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Tool wear monitoring in end milling of mould steel using acoustic emission

- Olufayo, Oluwole Ayodeji

Authors: Olufayo, Oluwole Ayodeji
Subjects: Acoustic emission testing , Tool-steel
Language: English
Type: Thesis , Masters , MEngineering
Identifier: vital:9651 , http://hdl.handle.net/10948/d1014688
Description: Today’s production industry is faced with the challenge of maximising its resources and productivity. Tool condition monitoring (TCM) is an important diagnostic tool and if integrated in manufacturing, machining efficiency will increase as a result of reducing downtime resulting from tool failures by intensive wear. The research work presented in the study highlights the principles in tool condition monitoring and identifies acoustic emission (AE) as a reliable sensing technique for the detection of wear conditions. It reviews the importance of acoustic emission as an efficient technique and proposes a TCM model for the prediction of tool wear. The study presents a TCM framework to monitor an end-milling operation of H13 tool steel at different cutting speeds and feed rates. For this, three industrial acoustic sensors were positioned on the workpiece. The framework identifies a feature selection, extraction and conditioning process and classifies AE signals using an artificial neural network algorithm to create an autonomous system. It concludes by recognizing the mean and rms features as viable features in the identification of tool state and observes that chip coloration provides direct correlation to the temperature of machining as well as tool condition. This proposed model is aimed at creating a timing schedule for tool change in industries. This model ultimately links the rate of wear formation to characteristic AE features.
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Towards mineral beneficiation: from basic chemistry to applications

- Tshentu, Zenixole

Authors: Tshentu, Zenixole
Subjects: Metallurgy , Ore-dressing , f-sa
Language: English
Type: text , Lectures
Identifier: http://hdl.handle.net/10948/55783 , vital:53876
Description: The role of mineral beneficiation in the survival, growth, development and sustainability of a developing economy cannot be overstated. Our development as a human species has always been involvedly linked with the use of mineral resources from the stone, bronze and iron ages through the early modern eras to the present. In the current modern era, characterized by highly technological equipment, fourth industrial revolution (4IR) and new energy technologies, the role of mineral beneficiation has been elevated. Precious metals find use in the fine chemicals and petrochemicals industry, fuel cells, electrical and electronic products, medical and dentistry applications, jewellery, autocatalysts, and glass and ceramics. The markets for precious metals keep growing and the supply does not meet demand. The development of methods for recovery of metal value from feeds of mineral ore solutions, solutions of spent secondary resources and from mining wastewaters remains of great importance. Further beneficiation strategies for utilization of mineral products in other “value-added” applications are also important for the growth of the mineral markets. The usage of platinum, palladium and rhodium in the autocatalyst industry has grown significantly and this has further elevated the importance of platinum group metals (PGMs), but other areas of application of the strategic metals need to be harnessed. The four stages of beneficiation, namely, primary, secondary, tertiary and final stage, provide an opportunity to beneficiate to greater value for domestic or export use. Our own research work is engaged in several of these stages, from hydrometallurgical recovery of base metals and platinum group metals from feeds of primary mining and solutions of waste secondary resources such as spent catalytic converters and e-waste to the use of metals in “value added” products such as metalbased catalysts for the fuel industry and in metallodrugs. Examples of “value added” products include rhodium as a promoter in molybdenum sulfide as a catalyst for hydrodesulfurization of fuel oil, vanadium as a catalyst in oxidative desulfurization of fuel oil, vanadium and palladium as therapeutic agents for diabetes and cancer, respectively. Current and future work involves (i) the development of metal-selective scavengers to recover lost metal value in mining wastewaters, and (ii) the design of metal-based catalytic materials for refinement of bio-based oils to biofuel as well as for production of green LPG through hydroprocessing. Our work centres around both basic and applied chemistry towards mineral beneficiation and with a bias towards greener production.
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Tribological characteristics of polymers under high force small oscillating angular contact

- Bradfield, Jarad Wade

Authors: Bradfield, Jarad Wade
Subjects: Tribology , Polymers.
Language: English
Type: Thesis , Masters , MTech (Mechanical Engineering)
Identifier: vital:9637 , http://hdl.handle.net/10948/d1020598
Description: This study was intended to establish which polymer material is best suited as the material for bushes used in high force small oscillating angular contact applications as typically found in a large sugar mill coupling. A Tribometer as well as a designed and manufactured Bearing Testing Machine, which simulates and accelerates the wear caused in the intended application, was used to determine the wear rates and coefficients of friction for seven polymer materials. Materials were selected for their superior mechanical and thermal properties. The Tribometer was fitted with a linear reciprocating rig, so as to simulate the small oscillating movement prevalent in the intended application. Each Tribometer test ran for a duration of two hours with a frequency of 33.1 Herts and a normal loading of 40N. Bearing Testing Machine tests were done under similar constraints but with 30kN loading present on the surface of a bushes inner race. These tests had a longer duration of 24 or 48 hours or until intense wearing occurred. Initially both testing methods will be analysed independently of each other in order to try and identify a relationship between the wear rate and coefficient of friction for the different polymers. The different testing methods’ results will be compared to each other in order to establish if a correlation between the materials tested could be found.
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Tsimbarume, the Hardened Bachelor

- Tracey, Hugh

Authors: Tracey, Hugh
Subjects: African story , Bachelor , Hunter , Expectation
Language: English
Type: Sound , Story
Identifier: vital:15462 , MOA33-04 , http://hdl.handle.net/10962/d1017816 , MOA33
Description: Traditional african story of the bachelor who became a hunter and found more than he had expected. , This recording is held at the International Library of African Music. For further information contact ilamlibrary@ru.ac.za , This recording was digitised by the International Library of African Music , Original format: 15ips reel , Equipment used in digitisation: Studer B 67 Tape Recorder; Nagra III , Software: Sound Forge V.6 , Sample rate: 44100Hz 16Bit Stereo
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Tuning the physico-electrochemical properties of novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine complex using phenylamine-functionalised SWCNTs

- Agboola, Bolade Oyeyinka, Ozoemena, Kenneth I., Nyokong, Tebello, Fukuda, Takamitsu, Kobayashi, Nagao

Authors: Agboola, Bolade Oyeyinka , Ozoemena, Kenneth I. , Nyokong, Tebello , Fukuda, Takamitsu , Kobayashi, Nagao
Language: English
Type: Article
Identifier: vital:7238 , http://hdl.handle.net/10962/d1019689
Description: The integration of phenylamine-functionalised SWCNTs (SWCNT-phenylamine) with a novel cobalt (II) octa[(3,5-biscarboxylate)-phenoxy] phthalocyanine (CoOBPPc) complex has been described. The physical and electrochemical properties of the CoOBPPc-SWCNT-phenylamine hybrid were evaluated using spectroscopy (IR and UV–vis), field emission scanning electron microscopy and electrochemistry (cyclic voltammetry and electrochemical impedance spectroscopy). Integration of SWCNT-phenylamine resulted in the physical transformation of the CoOBCPPc from the usually bluish colour of cobalt phthalocyanine complexes to a beautiful bright green colour. In addition, the heterogeneous electron transfer kinetics and electrocatalytic properties of the CoOBCPPc were greatly enhanced following the attachment of the SWCNT-phenylamine. The potential electrocatalytic application of the hybrid was tested using β-nicotinamide adenine dinucleotide (NADH) as a model biological analyte. Interestingly, the onset oxidation potential of this analyte was significantly reduced (300 mV) by this hybrid compared to the bare electrode. , Original publication is available at http://dx.doi.org/doi:10.1016/j.carbon.2009.10.023
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Two decades of curriculum transformation: what have we learnt and where do we go from here?

- Blignaut, Sylvan

Authors: Blignaut, Sylvan
Subjects: Curriculum change -- South Africa , Education -- South Africa , f-sa
Language: English
Type: text , Lectures
Identifier: http://hdl.handle.net/10948/16076 , vital:28318
Description: In this lecture, I will revisit the implementation of a new curriculum in South Africa’s schooling system and provide a brief overview of why curriculum change is so complex and fraught with difficulties. I will argue that an important reason for the failure of curriculum implementation could be ascribed to a relative neglect by policymakers of “teacher landscapes” or the beliefs teachers have about teaching. I will argue that it “matters what teachers think and do” and if policymakers do not take account of this reality, successful curriculum implementation will remain a challenge.
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Ultra-high precision manufacturing

- Abou-El-Hossein, Khaled

Authors: Abou-El-Hossein, Khaled
Subjects: Machining , Diamond turning , f-sa
Language: English
Type: text , Lectures
Identifier: http://hdl.handle.net/10948/20878 , vital:29410
Description: One of the engineering areas focusing on the research and development of highvalue components and manufacturing technologies is precision engineering. Precision engineering represents a variety of engineering and science disciplines ranging from areas such as mechanical, electronics and industrial engineering to chemistry, physics, optics and materials science. This paper aims at familiarising the reader with the recent advances in ultra-high precision manufacturing technologies and their applications for the production of various critical components employed in different sectors of the industry. In this paper, the principles of ultra-high precision manufacturing will be discussed followed by examples of its use in various industrial applications. The status of ultra-high precision manufacturing in terms of current research issues and future trends will be discussed. In addition, research activities and projects in the area of precision manufacturing that are currently conducted at the NMMU will be also highlighted. Finally, the author looks forward to presenting herewith comprehensive information that could be useful to the reader and easy to understand by the bigger NMMU’s community.
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Ultrafast Photodynamics of the Indoline Dye D149 Adsorbed to Porous ZnO in Dye-Sensitized Solar Cells

- Rohwer, Egmont, Richter, Christoph, Heming, Nadine, Strauch, Kerstin, Litwinski, Christian, Nyokong, Tebello, Schlettwein, Derck, Schwoerer, Heinrich

Authors: Rohwer, Egmont , Richter, Christoph , Heming, Nadine , Strauch, Kerstin , Litwinski, Christian , Nyokong, Tebello , Schlettwein, Derck , Schwoerer, Heinrich
Language: English
Type: Article
Identifier: vital:7326 , http://hdl.handle.net/10962/d1020576
Description: We investigate the ultrafast dynamics of the photoinduced electron transfer between surface-adsorbed indoline D149 dye and porous ZnO as used in the working electrodes of dye-sensitized solar cells. Transient absorption spectroscopy was conducted on the dye in solution, on solid state samples and for the latter in contact to a I−/I3− redox electrolyte typical for dye-sensitized solar cells to elucidate the effect of each component in the observed dynamics. D149 in a solution of 1:1 acetonitrile and tert-butyl alcohol shows excited-state lifetimes of 300±50 ps. This signature is severely quenched when D149 is adsorbed to ZnO, with the fastest component of the decay trace measured at 150±20 fs due to the charge-transfer mechanism. Absorption bands of the oxidized dye molecule were investigated to determine regeneration times which are in excess of 1 ns. The addition of the redox electrolyte to the system results in faster regeneration times, of the order of 1 ns. , Original publication is available at http://dx.doi.org/10.1002/cphc.201200715
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Unsymmetrically Substituted Nickel Triazatetra-Benzcorrole and Phthalocynanine Complexes: Conjugation to Quantum Dots and Applications as Fluorescent “Turn ON” Sensors

- Adegoke, Oluwasesan, Nyokong, Tebello

Authors: Adegoke, Oluwasesan , Nyokong, Tebello
Language: English
Type: Article
Identifier: vital:7311 , http://hdl.handle.net/10962/d1020403
Description: We report on the design and application of fluorescent nanoprobes based on the covalent linking of L-glutathione-capped CdSe@ZnS quantum dots (QDs) to newly synthesized unsymmetrically substituted nickel mercaptosuccinic acid triazatetra-benzcorrole (3) and phthalocyanine (4) complexes. Fluorescence quenching of the QDs occurred on conjugation to complexes 3 or 4. The nanoprobes were selectively screened in the presence of different cations and Hg2+ showed excellent affinity in “turning ON” the fluorescence of the nanoprobes. Experimental results showed that the sensitivity of QDs-4 towards Hg2+ was much higher than that of QDs-3 nanoprobe. The mechanism of reaction has been elucidated based on the ability of Hg2+ to coordinate with the sulphur atom of the Ni complex ring and apparently “turn ON” the fluorescence of the linked QDs. , Original publication is available at http://dx.doi.org/10.1007/s10895-013-1317-4
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Utilising new technology to enable sustainable chemical and drug manufacturing in Africa

- Watts, Paul

Authors: Watts, Paul
Subjects: Drug development , Pharmacology , f-sa
Language: English
Type: text , Lectures
Identifier: http://hdl.handle.net/10948/21000 , vital:29426
Description: Over the last few decades organic chemists have developed highly sophisticated chemical reactions to prepare very complex molecules. The pharmaceutical industry uses the methodology that academics develop within research programmes to manufacture drugs to treat a plethora of medical conditions. When unwell, all citizens expect treatment, however it needs to be remembered that the pharmaceutical industry is a business in order to make a profit for its shareholders, and consequently only rich nations can afford access to the most modern treatments available.
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