The structure of aliphatic amine adducts of uranyl acetylacetonate. I. Dioxobis(2,4-pentanedionato)mono (2-N-methylaminopentan-4-one)uranium(VI)

Title: The structure of aliphatic amine adducts of uranyl acetylacetonate. I. Dioxobis(2,4-pentanedionato)mono (2-N-methylaminopentan-4-one)uranium(VI)
Creator: Haigh, John M, Nassimbeni, Luigi R, Pauptit, Richard A, Rodgers, Allen L, Sheldrick, George M
Subject: Aliphatic amine adducts
Subject: Uranyl acetylacetonate
Date: 1976
Type: Article
Type: text
Identifier: vital:6373
Identifier: http://hdl.handle.net/10962/d1006077
Description: Crystals of the title compound are monoclinic with a= 8.314 (5), b= 22.723 (9), c= 12.589 (6) A, /3= 123.0 (2t, Z=4, space group P2dc. The structure was determined by Patterson and Fourier methods and refined by full-matrix least squares to a final R of 0.030 for 2043 independent reflexions. The U atom has pentagonal bipyramidal coordination and the N-methylacetylacetoneamine is bonded to U via O. There are two intramolecular N-H. . .0 hydrogen bonds which govern the geometry of the adduct molecule.
Format: 4 pages, pdf
Language: English
Relation: Haigh, J.M. and Nassimbeni, L.R. and Pauptit, R.A. and Rodgers, A.L. and Sheldrick, G.M. (1976) The structure of aliphatic amine adducts of uranyl acetylacetonate. I. Dioxobis(2,4-pentanedionato)mono (2-N-methylaminopentan-4-one)uranium(VI). Acta Crystallographica, B32 . pp. 1398-1401

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Haigh, John M (Prof)

RU Department of Pharmacy

SDG 03. Good Health and Well-Being

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