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3000 miles from home: a new Gastrosericus baobabicus Pulawski, 1995 (Hymenoptera, Larridae) distribution record highlights that the Sahel has a distinct entomofaunal signature

  • Authors: Clitheroe, C-L , Villet, Martin H
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6846 , http://hdl.handle.net/10962/d1011099
  • Description: [from introduction] On October 30, 1953, an unidentified female wasp (Fig. 1) was collected from ‘Belet Uen, Somaliland’ (= Beledweyne, 4°44’N 45°12’E), situated in the valley of the Shebelle River, HiraanProvince,Somalia. It was deposited in the aculeate Hymenoptera collection of the Albany Museum, Grahamstown by D. Greathead prior to 1968. Apart from the words ‘Somaliland’ and ‘Desert Locust Survey’ the label is handwritten and the collector’snameis not recorded. Greathead’s sister, S. Gess (Albany Museum), deciphered the label and stated that he had worked for the Desert Locust Survey, investigating the natural enemies of locusts and had been in Somalia (then Somaliland) at that time (Murphy & Cock 2007). The specimen was sent in 2004 by F. Gess to W. Pulawski, who determined it as Gastrosericus baobabicus Pulawski, 1995. Gastrosericus species prey on spiders and a variety of small insects (Pulawski 1995), including Orthoptera (Krombein & Pulawski 1986), so it is likely that Greathead collected the specimen in connection with his interest in the insect enemies of Acridoidea (Orthoptera) (Greathead 1962).
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  • Date Issued: 2011

Above ground woody community attributes, biomass and carbon stocks along a rainfall gradient in the savannas of the central lowveld, South Africa

  • Authors: Shackleton, Charlie M , Scholes, Robert J
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6658 , http://hdl.handle.net/10962/d1007079
  • Description: Enumeration of carbon stocks at benchmark sites is a necessary activity in assessing the potential carbon sequestration and possible generation of credits through restoration of intensively impacted sites. However, there is a lack of empirical studies throughout much of the savannas of sub-Saharan Africa, including South Africa. We report an estimation of species specific and site biomass and carbon stocks, and general vegetation structural attributes from three protected areas along a rainfall gradient in the central lowveld, South Africa. Estimates of biomass and carbon stocks were effected through destructive sampling to establish locally derived allometric equations. There was a gradient of increasing woody density, height of the canopy, number of species, density of regenerative stems and a greater proportion of stems in small size classes from the arid locality to the mesic locality, with the semi-arid locality being intermediate. The proportion of spinescent species decreased with increasing rainfall. The mesic locality was significantly more woody than either the arid or semi-arid sites, having double the biomass, four times the density and 40% higher basal area. Above ground carbon pools were also higher; carbon stocks were approximately 9 t/ha for the arid and semi-arid sites and 18 t/ha for the mesic site.
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  • Date Issued: 2011

Culture as a discursive resource opposing legal abortion

  • Authors: Macleod, Catriona I , Sigcau, Nomakhosi , Luwaca, Pumeza
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6293 , http://hdl.handle.net/10962/d1014721 , http://dx.doi.org/10.1080/09581596.2010.492211
  • Description: The notion of ‘culture’ features in the abortion literature to explicate, first, contestation of the meaning of abortion (as in the ‘culture wars’ about abortion), second, the normalisation of abortion in certain countries (as in ‘abortion culture’), third, the response of women to abortion within a particular social milieu and fourth, cross-cultural variability in attitudes towards and experiences of abortion. What is missing is an exploration of how ‘culture’ may be deployed as a discursive resource to oppose legal abortion. In this article, we report on a study conducted in a rural area of South Africa. We conducted focus group discussions utilising hypothetical vignettes to stimulate talk. Although, inconsistencies were evident in participants’ talk, in the context of cultural discussions, abortion was constructed as killing and inevitably destructive of cultural values and traditions. Abortion was equated with colonialist interventions and as something that should be opposed in the preservation of culture. Furthermore, cultural opposition to abortion was rooted in fears around the breakdown of gendered and generational power relations. Examples of how culture may be used in everyday interactions to induce shame and negative experiences are also discussed.
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  • Date Issued: 2011

Designer ligands : the search for metal ion selectivity

  • Authors: Kaye, P T
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6576 , http://hdl.handle.net/10962/d1004139
  • Description: The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as biomimetic models of the metalloenzyme, tyrosinase, and for the selective extraction of silver, nickel and platinum group metal ions in the presence of contaminating metal ions. Attention has also been given to the development of efficient, metal-selective molecular imprinted polymers.
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  • Date Issued: 2011

Dimethylglyoxime based ion-imprinted polymer for the determination of Ni(II) ions from aqueous samples

  • Authors: Rammika, M , Darko, G , Tshentu, Z , Sewry, J D , Torto, N
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6590 , http://hdl.handle.net/10962/d1004173
  • Description: A Ni(II)-dimethylglyoxime ion-imprinted polymer {Ni(II)-DMG IIP} was synthesised by the bulk polymerisation method. The morphology of the Ni(II)-DMG IIP and non-imprinted polymer were observed by scanning electron microscopy and the chemical structures were evaluated by infrared spectroscopy. Selectivity of the Ni(II)-DMG IIP was studied by analysing, using an inductively coupled plasma-optical emission spectrometer, for Ni(II) ions that were spiked with varying concentrations of Co(II), Cu(II), Zn(II), Pd(II), Fe(II), Ca(II), Mg(II), Na(I) and K(I) in aqueous samples. The studies revealed Ni(II) recoveries ranging from 93 to 100% in aqueous solutions with minimal interference from competing ions. Enrichment factors ranged from 2 to 18 with a binding capacity of 120 μg∙g−1. Co(II) was the only ion found to slightly interfere with the determination of Ni(II). Selectivity studies confirmed that the Ni(II)-DMG IIP had very good selectivity, characterised by %RSD of less than 5%. The limits of detection and quantification were 3x10-4 μg∙mℓ−1 and 9x10-4 μg∙mℓ−1, respectively. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3) and the concentration of Ni(II) obtained was in close agreement with the certified one. The Ni(II)-DMG IIP was successfully employed to trap Ni(II) ions from a matrix of sea, river and sewage water. It is believed that the Ni(II)-DMG IIP has potential to be used as sorbent material for pre-concentration of Ni(II) ions from aqueous solutions by solid-phase extraction.
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  • Date Issued: 2011

Diverse pollination systems of the twin-spurred orchid genus Satyrium in African grasslands

  • Authors: Johnson, S.D , Peter, C.I , Ellis, A.G , Boberg, E , Botes, C , Van der Niet, T
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6558 , http://hdl.handle.net/10962/d1006025 , http://dx.doi.org/10.1007/s00606-010-0411-1
  • Description: The large terrestrial orchid genus Satyrium underwent evolutionary radiations in the Cape floral region and the grasslands of southern and eastern Africa. These radiations were accompanied by tremendous diversification of the unusual twin-spurred flowers that characterize the genus, but pollination data required to interpret these patterns of floral evolution have been lacking for grassland species in the genus. Here we document pollinators, nectar properties, and levels of pollination success for 11 grassland Satyrium species in southern and south-central Africa. Pollinators of these species include bees, beetles, butterflies, hawkmoths, noctuid moths, long-proboscid flies, and sunbirds. Most species appear to be specialized for pollination by one functional pollinator group. Long-proboscid fly pollination systems are reported for the first time in Satyrium (in S. macrophyllum and a high-altitude form of S. neglectum). Floral morphology, especially spur length and rostellum structure, differs markedly among plants with different pollinators, while nectar volume, concentration, and sugar composition are fairly uniform across species. Most taxa exhibited high levels of pollination success (>50% of flowers pollinated), a trend that can be attributed to the presence of nectar in the twin spurs.
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  • Date Issued: 2011

Does the growth of structure affect our dynamical models of the Universe? The averaging, backreaction, and fitting problems in cosmology

  • Authors: Clarkson, C , Ellis, G , Larena, Julien , Umeh, O
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6791 , http://hdl.handle.net/10962/d1006944
  • Description: Structure occurs over a vast range of scales in the Universe. Our large-scale cosmological models are coarse-grained representations of what exists, which have much less structure than there really is. An important problem for cosmology is determining the influence the small-scale structure in the Universe has on its large-scale dynamics and observations. Is there a significant, general relativistic, backreaction effect from averaging over structure? One issue is whether the process of smoothing over structure can contribute to an acceleration term and so alter the apparent value of the cosmological constant. If this is not the case, are there other aspects of concordance cosmology that are affected by backreaction effects? Despite much progress, this 'averaging problem' is still unanswered, but it cannot be ignored in an era of precision cosmology, for instance it may affect aspects of baryon acoustic oscillation observations.
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  • Date Issued: 2011

Elucidation of the complex Baylis-Hillman reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone

  • Authors: Idahosa, Kenudi C , Molefe, Duduzile M , Pakade, Vusumzi E , Brown, Michael E
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6574 , http://hdl.handle.net/10962/d1004137
  • Description: DABCO-catalyzed reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone (MVK) affords a mixture of products, comprising the ‘normal’ Baylis-Hillman adduct, theMVKdimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts. 1HNMRspectroscopy-based kinetic studies have provided clear insights into the competing pathways and product distribution in this complex reaction.
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  • Date Issued: 2011

Energy versus angular momentum in black hole binaries

  • Authors: Damour, T , Nagar, A , Pollney, D , Reisswig, C
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6792 , http://hdl.handle.net/10962/d1006946
  • Description: Using accurate numerical-relativity simulations of (nonspinning) black-hole binaries with mass ratios 1∶1, 2∶1, and 3∶1, we compute the gauge-invariant relation between the (reduced) binding energy E and the (reduced) angular momentum j of the system. We show that the relation E(j) is an accurate diagnostic of the dynamics of a black-hole binary in a highly relativistic regime. By comparing the numerical-relativity ENR(j) curve with the predictions of several analytic approximation schemes, we find that, while the canonically defined, nonresummed post-Newtonian–expanded EPN(j) relation exhibits large and growing deviations from ENR(j), the prediction of the effective one body formalism, based purely on known analytical results (without any calibration to numerical relativity), agrees strikingly well with the numerical-relativity results.
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  • Date Issued: 2011

Evaluating the Wald entropy from two-derivative terms in quadratic actions

  • Authors: Brustein, R , Gorbonos, D , Hadad, M , Medved, A J M
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6816 , http://hdl.handle.net/10962/d1004326
  • Description: We evaluate the Wald Noether charge entropy for a black hole in generalized theories of gravity. Expanding the Lagrangian to second order in gravitational perturbations, we show that contributions to the entropy density originate only from the coefficients of two-derivative terms. The same considerations are extended to include matter fields and to show that arbitrary powers of matter fields and their symmetrized covariant derivatives cannot contribute to the entropy density. We also explain how to use the linearized gravitational field equation rather than quadratic actions to obtain the same results. Several explicit examples are presented that allow us to clarify subtle points in the derivation and application of our method.
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  • Date Issued: 2011

Evaluation of the kinetics and mechanism of drug release from Econazole nitrate nanosponge loaded Carbapol Hydrogel

  • Authors: Sharma, Renuka , Walker, Roderick B , Pathak, Kamla
  • Date: 2011
  • Language: English
  • Type: text , Article
  • Identifier: vital:6437 , http://hdl.handle.net/10962/d1006614
  • Description: The objective of this study was to investigate the mechanism of release of econazole nitrate (EN) nanosponges loaded hydrogel and to compare it with EN hydrogel so as to develop an extended release topical drug delivery system of EN. Nanosponges of EN were prepared using ethyl cellulose and PVA by emulsion solvent evaporation method. On the basis of pharmacotechnical evaluation nanosponges with least particle size of 230.1 nm and good rheological properties were formulated as hydrogel (F1 – F7). In vitro drug release data of EN nanosponges loaded hydrogels in phosphate buffer pH 6.8 and 7.4 when analysed by GraphPad Prism software version 4.0 San Diego, USA best fitted the Makoid-2 Banakar model (R value greater than 0.98). The Korsmeyer-Peppas release exponent (n) ranged between 0.331 – 0.418, which confirmed diffusion as the principle mechanism of drug release. The release mechanism was further confirmed by calculating the ratio of exponents A/B ratio derived from the Kopcha model.
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  • Date Issued: 2011

Good Chemistry

  • Authors: Grange, Helen
  • Date: 2011
  • Subjects: Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
  • Language: English
  • Type: Article , text
  • Identifier: vital:7185 , http://hdl.handle.net/10962/d1006276 , Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
  • Description: Helen Grange profiles four women who've fearlessly taken on the complex predominantly male-dominated field of science.
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  • Date Issued: 2011

Has deregulation of non-timber forest product controls and marketing in Orissa state (India) affected local patterns of use and marketing

  • Authors: Mahapatra, A K , Shackleton, Charlie M
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6643 , http://hdl.handle.net/10962/d1006872
  • Description: State control of marketing agricultural or forestry products may lead to a trade monopoly and restricted competition, resulting in inequitable returns to producers. Consequently, market deregulation for agriculture and other natural products has been advocated to improve market efficiencies, participation and returns for the producers and local traders. The study examines the impact of deregulation of state marketing controls on collection, sale and returns to extractors and traders from non-timber forest products. It assessed whether deregulation policy resulted in greater benefits to primary extractors and a win–win situation for both producers and traders? Mixed effects were found, with no significant changes in terms of trade, demand, or quantum of consumption; but there was an overall increase in the procurement price for several products following deregulation. The collection and farm gate price of tree based oilseeds and honey increased due to lower transaction costs, and ease of trading with a continued demand for these products. The impact on less valuable products was insignificant. Abolition of monopolistic trading increased competition and had a pull effect on the local market prices of several NTFPs. Although traders paid a higher price to procure products, overall they also benefited being able to sell the purchased products to merchants and manufacturers at a better margin than previously.
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  • Date Issued: 2011

I love laser : it's my guiding light

  • Authors: Nolan, Cathy
  • Date: 2011
  • Subjects: Nyokong, Tebello
  • Language: English
  • Type: Article , text
  • Identifier: vital:7184 , http://hdl.handle.net/10962/d1006274 , http://unesdoc.unesco.org/images/0019/001906/190645e.pdf#190680 , Nyokong, Tebello
  • Description: What is the common thread that could possibly link denim jeans, cancer and pesticides? None is evident. Yet when South African chemist Tebello Nyokong describes her fascinating research, the link that emerges is light. Nyokong, a specialist in nanochemistry, loves laser, and is using it in ways that could have a revolutionary impact on medicine and the environment.
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  • Date Issued: 2011

Ilam's Archival Revitalisation: the past five years at the International Library of African Music

  • Authors: Still-Drewett, F
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6983 , http://hdl.handle.net/10962/d1006719
  • Description: The International Library for African Music (ILAM) was begun in 1954 by ethnomusicologist Hugh Tracey (1903–1977). Since 2007, an active set of projects in preservation and digitisation of both sound and photographic archives have meant that this highly important archive of traditional African music has been stabilized and conserved. New outreach education projects are helping distribute the wealth of the collection back to the African people. ILAM now has a more secure future and makes seminal contributions in the fields of research, publication and education for African music. French Abstract La Bibliothèque Internationale pour la Musique Africaine (ILAM) a été établie en 1954 par l’ethnomusicologue Hugh Tracey (1903–1977). Depuis 2007, un ensemble de projets actifs dans la préservation et la numérisation des archives sonores et photographiques, a eu comme résultat que ces archives très importantes de la musique traditionnelle africaine ont été stabilisées et conservées. De nouveaux projets d’éducation et de sensibilisation aident à distribuer la richesse de cette collection à la population africaine. ILAM a maintenant un avenir plus sûr et apporte une contribution fondamentale dans les domaines de la recherche, la publication et l’enseignement de la musique africaine. German Abstract Die International Library for African Music (ILAM) wurde im Jahr 1954 durch den Musi kethnolo - gen Hugh Tracey (1903–1977) gegründet. Seit 2007 laufende Projekte zur Bestandssicherung und Digitalisierung des Schall- und Fotoarchivs helfen, dieses überaus wichtige Archiv für traditionelle afrikanische Musik zu erhalten und in seiner Existenz zu stabilisieren. Neue, nach außen wirkende Bildungsprojekte tragen dazu bei, den Reichtum der Sammlung an die afrikanische Bevölkerung zurückzugeben. Durch seine nun gesicherte Zukunft kann ILAM für die afrikanische Musik grundlegende Beiträge in Forschung, Veröffentlichung und Bildung leisten. Afrikaans Abstract Die International Library of African Music (ILAM) is in 1954 deur die etnomusikoloog, Hugh Tracey (1903–1977), gestig. Aktiewe preserverings- en digitaliseringsprojekte van beide klank- en foto-argiewe sedert 2007, het tot gevolg gehad dat hierdie hoogs belangrike argief van tradisionele Afrikamusiek gestabiliseer en bewaar kon word. Nuwe ontwikkelings-uitreikprojekte dra daartoe by dat die rykdom van hierdie versameling teruggeploeg word aan Afrika. ILAM het tans ‘n meer versekerde toekoms en lewer invloedryke bydraes op die gebied van navorsing, publikasie en opleiding in Afrikamusiek. IsiXhosa Abstract Ithala lehlabathi lomculo wase-Afrika, i- International Library for African Music (ILAM) laqalwa ngo- 1954 yingcali yomculo weentlanga ngeentlanga, uHugh Tracey (1903–1977). Ukususela ngo-2007 umsebenzi wokulondoloza nokugcina ngekhompyutha isandi seengoma kwakunye neefoto uthetha ukuba le mbali ibalulekileyo kumculo we-Afrika wemveli iqiniselwe kwaye igcinwe ngononophelo. Iiprojekti ezintsha zokolulela isandla kwabanye abantu ziyanceda ekusasazeni le ndyebo kwabo bantu isuka kubo, ama-Afrika. Ngoku i-ILAM inekamva elingagunqgiyo kwaye inegalelo elibonakalayo kuphando, upapasho nemfundo ngomculo wase-Afrika.
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  • Date Issued: 2011

Incorporation of Ni(II)-dimethylglyoxime ion-imprinted polymer into electrospun polysulphone nanofibre for the determination of Ni(II) ions from aqueous samples

  • Authors: Rammika, M , Darko, G , Torto, N
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6589 , http://hdl.handle.net/10962/d1004172
  • Description: Ni(II)-dimethylglyoxime ion-imprinted polymer (Ni(II)-DMG IIP) was encapsulated in polysulphone and electrospun into nanofibres with diameters ranging from 406 to 854 nm. The structures of the Ni(II)-DMG encapsulated-IIP nanofibre, non-imprinted encapsulated-polymer nanofibre and polysulphone nanofibre mats were observed by scanning electron microscopy and evaluated by infrared spectroscopy. Electrospinning increased the specific surface area of the Ni(II)-DMG encapsulated-IIP nanofibre mats, as was evidenced by the low masses of the Ni(II)-DMG encapsulated-IIP nanofibre mats used. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3); the concentration of Ni(II) obtained was close to the certified one. The limit of detection was found to be 4.0x10-4 μg∙mℓ−1 while the limit of quantification was found to be 1.2x10-3 μg∙mℓ−1. The recovery of Ni(II) achieved using the Ni(II)-DMG imprinted nanofibre mats in water samples was found to range from 83 to 89%, while that of non-imprinted nanofibre mats was found to range from 59 to 65%, and that of polysulphone from 55 to 62%.
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  • Date Issued: 2011

Late Quaternary environmental phases in the Eastern Cape and adjacent Plettenberg Bay-Knysna region and Little Karoo, South Africa

  • Authors: Lewis, Colin A
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6712 , http://hdl.handle.net/10962/d1006749
  • Description: Four major climato-environmental phases have been identified in the Eastern Cape, Plettenberg Bay-Knysna region and Little Karoo between somewhat before ~ 40 000 cal. a BP and the present: the Birnam Interstadial from before 40 000 cal. a BP until ~ 24 000 cal. a BP; the Bottelnek Stadial (apparently equating with the Last Glacial Maximum) from ~24 000 cal. a BP until before ~ 18 350 cal. a BP; the Aliwal North (apparently equating with the Late Glacial) from before ~ 18 350 cal. a BP until ~ 11 000 cal. a BP; the Dinorben (apparently equating with the Holocene) from ~ 11 000 cal. a BP until the present. The evidence for, and the characteristics of, these phases is briefly described.
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  • Date Issued: 2011

Molecular systematics of the African snake family Lamprophiidae Fitzinger, 1843 (Serpentes: Elapoidea), with particular focus on the genera Lamprophis Fitzinger 1843 and Mehelya Csiki 1903

  • Authors: Kelly, Christopher M R , Branch, William R , Broadley, Donald G , Barker, Nigel P , Villet, Martin H
  • Date: 2011
  • Language: English
  • Type: Article
  • Identifier: vital:6861 , http://hdl.handle.net/10962/d1011151
  • Description: The snake family Lamprophiidae Fitzinger (Serpentes: Elapoidea) is a putatively Late Eocene radiation of nocturnal snakes endemic to the African continent. It incorporates many of the most characteristic and prolific of Africa's non-venomous snake species, including the widespread type genus Lamprophis Fitzinger, 1843 (house snakes). We used approximately 2500 bases of mitochondrial and nuclear DNA sequence data from 28 (41%) of the approximately 68 recognised lamprophiid species in nine of the eleven genera to investigate phylogenetic structure in the family and to inform taxonomy at the generic level. Cytochrome b, ND4 and tRNA gene sequences (mitochondrial) and c-mos sequences (nuclear) were analysed using Maximum Likelihood, Bayesian Inference and Maximum Parsimony methods. The genus Mehelya Csiki, 1903 was paraphyletic with respect to Gonionotophis Boulenger, 1893. To address this, the concept of Gonionotophis is expanded to include all current Mehelya species. The genus Lamprophis emerged polyphyletic: the enigmatic Lamprophis swazicus was sister to Hormonotus modestus from West Africa, and not closely related to its nominal congeners. It is moved to a new monotypic genus (Inyoka gen. nov.). The remaining Lamprophis species occur in three early-diverging lineages. (1) Lamprophis virgatus and the widely distributed Lamprophis fuliginosus species complex (which also includes Lamprophis lineatus and Lamprophis olivaceus) formed a clade for which the generic name Boaedon Duméril, Bibron & Duméril, 1854 is resurrected. (2) The water snakes (Lycodonomorphus) were nested within Lamprophis (sensu lato), sister to Lamprophis inornatus. We transfer this species to the genus Lycodonomorphus Fitzinger, 1843. (3) We restrict Lamprophis (sensu strictissimo) to a small clade of four species endemic to southern Africa: the type species of Lamprophis Fitzinger, 1843 (Lamprophis aurora) plus Lamprophis fiskii, Lamprophis fuscus and Lamprophis guttatus.
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  • Date Issued: 2011
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