Gem-bearing granitic pegmatites in Malawi: their mineralogy, geochemistry, age, and fluid compositional variations
- Kankuzi, Charles Frienderson
- Authors: Kankuzi, Charles Frienderson
- Date: 2019
- Subjects: Granite , Pegmatites , Geochemistry , Fluid inclusions , Nonferrous metals
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/97905 , vital:31505 , DOI https://doi.org/10.21504/10962/97905
- Description: The gem bearing granitic pegmatites from different pegmatite fields across Malawi intrude all important geological entities from the Palaeoproterozoic in the north, the Mesoproterozoic in central Malawi and the Pan-African basement in the south. U/Pb zircon and Rb/Sr mineral isochron ages indicate pegmatite emplacement from the Palaeoproterozoic to Pan-African and Mesozoic time. Most pegmatites are related to the Pan-African cycle; no Mesoproterozoic pegmatites were observed in this study. Within the Pan-African pegmatite groups there are two important subgroups. Some pegmatites show Sr isotopic compositions that indicate mantle components contributing to the parental granites from which the pegmatites evolved. Others show higher Sr initials, indicating crustal granites as primary pegmatite sources or significant crustal contamination. Only for few pegmatites, such as the Palaeoproterozoic and Ordovician gem tourmaline pegmatites in the Chitipa and Dowa Districts, the granitic source is evident from their field context. For all others the granitic origin is interpreted by mineralogical and geochemical evidence. All analysed pegmatites belong to either the Rare Element Class or the Miarolitic Class, but they vary in their degree of fractionation. The more evolved pegmatites are more enriched in incompatible elements such as Be, Li, B, and Ta, which resulted in the formation of gem minerals such as beryl, aquamarine, tourmaline and topaz, which may or may not be associated with tantalite. The Rare Element pegmatites can be further subdivided into the REL-Li subclass, beryl type, beryl-columbite subtype, and in the complex type and elbaite subtype. The Miarolitic pegmatites include Mi-Li subclass and beryl-topaz type. Fluid inclusion studies (heating-cooling stage, Raman spectroscopy) identified a variety of fluid compositions that were present at different times and different places, indicating a variety of fluid sources. They range from aqueous-saline to CO2–rich carbonic fluids (CO2 +C3H8+ N2), or aqueous-carbonic fluids (H2O-CO2-CH4 and H2O-CO2-H2-H2S-CH4). The dominant solutes and species for the pegmatites show genetic variations over time and orogen (Paleo-/Meso-/Neoproterozoic). Uniform homogenisation temperatures and salinities in individual samples indicate that the gem-bearing pegmatites contained homogeneous fluids at the time of their capturing in quartz. Based on fluid inclusion data, the estimated trapping conditions of inclusions in quartz for all studied pegmatites except for one pegmatite suggest low pressures between 0.9 to 2.6 kb at temperatures of 400-600 C. The other pegmatite formed at slightly higher pressures of 2.2 to 3.6 kb. However, the pressure range for all the pegmatites is in agreement with the known liquidus conditions of Rare-Element pegmatite crystallisation. The shallow crustal emplacement level (3.4-9.8 km) and the greater depth (8.3 to 13.6 km) favoured the formation of gemstones. , Thesis (PhD) -- Faculty of Science, Geology, 2019
- Full Text: false
- Date Issued: 2019
- Authors: Kankuzi, Charles Frienderson
- Date: 2019
- Subjects: Granite , Pegmatites , Geochemistry , Fluid inclusions , Nonferrous metals
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/97905 , vital:31505 , DOI https://doi.org/10.21504/10962/97905
- Description: The gem bearing granitic pegmatites from different pegmatite fields across Malawi intrude all important geological entities from the Palaeoproterozoic in the north, the Mesoproterozoic in central Malawi and the Pan-African basement in the south. U/Pb zircon and Rb/Sr mineral isochron ages indicate pegmatite emplacement from the Palaeoproterozoic to Pan-African and Mesozoic time. Most pegmatites are related to the Pan-African cycle; no Mesoproterozoic pegmatites were observed in this study. Within the Pan-African pegmatite groups there are two important subgroups. Some pegmatites show Sr isotopic compositions that indicate mantle components contributing to the parental granites from which the pegmatites evolved. Others show higher Sr initials, indicating crustal granites as primary pegmatite sources or significant crustal contamination. Only for few pegmatites, such as the Palaeoproterozoic and Ordovician gem tourmaline pegmatites in the Chitipa and Dowa Districts, the granitic source is evident from their field context. For all others the granitic origin is interpreted by mineralogical and geochemical evidence. All analysed pegmatites belong to either the Rare Element Class or the Miarolitic Class, but they vary in their degree of fractionation. The more evolved pegmatites are more enriched in incompatible elements such as Be, Li, B, and Ta, which resulted in the formation of gem minerals such as beryl, aquamarine, tourmaline and topaz, which may or may not be associated with tantalite. The Rare Element pegmatites can be further subdivided into the REL-Li subclass, beryl type, beryl-columbite subtype, and in the complex type and elbaite subtype. The Miarolitic pegmatites include Mi-Li subclass and beryl-topaz type. Fluid inclusion studies (heating-cooling stage, Raman spectroscopy) identified a variety of fluid compositions that were present at different times and different places, indicating a variety of fluid sources. They range from aqueous-saline to CO2–rich carbonic fluids (CO2 +C3H8+ N2), or aqueous-carbonic fluids (H2O-CO2-CH4 and H2O-CO2-H2-H2S-CH4). The dominant solutes and species for the pegmatites show genetic variations over time and orogen (Paleo-/Meso-/Neoproterozoic). Uniform homogenisation temperatures and salinities in individual samples indicate that the gem-bearing pegmatites contained homogeneous fluids at the time of their capturing in quartz. Based on fluid inclusion data, the estimated trapping conditions of inclusions in quartz for all studied pegmatites except for one pegmatite suggest low pressures between 0.9 to 2.6 kb at temperatures of 400-600 C. The other pegmatite formed at slightly higher pressures of 2.2 to 3.6 kb. However, the pressure range for all the pegmatites is in agreement with the known liquidus conditions of Rare-Element pegmatite crystallisation. The shallow crustal emplacement level (3.4-9.8 km) and the greater depth (8.3 to 13.6 km) favoured the formation of gemstones. , Thesis (PhD) -- Faculty of Science, Geology, 2019
- Full Text: false
- Date Issued: 2019
An overview of energy minerals in the Springbok Flatsbasin, South Africa : implications for geochemical and geophysical exploration
- Authors: Ledwaba, Lebogang John
- Date: 2015
- Subjects: Energy minerals -- South Africa -- Springbok Flats (Limpopo) , Geochemistry , Prospecting -- Geophysical methods , Coal -- South Africa -- Springbok Flats (Limpopo) , Uranium -- South Africa -- Springbok Flats (Limpopo) , Coalbed methane -- South Africa -- Springbok Flats (Limpopo)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5092 , http://hdl.handle.net/10962/d1019880
- Description: This study is informed by the rising demand for power needs in South Africa and aims at understanding the geophysical and geochemical characteristics of the energy minerals in the Springbok Flats Basin and relating them to the prevailing geological and structural setting for improved exploration targeting. The Springbok Flats Basin is part of the Karoo sediments and host to uranium, coal and coal bed methane (CBM) resources. The lithology sections in the basin indicate presence of basaltic lavas at the top, underlain by mudrocks, siltstones, sandstones, conglomerates and diamictite, with interbedded coal beds occasionally. The coals are uraniferous and shale bounded and of lower Beaufort age at 250 Ma. The regional radiometric data identifies the regional extent of the Springbok Flats Basin as a basin with low total count values. This information is useful in exploration as it gives an idea of the limits of the area where to focus application for prospecting licenses. The reduced to pole of the total magnetic field, residuals and first vertical derivative maps clearly show the high magnetic susceptibility nature of the surrounding Bushveld rocks as compared to the low Karoo sediment susceptibility within the basin. There are distinct ring shaped picks within the basin possibly due to known Karoo dolerite sills in particular to the central south western part of the grid. The regional geochemical mapping program is a cost-effective way of providing an overview of the relative abundance levels, regional trends and anomalous patterns in the underlying lithological units. Background values of elements in soils over different lithological units and the identification of anomalous values relative to these elements can easily be identified. The geochemical results show an excellent correlation between soil chemistry and underlying geological formations. A few distinct gravity highs are clearly shown within the basin. Assuming the effect of the Letaba basalt to the gravity readings is uniform across the basin; these distinct anomalies could be due to Karoo dolerite sills as they coincide with areas of distinct high magnetic signature. A conceptual model was generated assuming that the Karoo sediments’ layering is uniform across the gravity profile but changes in the residual are due to an increased thickness of the sill supported by the gentle changes on the surface topography. Satellite imagery has got its challenges especially in areas of vegetation but it does provide a very useful tool in exploration. A number of spectral analysis techniques and band rations can be used to differentiate the areas underlain by the Letaba basalts, the Karoo sandstones/shale and Bushveld granites for mapping purposes. The priority focus will be on the shallower Karoo sediments because of the potential for cheaper mining. Exploration targeting needs to be guided by observed geochemical and geophysical characteristics in order to prioritize areas taking into account the presence of Karoo intrusives such as the dolerite sills that tend to devolatize the coal hence affecting the quality/rank. Structures and gravity signatures are very important in delineating areas with thick sediments that have a potential for CBM. The same understanding in targeting goes a long way in planning drill holes, resource modelling and pre-feasibility stages for mine planning. A high resolution airborne geophysical survey is recommended over the basin to better resolve structures. Geophysical borehole logging is recommended to be part of the exploration drilling programs in the Springbok Flats Basin in order to define the in-situ geophysical characteristics. Geophysical logging is useful in particular for the uranium reserves that cannot be delineated from the surface due to deep intersection.
- Full Text:
- Date Issued: 2015
- Authors: Ledwaba, Lebogang John
- Date: 2015
- Subjects: Energy minerals -- South Africa -- Springbok Flats (Limpopo) , Geochemistry , Prospecting -- Geophysical methods , Coal -- South Africa -- Springbok Flats (Limpopo) , Uranium -- South Africa -- Springbok Flats (Limpopo) , Coalbed methane -- South Africa -- Springbok Flats (Limpopo)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5092 , http://hdl.handle.net/10962/d1019880
- Description: This study is informed by the rising demand for power needs in South Africa and aims at understanding the geophysical and geochemical characteristics of the energy minerals in the Springbok Flats Basin and relating them to the prevailing geological and structural setting for improved exploration targeting. The Springbok Flats Basin is part of the Karoo sediments and host to uranium, coal and coal bed methane (CBM) resources. The lithology sections in the basin indicate presence of basaltic lavas at the top, underlain by mudrocks, siltstones, sandstones, conglomerates and diamictite, with interbedded coal beds occasionally. The coals are uraniferous and shale bounded and of lower Beaufort age at 250 Ma. The regional radiometric data identifies the regional extent of the Springbok Flats Basin as a basin with low total count values. This information is useful in exploration as it gives an idea of the limits of the area where to focus application for prospecting licenses. The reduced to pole of the total magnetic field, residuals and first vertical derivative maps clearly show the high magnetic susceptibility nature of the surrounding Bushveld rocks as compared to the low Karoo sediment susceptibility within the basin. There are distinct ring shaped picks within the basin possibly due to known Karoo dolerite sills in particular to the central south western part of the grid. The regional geochemical mapping program is a cost-effective way of providing an overview of the relative abundance levels, regional trends and anomalous patterns in the underlying lithological units. Background values of elements in soils over different lithological units and the identification of anomalous values relative to these elements can easily be identified. The geochemical results show an excellent correlation between soil chemistry and underlying geological formations. A few distinct gravity highs are clearly shown within the basin. Assuming the effect of the Letaba basalt to the gravity readings is uniform across the basin; these distinct anomalies could be due to Karoo dolerite sills as they coincide with areas of distinct high magnetic signature. A conceptual model was generated assuming that the Karoo sediments’ layering is uniform across the gravity profile but changes in the residual are due to an increased thickness of the sill supported by the gentle changes on the surface topography. Satellite imagery has got its challenges especially in areas of vegetation but it does provide a very useful tool in exploration. A number of spectral analysis techniques and band rations can be used to differentiate the areas underlain by the Letaba basalts, the Karoo sandstones/shale and Bushveld granites for mapping purposes. The priority focus will be on the shallower Karoo sediments because of the potential for cheaper mining. Exploration targeting needs to be guided by observed geochemical and geophysical characteristics in order to prioritize areas taking into account the presence of Karoo intrusives such as the dolerite sills that tend to devolatize the coal hence affecting the quality/rank. Structures and gravity signatures are very important in delineating areas with thick sediments that have a potential for CBM. The same understanding in targeting goes a long way in planning drill holes, resource modelling and pre-feasibility stages for mine planning. A high resolution airborne geophysical survey is recommended over the basin to better resolve structures. Geophysical borehole logging is recommended to be part of the exploration drilling programs in the Springbok Flats Basin in order to define the in-situ geophysical characteristics. Geophysical logging is useful in particular for the uranium reserves that cannot be delineated from the surface due to deep intersection.
- Full Text:
- Date Issued: 2015
Gold mineralisation at Masumbi Au-Cu Prospect, west Kenya : implication for gold exploration in the Archaean Ndori Greenstone Belt of Kenya
- Authors: Salimo, Luckmore
- Date: 2014
- Subjects: Gold mines and mining -- Kenya -- Nyanza Province , Copper -- Kenya -- Nyanza Province , Prospecting -- Kenya -- Nyanza Province , Chalcopyrite -- Kenya -- Nyanza Province , Metamorphism (Geology) , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5096 , http://hdl.handle.net/10962/d1020961
- Description: The Masumbi Au-Cu deposit in the Ndori Greenstone Belt of western Kenya is hosted in dacitic volcanics of the Nyanzian Group (2710 ± 340 Ma) and dioritic to granodioritic felsic intrusives (2504 ± 48 Ma). The deposit is characterised by gold and copper mineralisation that is associated with quartz-sulphide veins and veinlets. The copper mineralisation typically occurs as chalcopyrite. Gold is closely associated with pyrite in mineralogy and its pathfinder elements silver, bismuth, tellurium and selenium in geochemistry. The gold occurs in two forms that may indicate two generations of precipitation: the equant and the elongate forms. Based on Au/Ag ratios, the equant gold grains can be classified as native gold as their gold content is greater than 90 wt%. The elongate gold grains can be classified as electrums as their silver content is greater than 38 wt%. While there is a strong Au-Ag association within individual gold grains supporting an orogenic model for the gold mineralisation, mineralisation at the Masumbi Prospect appears atypical of Archaean orogenic gold deposits because of the abundance of copper (up to 0.43%). The enrichment of silver, copper, bismuth and tellurium in ore assemblages is common in porphyry, VMS and epithermal systems, but their presence at Masumbi does not preclude the formation as an orogenic deposit. Assay results from three Masumbi diamond drill-holes show an apparent correlation between gold and copper. However, petrography and electron probe microanalyses results from this study indicate that chalcopyrite is an earlier phase than pyrite as it occasionally occurs as inclusions in pyrite. This petrogenetic relationship between pyrite and chalcopyrite suggests that there is no temporal relationship between gold and copper mineralisation. Statistical analysis of the assays shows no linear correlation between gold and copper thereby supporting the above findings. The gold and copper mineralisation have been interpreted as forming as two separate events with copper forming first followed by gold. These events are both related to the intrusion of the felsic rocks that are associated with the Aruan metamorphic event that has been responsible for the bulk of the gold mineralisation on the Tanzanian Craton. The common alteration assemblage in the Masumbi rocks comprises chlorite and epidote. This alteration assemblage is typical of regional greenschist metamorphic facies grading into amphibolite metamorphic facies in the Nyanzian Group of Kenya. However, these alteration minerals could possibly be products of propylitic alteration in the rock groundmass. Other alteration mineral assemblages, possibly of hydrothermal origin, comprise muscovite, sericite, quartz, carbonate, associated with the sulphides pyrite and chalcopyrite. Although the occurrence of gold appears to be controlled by the presence of pyrite, it is also associated with silicification. Exploration methods have been proposed to target undiscovered gold deposits in the Ndori Greenstone Belt that are similar to the Masumbi deposit. These methods could probably be applied to vein-type gold deposits in other granite-greenstone terranes in the Lake Victoria Goldfields.
- Full Text:
- Date Issued: 2014
- Authors: Salimo, Luckmore
- Date: 2014
- Subjects: Gold mines and mining -- Kenya -- Nyanza Province , Copper -- Kenya -- Nyanza Province , Prospecting -- Kenya -- Nyanza Province , Chalcopyrite -- Kenya -- Nyanza Province , Metamorphism (Geology) , Geochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5096 , http://hdl.handle.net/10962/d1020961
- Description: The Masumbi Au-Cu deposit in the Ndori Greenstone Belt of western Kenya is hosted in dacitic volcanics of the Nyanzian Group (2710 ± 340 Ma) and dioritic to granodioritic felsic intrusives (2504 ± 48 Ma). The deposit is characterised by gold and copper mineralisation that is associated with quartz-sulphide veins and veinlets. The copper mineralisation typically occurs as chalcopyrite. Gold is closely associated with pyrite in mineralogy and its pathfinder elements silver, bismuth, tellurium and selenium in geochemistry. The gold occurs in two forms that may indicate two generations of precipitation: the equant and the elongate forms. Based on Au/Ag ratios, the equant gold grains can be classified as native gold as their gold content is greater than 90 wt%. The elongate gold grains can be classified as electrums as their silver content is greater than 38 wt%. While there is a strong Au-Ag association within individual gold grains supporting an orogenic model for the gold mineralisation, mineralisation at the Masumbi Prospect appears atypical of Archaean orogenic gold deposits because of the abundance of copper (up to 0.43%). The enrichment of silver, copper, bismuth and tellurium in ore assemblages is common in porphyry, VMS and epithermal systems, but their presence at Masumbi does not preclude the formation as an orogenic deposit. Assay results from three Masumbi diamond drill-holes show an apparent correlation between gold and copper. However, petrography and electron probe microanalyses results from this study indicate that chalcopyrite is an earlier phase than pyrite as it occasionally occurs as inclusions in pyrite. This petrogenetic relationship between pyrite and chalcopyrite suggests that there is no temporal relationship between gold and copper mineralisation. Statistical analysis of the assays shows no linear correlation between gold and copper thereby supporting the above findings. The gold and copper mineralisation have been interpreted as forming as two separate events with copper forming first followed by gold. These events are both related to the intrusion of the felsic rocks that are associated with the Aruan metamorphic event that has been responsible for the bulk of the gold mineralisation on the Tanzanian Craton. The common alteration assemblage in the Masumbi rocks comprises chlorite and epidote. This alteration assemblage is typical of regional greenschist metamorphic facies grading into amphibolite metamorphic facies in the Nyanzian Group of Kenya. However, these alteration minerals could possibly be products of propylitic alteration in the rock groundmass. Other alteration mineral assemblages, possibly of hydrothermal origin, comprise muscovite, sericite, quartz, carbonate, associated with the sulphides pyrite and chalcopyrite. Although the occurrence of gold appears to be controlled by the presence of pyrite, it is also associated with silicification. Exploration methods have been proposed to target undiscovered gold deposits in the Ndori Greenstone Belt that are similar to the Masumbi deposit. These methods could probably be applied to vein-type gold deposits in other granite-greenstone terranes in the Lake Victoria Goldfields.
- Full Text:
- Date Issued: 2014
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