells Spectrum, Solar
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/11147 , vital:26889
- Description: The presence of inhomogeneities in semiconductor materials used to fabricate solar cell devices may result in spatial non uniformities in the device properties which may affect current generation in these devices. Besides, current reducing defects such as inclusions, local shunts and optical blockages may be introduced during the various device manufacturing processes which may adversely affect the performance and overall efficiency of solar cells. Diagnostic techniques are therefore needed to identify these defects so as to improve the production technology. This thesis presents the Light Beam Induced Current (LBIC) technique for mapping spatial non uniformities in solar cell devices. The LBIC is a non destructive characterisation technique that uses a focused light beam to raster scan a solar cell surface as the photo-generated current is recorded as a function of position to generate a photo-response map. The technique was used to obtain photoresponse maps for a mc-Si, Back contact Back junction (BC-BJ) silicon solar cell and the InGaP/InGaAs/Ge concentrating triple junction (CTJ) solar cell from which various local current reducing defects were mapped. A reflection signal detector was incorporated into the LBIC measurement system to enable us distinguish between optical blockages on the cell surface and current reducing defects within the solar cell devices. By dynamically biasing the solar cell devices, the electrical activity of the identified defects was investigated and also point-by-point current-voltage (I-V) characteristics were obtained. An interval division algorithm was applied to the measured point-by-point I-V characteristics to extract device and performance parameters from which device and performance parameter uniformity of the devices were mapped. Dark and full cell solar illumination I-V characteristics were also measured to extract device parameters. Analysis of extracted parameters revealed differences between extracted dark and illuminated device parameters which was attributed to departure from the superposition principle due to non-linearity of the semiconductor device equations with respect to carrier concentration. An investigation into the effect of illumination intensity on the I-V parameters of a spot illuminated BC-BJ Si solar cell showed a linear increase and a logarithmic increase of the short circuit current and open circuit voltage respectively with intensity while the series resistance decreased with intensity, which was attributed to increase in conductivity of the active layer. The ideality factor and saturation current were observed to increase while the shunt resistance initially increased before decreasing at higher intensity levels. Under monochromatic illumination, the photo-response of the BC-BJ Si cell was higher at 785nm than at 445nm due to low absorption coefficient of Si for longer wavelength radiations, resulting in carrier generation within the bulk, where there is a higher probability of carriers being collected at the p-n junction before they recombine. Under solar illumination, as the spectral content was altered using long pass colour filters with cut off wavelengths of 610nm and 1000nm, the performance parameters were observed to decrease and this was mainly due to decrease in intensity. For the CTJ solar cell, however, blocking of radiations below 610nm resulted in current mismatch that severely degraded the short circuit current (Isc). The current mismatch affected the extracted device and performance parameters. With a 1000nm long pass filter, a dark I-V was obtained since only the bottom Ge subcell was activated.
- Full Text:
- Date Issued: 2015
- Authors: Kwarikunda, Nicholas
- Date: 2015
- Subjects: Solor cells Spectrum, Solar
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/11147 , vital:26889
- Description: The presence of inhomogeneities in semiconductor materials used to fabricate solar cell devices may result in spatial non uniformities in the device properties which may affect current generation in these devices. Besides, current reducing defects such as inclusions, local shunts and optical blockages may be introduced during the various device manufacturing processes which may adversely affect the performance and overall efficiency of solar cells. Diagnostic techniques are therefore needed to identify these defects so as to improve the production technology. This thesis presents the Light Beam Induced Current (LBIC) technique for mapping spatial non uniformities in solar cell devices. The LBIC is a non destructive characterisation technique that uses a focused light beam to raster scan a solar cell surface as the photo-generated current is recorded as a function of position to generate a photo-response map. The technique was used to obtain photoresponse maps for a mc-Si, Back contact Back junction (BC-BJ) silicon solar cell and the InGaP/InGaAs/Ge concentrating triple junction (CTJ) solar cell from which various local current reducing defects were mapped. A reflection signal detector was incorporated into the LBIC measurement system to enable us distinguish between optical blockages on the cell surface and current reducing defects within the solar cell devices. By dynamically biasing the solar cell devices, the electrical activity of the identified defects was investigated and also point-by-point current-voltage (I-V) characteristics were obtained. An interval division algorithm was applied to the measured point-by-point I-V characteristics to extract device and performance parameters from which device and performance parameter uniformity of the devices were mapped. Dark and full cell solar illumination I-V characteristics were also measured to extract device parameters. Analysis of extracted parameters revealed differences between extracted dark and illuminated device parameters which was attributed to departure from the superposition principle due to non-linearity of the semiconductor device equations with respect to carrier concentration. An investigation into the effect of illumination intensity on the I-V parameters of a spot illuminated BC-BJ Si solar cell showed a linear increase and a logarithmic increase of the short circuit current and open circuit voltage respectively with intensity while the series resistance decreased with intensity, which was attributed to increase in conductivity of the active layer. The ideality factor and saturation current were observed to increase while the shunt resistance initially increased before decreasing at higher intensity levels. Under monochromatic illumination, the photo-response of the BC-BJ Si cell was higher at 785nm than at 445nm due to low absorption coefficient of Si for longer wavelength radiations, resulting in carrier generation within the bulk, where there is a higher probability of carriers being collected at the p-n junction before they recombine. Under solar illumination, as the spectral content was altered using long pass colour filters with cut off wavelengths of 610nm and 1000nm, the performance parameters were observed to decrease and this was mainly due to decrease in intensity. For the CTJ solar cell, however, blocking of radiations below 610nm resulted in current mismatch that severely degraded the short circuit current (Isc). The current mismatch affected the extracted device and performance parameters. With a 1000nm long pass filter, a dark I-V was obtained since only the bottom Ge subcell was activated.
- Full Text:
- Date Issued: 2015
Organizational culture in the South African construction industry : effects on work-life balance and individual performance
- Dlamini, Gcebekile Tikhokhile
- Authors: Dlamini, Gcebekile Tikhokhile
- Date: 2015
- Subjects: Construction industry -- South Africa , Work-life balance -- South Africa , Corporate culture -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9702 , http://hdl.handle.net/10948/d1018513
- Description: The South African construction industry plays an important role in the economy and overall development of the country, with respect to its total fiscal contribution and the total number of people who are employed. In addition, it is a major contributor to infrastructure development. However, the human resource base within this industry is confronted with a plethora of challenges that are inherent to the construction industry. These manifest themselves in stressful working conditions and long working hours, labour intensive jobs, reduced job security due to job losses and short-term projects, and the feeble health and safety (H&S) standards. Together with a variety of socio-economic and political issues, these challenges form a perceived and broad organisational culture of this industry, which impacts on the industry‟s productivity. As construction management efforts in the development of the human resources base increase, the industry recognises that work-life balance is an important and critical issue in the 21st century. Construction management is a discipline that embodies two interdependent dimensions; the management of the business of construction and the management of projects. Of the latter, the key principles thereof are, as part of a management strategy, planning, organizing, leading, controlling and coordinating projects. To achieve these strategic components, an effective human resource base is required. Work-life balance is therefore a management issue and organizational culture sets a backdrop from which it can be understood. This study focused on the status of the organisational culture of the production establishments that form part of the construction industry and the manner in which it manifests on the work-life balance of the workers. Furthermore, the correlation between work-life balance and individual work performance was examined. An exploratory research approach was adopted and the research technique followed an interview protocol. The main findings demonstrate that the South African construction industry is predominantly a clan culture with minor characteristics of the hierarchy, adhocracy and market cultures. Furthermore, work-life balance is difficult to attain and it influences individual work performance. The main conclusion is that organizational culture in construction firms is imbalanced. Thus, the main recommendation is that the industry adopts a balanced organizational culture and modern human resource practices.
- Full Text:
- Date Issued: 2015
- Authors: Dlamini, Gcebekile Tikhokhile
- Date: 2015
- Subjects: Construction industry -- South Africa , Work-life balance -- South Africa , Corporate culture -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9702 , http://hdl.handle.net/10948/d1018513
- Description: The South African construction industry plays an important role in the economy and overall development of the country, with respect to its total fiscal contribution and the total number of people who are employed. In addition, it is a major contributor to infrastructure development. However, the human resource base within this industry is confronted with a plethora of challenges that are inherent to the construction industry. These manifest themselves in stressful working conditions and long working hours, labour intensive jobs, reduced job security due to job losses and short-term projects, and the feeble health and safety (H&S) standards. Together with a variety of socio-economic and political issues, these challenges form a perceived and broad organisational culture of this industry, which impacts on the industry‟s productivity. As construction management efforts in the development of the human resources base increase, the industry recognises that work-life balance is an important and critical issue in the 21st century. Construction management is a discipline that embodies two interdependent dimensions; the management of the business of construction and the management of projects. Of the latter, the key principles thereof are, as part of a management strategy, planning, organizing, leading, controlling and coordinating projects. To achieve these strategic components, an effective human resource base is required. Work-life balance is therefore a management issue and organizational culture sets a backdrop from which it can be understood. This study focused on the status of the organisational culture of the production establishments that form part of the construction industry and the manner in which it manifests on the work-life balance of the workers. Furthermore, the correlation between work-life balance and individual work performance was examined. An exploratory research approach was adopted and the research technique followed an interview protocol. The main findings demonstrate that the South African construction industry is predominantly a clan culture with minor characteristics of the hierarchy, adhocracy and market cultures. Furthermore, work-life balance is difficult to attain and it influences individual work performance. The main conclusion is that organizational culture in construction firms is imbalanced. Thus, the main recommendation is that the industry adopts a balanced organizational culture and modern human resource practices.
- Full Text:
- Date Issued: 2015
Performing whiteness; representing otherness : Hugh Tracey and African music
- Authors: Coetzee, Paulette June
- Date: 2015
- Subjects: Tracey, Hugh , Music -- Africa , International Library of African Music , Ethnomusicology -- Africa , Ethnomusicologists -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2327 , http://hdl.handle.net/10962/d1016502
- Description: This thesis provides a critical study of texts associated with Hugh Tracey (1903–1977). Tracey is well-known for his work in African music studies, particularly for his major contribution to the recorded archive of musical sound in sub-Saharan Africa and his founding of the International Library of African Music (ILAM) in 1954. My reading of him is informed by a postcolonial perspective, whiteness studies and African scholarship on ways in which constructions of African identity and tradition have been shaped by the colonial archive. In my view, Tracey was part of a mid-twentieth century movement which sought to marshal positive representations of traditional African culture in the interest of maintaining and strengthening colonial rule. While his recording project may have fostered inclusion through creating spaces for indigenous musicians to be heard, it also functioned to promote racist exclusion in the manner of its production, distribution and claims to expertise. Moreover, his initial strategy for ILAM’s sustainability targeted colonial government and industry as primary clients, with the promise that promoting traditional music as a means of entertainment and self-expression for black subjects and workers would ease administration and reduce conflict. I believe that it is important to acknowledge and interrogate the problematic racial attitudes and practices associated with the history of Tracey’s archive – not to undermine its significance in any way but to allow it to be better understood and used more productively in the future.
- Full Text:
- Date Issued: 2015
- Authors: Coetzee, Paulette June
- Date: 2015
- Subjects: Tracey, Hugh , Music -- Africa , International Library of African Music , Ethnomusicology -- Africa , Ethnomusicologists -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2327 , http://hdl.handle.net/10962/d1016502
- Description: This thesis provides a critical study of texts associated with Hugh Tracey (1903–1977). Tracey is well-known for his work in African music studies, particularly for his major contribution to the recorded archive of musical sound in sub-Saharan Africa and his founding of the International Library of African Music (ILAM) in 1954. My reading of him is informed by a postcolonial perspective, whiteness studies and African scholarship on ways in which constructions of African identity and tradition have been shaped by the colonial archive. In my view, Tracey was part of a mid-twentieth century movement which sought to marshal positive representations of traditional African culture in the interest of maintaining and strengthening colonial rule. While his recording project may have fostered inclusion through creating spaces for indigenous musicians to be heard, it also functioned to promote racist exclusion in the manner of its production, distribution and claims to expertise. Moreover, his initial strategy for ILAM’s sustainability targeted colonial government and industry as primary clients, with the promise that promoting traditional music as a means of entertainment and self-expression for black subjects and workers would ease administration and reduce conflict. I believe that it is important to acknowledge and interrogate the problematic racial attitudes and practices associated with the history of Tracey’s archive – not to undermine its significance in any way but to allow it to be better understood and used more productively in the future.
- Full Text:
- Date Issued: 2015
Photophysical studies of Zinc phthalocyanine-silica nanoparticles conjugates
- Authors: Fashina, Adedayo
- Date: 2015
- Subjects: Nanoparticles , Phthalocyanines , Zinc , Silica , Photochemistry , Adsorption
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4537 , http://hdl.handle.net/10962/d1017917
- Description: This thesis reports on the synthesis and characterization of both symmetrical and asymmetrical Zinc phthalocyanine complexes. The complexes contained groups such as carboxylic, amino and alkyne for covalent grafting to the surface of silica nanoparticles. The use of symmetrical and asymmetrical complexes was geared towards comparing the non-specific binding of the symmetrical complexes to the specific binding observed in the asymmetrical complexes. The complexes were also doped within the silica matrix and compared to the surface grafted conjugates. The complexes and the conjugates were well characterized with a variety of techniques. The fluorescence lifetimes of the phthalocyanine complexes containing either terminal carboxylic groups or an alkyne group showed a mono-exponential decay while the amino containing phthalocyanine complexes gave a bi-exponential decay. A similar trend was observed for their respective conjugates. Some of the conjugates of the asymmetrical complexes showed a decrease in fluorescence lifetimes and a corresponding decrease in fluorescence quantum yields. The fluorescence quantum yields for all the symmetrical complexes studied showed either an improvement or retained the luminescence of the grafted phthalocyanine complex. Most of the conjugates showed a faster intersystem crossing time in comparison to the complexes alone. The grafted or doped conjugates containing symmetrical phthalocyanine complexes with carboxyl groups showed improvements both in fluorescence and triplet quantum yields. All the conjugates except two showed an increase in triplet lifetimes when compared to their respective phthalocyanine complexes. Optical nonlinearities of nine of the phthalocyanine complexes were studied and all the complexes showed characteristic reverse saturable absorption behavior. Complex 10 showed the most promising optical limiting behavior. The aggregation and dissolution studies of the conjugates were also carried out in a simulated biological medium and the silicon level detected was noticed to have increased with incubation time.
- Full Text:
- Date Issued: 2015
- Authors: Fashina, Adedayo
- Date: 2015
- Subjects: Nanoparticles , Phthalocyanines , Zinc , Silica , Photochemistry , Adsorption
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4537 , http://hdl.handle.net/10962/d1017917
- Description: This thesis reports on the synthesis and characterization of both symmetrical and asymmetrical Zinc phthalocyanine complexes. The complexes contained groups such as carboxylic, amino and alkyne for covalent grafting to the surface of silica nanoparticles. The use of symmetrical and asymmetrical complexes was geared towards comparing the non-specific binding of the symmetrical complexes to the specific binding observed in the asymmetrical complexes. The complexes were also doped within the silica matrix and compared to the surface grafted conjugates. The complexes and the conjugates were well characterized with a variety of techniques. The fluorescence lifetimes of the phthalocyanine complexes containing either terminal carboxylic groups or an alkyne group showed a mono-exponential decay while the amino containing phthalocyanine complexes gave a bi-exponential decay. A similar trend was observed for their respective conjugates. Some of the conjugates of the asymmetrical complexes showed a decrease in fluorescence lifetimes and a corresponding decrease in fluorescence quantum yields. The fluorescence quantum yields for all the symmetrical complexes studied showed either an improvement or retained the luminescence of the grafted phthalocyanine complex. Most of the conjugates showed a faster intersystem crossing time in comparison to the complexes alone. The grafted or doped conjugates containing symmetrical phthalocyanine complexes with carboxyl groups showed improvements both in fluorescence and triplet quantum yields. All the conjugates except two showed an increase in triplet lifetimes when compared to their respective phthalocyanine complexes. Optical nonlinearities of nine of the phthalocyanine complexes were studied and all the complexes showed characteristic reverse saturable absorption behavior. Complex 10 showed the most promising optical limiting behavior. The aggregation and dissolution studies of the conjugates were also carried out in a simulated biological medium and the silicon level detected was noticed to have increased with incubation time.
- Full Text:
- Date Issued: 2015
Photophysicochemical properties and in vitro photodynamic therapy activities of zinc phthalocyanine conjugates with biomolecules and single-walled carbon nanotubes
- Authors: Ogbodu, Racheal O
- Date: 2015
- Subjects: Photochemotherapy , Phthalocyanines , Biomolecules
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4544 , http://hdl.handle.net/10962/d1017924
- Description: The synthesis, photophysicochemcial properties, in vitro dark toxicity and photodynamic therapy (PDT) activities of different derivatives of zinc phthalocyanine (ZnPc) conjugates with biomolecules (folic acid, bovine serum albumin (BSA), ascorbic acid, uridine or spermine) and single-walled carbon nanotubes (SWCNTs) are presented in this work. The fluorescence quantum yields (ΦF) (Subscript F) of the ZnPc derivatives or ZnPc-biomolecule conjugates remained relatively the same as compared to the precursor Pcs. Slight increases were observed in the ΦF (Subscript F) values of conjugates containing substituents such as pyrene, folic acid or BSA with intrinsic fluorescence properties. The triplet quantum yield (ΦT ) (Subscript T) values for some ZnPc conjugates increases compared to the precursor ZnPcs due to extended π conjugation (for the conjugate with pyrene) and the presence of phenyl ring that support spin-orbit charge transfer intersystem crossing to triplet state. While some conjugates showed decreases in the ΦT (Subscript T) values compared to precursor ZnPcs due to the presence of substituents that could quench photo-excited state properties. The singlet oxygen quantum yield (ΦΔ ) values follow the trends of the triplet quantum yield values. The conjugates containing BSA also show increases in the ΦΔ values without corresponding increases in ΦT (Subscript T) values due to the ability of BSA to generate free radicals including singlet oxygen. The presence of SWCNTs decreases the photophysicochemcial properties of some ZnPc-SWCNT conjugates compared to the precursor ZnPcs due to photo-induced electron transfer from an excited Pc complex (electron donor) to SWCNTs (electron acceptor). However, increases were observed in some ZnPc-SWCNT conjugates as a result of fast charge recombination process due to highly short-lived radical ion pair produced. These phenomena affected the ΦF (Suscript F) values, ΦT (Suscript T) values, and the ΦΔ values. Increases or decreases in ΦT (Suscript T) values resulted in corresponding increases or decreases in ΦΔ values
- Full Text:
- Date Issued: 2015
- Authors: Ogbodu, Racheal O
- Date: 2015
- Subjects: Photochemotherapy , Phthalocyanines , Biomolecules
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4544 , http://hdl.handle.net/10962/d1017924
- Description: The synthesis, photophysicochemcial properties, in vitro dark toxicity and photodynamic therapy (PDT) activities of different derivatives of zinc phthalocyanine (ZnPc) conjugates with biomolecules (folic acid, bovine serum albumin (BSA), ascorbic acid, uridine or spermine) and single-walled carbon nanotubes (SWCNTs) are presented in this work. The fluorescence quantum yields (ΦF) (Subscript F) of the ZnPc derivatives or ZnPc-biomolecule conjugates remained relatively the same as compared to the precursor Pcs. Slight increases were observed in the ΦF (Subscript F) values of conjugates containing substituents such as pyrene, folic acid or BSA with intrinsic fluorescence properties. The triplet quantum yield (ΦT ) (Subscript T) values for some ZnPc conjugates increases compared to the precursor ZnPcs due to extended π conjugation (for the conjugate with pyrene) and the presence of phenyl ring that support spin-orbit charge transfer intersystem crossing to triplet state. While some conjugates showed decreases in the ΦT (Subscript T) values compared to precursor ZnPcs due to the presence of substituents that could quench photo-excited state properties. The singlet oxygen quantum yield (ΦΔ ) values follow the trends of the triplet quantum yield values. The conjugates containing BSA also show increases in the ΦΔ values without corresponding increases in ΦT (Subscript T) values due to the ability of BSA to generate free radicals including singlet oxygen. The presence of SWCNTs decreases the photophysicochemcial properties of some ZnPc-SWCNT conjugates compared to the precursor ZnPcs due to photo-induced electron transfer from an excited Pc complex (electron donor) to SWCNTs (electron acceptor). However, increases were observed in some ZnPc-SWCNT conjugates as a result of fast charge recombination process due to highly short-lived radical ion pair produced. These phenomena affected the ΦF (Suscript F) values, ΦT (Suscript T) values, and the ΦΔ values. Increases or decreases in ΦT (Suscript T) values resulted in corresponding increases or decreases in ΦΔ values
- Full Text:
- Date Issued: 2015
Phthalocyanine-nanoparticle conjugates for photodynamic therapy of cancer and phototransformation of organic pollutants
- Authors: Khoza, Phindile Brenda
- Date: 2015
- Subjects: Phthalocyanines , Nanoparticles , Photochemotherapy , Cancer -- Chemotherapy , Zinc oxide , Photocatalysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4538 , http://hdl.handle.net/10962/d1017918
- Description: The synthesis and extensive spectroscopical characterization of novel phthalocyanines are reported. The new compounds were characterized by elemental analysis, FT-IR, ¹HNMR, mass spectrometry and UV–Vis spectroscopy. The new phthalocyanines showed remarkable photophysicochemical behaviour. The novel phthalocyanines were then conjugated to nanoparticles, silver and ZnO. The coupling of the novel Pcs to nanoparticles was through covalent bonding and ligand exchange. These conjugates were supported onto electrospun polystyrene fibers and chitosan microbeads for use as photocatalysts. The efficiency of the immobilized Pcs and Pc-nanoparticles was assessed by the phototrasfromation of organic pollutants, methyl orange and Rhodamine 6G as model dyes. Upon conjugating phthalocyanines to nanoparticles, there was a great increase in the rate of photodegradation of the model dyes. The photodynamic activity of the novel phthalocyanines upon conjugating to nanoparticles and selected targeting agents is also reported. The targeting agents employed in this study are folic acid and polylysine. Conjugating the phthalocyanines to folic acid or polylysine improved the solubility of the phthalocyanines in aqueous media. The potency of the conjugates was investigated on breast (MCF-7), prostate and melanoma cancer cell lines. The phthalocyanines showed no toxicity in the absence of light. However, upon illumination, a concentration dependent cellular decrease was observed.
- Full Text:
- Date Issued: 2015
- Authors: Khoza, Phindile Brenda
- Date: 2015
- Subjects: Phthalocyanines , Nanoparticles , Photochemotherapy , Cancer -- Chemotherapy , Zinc oxide , Photocatalysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4538 , http://hdl.handle.net/10962/d1017918
- Description: The synthesis and extensive spectroscopical characterization of novel phthalocyanines are reported. The new compounds were characterized by elemental analysis, FT-IR, ¹HNMR, mass spectrometry and UV–Vis spectroscopy. The new phthalocyanines showed remarkable photophysicochemical behaviour. The novel phthalocyanines were then conjugated to nanoparticles, silver and ZnO. The coupling of the novel Pcs to nanoparticles was through covalent bonding and ligand exchange. These conjugates were supported onto electrospun polystyrene fibers and chitosan microbeads for use as photocatalysts. The efficiency of the immobilized Pcs and Pc-nanoparticles was assessed by the phototrasfromation of organic pollutants, methyl orange and Rhodamine 6G as model dyes. Upon conjugating phthalocyanines to nanoparticles, there was a great increase in the rate of photodegradation of the model dyes. The photodynamic activity of the novel phthalocyanines upon conjugating to nanoparticles and selected targeting agents is also reported. The targeting agents employed in this study are folic acid and polylysine. Conjugating the phthalocyanines to folic acid or polylysine improved the solubility of the phthalocyanines in aqueous media. The potency of the conjugates was investigated on breast (MCF-7), prostate and melanoma cancer cell lines. The phthalocyanines showed no toxicity in the absence of light. However, upon illumination, a concentration dependent cellular decrease was observed.
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- Date Issued: 2015