My Friend, the stranger: Somali spaza shop operators in the villages around Cofimvaba, Eastern Cape, South Africa
- Authors: Maselwa, Avuyile
- Date: 2017
- Subjects: Immigrant business enterprises -- South Africa -- Eastern Cape , Somalis -- South Africa -- Eastern Cape , Somalis -- South Africa -- Eastern Cape -- Public opinion , Somalis -- South Africa -- Eastern Cape -- Case studies
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/41738 , vital:25127
- Description: This thesis presents a study of the relationships between Somali spaza operators and the villagers living in the villages around Cofimvaba. The Somali spaza operators are operating spazas in the villages around Cofimvaba in the Intsika Yethu District Municipality (IYDM) located in the Chris Hani District Municipality (CHDM). Spaza shops are general dealers selling daily consumption items, which usually operate in the informal sector, primarily in poorer black neighbourhoods, both urban and rural. Resentment of the very visible, post-apartheid, expansion of immigrant entrepreneurship - in the informal sector, notably in spazas- has been central to South African anti-immigrant sentiment, popularly dubbed “xenophobia,” which casts foreigners, mainly black or Asian, as stealing South African resources. Foreign spaza operators, many of them Somalis, have been subject to ongoing violence and looting for well over a decade, notably in the Eastern Cape and Western Cape provinces. Yet in the deeply impoverished villages around Cofimvaba, in the former Transkei black homeland in the Eastern Cape, where Somalis play a central and growing role in spazas, such attacks are unknown. The aim of this thesis is to understand why. Careful qualitative research in several villages has indicated key reasons. These include the relative absence of South African, locally- owned spazas, and so, the lack of a local group driving xenophobic resentment; the convenience offered by Somali-owned spazas in these isolated villages, the affordability of the products offered, and the availability of systems of credit for villagers; the investment of the Somali entrepreneurs into the villages through acts like charity; and their social interaction with villagers. The Somalis have redefined the local spaza sector, to the benefit of the villagers, and there is a degree of “xenophilia” as a result. The research also found that the growing number of Somali spaza operators in the villages was a direct result of the xenophobia experienced by this group in the urban townships. The villages around Cofimvaba benefit the Somali operator, not in a financial sense as these are not where the most profits have been made, but as sites where the traders feel safest. But although the villages are a sort of refuge, they are isolated and isolating. The Somalis resident in these areas struggle to maintain the strong ethnic group consciousness based on a strong vision of the Somali homeland, and a sense of being sojourners, hoping to relocate elsewhere.
- Full Text:
- Date Issued: 2017
- Authors: Maselwa, Avuyile
- Date: 2017
- Subjects: Immigrant business enterprises -- South Africa -- Eastern Cape , Somalis -- South Africa -- Eastern Cape , Somalis -- South Africa -- Eastern Cape -- Public opinion , Somalis -- South Africa -- Eastern Cape -- Case studies
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/41738 , vital:25127
- Description: This thesis presents a study of the relationships between Somali spaza operators and the villagers living in the villages around Cofimvaba. The Somali spaza operators are operating spazas in the villages around Cofimvaba in the Intsika Yethu District Municipality (IYDM) located in the Chris Hani District Municipality (CHDM). Spaza shops are general dealers selling daily consumption items, which usually operate in the informal sector, primarily in poorer black neighbourhoods, both urban and rural. Resentment of the very visible, post-apartheid, expansion of immigrant entrepreneurship - in the informal sector, notably in spazas- has been central to South African anti-immigrant sentiment, popularly dubbed “xenophobia,” which casts foreigners, mainly black or Asian, as stealing South African resources. Foreign spaza operators, many of them Somalis, have been subject to ongoing violence and looting for well over a decade, notably in the Eastern Cape and Western Cape provinces. Yet in the deeply impoverished villages around Cofimvaba, in the former Transkei black homeland in the Eastern Cape, where Somalis play a central and growing role in spazas, such attacks are unknown. The aim of this thesis is to understand why. Careful qualitative research in several villages has indicated key reasons. These include the relative absence of South African, locally- owned spazas, and so, the lack of a local group driving xenophobic resentment; the convenience offered by Somali-owned spazas in these isolated villages, the affordability of the products offered, and the availability of systems of credit for villagers; the investment of the Somali entrepreneurs into the villages through acts like charity; and their social interaction with villagers. The Somalis have redefined the local spaza sector, to the benefit of the villagers, and there is a degree of “xenophilia” as a result. The research also found that the growing number of Somali spaza operators in the villages was a direct result of the xenophobia experienced by this group in the urban townships. The villages around Cofimvaba benefit the Somali operator, not in a financial sense as these are not where the most profits have been made, but as sites where the traders feel safest. But although the villages are a sort of refuge, they are isolated and isolating. The Somalis resident in these areas struggle to maintain the strong ethnic group consciousness based on a strong vision of the Somali homeland, and a sense of being sojourners, hoping to relocate elsewhere.
- Full Text:
- Date Issued: 2017
My madam: same race, different class: living and working conditions of undocumented, migrant BaSotho domestic workers employed in black middle class houshold
- Madonsela, Koketso Njabulo Gosiame
- Authors: Madonsela, Koketso Njabulo Gosiame
- Date: 2017
- Subjects: Black women household empoyees -- South Africa , Black employers -- South Africa , Women household employees -- South Africa , Women, Sotho -- Employment -- South Africa , Businesspeople, Black -- South Africa , Migrant labor -- South Africa , Illegal aliens -- South Africa , Master and servant -- South Africa , Women, Black -- Employment -- South Africa , Industrial relations -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/35166 , vital:24337
- Description: Jacklyn Cock’s Maids and Madams is a study on domestic work in the Eastern Cape which places a focus on black domestic workers who work in white families. Cock’s study was ground-breaking research within labour development in South Africa (with regards to domestic service). The apartheid system regarded domestic work as that of social reproduction: domestic workers left their families to replenish and reproduce the labour power of white families, whose members were employed in a formal workplace. The contribution to this system, according to Cock (1989), was unbreakable because they did not earn enough money to disrupt the system. The respondents of this thesis are undocumented migrant Basotho domestic workers. These domestic workers have much in common with Cock’s respondents. For one, they leave their homes and families to replenish the labour power of black middle class families, whose members are employed in a formal workplace. The difference between this thesis and Cock’s study is that the respondents’ employers are members of the black middle class. Furthermore, the employees are undocumented Basotho domestic workers. Undocumented, migrant, Basotho domestic workers are in a similarly vulnerable position to that of Cock’s respondents. This dissertation engages with the extent to which Maids and Madams is still relevant to the living and working conditions of a new vulnerable workforce in the domestic sector: undocumented, female, Basotho domestic workers employed in black, middle-class households in Gauteng. The dissertation also finds that the relationship between the black migrant domestic worker and the black middle class employer is influenced cultural aspects of what domestic chores represent in black families, and the element of respect from employers (particularly to elderly domestic workers) or lack thereof. This dissertation underlines that the term “ousi” makes the Basotho domestic workers a collective, and not individuals. Thus the term “ousi” can be viewed as the term that takes away the identity of the domestic worker. The theoretical framework of the research is labour process theory (LPT). The new wave of labour process theorists are much more focused on the service industry. LPT is significant to this research because its focus is on the subjective experiences of the workers. This is the core purpose of the thesis. The focus of the new wave LPT involves a shift from understanding workers at a macro level to understanding the subjective experiences of the workers (in the service industry) at a micro level. This provides an appropriate framework to study the subjective working and living experiences of undocumented, migrant, Basotho domestic workers. The research design is based on qualitative research. The research made use of in-depth and semi-structured interviews. The selection of respondents was done through purposive sampling. They findings of this research highlighted the central themes in the relevant literature. However, the key findings of this research also reveal tensions and contradictions that are not explored in detail in the existing literature. For example, the relationship between the black middle class employer and the black domestic worker has tensions which originate from a cultural context. The respondents of this dissertation and their employers are of the same race, yet are of a different class.
- Full Text:
- Date Issued: 2017
- Authors: Madonsela, Koketso Njabulo Gosiame
- Date: 2017
- Subjects: Black women household empoyees -- South Africa , Black employers -- South Africa , Women household employees -- South Africa , Women, Sotho -- Employment -- South Africa , Businesspeople, Black -- South Africa , Migrant labor -- South Africa , Illegal aliens -- South Africa , Master and servant -- South Africa , Women, Black -- Employment -- South Africa , Industrial relations -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/35166 , vital:24337
- Description: Jacklyn Cock’s Maids and Madams is a study on domestic work in the Eastern Cape which places a focus on black domestic workers who work in white families. Cock’s study was ground-breaking research within labour development in South Africa (with regards to domestic service). The apartheid system regarded domestic work as that of social reproduction: domestic workers left their families to replenish and reproduce the labour power of white families, whose members were employed in a formal workplace. The contribution to this system, according to Cock (1989), was unbreakable because they did not earn enough money to disrupt the system. The respondents of this thesis are undocumented migrant Basotho domestic workers. These domestic workers have much in common with Cock’s respondents. For one, they leave their homes and families to replenish the labour power of black middle class families, whose members are employed in a formal workplace. The difference between this thesis and Cock’s study is that the respondents’ employers are members of the black middle class. Furthermore, the employees are undocumented Basotho domestic workers. Undocumented, migrant, Basotho domestic workers are in a similarly vulnerable position to that of Cock’s respondents. This dissertation engages with the extent to which Maids and Madams is still relevant to the living and working conditions of a new vulnerable workforce in the domestic sector: undocumented, female, Basotho domestic workers employed in black, middle-class households in Gauteng. The dissertation also finds that the relationship between the black migrant domestic worker and the black middle class employer is influenced cultural aspects of what domestic chores represent in black families, and the element of respect from employers (particularly to elderly domestic workers) or lack thereof. This dissertation underlines that the term “ousi” makes the Basotho domestic workers a collective, and not individuals. Thus the term “ousi” can be viewed as the term that takes away the identity of the domestic worker. The theoretical framework of the research is labour process theory (LPT). The new wave of labour process theorists are much more focused on the service industry. LPT is significant to this research because its focus is on the subjective experiences of the workers. This is the core purpose of the thesis. The focus of the new wave LPT involves a shift from understanding workers at a macro level to understanding the subjective experiences of the workers (in the service industry) at a micro level. This provides an appropriate framework to study the subjective working and living experiences of undocumented, migrant, Basotho domestic workers. The research design is based on qualitative research. The research made use of in-depth and semi-structured interviews. The selection of respondents was done through purposive sampling. They findings of this research highlighted the central themes in the relevant literature. However, the key findings of this research also reveal tensions and contradictions that are not explored in detail in the existing literature. For example, the relationship between the black middle class employer and the black domestic worker has tensions which originate from a cultural context. The respondents of this dissertation and their employers are of the same race, yet are of a different class.
- Full Text:
- Date Issued: 2017
Negotiating the line between information and panic: a case study of vanguard’s coverage of the ebola outbreak in Nigeria
- Authors: Akingbade, Olutobi Elijah
- Date: 2017
- Subjects: Digital media -- Marketing , Marketing -- Technological innovations , Internet marketing , Carbonated beverages -- Marketing , Coca Cola (Trademark) -- Marketing , Social media -- Economic aspects , Soft drink industry -- Internet marketing , Health behavior in adolescence , Advertising -- Carbonated beverages , Obesity in adolescence , Drinking behavior
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/5903 , vital:20986
- Description: This study titled ‘Negotiating the line between information and panic: A case study of Vanguard’s coverage of the Ebola Outbreak in Nigeria’ investigates and evaluates Vanguard’s coverage of the 2014 Ebola Virus Disease (EVD) outbreak in Nigeria. This study was conducted to understand how Vanguard negotiated the line between the dissemination of actual EVD information and the possibility of creating panic and fear during the coverage of the outbreak. Using qualitative content analysis and interview embedded within a qualitative research design, the study was carried out against the backdrop of relevant literature that asserts that the mass media is an important carrier, prime mover and producer of tensions, anxieties, fears and panics while the print media specifically is argued to have as part of its history the business of irrational fear mongering and the creation of panic about social problems. Vanguard, rated as one of the ten largest newspapers in Nigeria, was purposively selected for this study. Vanguard did substantial reporting and dissemination of the 2014 EVD outbreak and it was possible to draw on the availability and accessibility of the electronic archives of the EVD articles. Using the theory of moral panic, the normative theories of the media and theories about essential constituents of journalism culture as a theoretical framework, the study reveals that Vanguard’s coverage of the 2014 EVD outbreak was challenging and more demanding compared to coverage of previous outbreaks of viral diseases in Nigeria by the print medium. The study shows that lack of sufficient understanding of the science that underlies EVD, the initial exclusion of the media from the national response to contain the outbreak, and the lack of sufficient proactive measures by government and the print medium were powerful factors in how the epidemic was reported. The study also shows an interesting dimension in Vanguard’s early and latter coverage of the EVD outbreak while it lasted in Nigeria. This dimension reveals a high number of EVD articles with the propensity to inspire fear and panic in the early days of the coverage compared to EVD articles with the propensity to douse fear and panic in the early and latter days of the outbreak. The study shows that while the challenges encountered stem from Ebola’s mode of transmission, lack of scientific and medically proven cure and early coverage amidst uncertainties, the inherent tensions and anxieties that characterised the outbreak coupled with Vanguard’s fire brigade approach led to the relatively high number of EVD articles with the propensity to inspire fear and panic. The study recommends the mass media’s inclusion in national responses to epidemics and ongoing training for health journalists to update their knowledge base about emerging and infectious diseases. The study also recommends for further study a reception analysis to enhance the socio-cultural understanding of how the EVD articles were received.
- Full Text:
- Date Issued: 2017
- Authors: Akingbade, Olutobi Elijah
- Date: 2017
- Subjects: Digital media -- Marketing , Marketing -- Technological innovations , Internet marketing , Carbonated beverages -- Marketing , Coca Cola (Trademark) -- Marketing , Social media -- Economic aspects , Soft drink industry -- Internet marketing , Health behavior in adolescence , Advertising -- Carbonated beverages , Obesity in adolescence , Drinking behavior
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/5903 , vital:20986
- Description: This study titled ‘Negotiating the line between information and panic: A case study of Vanguard’s coverage of the Ebola Outbreak in Nigeria’ investigates and evaluates Vanguard’s coverage of the 2014 Ebola Virus Disease (EVD) outbreak in Nigeria. This study was conducted to understand how Vanguard negotiated the line between the dissemination of actual EVD information and the possibility of creating panic and fear during the coverage of the outbreak. Using qualitative content analysis and interview embedded within a qualitative research design, the study was carried out against the backdrop of relevant literature that asserts that the mass media is an important carrier, prime mover and producer of tensions, anxieties, fears and panics while the print media specifically is argued to have as part of its history the business of irrational fear mongering and the creation of panic about social problems. Vanguard, rated as one of the ten largest newspapers in Nigeria, was purposively selected for this study. Vanguard did substantial reporting and dissemination of the 2014 EVD outbreak and it was possible to draw on the availability and accessibility of the electronic archives of the EVD articles. Using the theory of moral panic, the normative theories of the media and theories about essential constituents of journalism culture as a theoretical framework, the study reveals that Vanguard’s coverage of the 2014 EVD outbreak was challenging and more demanding compared to coverage of previous outbreaks of viral diseases in Nigeria by the print medium. The study shows that lack of sufficient understanding of the science that underlies EVD, the initial exclusion of the media from the national response to contain the outbreak, and the lack of sufficient proactive measures by government and the print medium were powerful factors in how the epidemic was reported. The study also shows an interesting dimension in Vanguard’s early and latter coverage of the EVD outbreak while it lasted in Nigeria. This dimension reveals a high number of EVD articles with the propensity to inspire fear and panic in the early days of the coverage compared to EVD articles with the propensity to douse fear and panic in the early and latter days of the outbreak. The study shows that while the challenges encountered stem from Ebola’s mode of transmission, lack of scientific and medically proven cure and early coverage amidst uncertainties, the inherent tensions and anxieties that characterised the outbreak coupled with Vanguard’s fire brigade approach led to the relatively high number of EVD articles with the propensity to inspire fear and panic. The study recommends the mass media’s inclusion in national responses to epidemics and ongoing training for health journalists to update their knowledge base about emerging and infectious diseases. The study also recommends for further study a reception analysis to enhance the socio-cultural understanding of how the EVD articles were received.
- Full Text:
- Date Issued: 2017
New rules or no rules? a critical corpus analysis of gender in South African English televised-sport commentary
- Authors: Foster, Gordon
- Date: 2017
- Subjects: Critical discourse analysis , Sportscasters -- Language , Masculinity in sports , Masculinity in mass media , Mass media and sports , Competition (Psychology)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/36116 , vital:24480
- Description: This research project makes use of multiple linguistic and sociological theories. Using Critical Discourse Analysis (as developed by Fairclough 2001, 2013, Wodak 1995, 1997, and van Dijk 2001), and corpus linguistics (following Baker 2012, Baker et al., 2008 and Xiao & McEnery, 2005 - see Website Reference 4), it attempts to critically discuss the language evident in a corpus constructed from transcribed sport broadcasts televised in South Africa, interrogated with the use of AntConc software, maintaining a particular focus on gender representation. It does this with the help of CMT (Contemporary Metaphor Theory) as developed by Lakoff and Johnson (1980) and Lakoff (1993), which allows for the deconstruction and categorisation of metaphorical mappings in the data. With the help of CMT I describe the cognitive mapping of competition through war terminology and uncover a diligent committal to discourses which support hegemonic masculinity, as well as an underlying ideology that purports that rules are breakable and rule infringement will not be significantly penalised (particularly for men). Special attention is paid to collocating language and the ability of these terms to infuse a subject with an evaluative aura. This involves, in particular: using wordlists to identify pertinent content words in the corpus, addressing collocates to reveal semantic prosodies in the text, and analysing concordance data to see how particular discursive strategies were used in context. Particular interest is paid to the depictions of masculinity seen in sport as a potential reflection of the views held in competitive sport playing societies at large, and to this end it focuses on language and imagery which is used in the discursive construction of the terms: men, women, champion, and physicality. The ideology of male hegemony is found to be dominant in the corpus data, seen in, among other things: the positioning of women, the inclusion of traditional discourses relating to the performance of masculinity and the construction of the 'new man'. White, heterosexual men are shown to be represented as exemplars of hegemonic masculinity, subordinating both black and homosexual men. Laughter is also seen as affirmation of the naturalised cheekiness of men and boys and their tendency to break rules in order to succeed, and betting is identified as a potentially destructive influence in sport.
- Full Text:
- Date Issued: 2017
- Authors: Foster, Gordon
- Date: 2017
- Subjects: Critical discourse analysis , Sportscasters -- Language , Masculinity in sports , Masculinity in mass media , Mass media and sports , Competition (Psychology)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/36116 , vital:24480
- Description: This research project makes use of multiple linguistic and sociological theories. Using Critical Discourse Analysis (as developed by Fairclough 2001, 2013, Wodak 1995, 1997, and van Dijk 2001), and corpus linguistics (following Baker 2012, Baker et al., 2008 and Xiao & McEnery, 2005 - see Website Reference 4), it attempts to critically discuss the language evident in a corpus constructed from transcribed sport broadcasts televised in South Africa, interrogated with the use of AntConc software, maintaining a particular focus on gender representation. It does this with the help of CMT (Contemporary Metaphor Theory) as developed by Lakoff and Johnson (1980) and Lakoff (1993), which allows for the deconstruction and categorisation of metaphorical mappings in the data. With the help of CMT I describe the cognitive mapping of competition through war terminology and uncover a diligent committal to discourses which support hegemonic masculinity, as well as an underlying ideology that purports that rules are breakable and rule infringement will not be significantly penalised (particularly for men). Special attention is paid to collocating language and the ability of these terms to infuse a subject with an evaluative aura. This involves, in particular: using wordlists to identify pertinent content words in the corpus, addressing collocates to reveal semantic prosodies in the text, and analysing concordance data to see how particular discursive strategies were used in context. Particular interest is paid to the depictions of masculinity seen in sport as a potential reflection of the views held in competitive sport playing societies at large, and to this end it focuses on language and imagery which is used in the discursive construction of the terms: men, women, champion, and physicality. The ideology of male hegemony is found to be dominant in the corpus data, seen in, among other things: the positioning of women, the inclusion of traditional discourses relating to the performance of masculinity and the construction of the 'new man'. White, heterosexual men are shown to be represented as exemplars of hegemonic masculinity, subordinating both black and homosexual men. Laughter is also seen as affirmation of the naturalised cheekiness of men and boys and their tendency to break rules in order to succeed, and betting is identified as a potentially destructive influence in sport.
- Full Text:
- Date Issued: 2017
New spaces and old stories: the Luminance woman, black womanhood and the illusion of the “new” South Africa
- Alweendo, Ndapwa Magano Nelao
- Authors: Alweendo, Ndapwa Magano Nelao
- Date: 2017
- Subjects: Luminance stores (South Africa) , Dhlomo, Khanyi , Dlamini, Judy , Women, Black -- South Africa -- Social life and customes , Women, Black -- South Africa -- Social conditions , Clothing trade -- South Africa , Social classes -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/42619 , vital:25220
- Description: This study examines ideas of black womanhood in post-apartheid South Africa. The opening of the Luminance boutique in 2013, previously owned by South African businesswoman and media mogul Khanyi Dhlomo in Johannesburg’s ultra-exclusive Hyde Park Corner, has been articulated as representing a rupture in the public and private performance of black womanhood. Luminance has positioned itself as a provider of world-class style and beauty and has embraced a narrative of black women’s empowerment in the process. The study is based on narrative semistructured interviews conducted Johannesburg with black women who have shopped at the boutique and women who believe themselves as having a meaningful connection to the store. The literature on black women, both internationally and in South Africa, acknowledges that black women experience multiple and intersecting oppressions of race, class and gender, among others. Located within black feminist theory, the study argues that the Luminance woman does represent some rupture in the historic understanding of black womanhood in South Africa. This woman is an elite player in both the corporate world and the world of luxury consumption, and is certainly entering spaces to which black women have historically been denied access. However, this study argues that there is a danger in reducing this woman to an oversimplified character, allowing responses to her to ignore the complexities of her reality in favour of the simplicity of her story, and ignore the structural socioeconomic challenges that continue to shape the lives of all black women in postapartheid South Africa. In this regard, the Luminance woman, while on the surface appearing to be an empowering new iteration of womanhood that should inspire other black woman, contributes to the erasure of her particular marginal experiences, and the oppression of black women in general. The story of the Luminance women contributes to a narrative of individual hard work and determination that frames her as a respectable example of what the “new” South Africa has delivered for its citizens. This woman is a model example of a South African who has succeeded because she took advantage of the opportunities supposedly afforded to all in the post-1994 era. It is therefore argued that praise of the Luminance woman serves a dual purpose: to reinforce the myth of equal opportunity in South Africa, and to lessen the legitimacy of marginalised groups’ experiences of oppression, especially black women who continue to constitute the poor majority.
- Full Text:
- Date Issued: 2017
- Authors: Alweendo, Ndapwa Magano Nelao
- Date: 2017
- Subjects: Luminance stores (South Africa) , Dhlomo, Khanyi , Dlamini, Judy , Women, Black -- South Africa -- Social life and customes , Women, Black -- South Africa -- Social conditions , Clothing trade -- South Africa , Social classes -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/42619 , vital:25220
- Description: This study examines ideas of black womanhood in post-apartheid South Africa. The opening of the Luminance boutique in 2013, previously owned by South African businesswoman and media mogul Khanyi Dhlomo in Johannesburg’s ultra-exclusive Hyde Park Corner, has been articulated as representing a rupture in the public and private performance of black womanhood. Luminance has positioned itself as a provider of world-class style and beauty and has embraced a narrative of black women’s empowerment in the process. The study is based on narrative semistructured interviews conducted Johannesburg with black women who have shopped at the boutique and women who believe themselves as having a meaningful connection to the store. The literature on black women, both internationally and in South Africa, acknowledges that black women experience multiple and intersecting oppressions of race, class and gender, among others. Located within black feminist theory, the study argues that the Luminance woman does represent some rupture in the historic understanding of black womanhood in South Africa. This woman is an elite player in both the corporate world and the world of luxury consumption, and is certainly entering spaces to which black women have historically been denied access. However, this study argues that there is a danger in reducing this woman to an oversimplified character, allowing responses to her to ignore the complexities of her reality in favour of the simplicity of her story, and ignore the structural socioeconomic challenges that continue to shape the lives of all black women in postapartheid South Africa. In this regard, the Luminance woman, while on the surface appearing to be an empowering new iteration of womanhood that should inspire other black woman, contributes to the erasure of her particular marginal experiences, and the oppression of black women in general. The story of the Luminance women contributes to a narrative of individual hard work and determination that frames her as a respectable example of what the “new” South Africa has delivered for its citizens. This woman is a model example of a South African who has succeeded because she took advantage of the opportunities supposedly afforded to all in the post-1994 era. It is therefore argued that praise of the Luminance woman serves a dual purpose: to reinforce the myth of equal opportunity in South Africa, and to lessen the legitimacy of marginalised groups’ experiences of oppression, especially black women who continue to constitute the poor majority.
- Full Text:
- Date Issued: 2017
Ngomso 'special school': contestations of morality and education in the Eastern Cape
- Authors: Pattenden, Oliver
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/65200 , vital:28704
- Description: Expected release date-May 2019
- Full Text:
- Date Issued: 2017
- Authors: Pattenden, Oliver
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/65200 , vital:28704
- Description: Expected release date-May 2019
- Full Text:
- Date Issued: 2017
Nonlinear optical behavior of lanthanide phthalocyanines and their conjugates with a selection of nanomaterials
- Authors: Sekhosana, Kutloano Edward
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/4580 , vital:20695
- Description: This thesis presents novel asymmetrical and symmetrical lanthanide phthalocyanines (Pcs) characterized using a number techniques including proton nuclear magnetic resonance, electron spin resonance, time correlated single photon counting, FTIR spectrometry, MALDI-TOF mass spectrometry, UV-Vis spectrometry, Raman spectroscopy and CHNS elemental analysis. The design of theses lanthanide Pcs takes the form of mononuclear, binuclear, trinuclear, bis- and tris(phthalocyanines). Nanomaterials such as zinc oxide nanoparticles (ZnO NPs), multi-walled carbon nanotubes (MWCNTs) and graphene oxide nanosheets (GONS) (oxidized and reduced) were employed for covalent linkage to mono- and binuclear phthalocyanines as conjugates. Transmission electron microscopy was used to characterize ZnO NPs, MWCNTs and GONS alone and when linked to lanthanide Pcs. Lanthanide Pcs alone and when linked to ZnO NPs, MWCNTs and GONS where embedded in polymers such as poly (methyl methacrylate) (PMMA), poly (bisphenol A carbonate) (PBC) and poly (acrylic acid) (PAA) for thin film preparation. The thickness of the thin films was determined by utilization of the knife edge attachment of the A Bruker D8 Discover X-ray diffraction (XRD). Optical limiting properties of lanthanide Pcs alone and as conjugates in solution and when incorporated into polymers were determined by employing a Z-scan technique. It emerged that low symmetry lanthanide Pcs (19, 20 and 21), the blue forms of bis(phthalocyanines) (only in solution; 24 and 28) as well as tris(phthalocyanines) (30 and 31) exhibit low limiting threshold (Ilim) values in solution and thin films (particularly PBC and PAA). The low limiting threshold values make these lanthanide Pcs reliable optical limiters.
- Full Text:
- Date Issued: 2017
- Authors: Sekhosana, Kutloano Edward
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/4580 , vital:20695
- Description: This thesis presents novel asymmetrical and symmetrical lanthanide phthalocyanines (Pcs) characterized using a number techniques including proton nuclear magnetic resonance, electron spin resonance, time correlated single photon counting, FTIR spectrometry, MALDI-TOF mass spectrometry, UV-Vis spectrometry, Raman spectroscopy and CHNS elemental analysis. The design of theses lanthanide Pcs takes the form of mononuclear, binuclear, trinuclear, bis- and tris(phthalocyanines). Nanomaterials such as zinc oxide nanoparticles (ZnO NPs), multi-walled carbon nanotubes (MWCNTs) and graphene oxide nanosheets (GONS) (oxidized and reduced) were employed for covalent linkage to mono- and binuclear phthalocyanines as conjugates. Transmission electron microscopy was used to characterize ZnO NPs, MWCNTs and GONS alone and when linked to lanthanide Pcs. Lanthanide Pcs alone and when linked to ZnO NPs, MWCNTs and GONS where embedded in polymers such as poly (methyl methacrylate) (PMMA), poly (bisphenol A carbonate) (PBC) and poly (acrylic acid) (PAA) for thin film preparation. The thickness of the thin films was determined by utilization of the knife edge attachment of the A Bruker D8 Discover X-ray diffraction (XRD). Optical limiting properties of lanthanide Pcs alone and as conjugates in solution and when incorporated into polymers were determined by employing a Z-scan technique. It emerged that low symmetry lanthanide Pcs (19, 20 and 21), the blue forms of bis(phthalocyanines) (only in solution; 24 and 28) as well as tris(phthalocyanines) (30 and 31) exhibit low limiting threshold (Ilim) values in solution and thin films (particularly PBC and PAA). The low limiting threshold values make these lanthanide Pcs reliable optical limiters.
- Full Text:
- Date Issued: 2017
Nonlinear optical properties of Sn(IV) phthalocyanines: experimental and theoretical approach
- Authors: Louzada, Marcel Severiano
- Date: 2017
- Subjects: Phthalocyanines , Nonlinear optics
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/57852 , vital:26996
- Description: This work presents the nonlinear properties of six Sn(IV) Phthalocyanines. Three of the phthalocyanines are linked by an alkylthiol substituent and the rest are linked with a phenoxy substituent. For all six compounds non-linear optic analysis was carried out in four solvents: chloroform, toluene, dichloromethane, and tetrahydrofuran, and their differences were recorded. Calculation of the linear, singlet excited, triplet excited and two photon absorption cross-sections were also carried out and the results compared. To form a comparison the first order hyperpolarizabilities, DFT calculations were also performed and the results compared to see if the behaviour between the two properties can be predicted using DFT.
- Full Text:
- Date Issued: 2017
- Authors: Louzada, Marcel Severiano
- Date: 2017
- Subjects: Phthalocyanines , Nonlinear optics
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/57852 , vital:26996
- Description: This work presents the nonlinear properties of six Sn(IV) Phthalocyanines. Three of the phthalocyanines are linked by an alkylthiol substituent and the rest are linked with a phenoxy substituent. For all six compounds non-linear optic analysis was carried out in four solvents: chloroform, toluene, dichloromethane, and tetrahydrofuran, and their differences were recorded. Calculation of the linear, singlet excited, triplet excited and two photon absorption cross-sections were also carried out and the results compared. To form a comparison the first order hyperpolarizabilities, DFT calculations were also performed and the results compared to see if the behaviour between the two properties can be predicted using DFT.
- Full Text:
- Date Issued: 2017
Nonlinear optical responses of phthalocyanines in the presence of nanomaterials or when embedded in polymeric materials
- Authors: Bankole, Owolabi Mutolib
- Date: 2017
- Subjects: Phthalocyanines , Phthalocyanines -- Optical properties , Alkynes , Triazoles , Nonlinear optics , Photochemistry , Complex compounds , Amines , Mercaptopyridine
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/45794 , vital:25548
- Description: This work describes the synthesis, photophysical and nonlinear optical characterizations of alkynyl Pcs (1, 2, 3, 8 and 9), 1,2,3-triazole ZnPc (4), mercaptopyridine Pcs (5, 6 and 7) and amino Pcs (10 and 11). Complexes 1, 2, 4, 7, 8, 9 and 11 were newly synthesized and characterized using techniques including 1H-NMR, MALDI-TOF, UV-visible spectrophotometry, FTIR and elemental analysis. The results of the characterizations were in good agreement with their molecular structures, and confirmed the purity of the new molecules. Complex 10 was covalently linked to pristine graphene (GQDs), nitrogen- doped (NGQDs), and sulfur-nitrogen co-doped (SNGQDs) graphene quantum dots; gold nanoparticles (AuNPs); poly(acrylic acid) (PAA); Fe3O4@Ag core-shell and Fe3O4- Ag hybrid nanoparticles via covalent bonding. Complex 11 was linked to Agx Auy alloy nanoparticles via NH2-Au and/or Au-S bonding, 2 and 3 were linked to gold nanoparticles (AuNPs) via clicked reactions. Evidence of successful conjugation of 2, 3, 10 and 11 to nanomaterials was revealed within the UV-vis, EDS, TEM, XRD and XPS spectra. Optical limiting (OL) responses of the samples were evaluated using open aperture Z-scan technique at 532 nm and 10 ns radiation in solution or when embedded in polymer mixtures. The analyses of the Z-scan data for the studied samples did fit to a two-photon absorption mechanism (2PA), but the Pcs and Pc-nanomaterial or polymer composites also possess the multi-photon absorption mechanisms aided by the triplet-triplet population to have reverse saturable absorption (RSA) occur. Phthalocyanines doped in polymer matrices showed larger nonlinear absorption coefficients (ßeff), third-order susceptibility (Im [x(3)]) and second-order hyperpolarizability (y), with an accompanying low intensity threshold (Ium) than in solution. Aggregation in DMSO negatively affected NLO behaviour of Pcs (8 as a case study) at low laser power, and improved at relatively higher laser power. Heavy atom-substituted Pcs (6) enhanced NLO and OL properties than lighter atoms such as 5 and 7. Direct relationship between enhanced photophysical properties and nonlinear effects favoured by excited triplet absorption of the 2, 3, 10 and 11 in presence of nanomaterials was established. Major factor responsible for the enhanced nonlinearities of 10 in the presence of NGQDs and SNGQDs were fully described and attributed to the surface defects caused by the presence of heteroatoms such as nitrogen and sulfur. The studies showed that phthalocyanines-nanomaterial composites were useful in applications such as optical switching, pulse compressor and laser pulse narrowing.
- Full Text:
- Date Issued: 2017
- Authors: Bankole, Owolabi Mutolib
- Date: 2017
- Subjects: Phthalocyanines , Phthalocyanines -- Optical properties , Alkynes , Triazoles , Nonlinear optics , Photochemistry , Complex compounds , Amines , Mercaptopyridine
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/45794 , vital:25548
- Description: This work describes the synthesis, photophysical and nonlinear optical characterizations of alkynyl Pcs (1, 2, 3, 8 and 9), 1,2,3-triazole ZnPc (4), mercaptopyridine Pcs (5, 6 and 7) and amino Pcs (10 and 11). Complexes 1, 2, 4, 7, 8, 9 and 11 were newly synthesized and characterized using techniques including 1H-NMR, MALDI-TOF, UV-visible spectrophotometry, FTIR and elemental analysis. The results of the characterizations were in good agreement with their molecular structures, and confirmed the purity of the new molecules. Complex 10 was covalently linked to pristine graphene (GQDs), nitrogen- doped (NGQDs), and sulfur-nitrogen co-doped (SNGQDs) graphene quantum dots; gold nanoparticles (AuNPs); poly(acrylic acid) (PAA); Fe3O4@Ag core-shell and Fe3O4- Ag hybrid nanoparticles via covalent bonding. Complex 11 was linked to Agx Auy alloy nanoparticles via NH2-Au and/or Au-S bonding, 2 and 3 were linked to gold nanoparticles (AuNPs) via clicked reactions. Evidence of successful conjugation of 2, 3, 10 and 11 to nanomaterials was revealed within the UV-vis, EDS, TEM, XRD and XPS spectra. Optical limiting (OL) responses of the samples were evaluated using open aperture Z-scan technique at 532 nm and 10 ns radiation in solution or when embedded in polymer mixtures. The analyses of the Z-scan data for the studied samples did fit to a two-photon absorption mechanism (2PA), but the Pcs and Pc-nanomaterial or polymer composites also possess the multi-photon absorption mechanisms aided by the triplet-triplet population to have reverse saturable absorption (RSA) occur. Phthalocyanines doped in polymer matrices showed larger nonlinear absorption coefficients (ßeff), third-order susceptibility (Im [x(3)]) and second-order hyperpolarizability (y), with an accompanying low intensity threshold (Ium) than in solution. Aggregation in DMSO negatively affected NLO behaviour of Pcs (8 as a case study) at low laser power, and improved at relatively higher laser power. Heavy atom-substituted Pcs (6) enhanced NLO and OL properties than lighter atoms such as 5 and 7. Direct relationship between enhanced photophysical properties and nonlinear effects favoured by excited triplet absorption of the 2, 3, 10 and 11 in presence of nanomaterials was established. Major factor responsible for the enhanced nonlinearities of 10 in the presence of NGQDs and SNGQDs were fully described and attributed to the surface defects caused by the presence of heteroatoms such as nitrogen and sulfur. The studies showed that phthalocyanines-nanomaterial composites were useful in applications such as optical switching, pulse compressor and laser pulse narrowing.
- Full Text:
- Date Issued: 2017
Nontsizi Mgqwetho’s the nation’s bounty: a prophetic voice towards an African literary theory
- Authors: Nxasana, Thulani
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/4547 , vital:20687
- Description: This thesis seeks to examine the ways in which Africans and African scholarship in particular have relied on the West to lead the way in scientific inquiry, theory and ways of approaching literary texts thus the stunting effects of this in the growth and development of uniquely African literary scholarship and theorising. In his seminal work, Decolonising the Mind, Wa Thiong’o (1987a) stresses that “...how we view ourselves, our environment even, is very much dependent on where we stand in relationship to imperialism in its colonial and neocolonial stages; that if we are to do anything about our individual and collective being today, then we have to coldly and consciously look at what imperialism has been doing to us and to our view of ourselves in the universe” (Wa Thiong’o, 1987a, p.88). Although most African countries obtained their liberation decades ago, seemingly western cultural imperialism still dominates and plagues the African psyche; hence they largely look to the West and ways of the West for established and emergent theoretical conceptions. This thesis aims to interrogate popular western literary theories unquestioningly used to analyse African works, particularly feminism and post-colonial theory; furthermore, to show crucial factors not taken into account such as the evolving power dynamics in African societies, the role of the “sacred” or spirituality which often forms and informs the dynamics of the text, and lastly, based on the poetry of Nontsizi Mgqwetho, to advocate for the need for an African literary theory and put forward the essential tenets of such a theory. The poetry of Xhosa poet, Nontsizi Mgqwetho, is used to analyse the complexities and dynamics of African literary production written in African languages; her poetry is written in isiXhosa to a Xhosa audience, a far cry from the assumption that African literary texts are concerned with writing to the “centre” as post-colonial theorists claim. Her work explicitly provides Africans with an approach to overcome territorial and cultural imperialism; she sees within the African psyche and traditional values empowering modes of resistance against any type of domination and through her poetry illustrates meaningful ways that Africans can critically engage with and examine the positives and negatives of cultural exchange and or assimilation, and the effects thereof while at the same time remaining proudly Africa.
- Full Text:
- Date Issued: 2017
- Authors: Nxasana, Thulani
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/4547 , vital:20687
- Description: This thesis seeks to examine the ways in which Africans and African scholarship in particular have relied on the West to lead the way in scientific inquiry, theory and ways of approaching literary texts thus the stunting effects of this in the growth and development of uniquely African literary scholarship and theorising. In his seminal work, Decolonising the Mind, Wa Thiong’o (1987a) stresses that “...how we view ourselves, our environment even, is very much dependent on where we stand in relationship to imperialism in its colonial and neocolonial stages; that if we are to do anything about our individual and collective being today, then we have to coldly and consciously look at what imperialism has been doing to us and to our view of ourselves in the universe” (Wa Thiong’o, 1987a, p.88). Although most African countries obtained their liberation decades ago, seemingly western cultural imperialism still dominates and plagues the African psyche; hence they largely look to the West and ways of the West for established and emergent theoretical conceptions. This thesis aims to interrogate popular western literary theories unquestioningly used to analyse African works, particularly feminism and post-colonial theory; furthermore, to show crucial factors not taken into account such as the evolving power dynamics in African societies, the role of the “sacred” or spirituality which often forms and informs the dynamics of the text, and lastly, based on the poetry of Nontsizi Mgqwetho, to advocate for the need for an African literary theory and put forward the essential tenets of such a theory. The poetry of Xhosa poet, Nontsizi Mgqwetho, is used to analyse the complexities and dynamics of African literary production written in African languages; her poetry is written in isiXhosa to a Xhosa audience, a far cry from the assumption that African literary texts are concerned with writing to the “centre” as post-colonial theorists claim. Her work explicitly provides Africans with an approach to overcome territorial and cultural imperialism; she sees within the African psyche and traditional values empowering modes of resistance against any type of domination and through her poetry illustrates meaningful ways that Africans can critically engage with and examine the positives and negatives of cultural exchange and or assimilation, and the effects thereof while at the same time remaining proudly Africa.
- Full Text:
- Date Issued: 2017
Observing and evaluating creative mathematical reasoning through selected VITALmaths video clips and collaborative argumentation
- Authors: Kellen, Matthew Earl
- Date: 2017
- Subjects: Mathematics Study and teaching (Secondary) South Africa Grahamstown , Mathematics Study and teaching (Secondary) Audio-visual aids , Reasoning , Mathematical ability
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/6107 , vital:21032
- Description: Creative mathematical reasoning is a definition that the NCS policies allude to when they indicate the necessity for students to, “identify and solve problems and make decisions using critical and creative thinking.”(NCS, 2011: 9). Silver (1997) and Lithner (2008) focus on creativity of reasoning in terms of the flexibility, fluency and novelty in which one approaches a mathematical problem. Learners who can creatively select appropriate strategies that are mathematically founded, and justify their answers use creative mathematical reasoning. This research uses Visual Technology for the Autonomous Learning of Mathematics (VITALmaths) video clips that pose mathematics problems to stimulate articulated reasoning among small multi-age, multi-ability Grade 9 peer groups. Using VITALmaths clips that pose visual and open-ended task, set the stage for collaborative argumentation between peers. This study observes creative mathematical reasoning in two ways: Firstly by observing the interaction between peers in the process of arriving at an answer, and secondly by examining the end product of the peer group’s justification of their solution. (Ball & Bass, 2003) Six grade 8 and 9 learners from no-fee public schools in the township of Grahamstown, South Africa were selected for this case study. Participants were a mixed ability, mixed gendered, sample group from an after-school programme which focused on creating a space for autonomous learning. The six participants were split into two groups and audio and video recorded as they solved selected VITALmaths tasks and presented their evidence and solutions to the tasks. Audio and video recordings and written work were used to translate, transcribe, and code participant interactions according to a framework adapted from Krummheuer (2007) and Lithner (2008) and Silver (1997) and Toulmin (1954). This constituted the analysis of the process of creative mathematical reasoning. Group presentations of evidence and solutions to the VITALmaths tasks, were used in conjunction with an evaluation framework adapted from Lithner (2008) and Campos (2010). This was the product analysis of creative mathematical reasoning. This research found that there was significant evidence of creative mathematical reasoning in the process and product evaluation of group interactions and solutions. Process analysis showed that participants were very active, engaged, and creative in their participation, but struggled to integrate and implement ideas cohesively. Product analysis similarly showed that depth and concentration of strategies implemented are key to correct and exhaustive mathematically grounded solutions.
- Full Text:
- Date Issued: 2017
- Authors: Kellen, Matthew Earl
- Date: 2017
- Subjects: Mathematics Study and teaching (Secondary) South Africa Grahamstown , Mathematics Study and teaching (Secondary) Audio-visual aids , Reasoning , Mathematical ability
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/6107 , vital:21032
- Description: Creative mathematical reasoning is a definition that the NCS policies allude to when they indicate the necessity for students to, “identify and solve problems and make decisions using critical and creative thinking.”(NCS, 2011: 9). Silver (1997) and Lithner (2008) focus on creativity of reasoning in terms of the flexibility, fluency and novelty in which one approaches a mathematical problem. Learners who can creatively select appropriate strategies that are mathematically founded, and justify their answers use creative mathematical reasoning. This research uses Visual Technology for the Autonomous Learning of Mathematics (VITALmaths) video clips that pose mathematics problems to stimulate articulated reasoning among small multi-age, multi-ability Grade 9 peer groups. Using VITALmaths clips that pose visual and open-ended task, set the stage for collaborative argumentation between peers. This study observes creative mathematical reasoning in two ways: Firstly by observing the interaction between peers in the process of arriving at an answer, and secondly by examining the end product of the peer group’s justification of their solution. (Ball & Bass, 2003) Six grade 8 and 9 learners from no-fee public schools in the township of Grahamstown, South Africa were selected for this case study. Participants were a mixed ability, mixed gendered, sample group from an after-school programme which focused on creating a space for autonomous learning. The six participants were split into two groups and audio and video recorded as they solved selected VITALmaths tasks and presented their evidence and solutions to the tasks. Audio and video recordings and written work were used to translate, transcribe, and code participant interactions according to a framework adapted from Krummheuer (2007) and Lithner (2008) and Silver (1997) and Toulmin (1954). This constituted the analysis of the process of creative mathematical reasoning. Group presentations of evidence and solutions to the VITALmaths tasks, were used in conjunction with an evaluation framework adapted from Lithner (2008) and Campos (2010). This was the product analysis of creative mathematical reasoning. This research found that there was significant evidence of creative mathematical reasoning in the process and product evaluation of group interactions and solutions. Process analysis showed that participants were very active, engaged, and creative in their participation, but struggled to integrate and implement ideas cohesively. Product analysis similarly showed that depth and concentration of strategies implemented are key to correct and exhaustive mathematically grounded solutions.
- Full Text:
- Date Issued: 2017
On the shop-floor: ten years at Ford
- Authors: Cilibe, Mpumelelo
- Date: 2017
- Subjects: Creative writing (Higher education) South Africa , South African fiction (English) 21st century , Autobiographical fiction, South African (English) 21st century , Xhosa fiction 21st century , Short stories, Xhosa 21st century
- Language: English , Xhosa
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/7257 , vital:21234
- Description: My autobiographical novella covers a period of my life between 1974 and 1984, when I worked at the Ford Motor company Struandale Assembly plant in Port Elizabeth. This period predated the formation of NUMSA (the National Union of Metal Workers of South Africa) and COSATU - it was a time when automobile industry workers broke away from the race- based unions to form MACWUSA (Motor Assemblers and Component Workers Union of SA). Around the same time Rev Leon Sullivan was putting pressure on US companies, including Ford, to move away from apartheid labour practices. As quite an angry young man influenced by the Black Consciousness movement, I got deeply involved in union activities mainly for my own survival, and as a personal reaction to racism in the workplace. The story is told in a realist style, with many anecdotal detours giving the flavour of life in New Brighton in the 1980s. Important influences have been Bloke Modisane's autobiography, Blame Me on History and Studs Terkel's interviews of Ford plant workers and management in his book Working. , Growing up in New Brighton gave me so many stories that had never been written before but that were told person to person by the residents of my neighbourhood. Some of the tales in this collection are based on such stories. Others are stories that are reminiscent of childhood while growing up with an elder brother. I take the inspiration from different books that are in line with the stories that I am writing: collections of Extreme Fiction - Fabulists and Formalists that were edited by Robin Hemley and Michael Martone and The Best Bizarro Fiction of the Decade edited by Jeremy Robert Johnson and Cameron Pierce. Some stories by L.L. Ngewu and L.S. Ngcangata, and a novellette by P.T. Mtuze, Alitshoni Lingaphumi, also bring much influence as they reveal suffering in the lives of black people who endured forced removals, and other situations that are of interest to build my stories on. , Le ngqokolela yamabali iqulathe amabali asekelwe kumabali endandiweva ebaliswa ebuntwaneni bam ndisakhula. Amanye amabali angeenkumbulo zasebuntwaneni ngethuba ndandikhula nomkhuluwa wam ongasaphiliyo. Ifuthe lokuwaqamba ndilifumene kwiincwadi zababhali abanje ngabo bafumaneka kwiingqokolela ezihlelwe nguRobin Hemley no Michael Martone kwincwadi ethi Extreme Fiction - Fabulists and Formalists, noJeremy Robert Johnson enoCameron Pierce kwingqokolela ethi, The Best Bizarro Fiction of the Decade. Amanye amabali abenefuthe ndiwafumene kwiincwadi zooP.T. Mtuze, kwinovella yakhe ethi Alitshoni Lingaphumi, nakwezoL.L. Ngewu noL.S. Ngcangatha apho babalisa ngobomi basekuhlaleni ngexesha abantu babedudulwa befuduswa ngetshova ukususwa kwiindawo zabo zokuhlala. , This thesis is presented in two parts: English and isiXhosa
- Full Text:
- Date Issued: 2017
- Authors: Cilibe, Mpumelelo
- Date: 2017
- Subjects: Creative writing (Higher education) South Africa , South African fiction (English) 21st century , Autobiographical fiction, South African (English) 21st century , Xhosa fiction 21st century , Short stories, Xhosa 21st century
- Language: English , Xhosa
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/7257 , vital:21234
- Description: My autobiographical novella covers a period of my life between 1974 and 1984, when I worked at the Ford Motor company Struandale Assembly plant in Port Elizabeth. This period predated the formation of NUMSA (the National Union of Metal Workers of South Africa) and COSATU - it was a time when automobile industry workers broke away from the race- based unions to form MACWUSA (Motor Assemblers and Component Workers Union of SA). Around the same time Rev Leon Sullivan was putting pressure on US companies, including Ford, to move away from apartheid labour practices. As quite an angry young man influenced by the Black Consciousness movement, I got deeply involved in union activities mainly for my own survival, and as a personal reaction to racism in the workplace. The story is told in a realist style, with many anecdotal detours giving the flavour of life in New Brighton in the 1980s. Important influences have been Bloke Modisane's autobiography, Blame Me on History and Studs Terkel's interviews of Ford plant workers and management in his book Working. , Growing up in New Brighton gave me so many stories that had never been written before but that were told person to person by the residents of my neighbourhood. Some of the tales in this collection are based on such stories. Others are stories that are reminiscent of childhood while growing up with an elder brother. I take the inspiration from different books that are in line with the stories that I am writing: collections of Extreme Fiction - Fabulists and Formalists that were edited by Robin Hemley and Michael Martone and The Best Bizarro Fiction of the Decade edited by Jeremy Robert Johnson and Cameron Pierce. Some stories by L.L. Ngewu and L.S. Ngcangata, and a novellette by P.T. Mtuze, Alitshoni Lingaphumi, also bring much influence as they reveal suffering in the lives of black people who endured forced removals, and other situations that are of interest to build my stories on. , Le ngqokolela yamabali iqulathe amabali asekelwe kumabali endandiweva ebaliswa ebuntwaneni bam ndisakhula. Amanye amabali angeenkumbulo zasebuntwaneni ngethuba ndandikhula nomkhuluwa wam ongasaphiliyo. Ifuthe lokuwaqamba ndilifumene kwiincwadi zababhali abanje ngabo bafumaneka kwiingqokolela ezihlelwe nguRobin Hemley no Michael Martone kwincwadi ethi Extreme Fiction - Fabulists and Formalists, noJeremy Robert Johnson enoCameron Pierce kwingqokolela ethi, The Best Bizarro Fiction of the Decade. Amanye amabali abenefuthe ndiwafumene kwiincwadi zooP.T. Mtuze, kwinovella yakhe ethi Alitshoni Lingaphumi, nakwezoL.L. Ngewu noL.S. Ngcangatha apho babalisa ngobomi basekuhlaleni ngexesha abantu babedudulwa befuduswa ngetshova ukususwa kwiindawo zabo zokuhlala. , This thesis is presented in two parts: English and isiXhosa
- Full Text:
- Date Issued: 2017
Oxygen limitation and thermal tolerance: a comparison of pulmonate and patellogastropod limpets
- Authors: Kankondi, Sebbi
- Date: 2017
- Subjects: Thermal tolerance (Physiology) , Limpets -- Physiology , Limpets -- Effect of temperature on , Oxygen consumption (Physiology)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7570 , vital:21274
- Description: Since the scientific community anticipates a general change in the global climate, it has become increasingly important to develop predictive models which encompass mechanisms to generate reliable forecasts of the effects this change on ecological communities and processes. To this end, the oxygen- and capacity- limited thermal tolerance (OCLTT) theory has been developed as a link between various physiological processes, the thermal aspect of climate change and the associated shifts at different levels of biological organization. This study set out to assess the general applicability of the OCLTT theory in eurythermal pulmonate and patellogastropod limpets, whose distributions overlap on the high shore rocks of the warm temperate, south-east coast of South Africa.This was done by determining their microhabitat use, median lethal temperatures and cardiac, Arrhenius breakpoint temperatures as measures of their upper thermal tolerance limits, in both air and water. The main hypotheses of the study were that the pulmonate limpets would be more common than the patellogastropods in warmer microhabitats during low tide and would have higher thermal limits than the patellogastropods in air and vice versa in water. This was based on the assumption that the two limpet groups have different capabilities of oxygen consumption in air and water, due to differences in their respiratory organs and that this would be reflected in their thermal tolerances based on predictions made by the OCLTT. This assumption was important because oxygen consumption was not measured in this study. Previous research (e.g. Garrity, 1984), showed that a thermal stress gradient exists among rocky intertidal microhabitats. From most to least thermally stressful the gradient is horizontal surfaces> slopes> vertical surfaces> tide pools> crevices. The current study found that, while the pulmonate limpets, Siphonaria capensis and S. serrata, preferred rock pools, sloped, vertical and horizontal rock surfaces, the patellogastropod limpets, Cellana capensis and Scutellastra granularis, preferred rock pools and vertical rock surfaces. Furthermore, the pulmonate limpets were only common on horizontal rock surfaces where specific ameliorating conditions would have mitigated thermal stress there. In addition, C. capensis had similar thermal tolerance limits to the pulmonate limpets in air and the pulmonate limpets had similar and/or higher thermal tolerance limits compared to S. granularis in water. This indicates that the pulmonate limpets did not necessarily prefer warmer microhabitats than the patellogastropod limpets and that there were no differences in the collective upper thermal tolerance limits between the two limpet groups in either medium.Consequently, there was no indication from this study that an assumed superior capacity for oxygen supply translates into greater thermal tolerance and that the hypotheses based on the OCLTT were not supported. Although this was an indirect test of the OCLTT theory, I conclude that this study does not support the notion of its general applicability and that mechanisms other than those outlined by the OCLTT theory may help explain the patterns of thermal limitation observed in the current study.
- Full Text:
- Date Issued: 2017
- Authors: Kankondi, Sebbi
- Date: 2017
- Subjects: Thermal tolerance (Physiology) , Limpets -- Physiology , Limpets -- Effect of temperature on , Oxygen consumption (Physiology)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7570 , vital:21274
- Description: Since the scientific community anticipates a general change in the global climate, it has become increasingly important to develop predictive models which encompass mechanisms to generate reliable forecasts of the effects this change on ecological communities and processes. To this end, the oxygen- and capacity- limited thermal tolerance (OCLTT) theory has been developed as a link between various physiological processes, the thermal aspect of climate change and the associated shifts at different levels of biological organization. This study set out to assess the general applicability of the OCLTT theory in eurythermal pulmonate and patellogastropod limpets, whose distributions overlap on the high shore rocks of the warm temperate, south-east coast of South Africa.This was done by determining their microhabitat use, median lethal temperatures and cardiac, Arrhenius breakpoint temperatures as measures of their upper thermal tolerance limits, in both air and water. The main hypotheses of the study were that the pulmonate limpets would be more common than the patellogastropods in warmer microhabitats during low tide and would have higher thermal limits than the patellogastropods in air and vice versa in water. This was based on the assumption that the two limpet groups have different capabilities of oxygen consumption in air and water, due to differences in their respiratory organs and that this would be reflected in their thermal tolerances based on predictions made by the OCLTT. This assumption was important because oxygen consumption was not measured in this study. Previous research (e.g. Garrity, 1984), showed that a thermal stress gradient exists among rocky intertidal microhabitats. From most to least thermally stressful the gradient is horizontal surfaces> slopes> vertical surfaces> tide pools> crevices. The current study found that, while the pulmonate limpets, Siphonaria capensis and S. serrata, preferred rock pools, sloped, vertical and horizontal rock surfaces, the patellogastropod limpets, Cellana capensis and Scutellastra granularis, preferred rock pools and vertical rock surfaces. Furthermore, the pulmonate limpets were only common on horizontal rock surfaces where specific ameliorating conditions would have mitigated thermal stress there. In addition, C. capensis had similar thermal tolerance limits to the pulmonate limpets in air and the pulmonate limpets had similar and/or higher thermal tolerance limits compared to S. granularis in water. This indicates that the pulmonate limpets did not necessarily prefer warmer microhabitats than the patellogastropod limpets and that there were no differences in the collective upper thermal tolerance limits between the two limpet groups in either medium.Consequently, there was no indication from this study that an assumed superior capacity for oxygen supply translates into greater thermal tolerance and that the hypotheses based on the OCLTT were not supported. Although this was an indirect test of the OCLTT theory, I conclude that this study does not support the notion of its general applicability and that mechanisms other than those outlined by the OCLTT theory may help explain the patterns of thermal limitation observed in the current study.
- Full Text:
- Date Issued: 2017
Patterns of plant diversity and cultural meaning in a rural landscape in the Albany Thicket: effects of land-use and topography
- Authors: Ngqiyaza, Nozuko Princess
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/50237 , vital:25969
- Description: South Africa is the world's third most bio-diverse country, but pressures on this biodiversity are many and widespread. It is now well recognised that protected areas on their own are insufficient to protect biodiversity, and increasing emphasis is placed on developing models for ensuring the persistence of biodiversity in agricultural and rural landscapes. One of the major challenges, especially in rural areas, is the need to reconcile people’s need to use natural resources with biodiversity conservation. This study aimed to (1) examine the ecosystem services people derive from the natural vegetation and how this is distributed in space and (2) the effects of land use and topo-edaphic factors on species richness, composition and structure and how this is spatially distributed. I investigated two land-use types, i.e. a rural village and adjacent lightly used game farm(s) by comparing 20 sites under each land-use representing the range of topographic position. I sampled respondent’s uses and values, species richness and composition, woody density, structure and composition at these 40 sites. This allowed for comparison between the two land uses but also allowed me to examine the effect of topography and relative soil moisture (both known to have a string influence on vegetation in semi-arid areas), and to relate the ecosystem services to plant species richness, structure and woody composition. People derived a wide range of ecosystem services and this differed with distance from the village and vegetation type. Men and women performed different tasks and had different feelings and derived different use values across the landscapes. Both men and women showed a great appreciation for the thicket forest, Pteronia-dominated and grasslands sites. They recognised these areas and as sacred grounds where they have a strong connection with their ancestors. Women preferred utilising areas closer to the village because they feared crime and wild animals in more remote thicket or forest, while men utilised all areas across the land, but more frequently closer to the village. The older generation had a strong attachment to nature, perceiving it as a provider. The younger generation, especially the young women did not express such a deeply felt connection, but enjoyed getting to see where some of the medicinal plants and useful wood structures were harvested. Younger men would go far into the forest quite regularly, often as far the Great Fish River, when they hunt with their peers. Although a diversity of perceptions were presented, and not all conformed to traditional views and practices, most respondents derived a mix of ecosystem services, with the areas closer to the village providing recreational and direct use value to more people on a more regular basis but spiritual values associated with deep forest persisted, especially among the older generation. Species richness and composition was analysed in relation to Topographic Relative Moisture Index (TRMI), land use and distance from the village to see the effect of topography versus land use on the vegetation. The total number of plant species recorded was 386 for both study sites. Two hundred and ninety two species were recorded in Ntloko and 265 on the game farms. Of the species that were sampled, 121 were recorded in Ntloko only, 94 in the game farms only, and 171 species were shared. The number of useful plant species (fuel, medicine, forage, cultural and edibles) was recorded to be 110, 83 in Ntloko and 63 on the game farms. There was no significant difference in species richness and alpha diversity between the study sites, but the game farms had a higher projected total number of species, reflecting higher beta diversity in the game farms than the communal area. The point-centered quarter method (PCQ) was used to describe woody plant composition, tree density and structure. The woody structure and composition was analysed in relation to the above-mentioned factors and I found no significant difference in the density and overall woody structure and composition between the two study sites. Sites at Ntloko had a positive correlation between soil moisture and woody plant density and a higher density of palatable and unpalatable species. The game farms showed no significant changes in woody plant density with TRMI. This study showed that the communal area maintained comparable plant species richness and vegetation structure and composition to game farms. The rural landscape comprised a gradient from sites close to the village that were heavily impacted, not considered particularly special or sacred but safe, familiar and of utilitarian importance, to sites farther away with denser, less transformed thicket vegetation, which are considered to be of greater cultural, spiritual and aesthetic importance but less safe, familiar and accessible. This suggests that conservation outcomes can be achieved outside protected areas, and that biodiversity is valuable to local residents. Resource management should be implemented to maintain the ecosystem services provided in rural areas in a way that integrates local peoples’ perceptions, goals and values with ecological evidence.
- Full Text:
- Date Issued: 2017
- Authors: Ngqiyaza, Nozuko Princess
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/50237 , vital:25969
- Description: South Africa is the world's third most bio-diverse country, but pressures on this biodiversity are many and widespread. It is now well recognised that protected areas on their own are insufficient to protect biodiversity, and increasing emphasis is placed on developing models for ensuring the persistence of biodiversity in agricultural and rural landscapes. One of the major challenges, especially in rural areas, is the need to reconcile people’s need to use natural resources with biodiversity conservation. This study aimed to (1) examine the ecosystem services people derive from the natural vegetation and how this is distributed in space and (2) the effects of land use and topo-edaphic factors on species richness, composition and structure and how this is spatially distributed. I investigated two land-use types, i.e. a rural village and adjacent lightly used game farm(s) by comparing 20 sites under each land-use representing the range of topographic position. I sampled respondent’s uses and values, species richness and composition, woody density, structure and composition at these 40 sites. This allowed for comparison between the two land uses but also allowed me to examine the effect of topography and relative soil moisture (both known to have a string influence on vegetation in semi-arid areas), and to relate the ecosystem services to plant species richness, structure and woody composition. People derived a wide range of ecosystem services and this differed with distance from the village and vegetation type. Men and women performed different tasks and had different feelings and derived different use values across the landscapes. Both men and women showed a great appreciation for the thicket forest, Pteronia-dominated and grasslands sites. They recognised these areas and as sacred grounds where they have a strong connection with their ancestors. Women preferred utilising areas closer to the village because they feared crime and wild animals in more remote thicket or forest, while men utilised all areas across the land, but more frequently closer to the village. The older generation had a strong attachment to nature, perceiving it as a provider. The younger generation, especially the young women did not express such a deeply felt connection, but enjoyed getting to see where some of the medicinal plants and useful wood structures were harvested. Younger men would go far into the forest quite regularly, often as far the Great Fish River, when they hunt with their peers. Although a diversity of perceptions were presented, and not all conformed to traditional views and practices, most respondents derived a mix of ecosystem services, with the areas closer to the village providing recreational and direct use value to more people on a more regular basis but spiritual values associated with deep forest persisted, especially among the older generation. Species richness and composition was analysed in relation to Topographic Relative Moisture Index (TRMI), land use and distance from the village to see the effect of topography versus land use on the vegetation. The total number of plant species recorded was 386 for both study sites. Two hundred and ninety two species were recorded in Ntloko and 265 on the game farms. Of the species that were sampled, 121 were recorded in Ntloko only, 94 in the game farms only, and 171 species were shared. The number of useful plant species (fuel, medicine, forage, cultural and edibles) was recorded to be 110, 83 in Ntloko and 63 on the game farms. There was no significant difference in species richness and alpha diversity between the study sites, but the game farms had a higher projected total number of species, reflecting higher beta diversity in the game farms than the communal area. The point-centered quarter method (PCQ) was used to describe woody plant composition, tree density and structure. The woody structure and composition was analysed in relation to the above-mentioned factors and I found no significant difference in the density and overall woody structure and composition between the two study sites. Sites at Ntloko had a positive correlation between soil moisture and woody plant density and a higher density of palatable and unpalatable species. The game farms showed no significant changes in woody plant density with TRMI. This study showed that the communal area maintained comparable plant species richness and vegetation structure and composition to game farms. The rural landscape comprised a gradient from sites close to the village that were heavily impacted, not considered particularly special or sacred but safe, familiar and of utilitarian importance, to sites farther away with denser, less transformed thicket vegetation, which are considered to be of greater cultural, spiritual and aesthetic importance but less safe, familiar and accessible. This suggests that conservation outcomes can be achieved outside protected areas, and that biodiversity is valuable to local residents. Resource management should be implemented to maintain the ecosystem services provided in rural areas in a way that integrates local peoples’ perceptions, goals and values with ecological evidence.
- Full Text:
- Date Issued: 2017
Perceptions and livelihood uses of an invasive alien tree (acacia dealbata) by rural communities in the Eastern Cape
- Authors: Agripa, Ngorima
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/5326 , vital:20813
- Description: The negative impacts which invasive alien species have on ecosystems are well documented but there is paucity of information on their impacts on rural communities. Due to ecological impacts that may be associated with Acacia dealbata invasions the Agricultural Research Council Plant Protection Institute is considering releasing a biocontrol agent for A. dealbata. The actual social impacts of A. dealbata invasion and control are likely to be related to its importance in rural livelihoods. This thesis reports on the perceptions and livelihood uses of A. dealbata in the Eastern Cape. Three study sites were assessed, Matatiele, Mount Fletcher and Maclear. The study involved 150 household surveys, one focus group discussion and one transect walk at each site, key informant interviews and frequent house visits to acquire reliable data. Results show that 100 % of households in the three sites use Silver Wattle extensively for firewood. In Matatiele 64 %, 72 % in Mount Fletcher and 84 % of households in Maclear use Silver Wattle for fencing. To carve tools 76 % in Matatiele, 76 % in Mount Fletcher and 84 % households in Maclear use Silver Wattle. For medicinal purposes 18 % in Matatiele, 20 % in Mount Fletcher and 16 % in Maclear use Silver Wattle, whilst 78 % in Matatiele, 80 % in Mount Fletcher and 80 % in Maclear use it for fodder purposes. Many respondents felt that Silver Wattle is too abundant within their areas such that it now has many negative impacts associated with it. Perceptions of local people towards A. dealbata are neither static nor uniform, but are influenced by time since the invasion and now abundance of the species. There are no alternatives which provide the same services provided by Silver Wattle. Benefits and constraints due to A. dealbata invasion are experienced by everyone irrespective of wealth and gender. In conclusion, Silver Wattle is a valuable resource to these rural communities, but increasing abundance is incurring high costs to grazing resources and landscape accessibility.
- Full Text:
- Date Issued: 2017
- Authors: Agripa, Ngorima
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/5326 , vital:20813
- Description: The negative impacts which invasive alien species have on ecosystems are well documented but there is paucity of information on their impacts on rural communities. Due to ecological impacts that may be associated with Acacia dealbata invasions the Agricultural Research Council Plant Protection Institute is considering releasing a biocontrol agent for A. dealbata. The actual social impacts of A. dealbata invasion and control are likely to be related to its importance in rural livelihoods. This thesis reports on the perceptions and livelihood uses of A. dealbata in the Eastern Cape. Three study sites were assessed, Matatiele, Mount Fletcher and Maclear. The study involved 150 household surveys, one focus group discussion and one transect walk at each site, key informant interviews and frequent house visits to acquire reliable data. Results show that 100 % of households in the three sites use Silver Wattle extensively for firewood. In Matatiele 64 %, 72 % in Mount Fletcher and 84 % of households in Maclear use Silver Wattle for fencing. To carve tools 76 % in Matatiele, 76 % in Mount Fletcher and 84 % households in Maclear use Silver Wattle. For medicinal purposes 18 % in Matatiele, 20 % in Mount Fletcher and 16 % in Maclear use Silver Wattle, whilst 78 % in Matatiele, 80 % in Mount Fletcher and 80 % in Maclear use it for fodder purposes. Many respondents felt that Silver Wattle is too abundant within their areas such that it now has many negative impacts associated with it. Perceptions of local people towards A. dealbata are neither static nor uniform, but are influenced by time since the invasion and now abundance of the species. There are no alternatives which provide the same services provided by Silver Wattle. Benefits and constraints due to A. dealbata invasion are experienced by everyone irrespective of wealth and gender. In conclusion, Silver Wattle is a valuable resource to these rural communities, but increasing abundance is incurring high costs to grazing resources and landscape accessibility.
- Full Text:
- Date Issued: 2017
Phenomenology: preconceptions and experiences of non-chemists at Rhodes University using milk paint
- Authors: Kelly, Kelvin Leigh
- Date: 2017
- Subjects: Phenomenology , Art and science , Casein , Paint , Chemistry -- Study and teaching , Science -- Study and teaching -- Philosophy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/37942 , vital:24711
- Description: There exists an ever-increasing crisis in science education where students experience disinterest because of an inability to grasp true understanding of scientific subjects, and therefore there should be a call to increase the research of phenomenology in combination with science education. A rebalance and paradigm shift in the focus of the modes of teaching could result in a great improvement in the learning, comprehension, and intellectual self-confidence of students interested in the sciences. To study this, three research questions were established: How is chemistry perceived by non-chemists; what is the experience of the participants’ during the chemistry practical in a laboratory and; do the participants’ perspectives about chemistry change during the experience. The performed study consisted of a chemistry practical, two art works and, in some cases, an interview. Nine participants were asked to create the art under specific instructions of points of focus, namely their preconceptions prior to the practical (Artwork 1) and their lived experience during the practical (Artwork 2). Participants’ artworks were examined using methods of visual semiotics and classical art analysis techniques, looking at line, shape, and colour choice. The iterative analysis of the interviews from participants 1, 2, 7, and 9 coded with ATLAS.ti 7 software, led to the emergence of themes that constitute the core of the participants’ experience. This phenomenological study presents a path to engage the non-chemist with processes taking place in the laboratory by using ‘Kitchen Chemistry’ and illustrates how a phenomenological engagement with chemistry can make the subject more applicable to the general population of non-chemists.
- Full Text:
- Date Issued: 2017
- Authors: Kelly, Kelvin Leigh
- Date: 2017
- Subjects: Phenomenology , Art and science , Casein , Paint , Chemistry -- Study and teaching , Science -- Study and teaching -- Philosophy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/37942 , vital:24711
- Description: There exists an ever-increasing crisis in science education where students experience disinterest because of an inability to grasp true understanding of scientific subjects, and therefore there should be a call to increase the research of phenomenology in combination with science education. A rebalance and paradigm shift in the focus of the modes of teaching could result in a great improvement in the learning, comprehension, and intellectual self-confidence of students interested in the sciences. To study this, three research questions were established: How is chemistry perceived by non-chemists; what is the experience of the participants’ during the chemistry practical in a laboratory and; do the participants’ perspectives about chemistry change during the experience. The performed study consisted of a chemistry practical, two art works and, in some cases, an interview. Nine participants were asked to create the art under specific instructions of points of focus, namely their preconceptions prior to the practical (Artwork 1) and their lived experience during the practical (Artwork 2). Participants’ artworks were examined using methods of visual semiotics and classical art analysis techniques, looking at line, shape, and colour choice. The iterative analysis of the interviews from participants 1, 2, 7, and 9 coded with ATLAS.ti 7 software, led to the emergence of themes that constitute the core of the participants’ experience. This phenomenological study presents a path to engage the non-chemist with processes taking place in the laboratory by using ‘Kitchen Chemistry’ and illustrates how a phenomenological engagement with chemistry can make the subject more applicable to the general population of non-chemists.
- Full Text:
- Date Issued: 2017
Photophysical studies of conjugates of upconversion nanoparticles with aluminium phthalocyanines
- Authors: Watkins, Zane
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/4964 , vital:20747
- Description: NaYF4 :Yb/Er/Gd upconversion nanoparticles (UCNP) were synthesised and their photoemission stabilised by embedding these nanoparticles in electrospun fibres. The photophysical behaviour of chloro aluminium tetrasulfo-phthalocyanine chloride (ClAlTSPc) was studied in the presence of UCNPs on mixing the two species in solution. The fluorescence lifetimes for UCNPs were shortened at 658 nm in the presence of ClAlTSPc when the former was embedded in fibre and suspended in a dimethyl sulfoxide solution of the latter. A clear singlet oxygen generation by ClAlTSPc through Forster resonance energy transfer (FRET) was demonstrated using a singlet oxygen quencher, 1,3-diphenylisobenzofuran. UCNP capped with amino groups were then covalently attached to chloro aluminium tetrasulphonated phthalocyanine (ClAlTSPc) and chloro aluminium tetracarboxy phthalocyanine (ClAlTCPc). The conjugates were characterized using different techniques such as infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS) and Transmission electron microscopy (TEM). There was a decrease in fluorescence emission spectra of the UCNPs at 658 nm in the presence of the phthalocyanines. This decrease indicates an energy transfer between the donor UCNP and conjugated accepting phthalocyanine (Pc), due to FRET. Low FRET efficiencies of 18 and 21 % for ClAlTSPc and ClAlTCPc, respectively, were obtained.
- Full Text:
- Date Issued: 2017
- Authors: Watkins, Zane
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/4964 , vital:20747
- Description: NaYF4 :Yb/Er/Gd upconversion nanoparticles (UCNP) were synthesised and their photoemission stabilised by embedding these nanoparticles in electrospun fibres. The photophysical behaviour of chloro aluminium tetrasulfo-phthalocyanine chloride (ClAlTSPc) was studied in the presence of UCNPs on mixing the two species in solution. The fluorescence lifetimes for UCNPs were shortened at 658 nm in the presence of ClAlTSPc when the former was embedded in fibre and suspended in a dimethyl sulfoxide solution of the latter. A clear singlet oxygen generation by ClAlTSPc through Forster resonance energy transfer (FRET) was demonstrated using a singlet oxygen quencher, 1,3-diphenylisobenzofuran. UCNP capped with amino groups were then covalently attached to chloro aluminium tetrasulphonated phthalocyanine (ClAlTSPc) and chloro aluminium tetracarboxy phthalocyanine (ClAlTCPc). The conjugates were characterized using different techniques such as infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS) and Transmission electron microscopy (TEM). There was a decrease in fluorescence emission spectra of the UCNPs at 658 nm in the presence of the phthalocyanines. This decrease indicates an energy transfer between the donor UCNP and conjugated accepting phthalocyanine (Pc), due to FRET. Low FRET efficiencies of 18 and 21 % for ClAlTSPc and ClAlTCPc, respectively, were obtained.
- Full Text:
- Date Issued: 2017
Photosynthetic and growth responses of C3 and C4 grasses to short- duration sunflecks and resultant consequences for their performance in understory environments
- Authors: Adams, Claire Elizabeth
- Date: 2017
- Subjects: Understory plants -- Effect of light on , Grasses -- Effect of light on -- South Africa , Erharta -- Effect of light on , Brachiara -- Effect of light on
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/5016 , vital:20753
- Description: Low C4 grass species abundance in understory environments is thought to be as a result of their high-light requirements, lack of photosynthetic advantage relative to C3 species in cooler environments, and an inability to adequately utilise sunflecks. This study sets out to investigate this theory, hypothesizing that C3 grass species outperform C4 grass species under the canopy, not as a result of quantum efficiency temperature effects, but as a result of C4 species inability to utilize short-duration sunflecks. Short sunflecks could result in a breakdown in assimilate movement between the mesophyll (MSC) and bundle sheath (BSC) cells. The role of BSC leakiness, stomata and PSII efficiency on the ability of C3 and C4 Alloteropsis semialata to utilize short-duration sunflecks was investigated using gaseous exchange and chlorophyll fluorescence techniques, while the growth of both subspecies under a simulated flecking-light environment tested whether these measured responses translated into effects on growth. As C3 grasses are known to possess higher levels of stomatal conductance in relation to C4 species, results showed that C3 A. semialata was able to utilize short-duration sunflecks as a result of increased stomatal conductance and an ability to induce photosynthesis under various light flecking conditions. In contrast, C4 A. semialata was unable to utilize sunflecks possibly as a result of energetic limitations of the carboxylation mechanism (PSII) and not because of increased bundle sheath leakiness. These photosynthetic responses translated into growth differences when both types were grown in an artificially flecking light environment. The photosynthetic differences noted for C3 and C4 A.semialata were also evident in shade adapted understory grasses; Erharta erecta (C3), Dactylotenium australe (C4) and Brachiaria chusqueoides (C4). As photosynthetic induction was marginally more rapid in all species relative to A. semialata it suggests some degree of adaptation in shade grasses, however the inability of the C4 species to utilise short sunflecks remained. As a result, it was hypothesized that C3 shade adapted E. erecta and C4 B. chusqueoides, co-inhabiting the same forest understory, are able to do so because of differences in light micro-environments associated with each species. However, canopy openness and light profiles determined for theses micro-climates showed no differences and that both species have persisted within a relatively stable understory environment. The coexistence was possible as the understory was supplied with a significant proportion of its daily light in flecks sufficiently long as to not compromise C4 productivity. A survey of 10 species of grasses under various canopy densities and in the open showed a strong negative linear relationship between canopy openness and the rate at which photosynthesis was induced by flecking light, which has not been shown before. This did not result from the phylogenetic relationship between species and could be shown for a single species (E. erecta) growing in a range of light environments. This demonstrates that C4 grasses, despite adaptation, would be limited from sunfleck environments if a significant proportion of the daily light available consists of flecks of short-duration. The generation of such environments may occur as a result of woody thickening and could help explain the observed decline in C4 grasses under these conditions.
- Full Text:
- Date Issued: 2017
- Authors: Adams, Claire Elizabeth
- Date: 2017
- Subjects: Understory plants -- Effect of light on , Grasses -- Effect of light on -- South Africa , Erharta -- Effect of light on , Brachiara -- Effect of light on
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/5016 , vital:20753
- Description: Low C4 grass species abundance in understory environments is thought to be as a result of their high-light requirements, lack of photosynthetic advantage relative to C3 species in cooler environments, and an inability to adequately utilise sunflecks. This study sets out to investigate this theory, hypothesizing that C3 grass species outperform C4 grass species under the canopy, not as a result of quantum efficiency temperature effects, but as a result of C4 species inability to utilize short-duration sunflecks. Short sunflecks could result in a breakdown in assimilate movement between the mesophyll (MSC) and bundle sheath (BSC) cells. The role of BSC leakiness, stomata and PSII efficiency on the ability of C3 and C4 Alloteropsis semialata to utilize short-duration sunflecks was investigated using gaseous exchange and chlorophyll fluorescence techniques, while the growth of both subspecies under a simulated flecking-light environment tested whether these measured responses translated into effects on growth. As C3 grasses are known to possess higher levels of stomatal conductance in relation to C4 species, results showed that C3 A. semialata was able to utilize short-duration sunflecks as a result of increased stomatal conductance and an ability to induce photosynthesis under various light flecking conditions. In contrast, C4 A. semialata was unable to utilize sunflecks possibly as a result of energetic limitations of the carboxylation mechanism (PSII) and not because of increased bundle sheath leakiness. These photosynthetic responses translated into growth differences when both types were grown in an artificially flecking light environment. The photosynthetic differences noted for C3 and C4 A.semialata were also evident in shade adapted understory grasses; Erharta erecta (C3), Dactylotenium australe (C4) and Brachiaria chusqueoides (C4). As photosynthetic induction was marginally more rapid in all species relative to A. semialata it suggests some degree of adaptation in shade grasses, however the inability of the C4 species to utilise short sunflecks remained. As a result, it was hypothesized that C3 shade adapted E. erecta and C4 B. chusqueoides, co-inhabiting the same forest understory, are able to do so because of differences in light micro-environments associated with each species. However, canopy openness and light profiles determined for theses micro-climates showed no differences and that both species have persisted within a relatively stable understory environment. The coexistence was possible as the understory was supplied with a significant proportion of its daily light in flecks sufficiently long as to not compromise C4 productivity. A survey of 10 species of grasses under various canopy densities and in the open showed a strong negative linear relationship between canopy openness and the rate at which photosynthesis was induced by flecking light, which has not been shown before. This did not result from the phylogenetic relationship between species and could be shown for a single species (E. erecta) growing in a range of light environments. This demonstrates that C4 grasses, despite adaptation, would be limited from sunfleck environments if a significant proportion of the daily light available consists of flecks of short-duration. The generation of such environments may occur as a result of woody thickening and could help explain the observed decline in C4 grasses under these conditions.
- Full Text:
- Date Issued: 2017
Physical organic studies of substituted norbornyl systems: aspects of mechanisms and chirality
- Authors: Singh, Alicia
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/50558 , vital:25999
- Description: Fenchone and camphor are essential natural products that are available optically pure and contribute to the chiral pool in asymmetric synthesis. Further, they are both derivatives of norbornane, a structure that undergoes a remarkable diversity of rearrangements in acidic conditions. This work explores two aspects of the camphor/fenchone derived systems. Firstly an attempt to clarify rearrangement mechanisms on a camphor system successfully via deuterium labelling and unsuccessfully via derivatization of fenchone (with rearrangement) to produce other 13C-labelled camphor substitutions, has resulted in confirmation of a theoretically proposed, highly concerted Wagner-Meerwein, 6,2 - hydride shift, Wagner-Meerwein rearrangement in competition with an associated 2,3-methide shift. Kinetics and activation parameters for many steps have been resolved in this rearrangement of the deuterium labelled camphor-derived tosylate system to two pairs of isotopomers. Further, the kinetics and formation of an unexpected pair of dimers encountered during the scheme for 13C labelling are investigated in detail. These dimers (forming during the initial stages of the synthetic scheme) are unusual in that they are not expected rotamers of each other, but diastereomers resulting from chirality of a sulfur atom in a sulfite moiety. A feasible mechanism of formation that matches the kinetics has been proposed in this unexpectedly complex system, and thermodynamic parameters have been determined. The second aspect of substituted norbornyl systems pertains to their chirality, and the influence of this chirality on reaction mixtures, with an aim to identify novel chiral micellar catalysts for use in heterogeneous reaction mixtures. Headway has been made towards the synthesis of the appropriate surfactants to be used in the construction of these micelles, but extensive molecular dynamics simulations have illustrated the feasibility of forming the stable chiral micelles in a dual-solvent system, and detail precisely the influence of chirality on surrounding media. These studies add important physical organic data as well as show the immense possibilities pertaining to substituted norbornane systems.
- Full Text:
- Date Issued: 2017
- Authors: Singh, Alicia
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/50558 , vital:25999
- Description: Fenchone and camphor are essential natural products that are available optically pure and contribute to the chiral pool in asymmetric synthesis. Further, they are both derivatives of norbornane, a structure that undergoes a remarkable diversity of rearrangements in acidic conditions. This work explores two aspects of the camphor/fenchone derived systems. Firstly an attempt to clarify rearrangement mechanisms on a camphor system successfully via deuterium labelling and unsuccessfully via derivatization of fenchone (with rearrangement) to produce other 13C-labelled camphor substitutions, has resulted in confirmation of a theoretically proposed, highly concerted Wagner-Meerwein, 6,2 - hydride shift, Wagner-Meerwein rearrangement in competition with an associated 2,3-methide shift. Kinetics and activation parameters for many steps have been resolved in this rearrangement of the deuterium labelled camphor-derived tosylate system to two pairs of isotopomers. Further, the kinetics and formation of an unexpected pair of dimers encountered during the scheme for 13C labelling are investigated in detail. These dimers (forming during the initial stages of the synthetic scheme) are unusual in that they are not expected rotamers of each other, but diastereomers resulting from chirality of a sulfur atom in a sulfite moiety. A feasible mechanism of formation that matches the kinetics has been proposed in this unexpectedly complex system, and thermodynamic parameters have been determined. The second aspect of substituted norbornyl systems pertains to their chirality, and the influence of this chirality on reaction mixtures, with an aim to identify novel chiral micellar catalysts for use in heterogeneous reaction mixtures. Headway has been made towards the synthesis of the appropriate surfactants to be used in the construction of these micelles, but extensive molecular dynamics simulations have illustrated the feasibility of forming the stable chiral micelles in a dual-solvent system, and detail precisely the influence of chirality on surrounding media. These studies add important physical organic data as well as show the immense possibilities pertaining to substituted norbornane systems.
- Full Text:
- Date Issued: 2017
Political correctness and freedom of expression
- Authors: Embling, Geoffrey
- Date: 2017
- Subjects: Political correctness , Freedom of speech , Political correctness -- South Africa , Freedom of speech -- South Africa , Censorship , Censorship -- South Africa , South Africa -- Politics and government , Political satire, South African , Fanatacism , Toleration
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/40873 , vital:25035
- Description: A brief history of political correctness is discussed along with various definitions of it, ranging from political correctness being a benign attempt to prevent offense and avert discrimination to stronger views equating it with Communist censorship or branding it as "cultural Marxism". The aim of the research is to discover what political correctness is, how it relates to freedom of expression and what wider implications and effects it has on society. The moral foundations of rights and free speech in particular are introduced in order to set a framework to determine what authority people and governments have to censor others' expression. Different philosophical views on the limits of free speech are discussed, and arguments for and against hate speech are analysed and related to political correctness. The thesis looks at political correctness on university campuses, which involves speech codes, antidiscrimination legislation and changing the Western canon to a more multicultural syllabus. The recent South African university protests involving issues such as white privilege, university fees and rape are discussed and related to political correctness. The thesis examines the role of political correctness in the censorship of humour, it discusses the historical role of satire in challenging dogmatism and it looks at the psychology behind intolerance. Political correctness appeals to tolerance, which is sometimes elevated at the expense of truth. Truth and tolerance are therefore weighed up, along with their altered definitions in today's relativistic society. The last part of the thesis looks at South Africa's unique brand of political correctness, along with Black Economic Empowerment, colonialism and white guilt, and the research concludes that political correctness is a distinct form of censorship which has developed in modern democracies. The new forms of justice and morality seen in political correctness are distortions of left-wing liberalism, which appeal to different values to those of traditional liberalism.
- Full Text:
- Date Issued: 2017
- Authors: Embling, Geoffrey
- Date: 2017
- Subjects: Political correctness , Freedom of speech , Political correctness -- South Africa , Freedom of speech -- South Africa , Censorship , Censorship -- South Africa , South Africa -- Politics and government , Political satire, South African , Fanatacism , Toleration
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/40873 , vital:25035
- Description: A brief history of political correctness is discussed along with various definitions of it, ranging from political correctness being a benign attempt to prevent offense and avert discrimination to stronger views equating it with Communist censorship or branding it as "cultural Marxism". The aim of the research is to discover what political correctness is, how it relates to freedom of expression and what wider implications and effects it has on society. The moral foundations of rights and free speech in particular are introduced in order to set a framework to determine what authority people and governments have to censor others' expression. Different philosophical views on the limits of free speech are discussed, and arguments for and against hate speech are analysed and related to political correctness. The thesis looks at political correctness on university campuses, which involves speech codes, antidiscrimination legislation and changing the Western canon to a more multicultural syllabus. The recent South African university protests involving issues such as white privilege, university fees and rape are discussed and related to political correctness. The thesis examines the role of political correctness in the censorship of humour, it discusses the historical role of satire in challenging dogmatism and it looks at the psychology behind intolerance. Political correctness appeals to tolerance, which is sometimes elevated at the expense of truth. Truth and tolerance are therefore weighed up, along with their altered definitions in today's relativistic society. The last part of the thesis looks at South Africa's unique brand of political correctness, along with Black Economic Empowerment, colonialism and white guilt, and the research concludes that political correctness is a distinct form of censorship which has developed in modern democracies. The new forms of justice and morality seen in political correctness are distortions of left-wing liberalism, which appeal to different values to those of traditional liberalism.
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- Date Issued: 2017