Green skills supply: Research from providers’ vantage point(s)
- Authors: Lotz-Sisitka, Heila
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/392895 , vital:68810 , ISBN 9780429279362 , https://doi.org/10.4324/9780429279362
- Description: This chapter emerges from a need to consider the dynamics of supply side research for green skills from a providers’ vantage point. The chapter starts with the argument that environment and sustainability skills are cross institutional, cross sectoral and also inter- and transdisciplinary. The chapter notes that there are a wide variety and diversity of supply side studies that can offer perspective on the many dynamics of green skills supply and provisioning. Four cases have been selected and brought into view to illuminate the influence of context and history on designing curricula and the importance of reflexive curriculum review studies, whole institution approaches and transformative, transgressive forms of learning that move beyond the boundaries of single institutions. These studies are also brought into view to indicate the scope and depth of contextual, systemic and engaged research that is required to develop transformative orientations and perspectives on green skills supply, taking skills system supply beyond the traditional training needs analysis. The chapter argues that this is an important dimension of green skills research, if conceptualised within just transitions and transformations to sustainability.
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Green synthesis of zinc oxide nanoparticles using Solanum torvum (L) leaf extract and evaluation of the toxicological profile of the ZnO nanoparticles–hydrogel composite in Wistar albino rats
- Authors: Ezealisiji, Kenneth E , Siwe-Noundou, Xavier , Maduelosi, Blessing , Nwachukwu, Nkemakolam , Krause, Rui W M
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/194015 , vital:45416 , xlink:href="https://doi.org/10.1007/s40089-018-0263-1"
- Description: Current study reports a simple and one-pot synthesis of zinc oxide nanoparticles (ZnONPs) using an aqueous extract of Solanum torvum and evaluation of its toxicological profile (0.5% w/w and 1.0% w/w) in Wistar albino rats with respect to the biochemical index. The nanoparticles were characterized using ultraviolet–visible spectroscopy, transmission electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction technique. Dynamic light scattering (DLS) and zeta potential of synthesized nanoparticles were analyzed to know the average size and stability of particles. Synthesized nanoparticles were stable, discreet, and mostly spherical, and size of particles was within the nanometre range. Biochemical markers of hepatic and renal functions were measured. Zinc oxide nanoparticles significantly decreased serum uric acid level (p less than 0.001) in a dose-dependent manner, while the serum alkaline phosphatase level was increased at the two test doses. The level of alanine transaminase was increased after exposure for 28 days (p less than 0.05). This study concludes that biogenic zinc oxide nanoparticles-infused hydrogel applied dermatologically could affect hepatic and renal performance in rats, and there was an observed cumulative toxicological effect with time of exposure.
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How to engage with challenges facing Water and Sanitation Services (WSS) in small municipalities
- Authors: Clifford-Holmes, Jai K , Carnohan, Shane , Slinger, Jill W , Palmer, Carolyn G
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437869 , vital:73418 , ISBN 978-1 4312-0988-0 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/SP 120-18 web.pdf
- Description: Smaller South African municipalities have many urgent calls on their resources AT THE SAME TIME. • The need to pay salaries is sometimes more important than other concerns. • It is not always clear how different problems affect each other. • It is difficult to decide what to do each day. • There are always urgent crises to attend to. • There are many meetings to attend. • Operational and political priorities can be different. Thinking of, and talking about your municipality as a SYSTEM will help you to ACT in ways that reduce the impact of these issues. This handbook relates specifically to water and sanitation issues.
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How to engage with coal mines through Catchment Management Forums
- Authors: Munnik, Victor , Holleman, Helen , Wolff, Margaret G , Palmer, Carolyn G
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437882 , vital:73419 , ISBN 978-1 4312-0990-3 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/SP 122-18 web.pdf
- Description: This book was written for the catchment management forum (CMF) in the Upper Komati Forum (UKF), and they share their experience in order to help other CMFs understand the damage coal mining does to our water resources. This booklet should be used with How to think and act in ways that make Adaptive IWRM practically possible and How to establish and run a Catchment Management Forum.
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How to manage water quantity and water quality together
- Authors: Retief, Hugo , Holleman, Helen , Palmer, Carolyn G
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437907 , vital:73421 , ISBN 978-1 4312-0987-3 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/SP%20119-18%20web.pdf
- Description: All over the world water resources are under pressure due to over-use and pollution, and finding ways to meet the need for water is becoming increasingly difficult. Nat-ural variation in rainfall also contributes to making planning and management of flow and water quality, and especially these together, complex and difficult. People have realised that it is important to consider many factors when managing water – they call this Integrated Water Resource Management (IWRM). Integrating many factors is in line with the ideas that all the “How to” handbooks are based on. Please do read the foundation handbook: “How to think and act in ways that make Adap-tive IWRM practically possible”. In this handbook we consider how to integrate flow and water quality. Although some writers think taking account of all the many fac-tors is too difficult, others – including the authors of this handbook – believe it is essential to try if we want to find the balance between use and protection. IWRM also recognises that it is vital to involve stakeholders in decision-making if protec-tion of our water resources is going to be successful.
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How to think and act in ways that make Adaptive IWRM practically possible
- Authors: Palmer, Carolyn G , Biggs, Harry , Rogers, Kevin , du Toit, Derick , Pollard, Sharon
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437937 , vital:73423 , ISBN 978-1 4312-0984-2 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/SP%20116-18%20web.pdf
- Description: “We cross the river by feeling the stones with our feet” (Chinese proverb). Most of the ideas in this handbook you already know from living your life. Here we put your everyday experience and knowledge into the language of managing water. In the last twenty years, there has been a lot of talk about new ways to make Integrated Water Resource Management or “IWRM” work, but not nearly as much useful knowledge about how to put those ideas into practice. We now know how to use a set of ideas and ways of understanding that help us to make IWRM really work prac-tically. We call this practical way of working: Adaptive IWRM. This is the first in a series of handbooks to come out of a WRC project Practising Adaptive IWRM (Inte-grated Water Resource Management (IWRM) in South Africa: towards practising a new paradigm* [TPNP]). The TPNP project researchers have had experience with many different situations in southern Africa, where people have grappled* with put-ting the ideas of complexity* and integration into practice.
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How to use Strategic Adaptive Management (SAM) and the Adaptive Planning Process (APP) to build a shared catchment future
- Authors: Palmer, Carolyn G , Rogers, Kevin , Holleman, Helen , Wolff, Margaret G
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437965 , vital:73425 , ISBN 978-1 4312-0991-0 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/SP 123-18 web.pdf
- Description: For members of Catchment Management Forums (CMFs) and Catchment Manage-ment Agencies (CMAs). CMFs are made up of people who represent all the stake-holders in a catchment. They are the people who know the catchment best, and therefore are in the best position to alert CMAs to local issues and to help develop the strategic plans for their local catchment. However, catchments are dynamic*, complex* systems that need a special planning approach – and that is what this handbook is about. If one part of a catchment is neglected and damaged, it affects the whole system and everyone living in it. We use and recommend a flexible, adap-tive approach in which everyone involved in the planning is both a teacher and a learner, and where everyone contributes their special wisdom to developing a sustainable plan for the catchment.
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In vitro antimalarial, antitrypanosomal and HIV-1 integrase inhibitory activities of two Cameroonian medicinal plants
- Authors: Fouokeng, Yannick , Feumo Feusso, H M , Mbosso Teinkela, Jean E , Siwe-Noundou, Xavier , Wintjens, René T , Isaacs, Michelle , Hoppe, Heinrich , Krause, Rui W M , Azébazé, Anatole G B , Vardamides, Juliette C
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/195014 , vital:45519 , xlink:href="https://doi.org/10.1016/j.sajb.2018.10.008"
- Description: Antiplasmodial, antitrypanosomal and anti-HIV-1 activities of crude extracts, fractions and some isolated compounds from two Cameroonian medicinal plants: Antrocaryon klaineanum Pierre (Anacardiaceae) and Diospyros conocarpa Gürke ex K. Schum. (Ebenaceae) were assessed. The phytochemical studies led to the isolation of eight compounds (1–8) from Diospyros conocarpa and six compounds (6, 9–13) from Antrocaryon klaineanum. These compounds were identified as mangiferolic acid (1), 3β, 22(S)-dihydroxycycloart-24E-en-26-oic acid (2), lupeol (3), aridanin (4), betulin (5), betulinic acid (6), bergenin (7), D-quercitol(8), entilin C(9), entilin A(10), antrocarine A(11), 7R,20(S)-dihydroxy-4,24(28)-ergostadien-3-one(12) and stigmasterol glucoside (13). The criteria for activity were set as follows: an IC50 value more than 10 μg/mL for crude extracts and more than 1 μg/mL for pure compounds. The hexane/ethyl acetate (1:1) fraction of A.klaineanum root bark (AKERF1) and the hexane/ethyl acetate (1:1) fraction of A.klaineanum trunk bark (AKETF1) presented the strongest antiplasmodial activities with IC50 values of 0.4 and 4.4 μg/mL, respectively. Aridanin (4) and antrocarine A(11), as well as the crude extract of D.conocarpa roots (EDCR), AKERF1 and AKETF1 showed moderate trypanocidal effects. The crude extract of A.klaineanum root bark (AKER) and AKETF1 exhibited attractive activities on HIV-1 integrase with IC50 values of 1.96 and 24.04 μg/mL, respectively. The results provide baseline information on the use of A.klaineanum and D.conocarpa extracts, as well as certain components, as sources of new antiplasmodial, antitrypanosomal and anti-HIV drugs.
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Inhibition of aluminium corrosion using benzothiazole and its phthalocyanine derivative
- Authors: Nnaji, Nnaemeka , Nwaji, Njemuwa , Fomo, Gertrude , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186949 , vital:44550 , xlink:href="https://doi.org/10.1007/s12678-019-00538-1"
- Description: Cyclic voltammetry and potentiodynamic polarization techniques were used to study the effects of 4-[4-(1,3-benzothiazol2yl)phenoxy] phthalonitrile (BT) and tetrakis[(benzo[d]thiazol-2ylphenoxy) phthalocyaninato] gallium(III)chloride (ClGaBTPc) as aluminium corrosion inhibitors in 1.0 M hydrochloric acid. The presence of the inhibitors in the concentration range of 2 to 10 μM was found to retard the aluminium corrosion process such that the inhibition efficiency was found to range from 28.2 to 76.1% for BT and from 71.5 to 82.7% for ClGaBTPc. The latter was a better inhibitor. Scanning electron microscopy and energy-dispersive X-ray measurements reveal effective metal surface protection by the inhibitors, most probably by shielding it from the corrosion attacks of Cl− from the acid. The calculated quantum chemical parameters agreed with experimental results.
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Interactions between two biological control agents and their target weed: a beetle, a bug and a cactus weed
- Authors: Mnqeta, Zezethu , Paterson, Iain D
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417475 , vital:71456 , xlink:href="https://doi.org/10.1080/09583157.2019.1631960"
- Description: Pereskia aculeata Miller (Cactaceae) is an invasive alien shrub introduced into South Africa from Brazil. The leaf-feeding beetle, Phenrica guerini Bechyne (Chrysomelidae), was released as a biological control agent in South Africa in 1991 followed by the stem-wilting bug, Catorhintha schaffneri Brailovsky and Garcia (Coreidae), in 2014. This study investigated the interactions between the two agents under laboratory conditions. Potted plants were exposed to one of four treatments: control (no agents), P. guerini only, C. schaffneri only and both species together. Four densities, ranging from 2 to 12 insects per plant were used. Cathorhitha schaffneri alone at low to moderate densities resulted in the same reduction in number of leaves and shoot length as when combine with P. guerini. At the highest density, C. schaffneri reduced the number of leaves significantly more than any treatment. Mortality of P. guerini was significantly higher than C. schaffneri at the highest density when in combination. The antagonistic interaction between P. guerini and C. schaffneri suggests that these agents should not be released together because this would impact negatively on the overall biocontrol programme against P. aculeata. It is recommended that C. schaffneri should be released at sites where P. guerini is not present. Extrapolation of laboratory-based studies into the field is often challenging, so mass-rearing and releases of P. guerini should continue until there is convincing proof that C. schaffneri alone is more effective than P. guerini in the field.
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Investigation of novel substituted zinc and aluminium phthalocyanines for photodynamic therapy of epithelial breast cancer
- Authors: Mohammed, Imadalulla , Oluwole, David O , Nemakal, Majunatha , Sannegowda, Lokesh K , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186824 , vital:44537 , xlink:href="https://doi.org/10.1016/j.dyepig.2019.107592"
- Description: A series of phthalonitrile ligands were synthesized by nucleophilic substitution reaction using the hydroxyl or sulfanyl group precursors and the nitro moiety of the nitrophthalonitrile to yield corresponding oxy or sulfanyl bridged ligands. These ligands were subsequently subjected to cyclocondensation reaction with diamagnetic metal ions like zinc and aluminium to afford symmetrically substituted zinc and aluminium phthalocyanine (Pc) complexes and polymers. The ligands and Pc complexes were characterized by 1 H nuclear magnetic resonance, fourier transform infrared, ultraviolet visible and mass spectrometric techniques. Additionally, thermal gravimetric, and elemental analyzer were used for characterization of the Pc complexes. The photophysical and photochemical behaviour of the Pc complexes were investigated in dimethyl sulfoxide. Additionally, the complexes were tested against epithelial breast cancer cells for photodynamic therapy (PDT) effect. The substituted ZnPc complexes afforded higher singlet oxygen quantum yields as compared to the AlPc analogue. All the complexes showed innocuous invitro dark cytotoxicity and moderate PDT effect.
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Landscape, memory and learning to change in changing worlds: Contemplating intergenerational learning and traditional knowledge practices within social-ecological landscapes of change
- Authors: O'Donoghue, Rob B , Sandoval-Rivera, Juan Carlos , Payyappallimana, Unnikrishnan
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/388061 , vital:68304 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/187218"
- Description: The core paper and collection of short papers from Mexico, Africa, India and Sweden that make up this study on social-ecological landscapes developed as a South–South collaboration that was extended to include a case in the North. Our concern was to explore how situated, intergenerational knowledge commonly takes a back seat to the conceptual propositions that the environmental sciences have developed around matters of concern like biodiversity loss. In this way, scientific propositions have become the conceptual capital for informing future sustainability through Education for Sustainable Development (ESD). In response to this, a more situated turn has developed to engage both intergenerational practices and the institutional sciences, but the playing fields are seldom level and deliberations are often rife with misunderstandings.
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Listening to the Stories
- Authors: Pullanikkatil, Deepa , Shackleton, Charlie M
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/433565 , vital:72984 , ISBN 978-3-319-75580-9 , https://link.springer.com/chapter/10.1007/978-3-319-75580-9_25
- Description: This book has sought to contribute to the policy and academic debates regarding the opportunities and usefulness of the NTFP sector in reducing poverty. We have argued in the opening chapters that it is unlikely that NTFP use and trade will provide a pathway out of poverty for the millions of poor in the Global South. However, it is unlikely that any other one sector or intervention will. Consequently, the value of the NTFP sector and its role in poverty reduction for some needs to be added to the suite of strategies that governments, development agencies and NGOs consider when seeking to address poverty in the areas in which they operate.
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Livelihood benefits and costs from an invasive alien tree (Acacia dealbata) to rural communities in the Eastern Cape, South Africa
- Authors: Ngorima, A , Shackleton, Charlie M
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/179755 , vital:43168 , xlink:href="https://doi.org/10.1016/j.jenvman.2018.05.077"
- Description: The negative effects of invasive alien species (IAS) are increasingly invoked to justify widespread and usually top-down approaches for their management or eradication. However, very little of the research or discourse is based on investigating local perceptions, uses and struggles with IAS, and how their presence influences and changes local livelihoods. The objective of this study was to assess the perceptions and livelihood uses of Acacia dealbata by local communities at three localities in the montane grasslands of the Eastern Cape, South Africa, using a combination of random household interviews, focus group discussions and participatory tools. We calculated direct-use values for each product and household (based on quantity used and local prices) and disaggregated these by gender of the household head and wealth quartiles. The results revealed the dualistic role of A. dealbata in local livelihoods. On the one hand, A. dealbata was widely used for firewood (100% of households), tools (77%) and construction timber (73%), with limited use for traditional medicines and forage. The cumulative value of approximately ZAR 2870 (±US$224) per household per year (across all households) represents considerable cash saving to households, most of whom are quite poor by national and international measures. On the other hand, the increasing extent of A. dealbata (93% said it was increasing) exacerbates local household vulnerability though reported reductions in cultivated areas, crop yields and forage production, and allegedly higher risks of crime. This quandary is well encapsulated by the considerable majority of respondents (84%) not wanting higher extents and densities of A. dealbata, but an equally high majority not wanting its total removal from local landscapes. Most respondents disliked A. dealbata in fields, close to homesteads or along primary access routes, and were more tolerant of it away from such sites. Institutional and use dynamics have varied over several decades in response to the changing extent and densities of A. dealbata and the broader political and socio-economic contexts. These results indicate that greater efforts are required to understand perceptions and uses of IAS by the people who live with them, and to direct such understanding into more spatially and temporally contextualised response strategies where required.
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Magnetic nanoparticle-indium phthalocyanine conjugate embedded in electrospun fiber for photodynamic antimicrobial chemotherapy and photodegradation of methyl red
- Authors: Sindelo, Azole , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186857 , vital:44540 , xlink:href="https://doi.org/10.1016/j.heliyon.2019.e02352"
- Description: ClIn(III) octacarboxy phthalocyanine (ClInOCPc) when alone or conjugated to magnetic nanoparticles (MNPClInOCPc) was employed for both photodynamic antimicrobial chemotherapy of an unknown water sample and Staphylococcus aureus, and for photo-degradation of methyl red (MR). The singlet oxygen quantum yields (ΦΔ) in water using ClInOCPc and MNP-ClInOCPc embedded in polyacrylonitrile (PAN) electrospun fibers were 0.36 and 0.22, respectively. When in solution, MNP-ClInOCPc gave 90.6% photoinactivation of microbes in a water sample from the stream and of ClInOCPc resulted in 84.8 % photoinactivation. When embedded to the polymer, there was 48.0% clearance for ClInOCPc and 63.7% clearance for MNP-ClInOCPc for the microbes in the water sample from the stream. For the photo-degradation of MR, the rate of degradation increased with decrease of the MR concentration with the MNP-ClInOCPc having the fastest rate.
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Mainstreaming education for sustainable development: Elaborating the role of position-practice systems using seven laminations of scale
- Authors: Agbedahin, Adesuwa V , Lotz-Sisitka, Heila
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182428 , vital:43829 , xlink:href="https://doi.org/10.1080/14767430.2019.1602975"
- Description: The United Nations Sustainable Development Goal 4.7 proposes that Education for Sustainable Development (ESD) should be included at all levels of education, known as ‘mainstreaming’. However, there is little guidance as to how to achieve this. ESD mainstreaming demands more than simply a technical policy transfer; it also requires attention to the position-practice systems of involved agents. This article critically assesses the mainstreaming of ESD in the case of university educators in Africa who have participated in the International Training Programme on ESD in higher education. It clarifies their position-practice systems in terms of Bhaskar’s seven laminations of scale. This article therefore provides a detailed description of the ways in which agents' position-practice systems enable and constrain ESD mainstreaming. It also demonstrates that a critical realist perspective can contribute towards the understanding and achievement of transformation towards sustainability and can help to ensure the flourishing of both current and future generations.
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Making (non) sense of urban water flows: Qualities and processes for transformative and transgressive learning moments
- Authors: James, Anna
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/390665 , vital:68572 , xlink:href="https://doi.org/10.3390/su11236817"
- Description: Urban sustainability and justice depend upon the flow of water across complex urban space. Yet, the characteristics of urban space produce a fragmented sense of our water resources. Cape Town, South Africa, the context of this research, is one such city whose water challenges have been exacerbated by climate change-induced drought, to the extent that the city nearly shut off the water running to residents’ taps. This context presents a particular challenge for the focus of this special issue, transformative and transgressive learning, an emerging arena of thought and practice concerned with learning processes that might foster more sustainable socio-ecological relations. The empirical material for this research draws from 12 arts-based inquiry workshops run with youth in an environmental organisation over four months, exploring a local water crisis. The data were generated through an engaged arts-based research process. The paper traces how transformative and transgressive learning in the context of urban water crisis might be characterised as making (non)sense by bringing the empirical material into dialogue with five entry points of transformative and transgressive learning literature rooted in Freirean educational praxis. This paper crafts and engages the concept of making (non)sense, a way of thinking about qualities and processes of learning praxis that responds to the wicked sustainability challenges we face today, particularly in terms of a Global South perspective. I argue such a praxis needs qualities and processes that disrupt and trouble the norm in the context of the socio-ecological challenge of urban water.
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Mating preferences of two species of Eccritotarsus (Hemiptera: Miridae)
- Authors: Mnuguni, Sandiso
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417486 , vital:71457 , xlink:href="https://hdl.handle.net/10520/ejc-cristal-v10-n1-a7"
- Description: Eccritotarsus spp. are biological control agents that have been sourced from Brazil and Peru to control water hyacinth in South Africa. These agents have been released in over 30 sites and were thought to be the same species. The sequencing of mitochondrial DNA and interbreeding experiments have since confirmed the cryptic species to be separate species. The Brazilian population remains E. catarinensis while the Peruvian population is now E. eichhorniae. This paper assessed the mating behaviour of both species, to investigate behavioural traits that have resulted in reproductive isolation, which could have led to speciation. Mating choices in a form of no-choice, bi-choice and multi-choice tests were conducted within and between species in a 3:1, 2:1 and 1:1 sex ratio. The E. eichhorniae pair had more single and multiple copula incidences, higher average total copula duration and higher copula latency while the E.catarinensis♀×E.eichhorniae♂ pair had less single and multiple copula incidences, lower average total copula duration and lower copula latency. When the E.eichhorniae♀ and E.catarinensis♂ were given their respective choices, they only mated with conspecifics. However, when E.eichhorniae♀ are crossed with E.catarinensis♂ they do not produce offspring. These results suggest that interbreeding will be limited in South Africa.
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Measuring and modelling evapotranspiration in a South African grassland: Comparison of two improved Penman-Monteith formulations
- Authors: Gwate, Onalenna , Mantel, Sukhmani K , Palmer, Anthony R , Gibson, Lesley A , Munch, Zahn
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/438167 , vital:73440 , ISBN 1816-7950 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/44_03_16_3530.pdf
- Description: Accurately measuring evapotranspiration (ET) is important in the con-text of global atmospheric changes and for use with climate models. Direct ET measurement is costly to apply widely and local calibration and validation of ET models developed elsewhere improves confidence in ET derived from such models. is study sought to compare the per-formance of the Penman-Monteith-Leuning (PML) and Penman-Monteith-Palmer (PMP) ET models, over mesic grasslands in two study sites in South Africa. The study used routine meteorological data from a scientific-grade automatic weather station (AWS) to apply the PML and PMP models. The PML model was calibrated at one site and validated in both sites. On the other hand, the PMP model does not require cali-bration and hence it was validated in both sites.
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Methodological Survey of Simplified TD-DFT Methods for Fast and Accurate Interpretation of UV−Vis−NIR Spectra of Phthalocyanines
- Authors: Martynov, Alexander G , Mack, John , May, Aviwe K , Nyokong, Tebello , Gorbunova, Yulia G , Tsivadze, Aslan Yu
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186915 , vital:44547 , xlink:href="https://doi.org/10.1021/acsomega.8b03500"
- Description: A methodological survey of density functional theory (DFT) methods for the prediction of UV−visible (vis)−near-infrared (NIR) spectra of phthalocyanines is reported. Four methods, namely, full time-dependent (TD)-DFT and its Tamm−Dancoff approximation (TDA), together with their simplified modifications (sTD-DFT and sTDA, respectively), were tested by using the examples of unsubstituted and alkoxy-substituted metal-free ligands and zinc complexes. The theoretical results were compared with experimental data derived from UV−visible absorption and magnetic circular dichroism spectroscopy. Seven popular exchange-correlation functionals (BP86, B3LYP, TPSSh, M06, CAM-B3LYP, LC-BLYP, and ωB97X) were tested within these four approaches starting at a relatively modest level using 6-31G(d) basis sets and gas-phase BP86/def2-SVP optimized geometries. A gradual augmentation of the computational levels was used to identify the influence of starting geometry, solvation effects, and basis sets on the results of TD-DFT and sTD-DFT calculations. It was found that although these factors do influence the predicted energies of the vertical excitations, they do not affect the trends predicted in the spectral properties across series of structurally related substituted free bases and metallophthalocyanines. The best accuracy for the gas-phase vertical excitations was observed in the lower-energy Q-band region for calculations that made use of range-separated hybrids for both full and simplified TD-DFT approaches. The CAMB3LYP functional provided particularly accurate results in the context of the sTD-DFT approach. The description of the higherenergy B-band region is considerably less accurate, and this demonstrates the need for further advances in the accuracy of theoretical calculations. Together with a general increase in accuracy, the application of simplified TD-DFT methods affords a 2−3 orders of magnitude speedup of the calculations in comparison to the full TD-DFT approach. It is anticipated that this approach will be widely used on desktop computers during the interpretation of UV−vis−NIR spectra of phthalocyanines and related macrocycles in the years ahead.
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