Information technology audits in South African higher education institutions
- Authors: Angus, Lynne
- Date: 2013 , 2013-09-11
- Subjects: Electronic data processing -- Auditing , Delphi method , Education, Higher -- Computer networks -- Security measures , Information technology -- Security measures , COBIT (Information technology management standard) , IT infrastructure library , International Organization for Standardization
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4615 , http://hdl.handle.net/10962/d1006023 , Electronic data processing -- Auditing , Delphi method , Education, Higher -- Computer networks -- Security measures , Information technology -- Security measures , COBIT (Information technology management standard) , IT infrastructure library , International Organization for Standardization
- Description: The use of technology for competitive advantage has become a necessity, not only for corporate organisations, but for higher education institutions (HEIs) as well. Consequently, corporate organisations and HEIs alike must be equipped to protect against the pervasive nature of technology. To do this, they implement controls and undergo audits to ensure these controls are implemented correctly. Although HEIs are a different kind of entity to corporate organisations, HEI information technology (IT) audits are based on the same criteria as those for corporate organisations. The primary aim of this research, therefore, was to develop a set of IT control criteria that are relevant to be tested in IT audits for South African HEIs. The research method used was the Delphi technique. Data was collected, analysed, and used as feedback on which to progress to the next round of data collection. Two lists were obtained: a list of the top IT controls relevant to be tested at any organisation, and a list of the top IT controls relevant to be tested at a South African HEI. Comparison of the two lists shows that although there are some differences in the ranking of criteria used to audit corporate organisations as opposed to HEIs, the final two lists of criteria do not differ significantly. Therefore, it was shown that the same broad IT controls are required to be tested in an IT audit for a South African HEI. However, this research suggests that the risk weighting put on particular IT controls should possibly differ for HEIs, as HEIs face differing IT risks. If further studies can be established which cater for more specific controls, then the combined effect of this study and future ones will be a valuable contribution to knowledge for IT audits in a South African higher education context.
- Full Text:
- Date Issued: 2013
- Authors: Angus, Lynne
- Date: 2013 , 2013-09-11
- Subjects: Electronic data processing -- Auditing , Delphi method , Education, Higher -- Computer networks -- Security measures , Information technology -- Security measures , COBIT (Information technology management standard) , IT infrastructure library , International Organization for Standardization
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4615 , http://hdl.handle.net/10962/d1006023 , Electronic data processing -- Auditing , Delphi method , Education, Higher -- Computer networks -- Security measures , Information technology -- Security measures , COBIT (Information technology management standard) , IT infrastructure library , International Organization for Standardization
- Description: The use of technology for competitive advantage has become a necessity, not only for corporate organisations, but for higher education institutions (HEIs) as well. Consequently, corporate organisations and HEIs alike must be equipped to protect against the pervasive nature of technology. To do this, they implement controls and undergo audits to ensure these controls are implemented correctly. Although HEIs are a different kind of entity to corporate organisations, HEI information technology (IT) audits are based on the same criteria as those for corporate organisations. The primary aim of this research, therefore, was to develop a set of IT control criteria that are relevant to be tested in IT audits for South African HEIs. The research method used was the Delphi technique. Data was collected, analysed, and used as feedback on which to progress to the next round of data collection. Two lists were obtained: a list of the top IT controls relevant to be tested at any organisation, and a list of the top IT controls relevant to be tested at a South African HEI. Comparison of the two lists shows that although there are some differences in the ranking of criteria used to audit corporate organisations as opposed to HEIs, the final two lists of criteria do not differ significantly. Therefore, it was shown that the same broad IT controls are required to be tested in an IT audit for a South African HEI. However, this research suggests that the risk weighting put on particular IT controls should possibly differ for HEIs, as HEIs face differing IT risks. If further studies can be established which cater for more specific controls, then the combined effect of this study and future ones will be a valuable contribution to knowledge for IT audits in a South African higher education context.
- Full Text:
- Date Issued: 2013
Interaction of metallic nanoparticles with biomedical enzyme target: neuronal nitric oxide synthase
- Authors: Ngqwala, Nosiphiwe Patience
- Date: 2013
- Subjects: Nitric-oxide synthase Alzheimer's disease Arginine Nanoparticles Biochemical markers Biochemical markers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3875 , http://hdl.handle.net/10962/d1001536
- Description: Alzheimer's disease (AD) is the most common type of dementia characterized by intracellular appearance of neurofibrillary tangles, synaptic and neuronal loss; and extracellular accumulation of amyloid-β (Aβ) peptide in senile plaques. The initial causes leading to AD are unknown, and the available treatments are only effective at slowing the degeneration process. The accumulation of arginine in the brain of Alzheimer patients indicates a possible disruption of enzymes responsible for its metabolism. One such enzyme is neuronal nitric oxide synthase (nNOS) and controlling its activity by interacting with nanoparticles may lead to a delay in the onset of the disease. Neuronal nitric oxide synthase was purified using DEAE-Sephacel ion exchange resulting in 10 % yield, 0.43 fold recovery and specific activity 0.09 U/mg. The enzyme was found to be a dimer with a molecular mass of 150 kDa. Characterisation of the nNOS showed an optimum temperature and pH of 50°C and 7.5 respectively, and it was relatively stable at the optimum conditions (t½ = 100 min). The purity was analysed by SDS-PAGE followed by Western blot. Purified nNOS was challenged with 3-7 nm silver and 4-15 nm gold nanoparticles of between synthesized chemical using AgNO3 and either sodium borohydride or sodium citrate. Results showed that gold nanoparticles are more effective at low concentration (5 μM) than silver nanoparticles due to their size difference. Incubation of different concentration of nanoparticles (5, 15, 25, 50 μM) with the purified nNOS showed an initial decrease of 5% in enzyme activity which over time was restored to 80%. This suggests that different nanoparticles are produced in different sizes and interaction over a given time may result in enzyme association–dissociation mechanism. Inhibition studies showed a strong binding of both nanoparticles with Ki values of 1.4 μM and 0.2 μM for silver and gold, respectively. Both nanoparticles inhibited the activity of nNOS extensively as they bound strongly to the inhibition site on the enzyme and were more in contact with fluorophores nanoparticles. This was confirmed by fluorimetry with binding constants of 0.0084 μM and 0.01092 μM for silver and gold, respectively. Results of this study suggest that silver and gold nanoparticles competitively inhibit nNOS.
- Full Text:
- Date Issued: 2013
- Authors: Ngqwala, Nosiphiwe Patience
- Date: 2013
- Subjects: Nitric-oxide synthase Alzheimer's disease Arginine Nanoparticles Biochemical markers Biochemical markers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3875 , http://hdl.handle.net/10962/d1001536
- Description: Alzheimer's disease (AD) is the most common type of dementia characterized by intracellular appearance of neurofibrillary tangles, synaptic and neuronal loss; and extracellular accumulation of amyloid-β (Aβ) peptide in senile plaques. The initial causes leading to AD are unknown, and the available treatments are only effective at slowing the degeneration process. The accumulation of arginine in the brain of Alzheimer patients indicates a possible disruption of enzymes responsible for its metabolism. One such enzyme is neuronal nitric oxide synthase (nNOS) and controlling its activity by interacting with nanoparticles may lead to a delay in the onset of the disease. Neuronal nitric oxide synthase was purified using DEAE-Sephacel ion exchange resulting in 10 % yield, 0.43 fold recovery and specific activity 0.09 U/mg. The enzyme was found to be a dimer with a molecular mass of 150 kDa. Characterisation of the nNOS showed an optimum temperature and pH of 50°C and 7.5 respectively, and it was relatively stable at the optimum conditions (t½ = 100 min). The purity was analysed by SDS-PAGE followed by Western blot. Purified nNOS was challenged with 3-7 nm silver and 4-15 nm gold nanoparticles of between synthesized chemical using AgNO3 and either sodium borohydride or sodium citrate. Results showed that gold nanoparticles are more effective at low concentration (5 μM) than silver nanoparticles due to their size difference. Incubation of different concentration of nanoparticles (5, 15, 25, 50 μM) with the purified nNOS showed an initial decrease of 5% in enzyme activity which over time was restored to 80%. This suggests that different nanoparticles are produced in different sizes and interaction over a given time may result in enzyme association–dissociation mechanism. Inhibition studies showed a strong binding of both nanoparticles with Ki values of 1.4 μM and 0.2 μM for silver and gold, respectively. Both nanoparticles inhibited the activity of nNOS extensively as they bound strongly to the inhibition site on the enzyme and were more in contact with fluorophores nanoparticles. This was confirmed by fluorimetry with binding constants of 0.0084 μM and 0.01092 μM for silver and gold, respectively. Results of this study suggest that silver and gold nanoparticles competitively inhibit nNOS.
- Full Text:
- Date Issued: 2013
Interactions of arbuscular mycorrhizal fungi and spore-associated bacteria
- Authors: Ridsdale, Carmen Jane
- Date: 2013
- Subjects: Mycorrhizal fungi , Host plants , Bacteria
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4159 , http://hdl.handle.net/10962/d1018269
- Description: Arbuscular mycorrhizal (AM) fungi are naturally occurring in roots of terrestrial plants. AM fungi are capable of benefiting the host plant through various mechanisms such as enhanced nutrient supply, alleviation of environmental stress and inhibition of plant fungal pathogens. AM fungal spore-associated bacteria have been previously isolated and shown to have plant growthpromoting (PGP) abilities by several authors. Some bacterial isolates are able to promote AM fungal colonisation of host plants and are known to be mycorrhizal helper bacteria (MHB). This study focused on the isolation of AM fungal spore-associated bacteria, characterization of the isolates according to plant growth promoting abilities and evaluation of their potential to enhance plant growth and mycorrhizal colonisation. AM fungi were extracted from soils sampled from natural indigenous forest sources, raspberry (Rubus idaeus cv. Heritage) and strawberry (Fragaria ananassa) farms in South Africa and from a raspberry (Rubus idaeus cv. Autumn Bliss) plantation in Argentina. A total of 52 sporeassociated bacteria were isolated from the external and internal surfaces of AM fungal spore morphotypes from the two countries. The bacterial isolates were evaluated for their PGP abilities such as phosphate solubilisation, indole-3-acetic acid production, ammonia production and inhibition of the fungal pathogens Fusarium oxysporum and Phythophthora nicotianae through mechanisms such as siderophore and/ or hydrolytic enzyme production. A total of 23 bacterial isolates from both South Africa and Argentina showing the most potential to be PGP, were identified molecularly as belonging to the genera Acinetobacter, Alcaligenes, Bacillus, Microbacterium, Micrococcus, Serratia and Staphylococcus. The ability of ten selected bacterial isolates showing multiple PGP capacity were evaluated for their plant growth promotion and mycorrhizal colonisation enhancement ability on raspberry (Rubus idaeus cv. Meeker). Significant differences in increased shoot and root dry weights were shown by the treatments compared to the uninoculated control. The highest increase in shoot and root dry weights were shown by South African (Bacillus mycoides) and Argentinean (Alcaligenes faecalis) isolates. AM fungal colonisation was significantly enhanced by the South African (Bacillus mycoides) and Argentinean (Micrococcus luteus) isolates compared to the AM fungal singly inoculated control.
- Full Text:
- Date Issued: 2013
- Authors: Ridsdale, Carmen Jane
- Date: 2013
- Subjects: Mycorrhizal fungi , Host plants , Bacteria
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4159 , http://hdl.handle.net/10962/d1018269
- Description: Arbuscular mycorrhizal (AM) fungi are naturally occurring in roots of terrestrial plants. AM fungi are capable of benefiting the host plant through various mechanisms such as enhanced nutrient supply, alleviation of environmental stress and inhibition of plant fungal pathogens. AM fungal spore-associated bacteria have been previously isolated and shown to have plant growthpromoting (PGP) abilities by several authors. Some bacterial isolates are able to promote AM fungal colonisation of host plants and are known to be mycorrhizal helper bacteria (MHB). This study focused on the isolation of AM fungal spore-associated bacteria, characterization of the isolates according to plant growth promoting abilities and evaluation of their potential to enhance plant growth and mycorrhizal colonisation. AM fungi were extracted from soils sampled from natural indigenous forest sources, raspberry (Rubus idaeus cv. Heritage) and strawberry (Fragaria ananassa) farms in South Africa and from a raspberry (Rubus idaeus cv. Autumn Bliss) plantation in Argentina. A total of 52 sporeassociated bacteria were isolated from the external and internal surfaces of AM fungal spore morphotypes from the two countries. The bacterial isolates were evaluated for their PGP abilities such as phosphate solubilisation, indole-3-acetic acid production, ammonia production and inhibition of the fungal pathogens Fusarium oxysporum and Phythophthora nicotianae through mechanisms such as siderophore and/ or hydrolytic enzyme production. A total of 23 bacterial isolates from both South Africa and Argentina showing the most potential to be PGP, were identified molecularly as belonging to the genera Acinetobacter, Alcaligenes, Bacillus, Microbacterium, Micrococcus, Serratia and Staphylococcus. The ability of ten selected bacterial isolates showing multiple PGP capacity were evaluated for their plant growth promotion and mycorrhizal colonisation enhancement ability on raspberry (Rubus idaeus cv. Meeker). Significant differences in increased shoot and root dry weights were shown by the treatments compared to the uninoculated control. The highest increase in shoot and root dry weights were shown by South African (Bacillus mycoides) and Argentinean (Alcaligenes faecalis) isolates. AM fungal colonisation was significantly enhanced by the South African (Bacillus mycoides) and Argentinean (Micrococcus luteus) isolates compared to the AM fungal singly inoculated control.
- Full Text:
- Date Issued: 2013
International joint ventures and firm value: an empirical study of South African partner firms
- Mangwengwende, Tadiwanashe Mukudzeyi
- Authors: Mangwengwende, Tadiwanashe Mukudzeyi
- Date: 2013
- Subjects: Joint ventures Joint ventures -- South Africa Business enterprises -- Valuation International business enterprises
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1033 , http://hdl.handle.net/10962/d1004174
- Description: This study investigates international equity joint ventures (IJVs) and South African partner firm value creation at formation. In addition, it tests whether four contentious formation characteristics, namely, the geographical location of the IJV partner, the level of economic development in the IJV partner’s home country, the level of equity held by the South African firm and the industry of the South African firm, can explain when South African IJVs are value enhancing and when they are value diminishing. IJVs are a popular business mode and an important channel for infrastructure and skills investment in developing countries. However, despite their popularity and potential social benefits, these IJVs are predominantly created by the decisions of private firms to collaborate with foreign firms and governments. Consequently the preservation and development of the IJV investment channel is dependent on the encouragement of private firm IJV participation. It is at uncovering potential tools to encourage IJV participation by South African firms that IJV firm value creation becomes important because it stands as a motivator for South African firms’ involvement in IJVs. Existing literature on IJVs and partner firm value has presented conflicting evidence with support for the views that they are value enhancing, value diminishing or of no immediate consequence to their partners’ firm value. Consequently, previous research offers limited firm value support for IJVs. For South African firms considering joint ventures and national policy makers determined to promote IJVs there is a need for an investigation of South African partner IJV firm value effects. Moreover, it is also necessary to test potential explanatory variables that may help to explain when the IJVs are value enhancing and when they are not as this will inform IJV contract negotiations and how limited national government resources are used to promote IJVs. In order to assess firm value creation for South African firms this study performed event studies on IJV formation announcements from 1998 to 2011 using daily share returns from the Johannesburg Securities Exchange taking care to incorporate recent developments in the event study methodology. The study found that while the market responds to IJV announcements, its responses do not, on average, reflect that IJVs are firm value enhancing for their South African partners at formation. This stands in contrast to considerable empirical literature and IJV firm value creation theory. In addition, factoring in formation characteristics, argued to potentially help explain cases of value creation and destruction from IJVs, provided limited explanation for positive and negative wealth effectsfor South African firms entering IJVs. This result has important value for IJV participants, national economic policy makers and IJV researchers. For IJV participants and national policy makers, the results caution unfettered entry/support for IJVs and challenge the role of equity distribution in determining the value of the IJV to its partner firms. For IJV researchers, the results present new evidence questioning IJV firm value creation at formation and provide a potential explanation for the conflict in previous IJV research. The study makes four key contributions to the existing knowledge of IJV firm value creation. Firstly, it assesses IJV wealth effects for the hitherto untested South African IJVs. Secondly, in doing so it adds a new data set (South African IJVs) to the current IJV literature. Thirdly, in reviewing the literature on IJV firm value creation the study presents a disaggregated model of IJV firm value creation from which to develop IJV research and potentially solve the persistent conflict in empirical results on IJV partner wealth effects. Finally, it informs future South African IJV agreements by uncovering factors that influence and do not influence partner wealth effects for South African firms.
- Full Text:
- Date Issued: 2013
- Authors: Mangwengwende, Tadiwanashe Mukudzeyi
- Date: 2013
- Subjects: Joint ventures Joint ventures -- South Africa Business enterprises -- Valuation International business enterprises
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1033 , http://hdl.handle.net/10962/d1004174
- Description: This study investigates international equity joint ventures (IJVs) and South African partner firm value creation at formation. In addition, it tests whether four contentious formation characteristics, namely, the geographical location of the IJV partner, the level of economic development in the IJV partner’s home country, the level of equity held by the South African firm and the industry of the South African firm, can explain when South African IJVs are value enhancing and when they are value diminishing. IJVs are a popular business mode and an important channel for infrastructure and skills investment in developing countries. However, despite their popularity and potential social benefits, these IJVs are predominantly created by the decisions of private firms to collaborate with foreign firms and governments. Consequently the preservation and development of the IJV investment channel is dependent on the encouragement of private firm IJV participation. It is at uncovering potential tools to encourage IJV participation by South African firms that IJV firm value creation becomes important because it stands as a motivator for South African firms’ involvement in IJVs. Existing literature on IJVs and partner firm value has presented conflicting evidence with support for the views that they are value enhancing, value diminishing or of no immediate consequence to their partners’ firm value. Consequently, previous research offers limited firm value support for IJVs. For South African firms considering joint ventures and national policy makers determined to promote IJVs there is a need for an investigation of South African partner IJV firm value effects. Moreover, it is also necessary to test potential explanatory variables that may help to explain when the IJVs are value enhancing and when they are not as this will inform IJV contract negotiations and how limited national government resources are used to promote IJVs. In order to assess firm value creation for South African firms this study performed event studies on IJV formation announcements from 1998 to 2011 using daily share returns from the Johannesburg Securities Exchange taking care to incorporate recent developments in the event study methodology. The study found that while the market responds to IJV announcements, its responses do not, on average, reflect that IJVs are firm value enhancing for their South African partners at formation. This stands in contrast to considerable empirical literature and IJV firm value creation theory. In addition, factoring in formation characteristics, argued to potentially help explain cases of value creation and destruction from IJVs, provided limited explanation for positive and negative wealth effectsfor South African firms entering IJVs. This result has important value for IJV participants, national economic policy makers and IJV researchers. For IJV participants and national policy makers, the results caution unfettered entry/support for IJVs and challenge the role of equity distribution in determining the value of the IJV to its partner firms. For IJV researchers, the results present new evidence questioning IJV firm value creation at formation and provide a potential explanation for the conflict in previous IJV research. The study makes four key contributions to the existing knowledge of IJV firm value creation. Firstly, it assesses IJV wealth effects for the hitherto untested South African IJVs. Secondly, in doing so it adds a new data set (South African IJVs) to the current IJV literature. Thirdly, in reviewing the literature on IJV firm value creation the study presents a disaggregated model of IJV firm value creation from which to develop IJV research and potentially solve the persistent conflict in empirical results on IJV partner wealth effects. Finally, it informs future South African IJV agreements by uncovering factors that influence and do not influence partner wealth effects for South African firms.
- Full Text:
- Date Issued: 2013
Invasion of Lantana into India: analyzing introduction, spread, human adaptations and management
- Hari Krishnan, Ramesh Kannan
- Authors: Hari Krishnan, Ramesh Kannan
- Date: 2013
- Subjects: Lantana -- India Weeds -- Control -- India Plant introduction -- India Natural resources -- India Botany, Economic -- India Botany -- Social aspects -- India
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4728 , http://hdl.handle.net/10962/d1001756
- Description: Objectives and Research Questions 1. To reconstruct the history of invasion of Lantana in India from where, by who, and when was Lantana species introduced into India?, given its long history in the country, is it still spreading or has it become more or less stable? 2. To study the human adaptation to Lantana invasion: socioeconomic causes and consequences of the use of Lantana as an alternative source of livelihood for forest dependent communities in southern India; how have local communities adapted to the invasion?; what are the key determinants that may have driven communities to use Lantana?; what are the economic consequences of the use of Lantana by local communities? 3. To critically review local practices and forest policy for the management of Lantana in southern India.; how has the use of Lantana by local communities impacted its local regeneration?; does the use of Lantana in local context have implications for its management?; what has been the role of the Forest Department and its policies in managing Lantana?
- Full Text:
- Date Issued: 2013
- Authors: Hari Krishnan, Ramesh Kannan
- Date: 2013
- Subjects: Lantana -- India Weeds -- Control -- India Plant introduction -- India Natural resources -- India Botany, Economic -- India Botany -- Social aspects -- India
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4728 , http://hdl.handle.net/10962/d1001756
- Description: Objectives and Research Questions 1. To reconstruct the history of invasion of Lantana in India from where, by who, and when was Lantana species introduced into India?, given its long history in the country, is it still spreading or has it become more or less stable? 2. To study the human adaptation to Lantana invasion: socioeconomic causes and consequences of the use of Lantana as an alternative source of livelihood for forest dependent communities in southern India; how have local communities adapted to the invasion?; what are the key determinants that may have driven communities to use Lantana?; what are the economic consequences of the use of Lantana by local communities? 3. To critically review local practices and forest policy for the management of Lantana in southern India.; how has the use of Lantana by local communities impacted its local regeneration?; does the use of Lantana in local context have implications for its management?; what has been the role of the Forest Department and its policies in managing Lantana?
- Full Text:
- Date Issued: 2013
Investigating rural Ugandan women's engagement with HIV and AIDS-related programmes on community radio: a case study of Mama FM's Speak out and Listen
- Authors: Kigozi, James Musisi
- Date: 2013
- Subjects: Community radio , AIDS (Disease) in women -- Research -- Uganda , AIDS (Disease) -- Research -- Uganda , AIDS (Disease) and mass media -- Research -- Uganda , AIDS (Disease) -- Social aspects -- Uganda
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3414 , http://hdl.handle.net/10962/d1001845
- Description: The purpose of this study was to investigate how rural Ugandan women engage with discussions of HIV and AIDS on community radio. It explored how this audience may relate such broadcast discussions to their own lived experience of HIV and AIDS. It is explained in the study that, while the Uganda government has an official policy of openly discussing matters of HIV and AIDS, health communication strategies still operate within a context where there is an underlying "culture of silence" that discourages openness about sexual matters. It is also pointed out that there are widespread gender disparities among rural communities, which severely limit women's ability to make use of health communication initiatives aimed at educating them. Against this backdrop, the study sets out to explore audience responses to a particular example of Speak Out and Listen, a weekly programme broadcast on Mama FM, a Kampala-based radio station managed by the Uganda Media Women's Association (UMWA). The study maps out responses to the programme by a particular group of rural women. It is argued that these research participants' comments confirm the importance, noted in literature dealing with health education, of drawing for content on what members of an audience have to say about their own lived context. It is proposed that, despite the existence of a 'culture of silence', the women's comments demonstrate an ability to speak with confidence about their experience of living with HIV and AIDS. Thcy are able, more particularly to discuss the constraints placed by gendered power relations on women's ability to draw on the educational content of programming that targets people living with HIV and AIDS. As such, the comments that such women offer represent a valuable resource for HIV and AIDS related programming. The principal conclusion of the study is that health communication initiatives such as Speak Out and Listen would benefit from facilitating conversations with their target audience about their lived experience of HIV and AIDS, and incorporating such discussion into their programmes
- Full Text:
- Date Issued: 2013
- Authors: Kigozi, James Musisi
- Date: 2013
- Subjects: Community radio , AIDS (Disease) in women -- Research -- Uganda , AIDS (Disease) -- Research -- Uganda , AIDS (Disease) and mass media -- Research -- Uganda , AIDS (Disease) -- Social aspects -- Uganda
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3414 , http://hdl.handle.net/10962/d1001845
- Description: The purpose of this study was to investigate how rural Ugandan women engage with discussions of HIV and AIDS on community radio. It explored how this audience may relate such broadcast discussions to their own lived experience of HIV and AIDS. It is explained in the study that, while the Uganda government has an official policy of openly discussing matters of HIV and AIDS, health communication strategies still operate within a context where there is an underlying "culture of silence" that discourages openness about sexual matters. It is also pointed out that there are widespread gender disparities among rural communities, which severely limit women's ability to make use of health communication initiatives aimed at educating them. Against this backdrop, the study sets out to explore audience responses to a particular example of Speak Out and Listen, a weekly programme broadcast on Mama FM, a Kampala-based radio station managed by the Uganda Media Women's Association (UMWA). The study maps out responses to the programme by a particular group of rural women. It is argued that these research participants' comments confirm the importance, noted in literature dealing with health education, of drawing for content on what members of an audience have to say about their own lived context. It is proposed that, despite the existence of a 'culture of silence', the women's comments demonstrate an ability to speak with confidence about their experience of living with HIV and AIDS. Thcy are able, more particularly to discuss the constraints placed by gendered power relations on women's ability to draw on the educational content of programming that targets people living with HIV and AIDS. As such, the comments that such women offer represent a valuable resource for HIV and AIDS related programming. The principal conclusion of the study is that health communication initiatives such as Speak Out and Listen would benefit from facilitating conversations with their target audience about their lived experience of HIV and AIDS, and incorporating such discussion into their programmes
- Full Text:
- Date Issued: 2013
Investigating the problems experienced by virtual team members engaged in requirements elicitation
- Authors: De Abrew, Upuli Kanchana
- Date: 2013
- Subjects: Virtual work teams Virtual work teams -- South Africa System design System analysis
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1151 , http://hdl.handle.net/10962/d1007845
- Description: The constant acceleration in the rate of technological innovation, and the ever growing emphasis on the importance of information for competition has seen organisations around the world strive for the technologies that give them global customer reach. One of the most pervasive technological innovations developed is the internet, and its unique quality of being able to draw people from across the world together in one virtual space has given birth to the concept of virtual teams. Organisations have seized the advantages of such virtual teams to give them the cost and time reductions they need to stay competitive in the global marketplace. In the software industry, where product and service development is always a race against time, forward thinking software companies in the developed world have taken full advantage of the cost and time saving benefits that virtual teams have to offer. In addition, the rate of expansion of technology and software to support such teams is also growing exponentially, offering increasingly faster ways of virtual working. Despite the immense advantages offered by such teams, South African software development companies do not seem to engage in distributed work to any great degree. The importance of this research rests on the belief that South African software development companies will be unable to avoid engaging in distributed software development if they are to achieve and maintain competitiveness in the global marketplace. This research focuses on a sub-section of the software development process with a specific reference to South African software development. The requirements elicitation phase of software development is one of the initial stages of any software project. It is here that developers work with the users in order to identify requirements for the system to be built. It is acknowledged that other phases of distributed development also bring to bear their own problems, however, in the interests of scoping this research, only the requirements elicitation process is focused on. The research shows that most techniques of requirements elicitation can be adapted for use within the virtual environment, although each technique has its share of advantages and disadvantages. In addition, virtual team members experience problems during their general, day-to-day interactions, many of these arising from the dependence on technology for communication and task performance. The research identifies the problems in both categories, and develops a holistic model of virtual requirements elicitation to prevent or solve the problems experienced by virtual teams engaged in distributed requirements elicitation. The model is made up of three key frameworks, each of which prescribes actions to be taken to ensure the success of the virtual team within the requirements elicitation process. The model is verified through the testing of its critical success factors. Certain aspects of the model were adapted based on the findings of the study, but it was confirmed that the rationale behind the model is sound, indicating that it has the potential to solve the problems of virtual RE when implemented.
- Full Text:
- Date Issued: 2013
- Authors: De Abrew, Upuli Kanchana
- Date: 2013
- Subjects: Virtual work teams Virtual work teams -- South Africa System design System analysis
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1151 , http://hdl.handle.net/10962/d1007845
- Description: The constant acceleration in the rate of technological innovation, and the ever growing emphasis on the importance of information for competition has seen organisations around the world strive for the technologies that give them global customer reach. One of the most pervasive technological innovations developed is the internet, and its unique quality of being able to draw people from across the world together in one virtual space has given birth to the concept of virtual teams. Organisations have seized the advantages of such virtual teams to give them the cost and time reductions they need to stay competitive in the global marketplace. In the software industry, where product and service development is always a race against time, forward thinking software companies in the developed world have taken full advantage of the cost and time saving benefits that virtual teams have to offer. In addition, the rate of expansion of technology and software to support such teams is also growing exponentially, offering increasingly faster ways of virtual working. Despite the immense advantages offered by such teams, South African software development companies do not seem to engage in distributed work to any great degree. The importance of this research rests on the belief that South African software development companies will be unable to avoid engaging in distributed software development if they are to achieve and maintain competitiveness in the global marketplace. This research focuses on a sub-section of the software development process with a specific reference to South African software development. The requirements elicitation phase of software development is one of the initial stages of any software project. It is here that developers work with the users in order to identify requirements for the system to be built. It is acknowledged that other phases of distributed development also bring to bear their own problems, however, in the interests of scoping this research, only the requirements elicitation process is focused on. The research shows that most techniques of requirements elicitation can be adapted for use within the virtual environment, although each technique has its share of advantages and disadvantages. In addition, virtual team members experience problems during their general, day-to-day interactions, many of these arising from the dependence on technology for communication and task performance. The research identifies the problems in both categories, and develops a holistic model of virtual requirements elicitation to prevent or solve the problems experienced by virtual teams engaged in distributed requirements elicitation. The model is made up of three key frameworks, each of which prescribes actions to be taken to ensure the success of the virtual team within the requirements elicitation process. The model is verified through the testing of its critical success factors. Certain aspects of the model were adapted based on the findings of the study, but it was confirmed that the rationale behind the model is sound, indicating that it has the potential to solve the problems of virtual RE when implemented.
- Full Text:
- Date Issued: 2013
Investigation into the technical feasibility of biological treatment of precious metal refining wastewater
- Authors: Moore, Bronwyn Ann
- Date: 2013
- Subjects: Sewage -- Purification -- Biological treatment -- South Africa Sewage -- Purification -- Activated sludge process -- South Africa Water reuse -- South Africa Flotation -- South Africa Platinum mines and mining -- Waste disposal -- South Africa Platinum mines and mining -- Economic aspects -- South Africa Mine water -- Environmental aspects -- South Africa Platinum mines and mining -- Waste minimization -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3888 , http://hdl.handle.net/10962/d1002013
- Description: The hydrometallurgical refining of platinum group metals results in large volumes of liquid waste that requires suitable treatment before any disposal can be contemplated. The wastewater streams are characterized by extremes of pH, high inorganic ion content (such as chloride), significant residual metal loads and small amounts of entrained organic compounds. Historically these effluents were housed in evaporation reservoirs, however lack of space and growing water demands have led Anglo Platinum to consider treatment of these effluents. The aim of this study was to investigate whether biological wastewater treatment could produce water suitable for onsite reuse. Bench-scale activated sludge and anaerobic digestion for co-treatment of an acidic refinery waste stream with domestic wastewater were used to give preliminary data. Activated sludge showed better water treatment at lab scale in terms of removal efficiencies of ammonia (approximately 25%, cf. 20% in anaerobic digestion) and COD (70% cf. 43% in digestion) and greater robustness when biomass health was compared. Activated sludge was consequently selected for a pilot plant trial. The pilot plant was operated on-site and performed comparably with the bench-scale system, however challenges in the clarifier design led to losses of biomass and poor effluent quality (suspended solids washout). The pilot plant was unable to alter the pH of the feed, but a two week maturation period resulted in the pH increasing from 5.3 to 7.0. Tests on algal treatment as an alternative or follow-on unit operation to activated sludge showed it not to be a viable process. The activated sludge effluent was assessed for onsite reuse in flotation and it was found that there was no significant difference between its flotation performance and that of the process water currently used, indicating the effluent generated by the biological treatment system can be used successfully for flotation. Flotation is the method whereby minerals refining operations recover minerals of interest from ore through the addition of chemicals and aeration of the ore slurry. Target minerals adhere to the bubbles and can be removed from the process.
- Full Text:
- Date Issued: 2013
- Authors: Moore, Bronwyn Ann
- Date: 2013
- Subjects: Sewage -- Purification -- Biological treatment -- South Africa Sewage -- Purification -- Activated sludge process -- South Africa Water reuse -- South Africa Flotation -- South Africa Platinum mines and mining -- Waste disposal -- South Africa Platinum mines and mining -- Economic aspects -- South Africa Mine water -- Environmental aspects -- South Africa Platinum mines and mining -- Waste minimization -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3888 , http://hdl.handle.net/10962/d1002013
- Description: The hydrometallurgical refining of platinum group metals results in large volumes of liquid waste that requires suitable treatment before any disposal can be contemplated. The wastewater streams are characterized by extremes of pH, high inorganic ion content (such as chloride), significant residual metal loads and small amounts of entrained organic compounds. Historically these effluents were housed in evaporation reservoirs, however lack of space and growing water demands have led Anglo Platinum to consider treatment of these effluents. The aim of this study was to investigate whether biological wastewater treatment could produce water suitable for onsite reuse. Bench-scale activated sludge and anaerobic digestion for co-treatment of an acidic refinery waste stream with domestic wastewater were used to give preliminary data. Activated sludge showed better water treatment at lab scale in terms of removal efficiencies of ammonia (approximately 25%, cf. 20% in anaerobic digestion) and COD (70% cf. 43% in digestion) and greater robustness when biomass health was compared. Activated sludge was consequently selected for a pilot plant trial. The pilot plant was operated on-site and performed comparably with the bench-scale system, however challenges in the clarifier design led to losses of biomass and poor effluent quality (suspended solids washout). The pilot plant was unable to alter the pH of the feed, but a two week maturation period resulted in the pH increasing from 5.3 to 7.0. Tests on algal treatment as an alternative or follow-on unit operation to activated sludge showed it not to be a viable process. The activated sludge effluent was assessed for onsite reuse in flotation and it was found that there was no significant difference between its flotation performance and that of the process water currently used, indicating the effluent generated by the biological treatment system can be used successfully for flotation. Flotation is the method whereby minerals refining operations recover minerals of interest from ore through the addition of chemicals and aeration of the ore slurry. Target minerals adhere to the bubbles and can be removed from the process.
- Full Text:
- Date Issued: 2013
Language policy and planning in the Tshwane Metropolitan Municipality: the challenges of implementation
- Seshoka, Keaobaka Omphile Precious
- Authors: Seshoka, Keaobaka Omphile Precious
- Date: 2013 , 2013-03-26
- Subjects: Language policy -- South Africa -- City of Tshwane Metropolitan Municipality Language planning -- South Africa -- City of Tshwane Metropolitan Municipality Community development -- South Africa -- Gauteng Local government -- South Africa -- Gauteng Municipal services -- South Africa --Gauteng
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3554 , http://hdl.handle.net/10962/d1001519
- Description: This study explores the challenges related to language policy and planning in the City of Tshwane Metropolitan municipality. The study sets to look at the at the challenges affecting successful implementation by the City of Tshwane Metropolitan Municipality as a state organ charged with local development and service delivery for the communities. In terms of the Municipal Systems Act of 2000 municipalities are expected to respond to the language use and preferences of their local communities by making sure that their language policies are fully implemented. The researcher highlights that in instances where municipalities communicate information they are required to make special provision for the speakers of African languages in the communities that they serve in the languages they best understand. This work looks at various statutory language policy documents in South Africa in particular, that give the task of language policy implementation to municipalities as they are the local extension of the national government. This study also argues that municipalities are critical to implementation of language policy. It further notes that in order for the full social, economic and political transformation to take place in municipalities they have to be transformed linguistically in a radical way whereby all the official languages play a major role in all these spheres than before. This view is held by many scholars and researchers in the areas of language policy and planning. This study highlights that the challenges to successful language planning and policy in the government sectors are due to lack of commitment by the government, language practitioners and planners and increased monolingualism in the municipality. The study further explores the language policy and plan of the City of Tshwane Metropolitan Municipality and the the strategies that can contribute to successful optimization of language resources of the Tshwane Metropolitan Municipality in order to give effect to the use of local languages as contained in policy documents and also establish how the city of Tshwane can better reinforce its strategies to implement this language plan and policy. The main focus area of this research is on the language policy and plan of the City of Tshwane Metropolitan Municipality and assesses whether the language practices in these institutions are reflective of their policy and plan. It is hoped that the study will be able to give policy makers and those tasked with implementation, especially at government municipalities’ strategies for improvement in the functionality and the implementation of their language policies and plans. It is also hoped that recommendations and challenges highlighted by this research will be of a better assistance on how to better reinforce strategies to implement the language plan and policy in the government sectors.
- Full Text:
- Date Issued: 2013
- Authors: Seshoka, Keaobaka Omphile Precious
- Date: 2013 , 2013-03-26
- Subjects: Language policy -- South Africa -- City of Tshwane Metropolitan Municipality Language planning -- South Africa -- City of Tshwane Metropolitan Municipality Community development -- South Africa -- Gauteng Local government -- South Africa -- Gauteng Municipal services -- South Africa --Gauteng
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3554 , http://hdl.handle.net/10962/d1001519
- Description: This study explores the challenges related to language policy and planning in the City of Tshwane Metropolitan municipality. The study sets to look at the at the challenges affecting successful implementation by the City of Tshwane Metropolitan Municipality as a state organ charged with local development and service delivery for the communities. In terms of the Municipal Systems Act of 2000 municipalities are expected to respond to the language use and preferences of their local communities by making sure that their language policies are fully implemented. The researcher highlights that in instances where municipalities communicate information they are required to make special provision for the speakers of African languages in the communities that they serve in the languages they best understand. This work looks at various statutory language policy documents in South Africa in particular, that give the task of language policy implementation to municipalities as they are the local extension of the national government. This study also argues that municipalities are critical to implementation of language policy. It further notes that in order for the full social, economic and political transformation to take place in municipalities they have to be transformed linguistically in a radical way whereby all the official languages play a major role in all these spheres than before. This view is held by many scholars and researchers in the areas of language policy and planning. This study highlights that the challenges to successful language planning and policy in the government sectors are due to lack of commitment by the government, language practitioners and planners and increased monolingualism in the municipality. The study further explores the language policy and plan of the City of Tshwane Metropolitan Municipality and the the strategies that can contribute to successful optimization of language resources of the Tshwane Metropolitan Municipality in order to give effect to the use of local languages as contained in policy documents and also establish how the city of Tshwane can better reinforce its strategies to implement this language plan and policy. The main focus area of this research is on the language policy and plan of the City of Tshwane Metropolitan Municipality and assesses whether the language practices in these institutions are reflective of their policy and plan. It is hoped that the study will be able to give policy makers and those tasked with implementation, especially at government municipalities’ strategies for improvement in the functionality and the implementation of their language policies and plans. It is also hoped that recommendations and challenges highlighted by this research will be of a better assistance on how to better reinforce strategies to implement the language plan and policy in the government sectors.
- Full Text:
- Date Issued: 2013
Learners' participation in leadership: a case study in a secondary school in Namibia
- Authors: Uushona, Andreas Bishi
- Date: 2013
- Subjects: Educational leadership -- Namibia -- Case studies Student participation in administration -- Namibia -- Case studies School management and organization -- Namibia -- Case studies Student government -- Namibia Education, Secondary -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1395 , http://hdl.handle.net/10962/d1001749
- Description: Learner leadership is a worldwide issue in educational leadership and management. In preindependent Namibia secondary schools had the prefect system and the SRCs as learner leadership bodies which had little influence on schools’ decisions because they lacked credibility. In 2001 the Learners’ Representative Council (LRC) was legitimized as a learner leadership body in secondary schools through the Education Act 16 of 2001. However, recent research suggests that even these bodies are not functioning effectively for a variety of reasons. This prompted me to undertake research to develop an understanding of learners’ participation in leadership in a senior secondary school in Namibia. I used a qualitative case study, in an interpretive paradigm, in an attempt to achieve my research goal. The following questions guided the study: How is leadership understood by members of the organization? How learner leadership is understood? How are learners involved in leadership in the school? What potential exists for increased learners’ participation? What factors inhibit learners’ participation in leadership in the school? A population comprising of the school board chairperson, the principal, three heads of department, the superintendent, three teachers and five learners was composed from a senior secondary school in Namibia. Data were collected through focus groups, interviews, document analysis and observation and analyzed thematically for reflective discussion. The findings revealed that the LRC is functioning but providing little opportunity for learner leadership development. The most significant challenge relates to traditional and outdated views of leadership on the parts of teachers and education managers. Hence, in addition to a number of practical recommendations, the study recommends a change of mindset towards children so that opportunities are provided to contribute to their growth and development.
- Full Text:
- Date Issued: 2013
- Authors: Uushona, Andreas Bishi
- Date: 2013
- Subjects: Educational leadership -- Namibia -- Case studies Student participation in administration -- Namibia -- Case studies School management and organization -- Namibia -- Case studies Student government -- Namibia Education, Secondary -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1395 , http://hdl.handle.net/10962/d1001749
- Description: Learner leadership is a worldwide issue in educational leadership and management. In preindependent Namibia secondary schools had the prefect system and the SRCs as learner leadership bodies which had little influence on schools’ decisions because they lacked credibility. In 2001 the Learners’ Representative Council (LRC) was legitimized as a learner leadership body in secondary schools through the Education Act 16 of 2001. However, recent research suggests that even these bodies are not functioning effectively for a variety of reasons. This prompted me to undertake research to develop an understanding of learners’ participation in leadership in a senior secondary school in Namibia. I used a qualitative case study, in an interpretive paradigm, in an attempt to achieve my research goal. The following questions guided the study: How is leadership understood by members of the organization? How learner leadership is understood? How are learners involved in leadership in the school? What potential exists for increased learners’ participation? What factors inhibit learners’ participation in leadership in the school? A population comprising of the school board chairperson, the principal, three heads of department, the superintendent, three teachers and five learners was composed from a senior secondary school in Namibia. Data were collected through focus groups, interviews, document analysis and observation and analyzed thematically for reflective discussion. The findings revealed that the LRC is functioning but providing little opportunity for learner leadership development. The most significant challenge relates to traditional and outdated views of leadership on the parts of teachers and education managers. Hence, in addition to a number of practical recommendations, the study recommends a change of mindset towards children so that opportunities are provided to contribute to their growth and development.
- Full Text:
- Date Issued: 2013
Like Katherine
- Authors: Morgan, Jane Mary Kathleen
- Date: 2013
- Subjects: Creative writing , Fiction , South Africa , Creative writing (Higher education) , Short stories, South African (English) -- 21st century , South African fiction (English) -- 21st century , English language -- Writing
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:5964 , http://hdl.handle.net/10962/d1001814
- Description: Vicky, a thirty something English radio journalist, has moved to Cape Town to try and work out what it is that's missing from her life and to fill the gap. At first she thinks she's found what she's looking for, but a series of unsettling events makes her realise she has simply brought her problems with her. She goes back to England, ostensibly for work, where she is contacted by her stepbrother, Mark. They hardly know each other but he has a reason for wanting to find her. They meet and, for both of them, their encounters change the way they see themselves and their relationships. Vicky comes to understand more about her past and her family and, for the first time, to find a connection with her emotional life
- Full Text:
- Date Issued: 2013
- Authors: Morgan, Jane Mary Kathleen
- Date: 2013
- Subjects: Creative writing , Fiction , South Africa , Creative writing (Higher education) , Short stories, South African (English) -- 21st century , South African fiction (English) -- 21st century , English language -- Writing
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:5964 , http://hdl.handle.net/10962/d1001814
- Description: Vicky, a thirty something English radio journalist, has moved to Cape Town to try and work out what it is that's missing from her life and to fill the gap. At first she thinks she's found what she's looking for, but a series of unsettling events makes her realise she has simply brought her problems with her. She goes back to England, ostensibly for work, where she is contacted by her stepbrother, Mark. They hardly know each other but he has a reason for wanting to find her. They meet and, for both of them, their encounters change the way they see themselves and their relationships. Vicky comes to understand more about her past and her family and, for the first time, to find a connection with her emotional life
- Full Text:
- Date Issued: 2013
Linguistic minorities in the South African context : the case of Tshivenda
- Authors: Luvhengo, Nkhangweleni
- Date: 2013
- Subjects: Indigenous African languages , Apartheid , Tshivenda , Minority languages , Development , Status , Multilingualism , Sesotho , isiZulu , Perceptions , Linguistic minorities -- Research -- South Africa , Venda language -- Research -- South Africa , Language policy -- Research -- South Africa , Multilingualism -- Research -- South Africa , Linguistic rights -- Research -- South Africa , Language and languages -- Political aspects
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3558 , http://hdl.handle.net/10962/d1001862
- Description: After many years of the oppressive apartheid government, the new democratic era came into being in 1994. Lot of policy changes came into being, including language policy. This new language policy of the post-apartheid era recognises eleven official languages which include the nine indigenous African languages which were previously recognised as regional languages in the different homelands. The present study investigates the progress of Tshivenda in terms of status and development since it was accorded the official status in South Africa. Literature investigating the status of Tshivenda is generally sparse. This study investigates the status of Tshivenda in South Africa to explore how minority languages which are also recognised as official languages are treated. In most multilingual countries, there are issues which affect the development of minority languages, but the South African situation is interesting in that some of the minority languages are recognised as official languages. This study is a comparative in nature. Firstly, the study compares the level of corpus planning and development in Tshivenda and other indigenous South African languages. Secondly, it compares how people use Tshivenda in a rural area of Lukalo Village where the language is not under pressure from other languages and in Cosmo City, an urban area in Gauteng where Tshivenda speakers come into contact with speakers of more dominant languages such as isiZulu and Sesotho. Language use in different domains like, media, education, government and the home is considered in order to establish how people use languages and the factors which influence their linguistic behaviours. The study also establishes the perceptions and attitudes of the speakers of Tshivenda as a minority and those of the speakers of other languages towards Tshivenda’s role in the different domains such as education and the media. This study was influenced by previous research (Alexander 1989, Webb 2002) which found out that during the apartheid period Tshivenda speakers used to disguise their identity by adopting dominant languages like isiZulu and Sesotho in Johannesburg. Accordingly, the present research wanted to establish how the language policy change in the democratic era has impacted on the confidence of Tshivenda speakers regarding themselves and their language. This study establishes that although Tshivenda is now an official language in post-apartheid South Africa, it still has features of underdevelopment and marginalization that are typically of unofficial minority languages. Translation, lexicographic and terminological work in this language still lags behind that of other indigenous South African languages and there is still a shortage of school textbooks and adult literature in this language. As a result, using the language in education, the media and other controlling domains is still quite challenging, although positive developments such as the teaching of the language at university level can be noted. The Tshivenda speakers generally have a positive attitude towards their language and seem prepared to learn and use it confidently as long its functional value is enhanced, which is currently not happening. As a result, some Tshivenda speakers still regard English as a more worthwhile language to learn at the expense of their language
- Full Text:
- Date Issued: 2013
- Authors: Luvhengo, Nkhangweleni
- Date: 2013
- Subjects: Indigenous African languages , Apartheid , Tshivenda , Minority languages , Development , Status , Multilingualism , Sesotho , isiZulu , Perceptions , Linguistic minorities -- Research -- South Africa , Venda language -- Research -- South Africa , Language policy -- Research -- South Africa , Multilingualism -- Research -- South Africa , Linguistic rights -- Research -- South Africa , Language and languages -- Political aspects
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3558 , http://hdl.handle.net/10962/d1001862
- Description: After many years of the oppressive apartheid government, the new democratic era came into being in 1994. Lot of policy changes came into being, including language policy. This new language policy of the post-apartheid era recognises eleven official languages which include the nine indigenous African languages which were previously recognised as regional languages in the different homelands. The present study investigates the progress of Tshivenda in terms of status and development since it was accorded the official status in South Africa. Literature investigating the status of Tshivenda is generally sparse. This study investigates the status of Tshivenda in South Africa to explore how minority languages which are also recognised as official languages are treated. In most multilingual countries, there are issues which affect the development of minority languages, but the South African situation is interesting in that some of the minority languages are recognised as official languages. This study is a comparative in nature. Firstly, the study compares the level of corpus planning and development in Tshivenda and other indigenous South African languages. Secondly, it compares how people use Tshivenda in a rural area of Lukalo Village where the language is not under pressure from other languages and in Cosmo City, an urban area in Gauteng where Tshivenda speakers come into contact with speakers of more dominant languages such as isiZulu and Sesotho. Language use in different domains like, media, education, government and the home is considered in order to establish how people use languages and the factors which influence their linguistic behaviours. The study also establishes the perceptions and attitudes of the speakers of Tshivenda as a minority and those of the speakers of other languages towards Tshivenda’s role in the different domains such as education and the media. This study was influenced by previous research (Alexander 1989, Webb 2002) which found out that during the apartheid period Tshivenda speakers used to disguise their identity by adopting dominant languages like isiZulu and Sesotho in Johannesburg. Accordingly, the present research wanted to establish how the language policy change in the democratic era has impacted on the confidence of Tshivenda speakers regarding themselves and their language. This study establishes that although Tshivenda is now an official language in post-apartheid South Africa, it still has features of underdevelopment and marginalization that are typically of unofficial minority languages. Translation, lexicographic and terminological work in this language still lags behind that of other indigenous South African languages and there is still a shortage of school textbooks and adult literature in this language. As a result, using the language in education, the media and other controlling domains is still quite challenging, although positive developments such as the teaching of the language at university level can be noted. The Tshivenda speakers generally have a positive attitude towards their language and seem prepared to learn and use it confidently as long its functional value is enhanced, which is currently not happening. As a result, some Tshivenda speakers still regard English as a more worthwhile language to learn at the expense of their language
- Full Text:
- Date Issued: 2013
Linking institutional and ecological provisions for wastewater treatment discharge in a rural municipality, Eastern Cape, South Africa
- Authors: Muller, Matthew Justin
- Date: 2013
- Subjects: Sewage disposal plants -- South Africa -- Sundays Estuary (Eastern Cape) , Sewage disposal -- Law and legislation -- South Africa , Sewage -- Environmental aspects -- South Africa , Water-supply -- South Africa -- Management , Sewage disposal in rivers, lakes, etc. -- South Africa -- Sundays Estuary (Eastern Cape) , Rivers -- Environmental aspects -- South Africa -- Sundays Estuary (Eastern Cape) , Rivers -- Regulation -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:6044 , http://hdl.handle.net/10962/d1013048
- Description: The Green Drop Certification Programme, launched in 2008 alongside the Blue Drop Certification Programme, aims to provide the Department of Water Affairs with a national overview of how municipalities and their individual wastewater treatment works (WWTW) are complying with licence conditions set by the National Water Act (NWA) (No. 36 of 1998; DWAF 1998) and the Water Services Act (No. 108 of 1997; DWAF 1998). By publishing the results of each municipality’s performance, the programme aims to ensure continuous improvement in the wastewater treatment sector through public pressure. The programme has been identified by this project as a necessary linking tool between the NWA and the Water Services Act to ensure protection and sustainable use of South Africa’s natural water resources. It does this through assisting municipalities to improve their wastewater treatment operations which in theory will lead to discharged effluent that is compliant with discharge licence conditions. These discharge licences form part of the NWA’s enforcement tool of Source Directed Controls (SDC) which help a water resource meet the ecological goals set for it as part of Resource Directed Measures (RDM). The link between meeting the required SDC and achieving the RDM goals has never been empirically tested. This project aimed to determine the present ecological condition of the Uie River, a tributary of the Sundays River which the Sundays River Valley Municipality (SRVM) discharges its domestic effluent into. It then determined whether the SRVM’s WWTW was complying with the General Standard licence conditions and what the impact of the effluent on the river was through the analysis of monthly biomonitoring, water chemistry and habitat data. Lastly, the project examined the effectiveness of the Green Drop Certification Programme in bringing about change in the SRVM’s wastewater treatment sector, which previously achieved a Green Drop score of 5.6 percent. It wanted to examine the underlying assumption that a WWTW which improves its Green Drop score will be discharging a better quality effluent that will help a water resource meets the RDM goals set for it. The Kirkwood WWTW did not have a discharge licence at the time of assessment and was thus assessed under the General Standard licence conditions. It was found that the Kirkwood WWTW was not complying with the General Standard discharge licence conditions in the Uie River. This was having a negative impact on the river health, mainly through high concentrations of Total Inorganic Nitrogen (TIN-N), orthophosphate and turbidity. The SRVM should see an improvement in its Green Drop score for the Kirkwood WWTW. However, the municipality showed no implementation of necessary programmes. Implementation of these programmes would help the SRVM meet the General Standard licence conditions (part of SDC) which would help the Uie River meet the RDM goals set for it.
- Full Text:
- Date Issued: 2013
- Authors: Muller, Matthew Justin
- Date: 2013
- Subjects: Sewage disposal plants -- South Africa -- Sundays Estuary (Eastern Cape) , Sewage disposal -- Law and legislation -- South Africa , Sewage -- Environmental aspects -- South Africa , Water-supply -- South Africa -- Management , Sewage disposal in rivers, lakes, etc. -- South Africa -- Sundays Estuary (Eastern Cape) , Rivers -- Environmental aspects -- South Africa -- Sundays Estuary (Eastern Cape) , Rivers -- Regulation -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:6044 , http://hdl.handle.net/10962/d1013048
- Description: The Green Drop Certification Programme, launched in 2008 alongside the Blue Drop Certification Programme, aims to provide the Department of Water Affairs with a national overview of how municipalities and their individual wastewater treatment works (WWTW) are complying with licence conditions set by the National Water Act (NWA) (No. 36 of 1998; DWAF 1998) and the Water Services Act (No. 108 of 1997; DWAF 1998). By publishing the results of each municipality’s performance, the programme aims to ensure continuous improvement in the wastewater treatment sector through public pressure. The programme has been identified by this project as a necessary linking tool between the NWA and the Water Services Act to ensure protection and sustainable use of South Africa’s natural water resources. It does this through assisting municipalities to improve their wastewater treatment operations which in theory will lead to discharged effluent that is compliant with discharge licence conditions. These discharge licences form part of the NWA’s enforcement tool of Source Directed Controls (SDC) which help a water resource meet the ecological goals set for it as part of Resource Directed Measures (RDM). The link between meeting the required SDC and achieving the RDM goals has never been empirically tested. This project aimed to determine the present ecological condition of the Uie River, a tributary of the Sundays River which the Sundays River Valley Municipality (SRVM) discharges its domestic effluent into. It then determined whether the SRVM’s WWTW was complying with the General Standard licence conditions and what the impact of the effluent on the river was through the analysis of monthly biomonitoring, water chemistry and habitat data. Lastly, the project examined the effectiveness of the Green Drop Certification Programme in bringing about change in the SRVM’s wastewater treatment sector, which previously achieved a Green Drop score of 5.6 percent. It wanted to examine the underlying assumption that a WWTW which improves its Green Drop score will be discharging a better quality effluent that will help a water resource meets the RDM goals set for it. The Kirkwood WWTW did not have a discharge licence at the time of assessment and was thus assessed under the General Standard licence conditions. It was found that the Kirkwood WWTW was not complying with the General Standard discharge licence conditions in the Uie River. This was having a negative impact on the river health, mainly through high concentrations of Total Inorganic Nitrogen (TIN-N), orthophosphate and turbidity. The SRVM should see an improvement in its Green Drop score for the Kirkwood WWTW. However, the municipality showed no implementation of necessary programmes. Implementation of these programmes would help the SRVM meet the General Standard licence conditions (part of SDC) which would help the Uie River meet the RDM goals set for it.
- Full Text:
- Date Issued: 2013
Livelihood and coping strategy changes along rural-urban continua with an emphasis on natural resources
- Authors: Evans, Michelle Leigh
- Date: 2013
- Subjects: Natural resources -- South Africa -- Queenstown Natural resources -- South Africa -- Phalaborwa Rural-urban divide -- South Africa -- Queenstown Rural-urban divide -- South Africa -- Phalaborwa Income -- South Africa -- Queenstown Income -- South Africa -- Phalaborwa Women heads of households -- South Africa -- Queenstown Women heads of households -- South Africa -- Phalaborwa Adjustment (Psychology)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4731 , http://hdl.handle.net/10962/d1001958
- Description: Rapid urbanisation is one of the greatest challenges facing both developed and developing countries. Sub-Saharan Africa has historically been one of the least developed and least urbanised areas of the world. However, urbanisation is now occurring much more rapidly in countries that have lower levels of per capita income. Therefore, in the coming decades, urban population growth is expected to be more widespread in the developing countries of the world. Most research on the role of natural resources focuses on rural communities and little is known about the contribution these resources make along the rural-urban continuum in small and medium sized towns as well as the contribution to total livelihoods. This is because researchers and policy makers have often treated rural and urban areas and their residents as distinct entities that should be studied in isolation. This, however, is not a true reflection of household livelihoods which often include both rural and urban elements. This study therefore analysed the impact of urbanisation on livelihoods along a rural-urban continuum with an emphasis on natural resources in South Africa. The main characteristics as well as the livelihood portfolios of respondent households were investigated. Secondly, the coping strategies used by households along the rural-urban continuum were explored, and disaggregated according to the gender of the household head. Data were collected along the rural-urban continuum of two small towns, namely Queenstown, located in the Eastern Cape province and Phalaborwa, located in the Limpopo Province of South Africa. Sampling covered the town, peri-urban areas, townships and adjacent rural households. A standardised survey instrument was used to capture household details and livelihood activities and a total of 272 interviews were conducted. The rural areas near both towns were poorer than the township and urban areas with regards to assets, access to employment and annual household income across all cash and non-cash income streams. The engagement in land-based activities increased towards the rural areas. The use of natural resources, as well as the number of resources collected, increased along the continuum towards the rural areas, with 12.0% to 49.0% of urban households, 30.0% to 88.0% of township households and between 80.0% and 100.0% of rural households engaging in the use and collection of natural resources. While natural resource use and collection was lowest in the urban areas, a significant amount of resources were still collected by urban households. Income portfolios for all households were calculated to determine the direct-use value of wild natural capital to livelihoods as well as the contribution made from land (arable and livestock farming), welfare grants and employment. Employment, barring one exception in the rural areas of Phalaborwa, was the largest contributor in terms of mean annual income along the continuum in both towns, followed by grants and pensions in the township and rural areas. In Phalaborwa, however, wild natural capital was found to be the largest contributor to local livelihoods, contributing 48.0% of the mean annual income. Household portfolios become more diversified in the poorer, rural areas as well as in households headed by females. The main shocks reported along the continuum in both Queenstown and Phalaborwa were death in the family, followed by a loss of employment, which was concentrated in male-headed households. Coping strategies resulting in the attainment of cash income fast, such as borrowing money from friends/relatives and cashing in retirements savings were favoured over longer term strategies such as finding local wage employment. Female-headed households were found to rely significantly on social groups or clubs as a coping strategy, highlighting the importance of social capital and social relations in female-headed households
- Full Text:
- Date Issued: 2013
- Authors: Evans, Michelle Leigh
- Date: 2013
- Subjects: Natural resources -- South Africa -- Queenstown Natural resources -- South Africa -- Phalaborwa Rural-urban divide -- South Africa -- Queenstown Rural-urban divide -- South Africa -- Phalaborwa Income -- South Africa -- Queenstown Income -- South Africa -- Phalaborwa Women heads of households -- South Africa -- Queenstown Women heads of households -- South Africa -- Phalaborwa Adjustment (Psychology)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4731 , http://hdl.handle.net/10962/d1001958
- Description: Rapid urbanisation is one of the greatest challenges facing both developed and developing countries. Sub-Saharan Africa has historically been one of the least developed and least urbanised areas of the world. However, urbanisation is now occurring much more rapidly in countries that have lower levels of per capita income. Therefore, in the coming decades, urban population growth is expected to be more widespread in the developing countries of the world. Most research on the role of natural resources focuses on rural communities and little is known about the contribution these resources make along the rural-urban continuum in small and medium sized towns as well as the contribution to total livelihoods. This is because researchers and policy makers have often treated rural and urban areas and their residents as distinct entities that should be studied in isolation. This, however, is not a true reflection of household livelihoods which often include both rural and urban elements. This study therefore analysed the impact of urbanisation on livelihoods along a rural-urban continuum with an emphasis on natural resources in South Africa. The main characteristics as well as the livelihood portfolios of respondent households were investigated. Secondly, the coping strategies used by households along the rural-urban continuum were explored, and disaggregated according to the gender of the household head. Data were collected along the rural-urban continuum of two small towns, namely Queenstown, located in the Eastern Cape province and Phalaborwa, located in the Limpopo Province of South Africa. Sampling covered the town, peri-urban areas, townships and adjacent rural households. A standardised survey instrument was used to capture household details and livelihood activities and a total of 272 interviews were conducted. The rural areas near both towns were poorer than the township and urban areas with regards to assets, access to employment and annual household income across all cash and non-cash income streams. The engagement in land-based activities increased towards the rural areas. The use of natural resources, as well as the number of resources collected, increased along the continuum towards the rural areas, with 12.0% to 49.0% of urban households, 30.0% to 88.0% of township households and between 80.0% and 100.0% of rural households engaging in the use and collection of natural resources. While natural resource use and collection was lowest in the urban areas, a significant amount of resources were still collected by urban households. Income portfolios for all households were calculated to determine the direct-use value of wild natural capital to livelihoods as well as the contribution made from land (arable and livestock farming), welfare grants and employment. Employment, barring one exception in the rural areas of Phalaborwa, was the largest contributor in terms of mean annual income along the continuum in both towns, followed by grants and pensions in the township and rural areas. In Phalaborwa, however, wild natural capital was found to be the largest contributor to local livelihoods, contributing 48.0% of the mean annual income. Household portfolios become more diversified in the poorer, rural areas as well as in households headed by females. The main shocks reported along the continuum in both Queenstown and Phalaborwa were death in the family, followed by a loss of employment, which was concentrated in male-headed households. Coping strategies resulting in the attainment of cash income fast, such as borrowing money from friends/relatives and cashing in retirements savings were favoured over longer term strategies such as finding local wage employment. Female-headed households were found to rely significantly on social groups or clubs as a coping strategy, highlighting the importance of social capital and social relations in female-headed households
- Full Text:
- Date Issued: 2013
Livelihoods and natural resource use along the rural-urban continuum
- Authors: Ward, Catherine Dale
- Date: 2013
- Subjects: Natural resources -- South Africa , Human ecology -- South Africa , Cities and towns -- Growth -- South Africa , Natural resources -- Management -- South Africa , Rural poor -- South Africa , Urban poor -- South Africa , Sustainable development -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4727 , http://hdl.handle.net/10962/d1001669 , Natural resources -- South Africa , Human ecology -- South Africa , Cities and towns -- Growth -- South Africa , Natural resources -- Management -- South Africa , Rural poor -- South Africa , Urban poor -- South Africa , Sustainable development -- South Africa
- Description: Over the last century, developing countries have undergone rapid urbanisation resulting in marked social, economic and environmental changes. Africa is the least urbanised continent in the world but trends indicate that it is also the most rapidly urbanising region, accompanied by rising urban poverty. Urbanisation processes are often most pronounced in smaller urban centres since they experience the most severe pressures of population growth. Little is known about the role natural resources play along the rural-urban continuum and even less is known about the contribution of these resources within an urban context, particularly in small urban centres. In many sub-Saharan African cities, urban agriculture (the informal production of food in urban areas) has been used as a strategy to cope with increasing poverty levels but its role remains widely debated and uncertain. This thesis seeks to analyse the impacts of urbanisation on livelihoods and natural resource use, including home gardening and the collection of wild resources, in two South African towns and data was collected along the rural-urban continuum in Queenstown (Eastern Cape province) and Phalaborwa (Limpopo Province). Practices and contributions associated with agriculture and wild resource use were found to be significantly higher in Phalaborwa and this could be attributed to favourable environmental conditions and accessibility to wild resources due to the surrounding Mopani Bushveld. Rural households in Queenstown and Phalaborwa were more reliant on natural resources than their urban counterparts, but still diverse and incorporated a number of land-based and cash income generating strategies. Urban households tended to rely on one primary cash income strategy such as wage employment or state grants. However, natural resources did appear to play a subtle role in urban settings and particularly in the townships, where exclusion of natural resource contributions saw poverty levels increase up to 5%. Home gardening was practised by a wide range of people and not restricted to any one income group and, not surprisingly, wealthy cultivators who had access to resources such as land, water and fertilizer enjoyed increased benefits such as high produce yields. The results obtained suggest that rural-urban dynamics are complex and natural resource use in local livelihoods is contextualised within environmental settings, social preferences and historical contexts. Increasing pressures from the influx of people into small urban centres calls for a better understanding to how these processes are affecting livelihoods and natural resources to ensure sustainable management in the future.
- Full Text:
- Date Issued: 2013
- Authors: Ward, Catherine Dale
- Date: 2013
- Subjects: Natural resources -- South Africa , Human ecology -- South Africa , Cities and towns -- Growth -- South Africa , Natural resources -- Management -- South Africa , Rural poor -- South Africa , Urban poor -- South Africa , Sustainable development -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4727 , http://hdl.handle.net/10962/d1001669 , Natural resources -- South Africa , Human ecology -- South Africa , Cities and towns -- Growth -- South Africa , Natural resources -- Management -- South Africa , Rural poor -- South Africa , Urban poor -- South Africa , Sustainable development -- South Africa
- Description: Over the last century, developing countries have undergone rapid urbanisation resulting in marked social, economic and environmental changes. Africa is the least urbanised continent in the world but trends indicate that it is also the most rapidly urbanising region, accompanied by rising urban poverty. Urbanisation processes are often most pronounced in smaller urban centres since they experience the most severe pressures of population growth. Little is known about the role natural resources play along the rural-urban continuum and even less is known about the contribution of these resources within an urban context, particularly in small urban centres. In many sub-Saharan African cities, urban agriculture (the informal production of food in urban areas) has been used as a strategy to cope with increasing poverty levels but its role remains widely debated and uncertain. This thesis seeks to analyse the impacts of urbanisation on livelihoods and natural resource use, including home gardening and the collection of wild resources, in two South African towns and data was collected along the rural-urban continuum in Queenstown (Eastern Cape province) and Phalaborwa (Limpopo Province). Practices and contributions associated with agriculture and wild resource use were found to be significantly higher in Phalaborwa and this could be attributed to favourable environmental conditions and accessibility to wild resources due to the surrounding Mopani Bushveld. Rural households in Queenstown and Phalaborwa were more reliant on natural resources than their urban counterparts, but still diverse and incorporated a number of land-based and cash income generating strategies. Urban households tended to rely on one primary cash income strategy such as wage employment or state grants. However, natural resources did appear to play a subtle role in urban settings and particularly in the townships, where exclusion of natural resource contributions saw poverty levels increase up to 5%. Home gardening was practised by a wide range of people and not restricted to any one income group and, not surprisingly, wealthy cultivators who had access to resources such as land, water and fertilizer enjoyed increased benefits such as high produce yields. The results obtained suggest that rural-urban dynamics are complex and natural resource use in local livelihoods is contextualised within environmental settings, social preferences and historical contexts. Increasing pressures from the influx of people into small urban centres calls for a better understanding to how these processes are affecting livelihoods and natural resources to ensure sustainable management in the future.
- Full Text:
- Date Issued: 2013
Log analysis aided by latent semantic mapping
- Authors: Buys, Stephanus
- Date: 2013 , 2013-04-14
- Subjects: Latent semantic indexing , Data mining , Computer networks -- Security measures , Computer hackers , Computer security
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4575 , http://hdl.handle.net/10962/d1002963 , Latent semantic indexing , Data mining , Computer networks -- Security measures , Computer hackers , Computer security
- Description: In an age of zero-day exploits and increased on-line attacks on computing infrastructure, operational security practitioners are becoming increasingly aware of the value of the information captured in log events. Analysis of these events is critical during incident response, forensic investigations related to network breaches, hacking attacks and data leaks. Such analysis has led to the discipline of Security Event Analysis, also known as Log Analysis. There are several challenges when dealing with events, foremost being the increased volumes at which events are often generated and stored. Furthermore, events are often captured as unstructured data, with very little consistency in the formats or contents of the events. In this environment, security analysts and implementers of Log Management (LM) or Security Information and Event Management (SIEM) systems face the daunting task of identifying, classifying and disambiguating massive volumes of events in order for security analysis and automation to proceed. Latent Semantic Mapping (LSM) is a proven paradigm shown to be an effective method of, among other things, enabling word clustering, document clustering, topic clustering and semantic inference. This research is an investigation into the practical application of LSM in the discipline of Security Event Analysis, showing the value of using LSM to assist practitioners in identifying types of events, classifying events as belonging to certain sources or technologies and disambiguating different events from each other. The culmination of this research presents adaptations to traditional natural language processing techniques that resulted in improved efficacy of LSM when dealing with Security Event Analysis. This research provides strong evidence supporting the wider adoption and use of LSM, as well as further investigation into Security Event Analysis assisted by LSM and other natural language or computer-learning processing techniques. , LaTeX with hyperref package , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
- Authors: Buys, Stephanus
- Date: 2013 , 2013-04-14
- Subjects: Latent semantic indexing , Data mining , Computer networks -- Security measures , Computer hackers , Computer security
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4575 , http://hdl.handle.net/10962/d1002963 , Latent semantic indexing , Data mining , Computer networks -- Security measures , Computer hackers , Computer security
- Description: In an age of zero-day exploits and increased on-line attacks on computing infrastructure, operational security practitioners are becoming increasingly aware of the value of the information captured in log events. Analysis of these events is critical during incident response, forensic investigations related to network breaches, hacking attacks and data leaks. Such analysis has led to the discipline of Security Event Analysis, also known as Log Analysis. There are several challenges when dealing with events, foremost being the increased volumes at which events are often generated and stored. Furthermore, events are often captured as unstructured data, with very little consistency in the formats or contents of the events. In this environment, security analysts and implementers of Log Management (LM) or Security Information and Event Management (SIEM) systems face the daunting task of identifying, classifying and disambiguating massive volumes of events in order for security analysis and automation to proceed. Latent Semantic Mapping (LSM) is a proven paradigm shown to be an effective method of, among other things, enabling word clustering, document clustering, topic clustering and semantic inference. This research is an investigation into the practical application of LSM in the discipline of Security Event Analysis, showing the value of using LSM to assist practitioners in identifying types of events, classifying events as belonging to certain sources or technologies and disambiguating different events from each other. The culmination of this research presents adaptations to traditional natural language processing techniques that resulted in improved efficacy of LSM when dealing with Security Event Analysis. This research provides strong evidence supporting the wider adoption and use of LSM, as well as further investigation into Security Event Analysis assisted by LSM and other natural language or computer-learning processing techniques. , LaTeX with hyperref package , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2013
Low symmetry metallophthalocyanines and their nanoparticle conjugates for photodynamic antimicrobial chemotherapy
- Authors: Masilela, Nkosiphile
- Date: 2013
- Subjects: Nanoparticles Anti-infective agents Chemotherapy Photochemotherapy Quantum dots Gold Silver , Phthalocyanines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4278 , http://hdl.handle.net/10962/d1001906
- Description: This thesis reports on the syntheses of novel low symmetrically substituted Zn, Sn, Ge and Ti MPc complexes containing a single carboxylic or cysteinyl group available for attachments to MNPs. The complexes were extensively characterized by various techniques to ensure their purity. Various metallic nanoparticles consisting of silver (AgNPs), gold (AuNPs) as well as quantum dots (QDs) were successfully prepared and conjugated to the low symmetry phthalocyanine complexes. The conjugates were successfully characterized using many techniques. The Q-band maxima of the MPcs were observed at completely different wavelength regions depending on the nature of the substituents and the central metal used. Blue shifting of the Q band in the absorption spectra was observed for the complexes in the presence of AuNPs, while aggregation was observed in the presence of quantum dots. The complexes were successfully electrospun into polymer fibers for the antimicrobial inhibition of bacteria. The photophysical and photochemical properties of these complexes were extensively investigated. Higher triplet and singlet oxygen quantum yields were achieved for the Ge Pc complexes, with all the complexes giving reasonable singlet oxygen quantum yields. An enhancement in triplet and singlet oxygen quantum yields was observed for all the complexes in the presence of metal nanoparticles. However, the singlet oxygen quantum yields decreased for all the complexes when incorporated into electrospun fibers. The antimicrobial behaviour of the complexes was investigated against Bacillus Subtilis and Staphylococcus Aureus in solution and in the fiber matrix. High antimicrobial inhibitions were observed for the Ge complexes followed by the ZnPc derivatives. All the low symmetry ZnPc derivatives were conjugated to AgNPs and their antimicrobial behaviour was compared to their symmetrical counterparts. The best antimicrobial inhibition behaviour was observed for the low symmetry Pcs when compared to their symmetrical counterparts. In the absence and in the presence of AgNPs, axially ligated SiPc also showed better antimicrobial activity when it was compared to the unsubstituted ZnPc complex.
- Full Text:
- Date Issued: 2013
- Authors: Masilela, Nkosiphile
- Date: 2013
- Subjects: Nanoparticles Anti-infective agents Chemotherapy Photochemotherapy Quantum dots Gold Silver , Phthalocyanines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4278 , http://hdl.handle.net/10962/d1001906
- Description: This thesis reports on the syntheses of novel low symmetrically substituted Zn, Sn, Ge and Ti MPc complexes containing a single carboxylic or cysteinyl group available for attachments to MNPs. The complexes were extensively characterized by various techniques to ensure their purity. Various metallic nanoparticles consisting of silver (AgNPs), gold (AuNPs) as well as quantum dots (QDs) were successfully prepared and conjugated to the low symmetry phthalocyanine complexes. The conjugates were successfully characterized using many techniques. The Q-band maxima of the MPcs were observed at completely different wavelength regions depending on the nature of the substituents and the central metal used. Blue shifting of the Q band in the absorption spectra was observed for the complexes in the presence of AuNPs, while aggregation was observed in the presence of quantum dots. The complexes were successfully electrospun into polymer fibers for the antimicrobial inhibition of bacteria. The photophysical and photochemical properties of these complexes were extensively investigated. Higher triplet and singlet oxygen quantum yields were achieved for the Ge Pc complexes, with all the complexes giving reasonable singlet oxygen quantum yields. An enhancement in triplet and singlet oxygen quantum yields was observed for all the complexes in the presence of metal nanoparticles. However, the singlet oxygen quantum yields decreased for all the complexes when incorporated into electrospun fibers. The antimicrobial behaviour of the complexes was investigated against Bacillus Subtilis and Staphylococcus Aureus in solution and in the fiber matrix. High antimicrobial inhibitions were observed for the Ge complexes followed by the ZnPc derivatives. All the low symmetry ZnPc derivatives were conjugated to AgNPs and their antimicrobial behaviour was compared to their symmetrical counterparts. The best antimicrobial inhibition behaviour was observed for the low symmetry Pcs when compared to their symmetrical counterparts. In the absence and in the presence of AgNPs, axially ligated SiPc also showed better antimicrobial activity when it was compared to the unsubstituted ZnPc complex.
- Full Text:
- Date Issued: 2013
Mathematics teachers' experiences of designing and implementing a circle geometry teaching programme using the van Hiele phases of instruction as a conceptual framework: a Namibian case study
- Authors: Dongwi, Beata Lididimikeni
- Date: 2013
- Subjects: Geometry -- Study and teaching (Secondary) -- Namibia Mathematics -- Study and teaching -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1412 , http://hdl.handle.net/10962/d1003133
- Description: The aim of this case study was to examine, analyze and report on the findings of the experiences of selected mathematics teachers when they used the van Hiele phases of instruction in designing and implementing a Grade 11 circle geometry teaching programme. The sample consisted of three selected mathematics teachers from the school where the researcher teaches. This school is located in the Oshikoto Education Region in Namibia. The school serves a multicultural group of 759 learners from a middle-class economic background. The site and participants were selected conveniently as the researcher had unrestricted access to both the facilities and the participants. This research takes the form of a case study and is underpinned by the interpretive paradigm. Data for this research was collected using a variety of techniques such as interviews, classroom observation and document analysis. This facilitated easy triangulation of the data. The findings of this research make four claims with regard to the experiences of the mathematics teachers with designing and implementing the circle geometry teaching programme using the five van Hiele phases of instruction as a conceptual framework. The findings revealed that firstly, all three participating mathematics teachers used and implemented all the five van Hiele phases of instruction in their lessons I observed. Secondly, the teachers navigated quite freely from one phase of instruction to the next, but also returned to the earlier phases for clarification and reinforcement in their teaching. Thirdly, the teachers saw the phases of instruction as a good pedagogical tool or template for planning and presenting lessons. Fourthly, the majority of the learners followed the instructions and seemed to obtain the answers faster than expected. The lesson presentations were lively and both teachers and learners communicated at length to discover angle properties of circles while developing and nurturing the technical language of geometry.
- Full Text:
- Date Issued: 2013
- Authors: Dongwi, Beata Lididimikeni
- Date: 2013
- Subjects: Geometry -- Study and teaching (Secondary) -- Namibia Mathematics -- Study and teaching -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1412 , http://hdl.handle.net/10962/d1003133
- Description: The aim of this case study was to examine, analyze and report on the findings of the experiences of selected mathematics teachers when they used the van Hiele phases of instruction in designing and implementing a Grade 11 circle geometry teaching programme. The sample consisted of three selected mathematics teachers from the school where the researcher teaches. This school is located in the Oshikoto Education Region in Namibia. The school serves a multicultural group of 759 learners from a middle-class economic background. The site and participants were selected conveniently as the researcher had unrestricted access to both the facilities and the participants. This research takes the form of a case study and is underpinned by the interpretive paradigm. Data for this research was collected using a variety of techniques such as interviews, classroom observation and document analysis. This facilitated easy triangulation of the data. The findings of this research make four claims with regard to the experiences of the mathematics teachers with designing and implementing the circle geometry teaching programme using the five van Hiele phases of instruction as a conceptual framework. The findings revealed that firstly, all three participating mathematics teachers used and implemented all the five van Hiele phases of instruction in their lessons I observed. Secondly, the teachers navigated quite freely from one phase of instruction to the next, but also returned to the earlier phases for clarification and reinforcement in their teaching. Thirdly, the teachers saw the phases of instruction as a good pedagogical tool or template for planning and presenting lessons. Fourthly, the majority of the learners followed the instructions and seemed to obtain the answers faster than expected. The lesson presentations were lively and both teachers and learners communicated at length to discover angle properties of circles while developing and nurturing the technical language of geometry.
- Full Text:
- Date Issued: 2013
Mechanisms of luminescence in α-Al₂O₃:C : investigations using time-resolved optical stimulation and thermoluminescence techniques
- Authors: Nyirenda, Angel Newton
- Date: 2013
- Subjects: Thermoluminescence Aluminum oxide Optically stimulated luminescence dating Radiation dosimetry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5447 , http://hdl.handle.net/10962/d1002961
- Description: Carbon-doped aluminium oxide, α-Al₂O₃:C, is a ultra-sensitive dosimeter of topical research interest. The aim of this project was to investigate the dynamics of luminesce in this material. The methods of investigation consisted of thermoluminescence and time-resolved optical stimulation. Thermoluminescence measurements provide information on trap distribution and kinetic parameters of the traps involved in luminescence whereas time-resolved optical stimulation is a handy technique in investigation of luminescence lifetimes and provides an insight into the charge transitions between traps and recombination centres. Measurements were made on samples annealed at a nominal temperature of 900⁰C for 15 minutes. The material shows the presence of five thermoluminescence peaks at 37⁰C, 160⁰C, 300⁰C 410⁰C, and 480⁰C at a heating rate of 0.03k/s when irradiated to 6.0 Gy of beta. The main peak at 160⁰C, shows a linear dose response for doses between 0.1 Gy and 10 Gy and then goes sublinear above 10 Gy, the peak at 37⁰C shows a sublinear dose response for doses between 0.1 Gy and 10 Gy and appears to saturate thereafter, whereas the dose response of the peak at 300⁰C goes from linear to supralinear then apparently quadratic behaviour in the dose range of 0.1 Gy to 16.0 Gy. The trap depth of the main peak, that is, its activation energy as determined below the conduction band, has been approximated at 1.3 eV with a kinetic order of approximately 1.2. Time-resolved optical stimulation has been used to investigate luminescence lifetimes. The mean luminescence lifetime obtained for the sample at ambient temperatures is 35.0±1.0 ms. The investigations of the dependence of luminescence lifetimes on measurement temperature show that the material suffers from thermal quenching effects at measurement temperatures above 140⁰C with the activation energy of thermal quenching estimated at 1.045±0.002 eV. Shallow traps i.e. traps lying close to the conduction band, seem to elongate the lifetimes of optically stimulated luminescence in the material at temperatures between 30⁰C - 80⁰C due to charge retrapping. The material exhibits both fading and recuperation of the optically stimulated luminescence signal with storage time.
- Full Text:
- Date Issued: 2013
- Authors: Nyirenda, Angel Newton
- Date: 2013
- Subjects: Thermoluminescence Aluminum oxide Optically stimulated luminescence dating Radiation dosimetry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5447 , http://hdl.handle.net/10962/d1002961
- Description: Carbon-doped aluminium oxide, α-Al₂O₃:C, is a ultra-sensitive dosimeter of topical research interest. The aim of this project was to investigate the dynamics of luminesce in this material. The methods of investigation consisted of thermoluminescence and time-resolved optical stimulation. Thermoluminescence measurements provide information on trap distribution and kinetic parameters of the traps involved in luminescence whereas time-resolved optical stimulation is a handy technique in investigation of luminescence lifetimes and provides an insight into the charge transitions between traps and recombination centres. Measurements were made on samples annealed at a nominal temperature of 900⁰C for 15 minutes. The material shows the presence of five thermoluminescence peaks at 37⁰C, 160⁰C, 300⁰C 410⁰C, and 480⁰C at a heating rate of 0.03k/s when irradiated to 6.0 Gy of beta. The main peak at 160⁰C, shows a linear dose response for doses between 0.1 Gy and 10 Gy and then goes sublinear above 10 Gy, the peak at 37⁰C shows a sublinear dose response for doses between 0.1 Gy and 10 Gy and appears to saturate thereafter, whereas the dose response of the peak at 300⁰C goes from linear to supralinear then apparently quadratic behaviour in the dose range of 0.1 Gy to 16.0 Gy. The trap depth of the main peak, that is, its activation energy as determined below the conduction band, has been approximated at 1.3 eV with a kinetic order of approximately 1.2. Time-resolved optical stimulation has been used to investigate luminescence lifetimes. The mean luminescence lifetime obtained for the sample at ambient temperatures is 35.0±1.0 ms. The investigations of the dependence of luminescence lifetimes on measurement temperature show that the material suffers from thermal quenching effects at measurement temperatures above 140⁰C with the activation energy of thermal quenching estimated at 1.045±0.002 eV. Shallow traps i.e. traps lying close to the conduction band, seem to elongate the lifetimes of optically stimulated luminescence in the material at temperatures between 30⁰C - 80⁰C due to charge retrapping. The material exhibits both fading and recuperation of the optically stimulated luminescence signal with storage time.
- Full Text:
- Date Issued: 2013
Microsatellite and morphometric analysis of chokka squid (Loligo reynaudi) from different spawning aggregations around the South African coast
- Authors: Stonier, Terence Anthony
- Date: 2013
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5344 , http://hdl.handle.net/10962/d1006779
- Description: Accurate information on stock structure is very important to the effective management of any commercially exploited species (Angel et al. 1994), particularly in annual species like Loligo reynaudi. Previous molecular work on a number of fish and cephalopod species has shown that stock structuring may be more complex than originally believed and while much scientific work has been conducted on Loligo reynaudi to date, molecular work has been lacking and this species’ fishery is currently managed as a single stock. The primary aim of this project was to examine the population genetics of Loligo reynaudi on a molecular level, by looking at the levels of genetic variation between different spawning aggregations along the inshore distribution of the chokka squid, with particular attention being paid to any variation between Eastern Cape and Agulhas Bank groups. The secondary aim was to conduct a morphological analysis on samples from the same major areas in order to see if any genetic variation observed would be complemented by phenotypic variation. Two separate sample sets were collected; Genetic samples were collected from 6 different spawning sites along the South African Coast between April and July, 2006 and whole individuals for morphometric analysis were collected from 4 spawning sites between April and July 2007. Samples were screened for genetic variation between different spawning aggregations along the inshore distribution of chokka squid, from Port Alfred in the Eastern Cape, to the western Agulhas Bank. After this a morphometric analysis on samples from the same major areas, Eastern Cape, Agulhas Bank and Angola, was carried out. Genetic results showed significant variation between some of the sample groups. As expected, the Angolan outgroup consistently showed significant variation from other samples, while there was evidence of differentiation between the South African samples themselves. These results could have implications for the previously documented life cycle model of Loligo reynaudi and provide a basis for further study at a finer resolution into where exactly the boundaries of these different groupings can be found. This stock structuring has implications for the management of the species and warrants further genetic research with microsatellites proving to be a powerful tool in the explanation of stock structuring. Unfortunately, due to possible errors in taking measurements, morphometric analysis did not yield useful results which can be described and interpreted in this study. It is felt that further genetic study conducted on a finer scale, should be accompanied by a repeat of the morphometric analysis.
- Full Text:
- Date Issued: 2013
- Authors: Stonier, Terence Anthony
- Date: 2013
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5344 , http://hdl.handle.net/10962/d1006779
- Description: Accurate information on stock structure is very important to the effective management of any commercially exploited species (Angel et al. 1994), particularly in annual species like Loligo reynaudi. Previous molecular work on a number of fish and cephalopod species has shown that stock structuring may be more complex than originally believed and while much scientific work has been conducted on Loligo reynaudi to date, molecular work has been lacking and this species’ fishery is currently managed as a single stock. The primary aim of this project was to examine the population genetics of Loligo reynaudi on a molecular level, by looking at the levels of genetic variation between different spawning aggregations along the inshore distribution of the chokka squid, with particular attention being paid to any variation between Eastern Cape and Agulhas Bank groups. The secondary aim was to conduct a morphological analysis on samples from the same major areas in order to see if any genetic variation observed would be complemented by phenotypic variation. Two separate sample sets were collected; Genetic samples were collected from 6 different spawning sites along the South African Coast between April and July, 2006 and whole individuals for morphometric analysis were collected from 4 spawning sites between April and July 2007. Samples were screened for genetic variation between different spawning aggregations along the inshore distribution of chokka squid, from Port Alfred in the Eastern Cape, to the western Agulhas Bank. After this a morphometric analysis on samples from the same major areas, Eastern Cape, Agulhas Bank and Angola, was carried out. Genetic results showed significant variation between some of the sample groups. As expected, the Angolan outgroup consistently showed significant variation from other samples, while there was evidence of differentiation between the South African samples themselves. These results could have implications for the previously documented life cycle model of Loligo reynaudi and provide a basis for further study at a finer resolution into where exactly the boundaries of these different groupings can be found. This stock structuring has implications for the management of the species and warrants further genetic research with microsatellites proving to be a powerful tool in the explanation of stock structuring. Unfortunately, due to possible errors in taking measurements, morphometric analysis did not yield useful results which can be described and interpreted in this study. It is felt that further genetic study conducted on a finer scale, should be accompanied by a repeat of the morphometric analysis.
- Full Text:
- Date Issued: 2013