Singly and Doubly N-Confused Calix [4] phyrin Organoplatinum (II) Complexes as Near-IR Triplet Sensitizers
- Pushpanandan, Poornenth, Maurya, Yogesh Kumar, Omagari, Toshihiro, Hirosawa, Ryuji, Ishida, Masatoshi, Mori, Shigeki, Yasutake, Yuhsuke, Fukatsu, Susumu, Mack, John, Nyokong, Tebello, Furuta, Hiroyuki
- Authors: Pushpanandan, Poornenth , Maurya, Yogesh Kumar , Omagari, Toshihiro , Hirosawa, Ryuji , Ishida, Masatoshi , Mori, Shigeki , Yasutake, Yuhsuke , Fukatsu, Susumu , Mack, John , Nyokong, Tebello , Furuta, Hiroyuki
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/233144 , vital:50061 , xlink:href="https://doi.org/10.1021/acs.inorgchem.7b02047"
- Description: Organoplatinum(II) complexes of calix[4]phyrin analogues, singly N-confused calix[4]phyrin (Pt-2), and doubly N-confused calix[4]phyrin (Pt-3), were synthesized and characterized. The explicit structures of these organoplatinum(II) complexes were elucidated by single-crystal X-ray diffraction and spectroscopic studies. The introduction of N-confused pyrrole rings to the parent calix[4]phyrin scaffold was found to have profound effects on the photophysical properties, such as the bathochromic shifts of both the absorption and phosphorescence maxima. The triplet excited state properties of these platinum complexes were analyzed by DFT calculations at the B3LYP level. The organoplatinum(II) complexes derived from the deformed scaffolds can serve as potent triplet sensitizers for singlet oxygen generation under aerobic conditions.
- Full Text:
- Date Issued: 2017
- Authors: Pushpanandan, Poornenth , Maurya, Yogesh Kumar , Omagari, Toshihiro , Hirosawa, Ryuji , Ishida, Masatoshi , Mori, Shigeki , Yasutake, Yuhsuke , Fukatsu, Susumu , Mack, John , Nyokong, Tebello , Furuta, Hiroyuki
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/233144 , vital:50061 , xlink:href="https://doi.org/10.1021/acs.inorgchem.7b02047"
- Description: Organoplatinum(II) complexes of calix[4]phyrin analogues, singly N-confused calix[4]phyrin (Pt-2), and doubly N-confused calix[4]phyrin (Pt-3), were synthesized and characterized. The explicit structures of these organoplatinum(II) complexes were elucidated by single-crystal X-ray diffraction and spectroscopic studies. The introduction of N-confused pyrrole rings to the parent calix[4]phyrin scaffold was found to have profound effects on the photophysical properties, such as the bathochromic shifts of both the absorption and phosphorescence maxima. The triplet excited state properties of these platinum complexes were analyzed by DFT calculations at the B3LYP level. The organoplatinum(II) complexes derived from the deformed scaffolds can serve as potent triplet sensitizers for singlet oxygen generation under aerobic conditions.
- Full Text:
- Date Issued: 2017
Situated learning in relation to human conduct and social-ecological change
- Authors: O’Donoghue, R
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436278 , vital:73254 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_2
- Description: This chapter traces how education has developed to provide orientation in a modern world that is characterised by emerging risk. It examines how ESD initially developed as a modernist process to enable social reorientation and has been centred on problem-solving engagement in relation to issues and risk. The intractable complexity of most social-ecological problems has meant that change-orientated and transformative imagi-naries arising in learning are not easily realised in tangible change to resolve the problems at hand. The chapter thus poses the question, “Is ESD as situated learning with trans-gressive social-ecological reorientation possible?” To address this question, the study reviews ESD as a reflexive social process in modernity and tracks some of the expansive trajectories in the developing field over the last 10 years of the UN Decade of Education for Sustainable Development in Southern Africa.
- Full Text:
- Date Issued: 2017
- Authors: O’Donoghue, R
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436278 , vital:73254 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_2
- Description: This chapter traces how education has developed to provide orientation in a modern world that is characterised by emerging risk. It examines how ESD initially developed as a modernist process to enable social reorientation and has been centred on problem-solving engagement in relation to issues and risk. The intractable complexity of most social-ecological problems has meant that change-orientated and transformative imagi-naries arising in learning are not easily realised in tangible change to resolve the problems at hand. The chapter thus poses the question, “Is ESD as situated learning with trans-gressive social-ecological reorientation possible?” To address this question, the study reviews ESD as a reflexive social process in modernity and tracks some of the expansive trajectories in the developing field over the last 10 years of the UN Decade of Education for Sustainable Development in Southern Africa.
- Full Text:
- Date Issued: 2017
Solvent effect on the third-order nonlinear optical properties of α-and β-tertbutyl phenoxy-substituted tin (IV) chloride phthalocyanines
- Louzada, Marcel, Britton, Jonathan, Nyokong, Tebello, Khene, Samson M
- Authors: Louzada, Marcel , Britton, Jonathan , Nyokong, Tebello , Khene, Samson M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188910 , vital:44797 , xlink:href="https://doi.org/10.1021/acs.jpca.7b07349"
- Description: This paper investigates the third-order nonlinear optical properties of 4α-(4-tert-butylphenoxy) phthalocyaninato dichlorotin(IV) (α-SnOtBpPc) and 4β-(4-tert-butylphenoxy) phthalocyaninato dichlorotin(IV) (β-SnOtBpPc) in different organic solvents. The third-order susceptibilities of α-SnOtBpPc and βSnOtBpPc are reported in different solvents, using Z-scan techniques with 10 ns laser pulses at 532 nm. Their nonlinear absorption coefficient and absorption cross sections were also determined. The molecular imaginary components of the secondorder hyperpolarizability Im[γ] of α-SnOtBpPc and β-SnOtBpPc were found to be 2.60 × 10−31 and 2.94 × 10−31 esu (tetrahydrofuran), 2.12 × 10−31 and 2.54 × 10−31 esu (chloroform), 3.06 × 10−31 and 2.54 × 10−31 esu (dichloromethane), and 1.27 × 10−31 and 1.50 × 10−31 esu (toluene), respectively. This study found that substitution at the α position has an effect of lowering the two-photon (2PA) cross section value for α-SnOtBpPc compared to that for β-SnOtBpPc, with values of 64.30 and 456.65 GM, respectively. The large 2PA cross section observed in β-SnOtBpPc is attributed to the decreased energy difference between the virtual state and the LUMO.
- Full Text:
- Date Issued: 2017
- Authors: Louzada, Marcel , Britton, Jonathan , Nyokong, Tebello , Khene, Samson M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188910 , vital:44797 , xlink:href="https://doi.org/10.1021/acs.jpca.7b07349"
- Description: This paper investigates the third-order nonlinear optical properties of 4α-(4-tert-butylphenoxy) phthalocyaninato dichlorotin(IV) (α-SnOtBpPc) and 4β-(4-tert-butylphenoxy) phthalocyaninato dichlorotin(IV) (β-SnOtBpPc) in different organic solvents. The third-order susceptibilities of α-SnOtBpPc and βSnOtBpPc are reported in different solvents, using Z-scan techniques with 10 ns laser pulses at 532 nm. Their nonlinear absorption coefficient and absorption cross sections were also determined. The molecular imaginary components of the secondorder hyperpolarizability Im[γ] of α-SnOtBpPc and β-SnOtBpPc were found to be 2.60 × 10−31 and 2.94 × 10−31 esu (tetrahydrofuran), 2.12 × 10−31 and 2.54 × 10−31 esu (chloroform), 3.06 × 10−31 and 2.54 × 10−31 esu (dichloromethane), and 1.27 × 10−31 and 1.50 × 10−31 esu (toluene), respectively. This study found that substitution at the α position has an effect of lowering the two-photon (2PA) cross section value for α-SnOtBpPc compared to that for β-SnOtBpPc, with values of 64.30 and 456.65 GM, respectively. The large 2PA cross section observed in β-SnOtBpPc is attributed to the decreased energy difference between the virtual state and the LUMO.
- Full Text:
- Date Issued: 2017
Strengthening teachers’ knowledge and practices through a biodiversity education professional development programme
- Songqwaru, Zintle, Shava, Soul
- Authors: Songqwaru, Zintle , Shava, Soul
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436294 , vital:73255 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_15
- Description: What constitutes adequate teacher professional development support that enables teachers to engage meaningfully with ESD learning processes? In an attempt to answer this question, this chapter focuses on how continuing teacher profes-sional development programmes can support teachers of Life Sciences to teach biodiversity as a grounding concept to strengthen educational quality and relevance of Life Sciences education. It reflects on how continuing teacher professional development programmes may be designed and implemented to support South African teachers to work creatively with a con-tent and assessment-referenced national school curriculum. The chapter focuses on what content knowledge, teaching and assessment approaches to include as well as teachers’ reflections on the impacts of such a programme.
- Full Text:
- Date Issued: 2017
- Authors: Songqwaru, Zintle , Shava, Soul
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436294 , vital:73255 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_15
- Description: What constitutes adequate teacher professional development support that enables teachers to engage meaningfully with ESD learning processes? In an attempt to answer this question, this chapter focuses on how continuing teacher profes-sional development programmes can support teachers of Life Sciences to teach biodiversity as a grounding concept to strengthen educational quality and relevance of Life Sciences education. It reflects on how continuing teacher professional development programmes may be designed and implemented to support South African teachers to work creatively with a con-tent and assessment-referenced national school curriculum. The chapter focuses on what content knowledge, teaching and assessment approaches to include as well as teachers’ reflections on the impacts of such a programme.
- Full Text:
- Date Issued: 2017
Synthesis and photophysical studies of asymmetric zinc phthalocyanine–magnetic nanoparticle conjugates
- Matlou, Gauta G, Kobayashi, Nagao, Kimura, Mutsumi, Nyokong, Tebello
- Authors: Matlou, Gauta G , Kobayashi, Nagao , Kimura, Mutsumi , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232895 , vital:50036 , xlink:href="https://doi.org/10.1039/C7NJ01716B"
- Description: This work reports on the synthesis and amide bond linkage of carboxylic acid functionalized asymmetric zinc phthalocyanine (ZnPc) complexes to amino magnetic nanoparticles (AMNPs). The work further compares the photophysical and photochemical parameters of the Pc complexes alone with those linked to form ZnPc–AMNPs with further relation to the type of the spacer between the Pc and the AMNPs. Infrared spectroscopy confirmed the presence of the amide bond formed between the Pc complexes and the AMNPs. The triplet quantum yields ranged from 0.62 to 0.87. However, low singlet oxygen quantum yields were obtained due to competing pathways and the insufficient energy transfer from the excited triplet state of the ZnPc molecules to the molecular oxygen.
- Full Text:
- Date Issued: 2017
- Authors: Matlou, Gauta G , Kobayashi, Nagao , Kimura, Mutsumi , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232895 , vital:50036 , xlink:href="https://doi.org/10.1039/C7NJ01716B"
- Description: This work reports on the synthesis and amide bond linkage of carboxylic acid functionalized asymmetric zinc phthalocyanine (ZnPc) complexes to amino magnetic nanoparticles (AMNPs). The work further compares the photophysical and photochemical parameters of the Pc complexes alone with those linked to form ZnPc–AMNPs with further relation to the type of the spacer between the Pc and the AMNPs. Infrared spectroscopy confirmed the presence of the amide bond formed between the Pc complexes and the AMNPs. The triplet quantum yields ranged from 0.62 to 0.87. However, low singlet oxygen quantum yields were obtained due to competing pathways and the insufficient energy transfer from the excited triplet state of the ZnPc molecules to the molecular oxygen.
- Full Text:
- Date Issued: 2017
Synthesis of silver nanoparticles from a Desmodium adscendens extract and its antibacterial evaluation on wound dressing material
- Lakkakula, Jaya R, Ndinteh, Derek T, van Vuuren, Sandy F, Olivier, Denise K, Krause, Rui W M
- Authors: Lakkakula, Jaya R , Ndinteh, Derek T , van Vuuren, Sandy F , Olivier, Denise K , Krause, Rui W M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/195025 , vital:45520 , xlink:href="https://doi.org/10.1049/iet-nbt.2017.0084"
- Description: The one-pot synthesis of silver nanoparticles (AgNPs) using the medium-polar extract of Desmodium adscendens (Sw.) DC. is presented here as an alternative synthesis of metal NPs. Characterisation of the formed NPs showed polydispersed AgNPs ranging from 15 to 100 nm where the concentration of metal ions was found to play a role in the size and shape of the prepared NPs. It could be established that the flavonoids, saponins, and alkaloids present in the extract acted as both reducing and stabilising agents during the formation of the capped metal NPs. This means of NP synthesis was also employed during the in situ immobilisation of AgNPs on gauze and plaster. An evaluation of the antibacterial activity of the medium-polar D. adscendens extract, AgNPs suspended in solution, and the immobilised AgNPs against Staphylococcus aureus (ATCC 25923), Bacillus cereus (ATCC 11778), and Escherichia coli (ATCC 25922) showed high efficacy against the latter in particular. This suggests that gauze, dilute silver nitrate solutions, and D. adscendens extract could be used successfully in the simple in situ preparation of effective antibacterial wound dressings.
- Full Text:
- Date Issued: 2017
- Authors: Lakkakula, Jaya R , Ndinteh, Derek T , van Vuuren, Sandy F , Olivier, Denise K , Krause, Rui W M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/195025 , vital:45520 , xlink:href="https://doi.org/10.1049/iet-nbt.2017.0084"
- Description: The one-pot synthesis of silver nanoparticles (AgNPs) using the medium-polar extract of Desmodium adscendens (Sw.) DC. is presented here as an alternative synthesis of metal NPs. Characterisation of the formed NPs showed polydispersed AgNPs ranging from 15 to 100 nm where the concentration of metal ions was found to play a role in the size and shape of the prepared NPs. It could be established that the flavonoids, saponins, and alkaloids present in the extract acted as both reducing and stabilising agents during the formation of the capped metal NPs. This means of NP synthesis was also employed during the in situ immobilisation of AgNPs on gauze and plaster. An evaluation of the antibacterial activity of the medium-polar D. adscendens extract, AgNPs suspended in solution, and the immobilised AgNPs against Staphylococcus aureus (ATCC 25923), Bacillus cereus (ATCC 11778), and Escherichia coli (ATCC 25922) showed high efficacy against the latter in particular. This suggests that gauze, dilute silver nitrate solutions, and D. adscendens extract could be used successfully in the simple in situ preparation of effective antibacterial wound dressings.
- Full Text:
- Date Issued: 2017
Synthesis, photophysical and nonlinear optical properties of a series of ball-type phthalocyanines in solution and thin films
- Nwaji, Njemuwa, Mack, John, Britton, Jonathan, Nyokong, Tebello
- Authors: Nwaji, Njemuwa , Mack, John , Britton, Jonathan , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188976 , vital:44803 , xlink:href="https://doi.org/10.1039/C6NJ03662G"
- Description: In this study, we report on the enhanced nonlinear optical properties of novel tetrakis-4-(hexadecane-1,2-dioxyl)-bis(phthalocyaninato zinc(II)) (4), tetrakis-4-(hexadecane-1,2-dioxyl)-bis(phthalocyaninato gallium chloride) (5) and tetrakis-4-(hexadecane-1,2-dioxyl)-bis(phthalocyaninato indium chloride) (6) both in solution and when embedded in polymer thin films. Complexes 5 and 6 bearing heavy atoms showed enhanced triplet quantum yield and nonlinear optical response. The nonlinear third-order susceptibility and second-order hyperpolarizability values are also reported. Time dependent density functional theory (TD-DFT) calculations were performed in order to explain the origin of the observed UV-vis and magnetic circular dichroism (MCD) spectra of the complexes.
- Full Text:
- Date Issued: 2017
- Authors: Nwaji, Njemuwa , Mack, John , Britton, Jonathan , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188976 , vital:44803 , xlink:href="https://doi.org/10.1039/C6NJ03662G"
- Description: In this study, we report on the enhanced nonlinear optical properties of novel tetrakis-4-(hexadecane-1,2-dioxyl)-bis(phthalocyaninato zinc(II)) (4), tetrakis-4-(hexadecane-1,2-dioxyl)-bis(phthalocyaninato gallium chloride) (5) and tetrakis-4-(hexadecane-1,2-dioxyl)-bis(phthalocyaninato indium chloride) (6) both in solution and when embedded in polymer thin films. Complexes 5 and 6 bearing heavy atoms showed enhanced triplet quantum yield and nonlinear optical response. The nonlinear third-order susceptibility and second-order hyperpolarizability values are also reported. Time dependent density functional theory (TD-DFT) calculations were performed in order to explain the origin of the observed UV-vis and magnetic circular dichroism (MCD) spectra of the complexes.
- Full Text:
- Date Issued: 2017
The contradictory conceptions of research in historically black universities
- Muthama, Evelyn, McKenna, Sioux
- Authors: Muthama, Evelyn , McKenna, Sioux
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187183 , vital:44577 , xlink:href="http://dx.doi. org/10.18820/2519593X/pie. v35i1.10"
- Description: Research is conceptualised in multiple and contradictory ways within and across Historically Black Universities (HBUs) with consequences for knowledge production. Under the apartheid regime, research was deliberately underdeveloped in such institutions and this continues to have an impact. We argue that if HBUs are to move from the constraints of the past into the possibilities of the future, there is a need for a thorough understanding both of how research is currently conceptualised, and of the consequences of such conceptions for research output. We used a critical discourse analysis of interviews, documents and survey data from seven HBUs to identify the dominant discourses about the purposes of research. The findings are four dominant conceptions of research that sometimes contradict each other across and within the HBUs. These are research as integral to academic identity; research for social justice; research as an economic driver and research as an instrumentalist requirement for job security, promotion and incentives. These conceptions seemed to emerge in part because of the history of the institutions and create both constraining and enabling effects on research production.
- Full Text:
- Date Issued: 2017
- Authors: Muthama, Evelyn , McKenna, Sioux
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187183 , vital:44577 , xlink:href="http://dx.doi. org/10.18820/2519593X/pie. v35i1.10"
- Description: Research is conceptualised in multiple and contradictory ways within and across Historically Black Universities (HBUs) with consequences for knowledge production. Under the apartheid regime, research was deliberately underdeveloped in such institutions and this continues to have an impact. We argue that if HBUs are to move from the constraints of the past into the possibilities of the future, there is a need for a thorough understanding both of how research is currently conceptualised, and of the consequences of such conceptions for research output. We used a critical discourse analysis of interviews, documents and survey data from seven HBUs to identify the dominant discourses about the purposes of research. The findings are four dominant conceptions of research that sometimes contradict each other across and within the HBUs. These are research as integral to academic identity; research for social justice; research as an economic driver and research as an instrumentalist requirement for job security, promotion and incentives. These conceptions seemed to emerge in part because of the history of the institutions and create both constraining and enabling effects on research production.
- Full Text:
- Date Issued: 2017
The contribution of NTFP trade to rural livelihoods in different agro-ecological zones of South Africa
- Mugido, Worship, Shackleton, Charlie M
- Authors: Mugido, Worship , Shackleton, Charlie M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398370 , vital:69404 , xlink:href="https://doi.org/10.1505/146554817821865063"
- Description: In South Africa, there is extensive NTFP trade within communities and via external markets. However, there is a limited indication of the proportion of all households trading one or more NTFPs, and how it varies in relation to local context. Therefore, this study sought to establish the proportion of households trading in NTFPs in sites of different distances to urban markets and agro-ecological zones of South Africa. The results showed that about 6.4% households reported selling NTFPs for various reasons, with many (22%) citing the need to earn cash income and limited employment opportunities (16.9%). Even though the returns from trading NTFPs are relatively low, every earning is very important to many cash-strapped rural households. This was demonstrated by the fact that many sellers of NTFPs used their earnings to augment household income and cover their living expenses.
- Full Text: false
- Date Issued: 2017
- Authors: Mugido, Worship , Shackleton, Charlie M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398370 , vital:69404 , xlink:href="https://doi.org/10.1505/146554817821865063"
- Description: In South Africa, there is extensive NTFP trade within communities and via external markets. However, there is a limited indication of the proportion of all households trading one or more NTFPs, and how it varies in relation to local context. Therefore, this study sought to establish the proportion of households trading in NTFPs in sites of different distances to urban markets and agro-ecological zones of South Africa. The results showed that about 6.4% households reported selling NTFPs for various reasons, with many (22%) citing the need to earn cash income and limited employment opportunities (16.9%). Even though the returns from trading NTFPs are relatively low, every earning is very important to many cash-strapped rural households. This was demonstrated by the fact that many sellers of NTFPs used their earnings to augment household income and cover their living expenses.
- Full Text: false
- Date Issued: 2017
The culture hut concept as curriculum innovation: Engaging the dialectic nature of heritage in Zimbabwean schools to support ESD learning
- Authors: Zazu, Cryton
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436895 , vital:73314 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_5
- Description: Influenced by Zimbabwe’s cultural policy of 2004, the culture hut concept entails the establishment of a culture hut or village within schools as a curriculum innovation aimed at promoting the teaching and learning of culture within the country’s formal education system. The culture hut is representative of what can be viewed as a ‘mini cultural museum’ in which cultural ar-tefacts and objects are displayed. All schools in Zimbabwe are, therefore, as a matter of policy expected to have a culture hut; hence the culture hut concept itself as a curriculum innovation has, since 2004, became popular in the country. Despite its popularity, little research has been done to evaluate how this curriculum innovation is adding value to Zimbabwe’s education system. It is against this background that this chapter interro-gates the culture hut concept in Zimbabwe, pointing out some of the shortfalls in its current application and highlighting how, if carefully constituted, such curriculum innovation can foster the type of learning envisaged within the Education for Sus-tainable Development (ESD) framework. This chapter, as much as it provides a critique of how the culture hut concept is being used in Zimbabwean schools, also points to what could be done to reconstitute and use this curriculum innovation in ways that support more ESD learning.
- Full Text:
- Date Issued: 2017
- Authors: Zazu, Cryton
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436895 , vital:73314 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_5
- Description: Influenced by Zimbabwe’s cultural policy of 2004, the culture hut concept entails the establishment of a culture hut or village within schools as a curriculum innovation aimed at promoting the teaching and learning of culture within the country’s formal education system. The culture hut is representative of what can be viewed as a ‘mini cultural museum’ in which cultural ar-tefacts and objects are displayed. All schools in Zimbabwe are, therefore, as a matter of policy expected to have a culture hut; hence the culture hut concept itself as a curriculum innovation has, since 2004, became popular in the country. Despite its popularity, little research has been done to evaluate how this curriculum innovation is adding value to Zimbabwe’s education system. It is against this background that this chapter interro-gates the culture hut concept in Zimbabwe, pointing out some of the shortfalls in its current application and highlighting how, if carefully constituted, such curriculum innovation can foster the type of learning envisaged within the Education for Sus-tainable Development (ESD) framework. This chapter, as much as it provides a critique of how the culture hut concept is being used in Zimbabwean schools, also points to what could be done to reconstitute and use this curriculum innovation in ways that support more ESD learning.
- Full Text:
- Date Issued: 2017
The effect of point of substitution and silver based nanoparticles on the photophysical and optical nonlinearity of indium carboxyphenoxy phthalocyanine
- Oluwole, David O, Ngxeke, Sixolisile M, Britton, Jonathan, Nyokong, Tebello
- Authors: Oluwole, David O , Ngxeke, Sixolisile M , Britton, Jonathan , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188596 , vital:44768 , xlink:href="https://doi.org/10.1016/j.jphotochem.2017.07.032"
- Description: Indium(III) chloride 1,8(11),15(18),22(25)-tetra-(3-carboxyphenoxy) phthalocyanine (1) and indium(III) chloride 2,9(10),16(17),23(24)-tetra–(3-carboxyphenoxy) phthalocyanine (2) were covalently linked to glutathione capped silver nanoparticles (AgNPs–GSH) and silver selenide/zinc sulfide (Ag2Se/ZnS–GSH) quantum dots via amide bond formation. The photophysical and nonlinear optical behaviour of the metallophthalocyanines and their conjugates with nanoparticles were investigated using the open aperture Z–scan technique. Complex 2 showed enhanced photophysical properties compared to 1. The conjugates revealed improved triplet state quantum yields (except for 1-AgNPs-GSH which afforded lower triplet state quantum yields in comparison to 1) and nonlinear optical activities in comparison to the Pc complexes. The synthesized complexes, nanoparticles and their conjugates could be potential nonlinear optical materials due to their good nonlinear optical activities.
- Full Text:
- Date Issued: 2017
- Authors: Oluwole, David O , Ngxeke, Sixolisile M , Britton, Jonathan , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188596 , vital:44768 , xlink:href="https://doi.org/10.1016/j.jphotochem.2017.07.032"
- Description: Indium(III) chloride 1,8(11),15(18),22(25)-tetra-(3-carboxyphenoxy) phthalocyanine (1) and indium(III) chloride 2,9(10),16(17),23(24)-tetra–(3-carboxyphenoxy) phthalocyanine (2) were covalently linked to glutathione capped silver nanoparticles (AgNPs–GSH) and silver selenide/zinc sulfide (Ag2Se/ZnS–GSH) quantum dots via amide bond formation. The photophysical and nonlinear optical behaviour of the metallophthalocyanines and their conjugates with nanoparticles were investigated using the open aperture Z–scan technique. Complex 2 showed enhanced photophysical properties compared to 1. The conjugates revealed improved triplet state quantum yields (except for 1-AgNPs-GSH which afforded lower triplet state quantum yields in comparison to 1) and nonlinear optical activities in comparison to the Pc complexes. The synthesized complexes, nanoparticles and their conjugates could be potential nonlinear optical materials due to their good nonlinear optical activities.
- Full Text:
- Date Issued: 2017
The effects of expansive shrubs on plant species richness and soils in semi-arid communal lands, South Africa
- Sholto-Douglas, Craig, Shackleton, Charlie M, Ruwanza, Sheunesu, Dold, Tony
- Authors: Sholto-Douglas, Craig , Shackleton, Charlie M , Ruwanza, Sheunesu , Dold, Tony
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398394 , vital:69408 , xlink:href="https://doi.org/10.1002/ldr.2745"
- Description: Expansion by expansive species can have severe ecological, social and economic impacts through the reduction of ecosystem goods and services and species richness. However, expansion by expansive species may also offer benefits to ecosystems and humans, through the supply of ecosystem goods and services (such as firewood, fodder and fruits), as well as potentially offering refugia in heavily used landscapes. Here, we examine the effects of four expansive dwarf shrub species (Aspalathus subtingens, Dicerothamnus rhinocerotis, Pteronia incana and Oedera genistifolia) on plant species richness (at the point scale), vegetation cover, soil properties and whether the expansive species offer refugia to other species. Plant species richness, cover and soil properties were recorded in 1-m2 quadrats located within a mosaic of expanded and non-expanded patches for the four expansive shrub species. Plant species richness was significantly higher in the non-expanded areas compared to the expanded ones for all four expansive species. Some of the expansive shrubs provided refugia to certain plant species and limited the frequency of other species. With regard to species composition, there was little separation of expanded and non-expanded samples within sites, indicating that the site factors were stronger determinants of plant species richness and composition than expansion. Therefore, it is more likely that the reduction in species richness in expanded sites is caused by multiple drivers, including vegetation attributes cover, litter cover and soil nutrients (organic C, Zn and P) and soil compaction.
- Full Text:
- Date Issued: 2017
- Authors: Sholto-Douglas, Craig , Shackleton, Charlie M , Ruwanza, Sheunesu , Dold, Tony
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398394 , vital:69408 , xlink:href="https://doi.org/10.1002/ldr.2745"
- Description: Expansion by expansive species can have severe ecological, social and economic impacts through the reduction of ecosystem goods and services and species richness. However, expansion by expansive species may also offer benefits to ecosystems and humans, through the supply of ecosystem goods and services (such as firewood, fodder and fruits), as well as potentially offering refugia in heavily used landscapes. Here, we examine the effects of four expansive dwarf shrub species (Aspalathus subtingens, Dicerothamnus rhinocerotis, Pteronia incana and Oedera genistifolia) on plant species richness (at the point scale), vegetation cover, soil properties and whether the expansive species offer refugia to other species. Plant species richness, cover and soil properties were recorded in 1-m2 quadrats located within a mosaic of expanded and non-expanded patches for the four expansive shrub species. Plant species richness was significantly higher in the non-expanded areas compared to the expanded ones for all four expansive species. Some of the expansive shrubs provided refugia to certain plant species and limited the frequency of other species. With regard to species composition, there was little separation of expanded and non-expanded samples within sites, indicating that the site factors were stronger determinants of plant species richness and composition than expansion. Therefore, it is more likely that the reduction in species richness in expanded sites is caused by multiple drivers, including vegetation attributes cover, litter cover and soil nutrients (organic C, Zn and P) and soil compaction.
- Full Text:
- Date Issued: 2017
The photophysical studies of Pluronic F127/P123 micelle mixture system loaded with metal free and Zn 5, 10, 15, 20-tetrakis [4-(benzyloxy) phenyl] porphyrins
- Managa, Muthumuni, Ngoy, Bokolombe P, Nyokong, Tebello
- Authors: Managa, Muthumuni , Ngoy, Bokolombe P , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188932 , vital:44799 , xlink:href="https://doi.org/10.1016/j.jphotochem.2017.02.018"
- Description: Binary mixtures of Pluronics are studied as drug nanocarriers in this work. H2 and Zn 5,10,15,20-tetrakis[4-(benzyloxy) phenyl] porphyrin were encapsulated onto binary micelle mixture of Pluronic F127/P123. The fluorescence and singlet oxygen generating behaviour of the porphyrins were investigated following incorporation. The fluorescence quantum yield for H2TBnOPP (ΦF = 0.034) was higher than that of ZnTBnOPP (ΦF = 0.023) and decreased when ZnTBnOPP or H2TBnOPP when in the presence of Pluronic F127/P123 binary mixtures. The kq values were 2.8 × 108 and 3.7 × 108 M−1 s−1, for H2TBnOPP + Pluronic F127/P123 and ZnTBnOPP + Pluronic F127/P123 in water, respectively. The binding constants (Kb) were 1.58 × 105 M−1 and 1.02 × 105 M−1 for ZnTBnOPP + Pluronic F127/P123 and H2TBnOPP + Pluronic F127/P123, respectively.
- Full Text:
- Date Issued: 2017
- Authors: Managa, Muthumuni , Ngoy, Bokolombe P , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188932 , vital:44799 , xlink:href="https://doi.org/10.1016/j.jphotochem.2017.02.018"
- Description: Binary mixtures of Pluronics are studied as drug nanocarriers in this work. H2 and Zn 5,10,15,20-tetrakis[4-(benzyloxy) phenyl] porphyrin were encapsulated onto binary micelle mixture of Pluronic F127/P123. The fluorescence and singlet oxygen generating behaviour of the porphyrins were investigated following incorporation. The fluorescence quantum yield for H2TBnOPP (ΦF = 0.034) was higher than that of ZnTBnOPP (ΦF = 0.023) and decreased when ZnTBnOPP or H2TBnOPP when in the presence of Pluronic F127/P123 binary mixtures. The kq values were 2.8 × 108 and 3.7 × 108 M−1 s−1, for H2TBnOPP + Pluronic F127/P123 and ZnTBnOPP + Pluronic F127/P123 in water, respectively. The binding constants (Kb) were 1.58 × 105 M−1 and 1.02 × 105 M−1 for ZnTBnOPP + Pluronic F127/P123 and H2TBnOPP + Pluronic F127/P123, respectively.
- Full Text:
- Date Issued: 2017
The relevance of cross-scale connections and spatial interactions for ecosystem service delivery by protected areas: Insights from southern Africa
- de Vos, Alta, Cumming, Graeme S, Roux, Dirk J
- Authors: de Vos, Alta , Cumming, Graeme S , Roux, Dirk J
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416438 , vital:71348 , xlink:href="https://doi.org/10.1016/j.ecoser.2017.11.014"
- Description: The ecosystem services (ES) concept can frame the value of protected areas (PAs) to society and identify management actions that bridge biodiversity conservation and human benefits. In this special issue on ES flows to and from southern African PAs we consider two themes: (1) water as a biophysical and social-ecological connector; and (2) cross-scale interactions and connections as influences on cultural ecosystem service (CES) provision. Freshwater flows have supporting, regulating, and cultural elements, leading to complexities in governance as well as place attachment, intellectual, and recreational services. Scale dependence in CES creates trade-offs that challenge the usefulness of the ES framework for PA management. Ecosystem service production can potentially create political support for PAs and helps to build connections and feedbacks that increase PA resilience. Papers in the feature highlight a need to understand trade-offs in optimising for biodiversity vs. particular bundles of ES; impacts of investment in built infrastructure on ES use; how managers facilitate ES; scale and heterogeneity as influences; the role of adaptive monitoring of PAs as social–ecological systems; and services and benefits from PAs that are not well-articulated in ES classifications. PA research can thus add nuance, depth and substance to broader thinking around CES.
- Full Text:
- Date Issued: 2017
- Authors: de Vos, Alta , Cumming, Graeme S , Roux, Dirk J
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416438 , vital:71348 , xlink:href="https://doi.org/10.1016/j.ecoser.2017.11.014"
- Description: The ecosystem services (ES) concept can frame the value of protected areas (PAs) to society and identify management actions that bridge biodiversity conservation and human benefits. In this special issue on ES flows to and from southern African PAs we consider two themes: (1) water as a biophysical and social-ecological connector; and (2) cross-scale interactions and connections as influences on cultural ecosystem service (CES) provision. Freshwater flows have supporting, regulating, and cultural elements, leading to complexities in governance as well as place attachment, intellectual, and recreational services. Scale dependence in CES creates trade-offs that challenge the usefulness of the ES framework for PA management. Ecosystem service production can potentially create political support for PAs and helps to build connections and feedbacks that increase PA resilience. Papers in the feature highlight a need to understand trade-offs in optimising for biodiversity vs. particular bundles of ES; impacts of investment in built infrastructure on ES use; how managers facilitate ES; scale and heterogeneity as influences; the role of adaptive monitoring of PAs as social–ecological systems; and services and benefits from PAs that are not well-articulated in ES classifications. PA research can thus add nuance, depth and substance to broader thinking around CES.
- Full Text:
- Date Issued: 2017
The safety net function of NTFPs in different agro-ecological zones of South Africa
- Mugido, Worship, Shackleton, Charlie M
- Authors: Mugido, Worship , Shackleton, Charlie M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180111 , vital:43311 , xlink:href="https://doi.org/10.1007/s11111-017-0285-z"
- Description: Various South African studies have shown that rural households use NTFPs as safety nets in times of misfortune. However being focused on one or two sites, they do not show the prevalence of NTFP use as safety nets across multiple sites. In addition, they do not show the use of NTFPs as safety nets by rural households in different agro-ecological zones. The results of the study showed that about 79% of the total households interviewed experienced at least one shock of some magnitude in the previous 12 months. The most experienced shocks were illness, death, crop failure, and hunger. The households employed various coping strategies in response to different types of shocks, with the three widely used strategies being assistance from friends and relatives, using cash savings, and using NTFPs. Households in low agro-ecological zones used NTFPs as safety nets more than households in high agro-ecological zones.
- Full Text:
- Date Issued: 2017
- Authors: Mugido, Worship , Shackleton, Charlie M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180111 , vital:43311 , xlink:href="https://doi.org/10.1007/s11111-017-0285-z"
- Description: Various South African studies have shown that rural households use NTFPs as safety nets in times of misfortune. However being focused on one or two sites, they do not show the prevalence of NTFP use as safety nets across multiple sites. In addition, they do not show the use of NTFPs as safety nets by rural households in different agro-ecological zones. The results of the study showed that about 79% of the total households interviewed experienced at least one shock of some magnitude in the previous 12 months. The most experienced shocks were illness, death, crop failure, and hunger. The households employed various coping strategies in response to different types of shocks, with the three widely used strategies being assistance from friends and relatives, using cash savings, and using NTFPs. Households in low agro-ecological zones used NTFPs as safety nets more than households in high agro-ecological zones.
- Full Text:
- Date Issued: 2017
The Uptake of Education for Sustainable Development in Geography Curricula in South African Secondary Schools
- Authors: Dube, Carolina
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436319 , vital:73257 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_7
- Description: Curriculum innovation that took place in the post-apartheid era in South Africa provided opportunities for integrating environ-mental concerns and sustainability issues in subjects such as geography and science at further education and training level (FET). However, evidence from my PhD study in geography education at FET level shows that there are major challenges in the implementation of education for sustainable develop-ment (ESD) in the school context. These relate, firstly, to teachers’ lack of content knowledge (CK) and pedagogical content knowledge (PCK) and, secondly, to contextual issues and structural constraints within schools. In order to overcome some of the challenges, a standards-based teacher training model is recommended to ensure the mastery of appropriate competencies for the implementation of environmental educa-tion (EE) and ESD.
- Full Text:
- Date Issued: 2017
- Authors: Dube, Carolina
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436319 , vital:73257 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_7
- Description: Curriculum innovation that took place in the post-apartheid era in South Africa provided opportunities for integrating environ-mental concerns and sustainability issues in subjects such as geography and science at further education and training level (FET). However, evidence from my PhD study in geography education at FET level shows that there are major challenges in the implementation of education for sustainable develop-ment (ESD) in the school context. These relate, firstly, to teachers’ lack of content knowledge (CK) and pedagogical content knowledge (PCK) and, secondly, to contextual issues and structural constraints within schools. In order to overcome some of the challenges, a standards-based teacher training model is recommended to ensure the mastery of appropriate competencies for the implementation of environmental educa-tion (EE) and ESD.
- Full Text:
- Date Issued: 2017
The use of experimental design for the development of a capillary zone electrophoresis method for the quantitation of captopril
- Mukozhiwa, S Y, Khamanga, Sandile M, Walker, Roderick B
- Authors: Mukozhiwa, S Y , Khamanga, Sandile M , Walker, Roderick B
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183828 , vital:44073 , xlink:href="https://doi.org/10.1691/ph.2017.7071"
- Description: A capillary zone electrophoresis (CZE) method for the quantitation of captopril (CPT) using UV detection was developed. Influence of electrolyte concentration and system variables on electrophoretic separation was evaluated and a central composite design (CCD) was used to optimize the method. Variables investigated were pH, molarity, applied voltage and capillary length. The influence of sodium metabisulphite on the stability of test solutions was also investigated. The use of sodium metabisulphite prevented degradation of CPT over 24 hours. A fused uncoated silica capillary of 67.5cm total and 57.5 cm effective length was used for analysis. The applied voltage and capillary length affected the migration time of CPT significantly. A 20 mM phosphate buffer adjusted to pH 7.0 was used as running buffer and an applied voltage of 23.90 kV was suitable to effect a separation. The optimized electrophoretic conditions produced sharp, well-resolved peaks for CPT and sodium metabisulphite. Linear regression analysis of the response for CPT standards revealed the method was linear (R2 = 0.9995) over the range 5-70 μg/mL. The limits of quantitation and detection were 5 and 1.5 μg/mL. A simple, rapid and reliable CZE method has been developed and successfully applied to the analysis of commercially available CPT products.
- Full Text:
- Date Issued: 2017
- Authors: Mukozhiwa, S Y , Khamanga, Sandile M , Walker, Roderick B
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183828 , vital:44073 , xlink:href="https://doi.org/10.1691/ph.2017.7071"
- Description: A capillary zone electrophoresis (CZE) method for the quantitation of captopril (CPT) using UV detection was developed. Influence of electrolyte concentration and system variables on electrophoretic separation was evaluated and a central composite design (CCD) was used to optimize the method. Variables investigated were pH, molarity, applied voltage and capillary length. The influence of sodium metabisulphite on the stability of test solutions was also investigated. The use of sodium metabisulphite prevented degradation of CPT over 24 hours. A fused uncoated silica capillary of 67.5cm total and 57.5 cm effective length was used for analysis. The applied voltage and capillary length affected the migration time of CPT significantly. A 20 mM phosphate buffer adjusted to pH 7.0 was used as running buffer and an applied voltage of 23.90 kV was suitable to effect a separation. The optimized electrophoretic conditions produced sharp, well-resolved peaks for CPT and sodium metabisulphite. Linear regression analysis of the response for CPT standards revealed the method was linear (R2 = 0.9995) over the range 5-70 μg/mL. The limits of quantitation and detection were 5 and 1.5 μg/mL. A simple, rapid and reliable CZE method has been developed and successfully applied to the analysis of commercially available CPT products.
- Full Text:
- Date Issued: 2017
Towards professional learning communities: A review
- Tshiningayamwe, Sirkka, Songqwaru, Zintle
- Authors: Tshiningayamwe, Sirkka , Songqwaru, Zintle
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436305 , vital:73256 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_19
- Description: Professional learning communities (PLCs) have proven to be effective models of teachers’ professional development. Therefore, for effective Education for Sustainable Develop-ment (ESD), PLCs should be considered in the planning of teacher professional development initiatives. This will enable teachers to address issues of quality teaching, learning and sustainable development issues. In the South African context, a ‘professional learning community’ is an emerging policy con-cept. This chapter thus provides a review of the emergence of teacher clusters in South Africa using a reflexive spiral model and praxis tasks. The chapter also draws from the Namibian and South African teacher cluster literature to comment on how teacher clusters could potentially be translated into PLCs to transform teachers’ practices as they relate to ESD.
- Full Text:
- Date Issued: 2017
- Authors: Tshiningayamwe, Sirkka , Songqwaru, Zintle
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/436305 , vital:73256 , ISBN 978-3-319-45989-9 , https://doi.org/10.1007/978-3-319-45989-9_19
- Description: Professional learning communities (PLCs) have proven to be effective models of teachers’ professional development. Therefore, for effective Education for Sustainable Develop-ment (ESD), PLCs should be considered in the planning of teacher professional development initiatives. This will enable teachers to address issues of quality teaching, learning and sustainable development issues. In the South African context, a ‘professional learning community’ is an emerging policy con-cept. This chapter thus provides a review of the emergence of teacher clusters in South Africa using a reflexive spiral model and praxis tasks. The chapter also draws from the Namibian and South African teacher cluster literature to comment on how teacher clusters could potentially be translated into PLCs to transform teachers’ practices as they relate to ESD.
- Full Text:
- Date Issued: 2017
Understanding spatial variation in the drivers of nature-based tourism and their influence on the sustainability of private land conservation
- Baum, Julia, Cumming, Graeme S, de Vos, Alta
- Authors: Baum, Julia , Cumming, Graeme S , de Vos, Alta
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416481 , vital:71352 , xlink:href="https://doi.org/10.1016/j.ecolecon.2017.05.005"
- Description: Protected areas connect socio-economic and ecological systems through their provision of ecosystem goods and services. Analysis of ecosystem services allows the expression of ecological benefits in economic terms. However, cultural services, such as recreation opportunities, have proved difficult to quantify. An important challenge for the analysis of cultural services is to understand the geography of service provision in relation to both human and ecological system elements. We used data on visitation rates and measures of context, content, connectivity, and location for 64 private land conservation areas (PLCAs) to better understand geographic influences on cultural service provision. Visitation to PLCAs was influenced by a combination of ecological and socio-economic drivers. Variance partitioning analysis showed that ecology explained the largest proportion of overall variation in visitation rates (26%), followed by location (22%). In tests using generalized linear mixed models, individual factors that significantly explained visitation rates included the number of mammal species, the number of Big 5-species (ecological variables), the number of facilities provided (infrastructure) and average accommodation charges (affordability). Our analysis has important implications for the economic sustainability of PLCAs and more generally for understanding the relevance of spatial variation for analyses of cultural services.
- Full Text:
- Date Issued: 2017
- Authors: Baum, Julia , Cumming, Graeme S , de Vos, Alta
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/416481 , vital:71352 , xlink:href="https://doi.org/10.1016/j.ecolecon.2017.05.005"
- Description: Protected areas connect socio-economic and ecological systems through their provision of ecosystem goods and services. Analysis of ecosystem services allows the expression of ecological benefits in economic terms. However, cultural services, such as recreation opportunities, have proved difficult to quantify. An important challenge for the analysis of cultural services is to understand the geography of service provision in relation to both human and ecological system elements. We used data on visitation rates and measures of context, content, connectivity, and location for 64 private land conservation areas (PLCAs) to better understand geographic influences on cultural service provision. Visitation to PLCAs was influenced by a combination of ecological and socio-economic drivers. Variance partitioning analysis showed that ecology explained the largest proportion of overall variation in visitation rates (26%), followed by location (22%). In tests using generalized linear mixed models, individual factors that significantly explained visitation rates included the number of mammal species, the number of Big 5-species (ecological variables), the number of facilities provided (infrastructure) and average accommodation charges (affordability). Our analysis has important implications for the economic sustainability of PLCAs and more generally for understanding the relevance of spatial variation for analyses of cultural services.
- Full Text:
- Date Issued: 2017
Using Dialectical Critical Realism in the Analysis of Career Stories in Learning Pathways Research
- Lotz-Sisitka, Heila, Ramsarup, Preesha
- Authors: Lotz-Sisitka, Heila , Ramsarup, Preesha
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , bulletin
- Identifier: http://hdl.handle.net/10962/436416 , vital:73270 , ISBN bulletin , https://www.saqa.org.za/wp-content/uploads/2023/02/SAQA-Bulletin-2017-1.pdf#page=37
- Description: In this paper we expand on our earlier methodological deliberations asso-ciated with differentiation within systems, boundaries and transition mechanisms (see Paper 2 in this Bulletin). We explore the potential for using a combination of two methodological tools for our learning path-ways research, in order to address the central methodological question raised through the literature review of learning pathways research, which highlighted a macro-micro dualism this area of study (see Paper 3 in this Bulletin). In Paper 4, we seek to explore whether Bhaskar’s (1993) dialec-tical approach may help with addressing this methodological dualism. We do this through applying the dialectical method, to career stories research approaches, which are one of the foundational approaches used in learn-ing pathways research (see Paper 3 in this Bulletin). Our analysis in this paper therefore uses (a) the development of ‘career stories’ and (b) Criti-cal Realist analysis of these career stories, using Bhaskar’s (1993) dialecti-cal method which foregrounds both absence and emergence.
- Full Text:
- Date Issued: 2017
- Authors: Lotz-Sisitka, Heila , Ramsarup, Preesha
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , bulletin
- Identifier: http://hdl.handle.net/10962/436416 , vital:73270 , ISBN bulletin , https://www.saqa.org.za/wp-content/uploads/2023/02/SAQA-Bulletin-2017-1.pdf#page=37
- Description: In this paper we expand on our earlier methodological deliberations asso-ciated with differentiation within systems, boundaries and transition mechanisms (see Paper 2 in this Bulletin). We explore the potential for using a combination of two methodological tools for our learning path-ways research, in order to address the central methodological question raised through the literature review of learning pathways research, which highlighted a macro-micro dualism this area of study (see Paper 3 in this Bulletin). In Paper 4, we seek to explore whether Bhaskar’s (1993) dialec-tical approach may help with addressing this methodological dualism. We do this through applying the dialectical method, to career stories research approaches, which are one of the foundational approaches used in learn-ing pathways research (see Paper 3 in this Bulletin). Our analysis in this paper therefore uses (a) the development of ‘career stories’ and (b) Criti-cal Realist analysis of these career stories, using Bhaskar’s (1993) dialecti-cal method which foregrounds both absence and emergence.
- Full Text:
- Date Issued: 2017