Rhodes University Graduation Ceremony 2008
- Authors: Rhodes University
- Date: 2008
- Language: English
- Type: text
- Identifier: vital:8139 , http://hdl.handle.net/10962/d1007251
- Description: Rhodes University Graduation Ceremony [at the] 1820 Settlers National Monument Thursday, 27 March at 18:00 [and] Friday, 28 March at 10:30; 14:30 & 18:00 [and] Saturday, 29 March at 10:30
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Rhodes University Research Report 2008
- Authors: Rhodes University
- Date: 2008
- Language: English
- Type: Text
- Identifier: vital:563 , http://hdl.handle.net/10962/d1011963
- Description: [From Preface] This report outlines the extent and quality of our research outputs for 2008. Rhodes possesses an admirable research milieu and culture that provides the space for intellectual development, debate, and the flourishing of ideas. As the smallest university in South Africa, we take special pride in Rhodes University having amongst the highest per capita research outputs. One of the core goals of a university is to produce knowledge, a public responsibility that Rhodes takes very seriously, and we continuously seek new opportunities to do so. Many of Rhodes University’s academics, departments, institutes, centres, and units are at the leading edge of research and are actively advancing knowledge in a range of disciplines and fields. During 2008, Rhodes launched three new centres. The DST/Mintek Nanotechnology Innovation Centre (Sensors) was founded under the directorship of Professor Tebello Nyokong; the Centre for Higher Education Research, Teaching & Learning, was formed out of a much expanded Academic Development Centre, under the leadership of the Dean of Teaching and Learning, Professor Chrissie Boughey; and the Centre for the Study of Democracy was launched under the leadership of Professor Stephen Friedman as a joint venture of Rhodes and the University of Johannesburg. A second DST/NRF South African Research Chair was launched in the field of Marine Biology, with Professor Christopher McQuaid as its incumbent. Rhodes’s first DST/NRF Chair, Professor Tebello Nyokong, in the area of Medicinal Chemistry and Nanotechnology, had an outstanding year, with accolades coming from a range of sources. She was officially recognized by the National Research Foundation as one of the most productive researchers in the country with 35 ISI indexed journal papers published during the year, an extraordinary achievement by anyone’s standard, and with a large number of additional accredited outputs by her and her group during the year. In the area of the creative arts, Mrs Janet Buckland of our Drama Department won special recognition as the recipient of the national Woman of the Year award promoted by Shopright-Checkers and SABC 2, in both the Arts and culture section and as the overall recipient. Professor Fackson Banda of our Journalism Department won the 2008 MISA (Media Institute of Southern Africa) Press Freedom Award. In the Geology Department, Professor Goonie Marsh was awarded the Geological Society of South Africa’s highest scientific award, the Draper Memorial Medal, in recognition of his outstanding contribution to geological sciences in general, and particularly for his research work in the petrology of volcanic rocks and igneous provinces in South Africa. The Vice-Chancellor's Distinguished Senior Research Award for 2008 went to Professor Peter Vale of the Department of Political and International Studies, for the national and international impact of his scholarly activities over a sustained period. The Vice-Chancellor's Book Award for 2008 went to Professor Dan Wylie of the Department of English, for Myth of Iron - Shaka in History (UKZN Press, 2008). Rhodes postgraduates continue to excel in winning prestigious international and local scholarships, including the Rhodes (Oxford), Mandela Rhodes, Flanagan, Commonwealth, and Fulbright. A major challenge facing South African Universities is the development of a new generation of teacher-scholars, one that Rhodes University has been engaging with for a number of years. We acknowledge the strong support of the Mellon Foundation, which has assisted us in creating a focused programme aimed at cultivating a new generation of black and women researchers, and in making a contribution towards transforming our academic body in the process. I am pleased to be able to announce that the Kresge Foundation has agreed to fund this initiative for a further four years. I extend my congratulations and thanks to all of our researchers, collaborators, funders, donors, and partners who contributed to making 2008 a year in which research at Rhodes University flourished. Your expertise, dedication, rigour and generosity make Rhodes University the rich and distinctive intellectual space that it is.
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Risk assessment and the effects of overhead work - an automotive industry example
- Authors: Elliott, Andrew Brent
- Date: 2008
- Subjects: Human engineering -- South Africa , Industrial safety -- South Africa , Automobile industry workers -- South Africa -- Health risk assessment , Automobile industry and trade -- South Africa -- Safety measures , Musculoskeletal system -- Wounds and injuries -- Prevention , Lifting and carrying -- Safety measures , Work measurement , Posture
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5132 , http://hdl.handle.net/10962/d1005211 , Human engineering -- South Africa , Industrial safety -- South Africa , Automobile industry workers -- South Africa -- Health risk assessment , Automobile industry and trade -- South Africa -- Safety measures , Musculoskeletal system -- Wounds and injuries -- Prevention , Lifting and carrying -- Safety measures , Work measurement , Posture
- Description: The focus of this investigation was an analysis of the work demands being placed on South African automotive industry workers as there is a recognised problem with regard to the prevalence of musculoskeletal disorders (MSDs). Preliminary work was conducted to highlight the dominant risks and areas which elicited higher numbers of MSDs within the chosen automotive plant. An area of concern was highlighted through medical record analysis and the use of risk assessment tools, thereby prioritising the need for ergonomic intervention. In particular, the effects of varying restricted and overhead work heights on the biomechanical, physiological and psychophysical responses of an individual were investigated. Twenty-eight subjects were required to complete sixteen conditions. The conditions consisted of the adoption of restricted and upright overhead static postures, with half requiring the holding of four kilograms of weight in the hands and the remaining eight conditions having no weight. Testing was carried out using an electromyography unit, ergospirometer and a perceptual Body Discomfort Map and Scale. This involved a habituation and testing session. The results of the testing revealed the biomechanical and physiological responses were dependant on the change in height. Body discomfort was also shown to be variable over the changing height conditions. This indicates that there is a significant effect of height on an individual’s responses during overhead work. The extreme restricted (-200mm and -100mm) and upright (+300mm and +400mm) overhead conditions within this study were limiting, as they elicited the highest muscle activation, physiological responses and body discomfort ratings. Positions that are preferable to adopt, which were identified from the results in this study, indicate conditions closer to head height (0mm and +100mm) were favourable. The results therefore illustrate how awkward working postures during work are likely to elicit higher demands from an individual, which could lead to an increased risk for the development of a musculoskeletal disorder. The added factor of weight elicited significant results over all variables, excluding a respiratory The focus of this investigation was an analysis of the work demands being placed on South African automotive industry workers as there is a recognised problem with regard to the prevalence of musculoskeletal disorders (MSDs). Preliminary work was conducted to highlight the dominant risks and areas which elicited higher numbers of MSDs within the chosen automotive plant. An area of concern was highlighted through medical record analysis and the use of risk assessment tools, thereby prioritising the need for ergonomic intervention. In particular, the effects of varying restricted and overhead work heights on the biomechanical, physiological and psychophysical responses of an individual were investigated. Twenty-eight subjects were required to complete sixteen conditions. The conditions consisted of the adoption of restricted and upright overhead static postures, with half requiring the holding of four kilograms of weight in the hands and the remaining eight conditions having no weight. Testing was carried out using an electromyography unit, ergospirometer and a perceptual Body Discomfort Map and Scale. This involved a habituation and testing session. The results of the testing revealed the biomechanical and physiological responses were dependant on the change in height. Body discomfort was also shown to be variable over the changing height conditions. This indicates that there is a significant effect of height on an individual’s responses during overhead work. The extreme restricted (-200mm and -100mm) and upright (+300mm and +400mm) overhead conditions within this study were limiting, as they elicited the highest muscle activation, physiological responses and body discomfort ratings. Positions that are preferable to adopt, which were identified from the results in this study, indicate conditions closer to head height (0mm and +100mm) were favourable. The results therefore illustrate how awkward working postures during work are likely to elicit higher demands from an individual, which could lead to an increased risk for the development of a musculoskeletal disorder. The added factor of weight elicited significant results over all variables, excluding a respiratory individual.
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Rock magnetic stratigraphy of a mafic layered sill: a key to the Karoo volcanics plumbing system
- Authors: Maes, S M , Ferré, E E , Tikoff, B , Brown, P E , Marsh, Julian S
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144901 , vital:38389 , https://doi.org/10.1016/j.jvolgeores.2005.07.038
- Description: The Insizwa sill is an 1 km-thick subhorizontal layered mafic intrusion and part of the Karoo Large Igneous Province in South Africa. This well-exposed intrusion consists of several superimposed petrologically and geochemically distinct units. Magnetic methods were used to study the intrusion in order to constrain the physical processes active in these types of bodies during crystallization. Rock magnetism studies indicate that within different petrologic units bulk susceptibility is controlled by primary magnetite (with minor pyrrhotite) and/or paramagnetic minerals (olivine, pyroxene). New magnetic data based on 659 specimens obtained from 3 vertical borehole cores, each spaced 5 km apart, confirm the prominent vertical zonation in low field magnetic susceptibility (Klf), degree of anisotropy (Pj) and orientation of the anisotropy of magnetic susceptibility (AMS) axes.
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SA scientist one of the top five female physical scientists
- Authors: Limson, Janice L
- Date: 2008
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article , text
- Identifier: vital:7189 , http://hdl.handle.net/10962/d1006283 , http://www.scienceinafrica.co.za/2008/october/nyokong.htm
- Description: South African scientist Professor Tebello Nyokong scoops 2009 L’ORÉAL-UNESCO For Women in Science Award. Announced on November 10, South African scientist Professor Tebello Nyokong has become the first South African scientist to win the L’ORÉALUNESCO award for women in science for research in physical sciences.
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School principals' perceptions of team management : a multiple case-study of secondary schools
- Authors: Van der Mescht, Hennie , Tyala, Zakunzima
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:6105 , http://hdl.handle.net/10962/d1009732
- Description: The notion of school management through teams (team management), though not a new phenomenon in South Africa, was formalized after the advent of democracy in 1994 and the subsequent reorganization of the education system. The concept was subsequently fleshed out in official documentation where the composition and roles of school management teams (SMTs) were elaborated upon. The notion of team management is rooted in theories that stress participation, notably site-based (school-based) management, teamwork, and distributed leadership. We report on a study in which the perceptions of secondary school principals, in Grahamstown, South Africa, of team management were explored. The study was interpretive in orientation, and utilized qualitative data gathering techniques in all (ten) of the state-aided secondary schools in Grahamstown in the Eastern Cape province. We found that, while team management was generally welcomed and even celebrated by principals, there were fundamental tensions surrounding principals' understanding of their leadership roles in a team context. We consider the implications of these findings for leadership development in the context of team management.
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Shoppers Drug Mart or poachers Drug Mart?
- Authors: Attaran, Amir , Walker, Roderick B
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:6346 , http://hdl.handle.net/10962/d1006018
- Description: [From the text]: Shoppers Drug Mart (Pharmaprix in Quebec) is a familiar Canadian institution. Its 1000 stores dot the landscape; no pharmacy chain is larger. In many Canadian communities, the corporation's well-staffed local franchises give patients quality care. However, in South Africa, the same corporation is potentially contributing to a public health disaster. In 2005, 2006 and twice in 2007, it has dispatched recruiters to that country, with the mission of plucking pharmacists from a continent that has far too few for its needs. Shoppers Drug Mart promises 6-figure salaries and help to establish a brilliant career in Canada. The carrot, and the helping hand holding it, are huge.
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Should active recruitment of health workers from sub-Saharan Africa be viewed as a crime?
- Authors: Mills, E J , Schabas, W A , Volmink, J , Walker, Roderick B , Ford, N , Katabira, E , Anema, A , Joffres, M , Cahn, P , Montaner, J
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:6392 , http://hdl.handle.net/10962/d1006314
- Description: (Conclusion) When the international community permits for-profit companies to actively entice overworked and often underpaid workers away from the most vulnerable populations, it is contributing to the deterioration of essential health-care delivery. Improvement of the health of the world’s poor is a challenge that the international community is failing to adequately address. Current international treaties and commitments are severely compromised if we are unwilling to adhere to their principles and prevent obvious harms to poor people. Clear, enforced regulation is needed to prevent recruitment companies from enticing health workers away from their local work, and developed countries should adequately compensate less-developed countries for the human resources they have lost and continue to lose.
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Sing a swansong for the SABC as we know it : keep public broadcasting, redistribute the broadcaster
- Authors: Berger, Guy
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159326 , vital:40288 , https://hdl.handle.net/10520/EJC140098
- Description: Behind the dragged-out confrontations around the SABC are a politics of paralysis. That's not necessarily a bad thing if the alternative is the broadcaster being a tool of a single particular force. But it's also not exactly first prize for South Africans. Power is divided across so many centres that no single force has been able to easily prevail on SABC during the year.
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Social and ecological trade offs in combating land degradation: The case of invasion by a woody shrub (Euryops floribundus) at Macubeni, South Africa
- Authors: Shackleton, Charlie M , Gambiza, James
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181235 , vital:43711 , xlink:href="https://doi.org/10.1002/ldr.849"
- Description: Woody plant invasions, either of alien or indigenous species, are deemed to result in loss of ecosystem goods and services in many areas throughout the world, resulting in significant degradation and economic costs. Invasion of Euryops floribundus, a species indigenous to South Africa, is perceived to have reduced the grazing available for domestic livestock. Consequently, a programme of manual eradication has been implemented to improve the grazing resource and provide jobs for poverty alleviation. However, there is potential for a conflict of interest as our study shows that almost all households rely on Euryops for fuel and at times fencing material, whereas only a minority of households own livestock. Moreover, comparison of invaded and non-invaded sites indicated that the invaded sites harbour greater plant species richness and higher grass culm density per unit area of grass cover, as well as higher forb and litter cover. While invaded sites had lower grass cover, overall plant cover was no different between invaded and non-invaded sites. Multivariate analysis indicated no obvious differentiation in community composition between invaded and non-invaded areas, suggesting stronger drivers of community composition other than Euryops invasion presumed to be facilitated by the effects of high livestock densities. Overall, our study suggests that the clearing operation may well benefit from a better understanding of the social needs, perceptions of degradation by the various stakeholders and ecological dynamics of the area, especially local reliance on the resources, and the dynamics of the invasion, particularly its extent, rate of spread and susceptibility for re-invasion in the cleared areas.
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Solar cycle effects on GNSS-derived ionospheric total electron content observed over Southern Africa
- Authors: Moeketsi, Daniel Mojalefa
- Date: 2008
- Subjects: Ionosphere -- Africa, Southern Electrons Ionospheric electron density -- Africa, Southern Ionosondes -- Africa, Southern Electromagnetic waves
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5489 , http://hdl.handle.net/10962/d1005275
- Description: The South African Global Navigation Satellite System (GNSS) network of dual frequency receivers provide an opportunity to investigate solar cycle effects on ionospheric Total Electron Content (TEC) over the South Africa region by taking advantage of the dispersive nature of the ionospheric medium. For this task, the global University of New Brunswick Ionospheric Modelling Technique (UNB-IMT) was adopted, modified and applied to compute TEC using data from the southern African GNSS Network. TEC values were compared with CODE International GNSS services TEC predictions and Ionosonde-derived TEC (ITEC) measurements to test and validate the UNB-IMT results over South Africa. It was found that the variation trends of GTEC and ITEC over all stations are in good agreement and show pronounced seasonal variations with high TEC values around equinoxes for a year near solar maximum and less pronounced around solar minimum. Signature TEC depletions and enhanced spikes were prevalently evident around equinoxes, particularly for a year near solar maximum. These observations were investigated and further discussed with an analysis of the midday Disturbance Storm Time (DST) index of geomagnetic activity. The residual GTEC – ITEC corresponding to plasmaspheric electron content and equivalent ionospheric foF2 and total slab thickness parameters were computed and comprehensively discussed. The results verified the use of UNB-IMT as one of the tools for ionospheric research over South Africa. The UNB-IMT algorithm was applied to investigate TEC variability during different epochs of solar cycle 23. The results were investigated and further discussed by analyzing the GOES 8 and 10 satellites X-ray flux (0.1 – 0.8 nm) and SOHO Solar Extreme Ultraviolet Monitor higher resolution data. Comparison of UNB-IMT TEC derived from collocated HRAO and HARB GNSS receivers was undertaken for the solar X17 and X9 flare events, which occurred on day 301, 2003 and day 339, 2006. It was found that there exist considerable TEC differences between the two collocated receivers with some evidence of solar cycle dependence. Furthermore, the daytime UNB TEC compared with the International Reference Ionosphere 2001 predicted TEC found both models to show a good agreement. The UNB-IMT TEC was further applied to investigate the capabilities of geodetic Very Long Baseline Interferometry (VLBI) derived TEC using the Vienna TEC Model for space weather monitoring over HartRAO during the CONT02 and CONT05 campaigns conducted during the years 2002 (near solar maximum) and 005 (near solar minimum). The results verified the use of geodetic VLBI as one of the possible instruments for monitoring space weather impacts on the ionosphere over South Africa.
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South Africa and Malaysia: identity and history in South-South relations
- Authors: Haron, Muhammed
- Date: 2008
- Subjects: Critical theory South Africa -- Foreign relations -- Malaysia Malaysia -- Foreign relations -- South Africa South Africa -- Politics and government -- History Malaysia -- Politics and government -- History South Africa -- Politics and government Malaysia -- Politics and government South Africa -- Social conditions -- History Malaysia -- Social conditions -- History South Africa -- Economic conditions Malaysia -- Economic conditions
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2780 , http://hdl.handle.net/10962/d1002990
- Description: The focus of this thesis is on the bilateral relationship between South Africa and Malaysia. The thesis appropriates ‘critical theory,’ and as a flexible theoretical tool, and, as an open-ended, loose frame in order to give voice to the marginalized and voiceless from the South. The thesis thus looks at the politico-economic ties that have been developed and brings into view the socio-cultural relations that had been established between the peoples of the two sovereign nation-states during the apartheid and post-apartheid eras respectively. The basic purpose of this study was fivefold: (a) to contribute to the extant literature that concentrates on South Africa’s relations with Malaysia, (b) to examine the relationship at political and economic ties in some detail, (c) to demonstrate that apart from the afore-mentioned bonds IR specialists should also take into account the socio-cultural dimensions of international relations, (d) to bring to light the nation-state’s limitations when discussing the role of non-state actors and considering the contributions of other factors such as globalization, and (e) to stimulate further research on bilateral and multilateral relations in the South – particularly between South Africa and other states in Asia and Latin America - that would assist to better understand the past, present and perhaps the future.
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Spam Construction Trends
- Authors: Irwin, Barry V W , Friedman, Blake
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428762 , vital:72534 , https://www.researchgate.net/profile/Barry-Ir-win/publication/220803159_Spam_Construction_Trends/links/53fc76bd0cf2dca8ffff22fb/Spam-Construction-Trends.pdf
- Description: This paper replicates and extends Observed Trends in Spam Construction Tech-niques: A Case Study of Spam Evolution. A corpus of 169,274 spam email was col-lected over a period of five years. Each spam email was tested for construction techniques using SpamAssassin’s spamicity tests. The results of these tests were col-lected in a database. Formal definitions of Pu and Webb’s co-existence, extinction and complex trends were developed and applied to the results within the database. A comparison of the Spam Evolution Study and this paper’s results took place to de-termine the relevance of the trends. A geolocation analysis was conducted on the corpus, as an extension, to determine the major geographic sources of the corpus.
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Spatial and temporal variations in metals in the sediment and water of selected Eastern Cape Estuaries, South Africa
- Authors: Orr, Kyla Kathleen
- Date: 2008
- Subjects: Marine sediments -- South Africa -- Eastern Cape , Metals -- South Africa -- Eastern Cape , Metals -- Environmental aspects , Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape , Estuarine sediments -- South Africa -- Eastern Cape , Water quality -- South Africa -- Eastern Cape , Water pollution -- South Africa -- Eastern Cape , Environmental toxicology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5769 , http://hdl.handle.net/10962/d1005457 , Marine sediments -- South Africa -- Eastern Cape , Metals -- South Africa -- Eastern Cape , Metals -- Environmental aspects , Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape , Estuarine sediments -- South Africa -- Eastern Cape , Water quality -- South Africa -- Eastern Cape , Water pollution -- South Africa -- Eastern Cape , Environmental toxicology -- South Africa -- Eastern Cape
- Description: The spatio-temporal patterns in concentrations of selected metals within the sediment (Cd, Co, Cu, Fe, Pb, Ni and Zn) and water (Cd and Pb) of three permanently open estuaries (Kariega, Kowie, Great Fish) and six temporary open-closed estuaries (Mpekweni, East Kleinemonde, West Kleinemonde, Riet, Kasouga, Boknes) were investigated. The concentrations of metals were influenced by size composition and total organic content of the sediments. Enrichment factors (EFs), using Fe as a reference element, and baseline linear regression models for metals vs. Fe were calculated to assess the extent of metal enrichment in the sediments. The mean concentrations of metals in the sediments(mg·kg⁻¹) showed ranges of 0.28 – 2.31 for Cd, 1.26 – 6.24 Co, 0.69 – 6.93 for Cu, 2119 – 14912 for Fe, 2.29 –14.01 for Ni, 4.81 – 22.20 for Pb and 5.77 – 21.75 for Zn. Mean normalized enrichment factors ranged between 0.75 – 6.19 for Cd, 0.53 – 2.71 for Co, 0.22 – 0.84 for Cu, 0.30 – 1.87 for Ni, 0.99 – 3.17 for Pb and 0.14 – 0.98 for Zn. All nine estuaries had average enrichment factors of greater than 1 for Cd. In general there was no enrichment of Cu and Zn in the sediments of any of the estuaries included in this study (EFs < 1). The Kariega, East Kleinemonde, West Kleinemonde, Riet and Great Fish Estuaries showed some degree of enrichment for Co (1 < EF < 4), Ni (1 < EF < 2) and Pb (1 < EF < 4), while the Mpekweni, Kasouga, Boknes and Kowie Estuaries were unenriched with these metals (EF < 1). Enrichment factors for Cd, Co and Pb typically followed the development gradient along the estuaries, suggesting anthropogenic enrichment. The concentrations of Cd and Pb in the water of the nine estuaries were also determined. The average concentrations of Cd and Pb in the water (μg·ℓ⁻¹) ranged between 0.05 – 3.32 and 0.75 – 34.13 respectively. On average the concentrations of Cd and Pb in the water of all the estuaries were below the South African recommended water quality guidelines for coastal marine waters. Variations in metal concentrations associated with changes in hydrology (wet vs. dry season) were determined in the water and sediment of the Kariega, East Kleinemonde and Riet Estuaries. Cobalt, Pb and Ni enrichment in the Kariega Estuary sediment was significantly higher during the dry season, and the mean concentrations of Pb and Cd in the water column were 19-fold and 66-fold higher in the dry season. The elevated concentration of metals during the dry season could be related to accumulation of diffuse pollution from human activities within the catchment area. Conversely, inflow of fresh water into the estuary had the net effect of reducing the concentration and enrichment of these metals within the Kariega Estuary due to scouring and outflow of estuarine water and sediment into the marine environment. The temporal variations in metal concentrations and enrichment factors were less pronounced in the temporary open-closed estuaries than the permanently open Kariega Estuary. The observed trend can probably be related to the low anthropogenic impact within the catchment areas of these systems, and the relatively smaller size of the catchments. Significant spatial variations existed in metal enrichment in the sediment of both the East Kleinemonde and Riet estuaries, with the highest degrees of enrichment occurring in the sediments from the marine environment and lower reaches.
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Spontaneous charge transfer between zinc tetramethyl-tetra-2, 3-pyridinoporphyrazine and CdTe and ZnS quantum dots
- Authors: Moeno, Sharon , Idowu, Mopelola , Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265997 , vital:53908 , xlink:href="https://doi.org/10.1016/j.ica.2008.02.048"
- Description: Zinc tetramethyl-tetra-2,3-pyridinoporphyrazine (ZnTmtppa(-2)) gets reduced to the ZnTmtppa(-3) species on interaction with CdTe QDs capped with 2-mercaptoethanol (2-ME) or thioglycolic acid (TGA) and ZnS QDs capped with 2-ME. The interaction occurs without photolysis. The fluorescence of the QDs is quenched by ZnTmtppa resulting in large quenching constants. Binding of ZnTmtppa to QDs occurs with two molecules of the former binding to the latter.
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Stakeholders' perceptions of the shift to democratic leadership in a secondary school in the Eastern Cape : a case study
- Authors: Lombo, Mzimkhulu Solomon
- Date: 2008
- Subjects: Education -- South Africa -- Eastern Cape , Education and state -- South Africa -- Eastern Cape , Education -- Political aspects -- South Africa -- Eastern Cape , Education, Secondary -- South Africa -- Eastern Cape -- Case studies , Educational change -- South Africa -- Eastern Cape , Educational leadership -- South Africa -- Eastern Cape , School management and organization -- South Africa -- Eastern Cape , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2001 , http://hdl.handle.net/10962/d1015541
- Description: The advent of political democracy in South Africa in 1994 gave rise to new policy in education promoting democratic and participative ways of managing and leading schools. The intention was both to break from the apartheid past which was characterised by an authoritarian, nonparticipative mindset, as well as to point the way for future education development. Principals of schools were expected to develop structures and adopt management and leadership styles which were participative, inclusive and developmental. Many principals would not have been prepared for this shift in mindset, and notions of full participation in governance by parents, and representation of learners through constituted bodies would have been new to them. In this case study of one semi-urban secondary school in the Eastern Cape the researcher sought to establish whether and to what extent the school had moved towards the new management and leadership approaches. The study is interpretive in orientation, and made use of interviews and document analysis. This research has found that the school had democratised its management and leadership to a considerable degree, but that this was not necessarily due to profound changes on the part of the principal 's leadership. The principal emerged as a democratic leader by nature. More significant seem to be the structures which the school had put in place, both officially and internally, to promote widespread participation and the distribution of leadership. This decentralised system of management has contributed to a distinct organisation culture in the school characterised by warmth, openness and ubuntu.
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State sovereignty and alternative community in southern Africa: exploring the Zion Christian Church as the building block for deeper notions of regional community
- Authors: Radebe, Zandisiwe
- Date: 2008
- Subjects: Zionist Christian Church Southern African Development Community Community development -- Africa, Southern Regionalism -- Africa, Southern Sovereignty -- Africa, Southern Africa, Southern -- Economic integration
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2824 , http://hdl.handle.net/10962/d1003034
- Description: Regional community in southern Africa has been limited to the region’s states. As a result, deeper notions of community emanating from non-state actors, particularly transnational social movements, continue to be ignored. In an attempt to transcend state centrism, this thesis highlights alternative forms of regional community by exploring the Zion Christian Church (ZCC), one of southern Africa’s biggest and fastest growing cross-border movements. The ZCC is a potential agent for developing regional community from the bottom-up, driving a people-oriented regional integration approach in southern Africa. The ZCC, with its extensive following among the region’s poor, offers a compelling example of a grassroots and truly bottom-up approach to regional community. This thesis explores the possibility of the ZCC as a model of alternative community and identity centred on people’s daily experiences and grounded in a shared history and solidarity. It seeks to highlight the significance of transnational movements like the ZCC to policy makers in the region and it argues that grassroots communities are marching ahead of SADC member states and politicians in the area of integration. There exists a transnational cooperation amongst followers of the ZCC and other grassroots communities across the region and this cooperation transcends the traditional notion of state sovereignty, thereby highlighting deeper notions of what it means to be a community at regional level.
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Staying in touch Zimbabwean media
- Authors: Chatora, Arther
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454880 , vital:75383 , https://hdl.handle.net/10520/EJC140100
- Description: I have been studying in Grahamstown for five years and I now consider Grahamstown my second home. It has been fairly easy for me to settle here given the fact that Rhodes University is home to many Zimbabwe-an students and academic personnel. Diverse cultures merge in this town, giving it a cosmopolitan feel. Although seemingly far from Gra-hamstown, Zimbabwe gets a lot of representation from different media organisations.
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Sterols and sterolins in Hypoxis hemerocallidea (African potato)
- Authors: Nair, V D P , Kanfer, Isadore
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:6417 , http://hdl.handle.net/10962/d1006535
- Description: Commercially available health supplements and herbal remedies containing sterols and sterolins, either from African potato (Hypoxis hemerocallidea) alone, or whether enriched with sterols and sterolins, are claimed to be efficacious in the treatment of a variety of ailments. Sterols and sterolins in African potato are purported to be the relevant constituents that are required for the therapeutic claims of such products. A patent describing the extraction of sterolins from African potato plant material has claimed that approximately 9 mg sterolins can be isolated from 100 g of an enriched aqueous African potato extract. Our analysis of African potato plant material and its sterol and sterolin content, when similarly prepared, shows that the measureable content of sterols and sterolins in African potato is far less than the amounts of these compounds that have been claimed to be necessary for therapeutic benefit. We conclude that therapeutic claims relating to sterol and sterolin content in African potato are unsubstantiated, in view of the extremely low content of such compounds that we have isolated from our plant material, and in products containing African potato, or extracts thereof.
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Studies directed towards the synthesis of chromone carbaldehyde-derived HIV-1 protease inhibitors
- Authors: Molefe, Duduzile Mabel
- Date: 2008
- Subjects: Protease Inhibitors , HIV infections , HIV (Viruses) , AIDS (Disease) , Proteolytic enzymes , Heterocyclic compounds -- Derivatives , Chemical kinetics , Nuclear magnetic resonance spectroscopy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4526 , http://hdl.handle.net/10962/d1015542
- Description: A series of chromone-3-carbaldehydes have been prepared using Vilsmeier-Haack methodology while a corresponding series of chromone-2-carbaldeydes have been synthesized via the Kostanecki-Robinson reaction. Baylis-Hillman reactions have been conducted on both series of chromone carbaldehydes using three different catalysts, viz., 1,4-diazabicyclo(2.2.2]octane (DABCO), 1,8-diazabicyclo[5.4.0]undec- 7-ene (DBU) and 3-hydroxyquinuclidine (3HQ), and acrylonitrile, methyl acrylate and methyl vinyl ketone as the activated alkenes. These reactions have typically (but not always!) afforded both normal Baylis-Hillman and dimeric products. Attention has also been given to the use of 1-methyl-2-pyrrolidine (1-NMP), an ionic liquid, to replace normal organic solvents, and it has been found that, in the presence of DABCO, chromone-3-carbaldehydes afford the dimeric products alone. Reactions of chromone-3-carbaldehydes with methyl vinyl ketone have yielded unexpected, novel adducts, which appear to arise from preferential attack at C(2) in the chromone nucleus. Research on chromone-2-carbaldeydes under Baylis-Hillman conditions has also resulted in the formation of some interesting products instead of the expected Baylis-Hillman adducts. The Baylis-Hillman products have been explored as substrates for aza-Michael reactions using various amino derivatives including protected amino acids in the presence of the tetrabutylammonium bromide (TBAB) and the ionic liquid, 3-butyl-1- methylimidazoleboranetetrafluoride (BmimBF₄), as catalysts. The aza-Michael products have been targeted as truncated ritonavir analogues for investigation as potential HIV -1 protease inhibitors, and representative compounds have been subjected to enzyme inhibition assays to explore the extent and type of inhibition. Lineweaver-Burk and Dixon plots have indicated competitive inhibition in one case as well as non-competitive inhibition in another, and the inhibition constants (Ki) have been compared with that of the ritonavir. Computer modelling studies have also been conducted on selected chromonecontaining derivatives, using the ACCELRYS Cerius² platform. Interactive docking of the chromone-containing ligands into the HIV -1 protease receptor site, using the Ligandfit module, has indicated the importance of hydrogen-bonding interactions mediated by bridging water molecules situated in the receptor cavity. NMR spectroscopy has been used to elucidate complex and competing mechanistic pathways involved in the Baylis-Hillman reactions of selected 2-nitrobenzaldehydes with MVK in the presence of DABCO - reactions which afford the normal BaylisHillman product, the MVK dimer and syn- and anti-Baylis-Hillman type diadducts. The kinetic data confirm the concomitant operation of two pathways and reveal that, in the initial stage of the reaction, the product distribution is kinetically controlled, whereas in the latter stage, thermodynamic control results in the consumption of the normal Baylis-Hillman product and predominance of the anti-diadduct.
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