Redox reactions of an Mo (V) tetrasulfophthalocyanine
- Authors: Ferraudi, Guillermo , Nyokong, Tebello , Feliz, Mario , Perkovic, Marc , Rillema, D Paul
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295530 , vital:57351 , xlink:href="https://doi.org/10.1016/0020-1693(93)03664-V"
- Description: The preparation of an Mo(V) tetrasulfophthalocyanine and some of its thermal and photochemical reactions have been investigated in this work. Electrochemical processes have been followed by means of the UVVis spectral changes and compared with those observed in flash photolysis. Mo(IV) and Mo(V)-ligand-radical species are common intermediates of the electrochemical and photochemical reactions. In 254 nm irradiations of the Mo(V) tetrasulfophthalocyanine in aqueous solutions of 2-propanol, the macrocycle can be photohydrogenated and the product of the photolysis can be reoxidized with O2 back to the parent complex.
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Research priorities for environmental education in southern Africa: Preliminary report
- Authors: Janse van Rensburg, Eureta
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438781 , vital:73499 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137480"
- Description: In this preliminary research report I introduce initial interpretations of the results of a recently completed study on research priorities in southern Africa. The study has been sponsored by Murray and Roberts, Rhodes University and the HNRE (Human and Natural Resources in the Environment) Programme of the Human Sciences Research Council.
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A comparison of four microcomputer operating systems
- Authors: Wells, George C
- Date: 1993
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430422 , vital:72690 , https://doi.org/10.1007/BF01088835
- Description: This article describes a comparative study of four operating systems for IBM-PC compatible microcomputers. The assessment concentrated on the suitability of the operating systems for use in real-time applications, and on their use as development environments for real-time systems. The study evaluated the predictability and the performance of the operating systems in several areas critical in real-time systems by using comparative benchmarks. In addition, a small-scale simulation of a process control system was developed for each of the systems. The operating systems that were studied were UNIX, OS/2, QNX and FlexOS. These operating systems represent a broad spectrum of systems from general purpose operating systems to small, specialized real-time operating systems. The details of the evaluation process are given and a summary of the results is presented.
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Interaction of cyanide with iron (II) phthalocyanine
- Authors: Nyokong, Tebello
- Date: 1993
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295497 , vital:57347 , xlink:href="https://doi.org/10.1039/DT9930003601"
- Description: The kinetics and equilibria for the reaction between cyanide and iron (II) phthalocyanine [Fe(pc)](H2pc = phthalocyanine) in dimethyl sulfoxide (dmso) were studied at 25 °C. The complex [Fe(pc)(CN)2]2– is formed in two consecutive pseudo-first-order processes with k2f= 17.5 ± 0.8 dm3 mol–1 s–1 and k3f= 0.20 ± 0.05 dm3 mol–1 s–1, where k2f and k3f are the rate constants for the binding of the first and second cyanide ligands, respectively. The equilbrium constants were fund to be K2= 3.0 × 103 dm3 mol–1 and K3= 5.7 × 102 dm3 mol–1, for the formation of [Fe(pc)(CN)(dmso)]– and [Fe(pc)(CN)2]2–, respectively.
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Kinetics of the reaction of cyanide with ruthenium phthalocyanine complexes
- Authors: Nyokong, Tebello , Guthrie-Strachan, Jeffry
- Date: 1993
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295509 , vital:57348 , xlink:href="https://doi.org/10.1016/S0020-1693(00)85128-2"
- Description: Kinetic studies of the reaction of cyanide with (CO)(DMF)RuPc and (DMSO)2RuPc in DMF are reported. In the presence of a large excess of cyanide, the (CN)2RuPc complex is formed by pseudo first order kinetics. The reaction is first order in both cyanide and phthalocyanine, with specific rate constants of 5.2×10−2 and 7.2×10−2 M−1 s−1 for reactions of cyanide with (CO)(DMF)RuPc and (DMSO)2RuPc, respectively. The rate constants correspond to the coordination of the second cyanide ligand to the ruthenium phthalocyanine species.
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The nature of the oxidation products of dicyanoruthenium phthalocyanine in aqueous and non-aqueous solvents
- Authors: Nyokong, Tebello
- Date: 1993
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295543 , vital:57352 , xlink:href="https://doi.org/10.1016/S0277-5387(00)81741-6"
- Description: The cyclic voltammetry of [(CN)2RuIIPc]2− in acetonitrile or dichloromethane shows two oxidation couples at E12 = 0.31 and 0.85 V (vs S.C.E.) in CH2Cl2 and E12 = 0.45 and 1.15 V (vs S.C.E.) in acetonitrile. The spectroelectrochemistry of [(CN)2RuIIPc]2− in these solvents showed that oxidations occur at the phthalocyanine ligand. K2[(CN)2RuIIPc] dissolves in water at pHs greater than 5. The cyclic voltammetry of this complex showed oxidation couples at 0.32 and 0.29 V (vs S.C.E.) for aqueous solutions containing sodium sulphate (0.1M) and for buffered solutions (pH = 9), respectively. Both cyclic voltammetry and controlled potential coulometry gave evidence of electrocrystallization of the oxidation product. Chemical oxidations of [(CN)2RuIIPc]2− in water also showed phthalocyanine ligand oxidation.
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An approach to the evaluation of microcomputer operating systems with respect to real-time issues
- Authors: Wells, George C
- Date: 1991
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430484 , vital:72694 , https://doi.org/10.1016/0165-6074(91)90014-K
- Description: This paper gives an overview of the approach used for the assessment of several operating systems for microcomputers. The operating systems are all commercial products and cover a spectrum ranging from general purpose operating systems to small, real-time operating systems. The criteria used for the evaluation are discussed and the approach used is discussed in detail. The results of the evaluation are not discussed in this paper.
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The application of real-time design techniques to simulation
- Authors: Wells, George C
- Date: 1989
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430541 , vital:72698 , 10.1049/sej.1989.0040
- Description: The paper discusses the application of the Ward and Mellor structured development techniques for real-time systems to the field of simulation. The tools and heuristics used by Ward and Mellor are extended to provide a useful approach to the design of real-time simulations. This is illustrated by the example of a real-time simulation of a manufacturing plant and process control system.
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