Microfinance sustainability versus development objectives: an assessment of the South African environment
- Authors: Hoskinson, Brenda
- Date: 2008
- Subjects: Microfinance -- South Africa South Africa -- Economic conditions -- 1991- Poor -- Finance, Personal Microfinance -- South Africa Case studies
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2782 , http://hdl.handle.net/10962/d1002992
- Description: In a world where almost half of the population lives in poverty, the alleviation of poverty is a serious developmental challenge for many states. Microfinance has grown in popularity as a means for achieving poverty reduction all over the world. Due to the success of microfinance institutions, such as the Grameen Bank, in achieving self-sufficiency and improving the lives of its clients, the expectations for similar institutions are high. MFIs attempt to find a balance between business and development goals. It is not necessarily a contradiction to be a business seeking profit as well as being an institution committed to development. However, the values coupled with these two objectives are sometimes conflicting. Thus it is important to see how equilibrium can be achieved and to note what sacrifices must be made in order to reach a balance. This thesis will focus on examining and assessing the challenges faced by South African MFIs in balancing development goals while at the same time having to be self-sufficient. The Small Enterprise Foundation will be used as a case study to consider the particular experiences of a South African MFI. The evaluation of the unique challenges that the South African landscape presents will provide a context in which to understand microfinance operations and a clearer understanding of the particular problems and challenges faced by the South African micro-finance industry in balancing the achievement of development goals against the imperative to be self sustainable in providing services to the poor. Through that understanding the common conception of what makes a “successful” MFI will also be challenged.
- Full Text:
- Authors: Hoskinson, Brenda
- Date: 2008
- Subjects: Microfinance -- South Africa South Africa -- Economic conditions -- 1991- Poor -- Finance, Personal Microfinance -- South Africa Case studies
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2782 , http://hdl.handle.net/10962/d1002992
- Description: In a world where almost half of the population lives in poverty, the alleviation of poverty is a serious developmental challenge for many states. Microfinance has grown in popularity as a means for achieving poverty reduction all over the world. Due to the success of microfinance institutions, such as the Grameen Bank, in achieving self-sufficiency and improving the lives of its clients, the expectations for similar institutions are high. MFIs attempt to find a balance between business and development goals. It is not necessarily a contradiction to be a business seeking profit as well as being an institution committed to development. However, the values coupled with these two objectives are sometimes conflicting. Thus it is important to see how equilibrium can be achieved and to note what sacrifices must be made in order to reach a balance. This thesis will focus on examining and assessing the challenges faced by South African MFIs in balancing development goals while at the same time having to be self-sufficient. The Small Enterprise Foundation will be used as a case study to consider the particular experiences of a South African MFI. The evaluation of the unique challenges that the South African landscape presents will provide a context in which to understand microfinance operations and a clearer understanding of the particular problems and challenges faced by the South African micro-finance industry in balancing the achievement of development goals against the imperative to be self sustainable in providing services to the poor. Through that understanding the common conception of what makes a “successful” MFI will also be challenged.
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Namibian school principals' perceptions of their management needs
- Authors: Kapapero, Fanuel
- Date: 2008
- Subjects: School principals -- Self-rating of -- Namibia School principals -- Rating of -- Namibia School principals -- Management -- Namibia School principals -- Development -- Namibia School management and organization -- Namibia Educational leadership -- Namibia School supervision -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1674 , http://hdl.handle.net/10962/d1003557
- Description: The Namibian education system is at the crossroads as a result of the demands of the Education and Training Sector Improvement Programme (ETSIP), a programme initiated by the Government to address shortcomings in the education and training sector. ETSIP requires that school principals play a much more significant role to realize the goal of quality education, which is one of the major goals of education reform. In view of the ever-increasing responsibilities of the principals for ensuring the quality of education, the need for management development has become more apparent. Although management development for principals in the African context is a recent phenomenon, it has been a subject of extensive research over the years in many developed countries. The findings of these studies suggest that it has the potential to improve the quality of school leadership and ultimately lead to school improvement. In Namibia, literature suggests that little has been done to determine the needs of school principals with regards to their management development. This study therefore seeks to address that need. The study is situated in the interpretive research paradigm whose central purpose is to interpret and understand the phenomenon through the perceptions and experience of the participants. Data were collected by means of semi-structured interviews and document analysis. The findings generally suggest that principals perceive management development as vehicle to empowerment and capacity building. The findings further suggest that principals would prefer management programmes that are more experienced-based and offer opportunities for reflection. The findings also brought to light the aspect of monitoring and support as a critical element in the success of management development programmes. As far as the management development needs of school principals are concerned, the findings highlighted the following needs: the need to be trained on how to manage change which include the new curriculum and policies, training in information communication and technology and training in the management of human and financial resources which include instructional leadership and budgeting.
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- Authors: Kapapero, Fanuel
- Date: 2008
- Subjects: School principals -- Self-rating of -- Namibia School principals -- Rating of -- Namibia School principals -- Management -- Namibia School principals -- Development -- Namibia School management and organization -- Namibia Educational leadership -- Namibia School supervision -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1674 , http://hdl.handle.net/10962/d1003557
- Description: The Namibian education system is at the crossroads as a result of the demands of the Education and Training Sector Improvement Programme (ETSIP), a programme initiated by the Government to address shortcomings in the education and training sector. ETSIP requires that school principals play a much more significant role to realize the goal of quality education, which is one of the major goals of education reform. In view of the ever-increasing responsibilities of the principals for ensuring the quality of education, the need for management development has become more apparent. Although management development for principals in the African context is a recent phenomenon, it has been a subject of extensive research over the years in many developed countries. The findings of these studies suggest that it has the potential to improve the quality of school leadership and ultimately lead to school improvement. In Namibia, literature suggests that little has been done to determine the needs of school principals with regards to their management development. This study therefore seeks to address that need. The study is situated in the interpretive research paradigm whose central purpose is to interpret and understand the phenomenon through the perceptions and experience of the participants. Data were collected by means of semi-structured interviews and document analysis. The findings generally suggest that principals perceive management development as vehicle to empowerment and capacity building. The findings further suggest that principals would prefer management programmes that are more experienced-based and offer opportunities for reflection. The findings also brought to light the aspect of monitoring and support as a critical element in the success of management development programmes. As far as the management development needs of school principals are concerned, the findings highlighted the following needs: the need to be trained on how to manage change which include the new curriculum and policies, training in information communication and technology and training in the management of human and financial resources which include instructional leadership and budgeting.
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Natural resource harvesting and disturbance in communal lands: assessing the roles of local ecological knowledge, dependency and market access
- Authors: Steele, Melita Zoë
- Date: 2008
- Subjects: Non-timber forest products -- South Africa , Natural resources -- South Africa , Rural poor -- South Africa , Rural development -- South Africa , Forests and forestry -- South Africa , Households -- Economic aspects -- South Africa , Natural resources, Communal -- South Africa , Commons -- South Africa , Forest ecology -- South Africa , Harvesting
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4736 , http://hdl.handle.net/10962/d1004604 , Non-timber forest products -- South Africa , Natural resources -- South Africa , Rural poor -- South Africa , Rural development -- South Africa , Forests and forestry -- South Africa , Households -- Economic aspects -- South Africa , Natural resources, Communal -- South Africa , Commons -- South Africa , Forest ecology -- South Africa , Harvesting
- Description: A great deal of research has demonstrated that Non-Timber Forest Products (NTFPs) play a crucial role in the livelihoods of the rural poor, and are particularly important to the most marginalised people throughout the developing world. However, these livelihood benefits are not without cost to the natural resource base that rural communities depend so heavily upon. The continued dependence on NTFPs as a major livelihood source must be contingent upon the minimisation of the level of disturbance created through this dependency. This study assesses the level of disturbance created through natural resource harvesting in eight study sites around South Africa, and applies a predictive conceptual model created by Shankaar et al. (2004b) to try and ascertain under what conditions the level of disturbance created through natural resource harvesting will be high. It assesses the three key factors that Shankaar et al. (2004b) identified (level of Local Ecological Knowledge (LEK), level of dependency and access to markets) in relation to the level of disturbance found at each of the study sites. It was found that there was a statistically significant relationship between the level of dependency and the level of disturbance, but there was no statistically significant relationship between either access to markets or the level of LEK and disturbance. Regulation of land use is a key issue, with weak local institutions in communal areas making effective resource management difficult. The significance of these findings is discussed, and priorities for future research are identified. This study adds to the body of knowledge related to NTFP harvesting and critically analyses the conflicts between the livelihood gains and the level of disturbance created through NTFP harvesting in an attempt to ascertain how livelihoods can be safeguarded. And in the longer-term, so that management strategies can be identified where resource extraction is not at the cost of undermining the very livelihoods that depend upon the natural resource base.
- Full Text:
- Authors: Steele, Melita Zoë
- Date: 2008
- Subjects: Non-timber forest products -- South Africa , Natural resources -- South Africa , Rural poor -- South Africa , Rural development -- South Africa , Forests and forestry -- South Africa , Households -- Economic aspects -- South Africa , Natural resources, Communal -- South Africa , Commons -- South Africa , Forest ecology -- South Africa , Harvesting
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4736 , http://hdl.handle.net/10962/d1004604 , Non-timber forest products -- South Africa , Natural resources -- South Africa , Rural poor -- South Africa , Rural development -- South Africa , Forests and forestry -- South Africa , Households -- Economic aspects -- South Africa , Natural resources, Communal -- South Africa , Commons -- South Africa , Forest ecology -- South Africa , Harvesting
- Description: A great deal of research has demonstrated that Non-Timber Forest Products (NTFPs) play a crucial role in the livelihoods of the rural poor, and are particularly important to the most marginalised people throughout the developing world. However, these livelihood benefits are not without cost to the natural resource base that rural communities depend so heavily upon. The continued dependence on NTFPs as a major livelihood source must be contingent upon the minimisation of the level of disturbance created through this dependency. This study assesses the level of disturbance created through natural resource harvesting in eight study sites around South Africa, and applies a predictive conceptual model created by Shankaar et al. (2004b) to try and ascertain under what conditions the level of disturbance created through natural resource harvesting will be high. It assesses the three key factors that Shankaar et al. (2004b) identified (level of Local Ecological Knowledge (LEK), level of dependency and access to markets) in relation to the level of disturbance found at each of the study sites. It was found that there was a statistically significant relationship between the level of dependency and the level of disturbance, but there was no statistically significant relationship between either access to markets or the level of LEK and disturbance. Regulation of land use is a key issue, with weak local institutions in communal areas making effective resource management difficult. The significance of these findings is discussed, and priorities for future research are identified. This study adds to the body of knowledge related to NTFP harvesting and critically analyses the conflicts between the livelihood gains and the level of disturbance created through NTFP harvesting in an attempt to ascertain how livelihoods can be safeguarded. And in the longer-term, so that management strategies can be identified where resource extraction is not at the cost of undermining the very livelihoods that depend upon the natural resource base.
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Network-layer reservation TDM for ad-hoc 802.11 networks
- Authors: Duff, Kevin Craig
- Date: 2008
- Subjects: Computer networks -- Access control , Computers -- Access control , Computer networks -- Management , Time division multiple access , Ad hoc networks (Computer networks)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4574 , http://hdl.handle.net/10962/d1002773 , Computer networks -- Access control , Computers -- Access control , Computer networks -- Management , Time division multiple access , Ad hoc networks (Computer networks)
- Description: Ad-Hoc mesh networks offer great promise. Low-cost ad-hoc mesh networks can be built using popular IEEE 802.11 equipment, but such networks are unable to guarantee each node a fair share of bandwidth. Furthermore, hidden node problems cause collisions which can cripple the throughput of a network. This research proposes a novel mechanism which is able to overcome hidden node problems and provide fair bandwidth sharing among nodes on ad-hoc 802.11 networks, and can be implemented on existing network devices. The scheme uses TDM (time division multiplexing) with slot reservation. A distributed beacon packet latency measurement mechanism is used to achieve node synchronisation. The distributed nature of the mechanism makes it applicable to ad-hoc 802.11 networks, which can either grow or fragment dynamically.
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- Authors: Duff, Kevin Craig
- Date: 2008
- Subjects: Computer networks -- Access control , Computers -- Access control , Computer networks -- Management , Time division multiple access , Ad hoc networks (Computer networks)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4574 , http://hdl.handle.net/10962/d1002773 , Computer networks -- Access control , Computers -- Access control , Computer networks -- Management , Time division multiple access , Ad hoc networks (Computer networks)
- Description: Ad-Hoc mesh networks offer great promise. Low-cost ad-hoc mesh networks can be built using popular IEEE 802.11 equipment, but such networks are unable to guarantee each node a fair share of bandwidth. Furthermore, hidden node problems cause collisions which can cripple the throughput of a network. This research proposes a novel mechanism which is able to overcome hidden node problems and provide fair bandwidth sharing among nodes on ad-hoc 802.11 networks, and can be implemented on existing network devices. The scheme uses TDM (time division multiplexing) with slot reservation. A distributed beacon packet latency measurement mechanism is used to achieve node synchronisation. The distributed nature of the mechanism makes it applicable to ad-hoc 802.11 networks, which can either grow or fragment dynamically.
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Neuroprotective mechanisms of nevirapine and efavirenz in a model of neurodegeneration
- Authors: Zheve, Georgina Teurai
- Date: 2008
- Subjects: HIV infections -- Treatment AIDS (Disease) -- Treatment AIDS dementia complex -- Treatment Nervous system -- Degeneration -- Treatment Melatonin Neurotoxic agents Quinolinic acid
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: vital:3807 , http://hdl.handle.net/10962/d1003285
- Description: AIDS Dementia Complex (ADC) is a neurodegenerative disorder implicated in HIV-1 infection that is associated with elevated levels of the neurotoxin, quinolinic acid (QA) which causes a cascade of events to occur, leading to the production of reactive oxygen species (ROS), these being ultimately responsible for oxidative neurotoxicity. In clinical studies, Non-nucleoside reverse transcriptase inhibitors (NNRTIs), efavirenz (EFV) and nevirapine (NVP) have been shown to potentially delay the progressive degeneration of neurons, thus reducing the frequency and neurological deficits associated with ADC. Despite these neuroprotective implications, there is still no biochemical data to demonstrate the mechanisms through which these agents offer neuroprotection. The present study aims to elucidate and further characterize the possible antioxidant and neuroprotective mechanisms of NVP and EFV in vitro and in vivo, using QA-induced neurotoxicity as a model. Research has demonstrated that antioxidants and metal chelators have the ability to offer neuroprotection against free radical induced injury and may be beneficial in the prevention or treatment of neurodegeneration. Hence the antioxidant and metal binding properties of these agents were investigated respectively. Inorganic studies, including the 1, 1-diphenyl-2 picrylhydrazyl (DPPH) assay, show that these agents readily scavenge free radicals in vitro, thus postulating the antioxidant property of these agents. The enhancement of superoxide radical generation and iron mediated Fenton reaction by QA is related to lipid peroxidation in biological systems, the extent of which was assayed using the nitroblue tetrazolium and thiobarbituric acid method respectively. Both agents significantly curtail QA-induced lipid peroxidation and potentially scavenge superoxide anions generated by cyanide in vitro. Furthermore, in vivo results demonstrate the ability of NVP and EFV to protect hippocampal neurons against lipid peroxidation induced by QA and superoxide radicals generated as a consequence thereof. The alleviation of QA-induced oxidative stress in vitro possibly occurs through the binding of iron (II) and / or iron (III), and this argument is further strengthened by the ability of EFV and not NVP to reduce iron (II)-induced lipid peroxidation in vitro directly. In addition the ferrozine and electrochemistry assay were used to measure the extent of iron (II) Fe[superscript 2+] and iron (III) Fe[superscript 3+] chelation activity. Both assays demonstrate that these agents bind iron (II) and iron (III), and prevent redox recycling of iron and subsequent complexation of Fe[superscript 2+] with QA which enhances neuronal damage. Both NNRTIs inhibit the endogenous biosynthesis of QA by inhibiting liver tryptophan 2, 3-dioxygenase activity in vivo and subsequently increasing hippocampal serotonin levels. Furthermore, these agents reduce the turnover of hippocampal serotonin to 5-hydroxyindole acetic acid. NVP and not EFV increase 5-hydroxyindole acetic acid and norepinephrine levels in the hippocampus. The results of the pineal indole metabolism study show that NVP increases the synthesis of melatonin, but decreases N-acetylserotonin, 5-hydroxyindole acetic acid and 5-hydroxytryptophol levels. Furthermore, it shows that EFV decreases 5-hydroxyindole acetic acid and melatonin synthesis. Behavioural studies using a Morris water maze show that the post-treatment of rats with NVP and EFV significantly improves QA-induced spatial memory deficits in the hippocampus. This study therefore provides novel information regarding the neuroprotective mechanisms of NVP and EFV. These findings strengthen the argument that these NNRTIs not only have antiviral effects but possess potential neuroprotective properties, which may contribute to the effectiveness of these drugs in the treatment of ADC.
- Full Text:
- Authors: Zheve, Georgina Teurai
- Date: 2008
- Subjects: HIV infections -- Treatment AIDS (Disease) -- Treatment AIDS dementia complex -- Treatment Nervous system -- Degeneration -- Treatment Melatonin Neurotoxic agents Quinolinic acid
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: vital:3807 , http://hdl.handle.net/10962/d1003285
- Description: AIDS Dementia Complex (ADC) is a neurodegenerative disorder implicated in HIV-1 infection that is associated with elevated levels of the neurotoxin, quinolinic acid (QA) which causes a cascade of events to occur, leading to the production of reactive oxygen species (ROS), these being ultimately responsible for oxidative neurotoxicity. In clinical studies, Non-nucleoside reverse transcriptase inhibitors (NNRTIs), efavirenz (EFV) and nevirapine (NVP) have been shown to potentially delay the progressive degeneration of neurons, thus reducing the frequency and neurological deficits associated with ADC. Despite these neuroprotective implications, there is still no biochemical data to demonstrate the mechanisms through which these agents offer neuroprotection. The present study aims to elucidate and further characterize the possible antioxidant and neuroprotective mechanisms of NVP and EFV in vitro and in vivo, using QA-induced neurotoxicity as a model. Research has demonstrated that antioxidants and metal chelators have the ability to offer neuroprotection against free radical induced injury and may be beneficial in the prevention or treatment of neurodegeneration. Hence the antioxidant and metal binding properties of these agents were investigated respectively. Inorganic studies, including the 1, 1-diphenyl-2 picrylhydrazyl (DPPH) assay, show that these agents readily scavenge free radicals in vitro, thus postulating the antioxidant property of these agents. The enhancement of superoxide radical generation and iron mediated Fenton reaction by QA is related to lipid peroxidation in biological systems, the extent of which was assayed using the nitroblue tetrazolium and thiobarbituric acid method respectively. Both agents significantly curtail QA-induced lipid peroxidation and potentially scavenge superoxide anions generated by cyanide in vitro. Furthermore, in vivo results demonstrate the ability of NVP and EFV to protect hippocampal neurons against lipid peroxidation induced by QA and superoxide radicals generated as a consequence thereof. The alleviation of QA-induced oxidative stress in vitro possibly occurs through the binding of iron (II) and / or iron (III), and this argument is further strengthened by the ability of EFV and not NVP to reduce iron (II)-induced lipid peroxidation in vitro directly. In addition the ferrozine and electrochemistry assay were used to measure the extent of iron (II) Fe[superscript 2+] and iron (III) Fe[superscript 3+] chelation activity. Both assays demonstrate that these agents bind iron (II) and iron (III), and prevent redox recycling of iron and subsequent complexation of Fe[superscript 2+] with QA which enhances neuronal damage. Both NNRTIs inhibit the endogenous biosynthesis of QA by inhibiting liver tryptophan 2, 3-dioxygenase activity in vivo and subsequently increasing hippocampal serotonin levels. Furthermore, these agents reduce the turnover of hippocampal serotonin to 5-hydroxyindole acetic acid. NVP and not EFV increase 5-hydroxyindole acetic acid and norepinephrine levels in the hippocampus. The results of the pineal indole metabolism study show that NVP increases the synthesis of melatonin, but decreases N-acetylserotonin, 5-hydroxyindole acetic acid and 5-hydroxytryptophol levels. Furthermore, it shows that EFV decreases 5-hydroxyindole acetic acid and melatonin synthesis. Behavioural studies using a Morris water maze show that the post-treatment of rats with NVP and EFV significantly improves QA-induced spatial memory deficits in the hippocampus. This study therefore provides novel information regarding the neuroprotective mechanisms of NVP and EFV. These findings strengthen the argument that these NNRTIs not only have antiviral effects but possess potential neuroprotective properties, which may contribute to the effectiveness of these drugs in the treatment of ADC.
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Newsroom convergence at the Mail & Guardian: a case study
- Authors: Van Noort, Elvira Esmeralda
- Date: 2008
- Subjects: Mail & Guardian Convergence (Telecommunication) Journalism -- Management -- South Africa Mass media -- Management -- South Africa Journalism -- Technological innovations -- South Africa Online journalism -- South Africa Broadcast journalism -- South Africa Mass media -- Ownership Digital media -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3490 , http://hdl.handle.net/10962/d1002945
- Description: This case study researches newsroom convergence as a process at the Mail & Guardian newspaper and their online edition the Mail & Guardian Online. It focuses on the reporters’ and editors’ attitudes towards newsroom convergence and on cultural resistance against change; one of the major challenges in the process. With structured interviews, observations and questionnaires it was analysed that communication problems between the newsrooms, different production cycles and time management issues are other prominent difficulties. The case study furthermore provides a snapshot of the convergence phenomenon as a process in a particular South African news organisation. The outcomes could not only assist other news companies with convergence plans but also be used as a pilot study for further research on converged newsrooms in South Africa.
- Full Text:
- Authors: Van Noort, Elvira Esmeralda
- Date: 2008
- Subjects: Mail & Guardian Convergence (Telecommunication) Journalism -- Management -- South Africa Mass media -- Management -- South Africa Journalism -- Technological innovations -- South Africa Online journalism -- South Africa Broadcast journalism -- South Africa Mass media -- Ownership Digital media -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3490 , http://hdl.handle.net/10962/d1002945
- Description: This case study researches newsroom convergence as a process at the Mail & Guardian newspaper and their online edition the Mail & Guardian Online. It focuses on the reporters’ and editors’ attitudes towards newsroom convergence and on cultural resistance against change; one of the major challenges in the process. With structured interviews, observations and questionnaires it was analysed that communication problems between the newsrooms, different production cycles and time management issues are other prominent difficulties. The case study furthermore provides a snapshot of the convergence phenomenon as a process in a particular South African news organisation. The outcomes could not only assist other news companies with convergence plans but also be used as a pilot study for further research on converged newsrooms in South Africa.
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No other world: the poetry of Don Maclennan
- Authors: Robinson, Brendon Kimbale
- Date: 2008
- Subjects: Maclennan, Don Maclennan, Don -- Criticism and interpretation South African poetry (English) -- History and criticism
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2221 , http://hdl.handle.net/10962/d1002264
- Description: This is a study of the poetry of Don Maclennan in four chapters. Chapter One explores the poetry's deep involvement with the immediate world, and with the being that encounters it. Chapter Two examines the corpus's mistrust of abstract thought, and its suggestions for alternative ways of intepreting (or at least approaching an interpretation of) our existential situation. Chapter Three deals with Maclennan's writing on the subject of death, while the final chapter looks at the response of the poetry to the fact of death: put simply, this is to learn to love the situation we are in, and to record our thoughts for future generations, thus reaching beyond death to share with others the necessarily unique experience of our one and only life.
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- Authors: Robinson, Brendon Kimbale
- Date: 2008
- Subjects: Maclennan, Don Maclennan, Don -- Criticism and interpretation South African poetry (English) -- History and criticism
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2221 , http://hdl.handle.net/10962/d1002264
- Description: This is a study of the poetry of Don Maclennan in four chapters. Chapter One explores the poetry's deep involvement with the immediate world, and with the being that encounters it. Chapter Two examines the corpus's mistrust of abstract thought, and its suggestions for alternative ways of intepreting (or at least approaching an interpretation of) our existential situation. Chapter Three deals with Maclennan's writing on the subject of death, while the final chapter looks at the response of the poetry to the fact of death: put simply, this is to learn to love the situation we are in, and to record our thoughts for future generations, thus reaching beyond death to share with others the necessarily unique experience of our one and only life.
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Normative indications for Xhosa-speaking unskilled workers on the trail making test and the stroop test
- Authors: Andrews, Karen Anne Hope
- Date: 2008
- Subjects: Neuropsychology , Neuropsychological tests -- Sex differences , Educational tests and measurements -- Sex differences , Xhosa (African people) -- Education
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:2926 , http://hdl.handle.net/10962/d1002435 , Neuropsychology , Neuropsychological tests -- Sex differences , Educational tests and measurements -- Sex differences , Xhosa (African people) -- Education
- Description: The aim of the study was to produce preliminary normative indications for the Trail Making Test and the Stroop Test, administered in English, on a non-clinical sample of black, Xhosa-speaking, unskilled individuals (N = 33), with an educational level of 11 – 12 years, in two age categories (18 –29 and 30 – 40 years). The sample was equally distributed for gender and level of education. Participants, who were required to have a basic proficiency in English, were from traditionally black township schools with relatively disadvantaged quality of education. Within-sample age and gender effects were investigated. There were no significant age effects on the Trail Making Test, whereas there was one significant difference between age groups on the Stroop Test with respect to the Color-Word task, and a result that strongly approached significance on the Word task, with the younger group performing better than the older group. There were no significant gender effects on the Trail Making Test, whereas there was one significant difference between genders on the Stroop Test with respect to the Word task, and a result that approached significance on the Color task, with females performing better than males. Normative indications for both measures were compared to available normative data on western populations with higher levels and more advantaged quality of education. This comparison revealed consistently poorer performances for both the Trail Making Test and the Stroop Test, confirming the need for localised normative datasets to facilitate accurate neuropsychological diagnoses on culturally disadvantaged individuals.
- Full Text:
- Authors: Andrews, Karen Anne Hope
- Date: 2008
- Subjects: Neuropsychology , Neuropsychological tests -- Sex differences , Educational tests and measurements -- Sex differences , Xhosa (African people) -- Education
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:2926 , http://hdl.handle.net/10962/d1002435 , Neuropsychology , Neuropsychological tests -- Sex differences , Educational tests and measurements -- Sex differences , Xhosa (African people) -- Education
- Description: The aim of the study was to produce preliminary normative indications for the Trail Making Test and the Stroop Test, administered in English, on a non-clinical sample of black, Xhosa-speaking, unskilled individuals (N = 33), with an educational level of 11 – 12 years, in two age categories (18 –29 and 30 – 40 years). The sample was equally distributed for gender and level of education. Participants, who were required to have a basic proficiency in English, were from traditionally black township schools with relatively disadvantaged quality of education. Within-sample age and gender effects were investigated. There were no significant age effects on the Trail Making Test, whereas there was one significant difference between age groups on the Stroop Test with respect to the Color-Word task, and a result that strongly approached significance on the Word task, with the younger group performing better than the older group. There were no significant gender effects on the Trail Making Test, whereas there was one significant difference between genders on the Stroop Test with respect to the Word task, and a result that approached significance on the Color task, with females performing better than males. Normative indications for both measures were compared to available normative data on western populations with higher levels and more advantaged quality of education. This comparison revealed consistently poorer performances for both the Trail Making Test and the Stroop Test, confirming the need for localised normative datasets to facilitate accurate neuropsychological diagnoses on culturally disadvantaged individuals.
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Optimisation of a sampling protocol for long-term monitoring of temperate reef fishes
- Authors: Bennett, Rhett Hamilton
- Date: 2008
- Subjects: Marine parks and reserves -- South Africa , Coastal zone management -- South Africa , Fishery management -- South Africa , Reef fishes -- South Africa , Fish communities -- South Africa , Fish stock assessment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5309 , http://hdl.handle.net/10962/d1005154 , Marine parks and reserves -- South Africa , Coastal zone management -- South Africa , Fishery management -- South Africa , Reef fishes -- South Africa , Fish communities -- South Africa , Fish stock assessment
- Description: Marine Protected Areas (MPAs), the Ecosystem Approach to Fisheries management (EAF) and Integrated Coastal Management (ICM) have been identified as possible alternatives to traditional linefish management measures, which have largely failed. Monitoring and assessment of fish communities on a long-term basis is necessary, and will provide a means to evaluate the effectiveness of such management measures. Therefore, standardised protocols and optimal sampling methods for long-term monitoring (LTM) and assessment of coastal fish communities are essential. This study aimed to identify suitable methods and develop a protocol for assessment of inshore reef fish communities. A suitable location for evaluation of proposed methods was identified in the warm temperate biogeographical region of South Africa, encompassing the well-established Tsitsikamma Coastal National Park MPA and an adjacent exploited area. Chrysoblephus laticeps (roman) was identified as an indicator species for the study, as it has been well-studied and is well represented in the area. Underwater visual census (UVC) and controlled fishing were identified as suitable methods. UVC transects were found to be superior to point counts, in terms of sampling efficiency, variability, bias and required sample size. An effort of two angler hours per fishing station was shown to provide low catch variability, while at the same time a representative catch and low overall cost and required time. The methods were incorporated in a proposed sampling protocol, and evaluated. The methods were able to detect known differences between protected and exploited communities. It is recommended that LTM within protected areas, for detection of natural change, be focused on community-level indicators, while LTM in exploited areas, aimed at detection of anthropogenic change, be focused on species-level indicators. The proposed protocol with standardised methods will allow for comparisons across a network of LTM sites and provide the opportunity for a broad-scale assessment of the effects of environmental variables on reef fish stocks. The protocol developed in this study has application in other biogeographical regions in South Africa, and other parts of the world. Shift in the focus of much marine research, in South Africa and elsewhere, to LTM, highlights the relevance and timeous nature of this study.
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- Authors: Bennett, Rhett Hamilton
- Date: 2008
- Subjects: Marine parks and reserves -- South Africa , Coastal zone management -- South Africa , Fishery management -- South Africa , Reef fishes -- South Africa , Fish communities -- South Africa , Fish stock assessment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5309 , http://hdl.handle.net/10962/d1005154 , Marine parks and reserves -- South Africa , Coastal zone management -- South Africa , Fishery management -- South Africa , Reef fishes -- South Africa , Fish communities -- South Africa , Fish stock assessment
- Description: Marine Protected Areas (MPAs), the Ecosystem Approach to Fisheries management (EAF) and Integrated Coastal Management (ICM) have been identified as possible alternatives to traditional linefish management measures, which have largely failed. Monitoring and assessment of fish communities on a long-term basis is necessary, and will provide a means to evaluate the effectiveness of such management measures. Therefore, standardised protocols and optimal sampling methods for long-term monitoring (LTM) and assessment of coastal fish communities are essential. This study aimed to identify suitable methods and develop a protocol for assessment of inshore reef fish communities. A suitable location for evaluation of proposed methods was identified in the warm temperate biogeographical region of South Africa, encompassing the well-established Tsitsikamma Coastal National Park MPA and an adjacent exploited area. Chrysoblephus laticeps (roman) was identified as an indicator species for the study, as it has been well-studied and is well represented in the area. Underwater visual census (UVC) and controlled fishing were identified as suitable methods. UVC transects were found to be superior to point counts, in terms of sampling efficiency, variability, bias and required sample size. An effort of two angler hours per fishing station was shown to provide low catch variability, while at the same time a representative catch and low overall cost and required time. The methods were incorporated in a proposed sampling protocol, and evaluated. The methods were able to detect known differences between protected and exploited communities. It is recommended that LTM within protected areas, for detection of natural change, be focused on community-level indicators, while LTM in exploited areas, aimed at detection of anthropogenic change, be focused on species-level indicators. The proposed protocol with standardised methods will allow for comparisons across a network of LTM sites and provide the opportunity for a broad-scale assessment of the effects of environmental variables on reef fish stocks. The protocol developed in this study has application in other biogeographical regions in South Africa, and other parts of the world. Shift in the focus of much marine research, in South Africa and elsewhere, to LTM, highlights the relevance and timeous nature of this study.
- Full Text:
Perceptions of the gap between theory and practice in the preparation of English language teachers at the Lesotho College of Education
- Authors: Molete, Bakae
- Date: 2008
- Subjects: Lesotho College of Education Education -- Research -- Lesotho Teachers -- Training of -- Lesotho Student teaching -- Lesotho English language -- Study and teaching -- Lesotho Observation (Educational method) English teachers -- Training of -- Lesotho
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1936 , http://hdl.handle.net/10962/d1007682
- Description: The distinction between theory and practice can be traced back to Aristotle (384-322 B.C). Theory has been seen as the preserve of the academician who, through research, produces knowledge for the practitioner to use in his/her practice. This research sets out to investigate perceptions of the respondents with regard to the extent to which theory is applicable in practice. It does this in the context of teacher training at the Lesotho College of Education, (LCE), a teacher training college in Lesotho. In this research project; a case study of 5 students from the LCE who had been on teaching practice, their mentor teachers on teaching practice, and a college lecturer who had observed said students on teaching practice was used. Data was collected by means of focus group interviews and semi-structured interviews. Relevant documents in the form of classroom observation forms were also used. The findings from the data analysis revealed that students on teaching practice had, to a great extent, had difficulties in applying what they had learned at the college when they got to teaching practice. Difficulties were mainly experienced in the areas of classroom and time management as well as in the application of the teaching methods learned at the college. This research takes a closer look at these difficulties. It investigates their probable causes and, finally, suggests ways of responding to them.
- Full Text:
- Authors: Molete, Bakae
- Date: 2008
- Subjects: Lesotho College of Education Education -- Research -- Lesotho Teachers -- Training of -- Lesotho Student teaching -- Lesotho English language -- Study and teaching -- Lesotho Observation (Educational method) English teachers -- Training of -- Lesotho
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1936 , http://hdl.handle.net/10962/d1007682
- Description: The distinction between theory and practice can be traced back to Aristotle (384-322 B.C). Theory has been seen as the preserve of the academician who, through research, produces knowledge for the practitioner to use in his/her practice. This research sets out to investigate perceptions of the respondents with regard to the extent to which theory is applicable in practice. It does this in the context of teacher training at the Lesotho College of Education, (LCE), a teacher training college in Lesotho. In this research project; a case study of 5 students from the LCE who had been on teaching practice, their mentor teachers on teaching practice, and a college lecturer who had observed said students on teaching practice was used. Data was collected by means of focus group interviews and semi-structured interviews. Relevant documents in the form of classroom observation forms were also used. The findings from the data analysis revealed that students on teaching practice had, to a great extent, had difficulties in applying what they had learned at the college when they got to teaching practice. Difficulties were mainly experienced in the areas of classroom and time management as well as in the application of the teaching methods learned at the college. This research takes a closer look at these difficulties. It investigates their probable causes and, finally, suggests ways of responding to them.
- Full Text:
Performance of Mhande song-dance: a contextualized and comparative analysis
- Authors: Rutsate, Jerry
- Date: 2008
- Subjects: Karanga (African people) -- Music Shona (African people) -- Music Folk music -- Zimbabwe Music -- Zimbabwe Folk songs, Shona Mhande Dance music -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2655 , http://hdl.handle.net/10962/d1002321
- Description: This thesis is an investigation of the significance of Mhande song-dance in two performance contexts: the Mutoro ritual of the Karanga and the Chibuku Neshamwari Traditional Dance Competition. In addition, I undertake comparative analysis of the structure of Mhande music in relation to the structure of selected genres of Shona indigenous music. The position of Mhande in the larger context of Shona music is determined through analysis of transcriptions of the rhythmic, melodic and harmonic elements of chizambi mouth bow, karimba mbira, ngororombe panpipes, ngano story songs, game, hunting, war, and love songs. Mhande is an indigenous song-dance performed for the mutoro ceremony, the annual rain ritual of the Karanga. The Mhande repertoire consists of distinctive songs and rhythms used for communicating with the majukwa rain spirits. The rain spirits in turn communicate with God (Mwari) the provider of rain, on behalf of the Karanga. Mhande song-dance is performed exactly the same way in the annual Chibuku Neshamwari Traditional Dance Competitions as in the ritual context of the mutoro ceremony. However, in the context of the Competition, it is used for the expression of joy and as a form of cultural identity. The Competition is a forum in which Karanga songdance traditions such as Mhande, compete with other Shona song-dance traditions such as mbakumba, shangara and chinyambera. I contextualize and analyse Mhande song-dance by using the ‘Matonjeni Model’, which in terms of Karanga epistemology, is culture specific. This Model is grounded in description, interpretation and analysis; the primary methods in my research process.
- Full Text:
- Authors: Rutsate, Jerry
- Date: 2008
- Subjects: Karanga (African people) -- Music Shona (African people) -- Music Folk music -- Zimbabwe Music -- Zimbabwe Folk songs, Shona Mhande Dance music -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2655 , http://hdl.handle.net/10962/d1002321
- Description: This thesis is an investigation of the significance of Mhande song-dance in two performance contexts: the Mutoro ritual of the Karanga and the Chibuku Neshamwari Traditional Dance Competition. In addition, I undertake comparative analysis of the structure of Mhande music in relation to the structure of selected genres of Shona indigenous music. The position of Mhande in the larger context of Shona music is determined through analysis of transcriptions of the rhythmic, melodic and harmonic elements of chizambi mouth bow, karimba mbira, ngororombe panpipes, ngano story songs, game, hunting, war, and love songs. Mhande is an indigenous song-dance performed for the mutoro ceremony, the annual rain ritual of the Karanga. The Mhande repertoire consists of distinctive songs and rhythms used for communicating with the majukwa rain spirits. The rain spirits in turn communicate with God (Mwari) the provider of rain, on behalf of the Karanga. Mhande song-dance is performed exactly the same way in the annual Chibuku Neshamwari Traditional Dance Competitions as in the ritual context of the mutoro ceremony. However, in the context of the Competition, it is used for the expression of joy and as a form of cultural identity. The Competition is a forum in which Karanga songdance traditions such as Mhande, compete with other Shona song-dance traditions such as mbakumba, shangara and chinyambera. I contextualize and analyse Mhande song-dance by using the ‘Matonjeni Model’, which in terms of Karanga epistemology, is culture specific. This Model is grounded in description, interpretation and analysis; the primary methods in my research process.
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Photosynthetic and growth response of C₃ and C₄ subspecies of Alloteropsis semialata to nitrogen-supply
- Authors: Abraham, Trevor Ian
- Date: 2008
- Subjects: Photosynthesis , Plants -- Effect of nitrogen on , Growth (Plants) , Plant ecology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4182 , http://hdl.handle.net/10962/d1003750 , Photosynthesis , Plants -- Effect of nitrogen on , Growth (Plants) , Plant ecology
- Description: The greater photosynthetic nitrogen use efficiency (PNUE) of C4 compared with C3 plants may explain the relative success of C4 grasses in nutrient poor environments. This study compared the responses in photosynthetic parameters, leaf nitrogen and biomass allocation between the C3 and C4 subspecies of Alloteropsis semialata supplied soil nitrogen at three levels. Photosynthesis was assessed by means of CO2 response curves and the leaf nitrogen content assayed. Plants were destructively harvested, leaf areas determined and the dry biomass of functional plant components was measured. Results confirmed that the higher PNUE of C4 plants allowed them to accumulate more biomass than C3 plants at the high nitrogen level, despite smaller leaf areas. The greater productivity of C4 plants enabled them to invest more in storage and sexual reproduction than in leaves when compared to the C3 plants. In contrast the C3 plants invested biomass in less efficient and more nitrogen demanding leaves and bigger root systems. PNUE and photosynthetic rates were not significantly affected by nitrogen-limitation in either subspecies and the major response was a decrease in biomass accumulation and an increase in biomass allocation to roots. This altered root to shoot ratio was accompanied by a lowered allocation to sexual reproduction in the C4 subspecies, but an unaltered allocation to leaves, while in the C3 subspecies there was a decrease in leaf allocation. In a further experiment, the C4 subspecies was supplied three levels of nitrogen provided as nitrate, or alternatively as ammonium plus nitrate, and leaves were excised to within 5 cm of the ground at the start of treatment. Prior to flowering, photosynthesis was assessed by means of CO2 response curves and the plants were destructively harvested. Leaf areas and the dry biomass of functional plant components were determined, and at levels of nitrogen supply higher than those found in savanna soils the rate of photosynthesis was increased. Leaf re-growth was reduced by severe nitrogen limitation and co-provision of nitrate and ammonium had no significant effect other than increased tillering. Both subspecies of Alloteropsis semialata are adapted to nutrient poor environments and maintain photosynthetic rates by reducing leaf area. The C4 subspecies is likely to show greater resilience in disturbance-prone environments by exploiting its higher PNUE to allocate greater resources to storage and sexual reproduction, while the C3 subspecies is usually found in environments with closed canopies which favour vegetative growth, and allocate greater resources to leaves and roots.
- Full Text:
- Authors: Abraham, Trevor Ian
- Date: 2008
- Subjects: Photosynthesis , Plants -- Effect of nitrogen on , Growth (Plants) , Plant ecology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4182 , http://hdl.handle.net/10962/d1003750 , Photosynthesis , Plants -- Effect of nitrogen on , Growth (Plants) , Plant ecology
- Description: The greater photosynthetic nitrogen use efficiency (PNUE) of C4 compared with C3 plants may explain the relative success of C4 grasses in nutrient poor environments. This study compared the responses in photosynthetic parameters, leaf nitrogen and biomass allocation between the C3 and C4 subspecies of Alloteropsis semialata supplied soil nitrogen at three levels. Photosynthesis was assessed by means of CO2 response curves and the leaf nitrogen content assayed. Plants were destructively harvested, leaf areas determined and the dry biomass of functional plant components was measured. Results confirmed that the higher PNUE of C4 plants allowed them to accumulate more biomass than C3 plants at the high nitrogen level, despite smaller leaf areas. The greater productivity of C4 plants enabled them to invest more in storage and sexual reproduction than in leaves when compared to the C3 plants. In contrast the C3 plants invested biomass in less efficient and more nitrogen demanding leaves and bigger root systems. PNUE and photosynthetic rates were not significantly affected by nitrogen-limitation in either subspecies and the major response was a decrease in biomass accumulation and an increase in biomass allocation to roots. This altered root to shoot ratio was accompanied by a lowered allocation to sexual reproduction in the C4 subspecies, but an unaltered allocation to leaves, while in the C3 subspecies there was a decrease in leaf allocation. In a further experiment, the C4 subspecies was supplied three levels of nitrogen provided as nitrate, or alternatively as ammonium plus nitrate, and leaves were excised to within 5 cm of the ground at the start of treatment. Prior to flowering, photosynthesis was assessed by means of CO2 response curves and the plants were destructively harvested. Leaf areas and the dry biomass of functional plant components were determined, and at levels of nitrogen supply higher than those found in savanna soils the rate of photosynthesis was increased. Leaf re-growth was reduced by severe nitrogen limitation and co-provision of nitrate and ammonium had no significant effect other than increased tillering. Both subspecies of Alloteropsis semialata are adapted to nutrient poor environments and maintain photosynthetic rates by reducing leaf area. The C4 subspecies is likely to show greater resilience in disturbance-prone environments by exploiting its higher PNUE to allocate greater resources to storage and sexual reproduction, while the C3 subspecies is usually found in environments with closed canopies which favour vegetative growth, and allocate greater resources to leaves and roots.
- Full Text:
Plant community distribution and diversity, and threats to vegetation of the Kromme River peat basins, Eastern Cape Province, South Africa
- Authors: Nsor, Collins Ayine
- Date: 2008
- Subjects: Kromme River (Eastern Cape, South Africa) , Peatland ecology -- South Africa -- Eastern Cape , Plant diversity conservation -- South Africa -- Eastern Cape , Peatland plants -- South Africa -- Eastern Cape , Peatlands -- South Africa -- Eastern Cape , Biodiversity -- South Africa -- Eastern Cape , Wetland conservation -- South Africa -- Eastern Cape , Ecosystem management -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4760 , http://hdl.handle.net/10962/d1007151 , Kromme River (Eastern Cape, South Africa) , Peatland ecology -- South Africa -- Eastern Cape , Plant diversity conservation -- South Africa -- Eastern Cape , Peatland plants -- South Africa -- Eastern Cape , Peatlands -- South Africa -- Eastern Cape , Biodiversity -- South Africa -- Eastern Cape , Wetland conservation -- South Africa -- Eastern Cape , Ecosystem management -- South Africa -- Eastern Cape
- Description: This study examined the current plant diversity status and the impact of drivers of change on the peat basins of the Kromme River peatland. It was conducted at six sites over sixty one years in the Eastern Cape Province of South Africa. I reviewed the rapid habitat and biodiversity loss of wetlands globally and discussed the distribution of wetlands and specifically peatlands in South Africa. Plant species diversity was assessed using Modified- Whittaker plots. The influence of environmental variables on floristic composition and distribution was investigated using ordination techniques (DCA and CCA). Land use dynamics were assessed by applying GIS techniques on orthorectified aerial images. Six different peat basins were subjectively classified into good, medium and poor condition peat basins. The good condition peat basin (Krugersland) was the most diverse in plant species (4.1 Shannon-Weiner’s index) (p> 0.20; F = 11.04; df = 2), with the highest mean number of plant species (32.5 ± 3.4). This was followed by the medium condition class (Kammiesbos) (26.5 ± 9.0) and poor condition class (Companjesdrift) (22.5 ± 8.9). On average, species composition was not evenly distributed across the peat basins (p> 0.21; F = 0.94; df = 2), since 77.8% of the Shannon-Weiner evenness index obtained were less than one. However, there were variations in plant species richness across six peat basins as confirmed by Oneway ANOVA test (p= 0.0008, F = 1241.6, df = 4). Key environmental variables that influenced plant species distribution and structure were erosion and grazing intensity, potassium, phosphorus, soil pH and calcium. Total species variance accounted for in the first two axes for ground cover and plant height were 40.7% and 56.4% respectively. Alien species (e.g. Acacia mearnsii and Conyza scabrida) were common in degraded peat basins, whereas good condition peat basins supported indigenous species (e.g., Cyperus denudatus, Chrysanthemoides monolifera and Digitaria eriantha). Analysis of aerial images revealed a general progressive decrease in the peatland area between 1942 and 1969 in the good (Krugersland) and poor (Companjesdrift) condition class, with a marginal increase from 1969 to 2003. Peatland area in the good and poor condition class decreased by 5.3% and 8.3% respectively between 1942 and 1969, with a marginal increase of 1.5% and 4.1% respectively from 1969 to 2003. Annual net rate of change in peatland area over the 61 year period was -0.32% (good condition class) and - 0.79% (poor condition class). Transformed lands were impacted by drivers of change such as alien invasives, agricultural activities, erosion and sediment transport. The area under alien invasives increased by 50% between 1942 and 2003, with an annual net rate of change of +0.82 (good condition class) and +1.63% (poor condition class).
- Full Text:
- Authors: Nsor, Collins Ayine
- Date: 2008
- Subjects: Kromme River (Eastern Cape, South Africa) , Peatland ecology -- South Africa -- Eastern Cape , Plant diversity conservation -- South Africa -- Eastern Cape , Peatland plants -- South Africa -- Eastern Cape , Peatlands -- South Africa -- Eastern Cape , Biodiversity -- South Africa -- Eastern Cape , Wetland conservation -- South Africa -- Eastern Cape , Ecosystem management -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4760 , http://hdl.handle.net/10962/d1007151 , Kromme River (Eastern Cape, South Africa) , Peatland ecology -- South Africa -- Eastern Cape , Plant diversity conservation -- South Africa -- Eastern Cape , Peatland plants -- South Africa -- Eastern Cape , Peatlands -- South Africa -- Eastern Cape , Biodiversity -- South Africa -- Eastern Cape , Wetland conservation -- South Africa -- Eastern Cape , Ecosystem management -- South Africa -- Eastern Cape
- Description: This study examined the current plant diversity status and the impact of drivers of change on the peat basins of the Kromme River peatland. It was conducted at six sites over sixty one years in the Eastern Cape Province of South Africa. I reviewed the rapid habitat and biodiversity loss of wetlands globally and discussed the distribution of wetlands and specifically peatlands in South Africa. Plant species diversity was assessed using Modified- Whittaker plots. The influence of environmental variables on floristic composition and distribution was investigated using ordination techniques (DCA and CCA). Land use dynamics were assessed by applying GIS techniques on orthorectified aerial images. Six different peat basins were subjectively classified into good, medium and poor condition peat basins. The good condition peat basin (Krugersland) was the most diverse in plant species (4.1 Shannon-Weiner’s index) (p> 0.20; F = 11.04; df = 2), with the highest mean number of plant species (32.5 ± 3.4). This was followed by the medium condition class (Kammiesbos) (26.5 ± 9.0) and poor condition class (Companjesdrift) (22.5 ± 8.9). On average, species composition was not evenly distributed across the peat basins (p> 0.21; F = 0.94; df = 2), since 77.8% of the Shannon-Weiner evenness index obtained were less than one. However, there were variations in plant species richness across six peat basins as confirmed by Oneway ANOVA test (p= 0.0008, F = 1241.6, df = 4). Key environmental variables that influenced plant species distribution and structure were erosion and grazing intensity, potassium, phosphorus, soil pH and calcium. Total species variance accounted for in the first two axes for ground cover and plant height were 40.7% and 56.4% respectively. Alien species (e.g. Acacia mearnsii and Conyza scabrida) were common in degraded peat basins, whereas good condition peat basins supported indigenous species (e.g., Cyperus denudatus, Chrysanthemoides monolifera and Digitaria eriantha). Analysis of aerial images revealed a general progressive decrease in the peatland area between 1942 and 1969 in the good (Krugersland) and poor (Companjesdrift) condition class, with a marginal increase from 1969 to 2003. Peatland area in the good and poor condition class decreased by 5.3% and 8.3% respectively between 1942 and 1969, with a marginal increase of 1.5% and 4.1% respectively from 1969 to 2003. Annual net rate of change in peatland area over the 61 year period was -0.32% (good condition class) and - 0.79% (poor condition class). Transformed lands were impacted by drivers of change such as alien invasives, agricultural activities, erosion and sediment transport. The area under alien invasives increased by 50% between 1942 and 2003, with an annual net rate of change of +0.82 (good condition class) and +1.63% (poor condition class).
- Full Text:
Prototyping a peer-to-peer session initiation protocol user agent
- Authors: Tsietsi, Mosiuoa Jeremia
- Date: 2008 , 2008-03-10
- Subjects: Computer networks , Computer network protocols -- Standards , Data transmission systems -- Standards , Peer-to-peer architecture (Computer networks) , Computer network architectures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4646 , http://hdl.handle.net/10962/d1006603 , Computer networks , Computer network protocols -- Standards , Data transmission systems -- Standards , Peer-to-peer architecture (Computer networks) , Computer network architectures
- Description: The Session Initiation Protocol (SIP) has in recent years become a popular protocol for the exchange of text, voice and video over IP networks. This thesis proposes the use of a class of structured peer to peer protocols - commonly known as Distributed Hash Tables (DHTs) - to provide a SIP overlay with services such as end-point location management and message relay, in the absence of traditional, centralised resources such as SIP proxies and registrars. A peer-to-peer layer named OverCord, which allows the interaction with any specific DHT protocol via the use of appropriate plug-ins, was designed, implemented and tested. This layer was then incorporated into a SIP user agent distributed by NIST (National Institute of Standards and Technology, USA). The modified user agent is capable of reliably establishing text, audio and video communication with similarly modified agents (peers) as well as conventional, centralized SIP overlays.
- Full Text:
- Authors: Tsietsi, Mosiuoa Jeremia
- Date: 2008 , 2008-03-10
- Subjects: Computer networks , Computer network protocols -- Standards , Data transmission systems -- Standards , Peer-to-peer architecture (Computer networks) , Computer network architectures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4646 , http://hdl.handle.net/10962/d1006603 , Computer networks , Computer network protocols -- Standards , Data transmission systems -- Standards , Peer-to-peer architecture (Computer networks) , Computer network architectures
- Description: The Session Initiation Protocol (SIP) has in recent years become a popular protocol for the exchange of text, voice and video over IP networks. This thesis proposes the use of a class of structured peer to peer protocols - commonly known as Distributed Hash Tables (DHTs) - to provide a SIP overlay with services such as end-point location management and message relay, in the absence of traditional, centralised resources such as SIP proxies and registrars. A peer-to-peer layer named OverCord, which allows the interaction with any specific DHT protocol via the use of appropriate plug-ins, was designed, implemented and tested. This layer was then incorporated into a SIP user agent distributed by NIST (National Institute of Standards and Technology, USA). The modified user agent is capable of reliably establishing text, audio and video communication with similarly modified agents (peers) as well as conventional, centralized SIP overlays.
- Full Text:
Radio Frequency Identification (RFID) adoption in the South African retail sector: an investigation of perceptions held by members of the retail sector regarding the adoption constraints
- Authors: Liu, Haidi
- Date: 2008
- Subjects: Radio frequency identification systems , Retail trade -- South Africa , Business logistics -- Management -- South Africa , Retail trade -- Employees -- South Africa , Retail trade -- Technological innovations , Radio waves , Consumer profiling
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:1144 , http://hdl.handle.net/10962/d1002774 , Radio frequency identification systems , Retail trade -- South Africa , Business logistics -- Management -- South Africa , Retail trade -- Employees -- South Africa , Retail trade -- Technological innovations , Radio waves , Consumer profiling
- Description: Radio Frequency Identification (RFID) technology is a ethod of identifying unique items using radio waves that communicate between RFID tags and readers without line-of-sight readability. RFID technology provides great potential in many industries and a wide spectrum of possible uses. Areas of application include person identification, logistics, pharmaceutical, access control, security guard monitoring and asset management. One of the areas where RFID is being used and where it promises excellent results is the retail industry. While RFID systems have the potential to revolutionise the way products and goods are tracked and traced in the retail supply chain, barriers to its widespread adoption exist: for example; technical constraints, return on investment constraints, a lack of awareness and education and as well as privacy and security issues. The research aims to identify the barriers to the adoption of RFID and to investigate the perceptions of RFID held by members of the retail sector in South Africa (SA). Current research and available literature are used to identify RFID adoption barriers and a conceptual framework on this subject is proposed, which is then verified by SA retailers’ perceptions, established by means of a survey. Initial barriers to widespread adoption include a shortage in skills, a lack of standards, high costs associated with RFID devices, the difficulty of integrating with current legacy systems, and a lack of familiarity with the system. Finally, an enhanced framework is proposed, describing RFID adoption barriers within the South African retail sector. In summary, the framework is an outline of the barriers impacting RFID adoption in the SA retail sector that need to be considered and addressed. The framework identifies six categories of RFID adoption barriers, with each category containing two or more barriers relating to that particular category. These categories are Technological, Cost and return on investment, Privacy and security, Implementation, Organisational factors and People.
- Full Text:
- Authors: Liu, Haidi
- Date: 2008
- Subjects: Radio frequency identification systems , Retail trade -- South Africa , Business logistics -- Management -- South Africa , Retail trade -- Employees -- South Africa , Retail trade -- Technological innovations , Radio waves , Consumer profiling
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:1144 , http://hdl.handle.net/10962/d1002774 , Radio frequency identification systems , Retail trade -- South Africa , Business logistics -- Management -- South Africa , Retail trade -- Employees -- South Africa , Retail trade -- Technological innovations , Radio waves , Consumer profiling
- Description: Radio Frequency Identification (RFID) technology is a ethod of identifying unique items using radio waves that communicate between RFID tags and readers without line-of-sight readability. RFID technology provides great potential in many industries and a wide spectrum of possible uses. Areas of application include person identification, logistics, pharmaceutical, access control, security guard monitoring and asset management. One of the areas where RFID is being used and where it promises excellent results is the retail industry. While RFID systems have the potential to revolutionise the way products and goods are tracked and traced in the retail supply chain, barriers to its widespread adoption exist: for example; technical constraints, return on investment constraints, a lack of awareness and education and as well as privacy and security issues. The research aims to identify the barriers to the adoption of RFID and to investigate the perceptions of RFID held by members of the retail sector in South Africa (SA). Current research and available literature are used to identify RFID adoption barriers and a conceptual framework on this subject is proposed, which is then verified by SA retailers’ perceptions, established by means of a survey. Initial barriers to widespread adoption include a shortage in skills, a lack of standards, high costs associated with RFID devices, the difficulty of integrating with current legacy systems, and a lack of familiarity with the system. Finally, an enhanced framework is proposed, describing RFID adoption barriers within the South African retail sector. In summary, the framework is an outline of the barriers impacting RFID adoption in the SA retail sector that need to be considered and addressed. The framework identifies six categories of RFID adoption barriers, with each category containing two or more barriers relating to that particular category. These categories are Technological, Cost and return on investment, Privacy and security, Implementation, Organisational factors and People.
- Full Text:
Ray Charles: a psychobiographical study
- Authors: Biggs, Ilze
- Date: 2008
- Subjects: Charles, Ray, 1930-2004 Psychology -- Biographical methods -- Case studies Jazz singers -- Biography Blind entertainers -- Psychology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2933 , http://hdl.handle.net/10962/d1002442
- Description: Psychobiography is the formulation of an individual's narrative according to a psychological theory. Psychobiographical researchers face a number of challenges. One pertinent challenge is the limited amount of psychobiographical research conducted at academic institutions, including South Africa. Although a number of studies had been completed in the past decade, the impact of psychobiographical research remains negligible. Although much has been written about Ray Charles, none of the existing literature adopted a specific psychological focus. Charles developed from a young boy in a poverty stricken, racially segregated society into an exceptionally successful musician who worked productively until he died at the age of 73. He was selected as the subject on the basis of interest value, uniqueness and significance of life achievements. The primary aim of this study was to explore and describe the development of Charles according to Levinson's (Levinson, et. ai, 1978) theoretical framework. Levinson's theory of adult development identifies and describes the important changes that occur throughout the lifespan of an individual. A secondary aim was to provide an understanding of Charles within the social, economic and historical context in which he lived. The data collection and analysis was conducted according to Yin's (2003) 'analytic generalization'. The data was analysed according to three linked sub-processes proposed by Huberman and Miles (1994).
- Full Text:
- Authors: Biggs, Ilze
- Date: 2008
- Subjects: Charles, Ray, 1930-2004 Psychology -- Biographical methods -- Case studies Jazz singers -- Biography Blind entertainers -- Psychology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2933 , http://hdl.handle.net/10962/d1002442
- Description: Psychobiography is the formulation of an individual's narrative according to a psychological theory. Psychobiographical researchers face a number of challenges. One pertinent challenge is the limited amount of psychobiographical research conducted at academic institutions, including South Africa. Although a number of studies had been completed in the past decade, the impact of psychobiographical research remains negligible. Although much has been written about Ray Charles, none of the existing literature adopted a specific psychological focus. Charles developed from a young boy in a poverty stricken, racially segregated society into an exceptionally successful musician who worked productively until he died at the age of 73. He was selected as the subject on the basis of interest value, uniqueness and significance of life achievements. The primary aim of this study was to explore and describe the development of Charles according to Levinson's (Levinson, et. ai, 1978) theoretical framework. Levinson's theory of adult development identifies and describes the important changes that occur throughout the lifespan of an individual. A secondary aim was to provide an understanding of Charles within the social, economic and historical context in which he lived. The data collection and analysis was conducted according to Yin's (2003) 'analytic generalization'. The data was analysed according to three linked sub-processes proposed by Huberman and Miles (1994).
- Full Text:
Re-evaluating the law of vicarious liability in South Africa
- Authors: Small, Jonathan Noel
- Date: 2008
- Subjects: Independent contractors -- South Africa Law -- South Africa Torts -- South Africa Courts -- South Africa Jurisdiction -- South Africa International law -- South Africa Roman law Roman-Dutch law
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:3704 , http://hdl.handle.net/10962/d1004771
- Description: This thesis is an analysis of the law of vicarious liability and its application within the legal framework of delict in South Africa. A brief overview of the historical development of this branch of law is given, with reference to the influences of Roman, Roman-Dutch and English law. That is followed by an exposition of the 'modem' interpretation of vicarious liability as applied in South African courts, highlighting apparent inconsistencies and the need for reform in what has become a persistently controversial area of law. Specific attention is paid to the so-called 'course and scope enquiry' and to the enduring difficulties associated with attributing liability to employers for the deliberate wrongful conduct of their employees. It is argued that the courts have yet to reach consensus on a general principle capable of being applied to the facts of so-called 'deviation cases', and that consequently the legal divergence on these matters gives rise to uncertainty and concern. It is submitted that the way in which the traditional test for vicarious liability is currently applied fails to give true effect to the policy considerations upon which this branch of law is founded. By way of comparison with the South African position, a detailed account of the law of vicarious liability in comparable foreign jurisdictions is given, with emphasis placed on recent developments in England and the British Commonwealth. The study then moves to an analysis of the various policy considerations behind vicarious liability, with particular attention being paid to the role of risk-related liability and the role of risk-assumption in the 'course and scope' enquiry. A comparative analysis follows, highlighting differences between the approaches of the foreign jurisdictions and that taken by the South African courts. The work concludes with a proposal that the South African courts should broaden the scope of vicarious liability and opt for a model similar to that which has recently been adopted in Canada.
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- Authors: Small, Jonathan Noel
- Date: 2008
- Subjects: Independent contractors -- South Africa Law -- South Africa Torts -- South Africa Courts -- South Africa Jurisdiction -- South Africa International law -- South Africa Roman law Roman-Dutch law
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:3704 , http://hdl.handle.net/10962/d1004771
- Description: This thesis is an analysis of the law of vicarious liability and its application within the legal framework of delict in South Africa. A brief overview of the historical development of this branch of law is given, with reference to the influences of Roman, Roman-Dutch and English law. That is followed by an exposition of the 'modem' interpretation of vicarious liability as applied in South African courts, highlighting apparent inconsistencies and the need for reform in what has become a persistently controversial area of law. Specific attention is paid to the so-called 'course and scope enquiry' and to the enduring difficulties associated with attributing liability to employers for the deliberate wrongful conduct of their employees. It is argued that the courts have yet to reach consensus on a general principle capable of being applied to the facts of so-called 'deviation cases', and that consequently the legal divergence on these matters gives rise to uncertainty and concern. It is submitted that the way in which the traditional test for vicarious liability is currently applied fails to give true effect to the policy considerations upon which this branch of law is founded. By way of comparison with the South African position, a detailed account of the law of vicarious liability in comparable foreign jurisdictions is given, with emphasis placed on recent developments in England and the British Commonwealth. The study then moves to an analysis of the various policy considerations behind vicarious liability, with particular attention being paid to the role of risk-related liability and the role of risk-assumption in the 'course and scope' enquiry. A comparative analysis follows, highlighting differences between the approaches of the foreign jurisdictions and that taken by the South African courts. The work concludes with a proposal that the South African courts should broaden the scope of vicarious liability and opt for a model similar to that which has recently been adopted in Canada.
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Reading nonsense : a journey through the writing of Edward Lear
- Authors: Pendlebury, Kathleen Sarah
- Date: 2008
- Subjects: Lear, Edward, 1812-1888 Lear, Edward, 1812-1888 Criticism and interpretation English poetry -- 19th century -- Criticism and interpretation
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2206 , http://hdl.handle.net/10962/d1002249
- Description: In this thesis I have addressed some of the problems that have arisen in critical approaches to the nonsense works of Edward Lear from the late nineteenth century. I have entitled it “Reading Nonsense” because my central concern is with how best to apprehend the paradoxes inherent in literary nonsense, which inevitably raises interpretative questions. Because nonsense is a “basic type of communication” whose essence is “unresolved tension between [the] presence and absence of meaning” (Tigges, Anatomy 51), we are called upon either to “make sense of” that which claims to offer up no meaning or to surrender ourselves to meaninglessness. Broadly, critical approaches to nonsense fall into two classes: those that maintain that nonsense is not, in fact, “not sense”, but rather a kind of symbolic language that can be reconciled into meaning; and those which uphold the nonsensicality of nonsense, maintaining that certain ambiguities and paradoxes cannot be accounted for, and it is inappropriate to try to do so. In addition, Lear’s texts are situated in various traditions of writing for children and adults and in the distinctive setting of the Victorian era; and these cultural and literary influences play an important role in the interpretation and misinterpretation of nonsense. My first chapter comprises a mise en scène of the genre of literary nonsense; while in Chapter 2 I turn to the cultural backdrop of Lear’s nonsense in particular, and examine one of the claims frequently made in nonsense criticism: that Lear’s literary nonsense is distinctively “Victorian”. Chapter 3, “How to Read a Learian Limerick”, rests on the exegesis of nonsense that appears in Chapter 1, for here I propose a technique for reading Lear’s limericks that preserves both their “sensical” and nonsensical elements in contrast to critical analyses that attempt to reconcile the nonsense into a code. In Chapter 4 I examine Lear’s songs from the critical perspectives of nonsense and of romanticism. Finally, in conclusion, I consider the role and significance of humour in nonsense, and gesture towards further possible explorations, including in the appendix my essay on the nonsense poetry of South African writer Philip de Vos.
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- Authors: Pendlebury, Kathleen Sarah
- Date: 2008
- Subjects: Lear, Edward, 1812-1888 Lear, Edward, 1812-1888 Criticism and interpretation English poetry -- 19th century -- Criticism and interpretation
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2206 , http://hdl.handle.net/10962/d1002249
- Description: In this thesis I have addressed some of the problems that have arisen in critical approaches to the nonsense works of Edward Lear from the late nineteenth century. I have entitled it “Reading Nonsense” because my central concern is with how best to apprehend the paradoxes inherent in literary nonsense, which inevitably raises interpretative questions. Because nonsense is a “basic type of communication” whose essence is “unresolved tension between [the] presence and absence of meaning” (Tigges, Anatomy 51), we are called upon either to “make sense of” that which claims to offer up no meaning or to surrender ourselves to meaninglessness. Broadly, critical approaches to nonsense fall into two classes: those that maintain that nonsense is not, in fact, “not sense”, but rather a kind of symbolic language that can be reconciled into meaning; and those which uphold the nonsensicality of nonsense, maintaining that certain ambiguities and paradoxes cannot be accounted for, and it is inappropriate to try to do so. In addition, Lear’s texts are situated in various traditions of writing for children and adults and in the distinctive setting of the Victorian era; and these cultural and literary influences play an important role in the interpretation and misinterpretation of nonsense. My first chapter comprises a mise en scène of the genre of literary nonsense; while in Chapter 2 I turn to the cultural backdrop of Lear’s nonsense in particular, and examine one of the claims frequently made in nonsense criticism: that Lear’s literary nonsense is distinctively “Victorian”. Chapter 3, “How to Read a Learian Limerick”, rests on the exegesis of nonsense that appears in Chapter 1, for here I propose a technique for reading Lear’s limericks that preserves both their “sensical” and nonsensical elements in contrast to critical analyses that attempt to reconcile the nonsense into a code. In Chapter 4 I examine Lear’s songs from the critical perspectives of nonsense and of romanticism. Finally, in conclusion, I consider the role and significance of humour in nonsense, and gesture towards further possible explorations, including in the appendix my essay on the nonsense poetry of South African writer Philip de Vos.
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Reflective accounts of childhood inter-species experiences in a Southern-African context: a phenomenological-hermeneutic exploration
- Authors: Rump, Samantha
- Date: 2008
- Subjects: Child psychology -- South Africa Child development -- South Africa Human-animal relationships -- South Africa Children and animals -- South Africa Animal psychology -- South Africa Hermeneutics Phenomenology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3045 , http://hdl.handle.net/10962/d1002554
- Description: The aims of this research were to describe in rich phenomenological detail the recollected childhood experiences described by three South African adults of growing up with animals in the context of a traditionally African cultural perspective in South Africa; as well as to document the emotional, physical and social effects of inter-species relationships as described by these participants, in order to explore and situate these experiences in relation to broad international perspectives on the contribution of animals to human development. The question of how these described experiences correlate with broad international perspectives on the contribution of animals to human development comprised the hermeneutic of the study. Here it was found that the experiences of these South African individuals were generally in keeping with the trends found in the literature. Participants attributed to their childhood relationships with animals a variety of benefits. These benefits occur on a range of levels, from the physical to the cognitive, and the psychosocial. The emotional attachment of the participants to animals with whom they had interacted in childhood correlated with the nature of interspecies relationships as anticipated by the literature. Cultural differences in the conceptualisation of inter-species relationships, between western and traditionally African ideologies, appeared to influence the moral and ethical positions assumed by the participants, while the subjective nature of the described attachment between participants and animals remains qualitatively similar across cultures, when explored in relation to international research. The similarities between the experiences of the participants and international research findings lend credence to Wilson’s hypothesis that all human beings are potentially able to connect in deep and profound ways with their natural environment, and that this connection contributes to the development of social and cognitive skills, as well as constituting emotional support and stability. The research concludes with an examination of its own limitations and suggestions are made for further research.
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- Authors: Rump, Samantha
- Date: 2008
- Subjects: Child psychology -- South Africa Child development -- South Africa Human-animal relationships -- South Africa Children and animals -- South Africa Animal psychology -- South Africa Hermeneutics Phenomenology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3045 , http://hdl.handle.net/10962/d1002554
- Description: The aims of this research were to describe in rich phenomenological detail the recollected childhood experiences described by three South African adults of growing up with animals in the context of a traditionally African cultural perspective in South Africa; as well as to document the emotional, physical and social effects of inter-species relationships as described by these participants, in order to explore and situate these experiences in relation to broad international perspectives on the contribution of animals to human development. The question of how these described experiences correlate with broad international perspectives on the contribution of animals to human development comprised the hermeneutic of the study. Here it was found that the experiences of these South African individuals were generally in keeping with the trends found in the literature. Participants attributed to their childhood relationships with animals a variety of benefits. These benefits occur on a range of levels, from the physical to the cognitive, and the psychosocial. The emotional attachment of the participants to animals with whom they had interacted in childhood correlated with the nature of interspecies relationships as anticipated by the literature. Cultural differences in the conceptualisation of inter-species relationships, between western and traditionally African ideologies, appeared to influence the moral and ethical positions assumed by the participants, while the subjective nature of the described attachment between participants and animals remains qualitatively similar across cultures, when explored in relation to international research. The similarities between the experiences of the participants and international research findings lend credence to Wilson’s hypothesis that all human beings are potentially able to connect in deep and profound ways with their natural environment, and that this connection contributes to the development of social and cognitive skills, as well as constituting emotional support and stability. The research concludes with an examination of its own limitations and suggestions are made for further research.
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Removal and photocatalysis of 4-Nitrophenol using metallophthalocyanines
- Authors: Marais, Eloise Ann
- Date: 2008
- Subjects: Photocatalysis , Catalysis , Electrochemistry , Nitrophenols , Phthalocyanines
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4343 , http://hdl.handle.net/10962/d1005005 , Photocatalysis , Catalysis , Electrochemistry , Nitrophenols , Phthalocyanines
- Description: Photodegradation of 4-nitrophenol (4-Np) in the presence of water-soluble zinc phthalocyanines and water-insoluble metallophthalocyanines is reported. The water-soluble phthalocyanines employed include zinc tetrasulphophthalocyanine (ZnPcS[subscript 4]), zinc octacarboxyphthalocyanine (ZnPc(COOH)[subscript 8]) and a sulphonated ZnPc containing a mixture of differently sulphonated derivatives (ZnPcS[subscript mix]), while the water-insoluble phthalocyanines used include unsubstituted magnesium (MgPc), zinc (ZnPc) and chloroaluminium (ClAlPc) phthalocyanine complexes and the ring-substituted zinc tetranitro (ZnPc(NO[subscript 2])[subscript 4]), zinc tetraamino (ZnPc(NH[subscript 2])[subscript 4]), zinc hexadecafluoro (ZnPcF[subscript 16]) and zinc hexadecachloro (ZnPcCl[subscript 16]) phthalocyanines. The most effective water-soluble photocatalyst is ZnPcS[subscript mix] in terms of the high quantum yield obtained for 4-Np degradation (Φ[subscript 4-Np]) as well as its photostability. While ZnPc(COOH)[subscript 8] has the highest Φ[subscript 4-Np] value relative to the other water-soluble complexes, it degrades readily during photocatalysis. The Φ[subscript 4-Np] values were closely related to the singlet oxygen quantum yields Φ[subscript Δ] and hence aggregation. The rate constants for the reaction with 4-Np were kr = 0.67 x 10[superscript 6] mol[superscript -1] dm[superscript 3] s[superscript -1] for ZnPcS[subscript mix] and 7.7 x 10[superscript 6] mol[superscript -1] dm[superscript 3] s[superscript -1] for ZnPc(COOH)[subscript 8]. ClAlPc is the most effective photocatalyst relative to the other heterogeneous photocatalysts for the phototransformation of 4-Np, with 89 ± 8.4 % degradation of 4-Np achieved after 100 min. The least effective catalysts were ZnPcCl[subscript 16] and MgPc. The final products of the photocatalysis of 4-Np in the presence of the homogeneous photocatalysts include 4-nitrocatechol and hydroquinone, while degradation of 4-Np in the presence of the heterogeneous photocatalysts resulted in fumaric acid and 4-nitrocatechol. ClAlPc was employed for the heterogeneous photocatalysis of the non-systemic insecticide, methyl paraoxon. Complete degradation of the pesticide was confirmed by the disappearance of the HPLC trace for methyl paraoxon after 100 min of irradiation with visible light. The removal of 4-Np from an aqueous medium using commercially available Amberlite[superscript ®] IRA-900 modified with metal phthalocyanines was also investigated. The metallophthalocyanines immobilised onto the surface of Amberlite[superscript ®] IRA-900 include Fe (FePcS[subscript 4]), Co (CoPcS[subscript 4]) and Ni (NiPcS[subscript 4]) tetrasulphophthalocyanines, and differently sulphonated phthalocyanine mixtures of Fe (FePcS[subscript mix]), Co (CoPcS[subscript mix]) and Ni (NiPcS[subscript mix]). Adsorption rates were fastest for the modified adsorbents at pH 9. Using the Langmuir-Hinshelwood kinetic model, the complexes showed the following order of 4-Np adsorption: CoPcS[subscript mix] > NiPcS[subscript 4] > NiPcS[subscript mix] > FePcS[subscript 4] > FePcS[subscript mix] > CoPcS[subscript 4]. The adsorbents were regenerated using dilute HNO[subscript 3], with 76 % (7.6 x 10[superscript -5] mol) of 4-Np recovered within 150 min.
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- Authors: Marais, Eloise Ann
- Date: 2008
- Subjects: Photocatalysis , Catalysis , Electrochemistry , Nitrophenols , Phthalocyanines
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4343 , http://hdl.handle.net/10962/d1005005 , Photocatalysis , Catalysis , Electrochemistry , Nitrophenols , Phthalocyanines
- Description: Photodegradation of 4-nitrophenol (4-Np) in the presence of water-soluble zinc phthalocyanines and water-insoluble metallophthalocyanines is reported. The water-soluble phthalocyanines employed include zinc tetrasulphophthalocyanine (ZnPcS[subscript 4]), zinc octacarboxyphthalocyanine (ZnPc(COOH)[subscript 8]) and a sulphonated ZnPc containing a mixture of differently sulphonated derivatives (ZnPcS[subscript mix]), while the water-insoluble phthalocyanines used include unsubstituted magnesium (MgPc), zinc (ZnPc) and chloroaluminium (ClAlPc) phthalocyanine complexes and the ring-substituted zinc tetranitro (ZnPc(NO[subscript 2])[subscript 4]), zinc tetraamino (ZnPc(NH[subscript 2])[subscript 4]), zinc hexadecafluoro (ZnPcF[subscript 16]) and zinc hexadecachloro (ZnPcCl[subscript 16]) phthalocyanines. The most effective water-soluble photocatalyst is ZnPcS[subscript mix] in terms of the high quantum yield obtained for 4-Np degradation (Φ[subscript 4-Np]) as well as its photostability. While ZnPc(COOH)[subscript 8] has the highest Φ[subscript 4-Np] value relative to the other water-soluble complexes, it degrades readily during photocatalysis. The Φ[subscript 4-Np] values were closely related to the singlet oxygen quantum yields Φ[subscript Δ] and hence aggregation. The rate constants for the reaction with 4-Np were kr = 0.67 x 10[superscript 6] mol[superscript -1] dm[superscript 3] s[superscript -1] for ZnPcS[subscript mix] and 7.7 x 10[superscript 6] mol[superscript -1] dm[superscript 3] s[superscript -1] for ZnPc(COOH)[subscript 8]. ClAlPc is the most effective photocatalyst relative to the other heterogeneous photocatalysts for the phototransformation of 4-Np, with 89 ± 8.4 % degradation of 4-Np achieved after 100 min. The least effective catalysts were ZnPcCl[subscript 16] and MgPc. The final products of the photocatalysis of 4-Np in the presence of the homogeneous photocatalysts include 4-nitrocatechol and hydroquinone, while degradation of 4-Np in the presence of the heterogeneous photocatalysts resulted in fumaric acid and 4-nitrocatechol. ClAlPc was employed for the heterogeneous photocatalysis of the non-systemic insecticide, methyl paraoxon. Complete degradation of the pesticide was confirmed by the disappearance of the HPLC trace for methyl paraoxon after 100 min of irradiation with visible light. The removal of 4-Np from an aqueous medium using commercially available Amberlite[superscript ®] IRA-900 modified with metal phthalocyanines was also investigated. The metallophthalocyanines immobilised onto the surface of Amberlite[superscript ®] IRA-900 include Fe (FePcS[subscript 4]), Co (CoPcS[subscript 4]) and Ni (NiPcS[subscript 4]) tetrasulphophthalocyanines, and differently sulphonated phthalocyanine mixtures of Fe (FePcS[subscript mix]), Co (CoPcS[subscript mix]) and Ni (NiPcS[subscript mix]). Adsorption rates were fastest for the modified adsorbents at pH 9. Using the Langmuir-Hinshelwood kinetic model, the complexes showed the following order of 4-Np adsorption: CoPcS[subscript mix] > NiPcS[subscript 4] > NiPcS[subscript mix] > FePcS[subscript 4] > FePcS[subscript mix] > CoPcS[subscript 4]. The adsorbents were regenerated using dilute HNO[subscript 3], with 76 % (7.6 x 10[superscript -5] mol) of 4-Np recovered within 150 min.
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