Mineralogical, geochemical and lead isotopic analysis of the lead mineralization of the Skorpion Deposit, south western Namibia
- Authors: Uazeua, Kakunauua
- Date: 2019
- Subjects: Zinc ores -- Namibia , Formations (Geology) -- Namibia , Mineralogy -- Namibia , Lead -- Metallurgy -- Namibia , Lead -- Isotopes -- Namibia
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/68391 , vital:29250
- Description: The Skorpion none-sulphide Zinc Deposit is located in the para-autochtonous Port Nolloth Zone of the Gariep Belt, which overlays the Lower-Proterozoic Orange River Group basement rocks (Corrans et al., 1993). Situated in close proximity to the larger Rosh Pinah Zn-Pb deposit, the Skorpion Deposit contained a resource of 24.6 Mt at 10.6 % Zn and unquantified Cu and Pb prior to mining. To date, zinc has been the only metal exploited, with minor amounts of copper as a by-product. This study aims at understanding the mineralogical composition of the Skorpion lead mineralization and understanding the relationship between lead and the major metals such as zinc and copper in order to form a basis for further work that could determine the potential of processing lead as a by-product. As part of the study, work was also done on lead isotopes mainly with the aim of understanding the mineralization genesis and to determine the differences between the Skorpion and Rosh Pinah deposit which rationalize the inferior economic potential of the Skorpion lead mineralization. Results of the study have shown that majority of the lead mineralization is hosted by the felsic metavolcanics as galena and subordinately in the metasiliciclastics as pyromorphite, a lead manganese phosphate. In terms of the mineral textures, the lead minerals appear to be mainly secondary phases that have been remobilized and reprecipitated around pyrite, within pyrite cracks and intergrown with minerals such as chalcocite and greenockite. Lead has been mainly concentrated along fault zones. The elevated pyromorphite concentrations tend to occur within gossanous zones in close association with iron and manganese oxides. These textures represent supergene enrichment of a sulphide proto ore. However, contrary to copper and zinc mineralization, lead was not remobilized far from the proto ore merely as a function of its poor mobility in acidic fluids (Reddy et al., 1995). This substantiates the concentration of secondary lead in the felsic metavolcanics and to a much lesser extent, in the metasiliciclastics. Both secondary zinc and copper were reprecipitated in the metasiliciclastics, further away from the sulphide proto ore, hosted mainly by the felsic metavolcanics. The average lead isotope ratios of 206Pb/204Pb (17.26), 207Pb/204Pb (15.60) and 208Pb/204Pb (37.42) resemble results provided by Frimmel (2004) for both the Skorpion and Rosh Pinah deposits. For the Skorpion samples from Frimmel (2004) had the following average ratios: 206Pb/204Pb (17.29), 207Pb/204Pb (15.59) and 208Pb/204Pb (37.51). The Rosh Pinah samples had the following average ratios: 206Pb/204Pb (17.17), 207Pb/204Pb (15.61) and 208Pb/204Pb (37.45). These results indicate lead derivation from the lower 2.0 Ga Eburnean pre-Gariep basement in agreement with and Frimmel et al. (2004). The host felsic metavolcanics might have been derived from melting of the basement rocks during the formation of the Adamastor Ocean. In comparison to the Rosh Pinah deposit lead isotope signatures, the Skorpion lead isotopes overlap with the Rosh Pinah deposit isotopes, but have a much narrower range. This is an indication of a much shorter lived and potentially faster mineralization event contrary to the SEDEX type Rosh Pinah deposit. The smaller tonnage of the Skorpion deposit, its inferior lead concentrations and the elevated radiogenic lead isotopes point toward a VMS deposit which was formed in a small graben fed by shallow conduits during a short lived mineralization event. Sedimentary rocks covered the forming deposit at a fast rate and impaired the deposit advancement. The interaction between the upper crustal rocks and the mineralizing fluids is what may have resulted in the elevated radiogenic lead signature. In contrast to this, SEDEX deposits such as the Rosh Pinah Deposit, are generally fed by deep seated conduits that allow more longer lived leaching of metals from the underlying basement rocks and generally allow minor influence from upper crustal rocks.
- Full Text:
- Date Issued: 2019
- Authors: Uazeua, Kakunauua
- Date: 2019
- Subjects: Zinc ores -- Namibia , Formations (Geology) -- Namibia , Mineralogy -- Namibia , Lead -- Metallurgy -- Namibia , Lead -- Isotopes -- Namibia
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/68391 , vital:29250
- Description: The Skorpion none-sulphide Zinc Deposit is located in the para-autochtonous Port Nolloth Zone of the Gariep Belt, which overlays the Lower-Proterozoic Orange River Group basement rocks (Corrans et al., 1993). Situated in close proximity to the larger Rosh Pinah Zn-Pb deposit, the Skorpion Deposit contained a resource of 24.6 Mt at 10.6 % Zn and unquantified Cu and Pb prior to mining. To date, zinc has been the only metal exploited, with minor amounts of copper as a by-product. This study aims at understanding the mineralogical composition of the Skorpion lead mineralization and understanding the relationship between lead and the major metals such as zinc and copper in order to form a basis for further work that could determine the potential of processing lead as a by-product. As part of the study, work was also done on lead isotopes mainly with the aim of understanding the mineralization genesis and to determine the differences between the Skorpion and Rosh Pinah deposit which rationalize the inferior economic potential of the Skorpion lead mineralization. Results of the study have shown that majority of the lead mineralization is hosted by the felsic metavolcanics as galena and subordinately in the metasiliciclastics as pyromorphite, a lead manganese phosphate. In terms of the mineral textures, the lead minerals appear to be mainly secondary phases that have been remobilized and reprecipitated around pyrite, within pyrite cracks and intergrown with minerals such as chalcocite and greenockite. Lead has been mainly concentrated along fault zones. The elevated pyromorphite concentrations tend to occur within gossanous zones in close association with iron and manganese oxides. These textures represent supergene enrichment of a sulphide proto ore. However, contrary to copper and zinc mineralization, lead was not remobilized far from the proto ore merely as a function of its poor mobility in acidic fluids (Reddy et al., 1995). This substantiates the concentration of secondary lead in the felsic metavolcanics and to a much lesser extent, in the metasiliciclastics. Both secondary zinc and copper were reprecipitated in the metasiliciclastics, further away from the sulphide proto ore, hosted mainly by the felsic metavolcanics. The average lead isotope ratios of 206Pb/204Pb (17.26), 207Pb/204Pb (15.60) and 208Pb/204Pb (37.42) resemble results provided by Frimmel (2004) for both the Skorpion and Rosh Pinah deposits. For the Skorpion samples from Frimmel (2004) had the following average ratios: 206Pb/204Pb (17.29), 207Pb/204Pb (15.59) and 208Pb/204Pb (37.51). The Rosh Pinah samples had the following average ratios: 206Pb/204Pb (17.17), 207Pb/204Pb (15.61) and 208Pb/204Pb (37.45). These results indicate lead derivation from the lower 2.0 Ga Eburnean pre-Gariep basement in agreement with and Frimmel et al. (2004). The host felsic metavolcanics might have been derived from melting of the basement rocks during the formation of the Adamastor Ocean. In comparison to the Rosh Pinah deposit lead isotope signatures, the Skorpion lead isotopes overlap with the Rosh Pinah deposit isotopes, but have a much narrower range. This is an indication of a much shorter lived and potentially faster mineralization event contrary to the SEDEX type Rosh Pinah deposit. The smaller tonnage of the Skorpion deposit, its inferior lead concentrations and the elevated radiogenic lead isotopes point toward a VMS deposit which was formed in a small graben fed by shallow conduits during a short lived mineralization event. Sedimentary rocks covered the forming deposit at a fast rate and impaired the deposit advancement. The interaction between the upper crustal rocks and the mineralizing fluids is what may have resulted in the elevated radiogenic lead signature. In contrast to this, SEDEX deposits such as the Rosh Pinah Deposit, are generally fed by deep seated conduits that allow more longer lived leaching of metals from the underlying basement rocks and generally allow minor influence from upper crustal rocks.
- Full Text:
- Date Issued: 2019
The geology of a portion of the country between Witvlei and Omitara, South West Africa
- Fey, P
- Authors: Fey, P
- Date: 1972
- Subjects: Petrology -- Namibia , Stratigraphy -- Namibia , Mineralogy -- Namibia , Geology -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5052 , http://hdl.handle.net/10962/d1011821
- Description: A brief account of the location and physical aspects of the region is followed by descriptions of mapping and laboratory techniques employed. Recent ideas on regional stratigraphical correlation in South West Africa are critically reviewed. Strata lying southeast of the farm Losberg 105 have, on the basis of lithology and copper mineralisation, been correlated with the Tsumis Formation. The Hasib Formation, of predominantly marine character, has on structural grounds been excluded from the Damara System. The latter here has a greater thickness than elsewhere in South West Africa, unless isoclinal folding is much more prevalent than has been assumed. The occurrence on Eintracht 118 of a pebble conglomerate, tentatively equated with the Chuos Tillite, makes possible a subdivision of the Damara strata into the various series established in the literature. It has been found possible to differentiate between Kamtsas and Damara quartzites on petrological grounds. Further, it is concluded that the bulk of Hakos carbonate rocks originated as dolomites and have subsequently been dedolomitized to a greater or lesser extent. The area contains both ortho- and para-amphibolites, as well as one occurrence of intrusive granite. Evidence is given for at least three periods of deformation. It is oonsidered that, if the Hosib Formation was involved in a pre-Damara orogenic episode, later folding must have been co-axial with this. Sedimentation and metamorphism are treated in broad outline. There appears to have been a deepening of the basin of deposition from Hasib to Damara times. Cyclicity in sedimentation is evidenced by lithological associations in the Damara strata. The entire area falls into the greenschist facies of regional metamorphism. Superficial deposits include river gravel and, silt, quartzite- and vein quartz-rubble, calcrete and Kalahari sand. The economic geology is described with special reference to the widespread copper mineralisation.
- Full Text:
- Date Issued: 1972
- Authors: Fey, P
- Date: 1972
- Subjects: Petrology -- Namibia , Stratigraphy -- Namibia , Mineralogy -- Namibia , Geology -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5052 , http://hdl.handle.net/10962/d1011821
- Description: A brief account of the location and physical aspects of the region is followed by descriptions of mapping and laboratory techniques employed. Recent ideas on regional stratigraphical correlation in South West Africa are critically reviewed. Strata lying southeast of the farm Losberg 105 have, on the basis of lithology and copper mineralisation, been correlated with the Tsumis Formation. The Hasib Formation, of predominantly marine character, has on structural grounds been excluded from the Damara System. The latter here has a greater thickness than elsewhere in South West Africa, unless isoclinal folding is much more prevalent than has been assumed. The occurrence on Eintracht 118 of a pebble conglomerate, tentatively equated with the Chuos Tillite, makes possible a subdivision of the Damara strata into the various series established in the literature. It has been found possible to differentiate between Kamtsas and Damara quartzites on petrological grounds. Further, it is concluded that the bulk of Hakos carbonate rocks originated as dolomites and have subsequently been dedolomitized to a greater or lesser extent. The area contains both ortho- and para-amphibolites, as well as one occurrence of intrusive granite. Evidence is given for at least three periods of deformation. It is oonsidered that, if the Hosib Formation was involved in a pre-Damara orogenic episode, later folding must have been co-axial with this. Sedimentation and metamorphism are treated in broad outline. There appears to have been a deepening of the basin of deposition from Hasib to Damara times. Cyclicity in sedimentation is evidenced by lithological associations in the Damara strata. The entire area falls into the greenschist facies of regional metamorphism. Superficial deposits include river gravel and, silt, quartzite- and vein quartz-rubble, calcrete and Kalahari sand. The economic geology is described with special reference to the widespread copper mineralisation.
- Full Text:
- Date Issued: 1972
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