Interest rate behaviour in a more transparent South African monetary policy environment
- Authors: Ballim, Goolam Hoosen
- Date: 2005
- Subjects: South African Reserve Bank , Monetary policy -- South Africa , Banks and banking -- South Africa , Interest rates -- South Africa , South Africa -- Economic policy , South Africa -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1034 , http://hdl.handle.net/10962/d1004462 , South African Reserve Bank , Monetary policy -- South Africa , Banks and banking -- South Africa , Interest rates -- South Africa , South Africa -- Economic policy , South Africa -- Economic conditions
- Description: South Africa introduced inflation targeting as a monetary policy framework in 2000. This marked a sizable shift in monetary policy management from the previous "eclectic" approach and the explicit focus on M3 money supply before that. The study appraises the effectiveness of monetary policy under this new dispensation. However, the analysis does not centre on inflation outcomes, which can be a measure of effectiveness because they are the overriding objective of the South African Reserve Bank in effect, it is possible to have a target-friendly inflation rate for a length of time despite monetary policy that is ambiguous and encourages unpredictability in market interest rates. However, persistent policy opaqueness can, over time, damage a favourable inflation scenario. For instance, if the public is unsure about the Reserve Bank's desired inflation target, price setting in the wage and goods markets may eventually produce an inflation outcome that is higher than the Bank may have intended. Rather, this study adjudicates the effectiveness of monetary policy within the context of policy transparency, which is an intrinsic part of the inflation targeting framework. The study looks at the extent to which monetary policy transparency has enhanced both the anticipatory nature of the market's response to policy actions and the force that policy has on all interest rates in the financial system, particularly long-term rates. These concepts are important because through the transmission mechanism of monetary policy, the more deft market participants are at anticipating future Reserve Bank policy the greater the Bank's ability to steady the economy before the actual policy event. With the aid of regression models to estimate the response of market rates to policy changes, the results show that there is significant movement in market rates in anticipation of policy action, rather than on the day of the event or the day after. Indeed, the estimates for market rates movement on the day of and even the day after the policy action are generally minute. For instance, the R157 long-term government bond yield changes by a significant 41 basis points in response to a one percentage point change in the Reserve Bank's benchmark repo rate in the period between the last policy action and the day preceding the current action. In contrast, the R157 bond yield changes by an insignificant 2 basis points on the day of the current repo rate change and about 1 basis point the day after the current change. The results point to a robust relationship between policy transparency and the market's ability to foresee rate action. If this were not the case, it is likely that there would be persistent market surprise and, hence, noticeable movement in interest rates on the day of the rate action and perhaps even the day after. Another important observation is that monetary policy impacts significantly on both short- and long-term market rates. Again, certifying the robustness of monetary policy under the inflation targeting regime
- Full Text:
- Date Issued: 2005
- Authors: Ballim, Goolam Hoosen
- Date: 2005
- Subjects: South African Reserve Bank , Monetary policy -- South Africa , Banks and banking -- South Africa , Interest rates -- South Africa , South Africa -- Economic policy , South Africa -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1034 , http://hdl.handle.net/10962/d1004462 , South African Reserve Bank , Monetary policy -- South Africa , Banks and banking -- South Africa , Interest rates -- South Africa , South Africa -- Economic policy , South Africa -- Economic conditions
- Description: South Africa introduced inflation targeting as a monetary policy framework in 2000. This marked a sizable shift in monetary policy management from the previous "eclectic" approach and the explicit focus on M3 money supply before that. The study appraises the effectiveness of monetary policy under this new dispensation. However, the analysis does not centre on inflation outcomes, which can be a measure of effectiveness because they are the overriding objective of the South African Reserve Bank in effect, it is possible to have a target-friendly inflation rate for a length of time despite monetary policy that is ambiguous and encourages unpredictability in market interest rates. However, persistent policy opaqueness can, over time, damage a favourable inflation scenario. For instance, if the public is unsure about the Reserve Bank's desired inflation target, price setting in the wage and goods markets may eventually produce an inflation outcome that is higher than the Bank may have intended. Rather, this study adjudicates the effectiveness of monetary policy within the context of policy transparency, which is an intrinsic part of the inflation targeting framework. The study looks at the extent to which monetary policy transparency has enhanced both the anticipatory nature of the market's response to policy actions and the force that policy has on all interest rates in the financial system, particularly long-term rates. These concepts are important because through the transmission mechanism of monetary policy, the more deft market participants are at anticipating future Reserve Bank policy the greater the Bank's ability to steady the economy before the actual policy event. With the aid of regression models to estimate the response of market rates to policy changes, the results show that there is significant movement in market rates in anticipation of policy action, rather than on the day of the event or the day after. Indeed, the estimates for market rates movement on the day of and even the day after the policy action are generally minute. For instance, the R157 long-term government bond yield changes by a significant 41 basis points in response to a one percentage point change in the Reserve Bank's benchmark repo rate in the period between the last policy action and the day preceding the current action. In contrast, the R157 bond yield changes by an insignificant 2 basis points on the day of the current repo rate change and about 1 basis point the day after the current change. The results point to a robust relationship between policy transparency and the market's ability to foresee rate action. If this were not the case, it is likely that there would be persistent market surprise and, hence, noticeable movement in interest rates on the day of the rate action and perhaps even the day after. Another important observation is that monetary policy impacts significantly on both short- and long-term market rates. Again, certifying the robustness of monetary policy under the inflation targeting regime
- Full Text:
- Date Issued: 2005
Investigating call control using MGCP in conjuction with SIP and H.323
- Authors: Jacobs, Ashley
- Date: 2005 , 2005-03-14
- Subjects: Communication -- Technological innovations , Digital telephone systems , Computer networks , Computer network protocols , Internet telephony
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4631 , http://hdl.handle.net/10962/d1006516 , Communication -- Technological innovations , Digital telephone systems , Computer networks , Computer network protocols , Internet telephony
- Description: Telephony used to mean using a telephone to call another telephone on the Public Switched Telephone Network (PSTN), and data networks were used purely to allow computers to communicate. However, with the advent of the Internet, telephony services have been extended to run on data networks. Telephone calls within the IP network are known as Voice over IP. These calls are carried by a number of protocols, with the most popular ones currently being Session Initiation Protocol (SIP) and H.323. Calls can be made from the IP network to the PSTN and vice versa through the use of a gateway. The gateway translates the packets from the IP network to circuits on the PSTN and vice versa to facilitate calls between the two networks. Gateways have evolved and are now split into two entities using the master/slave architecture. The master is an intelligent Media Gateway Controller (MGC) that handles the call control and signalling. The slave is a "dumb" Media Gateway (MG) that handles the translation of the media. The current gateway control protocols in use are Megaco/H.248, MGCP and Skinny. These protocols have proved themselves on the edge of the network. Furthermore, since they communicate with the call signalling VoIP protocols as well as the PSTN, they have to be the lingua franca between the two networks. Within the VoIP network, the numbers of call signalling protocols make it difficult to communicate with each other and to create services. This research investigates the use of Gateway Control Protocols as the lowest common denominator between the call signalling protocols SIP and H.323. More specifically, it uses MGCP to investigate service creation. It also considers the use of MGCP as a protocol translator between SIP and H.323. A service was created using MGCP to allow H.323 endpoints to send Short Message Service (SMS) messages. This service was then extended with minimal effort to SIP endpoints. This service investigated MGCP’s ability to handle call control from the H.323 and SIP endpoints. An MGC was then successfully used to perform as a protocol translator between SIP and H.323.
- Full Text:
- Date Issued: 2005
- Authors: Jacobs, Ashley
- Date: 2005 , 2005-03-14
- Subjects: Communication -- Technological innovations , Digital telephone systems , Computer networks , Computer network protocols , Internet telephony
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4631 , http://hdl.handle.net/10962/d1006516 , Communication -- Technological innovations , Digital telephone systems , Computer networks , Computer network protocols , Internet telephony
- Description: Telephony used to mean using a telephone to call another telephone on the Public Switched Telephone Network (PSTN), and data networks were used purely to allow computers to communicate. However, with the advent of the Internet, telephony services have been extended to run on data networks. Telephone calls within the IP network are known as Voice over IP. These calls are carried by a number of protocols, with the most popular ones currently being Session Initiation Protocol (SIP) and H.323. Calls can be made from the IP network to the PSTN and vice versa through the use of a gateway. The gateway translates the packets from the IP network to circuits on the PSTN and vice versa to facilitate calls between the two networks. Gateways have evolved and are now split into two entities using the master/slave architecture. The master is an intelligent Media Gateway Controller (MGC) that handles the call control and signalling. The slave is a "dumb" Media Gateway (MG) that handles the translation of the media. The current gateway control protocols in use are Megaco/H.248, MGCP and Skinny. These protocols have proved themselves on the edge of the network. Furthermore, since they communicate with the call signalling VoIP protocols as well as the PSTN, they have to be the lingua franca between the two networks. Within the VoIP network, the numbers of call signalling protocols make it difficult to communicate with each other and to create services. This research investigates the use of Gateway Control Protocols as the lowest common denominator between the call signalling protocols SIP and H.323. More specifically, it uses MGCP to investigate service creation. It also considers the use of MGCP as a protocol translator between SIP and H.323. A service was created using MGCP to allow H.323 endpoints to send Short Message Service (SMS) messages. This service was then extended with minimal effort to SIP endpoints. This service investigated MGCP’s ability to handle call control from the H.323 and SIP endpoints. An MGC was then successfully used to perform as a protocol translator between SIP and H.323.
- Full Text:
- Date Issued: 2005
Investigation into the biological removal of sulphate from ethanol distillery wastewater using sulphate-reducing prokaryotes
- Authors: Smuts, Lizl
- Date: 2005
- Subjects: Sewage -- Purification -- Biological treatment , Prokaryotes , Sulfates , Distilleries -- Waste disposal
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3941 , http://hdl.handle.net/10962/d1004000 , Sewage -- Purification -- Biological treatment , Prokaryotes , Sulfates , Distilleries -- Waste disposal
- Description: Ethanol production wastewater is known to be toxic, and is not easily biodegradable. It also consists of a variety of coloured components adding to the complex composition of this wastewater. Disposal of this wastewater into water courses is not recommended and yet is performed all over the world. Investigation of this wastewater found that there was a high concentration of sulphate which, in the presence of sulphate-reducing prokaryotes can cause sulphide corrosion of cement. The concentration of sulphate in the wastewater was approximately 2770 mg/L. It was also found that the wastewater pH was very low and discharge of the wastewater into the wastewater treatment works caused a negative impact on the overall quality of the final wastewater discharged to sea. It was found using FISH techniques that there were no sulphate-reducing prokaryotes present in the wastewaters but that a sulphate-reducing population existed on the sewer wall. An anaerobic contact process was designed to treat this wastewater targeting sulphate reduction to sulphide, to be converted into elemental sulphur and to increase the wastewater pH. The process did not achieve this aim and only approximately 20-30 % reduction in sulphate from the wastewater was achieved with little to no change in the pH. A 95 % reduction in sulphate concentration was needed in order to reach acceptable discharge limits. Sulphate reduction could not be carried out, even under ideal laboratory conditions. It was found that the barrier causing the digester failure was the high concentration of phenols present in the wastewater (3.3 g/L) together with the production of high concentrations of volatile fatty acids (on average 13 g acetic/L). These two components are known to cause digester failure, especially phenols, and phenols are usually only degraded by fungal species. It was concluded that the wastewater itself was not amenable to this method of biological treatment.
- Full Text:
- Date Issued: 2005
- Authors: Smuts, Lizl
- Date: 2005
- Subjects: Sewage -- Purification -- Biological treatment , Prokaryotes , Sulfates , Distilleries -- Waste disposal
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3941 , http://hdl.handle.net/10962/d1004000 , Sewage -- Purification -- Biological treatment , Prokaryotes , Sulfates , Distilleries -- Waste disposal
- Description: Ethanol production wastewater is known to be toxic, and is not easily biodegradable. It also consists of a variety of coloured components adding to the complex composition of this wastewater. Disposal of this wastewater into water courses is not recommended and yet is performed all over the world. Investigation of this wastewater found that there was a high concentration of sulphate which, in the presence of sulphate-reducing prokaryotes can cause sulphide corrosion of cement. The concentration of sulphate in the wastewater was approximately 2770 mg/L. It was also found that the wastewater pH was very low and discharge of the wastewater into the wastewater treatment works caused a negative impact on the overall quality of the final wastewater discharged to sea. It was found using FISH techniques that there were no sulphate-reducing prokaryotes present in the wastewaters but that a sulphate-reducing population existed on the sewer wall. An anaerobic contact process was designed to treat this wastewater targeting sulphate reduction to sulphide, to be converted into elemental sulphur and to increase the wastewater pH. The process did not achieve this aim and only approximately 20-30 % reduction in sulphate from the wastewater was achieved with little to no change in the pH. A 95 % reduction in sulphate concentration was needed in order to reach acceptable discharge limits. Sulphate reduction could not be carried out, even under ideal laboratory conditions. It was found that the barrier causing the digester failure was the high concentration of phenols present in the wastewater (3.3 g/L) together with the production of high concentrations of volatile fatty acids (on average 13 g acetic/L). These two components are known to cause digester failure, especially phenols, and phenols are usually only degraded by fungal species. It was concluded that the wastewater itself was not amenable to this method of biological treatment.
- Full Text:
- Date Issued: 2005
Isolation, purification and characterization of inulin and fructooligosaccharides from chicorium intybus and inulinase from aspergillus niger
- Mavumengwana, Vuyo Bhongelethu
- Authors: Mavumengwana, Vuyo Bhongelethu
- Date: 2005
- Subjects: Aspergillus , Inulin , Chicory -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3954 , http://hdl.handle.net/10962/d1004013 , Aspergillus , Inulin , Chicory -- South Africa
- Description: Inulin is a non-digestible carbohydrate fructan polymer consisting mainly of β (1→2) fructosyl fructose links. Enzymatic hydrolysis of inulin by inulinase results in the production of low D.P (degree of polymerization) oligosaccharides also called fructooligosaccharides(FOS). Isolation of inulin from chicory root (Chicorium intybus) was achieved by first, extraction using deionized water (600C), followed by carbonation (0.1 M Ca(OH)2 and CO2 gas). This was filtered in order to remove the non sugars, thereafter, treated successfully with polyamide 6 powder. A cation exchanger and an anion exchanger were used to further exclude other components such as tannins and pigments. The extracted inulin was quantified using the Somogyi-Nelson colourimetric assay. Chicory root (207 g, 30 % being water) yielded 30 g of the raw extract. A 100 mg of the raw extract was assayed and found to contain 11 % yield of inulin which was 80.2 % in purity and 4 % free fructose. Analysis of the crude and purified inulin extracts on the MALDI TOF spectrometry showed the samples to have a DP of 2 to 22 and 2 to 27 respectively. Maximum inulinase production from Aspergillus niger grown on inulin was observed after 60 hours. The enzyme activity was found to be 1.168 U/ml with a temperature and pH optimum of 30 °C and 7.7 respectively. The enzyme proved to be unstable as it progressively lost its total activity during attempts at purification.
- Full Text:
- Date Issued: 2005
- Authors: Mavumengwana, Vuyo Bhongelethu
- Date: 2005
- Subjects: Aspergillus , Inulin , Chicory -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3954 , http://hdl.handle.net/10962/d1004013 , Aspergillus , Inulin , Chicory -- South Africa
- Description: Inulin is a non-digestible carbohydrate fructan polymer consisting mainly of β (1→2) fructosyl fructose links. Enzymatic hydrolysis of inulin by inulinase results in the production of low D.P (degree of polymerization) oligosaccharides also called fructooligosaccharides(FOS). Isolation of inulin from chicory root (Chicorium intybus) was achieved by first, extraction using deionized water (600C), followed by carbonation (0.1 M Ca(OH)2 and CO2 gas). This was filtered in order to remove the non sugars, thereafter, treated successfully with polyamide 6 powder. A cation exchanger and an anion exchanger were used to further exclude other components such as tannins and pigments. The extracted inulin was quantified using the Somogyi-Nelson colourimetric assay. Chicory root (207 g, 30 % being water) yielded 30 g of the raw extract. A 100 mg of the raw extract was assayed and found to contain 11 % yield of inulin which was 80.2 % in purity and 4 % free fructose. Analysis of the crude and purified inulin extracts on the MALDI TOF spectrometry showed the samples to have a DP of 2 to 22 and 2 to 27 respectively. Maximum inulinase production from Aspergillus niger grown on inulin was observed after 60 hours. The enzyme activity was found to be 1.168 U/ml with a temperature and pH optimum of 30 °C and 7.7 respectively. The enzyme proved to be unstable as it progressively lost its total activity during attempts at purification.
- Full Text:
- Date Issued: 2005
Making meaning, making a home: students watching Generations
- Authors: O'Shea, Catherine Mary
- Date: 2005
- Subjects: Generations (Television program) , Students, Black -- South Africa -- Attitudes , Television soap operas -- South Africa , Cross-cultural studies -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3479 , http://hdl.handle.net/10962/d1002934 , Generations (Television program) , Students, Black -- South Africa -- Attitudes , Television soap operas -- South Africa , Cross-cultural studies -- South Africa
- Description: This thesis is a reception analysis using qualitative interviews to investigate black students' watching of a South African soap opera, Generations, taking into account the context of a largely white South African university campus. The findings of this study are that students find pleasure in talking about Generations and hold seemingly contradictory views on whether it is 'realistic' or not. The analysis concludes that watching Generations does serve to affirm these students' black identity, since there is a particular need to do so on a campus where black students witness and experience racial discrimination.
- Full Text:
- Date Issued: 2005
- Authors: O'Shea, Catherine Mary
- Date: 2005
- Subjects: Generations (Television program) , Students, Black -- South Africa -- Attitudes , Television soap operas -- South Africa , Cross-cultural studies -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3479 , http://hdl.handle.net/10962/d1002934 , Generations (Television program) , Students, Black -- South Africa -- Attitudes , Television soap operas -- South Africa , Cross-cultural studies -- South Africa
- Description: This thesis is a reception analysis using qualitative interviews to investigate black students' watching of a South African soap opera, Generations, taking into account the context of a largely white South African university campus. The findings of this study are that students find pleasure in talking about Generations and hold seemingly contradictory views on whether it is 'realistic' or not. The analysis concludes that watching Generations does serve to affirm these students' black identity, since there is a particular need to do so on a campus where black students witness and experience racial discrimination.
- Full Text:
- Date Issued: 2005
Marine biotechnology : evaluation and development of methods for the discovery of natural products from fungi
- Authors: Pather, Simisha
- Date: 2005 , 2013-06-18
- Subjects: Marine biotechnology , Marine fungi -- South Africa , Natural products -- South Africa , Marine plants -- South Africa , Marine metabolites -- South Africa , Cancer -- Treatment , DNA
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3839 , http://hdl.handle.net/10962/d1007652 , Marine biotechnology , Marine fungi -- South Africa , Natural products -- South Africa , Marine plants -- South Africa , Marine metabolites -- South Africa , Cancer -- Treatment , DNA
- Description: One of the major impediments in the development of marine natural products is the provision of biologically active natural products in sufficient quantity for complete pharmacological evaluation, clinical trials and eventual commercial production. Marine microorganisms show great promise in providing a renewable source of biologically active natural products. The main aim of this study was to develop and evaluate methods for the isolation, identification and cultivation of marine fungi from the South African marine environment for the production of biologically active secondary metabolites. Twenty-four species of fungi were isolated from marine algae collected from the intertidal zone near Port Alfred, South Africa. The fungi were cultivated in small-scale under static and agitated conditions and their crude intra- and extracellular organic extracts were screened by ¹H NMR and a series of bioassays. Using this as a basis, one isolate was selected for further study. By analyses of the lTS1 region of the ribosomal DNA, the fungal isolate was identified as a marine-derived isolate of Eurotium rubrum (Aspergillus ruber). Although E. rubrum has been isolated from the marine environment, no investigations have been undertaken to determine the adaptation of these isolates to the marine environment. In order to optimise productivity, creativity and incubation time, the fungus was cultivated in small-scale using a variety of carbon (glucose, fructose, lactose, sucrose, marmitol and maltose) and nitrogen sources (ammonium tartrate, urea, peptone and yeast extract). An HPLC-DAD method was developed to assess the metabolic creativity and productivity under different fermentation conditions. Distinctive variations in the range and yield of metabolites produced as well as morphology and growth time were observed. The crude extracts from all fermentations were combined and six known compounds were isolated by reversed-phase chromatography and their structures elucidated by spectroscopic techniques. The known compounds were fIavoglaucin, aspergin, isodihydroauroglaucin, isotetrahydroauroglaucin, neoechinuline A and physcion. Neoechinuline A, isodihydroauroglaucin and isotetrahydroauroglaucin showed activity against oesophageal and cervical cancer cell lines.
- Full Text:
- Date Issued: 2005
- Authors: Pather, Simisha
- Date: 2005 , 2013-06-18
- Subjects: Marine biotechnology , Marine fungi -- South Africa , Natural products -- South Africa , Marine plants -- South Africa , Marine metabolites -- South Africa , Cancer -- Treatment , DNA
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3839 , http://hdl.handle.net/10962/d1007652 , Marine biotechnology , Marine fungi -- South Africa , Natural products -- South Africa , Marine plants -- South Africa , Marine metabolites -- South Africa , Cancer -- Treatment , DNA
- Description: One of the major impediments in the development of marine natural products is the provision of biologically active natural products in sufficient quantity for complete pharmacological evaluation, clinical trials and eventual commercial production. Marine microorganisms show great promise in providing a renewable source of biologically active natural products. The main aim of this study was to develop and evaluate methods for the isolation, identification and cultivation of marine fungi from the South African marine environment for the production of biologically active secondary metabolites. Twenty-four species of fungi were isolated from marine algae collected from the intertidal zone near Port Alfred, South Africa. The fungi were cultivated in small-scale under static and agitated conditions and their crude intra- and extracellular organic extracts were screened by ¹H NMR and a series of bioassays. Using this as a basis, one isolate was selected for further study. By analyses of the lTS1 region of the ribosomal DNA, the fungal isolate was identified as a marine-derived isolate of Eurotium rubrum (Aspergillus ruber). Although E. rubrum has been isolated from the marine environment, no investigations have been undertaken to determine the adaptation of these isolates to the marine environment. In order to optimise productivity, creativity and incubation time, the fungus was cultivated in small-scale using a variety of carbon (glucose, fructose, lactose, sucrose, marmitol and maltose) and nitrogen sources (ammonium tartrate, urea, peptone and yeast extract). An HPLC-DAD method was developed to assess the metabolic creativity and productivity under different fermentation conditions. Distinctive variations in the range and yield of metabolites produced as well as morphology and growth time were observed. The crude extracts from all fermentations were combined and six known compounds were isolated by reversed-phase chromatography and their structures elucidated by spectroscopic techniques. The known compounds were fIavoglaucin, aspergin, isodihydroauroglaucin, isotetrahydroauroglaucin, neoechinuline A and physcion. Neoechinuline A, isodihydroauroglaucin and isotetrahydroauroglaucin showed activity against oesophageal and cervical cancer cell lines.
- Full Text:
- Date Issued: 2005
Phylogeography and comparative ecophysiology of Chrysanthemoides Turn. Ex Medik. (Tribe Calenduleae)
- Authors: Howis, Seranne
- Date: 2005
- Subjects: Chrysanthemoides , Phylogeny , Ecophysiology , DNA , Plant genetics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4256 , http://hdl.handle.net/10962/d1008189
- Description: Chrysanthem Oides is a common Southern African shrub that grows in a variety of habitats. From coastal shrubland and fynbos to mountainous areas as far north as Kenya. The genus has two species and 8 subspecies. The diagnoses and delimitation of which have been based almost exclusively on morphological characteristics. This project aims to investigate, with the use of phylogenetic species concepts. The validity of these subspecies. Unlike biological species concepts that rely on reproductive isolation as a defining character of a species. Phylogenetic species concepts (PSC) are concerned with delimiting evolutionary significant units (ESUs). ESUs are evolutionarily isolated lineages, and under the PSC a species is an aggregation of organisms consistently diagnosable by a fixed character or combination of characters. This project therefore searched for genetic and physiological characters by which to delimit ESUs within the Cill), samhemoides genus. DNA sequencing was used to investigate the genetic characters, while gas exchange studies were used to investigate the ecophysiological characters. DNA sequence analysis indicated that the ESUs can be diagnosed by genetic means and that one species may be of hybrid origin. Field studies of three disparate genetically identifiable ESUs from three disparate climates found that there are noticeable differences in ecophysiological responses of these ESUs in the field. Plants from each ESU were transferred to a greenhouse and grown under identical conditions for several months and compared to determine if these traits are inherent, or elastic in relation to environmental conditions. Under simulated high rainfall conditions. There does not appear to be a significant difference in the photosynthetic traits.
- Full Text:
- Date Issued: 2005
Phylogeography and comparative ecophysiology of Chrysanthemoides Turn. Ex Medik. (Tribe Calenduleae)
- Authors: Howis, Seranne
- Date: 2005
- Subjects: Chrysanthemoides , Phylogeny , Ecophysiology , DNA , Plant genetics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4256 , http://hdl.handle.net/10962/d1008189
- Description: Chrysanthem Oides is a common Southern African shrub that grows in a variety of habitats. From coastal shrubland and fynbos to mountainous areas as far north as Kenya. The genus has two species and 8 subspecies. The diagnoses and delimitation of which have been based almost exclusively on morphological characteristics. This project aims to investigate, with the use of phylogenetic species concepts. The validity of these subspecies. Unlike biological species concepts that rely on reproductive isolation as a defining character of a species. Phylogenetic species concepts (PSC) are concerned with delimiting evolutionary significant units (ESUs). ESUs are evolutionarily isolated lineages, and under the PSC a species is an aggregation of organisms consistently diagnosable by a fixed character or combination of characters. This project therefore searched for genetic and physiological characters by which to delimit ESUs within the Cill), samhemoides genus. DNA sequencing was used to investigate the genetic characters, while gas exchange studies were used to investigate the ecophysiological characters. DNA sequence analysis indicated that the ESUs can be diagnosed by genetic means and that one species may be of hybrid origin. Field studies of three disparate genetically identifiable ESUs from three disparate climates found that there are noticeable differences in ecophysiological responses of these ESUs in the field. Plants from each ESU were transferred to a greenhouse and grown under identical conditions for several months and compared to determine if these traits are inherent, or elastic in relation to environmental conditions. Under simulated high rainfall conditions. There does not appear to be a significant difference in the photosynthetic traits.
- Full Text:
- Date Issued: 2005
Population dynamics of selected ichthyofaunal components in the temperate, temporarily open/closed Kasouga Estuary, South Africa
- Authors: Tweddle, Gavin Paul
- Date: 2005
- Subjects: Estuaries -- South Africa -- Eastern Cape , Estuarine fishes -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5742 , http://hdl.handle.net/10962/d1005428 , Estuaries -- South Africa -- Eastern Cape , Estuarine fishes -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Description: The spatial and temporal pattern of ichthyofaunal community composition in relation to selected physico-chemical (temperature and salinity) and biological variables (chlorophyll-a and zooplankton) was investigated at ten stations in the temperate temporarily open/closed Kasouga estuary. In addition, the food web structure in the estuary was investigated using stable carbon isotope analysis. Results of the 5 metre seine net survey indicated that ichthyofaunal composition and biomass in the Kasouga estuary was largely determined by seasonality and mouth condition. Maximum abundance and biomass of ichthyofauna was recorded during summer or during those periods when overtopping occurred. Overtopping coincided with the recruitment of marine estuarine dependant species, which dominated the catches both numerically and in biomass. The recruitment of these species resulted in an increase in diversity of the ichthyofaunal community. There were no significant spatial patterns in the distribution of smaller ichthyofauna (<50mm SL) identified in Bray-Curtis similarity matrices using cluster analysis (Primer 5 v5.2.4). Spearman’s correlation analysis revealed that there were no significant correlations between abundance and biomass of ichthyofauna and selected physico-chemical and biological variables other than salinity (P>0.05 in all other cases). There were two distinct spatial patterns in the distribution of the larger ichthyofauna (>50mm SL). These corresponded to a grouping associated with the mouth region and a grouping associated with the remaining regions of the estuary. Stable isotope analysis indicated that the primary source of carbon utilised by the ichthyofauna of the Kasouga estuary was derived from the channel, most likely microphytobenthic algae. The contributions of the riparian and salt marsh vegetation to the total carbon flow appear to be minimal.
- Full Text:
- Date Issued: 2005
- Authors: Tweddle, Gavin Paul
- Date: 2005
- Subjects: Estuaries -- South Africa -- Eastern Cape , Estuarine fishes -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5742 , http://hdl.handle.net/10962/d1005428 , Estuaries -- South Africa -- Eastern Cape , Estuarine fishes -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Description: The spatial and temporal pattern of ichthyofaunal community composition in relation to selected physico-chemical (temperature and salinity) and biological variables (chlorophyll-a and zooplankton) was investigated at ten stations in the temperate temporarily open/closed Kasouga estuary. In addition, the food web structure in the estuary was investigated using stable carbon isotope analysis. Results of the 5 metre seine net survey indicated that ichthyofaunal composition and biomass in the Kasouga estuary was largely determined by seasonality and mouth condition. Maximum abundance and biomass of ichthyofauna was recorded during summer or during those periods when overtopping occurred. Overtopping coincided with the recruitment of marine estuarine dependant species, which dominated the catches both numerically and in biomass. The recruitment of these species resulted in an increase in diversity of the ichthyofaunal community. There were no significant spatial patterns in the distribution of smaller ichthyofauna (<50mm SL) identified in Bray-Curtis similarity matrices using cluster analysis (Primer 5 v5.2.4). Spearman’s correlation analysis revealed that there were no significant correlations between abundance and biomass of ichthyofauna and selected physico-chemical and biological variables other than salinity (P>0.05 in all other cases). There were two distinct spatial patterns in the distribution of the larger ichthyofauna (>50mm SL). These corresponded to a grouping associated with the mouth region and a grouping associated with the remaining regions of the estuary. Stable isotope analysis indicated that the primary source of carbon utilised by the ichthyofauna of the Kasouga estuary was derived from the channel, most likely microphytobenthic algae. The contributions of the riparian and salt marsh vegetation to the total carbon flow appear to be minimal.
- Full Text:
- Date Issued: 2005
Population structure, physiology and feeding ecology of the mysid Mesopodopsis wooldridgei (Whittmann) in a large permanently open estuary
- Authors: Mesher, Colette Suzanne
- Date: 2005
- Subjects: Mysidacea -- Physiology , Mysidacea -- Ecology , Mysidacea -- Feeding and feeds , Zooplankton -- South Africa -- Great Fish Estuary
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5746 , http://hdl.handle.net/10962/d1005432 , Mysidacea -- Physiology , Mysidacea -- Ecology , Mysidacea -- Feeding and feeds , Zooplankton -- South Africa -- Great Fish Estuary
- Description: This project had three main aims. The first aim was to investigate the metabolic physiology of the mysid Mesopodopsis wooldridgei. Secondly, the study examined the contribution of the mysid to the zooplankton community. Finally the study attempted to clarify the primary sources of carbon utilised by the mysid using stable carbon isotope analysis. The study was conducted in the freshwater dominated permanently open Great Fish Estuary (33°30’S; 27°08’E) located along the south-eastern coastline of southern Africa. Mass specific oxygen consumption rates of Mesopodopsis wooldridgei ranged between 0.11 and 8.38 ml O2 mg ww-1 h-1 and increased with an increase in water temperature. There were no significant differences in the respiration rates between the male and female mysids (P > 0.05). At a constant temperature (20°C), the oxygen consumption rate of M. wooldridgei decreased with an increase in salinity. Salinity tolerance of the mysid was strongly modified by temperature. At 5‰ and 30°C, mysids exhibited mass mortality. The Q10 value for M. wooldridgei at 15, 25 and 35‰ was estimated at 2.34, 1.44 and 2.14, respectively. Results of the study suggest that M. wooldridgei is well adapted to surviving in environments characterised by variations in temperature and salinity. Within the Great Fish Estuary, total chl. a concentration ranged between 2.68 μg L-1 and 31.12 μg L-1 and was always dominated by large phytoplankton cells (>5 μm). Average zooplankton abundance ranged between 62 and 28 917 ind. m-3 and biomass between 10 and 203 mg Dwt m-3. The zooplankton community was numerically dominated by the calanoid copepod Pseudodiaptomus hessei, which comprised up to 100% (range between 12 and 100%) of the total zooplankton counted. Total zooplankton biomass during the day was dominated by copepods and by mysids during the nighttime. Among the mysids, M. wooldridgei was the most numerically abundant mysid and comprised <10% of the total zooplankton abundance. Numerical analysis found no seasonal pattern in the total zooplankton abundance (including mysids). The lack of any seasonality could be attributed to the continuous freshwater inflow into the estuary due to the inter-basin transfer of water from the Gariep Dam to the Fish River system. A distinct spatial pattern in the zooplankton community structure was evident with the upper stations almost entirely dominated by the copepod P. hessei, while at stations occupied in the lower reaches of the estuary, the zooplankton community comprised a mixture of freshwater, estuarine and marine breeding zooplankton species. The mysids also demonstrated a distinct spatial pattern in their distribution. Mysids were generally absent from the upper reaches, while in the middle reaches Rhopalophthalmus terranatalis and M. wooldridgei were numerically dominant. Gastrosaccus brevifissura dominated in the lower regions of the estuary. Stable isotope analysis (δ13C) indicated that the dominant source of carbon utilised by the numerically dominant copepods and juvenile M. wooldridgei within the estuary was derived from the extensive phytoplankton stocks within the system. In contrast, sub-adult and adult mysids (R. terranatalis, M. wooldridgei and G. brevifissura) appeared to consume a combination of phytoplankton and copepods. The contribution of the various sources of carbon to the total carbon intake of the mysid remains unknown.
- Full Text:
- Date Issued: 2005
- Authors: Mesher, Colette Suzanne
- Date: 2005
- Subjects: Mysidacea -- Physiology , Mysidacea -- Ecology , Mysidacea -- Feeding and feeds , Zooplankton -- South Africa -- Great Fish Estuary
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5746 , http://hdl.handle.net/10962/d1005432 , Mysidacea -- Physiology , Mysidacea -- Ecology , Mysidacea -- Feeding and feeds , Zooplankton -- South Africa -- Great Fish Estuary
- Description: This project had three main aims. The first aim was to investigate the metabolic physiology of the mysid Mesopodopsis wooldridgei. Secondly, the study examined the contribution of the mysid to the zooplankton community. Finally the study attempted to clarify the primary sources of carbon utilised by the mysid using stable carbon isotope analysis. The study was conducted in the freshwater dominated permanently open Great Fish Estuary (33°30’S; 27°08’E) located along the south-eastern coastline of southern Africa. Mass specific oxygen consumption rates of Mesopodopsis wooldridgei ranged between 0.11 and 8.38 ml O2 mg ww-1 h-1 and increased with an increase in water temperature. There were no significant differences in the respiration rates between the male and female mysids (P > 0.05). At a constant temperature (20°C), the oxygen consumption rate of M. wooldridgei decreased with an increase in salinity. Salinity tolerance of the mysid was strongly modified by temperature. At 5‰ and 30°C, mysids exhibited mass mortality. The Q10 value for M. wooldridgei at 15, 25 and 35‰ was estimated at 2.34, 1.44 and 2.14, respectively. Results of the study suggest that M. wooldridgei is well adapted to surviving in environments characterised by variations in temperature and salinity. Within the Great Fish Estuary, total chl. a concentration ranged between 2.68 μg L-1 and 31.12 μg L-1 and was always dominated by large phytoplankton cells (>5 μm). Average zooplankton abundance ranged between 62 and 28 917 ind. m-3 and biomass between 10 and 203 mg Dwt m-3. The zooplankton community was numerically dominated by the calanoid copepod Pseudodiaptomus hessei, which comprised up to 100% (range between 12 and 100%) of the total zooplankton counted. Total zooplankton biomass during the day was dominated by copepods and by mysids during the nighttime. Among the mysids, M. wooldridgei was the most numerically abundant mysid and comprised <10% of the total zooplankton abundance. Numerical analysis found no seasonal pattern in the total zooplankton abundance (including mysids). The lack of any seasonality could be attributed to the continuous freshwater inflow into the estuary due to the inter-basin transfer of water from the Gariep Dam to the Fish River system. A distinct spatial pattern in the zooplankton community structure was evident with the upper stations almost entirely dominated by the copepod P. hessei, while at stations occupied in the lower reaches of the estuary, the zooplankton community comprised a mixture of freshwater, estuarine and marine breeding zooplankton species. The mysids also demonstrated a distinct spatial pattern in their distribution. Mysids were generally absent from the upper reaches, while in the middle reaches Rhopalophthalmus terranatalis and M. wooldridgei were numerically dominant. Gastrosaccus brevifissura dominated in the lower regions of the estuary. Stable isotope analysis (δ13C) indicated that the dominant source of carbon utilised by the numerically dominant copepods and juvenile M. wooldridgei within the estuary was derived from the extensive phytoplankton stocks within the system. In contrast, sub-adult and adult mysids (R. terranatalis, M. wooldridgei and G. brevifissura) appeared to consume a combination of phytoplankton and copepods. The contribution of the various sources of carbon to the total carbon intake of the mysid remains unknown.
- Full Text:
- Date Issued: 2005
Primary caregivers' experience of raising children with autism: a phenomenological perspective
- Authors: Swanepoel, Yolandi
- Date: 2005
- Subjects: Autism in children Autistic children Autism in children -- Diagnosis Parents of autistic children
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3067 , http://hdl.handle.net/10962/d1002576
- Description: Autism occupies an extreme position among childhood pathologies due to its severity, duration and impact on the family. In this qualitative study, four primary caregivers of autistic children were interviewed regarding their experiences of the diagnostic process, their post-diagnostic adjustment, and how helping professionals can improve their service rendering to these families. This study utilised a phenomenological approach to look at primary caregivers as the best-informed authority to explore and describe their lived realities and experiences of raising their autistic children in South Africa. The rationale for a phenomenological approach in this study is that such an interpretative inquiry enables material to be collected and analysed within the specific context of the subjective realities of primary caregivers of autistic children in South Africa. The researcher utilised semi-structured, in-depth, face-to-face interviews as method of data collection. Each participant was interviewed over the course of three separate interviews. The themes and categories that resulted from a content analysis of the material were grouped into two broad fields of experience, namely: (1) experiences surrounding the diagnostic process; and (2) the pervasive influence of autism on different areas of family life. In terms of experiences surrounding children’s diagnosis, four themes were identified: (1) Being a new parent and making sense out of chaos; (2) Responsibility and blame; (3) Confusion and disillusionment during early experiences with helping professionals; and (4) Feelings about the diagnosis. The pervasive influence of autism on different areas of family life includes: (5) Strained family relationships; (6) Challenges of behaviour management and disciplining the autistic child; (7) Challenges of finding suitable resources for education and day-care; and (8) Maintaining the family unit and doing things as a family.
- Full Text:
- Date Issued: 2005
- Authors: Swanepoel, Yolandi
- Date: 2005
- Subjects: Autism in children Autistic children Autism in children -- Diagnosis Parents of autistic children
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3067 , http://hdl.handle.net/10962/d1002576
- Description: Autism occupies an extreme position among childhood pathologies due to its severity, duration and impact on the family. In this qualitative study, four primary caregivers of autistic children were interviewed regarding their experiences of the diagnostic process, their post-diagnostic adjustment, and how helping professionals can improve their service rendering to these families. This study utilised a phenomenological approach to look at primary caregivers as the best-informed authority to explore and describe their lived realities and experiences of raising their autistic children in South Africa. The rationale for a phenomenological approach in this study is that such an interpretative inquiry enables material to be collected and analysed within the specific context of the subjective realities of primary caregivers of autistic children in South Africa. The researcher utilised semi-structured, in-depth, face-to-face interviews as method of data collection. Each participant was interviewed over the course of three separate interviews. The themes and categories that resulted from a content analysis of the material were grouped into two broad fields of experience, namely: (1) experiences surrounding the diagnostic process; and (2) the pervasive influence of autism on different areas of family life. In terms of experiences surrounding children’s diagnosis, four themes were identified: (1) Being a new parent and making sense out of chaos; (2) Responsibility and blame; (3) Confusion and disillusionment during early experiences with helping professionals; and (4) Feelings about the diagnosis. The pervasive influence of autism on different areas of family life includes: (5) Strained family relationships; (6) Challenges of behaviour management and disciplining the autistic child; (7) Challenges of finding suitable resources for education and day-care; and (8) Maintaining the family unit and doing things as a family.
- Full Text:
- Date Issued: 2005
Puerulus and early juvenile recruitment of the rock lobster jasus lalandii in relation to the environment at Lüderitz Bay, Namibia
- Authors: Keulder, Felicia Juanita
- Date: 2005
- Subjects: Jasus lalandii , Lobster fisheries -- Namibia , Lobster culture -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5315 , http://hdl.handle.net/10962/d1005160 , Jasus lalandii , Lobster fisheries -- Namibia , Lobster culture -- Namibia
- Description: A global decline in the lobster fishery has necessitated the growout of wild-caught postlarvae (pueruli) on farms to meet the worlds lobster demand. A limited knowledge on puerulus settlement in the West Coast rock lobster (Jasus lalandii) constitutes a major barrier for J. lalandii culture development in Southern Africa. As an extension of an existing long-term puerulus monitoring program of the Ministry of Fisheries and Marine Resources of Namibia, the present study monitored puerulus recruitment (supply), puerulus condition and juvenile growth of J. lalandii and their relationship with environmental variables on an oyster farm at Lüderitz Bay, Namibia. Implications for lobster aquaculture and fisheries management are discussed. Oyster bags, crates and collectors were sampled daily, weekly and bimonthly, for pueruli and juveniles, respectively, between August 2001 and July 2003 to establish spatialtemporal patterns in their distribution. Animals were transported to the laboratory for morphometric analyses where they were staged as puerulus (Pt = transparent; Pp = pigmented) and juvenile lobsters. The carapace lengths (0.1mm CL) and wet weights (0.01gram) of animals were recorded. Carapace length frequencies were subjected to Modal Progression analysis to identify early juvenile cohorts and calculate their growths. The weight-length ratios calculated and percentage fat content were used as indices of nutritional condition. Seasonal peaks in puerulus and juvenile abundance were estimated using Periodic Regression analysis. The relationships of puerulus and juvenile abundance with respect to sea surface temperature (SST), wind speed-direction, moon phase, swell and tidal range were established using time lag analysis (ADL). Transparent pueruli were randomly distributed on oyster bags and crates, and also between collector sites, suggesting that they have no particular settlement preference for certain areas on these structures (p>0.05; n=150). Pigmented puerulus (p<0.05; n=566) and juveniles (p<0.05; n=3528) preferred structurally complex structures that provided better shelter such as crates, which were more sheltered from sea swells, compared to oyster bags. Among oyster rafts, pigmented puerulus and juveniles preferred occupying the sheltered and centred raft areas, which provided better protection from wave action, compared to exposed raft areas, which were exposed to the incoming swell. Puerulus and juvenile lobster appeared to recolonise adjacent bags and crates, and possibly migrate to the substrate and off the farm due to the disturbance of the habitat during harvesting. The booth crevice collector was more efficient in collecting puerulus possibly due to the high structurally complex habitat and the better shelter they provided compared to the hogshair collector. The occupation of structurally complex habitats by early benthic stages may be related to morphological changes associated with metamorphosis. Puerulus settlement peaked during early spring (August-September) and was related to low sea surface temperatures (12.3°C), strong south winds, and moderate swells in the week preceding settlement. These conditions are synonymous with the “spring upwelling” season of the Lüderitz upwelling cell in the central Benguela current region. Puerulus nutritional condition peaked during this period possibly due to high levels of planktonic food (due to high nutrients from upwelling) that was available to the late stage phyllosoma larvae further offshore. A “good” puerulus settlement year during 2000 was associated with lower than average SST (11.6°C) and strong south winds and was followed by “poor” puerulus settlement years during 2001 and 2002 when higher than average SST were experienced with below average wind speeds experienced during 2001 only. Puerulus of J. lalandii recruited in high numbers into Lüderitz Bay during the new moon, full moon and last quarter moon phases by making use of the increased tides during these phases of the lunar cycle. Peak juvenile abundance during early summer (November-December) lagged by 8 weeks was significantly correlated with peak puerulus abundance. Puerulus size was similar (8.5–9.7mm CL) over the study period. Juvenile cohorts, 9.9-20.6mm CL in size recruited in 2 distinct waves in August 2001-June 2002 and July 2002-February 2003. The 2001/2002 recruits had higher monthly growth increments and better nutritional condition compared to 2002/2003 recruits. Peak frequencies of 2nd moult juveniles (9.9- 10.8mm CL) occurred in September of both recruitment events with nutritional condition being poorest during the 2002/2003 event. The nutritional condition of the settling puerulus did not appear to be related to the subsequent growth of juvenile lobster. These preliminary results suggest that pueruli recruit once a year mainly during late winter/ early spring under conditions typical of coastal upwelling in the Benguela current near Lüderitz. It appears that puerulus settlement is driven by favourable shoreward currents, which help in transporting puerulus to their settlement grounds. Puerulus supply is highly variable between years, which appears to be consistent with a highly variable Benguela environment. The oyster farm supported a substantial standing stock averaging 123 800 lobster per day (range: 22 600-325 300 lobster per day) of which 26 600 were puerulus and 97 200 were juveniles, that may have been harvested once off on any given day during the sample period. Monthly harvesting of the total lobster standing stock during the one and a half year sampling period was just over 2 million lobsters (505 700 pueruli and 1.85 million juveniles) and would potentially have been sufficient seed for a 200 ton lobster production in puerulus lobster growout facilities. In the light of high inter-annual variation in puerulus settlement observed at Lüderitz, the seed supply at the Lüderitz oyster farm is clearly limited and therefore it is prudent that other sites of high puerulus settlement is established before large commercial scale lobster growout can commence. The migration of lobster off the farm suggested that these lobsters potentially recruit to the fishery and therefore harvesting the entire standing stock on the farm may have adverse negative effects on the wild fishery. A policy decision will be required as to whether more efficient harvesting of lobster from the farm should be allowed. If puerulus removal in J. lalandii for aquaculture is allowed in the near future, it should be conducted on an experimental scale or small commercial scale until the potential effects on recruitment into the fishery are clearer.
- Full Text:
- Date Issued: 2005
- Authors: Keulder, Felicia Juanita
- Date: 2005
- Subjects: Jasus lalandii , Lobster fisheries -- Namibia , Lobster culture -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5315 , http://hdl.handle.net/10962/d1005160 , Jasus lalandii , Lobster fisheries -- Namibia , Lobster culture -- Namibia
- Description: A global decline in the lobster fishery has necessitated the growout of wild-caught postlarvae (pueruli) on farms to meet the worlds lobster demand. A limited knowledge on puerulus settlement in the West Coast rock lobster (Jasus lalandii) constitutes a major barrier for J. lalandii culture development in Southern Africa. As an extension of an existing long-term puerulus monitoring program of the Ministry of Fisheries and Marine Resources of Namibia, the present study monitored puerulus recruitment (supply), puerulus condition and juvenile growth of J. lalandii and their relationship with environmental variables on an oyster farm at Lüderitz Bay, Namibia. Implications for lobster aquaculture and fisheries management are discussed. Oyster bags, crates and collectors were sampled daily, weekly and bimonthly, for pueruli and juveniles, respectively, between August 2001 and July 2003 to establish spatialtemporal patterns in their distribution. Animals were transported to the laboratory for morphometric analyses where they were staged as puerulus (Pt = transparent; Pp = pigmented) and juvenile lobsters. The carapace lengths (0.1mm CL) and wet weights (0.01gram) of animals were recorded. Carapace length frequencies were subjected to Modal Progression analysis to identify early juvenile cohorts and calculate their growths. The weight-length ratios calculated and percentage fat content were used as indices of nutritional condition. Seasonal peaks in puerulus and juvenile abundance were estimated using Periodic Regression analysis. The relationships of puerulus and juvenile abundance with respect to sea surface temperature (SST), wind speed-direction, moon phase, swell and tidal range were established using time lag analysis (ADL). Transparent pueruli were randomly distributed on oyster bags and crates, and also between collector sites, suggesting that they have no particular settlement preference for certain areas on these structures (p>0.05; n=150). Pigmented puerulus (p<0.05; n=566) and juveniles (p<0.05; n=3528) preferred structurally complex structures that provided better shelter such as crates, which were more sheltered from sea swells, compared to oyster bags. Among oyster rafts, pigmented puerulus and juveniles preferred occupying the sheltered and centred raft areas, which provided better protection from wave action, compared to exposed raft areas, which were exposed to the incoming swell. Puerulus and juvenile lobster appeared to recolonise adjacent bags and crates, and possibly migrate to the substrate and off the farm due to the disturbance of the habitat during harvesting. The booth crevice collector was more efficient in collecting puerulus possibly due to the high structurally complex habitat and the better shelter they provided compared to the hogshair collector. The occupation of structurally complex habitats by early benthic stages may be related to morphological changes associated with metamorphosis. Puerulus settlement peaked during early spring (August-September) and was related to low sea surface temperatures (12.3°C), strong south winds, and moderate swells in the week preceding settlement. These conditions are synonymous with the “spring upwelling” season of the Lüderitz upwelling cell in the central Benguela current region. Puerulus nutritional condition peaked during this period possibly due to high levels of planktonic food (due to high nutrients from upwelling) that was available to the late stage phyllosoma larvae further offshore. A “good” puerulus settlement year during 2000 was associated with lower than average SST (11.6°C) and strong south winds and was followed by “poor” puerulus settlement years during 2001 and 2002 when higher than average SST were experienced with below average wind speeds experienced during 2001 only. Puerulus of J. lalandii recruited in high numbers into Lüderitz Bay during the new moon, full moon and last quarter moon phases by making use of the increased tides during these phases of the lunar cycle. Peak juvenile abundance during early summer (November-December) lagged by 8 weeks was significantly correlated with peak puerulus abundance. Puerulus size was similar (8.5–9.7mm CL) over the study period. Juvenile cohorts, 9.9-20.6mm CL in size recruited in 2 distinct waves in August 2001-June 2002 and July 2002-February 2003. The 2001/2002 recruits had higher monthly growth increments and better nutritional condition compared to 2002/2003 recruits. Peak frequencies of 2nd moult juveniles (9.9- 10.8mm CL) occurred in September of both recruitment events with nutritional condition being poorest during the 2002/2003 event. The nutritional condition of the settling puerulus did not appear to be related to the subsequent growth of juvenile lobster. These preliminary results suggest that pueruli recruit once a year mainly during late winter/ early spring under conditions typical of coastal upwelling in the Benguela current near Lüderitz. It appears that puerulus settlement is driven by favourable shoreward currents, which help in transporting puerulus to their settlement grounds. Puerulus supply is highly variable between years, which appears to be consistent with a highly variable Benguela environment. The oyster farm supported a substantial standing stock averaging 123 800 lobster per day (range: 22 600-325 300 lobster per day) of which 26 600 were puerulus and 97 200 were juveniles, that may have been harvested once off on any given day during the sample period. Monthly harvesting of the total lobster standing stock during the one and a half year sampling period was just over 2 million lobsters (505 700 pueruli and 1.85 million juveniles) and would potentially have been sufficient seed for a 200 ton lobster production in puerulus lobster growout facilities. In the light of high inter-annual variation in puerulus settlement observed at Lüderitz, the seed supply at the Lüderitz oyster farm is clearly limited and therefore it is prudent that other sites of high puerulus settlement is established before large commercial scale lobster growout can commence. The migration of lobster off the farm suggested that these lobsters potentially recruit to the fishery and therefore harvesting the entire standing stock on the farm may have adverse negative effects on the wild fishery. A policy decision will be required as to whether more efficient harvesting of lobster from the farm should be allowed. If puerulus removal in J. lalandii for aquaculture is allowed in the near future, it should be conducted on an experimental scale or small commercial scale until the potential effects on recruitment into the fishery are clearer.
- Full Text:
- Date Issued: 2005
Research portfolio
- Authors: Shihako, Mathilde
- Date: 2005
- Subjects: Rundu College of Education (Namibia) Education -- Namibia Educational change -- Namibia Curriculum planning -- Namibia Teaching -- Namibia Teachers -- Training of -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1729 , http://hdl.handle.net/10962/d1003612
- Description: This portfolio discusses various important aspects that affect teacher education. The portfolio has become an important tool for assessment in education. The research component of the masters' course that I attended is reflected in this portfolio. To complete this course several aspects were covered. The educational reform process in the Namibian context requires the use of appropriate resources, an environment conducive to learning, active involvement of the learners and teachers who should have a better understanding of the system adopted. Teacher educators are seen as important in transforming Namibian education in the sense of breaking the cycle of authoritarianism and inequities that existed in schooling prior to independence in 1990, and that still continue to exist in many Namibian schools today. Much effort has been devoted to creating conditions in colleges of education, where future teachers experience the same kind of teaching and learning that is envisioned for schools in the country. To accomplish this a great deal of effort has been devoted to the professional development of teacher educators. This masters' course was initiated to address the shortcomings of teacher education in Namibia. The preparation of teacher educators to be willing and able to prepare teachers in a manner that is consistent with national educational goals has been a neglected element of educational reform in Third World countries (Taylor and Peacock, 1997). Nahas Angula defines teachers as critical agents in creating the reform in relation to several broad principals: access, equity, quality, and democracy. As Ebbutt and Elliot (1998) point out, these principles are defined in very broad terms and provide the opportunity for teachers, teacher educators, and administrators to translate the ideals in particular contexts through practical reflection and deliberation. The Namibian reforms are underpinned by democratic ideals, the intention being to develop broad participation in defining and developing the reform tenets in specific contexts. In Namibia it has been recognized that qualitative changes in classroom practice will only occur when teachers understand them and accept them as their own. It is also recognized that because many teachers have been educated under the authoritarian system of the past, conceptual changes are needed in the minds of the teachers for the reforms to be successful. These include a shift from the belief of teachers as civil servants who are merely to "deliver" a curriculum dictated from above, to one of teachers as reflective professionals who play important roles in interpreting and defining the reforms and in giving meaning to such values as learner-centered and democratic education, continuous assessment, and critical inquiry (Swarts 1998). In the case of Namibia, we have a situation where there is an attempt to fundamentally transform an authoritarian education system that emphasized repetition and rote learning of received knowledge to one where learners are active participants in the learning process and where the curriculum is relevant to and respectful of different cultural traditions and communities. The learner-centered philosophy that guides post-independence educational reforms in Namibia calls for breaking down the authoritarian teacher-student relationships of the past. It encourages teachers to begin instruction by gaining an understanding of their learners' existing knowledge, skills, and understandings and to actively involve them in the learning process toward the goal of preparing citizens for a democratic society. The background above will help the readers to understand the sections covered in this portfolio. In the first part, the portfolio looks at a case study that analyses pre- and post-independence teacher education in Namibia. This study focuses on the Rundu College of Education and investigates the implementation of the Basic Education Teacher Diploma (BETD) Broad Curriculum in relation to the History syllabus. This paper presents information on what led to post-independence teacher education reforms in Namibia and why the reform was necessary. The BETD Broad Curriculum advocates the principles underpinning teacher education reforms in Namibia. The analysis looks at whether the History syllabus applies the principles of teacher education reform in relation to practice in the classroom. This paper addresses the historical background of a History curriculum, which shows the importance of a contextual understanding of the theoretical framework. The second paper looks at the theories underpinning the pre- and post-independence curriculum and the reform process in Namibia, how each theory views knowledge and why a decision was taken to apply them. The third paper is a literature review that links the epistemological ideals of reform to the classroom situation. This paper provides the basis for a small-scale empirical research. The research proposal included in the portfolio emerged from the earlier studies and identifies a key area for investigation within the domain of my particular area of teaching. The identified research problem investigated is presented in the final paper of the portfolio. These research findings can be applied to different situations in different schools. The portfolio is completed by the presentation of a short reflection of the role of the portfolio in this masters' course.
- Full Text:
- Date Issued: 2005
- Authors: Shihako, Mathilde
- Date: 2005
- Subjects: Rundu College of Education (Namibia) Education -- Namibia Educational change -- Namibia Curriculum planning -- Namibia Teaching -- Namibia Teachers -- Training of -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1729 , http://hdl.handle.net/10962/d1003612
- Description: This portfolio discusses various important aspects that affect teacher education. The portfolio has become an important tool for assessment in education. The research component of the masters' course that I attended is reflected in this portfolio. To complete this course several aspects were covered. The educational reform process in the Namibian context requires the use of appropriate resources, an environment conducive to learning, active involvement of the learners and teachers who should have a better understanding of the system adopted. Teacher educators are seen as important in transforming Namibian education in the sense of breaking the cycle of authoritarianism and inequities that existed in schooling prior to independence in 1990, and that still continue to exist in many Namibian schools today. Much effort has been devoted to creating conditions in colleges of education, where future teachers experience the same kind of teaching and learning that is envisioned for schools in the country. To accomplish this a great deal of effort has been devoted to the professional development of teacher educators. This masters' course was initiated to address the shortcomings of teacher education in Namibia. The preparation of teacher educators to be willing and able to prepare teachers in a manner that is consistent with national educational goals has been a neglected element of educational reform in Third World countries (Taylor and Peacock, 1997). Nahas Angula defines teachers as critical agents in creating the reform in relation to several broad principals: access, equity, quality, and democracy. As Ebbutt and Elliot (1998) point out, these principles are defined in very broad terms and provide the opportunity for teachers, teacher educators, and administrators to translate the ideals in particular contexts through practical reflection and deliberation. The Namibian reforms are underpinned by democratic ideals, the intention being to develop broad participation in defining and developing the reform tenets in specific contexts. In Namibia it has been recognized that qualitative changes in classroom practice will only occur when teachers understand them and accept them as their own. It is also recognized that because many teachers have been educated under the authoritarian system of the past, conceptual changes are needed in the minds of the teachers for the reforms to be successful. These include a shift from the belief of teachers as civil servants who are merely to "deliver" a curriculum dictated from above, to one of teachers as reflective professionals who play important roles in interpreting and defining the reforms and in giving meaning to such values as learner-centered and democratic education, continuous assessment, and critical inquiry (Swarts 1998). In the case of Namibia, we have a situation where there is an attempt to fundamentally transform an authoritarian education system that emphasized repetition and rote learning of received knowledge to one where learners are active participants in the learning process and where the curriculum is relevant to and respectful of different cultural traditions and communities. The learner-centered philosophy that guides post-independence educational reforms in Namibia calls for breaking down the authoritarian teacher-student relationships of the past. It encourages teachers to begin instruction by gaining an understanding of their learners' existing knowledge, skills, and understandings and to actively involve them in the learning process toward the goal of preparing citizens for a democratic society. The background above will help the readers to understand the sections covered in this portfolio. In the first part, the portfolio looks at a case study that analyses pre- and post-independence teacher education in Namibia. This study focuses on the Rundu College of Education and investigates the implementation of the Basic Education Teacher Diploma (BETD) Broad Curriculum in relation to the History syllabus. This paper presents information on what led to post-independence teacher education reforms in Namibia and why the reform was necessary. The BETD Broad Curriculum advocates the principles underpinning teacher education reforms in Namibia. The analysis looks at whether the History syllabus applies the principles of teacher education reform in relation to practice in the classroom. This paper addresses the historical background of a History curriculum, which shows the importance of a contextual understanding of the theoretical framework. The second paper looks at the theories underpinning the pre- and post-independence curriculum and the reform process in Namibia, how each theory views knowledge and why a decision was taken to apply them. The third paper is a literature review that links the epistemological ideals of reform to the classroom situation. This paper provides the basis for a small-scale empirical research. The research proposal included in the portfolio emerged from the earlier studies and identifies a key area for investigation within the domain of my particular area of teaching. The identified research problem investigated is presented in the final paper of the portfolio. These research findings can be applied to different situations in different schools. The portfolio is completed by the presentation of a short reflection of the role of the portfolio in this masters' course.
- Full Text:
- Date Issued: 2005
School management team members' perceptions of their roles in managing Grahamstown secondary schools
- Authors: Tyala, Zakunzima
- Date: 2005
- Subjects: School management teams -- South Africa -- Grahamstown School management and organization -- South Africa -- Grahamstown Educational leadership -- South Africa -- Grahamstown Education, Secondary -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1759 , http://hdl.handle.net/10962/d1003644
- Description: During the apartheid era, that is, before 1994, the education management system in South Africa was fragmented, authoritarian and top-down. Principals were expected to manage schools on their own without consulting the rest of the staff. The birth of political democracy in 1994 resulted in many changes in the education system. These changes include the creation of one national department. In line with this democratisation came the concept of school management teams (SMTs). Because of the democratic nature of this kind of a structure (SMT), it is required that educators work co-operatively and as a team. This has been problematic in some schools where the principal has traditionally felt comfortable taking decisions on his or her own without any input from relevant stakeholders. Furthermore, through the legacy of apartheid, teachers themselves have dogmatically been oriented to being the recipients of instructions and to view management as the prerogative of the principals only. The formalisation of SMTs thus brings new challenges to both principals and staff members, essentially the notion of democratic or team-management. The object of this study is to find out how the concept of democratic management is being received. This study includes all the government-aided high schools in Grahamstown (ten of them). Studying all 10 high schools - 6 from the local township, 3 ex-model C schools, and 1 from the coloured township – has produced a broad and varied picture of how SMTs are being received in Grahamstown secondary schools. The study was framed within the interpretive approach, and sought to unpack the perceptions of SMT members with regard to SMTs. An interpretive paradigm made it possible for me to gain an in-depth understanding of SMT members’ perceptions of team-management within their contexts. I used questionnaires, interviews and observation as research tools to gather data. This study has found that, although the concept of team management is well-received, there are significant obstacles to the acceptance of teamwork as an alternative form of management. Many of these may be the result of decades of disempowering governance strategies, resulting in impoverished notions of school ownership and joint responsibility. Some relate to the political nature of schools as organisations. Despite these problems, the study has confirmed that team-management is the preferred approach for a variety of reasons. Team-management usually results in enriched decision-making, the sharing of responsibilities and higher levels of support. A major systemic shortcoming highlighted by the study is the absence of meaningful training in democratic educational management.
- Full Text:
- Date Issued: 2005
School management team members' perceptions of their roles in managing Grahamstown secondary schools
- Authors: Tyala, Zakunzima
- Date: 2005
- Subjects: School management teams -- South Africa -- Grahamstown School management and organization -- South Africa -- Grahamstown Educational leadership -- South Africa -- Grahamstown Education, Secondary -- South Africa -- Grahamstown
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1759 , http://hdl.handle.net/10962/d1003644
- Description: During the apartheid era, that is, before 1994, the education management system in South Africa was fragmented, authoritarian and top-down. Principals were expected to manage schools on their own without consulting the rest of the staff. The birth of political democracy in 1994 resulted in many changes in the education system. These changes include the creation of one national department. In line with this democratisation came the concept of school management teams (SMTs). Because of the democratic nature of this kind of a structure (SMT), it is required that educators work co-operatively and as a team. This has been problematic in some schools where the principal has traditionally felt comfortable taking decisions on his or her own without any input from relevant stakeholders. Furthermore, through the legacy of apartheid, teachers themselves have dogmatically been oriented to being the recipients of instructions and to view management as the prerogative of the principals only. The formalisation of SMTs thus brings new challenges to both principals and staff members, essentially the notion of democratic or team-management. The object of this study is to find out how the concept of democratic management is being received. This study includes all the government-aided high schools in Grahamstown (ten of them). Studying all 10 high schools - 6 from the local township, 3 ex-model C schools, and 1 from the coloured township – has produced a broad and varied picture of how SMTs are being received in Grahamstown secondary schools. The study was framed within the interpretive approach, and sought to unpack the perceptions of SMT members with regard to SMTs. An interpretive paradigm made it possible for me to gain an in-depth understanding of SMT members’ perceptions of team-management within their contexts. I used questionnaires, interviews and observation as research tools to gather data. This study has found that, although the concept of team management is well-received, there are significant obstacles to the acceptance of teamwork as an alternative form of management. Many of these may be the result of decades of disempowering governance strategies, resulting in impoverished notions of school ownership and joint responsibility. Some relate to the political nature of schools as organisations. Despite these problems, the study has confirmed that team-management is the preferred approach for a variety of reasons. Team-management usually results in enriched decision-making, the sharing of responsibilities and higher levels of support. A major systemic shortcoming highlighted by the study is the absence of meaningful training in democratic educational management.
- Full Text:
- Date Issued: 2005
Screening of technologies for the recovery of rhodium (III) metal ions from a precious metal refinery wastewater
- Authors: Mack, Cherie-Lynn
- Date: 2005
- Subjects: Rhodium , Metal ions , Sewage -- Purification -- Metals removal , Platinum group
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3987 , http://hdl.handle.net/10962/d1004046 , Rhodium , Metal ions , Sewage -- Purification -- Metals removal , Platinum group
- Description: The selective recovery of rhodium from wastewaters, in which the metal would be otherwise lost, would be highly profitable if the process were suitably low-cost. Current recovery processes are generally high maintenance and high-cost, whereas biological processes can be engineered to run with little external input in terms of cost and maintenance. Three emerging technologies were chosen based on their reported efficiency when removing base metals from wastewaters. The first technology screened, the sulphide-extraction membrane bioreactor (SEMB), consists of a sulphate-reducing prokaryote (SRP) anaerobic digester, in which a silicone membrane is submerged. Wastewater is passed through the membrane and metal ions are precipitated as metal sulphides by the hydrogen sulphide gas, which is capable of permeating the membrane. The second technology screened was a fluidized sand bed reactor in which metal ions are removed from solution via induction of nucleated precipitation by sodium carbonate onto the sand grains. The third, and most well established removal technology screened was a biosorption system using immobilized Saccharomyces cerevisiae biomass as the biosorbent. Experimental trials with each technology highlighted drawbacks with each; the SEMB system proved to be largely ineffective when challenged with the removal of rhodium from the wastewater as the rhodium precipitate fouled the membrane within hours, the fluidized bed system seemed unable to overcome the acidity of the wastewater and thus could not precipitate out the rhodium metal, and the efficiency of the biosorption process was hampered by the diversity of rhodium species present in the wastewater, which reduced the amount recovered. The outcomes of the trials with each technology indicated that further optimization of the technology or pretreatment of the wastewater is necessary before any of these options can be implemented. It could be concluded, however, that despite further optimization, both the SEMB and the fluidized bed system were not applicable in this case as precipitation would be non-specific, resulting in the necessity for further steps in order to purify the rhodium ions. Hence, the biosorption system was shown to be most applicable, and further optimization of the system could yield a highly efficient rhodium recovery process.
- Full Text:
- Date Issued: 2005
- Authors: Mack, Cherie-Lynn
- Date: 2005
- Subjects: Rhodium , Metal ions , Sewage -- Purification -- Metals removal , Platinum group
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3987 , http://hdl.handle.net/10962/d1004046 , Rhodium , Metal ions , Sewage -- Purification -- Metals removal , Platinum group
- Description: The selective recovery of rhodium from wastewaters, in which the metal would be otherwise lost, would be highly profitable if the process were suitably low-cost. Current recovery processes are generally high maintenance and high-cost, whereas biological processes can be engineered to run with little external input in terms of cost and maintenance. Three emerging technologies were chosen based on their reported efficiency when removing base metals from wastewaters. The first technology screened, the sulphide-extraction membrane bioreactor (SEMB), consists of a sulphate-reducing prokaryote (SRP) anaerobic digester, in which a silicone membrane is submerged. Wastewater is passed through the membrane and metal ions are precipitated as metal sulphides by the hydrogen sulphide gas, which is capable of permeating the membrane. The second technology screened was a fluidized sand bed reactor in which metal ions are removed from solution via induction of nucleated precipitation by sodium carbonate onto the sand grains. The third, and most well established removal technology screened was a biosorption system using immobilized Saccharomyces cerevisiae biomass as the biosorbent. Experimental trials with each technology highlighted drawbacks with each; the SEMB system proved to be largely ineffective when challenged with the removal of rhodium from the wastewater as the rhodium precipitate fouled the membrane within hours, the fluidized bed system seemed unable to overcome the acidity of the wastewater and thus could not precipitate out the rhodium metal, and the efficiency of the biosorption process was hampered by the diversity of rhodium species present in the wastewater, which reduced the amount recovered. The outcomes of the trials with each technology indicated that further optimization of the technology or pretreatment of the wastewater is necessary before any of these options can be implemented. It could be concluded, however, that despite further optimization, both the SEMB and the fluidized bed system were not applicable in this case as precipitation would be non-specific, resulting in the necessity for further steps in order to purify the rhodium ions. Hence, the biosorption system was shown to be most applicable, and further optimization of the system could yield a highly efficient rhodium recovery process.
- Full Text:
- Date Issued: 2005
Secondary school principals' perceptions and experience of management development programmes
- Authors: Madasi, Vuyelwa
- Date: 2005
- Subjects: Educational change -- South Africa School management and organization -- South Africa Educational leadership -- South Africa Educational planning -- South Africa School improvement programs -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1763 , http://hdl.handle.net/10962/d1003648
- Description: Management development in educational contexts is a relatively recent development in South Africa. The Task Team Report on Education Management Development of 1996 drew pertinent attention to the need for education management development in South Africa, and set an agenda for such development. Since then many management development programmes have been launched by both National and Provincial government. However, very little research seems to have been conducted on these programmes, especially on how they have been received. This study seeks to address that need. The study is a qualitative phenomenological investigation of how four secondary school principals experienced and perceived the management development programmes they have attended. In line with a phenomenological approach, the study sets aside preconceived ideas and attempts to describe the phenomenon through the eyes of the participants. Findings suggest that management development programmes are perceived as having a big role to play in the development of school managers, but that the programmes on offer suffer from various shortcomings. These include poor planning, lack of organisational and facilitating skills in presenters, lack of commitment, monitoring and support from the bodies offering the courses, and especially the failure of training programmes to bring about increased confidence and self-awareness among participants. Increased selfawareness can help in personal and organisational renewal and growth, and help to minimise the dependency syndrome among principals. Particular needs highlighted by the findings include training in the new curriculum (Outcomes Based Education), holistic development by experts in all facets of school management, training of School Governing Bodies and development of all educators in management as future managers. These findings may prove helpful to education departments and other bodies in the planning and delivery of programmes for new and incumbent school managers.
- Full Text:
- Date Issued: 2005
- Authors: Madasi, Vuyelwa
- Date: 2005
- Subjects: Educational change -- South Africa School management and organization -- South Africa Educational leadership -- South Africa Educational planning -- South Africa School improvement programs -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1763 , http://hdl.handle.net/10962/d1003648
- Description: Management development in educational contexts is a relatively recent development in South Africa. The Task Team Report on Education Management Development of 1996 drew pertinent attention to the need for education management development in South Africa, and set an agenda for such development. Since then many management development programmes have been launched by both National and Provincial government. However, very little research seems to have been conducted on these programmes, especially on how they have been received. This study seeks to address that need. The study is a qualitative phenomenological investigation of how four secondary school principals experienced and perceived the management development programmes they have attended. In line with a phenomenological approach, the study sets aside preconceived ideas and attempts to describe the phenomenon through the eyes of the participants. Findings suggest that management development programmes are perceived as having a big role to play in the development of school managers, but that the programmes on offer suffer from various shortcomings. These include poor planning, lack of organisational and facilitating skills in presenters, lack of commitment, monitoring and support from the bodies offering the courses, and especially the failure of training programmes to bring about increased confidence and self-awareness among participants. Increased selfawareness can help in personal and organisational renewal and growth, and help to minimise the dependency syndrome among principals. Particular needs highlighted by the findings include training in the new curriculum (Outcomes Based Education), holistic development by experts in all facets of school management, training of School Governing Bodies and development of all educators in management as future managers. These findings may prove helpful to education departments and other bodies in the planning and delivery of programmes for new and incumbent school managers.
- Full Text:
- Date Issued: 2005
September 11 : catalyst for structural-genealogical narrative of a new world (Dis)order
- Authors: Buijs, Lorena Maria Elisa
- Date: 2005
- Subjects: September 11 Terrorist Attacks, 2001 , United States -- Politics and government -- 2001- , Terrorism -- Government policy -- United States , United States -- Foreign relations -- Middle East , Middle East -- Foreign relations -- United States , Islam and world politics , Terrorism -- Religious aspects -- Islam , Jihad
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2852 , http://hdl.handle.net/10962/d1006463 , September 11 Terrorist Attacks, 2001 , United States -- Politics and government -- 2001- , Terrorism -- Government policy -- United States , United States -- Foreign relations -- Middle East , Middle East -- Foreign relations -- United States , Islam and world politics , Terrorism -- Religious aspects -- Islam , Jihad
- Description: The attacks of September 11, 2001, have changed America forever. In a horrific manner the vulnerability of the highly developed states was demonstrated and exposed in world politics. The event is ushering a new political era where far reaching shifts in international relations are under way. In the post Cold-War international world it appears that the ideological conflict between capitalism and socialism has been replaced by a new world order. One that has retained the binary conflict structure of the Cold War, except that this binary is now presented by political Islam and consumerist's capitalism (Martin, 2000:155). Indeed, in the previous bipolar world order, the acute distinction between capitalism and communism served to attenuate the discord in and between religions. This complex blurring of distinctions has been systematically heightened since the end of the Cold War, as it has allowed Western governments to maintain controlling interests outside of their dominions (Gupta, 2002:6) . This struggle has since been conceived in a variety of different, but related ways: A 'Clash of Civilizations' (Huntington 1996), or as an inescapable dialectic typical of the process of globalization itself (Barber, 1996:245). In the case of Huntington's (1996:19-20) genealogical narrative, he refers to global politics and the way in which the future will be reconfigured according to cultural identities. The division along these cultural lines, will furthermore "shape" the patterns of cohesion, disintegration, and conflict in the Post-Cold War world" (Huntington, 1996:20). Huntington's thesis is rather overriding in explaining the clash between the supposedly 'West' vs. 'Rest', whose interaction is historically determined. Yet, the genealogical narrative is not sufficient in taking into account the dynamics of globalization. Benjamin Barber's structural narrative, on the other hand, goes to great lengths to illustrate the paradoxical relationship between Jihad and McWorld, and how both forces tend to survive in a world that they inevitably create. By' acknowledging the relevance of both binaries (East/West), it is hoped to transcend them by presenting a structural-genealogical grand narrative, which will essentially allow one to understand Jihad as being a structural moment of the genealogical narrative. Given this general strategy, it will become perceptible that Jihad is one form of anti-globalization as the structural narratives become part of the genealogical and the genealogical part of the structural. In essence, then, this thesis is attempting to come to grips with the phenomenon of September 11, from a political-philosophical perspective. More specifically, this study will firstly be looking at two different, but related narratives that have emerged post-September 11, to make sense of the event. Given the structural-genealogical approach, the central concern in this study is consequently to look at two separate but related interests. The one pertains to history and the other to historiography.
- Full Text:
- Date Issued: 2005
- Authors: Buijs, Lorena Maria Elisa
- Date: 2005
- Subjects: September 11 Terrorist Attacks, 2001 , United States -- Politics and government -- 2001- , Terrorism -- Government policy -- United States , United States -- Foreign relations -- Middle East , Middle East -- Foreign relations -- United States , Islam and world politics , Terrorism -- Religious aspects -- Islam , Jihad
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2852 , http://hdl.handle.net/10962/d1006463 , September 11 Terrorist Attacks, 2001 , United States -- Politics and government -- 2001- , Terrorism -- Government policy -- United States , United States -- Foreign relations -- Middle East , Middle East -- Foreign relations -- United States , Islam and world politics , Terrorism -- Religious aspects -- Islam , Jihad
- Description: The attacks of September 11, 2001, have changed America forever. In a horrific manner the vulnerability of the highly developed states was demonstrated and exposed in world politics. The event is ushering a new political era where far reaching shifts in international relations are under way. In the post Cold-War international world it appears that the ideological conflict between capitalism and socialism has been replaced by a new world order. One that has retained the binary conflict structure of the Cold War, except that this binary is now presented by political Islam and consumerist's capitalism (Martin, 2000:155). Indeed, in the previous bipolar world order, the acute distinction between capitalism and communism served to attenuate the discord in and between religions. This complex blurring of distinctions has been systematically heightened since the end of the Cold War, as it has allowed Western governments to maintain controlling interests outside of their dominions (Gupta, 2002:6) . This struggle has since been conceived in a variety of different, but related ways: A 'Clash of Civilizations' (Huntington 1996), or as an inescapable dialectic typical of the process of globalization itself (Barber, 1996:245). In the case of Huntington's (1996:19-20) genealogical narrative, he refers to global politics and the way in which the future will be reconfigured according to cultural identities. The division along these cultural lines, will furthermore "shape" the patterns of cohesion, disintegration, and conflict in the Post-Cold War world" (Huntington, 1996:20). Huntington's thesis is rather overriding in explaining the clash between the supposedly 'West' vs. 'Rest', whose interaction is historically determined. Yet, the genealogical narrative is not sufficient in taking into account the dynamics of globalization. Benjamin Barber's structural narrative, on the other hand, goes to great lengths to illustrate the paradoxical relationship between Jihad and McWorld, and how both forces tend to survive in a world that they inevitably create. By' acknowledging the relevance of both binaries (East/West), it is hoped to transcend them by presenting a structural-genealogical grand narrative, which will essentially allow one to understand Jihad as being a structural moment of the genealogical narrative. Given this general strategy, it will become perceptible that Jihad is one form of anti-globalization as the structural narratives become part of the genealogical and the genealogical part of the structural. In essence, then, this thesis is attempting to come to grips with the phenomenon of September 11, from a political-philosophical perspective. More specifically, this study will firstly be looking at two different, but related narratives that have emerged post-September 11, to make sense of the event. Given the structural-genealogical approach, the central concern in this study is consequently to look at two separate but related interests. The one pertains to history and the other to historiography.
- Full Text:
- Date Issued: 2005
Strategic leadership within the Duke of Edinburgh's International Award Association between 1988 and 2004
- Authors: Andrew, Craig Bruce
- Date: 2005
- Subjects: Duke of Edinburgh's Award (Organization) Duke of Edinburgh's Award -- History Nonprofit organizations -- Management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:764 , http://hdl.handle.net/10962/d1003885
- Description: Providing strategic leadership for global Not-for-Profit organisations poses great challenges to the leadership structures of these voluntary organisations. This study looks at the phenomenon of strategic leadership in the Duke of Edinburgh’s (DOE) International Award Association (IAA) as a global Not-for-Profit Organisation (NPO). The main aim of the research was an in-depth examination of the processes involved in leadership at the top level in a global NPO. Eight strategic leaders from the top management team were interviewed. Further information was generated from a study of the Annual Reports spanning the 15 year period (1988/9 – 2003/4), and key strategic documents were used as supporting material. The research was conducted in a phenomenological paradigm, using the case study research method. Care was taken to minimize possible researcher bias and interpretations, as the researcher has been associated with this organisation for the past 18 years. It was found that the Royal Family play extremely valuable and multifaceted roles in the organisation. The triumvirate of The Royals; The Secretary General’s; and The Trustees; works well as individual ‘great groups’ yet when necessary, they form a collective collaborative grouping to effect strategic leadership for the IAA. The two main themes to emerge from the findings were the nature of the DOE as a global NPO and the role of strategic leadership in the DOE Award. The DOE Award has demonstrated that it has many unique strategic leadership features and is using these features to become more business-like in the application of its new strategic vision. The individual ‘great groups’ offer sound leadership throughout the process of overseeing and running the business of the DOE Award yet, when necessary and appropriate, these great groups appear to work collectively, perhaps in an unstructured manner, as the triumvirate of power. Their collective collaborative leadership is a unique feature of the DOE Award. The highly interactive role of the Royal Family is unique and sets the DOE Award apart from other similar youth organisations globally. The nature of the loose association of National Award Authorities all subscribing to the rules and conditions of association is also a very unique feature of this NPO. The DOE Award is not a movement organisation but is guided by its service ethic. The DOE Award is a service organisation in which the strategic leadership plays a crucial role yet the constitutional power resides with the International Award Association membership. This IAA membership meets every three years at the World Forum Triennium to approve all new policy and procedures.
- Full Text:
- Date Issued: 2005
- Authors: Andrew, Craig Bruce
- Date: 2005
- Subjects: Duke of Edinburgh's Award (Organization) Duke of Edinburgh's Award -- History Nonprofit organizations -- Management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:764 , http://hdl.handle.net/10962/d1003885
- Description: Providing strategic leadership for global Not-for-Profit organisations poses great challenges to the leadership structures of these voluntary organisations. This study looks at the phenomenon of strategic leadership in the Duke of Edinburgh’s (DOE) International Award Association (IAA) as a global Not-for-Profit Organisation (NPO). The main aim of the research was an in-depth examination of the processes involved in leadership at the top level in a global NPO. Eight strategic leaders from the top management team were interviewed. Further information was generated from a study of the Annual Reports spanning the 15 year period (1988/9 – 2003/4), and key strategic documents were used as supporting material. The research was conducted in a phenomenological paradigm, using the case study research method. Care was taken to minimize possible researcher bias and interpretations, as the researcher has been associated with this organisation for the past 18 years. It was found that the Royal Family play extremely valuable and multifaceted roles in the organisation. The triumvirate of The Royals; The Secretary General’s; and The Trustees; works well as individual ‘great groups’ yet when necessary, they form a collective collaborative grouping to effect strategic leadership for the IAA. The two main themes to emerge from the findings were the nature of the DOE as a global NPO and the role of strategic leadership in the DOE Award. The DOE Award has demonstrated that it has many unique strategic leadership features and is using these features to become more business-like in the application of its new strategic vision. The individual ‘great groups’ offer sound leadership throughout the process of overseeing and running the business of the DOE Award yet, when necessary and appropriate, these great groups appear to work collectively, perhaps in an unstructured manner, as the triumvirate of power. Their collective collaborative leadership is a unique feature of the DOE Award. The highly interactive role of the Royal Family is unique and sets the DOE Award apart from other similar youth organisations globally. The nature of the loose association of National Award Authorities all subscribing to the rules and conditions of association is also a very unique feature of this NPO. The DOE Award is not a movement organisation but is guided by its service ethic. The DOE Award is a service organisation in which the strategic leadership plays a crucial role yet the constitutional power resides with the International Award Association membership. This IAA membership meets every three years at the World Forum Triennium to approve all new policy and procedures.
- Full Text:
- Date Issued: 2005
Strategies used by subject advisors and facilitators to support lesson planning with an environmental learning focus : a case study of the Eastern Cape Neep-Get cluster
- Authors: Mbambisa, Nomaledi Peggy
- Date: 2005
- Subjects: Educational change -- South Africa Education and state -- South Africa Environmental education -- South Africa Competency-based education Curriculum change -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1926 , http://hdl.handle.net/10962/d1007586
- Description: Over the past ten years, South Africa has undergone substantial changes, following the advent of democracy. Key amongst these changes being the transformation of educational policy. These policy changes have introduced new structural frameworks within which we operate (including myself as a subject advisor) and new roles for educators. These policy changes affect all the levels of the education system, and have an impact at school level, where teachers are now responsible for learning programme development (including a focus on lesson planning). Lesson planning in an outcomes-based education framework is a challenging aspect of policy implementation. South Africa is faced with the challenges associated with policy change and implementation. The role of the subject advisors and facilitators who support the teachers to make sense of the curriculum is crucial, as they provide the interface between policy and practice. They are the people who work most with teachers, and have a responsibility for curriculum implementation. This study aimed to explore the strategies which are used by subject advisors and facilitators to support teachers develop lesson plans with an environmental learning focus. A qualitative case study was conducted in which I looked at how the support processes were provided by the subject advisors and facilitators in the Eastern Cape in particular the NEEP-GET cluster in the Makana district. The study employed a range of data producing techniques such as questionnaires, interviews, document analysis and observation. The data was analysed to report the findings. The research indicates that some strategies are used to provide curriculum and pedagogical support and guidance, but that these are superficially treated and others have not been attempted at all. This therefore shows that further growth in this area is possible amongst the subject advisors. Recommendations relevant to both the subject advisors and the Department of Education so as to enhance the support processes and professional development of subject advisors have been made.
- Full Text:
- Date Issued: 2005
- Authors: Mbambisa, Nomaledi Peggy
- Date: 2005
- Subjects: Educational change -- South Africa Education and state -- South Africa Environmental education -- South Africa Competency-based education Curriculum change -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1926 , http://hdl.handle.net/10962/d1007586
- Description: Over the past ten years, South Africa has undergone substantial changes, following the advent of democracy. Key amongst these changes being the transformation of educational policy. These policy changes have introduced new structural frameworks within which we operate (including myself as a subject advisor) and new roles for educators. These policy changes affect all the levels of the education system, and have an impact at school level, where teachers are now responsible for learning programme development (including a focus on lesson planning). Lesson planning in an outcomes-based education framework is a challenging aspect of policy implementation. South Africa is faced with the challenges associated with policy change and implementation. The role of the subject advisors and facilitators who support the teachers to make sense of the curriculum is crucial, as they provide the interface between policy and practice. They are the people who work most with teachers, and have a responsibility for curriculum implementation. This study aimed to explore the strategies which are used by subject advisors and facilitators to support teachers develop lesson plans with an environmental learning focus. A qualitative case study was conducted in which I looked at how the support processes were provided by the subject advisors and facilitators in the Eastern Cape in particular the NEEP-GET cluster in the Makana district. The study employed a range of data producing techniques such as questionnaires, interviews, document analysis and observation. The data was analysed to report the findings. The research indicates that some strategies are used to provide curriculum and pedagogical support and guidance, but that these are superficially treated and others have not been attempted at all. This therefore shows that further growth in this area is possible amongst the subject advisors. Recommendations relevant to both the subject advisors and the Department of Education so as to enhance the support processes and professional development of subject advisors have been made.
- Full Text:
- Date Issued: 2005
Stress-inducible protein 1: a bioinformatic analysis of the human, mouse and yeast STI1 gene structure
- Authors: Aken, Bronwen Louise
- Date: 2005
- Subjects: Molecular chaperones , Proteins -- Analysis , Heat shock proteins , Bioinformatics , Genetics -- Data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3990 , http://hdl.handle.net/10962/d1004049 , Molecular chaperones , Proteins -- Analysis , Heat shock proteins , Bioinformatics , Genetics -- Data processing
- Description: Stress-inducible protein 1 (Sti1) is a 60 kDa eukaryotic protein that is important under stress and non-stress conditions. Human Sti1 is also known as the Hsp70/Hsp90 organising protein (Hop) that coordinates the functional cooperation of heat shock protein 70 (Hsp70) and heat shock protein 90 (Hsp90) during the folding of various transcription factors and kinases, including certain oncogenic proteins and prion proteins. Limited studies have been conducted on the STI1 gene structure. Thus, the aim of this study was to develop a comprehensive description of human STI1 (hSTI1), mouse STI1 (mSTI1), and yeast STI1 (ySTI1) genes, using a bioinformatic approach. Genes encoded near the STI1 loci were identified for the three organisms using National Centre for Biotechnology Information (NCBI) MapViewer and the Saccharomyces Genome Database. Exon/intron boundaries were predicted using Hidden Markov model gene prediction software (HMMGene) and Genscan, and by alignment of the mRNA sequence with the genomic DNA sequence. Transcription factor binding sites (TFBS) were predicted by scanning the region 1000 base pairs (bp) upstream of the STI1 orthologues’ transcription start site (TSS) with Alibaba, Transcription element search software (TESS) and Transcription factor search (TFSearch). The promoter region was defined by comparing the number, type and position of TFBS across the orthologous STI1 genes. Additional putative TFBS were identified for ySTI1 by searching with software that aligns nucleic acid conserved elements (AlignACE) for over-represented motifs in the region upstream of the TSS of genes thought to be co-regulated with ySTI1. This study showed that hSTI1 and mSTI1 occur in a region of synteny with a number of genes of related function. Both hSTI1 and mSTI1 comprised 14 putative exons, while ySTI1 was encoded on a single exon. Human and mouse STI1 shared a perfectly conserved 55 bp region spanning their predicted TSS, although their TATA boxes were not conserved. A putative CpG island was identified in the region from -500 to +100 bp relative to the hSTI1 and mSTI1 TSS. This region overlapped with a region of high TFBS density, suggesting that the core promoter region was located in the region approximately 100 to 200 bp upstream of the TSS. Several conserved clusters of TFBS were also identified upstream of this promoter region, including binding sites for stimulatory protein 1 (Sp1), heat shock factor (HSF), nuclear factor kappa B (NF-kappaB), and the cAMP/enhancer binding protein (C/EBP). Microarray data suggested that ySTI1 was co-regulated with several heat shock proteins and substrates of the Hsp70/Hsp90 heterocomplex, and several putative regulatory elements were identified in the upstream region of these co-regulated genes, including a motif for HSF binding. The results of this research suggest several avenues of future experimental work, including the confirmation of the proposed core promoter, upstream regulatory elements, and CpG island, and the investigation into the co-regulation of mammalian STI1 with its surrounding genes. These results could also be used to inform STI1 gene knockout experiments in mice, to assess the biological importance of mammalian STI1.
- Full Text:
- Date Issued: 2005
- Authors: Aken, Bronwen Louise
- Date: 2005
- Subjects: Molecular chaperones , Proteins -- Analysis , Heat shock proteins , Bioinformatics , Genetics -- Data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3990 , http://hdl.handle.net/10962/d1004049 , Molecular chaperones , Proteins -- Analysis , Heat shock proteins , Bioinformatics , Genetics -- Data processing
- Description: Stress-inducible protein 1 (Sti1) is a 60 kDa eukaryotic protein that is important under stress and non-stress conditions. Human Sti1 is also known as the Hsp70/Hsp90 organising protein (Hop) that coordinates the functional cooperation of heat shock protein 70 (Hsp70) and heat shock protein 90 (Hsp90) during the folding of various transcription factors and kinases, including certain oncogenic proteins and prion proteins. Limited studies have been conducted on the STI1 gene structure. Thus, the aim of this study was to develop a comprehensive description of human STI1 (hSTI1), mouse STI1 (mSTI1), and yeast STI1 (ySTI1) genes, using a bioinformatic approach. Genes encoded near the STI1 loci were identified for the three organisms using National Centre for Biotechnology Information (NCBI) MapViewer and the Saccharomyces Genome Database. Exon/intron boundaries were predicted using Hidden Markov model gene prediction software (HMMGene) and Genscan, and by alignment of the mRNA sequence with the genomic DNA sequence. Transcription factor binding sites (TFBS) were predicted by scanning the region 1000 base pairs (bp) upstream of the STI1 orthologues’ transcription start site (TSS) with Alibaba, Transcription element search software (TESS) and Transcription factor search (TFSearch). The promoter region was defined by comparing the number, type and position of TFBS across the orthologous STI1 genes. Additional putative TFBS were identified for ySTI1 by searching with software that aligns nucleic acid conserved elements (AlignACE) for over-represented motifs in the region upstream of the TSS of genes thought to be co-regulated with ySTI1. This study showed that hSTI1 and mSTI1 occur in a region of synteny with a number of genes of related function. Both hSTI1 and mSTI1 comprised 14 putative exons, while ySTI1 was encoded on a single exon. Human and mouse STI1 shared a perfectly conserved 55 bp region spanning their predicted TSS, although their TATA boxes were not conserved. A putative CpG island was identified in the region from -500 to +100 bp relative to the hSTI1 and mSTI1 TSS. This region overlapped with a region of high TFBS density, suggesting that the core promoter region was located in the region approximately 100 to 200 bp upstream of the TSS. Several conserved clusters of TFBS were also identified upstream of this promoter region, including binding sites for stimulatory protein 1 (Sp1), heat shock factor (HSF), nuclear factor kappa B (NF-kappaB), and the cAMP/enhancer binding protein (C/EBP). Microarray data suggested that ySTI1 was co-regulated with several heat shock proteins and substrates of the Hsp70/Hsp90 heterocomplex, and several putative regulatory elements were identified in the upstream region of these co-regulated genes, including a motif for HSF binding. The results of this research suggest several avenues of future experimental work, including the confirmation of the proposed core promoter, upstream regulatory elements, and CpG island, and the investigation into the co-regulation of mammalian STI1 with its surrounding genes. These results could also be used to inform STI1 gene knockout experiments in mice, to assess the biological importance of mammalian STI1.
- Full Text:
- Date Issued: 2005
Synthesis, photochemical and photophysical properties of phthalocyanine derivatives
- Authors: Maqanda, Weziwe Theorine
- Date: 2005 , 2013-06-18
- Subjects: Photochemotherapy , Phthalocyanines , Zinc , Magnesium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4436 , http://hdl.handle.net/10962/d1007472 , Photochemotherapy , Phthalocyanines , Zinc , Magnesium
- Description: Substituted zinc and magnesium phthalocyanine and porphyrazine derivatives were synthesized according to the reported procedures. The magnesium and zinc phthalocyanine and porphyrazine derivatives were synthesized by ring enlargement of subphthalocyanine and statistical condensation of the two phthalonitrile derivatives. Characterization of the complexes involved the use of infrared spectroscopy, nuclear magnetic resonance spectroscopy, ultraviolet and visible spectroscopy, and Maldi-TOF spectroscopy (for selected compounds) and elemental analysis. Photochemical and photophysical properties of the complexes in non-aqueous solution was then investigated. Photobleaching quantum yields are in order of 10⁻⁵ indicating their relative photostability. Complexes containing more electron-donating substituents were more easily oxidized. For complexes 66 and 69 (as these complexes have the same number of substituents but differ in the metal center) photobleaching quantum yield for the ZincPc complex 69 was slightly less than that of the MgPc complex 66. Singlet oxygen quantum yields of the various complexes in DMSO using diphenylisobenzofuran (DPBF) as a quencher in organic solvents were determined. Singlet oxygen quantum yields of the complexes range from 0.23 to 0.67. High values of Φ[subscript]Δ ZnPc complexes was observed compared to the corresponding MgPc, complexes. This was evidenced by complexes 66 and 69 with Φ[subscript]Δ values of Φ[subscript]Δ = 0.26 and 0.40, respectively. Varying number of phenoxy substituents, complex 71 gave significantly large value of Φ[subscript]Δ compared to 70 (that is, the presence of more electron-donating substituted group, gave higher singlet oxygen quantum yields (0 .67 and 0.25 for 71 and 70 repectively). The triplet quantum yields and triplet lifetimes were determined by laser flash photolysis for selected compounds. The triplet quantum yields increase as the number of substituents increases e.g 68 > 67 > 66. Comparing porphyrazine complexes (63, 64 and 65), 63 with benzene attached to the ring, has higher triplet state lifetime (420 μs) compared to 64 and 65 containing long alkyl chain and tertbutyl substituents, 350 and 360 μs,respectively). The observed Φ[subscript]f values for 68 and 63 were quiet suprising, since low values are observed compared to the rest of the complexes (e.g 0.03 and 0.02 respectively). Although these values seem so low, they are sufficient for fluorescence imaging applications. The Φ[subscript]f values for the complexes under study are within the range reported for complexes currently used for PDT. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2005
- Authors: Maqanda, Weziwe Theorine
- Date: 2005 , 2013-06-18
- Subjects: Photochemotherapy , Phthalocyanines , Zinc , Magnesium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4436 , http://hdl.handle.net/10962/d1007472 , Photochemotherapy , Phthalocyanines , Zinc , Magnesium
- Description: Substituted zinc and magnesium phthalocyanine and porphyrazine derivatives were synthesized according to the reported procedures. The magnesium and zinc phthalocyanine and porphyrazine derivatives were synthesized by ring enlargement of subphthalocyanine and statistical condensation of the two phthalonitrile derivatives. Characterization of the complexes involved the use of infrared spectroscopy, nuclear magnetic resonance spectroscopy, ultraviolet and visible spectroscopy, and Maldi-TOF spectroscopy (for selected compounds) and elemental analysis. Photochemical and photophysical properties of the complexes in non-aqueous solution was then investigated. Photobleaching quantum yields are in order of 10⁻⁵ indicating their relative photostability. Complexes containing more electron-donating substituents were more easily oxidized. For complexes 66 and 69 (as these complexes have the same number of substituents but differ in the metal center) photobleaching quantum yield for the ZincPc complex 69 was slightly less than that of the MgPc complex 66. Singlet oxygen quantum yields of the various complexes in DMSO using diphenylisobenzofuran (DPBF) as a quencher in organic solvents were determined. Singlet oxygen quantum yields of the complexes range from 0.23 to 0.67. High values of Φ[subscript]Δ ZnPc complexes was observed compared to the corresponding MgPc, complexes. This was evidenced by complexes 66 and 69 with Φ[subscript]Δ values of Φ[subscript]Δ = 0.26 and 0.40, respectively. Varying number of phenoxy substituents, complex 71 gave significantly large value of Φ[subscript]Δ compared to 70 (that is, the presence of more electron-donating substituted group, gave higher singlet oxygen quantum yields (0 .67 and 0.25 for 71 and 70 repectively). The triplet quantum yields and triplet lifetimes were determined by laser flash photolysis for selected compounds. The triplet quantum yields increase as the number of substituents increases e.g 68 > 67 > 66. Comparing porphyrazine complexes (63, 64 and 65), 63 with benzene attached to the ring, has higher triplet state lifetime (420 μs) compared to 64 and 65 containing long alkyl chain and tertbutyl substituents, 350 and 360 μs,respectively). The observed Φ[subscript]f values for 68 and 63 were quiet suprising, since low values are observed compared to the rest of the complexes (e.g 0.03 and 0.02 respectively). Although these values seem so low, they are sufficient for fluorescence imaging applications. The Φ[subscript]f values for the complexes under study are within the range reported for complexes currently used for PDT. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2005