Mulling over Art with Andrew Mulenga: Shapley inspirations
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146893 , vital:38567 , https://www.themastonline.com/2019/11/05/mulling-over-art-shapley-inspirations/
- Description: Sponsored by the Confucius Institute at the University of Zambia (UNZA), the guiding idea of the exhibition “2019 Confucius Institute Art Exhibition and Open Day” at the Lusaka National Museum was a simple one, to celebrate the friendship of Zambia and China.
- Full Text:
- Date Issued: 2019
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146893 , vital:38567 , https://www.themastonline.com/2019/11/05/mulling-over-art-shapley-inspirations/
- Description: Sponsored by the Confucius Institute at the University of Zambia (UNZA), the guiding idea of the exhibition “2019 Confucius Institute Art Exhibition and Open Day” at the Lusaka National Museum was a simple one, to celebrate the friendship of Zambia and China.
- Full Text:
- Date Issued: 2019
Mulling over Art with Andrew Mulenga: UNZA, Hone students mitigate Zambia-China relations
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146837 , vital:38562 , https://www.themastonline.com/2019/10/01/mulling-overt-art-unza-hone-students-mitigate-zambia-china-relations/
- Description: China’s presence in Africa has been a contentious issue coupled with speculation that the Asian economic powerhouse is taking over the continent through some kind of neo-colonialism instigated by what some are calling the “Chinese Debt Trap”.
- Full Text:
- Date Issued: 2019
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146837 , vital:38562 , https://www.themastonline.com/2019/10/01/mulling-overt-art-unza-hone-students-mitigate-zambia-china-relations/
- Description: China’s presence in Africa has been a contentious issue coupled with speculation that the Asian economic powerhouse is taking over the continent through some kind of neo-colonialism instigated by what some are calling the “Chinese Debt Trap”.
- Full Text:
- Date Issued: 2019
Mulling over Art with Andrew Mulenga: Vincentio solo yields mixed reviews from ZAOU students
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146804 , vital:38559 , https://www.themastonline.com/2019/05/28/mulling-over-art-vincentio-solo-yields-mixed-reviews-from-zaou-students/
- Description: Every semester, the Zambian Open University’s Bachelor of Arts in Fine Art residential programme and examination periods include several field trips that involve visits to museums, art galleries, private collections, public discussions as well as theatre and film production houses within Lusaka. Among the many tours this semester was a visit by a combined group of over thirty 2nd, 3rd and 4th year students from across the country to Zambian abstract maestro Vincentio Phiri’s solo exhibition entitled “Omission” that ran at the Zambia Ultra Gallery at Garden City Mall on Great East Road in Lusaka from 14th to 30th April.
- Full Text:
- Date Issued: 2019
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146804 , vital:38559 , https://www.themastonline.com/2019/05/28/mulling-over-art-vincentio-solo-yields-mixed-reviews-from-zaou-students/
- Description: Every semester, the Zambian Open University’s Bachelor of Arts in Fine Art residential programme and examination periods include several field trips that involve visits to museums, art galleries, private collections, public discussions as well as theatre and film production houses within Lusaka. Among the many tours this semester was a visit by a combined group of over thirty 2nd, 3rd and 4th year students from across the country to Zambian abstract maestro Vincentio Phiri’s solo exhibition entitled “Omission” that ran at the Zambia Ultra Gallery at Garden City Mall on Great East Road in Lusaka from 14th to 30th April.
- Full Text:
- Date Issued: 2019
Mulling over Art with Andrew Mulenga: Wadada’s paintings: vehicles for peace
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146854 , vital:38564 , https://www.themastonline.com/2019/10/23/mulling-over-art-2/
- Description: ART can be argued to possess a visual agency that gives it the ability to sway popular mindsets or aid peacebuilding and help mediate social healing. It can help bring together aggressively opposing political parties by encouraging nonviolent politicking. In short, art is a vehicle for peace.
- Full Text:
- Date Issued: 2019
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146854 , vital:38564 , https://www.themastonline.com/2019/10/23/mulling-over-art-2/
- Description: ART can be argued to possess a visual agency that gives it the ability to sway popular mindsets or aid peacebuilding and help mediate social healing. It can help bring together aggressively opposing political parties by encouraging nonviolent politicking. In short, art is a vehicle for peace.
- Full Text:
- Date Issued: 2019
Mulling over Art with Andrew Mulenga: ZAOU releases 6th stream of Fine Art Students
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146882 , vital:38566 , https://www.themastonline.com/2019/12/31/mulling-over-art-zaou-releases-6th-stream-of-fine-art-students/
- Description: Friday the 13th of December marked the last day of a four-year academic journey for 14 Bachelor of Fine Arts students at the Zambian Open University. Held at the Lusaka National Museum, it culminated in what is now called the Fourth Year Undergraduate Fine Arts Expo, an annual event.
- Full Text:
- Date Issued: 2019
- Authors: Mulenga, Andrew
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146882 , vital:38566 , https://www.themastonline.com/2019/12/31/mulling-over-art-zaou-releases-6th-stream-of-fine-art-students/
- Description: Friday the 13th of December marked the last day of a four-year academic journey for 14 Bachelor of Fine Arts students at the Zambian Open University. Held at the Lusaka National Museum, it culminated in what is now called the Fourth Year Undergraduate Fine Arts Expo, an annual event.
- Full Text:
- Date Issued: 2019
Nano-enabled liposomal mucoadhesive films for enhanced efavirenz buccal drug delivery
- Okafor, Nnamadi I, Ngoepe, Mpho, Siwe-Noundou, Xavier, Krause, Rui W M
- Authors: Okafor, Nnamadi I , Ngoepe, Mpho , Siwe-Noundou, Xavier , Krause, Rui W M
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/194032 , vital:45417 , xlink:href="https://doi.org/10.1016/j.jddst.2019.101312"
- Description: Buccal films (BFs) were prepared using a solvent casting method using the liposomal suspension as the dispersing medium. Optimization of some physical properties of the films containing different amounts of polymers was done using digital Vernier calliper and digital weighing balance. The physiochemical properties of the best optimized properties were characterized using Differential scanning calorimetry (DSC), X-ray diffraction (XRD), Fourier transfer infrared spectroscopy (FTIR), Transmission Electron Microscopy (TEM), Energy dispersive X-ray spectroscopy (EDS), and Scanning Electron Microscopy (SEM). Permeation study of the BFs composed of Carbopol (CP) alone and CP to Pluronic 127 (PF127) demonstrated better bio-adhesive properties than the films made of other polymers such as HPMC (hydroxyl propyl methyl cellulose) and HPMC-PF127. These CP based BFs (without and with PF127) exhibited good film thickness 0.88 ± 0.10 and 0.76 ± 0.14 mm, with weight uniformity 68.22 ± 1.04 and 86.28 ± 2.16 mg, satisfactory flexibility values 258 and 321, and slightly acidic pH 6.43 ± 0.76 and 6.32 ± 0.01. The swelling percentage was found to be 50% for CP and 78% for CP-PF127. The cumulative amount of drug that permeated through the buccal epithelium after 24 h was about 66% from CP and 75% from CP-PF127.
- Full Text:
- Date Issued: 2019
- Authors: Okafor, Nnamadi I , Ngoepe, Mpho , Siwe-Noundou, Xavier , Krause, Rui W M
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/194032 , vital:45417 , xlink:href="https://doi.org/10.1016/j.jddst.2019.101312"
- Description: Buccal films (BFs) were prepared using a solvent casting method using the liposomal suspension as the dispersing medium. Optimization of some physical properties of the films containing different amounts of polymers was done using digital Vernier calliper and digital weighing balance. The physiochemical properties of the best optimized properties were characterized using Differential scanning calorimetry (DSC), X-ray diffraction (XRD), Fourier transfer infrared spectroscopy (FTIR), Transmission Electron Microscopy (TEM), Energy dispersive X-ray spectroscopy (EDS), and Scanning Electron Microscopy (SEM). Permeation study of the BFs composed of Carbopol (CP) alone and CP to Pluronic 127 (PF127) demonstrated better bio-adhesive properties than the films made of other polymers such as HPMC (hydroxyl propyl methyl cellulose) and HPMC-PF127. These CP based BFs (without and with PF127) exhibited good film thickness 0.88 ± 0.10 and 0.76 ± 0.14 mm, with weight uniformity 68.22 ± 1.04 and 86.28 ± 2.16 mg, satisfactory flexibility values 258 and 321, and slightly acidic pH 6.43 ± 0.76 and 6.32 ± 0.01. The swelling percentage was found to be 50% for CP and 78% for CP-PF127. The cumulative amount of drug that permeated through the buccal epithelium after 24 h was about 66% from CP and 75% from CP-PF127.
- Full Text:
- Date Issued: 2019
Navigating non-sense by exemplifying situated life experience and intergenerational heritage knowledge in Education for Sustainable Development learning spaces
- O'Donoghue, Rob B, Kibuka-Sebitosi, Esther, Tshiningayamwe, Sirkka A N, Palmer, Carl
- Authors: O'Donoghue, Rob B , Kibuka-Sebitosi, Esther , Tshiningayamwe, Sirkka A N , Palmer, Carl
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/388122 , vital:68308 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/186410"
- Description: This paper uses an activity system perspective to probe the related problems of knowledge abstraction and a lack of relevance as a modern legacy of colonial education practices in Africa. Its purpose is to contemplate Education for Sustainable Development (ESD) pedagogy to support learning that might be better situated in and resonate with local African contexts and the emerging sustainability concerns in everyday life. Colonial education trajectories and the recent inclusion of new environmental knowledge in African curriculum and civic learning contexts are examined. This points to how circulating environment and sustainability knowledge is being constituted in disciplinary fields as abstract concepts that are often difficult to relate to local sustainability concerns. Socio-cultural heritage and intergenerational meaning making are explored to uncover better situated ways of navigating much of the abstract ‘non-sense’ confronting African learners in many modern education contexts today. Illustrative examples of historical patterns of exclusion are scoped and two cases of pedagogical innovation are examined to contemplate how to navigate better situated and more relevant learning processes. Enacted in situated and co-engaged ways, ESD practices may enable the socio-cultural capital and environmental realities of local social-ecological contexts to articulate with better situated sustainability propositions for transitioning to more peaceful, just and sustainable futures.
- Full Text:
- Date Issued: 2019
- Authors: O'Donoghue, Rob B , Kibuka-Sebitosi, Esther , Tshiningayamwe, Sirkka A N , Palmer, Carl
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/388122 , vital:68308 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/186410"
- Description: This paper uses an activity system perspective to probe the related problems of knowledge abstraction and a lack of relevance as a modern legacy of colonial education practices in Africa. Its purpose is to contemplate Education for Sustainable Development (ESD) pedagogy to support learning that might be better situated in and resonate with local African contexts and the emerging sustainability concerns in everyday life. Colonial education trajectories and the recent inclusion of new environmental knowledge in African curriculum and civic learning contexts are examined. This points to how circulating environment and sustainability knowledge is being constituted in disciplinary fields as abstract concepts that are often difficult to relate to local sustainability concerns. Socio-cultural heritage and intergenerational meaning making are explored to uncover better situated ways of navigating much of the abstract ‘non-sense’ confronting African learners in many modern education contexts today. Illustrative examples of historical patterns of exclusion are scoped and two cases of pedagogical innovation are examined to contemplate how to navigate better situated and more relevant learning processes. Enacted in situated and co-engaged ways, ESD practices may enable the socio-cultural capital and environmental realities of local social-ecological contexts to articulate with better situated sustainability propositions for transitioning to more peaceful, just and sustainable futures.
- Full Text:
- Date Issued: 2019
New type of metal-free and Zinc (II), In (III), Ga (III) phthalocyanines carrying biologically active substituents: Synthesis and photophysicochemical properties and photodynamic therapy activity
- Sen, Pinar, Managa, Muthumuni, Nyokong, Tebello
- Authors: Sen, Pinar , Managa, Muthumuni , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186971 , vital:44552 , xlink:href="https://doi.org/10.1016/j.ica.2019.03.010"
- Description: This study reports on novel phthalocyanines having benzimidazole units which are known to have biological properties. 4-(4-(5-chloro-1H-benzo[d]imidazol-2-yl) substituted metal-free, Zn(II), In(III) and Ga(III) phthalocyanines were synthesized, these newly synthesized molecules that were substituted by oxygen bridges were fully characterized. For the purpose of determining their potency for photodynamic therapy, the photophysicochemical properties were investigated in DMSO. The H2Pc (4) showed higher fluorescence quantum yield and fluorescence lifetime as compared to metallated phthalocyanines derivatives. However, the highest singlet oxygen (ΦΔ) and triplet state quantum yields (ΦT) values were obtained with the In(III)Pc (5).
- Full Text:
- Date Issued: 2019
- Authors: Sen, Pinar , Managa, Muthumuni , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186971 , vital:44552 , xlink:href="https://doi.org/10.1016/j.ica.2019.03.010"
- Description: This study reports on novel phthalocyanines having benzimidazole units which are known to have biological properties. 4-(4-(5-chloro-1H-benzo[d]imidazol-2-yl) substituted metal-free, Zn(II), In(III) and Ga(III) phthalocyanines were synthesized, these newly synthesized molecules that were substituted by oxygen bridges were fully characterized. For the purpose of determining their potency for photodynamic therapy, the photophysicochemical properties were investigated in DMSO. The H2Pc (4) showed higher fluorescence quantum yield and fluorescence lifetime as compared to metallated phthalocyanines derivatives. However, the highest singlet oxygen (ΦΔ) and triplet state quantum yields (ΦT) values were obtained with the In(III)Pc (5).
- Full Text:
- Date Issued: 2019
Non-timber forest product use and market chains along a deforestation gradient in southwest Malawi
- Mahonya, Sophie, Shackleton, Charlie M, Schreckenberg, Kate
- Authors: Mahonya, Sophie , Shackleton, Charlie M , Schreckenberg, Kate
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/177465 , vital:42824 , https://doi.org/10.3389/ffgc.2019.00071
- Description: The importance of non-timber forest products (NTFPs) to rural livelihoods is widely acknowledged globally, as is the income generated from casual or fulltime trade on village and urban markets. However, there is less understanding of how the condition or status of the neighboring landscapes influence the use of and trade in NTFPs. Here we report on the use and trade in NTFPs in four villages situated along a gradient of decreasing forest cover in southwest Malawi using a mixed-methods approach. Data were sourced via a survey of 286 households, value chain analysis of the four most commonly traded NTFPs (thatch grass, edible orchids, mushrooms, and wild fruits), key informant interviews with NTFP traders and direct observations.
- Full Text:
- Date Issued: 2019
- Authors: Mahonya, Sophie , Shackleton, Charlie M , Schreckenberg, Kate
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/177465 , vital:42824 , https://doi.org/10.3389/ffgc.2019.00071
- Description: The importance of non-timber forest products (NTFPs) to rural livelihoods is widely acknowledged globally, as is the income generated from casual or fulltime trade on village and urban markets. However, there is less understanding of how the condition or status of the neighboring landscapes influence the use of and trade in NTFPs. Here we report on the use and trade in NTFPs in four villages situated along a gradient of decreasing forest cover in southwest Malawi using a mixed-methods approach. Data were sourced via a survey of 286 households, value chain analysis of the four most commonly traded NTFPs (thatch grass, edible orchids, mushrooms, and wild fruits), key informant interviews with NTFP traders and direct observations.
- Full Text:
- Date Issued: 2019
Nonlinear optical behavior of n-tuple decker phthalocyanines at the nanosecond regime
- Sekhosana, Kutloana E, Nyokong, Tebello
- Authors: Sekhosana, Kutloana E , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/234603 , vital:50212 , xlink:href="https://doi.org/10.1039/C9RA01836K"
- Description: The coordination system of rare-earth n-tuple decker phthalocyanines would be better suited with appropriate metal ions with the correct coordination number and the solvent system of the reaction, amongst other reasons, for the formation of n-tuple decker phthalocyanines. As a result, these complexes are very rare. In this manuscript, we present new n-tuple decker phthalocyanines in the form of double- (complex 2), quadruple- (complex 3a) and sextuple-decker phthalocyanines (complex 3b), all of which contain neodymium and cadmium metal ions. The primary focus is the investigation of the nonlinear optical (NLO) mechanisms responsible for the observed reverse saturable absorption. While the extension of the π-electron system has been found to enhance the nonlinear optical behavior of complexes 3a and 3b, a change in the NLO mechanisms has been observed, with complex 2 lacking the triplet state population, as revealed by a laser flash photolysis technique. It has also been established that the excited state absorption cross sections follow a clear order of magnitude for the complexes under investigation: σ23 (for 3b) > σ23 (for 3a) > σ1m (for 2). This trend evidences the effects of the extension of the π-electron system.
- Full Text:
- Date Issued: 2019
- Authors: Sekhosana, Kutloana E , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/234603 , vital:50212 , xlink:href="https://doi.org/10.1039/C9RA01836K"
- Description: The coordination system of rare-earth n-tuple decker phthalocyanines would be better suited with appropriate metal ions with the correct coordination number and the solvent system of the reaction, amongst other reasons, for the formation of n-tuple decker phthalocyanines. As a result, these complexes are very rare. In this manuscript, we present new n-tuple decker phthalocyanines in the form of double- (complex 2), quadruple- (complex 3a) and sextuple-decker phthalocyanines (complex 3b), all of which contain neodymium and cadmium metal ions. The primary focus is the investigation of the nonlinear optical (NLO) mechanisms responsible for the observed reverse saturable absorption. While the extension of the π-electron system has been found to enhance the nonlinear optical behavior of complexes 3a and 3b, a change in the NLO mechanisms has been observed, with complex 2 lacking the triplet state population, as revealed by a laser flash photolysis technique. It has also been established that the excited state absorption cross sections follow a clear order of magnitude for the complexes under investigation: σ23 (for 3b) > σ23 (for 3a) > σ1m (for 2). This trend evidences the effects of the extension of the π-electron system.
- Full Text:
- Date Issued: 2019
Nonlinear optical properties of metal free and nickel binuclear phthalocyanines
- Kabwe, Kapambwe P, Louzada, Marcel, Britton, Jonathan, Olomola,Temitope O, Nyokong, Tebello, Khene, Samson M
- Authors: Kabwe, Kapambwe P , Louzada, Marcel , Britton, Jonathan , Olomola,Temitope O , Nyokong, Tebello , Khene, Samson M
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186846 , vital:44539 , xlink:href="https://doi.org/10.1016/j.dyepig.2019.05.003"
- Description: This work employs the open and closed Z-scan aperture technique to comparatively study the nonlinear optical (NLO) properties of nickel and metal free 4-tert-butylphenoxy phthalocyanine, biphenyl bridged bis-4-tert-butylphenoxy phthalocyanine and naphthalene bridged bis-4-tert-butylphenoxy phthalocyanine. Density functional theory (DFT) calculations of dipolar and octupolar ( J=1 and J=3) contribution were determined theoretically from hyper-Rayleigh scattering (HRS) response ( HRS) values.
- Full Text:
- Date Issued: 2019
- Authors: Kabwe, Kapambwe P , Louzada, Marcel , Britton, Jonathan , Olomola,Temitope O , Nyokong, Tebello , Khene, Samson M
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186846 , vital:44539 , xlink:href="https://doi.org/10.1016/j.dyepig.2019.05.003"
- Description: This work employs the open and closed Z-scan aperture technique to comparatively study the nonlinear optical (NLO) properties of nickel and metal free 4-tert-butylphenoxy phthalocyanine, biphenyl bridged bis-4-tert-butylphenoxy phthalocyanine and naphthalene bridged bis-4-tert-butylphenoxy phthalocyanine. Density functional theory (DFT) calculations of dipolar and octupolar ( J=1 and J=3) contribution were determined theoretically from hyper-Rayleigh scattering (HRS) response ( HRS) values.
- Full Text:
- Date Issued: 2019
Nonlinear optical responses of carbazole-substituted phthalocyanines conjugated to graphene quantum dots and in thin films
- Majeed, Shereen A, Nwaji, Njemuwa, Mack, John, Nyokong, Tebello, Makhseed, Saad
- Authors: Majeed, Shereen A , Nwaji, Njemuwa , Mack, John , Nyokong, Tebello , Makhseed, Saad
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186938 , vital:44549 , xlink:href="https://doi.org/10.1016/j.jlumin.2019.04.034"
- Description: Three different phthalocyanine complexes substituted with carbazoles were conjugated to graphene quantum dots (GQDs) through π–π stacking. The morphologies, sizes, and crystallinities of the nanoconjugates were determined using Raman spectroscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, and X-ray diffraction. The nonlinear optical (NLO) properties of the metallophthalocyanines alone and when conjugated to the GQD nanomaterial in different solvents, as well as after having been embedded in thin films, were studied. The effects of the different substituents and solvents on the NLO properties of the metallophthalocyanines were evaluated. Enhancements in the photophysical properties of the complexes upon conjugation with the nanomaterial were observed. Fluorescence quantum yields, fluorescence lifetimes, triplet quantum yields, and triplet lifetimes were measured for the complexes, and for their conjugates in DMSO.
- Full Text:
- Date Issued: 2019
- Authors: Majeed, Shereen A , Nwaji, Njemuwa , Mack, John , Nyokong, Tebello , Makhseed, Saad
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186938 , vital:44549 , xlink:href="https://doi.org/10.1016/j.jlumin.2019.04.034"
- Description: Three different phthalocyanine complexes substituted with carbazoles were conjugated to graphene quantum dots (GQDs) through π–π stacking. The morphologies, sizes, and crystallinities of the nanoconjugates were determined using Raman spectroscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, and X-ray diffraction. The nonlinear optical (NLO) properties of the metallophthalocyanines alone and when conjugated to the GQD nanomaterial in different solvents, as well as after having been embedded in thin films, were studied. The effects of the different substituents and solvents on the NLO properties of the metallophthalocyanines were evaluated. Enhancements in the photophysical properties of the complexes upon conjugation with the nanomaterial were observed. Fluorescence quantum yields, fluorescence lifetimes, triplet quantum yields, and triplet lifetimes were measured for the complexes, and for their conjugates in DMSO.
- Full Text:
- Date Issued: 2019
Novel potential antimalarials through drug repurposing and multitargeting: a Computational Approach
- Diallo, Bakary N, Lobb, Kevin A, Tastan Bishop, Özlem
- Authors: Diallo, Bakary N , Lobb, Kevin A , Tastan Bishop, Özlem
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/162676 , vital:40972 , https://doi.org/10.21955/aasopenres.1114955.1
- Description: This study aims to identify potential antimalarials from Food and Drug Administration (FDA) approved drugs.
- Full Text:
- Date Issued: 2019
- Authors: Diallo, Bakary N , Lobb, Kevin A , Tastan Bishop, Özlem
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/162676 , vital:40972 , https://doi.org/10.21955/aasopenres.1114955.1
- Description: This study aims to identify potential antimalarials from Food and Drug Administration (FDA) approved drugs.
- Full Text:
- Date Issued: 2019
Of sacred crossroads: cultural studies and the Sacred A special issue edited by Sonjah Stanley Niaah
- Authors: Stanley Niaah, Sonjah
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146066 , vital:38492 , https://0-doi.org.wam.seals.ac.za/10.1515/culture-2019-0047
- Description: The Seventh International Association for Cultural Studies Crossroads Conference, held in 2008 at the University of the West Indies, in Mona, Jamaica, was staged for the first time with an overarching theme. Based on the cultural, spiritual and geographical diversity of the Caribbean region, the local conference organizing team insisted that the conference needed to reflect key aspects of the space. Consequently, the theme selected was “Of Sacred Crossroads”. The conference call for papers asked for a consideration of issues surrounding the dialogue between humanity and spirituality. In the face of increasing materialism and consumerism, as well as the prevailing emphasis on science and technology in contemporary society, participants celebrated the intangible heritage of humankind--that found in religion, art, dance, song, oratory, healing, re-creation, performance, ritual, belief systems, ethics, globalization and communication, among others.
- Full Text:
- Date Issued: 2019
Of sacred crossroads: cultural studies and the Sacred A special issue edited by Sonjah Stanley Niaah
- Authors: Stanley Niaah, Sonjah
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146066 , vital:38492 , https://0-doi.org.wam.seals.ac.za/10.1515/culture-2019-0047
- Description: The Seventh International Association for Cultural Studies Crossroads Conference, held in 2008 at the University of the West Indies, in Mona, Jamaica, was staged for the first time with an overarching theme. Based on the cultural, spiritual and geographical diversity of the Caribbean region, the local conference organizing team insisted that the conference needed to reflect key aspects of the space. Consequently, the theme selected was “Of Sacred Crossroads”. The conference call for papers asked for a consideration of issues surrounding the dialogue between humanity and spirituality. In the face of increasing materialism and consumerism, as well as the prevailing emphasis on science and technology in contemporary society, participants celebrated the intangible heritage of humankind--that found in religion, art, dance, song, oratory, healing, re-creation, performance, ritual, belief systems, ethics, globalization and communication, among others.
- Full Text:
- Date Issued: 2019
On-site evaluation of smoking, alcohol consumption and physical inactivity among commercial taxi drivers in Buffalo City Metropolitan Municipality, South Africa
- Adedokun, Aanuoluwa Odunayo, Ter Goon, Daniel, Owolabi, Eyitayo Omolara, Adeniyi, Oladele Vincent, Ajayi, Anthony Idowu
- Authors: Adedokun, Aanuoluwa Odunayo , Ter Goon, Daniel , Owolabi, Eyitayo Omolara , Adeniyi, Oladele Vincent , Ajayi, Anthony Idowu
- Date: 2019
- Subjects: Alcohol use , Substance use , Commercial drivers
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/11260/5086 , vital:44345 , https://doi.org/10.5539/gjhs.v11n2p110
- Description: Commercial drivers have been identified as eliciting behaviours that promote non- communicable diseases and road traffic accidents. The aim of the study is to determine the prevalence and pattern of alcohol use, smoking and physical inactivity among commercial taxi drivers in Buffalo City Metropolitan Municipality, South Africa. A cross-sectional study was conducted among 403 commercial drivers using the face-to-face interviews method. The WHO STEPwise questionnaire was used to obtain the demographic data, self-reported rate of alcohol consumption, tobacco use and physical inactivity. The participants’ mean age was 43.3 ± 12.5 years. About 30% of the participants were daily smokers, 37% consumed alcohol regularly and only 18% were physically active, whilst 82% were physically inactive. The prevalence of alcohol use, smoking and physical inactivity is high among commercial drivers in East London. Workplace health education on the health effects of these lifestyles’ risky behaviours on individuals and the general public should be given to the drivers.
- Full Text:
- Date Issued: 2019
- Authors: Adedokun, Aanuoluwa Odunayo , Ter Goon, Daniel , Owolabi, Eyitayo Omolara , Adeniyi, Oladele Vincent , Ajayi, Anthony Idowu
- Date: 2019
- Subjects: Alcohol use , Substance use , Commercial drivers
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/11260/5086 , vital:44345 , https://doi.org/10.5539/gjhs.v11n2p110
- Description: Commercial drivers have been identified as eliciting behaviours that promote non- communicable diseases and road traffic accidents. The aim of the study is to determine the prevalence and pattern of alcohol use, smoking and physical inactivity among commercial taxi drivers in Buffalo City Metropolitan Municipality, South Africa. A cross-sectional study was conducted among 403 commercial drivers using the face-to-face interviews method. The WHO STEPwise questionnaire was used to obtain the demographic data, self-reported rate of alcohol consumption, tobacco use and physical inactivity. The participants’ mean age was 43.3 ± 12.5 years. About 30% of the participants were daily smokers, 37% consumed alcohol regularly and only 18% were physically active, whilst 82% were physically inactive. The prevalence of alcohol use, smoking and physical inactivity is high among commercial drivers in East London. Workplace health education on the health effects of these lifestyles’ risky behaviours on individuals and the general public should be given to the drivers.
- Full Text:
- Date Issued: 2019
Optical limiting and femtosecond pump-probe transient absorbance properties of a 3, 5-distyrylBODIPY dye
- Ngoy, Bokolombe P, May, Aviwe K, Mack, John, Nyokong, Tebello
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186835 , vital:44538 , xlink:href="https://doi.org/10.3389/fchem.2019.00740"
- Description: The optical limiting (OL) properties of a 3,5-di-p-benzyloxystyrylBODIPY dye with an p-acetamidophenyl moiety at the meso-position have been investigated by using the open-aperture Z-scan technique at 532 nm with 10 ns laser pulses. There is a ca. 140 nm red shift of the main spectral band to 644 nm relative to the corresponding BODIPY core dye, due to the incorporation of p-benzyloxystyryl groups at the 3,5-positions. As a result, there is relatively weak absorbance across most of the visible region under ambient light conditions. Analysis of the observed reverse saturable absorbance (RSA) profiles demonstrates that the dye is potentially suitable for use in optical limiting applications as has been reported previously for other 3,5-distyrylBODIPY dyes. Time-resolved transient absorption spectroscopy and kinetic studies with femtosecond and nanosecond scale laser pulses provide the first direct spectral evidence that excited state absorption (ESA) from the S1 state is responsible for the observed OL properties.
- Full Text:
- Date Issued: 2019
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186835 , vital:44538 , xlink:href="https://doi.org/10.3389/fchem.2019.00740"
- Description: The optical limiting (OL) properties of a 3,5-di-p-benzyloxystyrylBODIPY dye with an p-acetamidophenyl moiety at the meso-position have been investigated by using the open-aperture Z-scan technique at 532 nm with 10 ns laser pulses. There is a ca. 140 nm red shift of the main spectral band to 644 nm relative to the corresponding BODIPY core dye, due to the incorporation of p-benzyloxystyryl groups at the 3,5-positions. As a result, there is relatively weak absorbance across most of the visible region under ambient light conditions. Analysis of the observed reverse saturable absorbance (RSA) profiles demonstrates that the dye is potentially suitable for use in optical limiting applications as has been reported previously for other 3,5-distyrylBODIPY dyes. Time-resolved transient absorption spectroscopy and kinetic studies with femtosecond and nanosecond scale laser pulses provide the first direct spectral evidence that excited state absorption (ESA) from the S1 state is responsible for the observed OL properties.
- Full Text:
- Date Issued: 2019
Out of Africa?: a dated molecular phylogeny of the cicada tribe Platypleurini Schmidt (Hemiptera: Cicadidae), with a focus on African genera and the genus Platypleura Amyot and Audinet‐Serville
- Price, Benjamin W, Marshall, David C, Barker, Nigel P, Simon, Chris, Villet, Martin H
- Authors: Price, Benjamin W , Marshall, David C , Barker, Nigel P , Simon, Chris , Villet, Martin H
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/140704 , vital:37911 , DOI: 10.1111/syen.12360
- Description: The Platypleurini is a large group of charismatic cicadas distributed from Cape Agulhas in South Africa, through tropical Africa, Madagascar, India and eastern Asia to Japan, with generic diversity concentrated in equatorial and southern Africa. This distribution suggests the possibility of a Gondwanan origin and dispersal to eastern Asia from Africa or India. We used a four-gene (three mitochondrial) molecular dataset, fossil calibrations and molecular clock information to explore the phylogenetic relationships of the platypleurine cicadas and the timing and geography of their diversification. The earliest splits in the tribe were found to separate forest genera in Madagascar and equatorial Africa from the main radiation, and all of the Asian/Indian species sampled formed a younger clade nested well within the African taxa.
- Full Text:
- Date Issued: 2019
- Authors: Price, Benjamin W , Marshall, David C , Barker, Nigel P , Simon, Chris , Villet, Martin H
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/140704 , vital:37911 , DOI: 10.1111/syen.12360
- Description: The Platypleurini is a large group of charismatic cicadas distributed from Cape Agulhas in South Africa, through tropical Africa, Madagascar, India and eastern Asia to Japan, with generic diversity concentrated in equatorial and southern Africa. This distribution suggests the possibility of a Gondwanan origin and dispersal to eastern Asia from Africa or India. We used a four-gene (three mitochondrial) molecular dataset, fossil calibrations and molecular clock information to explore the phylogenetic relationships of the platypleurine cicadas and the timing and geography of their diversification. The earliest splits in the tribe were found to separate forest genera in Madagascar and equatorial Africa from the main radiation, and all of the Asian/Indian species sampled formed a younger clade nested well within the African taxa.
- Full Text:
- Date Issued: 2019
Outcome of illustrated information leaflet on correct usage of asthma-metered dose inhaler:
- Wrench, Wendy W, Van Dyk, Lynette, Srinivas, Sunitha C, Dowse, Roslind
- Authors: Wrench, Wendy W , Van Dyk, Lynette , Srinivas, Sunitha C , Dowse, Roslind
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156640 , vital:40033 , https://doi.org/10.4102/phcfm.v11i1.2079
- Description: Research globally has shown that metered dose inhaler (MDI) technique is poor, with patient education and regular demonstration critical in maintaining correct use of inhalers. Patient information containing pictorial aids improves understanding of medicine usage; however, manufacturer leaflets illustrating MDI use may not be easily understood by low-literacy asthma patients. To develop and evaluate the outcome of a tailored, simplified leaflet on correct MDI technique in asthma patients with limited literacy skills.
- Full Text:
- Date Issued: 2019
- Authors: Wrench, Wendy W , Van Dyk, Lynette , Srinivas, Sunitha C , Dowse, Roslind
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156640 , vital:40033 , https://doi.org/10.4102/phcfm.v11i1.2079
- Description: Research globally has shown that metered dose inhaler (MDI) technique is poor, with patient education and regular demonstration critical in maintaining correct use of inhalers. Patient information containing pictorial aids improves understanding of medicine usage; however, manufacturer leaflets illustrating MDI use may not be easily understood by low-literacy asthma patients. To develop and evaluate the outcome of a tailored, simplified leaflet on correct MDI technique in asthma patients with limited literacy skills.
- Full Text:
- Date Issued: 2019
Paper beads on the move: mobilizing trajectories and subjectivities to shape contemporary art in Uganda
- Authors: Kasozi, Dorah
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145985 , vital:38484 , https://0-doi.org.wam.seals.ac.za/10.1162/afar_a_00459
- Description: Beads cannot simply be viewed as nonrepresentational, decorative entities. In Uganda, the art of paper bead[ing] is empowering women economically while mobilizing new trajectories that reflect the intersecting and shifting landscapes of public space and private space to shape inquiry into gender relationships, art, art-making, and politics.
- Full Text:
- Date Issued: 2019
- Authors: Kasozi, Dorah
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145985 , vital:38484 , https://0-doi.org.wam.seals.ac.za/10.1162/afar_a_00459
- Description: Beads cannot simply be viewed as nonrepresentational, decorative entities. In Uganda, the art of paper bead[ing] is empowering women economically while mobilizing new trajectories that reflect the intersecting and shifting landscapes of public space and private space to shape inquiry into gender relationships, art, art-making, and politics.
- Full Text:
- Date Issued: 2019
Participatory mapping in a developing country context: Lessons from South Africa
- Weyer, Dylan J, Bezerra, Joana C, de Vos, Alta
- Authors: Weyer, Dylan J , Bezerra, Joana C , de Vos, Alta
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416333 , vital:71340 , xlink:href="https://doi.org/10.3390/land8090134"
- Description: Digital participatory mapping improves accessibility to spatial information and the way in which knowledge is co-constructed and landscapes co-managed with impoverished communities. However, many unintended consequences for social and epistemic justice may be exacerbated in developing country contexts. Two South African case studies incorporating Direct-to-Digital participatory mapping in marginalized communities to inform land-use decision-making, and the ethical challenges of adopting this method are discussed. Understanding the past and present context of the site and the power dynamics at play is critical to develop trust and manage expectations among research participants. When employing unfamiliar technology, disparate literacy levels and language barriers create challenges for ensuring participants understand the risks of their involvement and recognize their rights. The logistics of using this approach in remote areas with poor infrastructure and deciding how best to leave the participants with the maps they have co-produced in an accessible format present further challenges. Overcoming these can however offer opportunity for redressing past injustices and empowering marginalized communities with a voice in decisions that affect their livelihoods.
- Full Text:
- Date Issued: 2019
- Authors: Weyer, Dylan J , Bezerra, Joana C , de Vos, Alta
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416333 , vital:71340 , xlink:href="https://doi.org/10.3390/land8090134"
- Description: Digital participatory mapping improves accessibility to spatial information and the way in which knowledge is co-constructed and landscapes co-managed with impoverished communities. However, many unintended consequences for social and epistemic justice may be exacerbated in developing country contexts. Two South African case studies incorporating Direct-to-Digital participatory mapping in marginalized communities to inform land-use decision-making, and the ethical challenges of adopting this method are discussed. Understanding the past and present context of the site and the power dynamics at play is critical to develop trust and manage expectations among research participants. When employing unfamiliar technology, disparate literacy levels and language barriers create challenges for ensuring participants understand the risks of their involvement and recognize their rights. The logistics of using this approach in remote areas with poor infrastructure and deciding how best to leave the participants with the maps they have co-produced in an accessible format present further challenges. Overcoming these can however offer opportunity for redressing past injustices and empowering marginalized communities with a voice in decisions that affect their livelihoods.
- Full Text:
- Date Issued: 2019