Investigating integrated catchment management using a simple water quantity and quality model : a case study of the Crocodile River Catchment, South Africa
- Authors: Retief, Daniel Christoffel Hugo
- Date: 2015
- Subjects: Watersheds -- South Africa -- Krokodilrivier (Mpumalanga) , Integrated water development -- South Africa -- Krokodilrivier (Mpumalanga) , Water quality management -- South Africa -- Krokodilrivier (Mpumalanga) , Water-supply -- South Africa -- Krokodilrivier (Mpumalanga) , Water quality -- Measurement
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:6050 , http://hdl.handle.net/10962/d1017875
- Description: Internationally, water resources are facing increasing pressure due to over-exploitation and pollution. Integrated Water Resource Management (IWRM) has been accepted internationally as a paradigm for integrative and sustainable management of water resources. However, in practice, the implementation and success of IWRM policies has been hampered by the lack of availability of integrative decision support tools, especially within the context of limited resources and observed data. This is true for the Crocodile River Catchment (CRC), located within the Mpumalanga Province of South Africa. The catchment has been experiencing a decline in water quality as a result of the point source input of a cocktail of pollutants, which are discharged from industrial and municipal wastewater treatment plants, as well as diffuse source runoff and return flows from the extensive areas of irrigated agriculture and mining sites. The decline in water quality has profound implications for a range of stakeholders across the catchment including increased treatment costs and reduced crop yields. The combination of deteriorating water quality and the lack of understanding of the relationships between water quantity and quality for determining compliance/non-compliance in the CRC have resulted in collaboration between stakeholders, willing to work in a participatory and transparent manner to create an Integrated Water Quality Management Plan (IWQMP). This project aimed to model water quality, (combined water quality and quantity), to facilitate the IWQMP aiding in the understanding of the relationship between water quantity and quality in the CRC. A relatively simple water quality model (WQSAM) was used that receives inputs from established water quantity systems models, and was designed to be a water quality decision support tool for South African catchments. The model was applied to the CRC, achieving acceptable simulations of total dissolved solids (used as a surrogate for salinity) and nutrients (including orthophosphates, nitrates +nitrites and ammonium) for historical conditions. Validation results revealed that there is little consistency within the catchment, attributed to the non-stationary nature of water quality at many of the sites in the CRC. The analyses of the results using a number of representations including, seasonal load distributions, load duration curves and load flow plots, confirmed that the WQSAM model was able to capture the variability of relationships between water quantity and quality, provided that simulated hydrology was sufficiently accurate. The outputs produced by WQSAM was seen as useful for the CRC, with the Inkomati-Usuthu Catchment Management Agency (IUCMA) planning to operationalise the model in 2015. The ability of WQSAM to simulate water quality in data scarce catchments, with constituents that are appropriate for the needs of water resource management within South Africa, is highly beneficial.
- Full Text:
- Date Issued: 2015
Isolation and structure elucidation of halogenated metabolites from Portieria hornemannii and Portieria tripinnata
- Authors: Adam, Mohammed
- Date: 2015
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/64674 , vital:28591
- Description: The red marine algal genus, Portieria, is known to produce a number of potent cytotoxic compounds with anticancer potential. The most important anticancer lead produced by this genus is the compound halomon. Unfortunately, the lack of sufficient quantities of this compound hampered its further development. Two Portieria species, Portieria hornemannii and Portieria tripinnata, are found along the South African coastline. Recent studies, based on DNA analysis, suggest that Portieria hornemannii may in fact be divided into several cryptic species. The current project is part of a larger study designed to investigate the use of secondary metabolites to identify new marine algal species. In this study 1H NMR profiles of the organic extracts of selected Portieria spp were compared in order to identify new species. Selected compounds were then isolated and characterised as potential chemotaxonomic markers. Four halogenated monoterpenes were isolated from Portieria hornemannii. Two of these were new compounds 4-(3-bromo-4-chloro-4-methylpentyl)-3-chlorofuran-2(5H)-one, which were isomers of each other. The two known compounds had been previously isolated from Portieria hornemannii samples off the Madagascar coast. These compounds could prove to be useful as chemotaxonomic marker compounds, as they have never been isolated from any other species of marine algae. Three known halogenated monoterpenes were isolated from Portieria tripinnata. These compounds had been previously isolated from different species of marine algae and therefore, could not serve as chemotaxonomic marker compounds for this species of marine alga. Further work needs to be done on Portieria tripinnata, with regards to its chemistry, as it is a species of marine algae that has not been previously researched.
- Full Text:
- Date Issued: 2015
Link between ghost artefacts, source suppression and incomplete calibration sky models
- Authors: Nunhokee, Chuneeta Devi
- Date: 2015
- Subjects: Interferometry , Calibration
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5556 , http://hdl.handle.net/10962/d1017900
- Description: Calibration is a fundamental step towards producing radio interferometric images. However, naive calibration produces calibration artefacts, in the guise of spurious emission, buried in the thermal noise. This work investigates these calibration artefacts, henceforth referred to as “ghosts”. A 21 cm observation with the Westerbork Synthesis Radio Telescope yielded similar ghost sources, and it was anticipated that they were due to calibrating with incomplete sky models. An analytical ghost distribution of a two-source scenario is derived to substantiate this theory and to seek answers to the related bewildering features (regular ghost pattern, points spread function-like sidelobes, independent of model flux). The theoretically predicted ghost distribution qualitatively matches with the observational ones and shows high dependence on the array geometry. The theory draws the conclusion that both the ghost phenomenon and suppression of the unmodelled flux have the same root cause. In addition, the suppression of the unmodelled flux is studied as functions of unmodelled flux, differential gain solution interval and the number of sources subjected to direction-dependent gains. These studies summarise that the suppression rate is constant irrespective of the degree of incompleteness of the calibration sky model. In the presence of a direction-dependent effect, the suppression drastically increases; however, this increase can be compensated for by using longer solution intervals.
- Full Text:
- Date Issued: 2015
Mapping and prediction of archaeological sites of habitation by modern humans using GIS and expert mapping on the south coast of South Africa
- Authors: Kleyn, Philippa May
- Date: 2015
- Subjects: Geographic information systems -- South Africa , Archaeological sites , Kitchen-middens -- South Africa , Prehistoric peoples -- South Africa , Prehistoric peoples -- Dwellings -- South Africa , Geological mapping -- South Africa , Coastal archaeology -- South Africa , Archaeological significance -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4890 , http://hdl.handle.net/10962/d1018662
- Description: South Africa contains many archaeological resources including shell middens from the Middle Stone Age (MSA) and Later Stone Age (LSA). These shell middens give researchers insight into the behaviour of modern humans where the first fossil evidence appears in Africa around 200 000 years ago (Klein, 2008). Research into shell middens is therefore vital to understand the origin of human kind. This study investigates whether Geographical Information Systems (GIS) is a useful tool for predicting locations of unknown shell midden sites using the characteristics of known areas of modern human habitation. This was done using suitability analysis and expert mapping techniques. Ground truthing of the results of the desktop analysis revealed that GIS is not a useful tool for predicting sites of modern habitation as the characteristics that determine human habitation are too variable.
- Full Text:
- Date Issued: 2015
Montane Wetlands of the South African Great Escarpment : plant communities and environmental drivers
- Authors: Janks, Matthew Richard
- Date: 2015
- Subjects: Mountain plants -- South Africa -- Eastern Cape , Wetland plants -- South Africa -- Eastern Cape , Wetland plants -- Effect of altitude on -- South Africa -- Eastern Cape , Wetland ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4274 , http://hdl.handle.net/10962/d1018917
- Description: Wetlands provide a number of valuable functions to both the surrounding environment and society. The anaerobic conditions created by flooding in wetlands provide a habitat that supports unique assemblages of plant life. High altitude wetlands are amongst the most species-rich in South Africa. They house a number of rare species and play a vital role in the supply of water to lower lying areas. These are some of the reasons that mountain wetlands are of high conservation value. A phytosociological study was undertaken on the high altitude wetlands of the Great Escarpment with the aim of classifying the plant communities and identifying the environmental drivers of plant community patterns within these ecosystems. Data collection was focused in the Eastern Cape and was supplemented with data from existing studies to gain a more complete understanding of the wetlands of the Great Escarpment of South Africa. Using the Braun-Blanquet approach, Hierarchical Cluster Analysis and Indicator Species Analysis; five broad wetland groups were identified, comprised of 33 individual plant communities and 81 indicator species. Multivariate analysis, including Canonical Correspondence Analysis revealed that the effects of altitude, such as temperature and rainfall, are the most significant large-scale drivers of vegetation patterns. Smaller scale drivers include wetness and soil nutrients including nitrogen, phosphorus, electrical conductivity, sodium, and organic content. The identification of indicator species served to reveal potentially important wetland species across different areas of the Great Escarpment. The effects of altitude on plant community patterns highlights the susceptibility of the high altitude specific communities to upward temperature zone shifts resulting from global warming. Other threats include livestock trampling, water extraction, and land use change for agricultural purposes. The relative absence of alien species in these wetlands gives an indication of their pristine condition and therefore their importance as a reference from which they may be monitored. A large proportion of the wetlands studied here occur outside protected areas, and given the rate of wetland loss in South Africa, it is important that continued effective land management is practiced to ensure that these ecosystems are conserved in the future .
- Full Text:
- Date Issued: 2015
Nanofiber immobilized cellulases and hemicellulases for fruit waste beneficiation
- Authors: Swart, Shanna
- Date: 2015
- Subjects: Agricultural wastes , Cellulase , Hemicellulose , Nanofibers , Electrospinning , Lignocellulose -- Biodegradation , Biomass conversion , Polysaccharides , Immobilized enzymes
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4153 , http://hdl.handle.net/10962/d1017914
- Full Text:
- Date Issued: 2015
Natural resource use as a coping and adaptation strategy to floods of vulnerable populations in the Eastern Cape
- Authors: Sachikonye, Mwazvita Tapiwa Beatrice
- Date: 2015
- Subjects: Flood damage prevention -- South Africa -- Eastern Cape , Natural resources -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape , Human ecology -- South Africa -- Eastern Cape , Nature -- Effect of human beings on -- South Africa -- Eastern Cape , Human beings -- Effect of environment on -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4786 , http://hdl.handle.net/10962/d1018194
- Description: Many of the anticipated increased occurances of natural hazards are not only a consequence of climate change, but rather of rapid and widespread land cover change and the subsequent loss of the buffering capacity provided by healthy ecosystems against natural hazards. Unplanned and unmanaged developments in informal settlements limit government’s ability to mitigate and manage, pointing towards natural resources as being integral for vulnerable communities in developing countries to cope with and mitigate flood disasters. There is a lack of understanding on how natural resources contribute to resilience of vulnerable populations in the Eastern Cape and how they are impacted by these populations before, during and after a flood shock. There also exists a gap in knowledge on how natural resources can mitigate the physical impacts of flooding in South Africa, more so in the Eastern Cape province. Using household questionnaires and GIS techniques, the strategies that households used to recover from the October 2012-February 2013 flood shocks were investigated in informal settlements of three towns (Grahamstown, Port Alfred and Port St Johns). Within the vulnerability paradigm and the sustainable livelihood framework, the study also quantified and evaluated the relative contribution of natural resources to recovery strategies, and lastly, the study investigated how patterns of land use, state of natural vegetation and household topographical location exacerbated or diminished the physical impacts of flooding. This study found that natural resources contributed up to 70 percent to recovery of households from the flood shock, most of this being to reconstruction of housing structures after the flood, less so to economic recovery. It was also found that at a settlement scale the buffering effect of vegetation, although variable amongst settlements, was significant. Settlements that were dominated by dense bush and small trees experienced up to 46 percent less impacts on their property than those surrounded by bare gravel and impervious roofs with degraded environments. The main findings of the research show that natural resources reduce the vulnerability of households in informal settlements to flooding in two significant ways; by physically mitigating against damage to shelters and by also providing an emergency-net function that substitutes financial capital in households. Their inclusion in disaster management has the potential to encourage the sustainable livelihoods of the urban poor in the Eastern Cape
- Full Text:
- Date Issued: 2015
Nonlinear optical studies of phthalocyanines and triazatetrabenzcorroles in solution and in thin films
- Authors: Mkhize, Nhlakanipho Colin
- Date: 2015
- Subjects: Phthalocyanines , Thin films , Nonlinear optics , Phosphorus
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4542 , http://hdl.handle.net/10962/d1017922
- Description: This work presents photophysical and nonlinear optical properties of a novel Cd 2,3-[octakis{4-tert-butylphenoxyphthalocyanine}] (CdOtBPPc) and compared with those of Pb 2,3-[octakis{4-tert-butylphenoxyphthalocyanine}] (PbOtBPPc). For both the CdOtBPPc and PbOtBPPc, third order imaginary susceptibility and second order hyperpolarizability values were found to be within the limit set for good optical limiters. The Pcs were embedded in poly (methyl methacrylate) (PMMA) and poly(bisphenol A carbonate) (PBC) as thin films. The optical limiting values of the Pcs once embedded in film were found to be greatly improved and the limiting intensity of each film was well below the maximum threshold. Both PbOtBPPc and CdOtBPPc showed better optical limiting when embedded in PBC compared to PMMA. CdOtBPPc shows better nonlinear optical behaviour than PbOtBPPc in solution and as thin films, even though the former is aggregated in solution. Novel phosphorus triazatetrabenzcorroles (TBC) tetrasubstituted at the α- and β- and octa substituted at the β- positions of the peripheral fused benzene rings with t-butylphenoxy substituents were prepared and characterized. The effects of the substituents and the missing aza-nitrogen on the electronic structures and optical spectroscopy are investigated with TD-DFT calculations and MCD spectroscopy. The optical limiting properties were investigated to examine whether the lower symmetry that results from the direct pyrrole-pyrrole bond and hence the permanent dipole moment that is introduced result in higher safety thresholds, relative to the values that have been reported for phthalocyanines. The suitability of the compounds for singlet oxygen applications has also been examined. Novel phosphorus phthalocyanines, analogous to the triazatetrabenzcorroles were also investigated. Due to their high photodegradation quantum yield however, only the fluorescence quantum yields and lifetimes were able to be determined.
- Full Text:
- Date Issued: 2015
On active layer processes and landforms in western Dronning Maud Land, Antarctica
- Authors: Scott, David Alan
- Date: 2015
- Subjects: Landforms -- Antarctica -- Queen Maud Land , Permafrost -- Antarctica -- Queen Maud Land , Permafrost -- Thermal properties -- Antarctica -- Queen Maud Land , Climatic changes -- Antarctica -- Queen Maud Land , Cryosphere , Drone aircraft -- Antarctica -- Queen Maud Land , 3-D modeling
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4893 , http://hdl.handle.net/10962/d1019757
- Description: Permafrost is a variable in Antarctic terrestrial ecosystems, and the role it plays in the cryosphere is not well understood. There is much still to be learnt about the thermal state, physical properties, thickness and age of permafrost in Western Dronning Maud Land (WDML). Active layer dynamics and observed change over time have the potential to improve our knowledge of climate change. Understanding the effects of a warming climate on permafrost can also be of benefit to infrastructure, especially in areas with a large amount of frozen ground such as Scandinavia, Canada and Russia. Active layer and permafrost dynamics of WDML, Antarctica, are presented and discussed using data from six study sites, namely the Robertskollen, Vesleskarvet, Flarjuven, Grunehogna, Slettjfell nunataks and the Troll research station in the Jutulsessen area. Ground and ambient air temperature, as well as ground moisture data were collected for each site. An inventory of active layer and permafrost landforms was compiled, as were the frequency of cycles over the zero-degree isotherm, and the depth of the active layer. Furthermore, 3D models, geo-referenced maps and Digital Elevation Models were created of study areas with the use of an Unmanned Aerial Vehicle (UAV). Polygonal features are the most common landscape feature and are common to most of the study sites. Robertskollen has the deepest active layer at over 66cm and Slettfjell the shallowest at 9cm. A maximum recorded air temperature of 8.76°C (10/11/2014) occurred at Troll with the second highest maximum of 6.77°C (22/12/2010) recorded at Vesleskarvet. Robertskollen has the highest observable biological growth and a maximum recorded ground temperature of 22.84°C (10/01/2014). Troll and Valterkulten, registered the second and third highest ground temperatures respectively. The high ground Temperature observed for Robertskollen may be ascribed to it being the lowest altitude site. The highest number of cycles over the zero-degree isotherm was observed at Troll (11.01%), followed by Robertskollen (10.99%). For relatively warm areas, such as Robertskollen it is recommended that two metre borehole loggers are installed in order to capture a detailed understanding of the active layer. The UAV proved to be a beneficial tool for capturing aerial photographs for post fieldwork analysis and 3D modelling.
- Full Text:
- Date Issued: 2015
Photo-physicochemical studies and photodynamic therapy activity of indium and gallium phthalocyanines
- Authors: Tshangana, Charmaine Sesethu
- Date: 2015
- Subjects: Quantum dots , Nanoparticles , Photochemotherapy , Phthalocyanines
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4548 , http://hdl.handle.net/10962/d1017928
- Description: The potential toxicity of seven different types of quantum dots without shell (L-cysteine-CdTe, TGA-CdTe, MPA-CdTe, TGA-CdSe) and with the shell (GSH-CdSe@ZnS, GSH-CdTe@ZnS,) with different capping agents were evaluated. The growth inhibitory effects of the various quantum dots on human pancreatic BON cancerous cells were determined. The least cytotoxic of the various quantum dots synthesized and the one displaying the lowest growth inhibitory potential and no embryotoxicity was determined to be the GSH-CdSe@ZnS quantum dots. The GSH-CdSe@ZnS quantum dots were then conjugated to gallium, aluminium and indium octacarboxy phthalocyanine and the photophysical behaviour of the conjugates studied for potential use in photodynamic therapy and imaging applications. The sizes, morphology, thermal stability and confirmation of successful conjugation was determined using X-ray diffraction (XRD), transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and Fourier transform infrared spectroscopy (FTIR), respectively. The study was extended by conjugating amino functionalized magnetic nanoparticles (Fe₃O₄) to indium octacarboxy phthalocyanine to study the photophysical behaviour of the conjugate as a potential bi-functional anti-cancer agent (hyperthermia and photodynamic therapy applications). A three-in-one multifunctional nanocomposite comprising of the quantum dots, magnetic nanoparticles and indium octacarboxy phthalocyanine was developed with the aim of developing a multifunctional composite that is able detect, monitor and treat cancer. All conjugates showed improved and enhanced photophysical behaviour. Finally, GSH-CdSe@ZnS conjugated to aluminium octacarboxy phthalocyanine was applied in human pancreatic carcinoid BON cells. The conjugates induced cell death dose-dependently.
- Full Text:
- Date Issued: 2015
Photodynamic antimicrobial chemotherapy activities of porphyrin- and phthalocyanine-platinum nanoparticle conjugates
- Authors: Managa, Muthumuni Elizabeth
- Date: 2015
- Subjects: Photochemotherapy , Anti-infective agents , Porphyrins , Phthalocyanines , Platinum , Nanoparticles , Bioconjugates , Electrospinning
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4539 , http://hdl.handle.net/10962/d1017919
- Description: This work reports on the conjugation of differently shaped Pt nanoparticles (PtNPs) with ClGa(III) 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin (1) as well as chloro - (5,10,15,20-tetrakis (4- (4- carboxy phenycarbonoimidoyl) phenyl) porphyrinato) gallium(III) (2) The work also reports on platination of dihydroxosilicon octacarboxyphthalocyanine (OH)₂SiOCPc (3) to give dihydroxosilicontris(diaquaplatinum)octacarboxyphthalocyanine (OH)₂SiOCPc(Pt)₃ (4). The resulting conjugates were used for photodynamic antimicrobial chemotherapy against S. aureus, E. coli and C. albicans. The degree of photo-inactivation is dependent on concentration of the conjugates, light dose (fluence) and illumination time. The log reduction obtained for 1 when conjugated to cubic PtNPs was 4.64 log (which indicate 99.99 percent of the bacteria have been killed), which is much higher than 3.94 log unit for 1-hexagonal PtNPs and 3.31 log units for 1-unshaped PtNPs. Complex 2 conjugated to hexagonal PtNPs showed 18 nm red shift in the Soret band when compared to 2 alone. Complex 2 and 2-hexagonal PtNPs as well showed promising photodynamic antimicrobial chemotherapy (PACT) activity against S. aureus, E. coli and C. albicans in solution where the log reduction obtained was 4.92, 3.76, and 3.95 respectively for 2-hexagonal PtNPs. The singlet oxygen quantum yields obtained were higher at 0.56 for 2-hexagonl PtNPs in DMF while that of 2 was 0.52 in the same solvent. This resulted in improved PACT activity for 2-hexagonal PtNPs compared to 2. Complex 4 showed slight blue shifting of the absorption spectrum when compared to complex 3 The antimicrobial activity of 4 were promising as the highest log reduction value was observed when compared to the porphyrin conjugates.
- Full Text:
- Date Issued: 2015
Population estimates and spatial ecology of brown hyaenas in Kwandwe private game reserve
- Authors: Welch, Rebecca Jane
- Date: 2015
- Subjects: Brown hyaena -- Reintroduction -- South Africa , Kwandwe Private Game Reserve
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5932 , http://hdl.handle.net/10962/d1017810
- Description: During the last 25 years, the Eastern Cape Province of South Africa has seen the establishment of many small to medium sized (≤ 440km2) game reserves. These reserves have reintroduced many of the larger indigenous wildlife that had been extirpated by the early 20th century. As such, these reserves and wildlife introductions have created many research opportunities, including investigations on the ecology of reintroduced carnivores in the Thicket biome. Brown hyaenas (Hyaena brunnea) are one of the large carnivore species that have been reintroduced into the area. As these animals have predominantly been studied in more open, arid systems, their reintroduction has provided an excellent opportunity to study the species in an alternate natural habitat. Information gathered from such investigations adds to our knowledge of the species and also provides information for the management of brown hyaenas within small, enclosed reserves. Data were collected over the period of one calendaryear, from February 2013 to February 2014 at Kwandwe Private Game Reserve in the Eastern Cape, South Africa. Brown hyaena population estimates were calculated using capture-recapture methods from individually identifiable images captured during a three month camera trapping survey. Images of brown hyaenas were separated into left- and right-side profiles. Twenty-eight individuals were positively identified from left-side images and 27 from right-side images. Non-spatial and spatially explicit capture-recapture analyses were both run in the program DENSITY 5.0. Density estimates ranged from 14 to 20 individuals/100km2 (equivalent to a total abundance of 26-37 individuals) depending on the method used. Despite the range of estimates, all are considerably higher than in other areaswhere densities have been calculated. Satellite/GPS collars were fitted to three individual brown hyaenas (two males and one female) to measure their home range size and use of space. Home range size was calculated using two different methods, Kernel utilisation distributions and Brownian bridges. Home range estimates were similar using both methods; however Brownian bridge methods appeared to exaggerate the use of space by individuals. Kernel home range sizes for the three individuals ranged between 42.62km2 and 79.88km2. These estimates are considerably smaller than previous findings from other parts of Africa and suggest that sufficient resources may be available within this enclosed system. The results from this study suggest that brown hyaenas are successful generalists in this enclosed system and are able to persist at high densities and occupy relatively small home ranges. This information is important for the managers of small reserves who wish to reintroduce brown hyaenas. Should brown hyaenas be introduced into reserves in the Thicket biome with sufficient resources, the numbers are likely to increase rapidly. If high numbers are not desired then preventative measures (e.g. contraception) should be investigated before release.
- Full Text:
- Date Issued: 2015
Post-treatment technologies for integrated algal pond systems
- Authors: Westensee, Dirk Karl
- Date: 2015
- Subjects: Sewage disposal plants -- South Africa -- Grahamstown , Water -- Purification -- Filtration , Water -- Purification -- Slow sand filtration , Sewage -- Purification -- Anaerobic treatment , Sewage -- Purification -- Biological treatment , Algae -- Biotechnology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5958 , http://hdl.handle.net/10962/d1018180
- Description: Integrated Algae Pond Systems (IAPS) are a derivation of the Oswald designed Algal Integrated Wastewater Pond Systems (AIWPS®) and combine the use of anaerobic and aerobic bioprocesses to effect wastewater treatment. IAPS technology was introduced to South Africa in 1996 and a pilot plant designed and commissioned at the Belmont Valley WWTW in Grahamstown. The system has been in continual use since implementation and affords a secondarily treated water for reclamation according to its design specifications which most closely resemble those of the AIWPS® Advanced Secondary Process developed by Oswald. As a consequence, and as might be expected, while the technology performed well and delivered a final effluent superior to most pond systems deployed in South Africa it was unable to meet The Department of Water Affairs General Standard for nutrient removal and effluent discharge. The work described in this thesis involved the design, construction, and evaluation of several tertiary treatment units (TTU') for incorporation into the IAPS process design. Included were; Maturation Ponds (MP), Slow Sand Filter (SSF) and Rock Filters (RF). Three MP's were constructed in series with a 12 day retention time and operated in parallel with a two-layered SSF and a three-stage RF. Water quality of the effluent emerging from each of these TTU's was monitored over a 10 month period. Significant decreases in the chemical oxygen demand (COD), ammonium-N, phosphate-P, nitrate-N, faecal coliforms (FC) and total coliforms (TC) were achieved by these TTU's. On average, throughout the testing period, water quality was within the statutory limit for discharge to a water course that is not a listed water course, with the exception of the total suspended solids (TSS). The RF was determined as the most suitable TTU for commercial use due to production of a better quality water, smaller footprint, lower construction costs and less maintenance required. From the results of this investigation it is concluded that commercial deployment of IAPS for the treatment of municipal sewage requires the inclusion of a suitable TTU. Furthermore, and based on the findings presented, RF appears most appropriate to ensure that quality of the final effluent meets the standard for discharge.
- Full Text:
- Date Issued: 2015
Prediction of interacting motifs within the protein subunits of Picornavirus capsids
- Authors: Ross, Caroline Jane
- Date: 2015
- Subjects: Picornaviruses , Antiviral agents , Poliovirus , Coxsackieviruses , Hepatitis A virus , Foot-and-mouth disease virus , Viral proteins
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4151 , http://hdl.handle.net/10962/d1017912
- Description: The Picornaviridae family contains a number of pathogens which are economically important including Poliovirus, Coxsakievirus, Hepatitis A Virus, and Foot-and-Mouth-Disease-Virus. Recently the emergence of novel picornaviruses associated with gastrointestinal, neurological and respiratory diseases in humans has been reported. Although effective vaccines for viruses such as FMDV, PV and HAV have been developed there are currently no antivirals available for the treatment of picornavirus infections. Picornaviruses proteins are classified as: the structural proteins VP1, VP2, VP3 and VP4 which form the subunits of the viral capsid and the replication proteins which function as proteases, RNA-polymerases, primers and membrane binding proteins. Although the host specificity and viral pathogenicity varies across members of the family, the icosahedral capsid is highly conserved. The capsid consists of 60 protomers, each containing a single copy of VP1, VP2 and VP3. A fourth capsid protein, VP4, resides on the internal side of the capsid. Capsid assembly is integral to life-cycle of picornaviruses; however the process is complex and not fully-understood. The overall aim of the study was to broaden the understanding of the evolution and function of the structural proteins across the Picornaviridae family. Firstly a comprehensive analysis of the phylogenetic relationships amongst the individual structural proteins was performed. The functions of the structural proteins were further investigated by an exhaustive motif analysis. A subsequent structural analysis of highly conserved motifs was performed with respect to representative enteroviruses, Foot-and-Mouth-Disease-Virus and Theiler’s Virus. This was supplemented by the in silico prediction of interacting residues within the crystal structures of these protomers. Findings in this study suggest that the capsid proteins may be evolving independently from the replication proteins through possible inter-typic recombination of functional protein regions. Moreover the study predicts that protomer assembly may be facilitated through a network of multiple subunit-subunit interactions. Multiple conserved motifs and principle residues predicted to facilitate capsid subunit-subunit interactions were identified. It was also concluded that motif conservation may support the theory of inter-typic recombination between closely related virus sub-types. As capsid assembly is critical to the viral life-cycle, the principle interacting motifs may serve as novel drug targets for the antiviral treatment of picornavirus infections. Thus the findings in the study may be fundamental to the development of treatments which are more economically feasible or clinically effective than current vaccinations.
- Full Text:
- Date Issued: 2015
Properties of traveling ionospheric disturbances (TIDs) over the Western Cape, South Africa
- Authors: Tyalimpi, Vumile Mike
- Date: 2015
- Subjects: Doppler radar , Geographic information systems , Traveling ionospheric disturbances -- south Africa , Ionospheric disturbances -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5557 , http://hdl.handle.net/10962/d1017901
- Description: Travelling Ionospheric Disturbances (TIDs) are said to be produced by atmospheric gravitational waves propagating through the neutral ionosphere. These are smaller in amplitude and period when compared to most ionospheric disturbances and hence more difficult to measure. Very little is known about the properties of the travelling ionospheric disturbances (TIDs) over the Southern Hemisphere regions since studies have been conducted mostly over the Northern Hemisphere regions. This study presents a framework, using a High Frequency (HF) Doppler radar to investigate the physical properties and the possible driving mechanisms of TIDs. This research focuses on studying the characteristics of the TIDs, such as period, velocity and temporal variations, using HF Doppler measurements taken in South Africa. By making use of a Wavelet Analysis technique, the TIDs’ characteristics were determined. A statistical summary on speed and direction of propagation of the observed TIDs was performed. The winter medium scale travelling ionospheric disturbances (MSTIDs) observed are generally faster than the summer MSTIDs. For all seasons, the MSTIDs had a preferred south-southwest direction of propagation. Most of the large scale travelling ionospheric disturbances (LSTIDs) were observed during the night and of these, the spring LSTIDs were fastest when compared to autumn and summer LSTIDs. The general direction of travel of the observed LSTIDs is south-southeast. Total Electron Content (TEC), derived from Global Positioning System (GPS) measurements, were used to validate some of the TID results obtained from the HF Doppler data. The Horizontal Wind Model (HWM07), magnetic K index, and solar terminators were used to determine the possible sources of the observed TIDs. Only 41% of the observed TIDs were successfully linked to their possible sources of excitation. The information gathered from this study will be valuable in future radio communications and will serve as means to improve the existing ionospheric models over the South African region.
- Full Text:
- Date Issued: 2015
Pseudo-random access compressed archive for security log data
- Authors: Radley, Johannes Jurgens
- Date: 2015
- Subjects: Computer security , Information storage and retrieval systems , Data compression (Computer science)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4723 , http://hdl.handle.net/10962/d1020019
- Description: We are surrounded by an increasing number of devices and applications that produce a huge quantity of machine generated data. Almost all the machine data contains some element of security information that can be used to discover, monitor and investigate security events.The work proposes a pseudo-random access compressed storage method for log data to be used with an information retrieval system that in turn provides the ability to search and correlate log data and the corresponding events. We explain the method for converting log files into distinct events and storing the events in a compressed file. This yields an entry identifier for each log entry that provides a pointer that can be used by indexing methods. The research also evaluates the compression performance penalties encountered by using this storage system, including decreased compression ratio, as well as increased compression and decompression times.
- Full Text:
- Date Issued: 2015
PyMORESANE: A Pythonic and CUDA-accelerated implementation of the MORESANE deconvolution algorithm
- Authors: Kenyon, Jonathan
- Date: 2015
- Subjects: Radio astronomy , Imaging systems in astronomy , MOdel REconstruction by Synthesis-ANalysis Estimators (MORESANE)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5563 , http://hdl.handle.net/10962/d1020098
- Description: The inadequacies of the current generation of deconvolution algorithms are rapidly becoming apparent as new, more sensitive radio interferometers are constructed. In light of these inadequacies, there is renewed interest in the field of deconvolution. Many new algorithms are being developed using the mathematical framework of compressed sensing. One such technique, MORESANE, has recently been shown to be a powerful tool for the recovery of faint difuse emission from synthetic and simulated data. However, the original implementation is not well-suited to large problem sizes due to its computational complexity. Additionally, its use of proprietary software prevents it from being freely distributed and used. This has motivated the development of a freely available Python implementation, PyMORESANE. This thesis describes the implementation of PyMORESANE as well as its subsequent augmentation with MPU and GPGPU code. These additions accelerate the algorithm and thus make it competitive with its legacy counterparts. The acceleration of the algorithm is verified by means of benchmarking tests for varying image size and complexity. Additionally, PyMORESANE is shown to work not only on synthetic data, but on real observational data. This verification means that the MORESANE algorithm, and consequently the PyMORESANE implementation, can be added to the current arsenal of deconvolution tools.
- Full Text:
- Date Issued: 2015
Regolith mapping and gold geochemical anomalies in the Siguiri Gold Mine of AngloGold Ashanti, Guinea, West Africa
- Authors: Bah, Boubacar
- Date: 2015
- Subjects: AngloGold Ashanti Ltd. , Regolith -- Guinea -- Siguiri (Region) , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Soil surveys -- Geochemical methods -- Guinea -- Siguiri (Region) , Kriging
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5090 , http://hdl.handle.net/10962/d1019878
- Description: Gold exploration in the laterite terrains of the Siguiri basin (Guinea-West Africa) is discussed in this thesis. It seeks to propose and develop effective and reliable geochemical exploration techniques applied in such laterite terrains. The study is also intended to investigate and provide some geological clues as to why, in some target areas, the reconnaissance test drilling across the geochemical anomalies couldn’t intersect economic gold mineralisation. Targets were generated based on soil geochemical results, some of which were drilled without delivering economic discoveries even on areas with strong and consistent geochemical signatures. To find the failure and define the appropriate methods to be used is the core of the thesis. More importantly, the geological observation is aimed at sourcing and establishing the nature and validity of geochemical anomalies within the license area and their relationship with the underlying lithologies and structural networks. The geological field work conducted during this study is mostly based on regolith and surface geological mapping. The thick laterite cover, deep weathering, bedrock geology, gold geochemistry (the gold geochemical anomalous results are defined according to historical data before 2007), soil formations and variations in climate conditions are emphasized to illustrate the importance of mineral element mobility and dispersion in the weathering profiles. The knowledge and experience in regolith geochemistry and regolith mapping provide the advantage to exploration geologists. The depletion of ore resources and reserves in Siguiri and the continuous decline of the gold price in comparison to the complexity of exploring for gold are demanding more scientific-related thoughts and techniques to be integrated in the available geological, geochemical and geophysical information so as to reduce costs. The integration of good exploration strategy and technique may result in the possibility of making viable discoveries in this highly competitive geological environment where the mineral resources become depleted every day.
- Full Text:
- Date Issued: 2015
Short-term changes to the life history of shad, Pomatomus saltatrix (Perciformes: Pomatomidae), in Southern Angola
- Authors: Bealey, Roy Steven John
- Date: 2015
- Subjects: Shad -- Angola , Bluefish -- Angola , Bluefish -- Climatic factors -- Angola , Bluefish -- Effect of temperature on -- Angola , Bluefish -- Effect of global warming on -- Angola , Bluefish -- Effect of fishing on -- Angola , Bluefish -- Life cycles , Pomatomidae -- Angola , Fishery management -- Angola , Climatic changes -- Angola
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5379 , http://hdl.handle.net/10962/d1017211
- Description: A general lack of biological information is hampering the effective management of Angola’s fisheries. While this lack of information is largely a result of the country’s extended civil war that ended in 2002, the subsequent rapid expansion of fisheries is most likely impacting fish abundance and influencing the biology of this regions fishes. Besides the influence of fisheries, the southern Angolan coastal region is considered to be a climate change “hotspot” due to rapidly (>0.8°C/decade) increasing water temperatures. These changes are thought to drive further changes to the biology of fishes. It is therefore critical to provide baseline biological information and to identify the impacts of exploitation and warming on the biology of southern Angolan fishes. Pomatomus saltatrix is a warm-temperate marine fish species that forms an important component of fisheries throughout its broad distribution. P. saltatrix is a migratory predator that displays variable growth and maturity schedules. Typically it is heavily targeted in a range of coastal fisheries of Angola and is therefore an ideal candidate to study the biological impacts of exploitation and climate change. The aim of this study was to provide the first description of P. saltatrix biology in Angola and examine recent changes of the species biological parameters in an attempt to uncouple fishery driven from climate driven changes. Samples of P. saltatrix were collected monthly using standardised biological methods from June 2005 to December 2006 (period 1) and from June 2012 to February 2013 (period 2). The average (508mm – 1st period, 462mm – 2nd period) and maximum (760mm – 1st period, 746mm – 2nd period) size of P. saltatrix was smaller during the second period to suggest selective overharvesting of large individuals by developing fisheries. Angolan P. saltatrix grew very rapidly in their first year and thereafter, relatively slowly when compared to other populations globally. However, fish grew faster (ω = 103 – 1st period, ω = 124 – 2nd period), matured at a larger size (303mm - 1st period, 336mm - 2nd period) and younger age (0.83 years - 1st period, 0.67 years – 2nd period) during the second period. Peaks in reproductive activity remained similar (November) during both periods but a temperature anomaly appears to have influenced spawning during period 2. Sardinella aurita was the dominant prey during both periods but a greater dependence upon mugilids was observed during the second period. Although the changes in life history were not statistically significant, the faster growth observed during period two could be attributed to both increasing temperature and/or exploitation. Fishes generally grow faster, mature smaller and attain a smaller maximum size in warmer temperatures. Fisheries targeting small and large specimens of a species (as observed in this study) largely have the same impacts as ocean warming. With rapidly increasing water temperatures and exploitation rates, faster growth and earlier maturation of P. saltatrix populations will mitigate the impacts of exploitation in the short-term. However, the sustainability of Angola’s P. saltatrix stock is questionable as phenotypic adaptation will have a limited thermal scope and overexploitation will, like in all fisheries, negatively influence recruitment. Ultimately, strict monitoring, regulation and control will be necessary to ensure the sustainability of the P. saltatrix resource in Angola as it continues to face increasing anthropogenic and environmental pressures. Management guidelines and future research suggestions are therefore outlined with reference to the results of analyses conducted during this study.
- Full Text:
- Date Issued: 2015
Statistical analysis of the ionospheric response during storm conditions over South Africa using ionosonde and GPS data
- Authors: Matamba, Tshimangadzo Merline
- Date: 2015
- Subjects: Ionospheric storms -- South Africa -- Grahamstown , Ionospheric storms -- South Africa -- Madimbo , Magnetic storms -- South Africa -- Grahamstown , Magnetic storms -- South Africa -- Madimbo , Ionosondes , Global Positioning System
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5555 , http://hdl.handle.net/10962/d1017899
- Description: Ionospheric storms are an extreme form of space weather phenomena which affect space- and ground-based technological systems. Extreme solar activity may give rise to Coronal Mass Ejections (CME) and solar flares that may result in ionospheric storms. This thesis reports on a statistical analysis of the ionospheric response over the ionosonde stations Grahamstown (33.3◦S, 26.5◦E) and Madimbo (22.4◦S,30.9◦E), South Africa, during geomagnetic storm conditions which occurred during the period 1996 - 2011. Total Electron Content (TEC) derived from Global Positioning System (GPS) data by a dual Frequency receiver and an ionosonde at Grahamstown, was analysed for the storms that occurred during the period 2006 - 2011. A comprehensive analysis of the critical frequency of the F2 layer (foF2) and TEC was done. To identify the geomagnetically disturbed conditions the Disturbance storm time (Dst) index with a storm criteria of Dst ≤ −50 nT was used. The ionospheric disturbances were categorized into three responses, namely single disturbance, double disturbance and not significant (NS) ionospheric storms. Single disturbance ionospheric storms refer to positive (P) and negative (N) ionospheric storms observed separately, while double disturbance storms refer to negative and positive ionospheric storms observed during the same storm period. The statistics show the impact of geomagnetic storms on the ionosphere and indicate that negative ionospheric effects follow the solar cycle. In general, only a few ionospheric storms (0.11%) were observed during solar minimum. Positive ionospheric storms occurred most frequently (47.54%) during the declining phase of solar cycle 23. Seasonally, negative ionospheric storms occurred mostly during the summer (63.24%), while positive ionospheric storms occurred frequently during the winter (53.62%). An important finding is that only negative ionospheric storms were observed during great geomagnetic storm activity (Dst ≤ −350 nT). For periods when both ionosonde and GPS was available, the two data sets indicated similar ionospheric responses. Hence, GPS data can be used to effectively identify the ionospheric response in the absence of ionosonde data.
- Full Text:
- Date Issued: 2015