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Leveraging LTSP to deploy a sustainable e-infrastructure for poor communities in South Africa

- Zvidzayi, Tichaona Manyara

Authors: Zvidzayi, Tichaona Manyara
Date: 2022-10-14
Subjects: Linux Terminal Server Project , Network computers , Thin client , Fat client , Cyberinfrastructure , Poverty reduction
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/365577 , vital:65761
Description: Poverty alleviation is one of the main challenges the South African government is facing. Information and knowledge are key strategic resources for both social and economic development, and nowadays they most often rely on Information and Communication Technologies (ICTs). Poor communities have limited or no access to functioning e-infrastructure, which underpins ICT. The Siyakhula Living Lab (SLL) is a joint project between the universities of Rhodes and Fort Hare that has been running for over 15 years now. The SLL solution is currently implemented in schools in the Eastern Cape’s Dwesa-Mbhashe municipality as well as schools in Makhanda (formerly Grahamstown). Over the years, a number of blueprints for the meaningful connection of poor communities was developed. The research reported in this thesis sought to review and improve the Siyakhula Living Lab (SLL) blueprint regarding fixed computing infrastructure (as opposed to networking and applications). The review confirmed the viability of the GNU/Linux Terminal Server Project (LTSP) based computing infrastructure deployed in schools to serve the surrounding community. In 2019 LTSP was redesigned and rewritten to improve on the previous version. Amongst other improvements, LTSP19+ has a smaller memory footprint and supports a graphical way to prepare and maintain the client’s image using virtual machines. These improvements increase the potential life of ICT projects implementing the SLL solution, increasing the participation of members of the community (especially teachers) to the maintenance of the computing installations. The review recommends the switching from thin clients deployments to full ("thick") clients deployments, still booting from the network and mounting their file systems on a central server. The switch is motivated by reasons that go from cost-effectiveness to the ability to survive the sudden unavailability of the central server. From experience in the previous deployment, electrical power surge protection should be mandatory. Also, UPS to protect the file system of the central server should be configured to start the shutdown immediately on electrical power loss in order to protect the life of the UPS battery (and make it possible to use cheaper UPS that report only on network power loss). The research study contributed to one real-life computing infrastructure deployment in the Ntsika school in Makhanda and one re-deployment in the Ngwane school in the Dwesa-Mbhashe area. For about two years, the research also supported continuous maintenance for the Ntsika, Ngwane and Mpume schools. , Thesis (MSc) -- Faculty of Science, Computer Science, 2022
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Long-term trends in fish length-at-age, catch-at-length and condition of the Namibian and South African commercially exploited species

- Iyambo, Elago Martha

Authors: Iyambo, Elago Martha
Date: 2022-10-14
Subjects: Fishery management South Africa , Fishery management Namibia , Fishes Growth , Fisheries Fishing effort , Climatic changes , Fishes Climatic factors
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/362872 , vital:65370
Description: Fish growth rate is a flexible trait that can evolve in response to fishing or environmental change. Therefore, knowledge of fish growth rate patterns, long-term and short-term responses to fishing effort and environmental change is important for fisheries management in the Benguela. Historical and current age length keys have been used as indicators of annual fish growth in the Benguela, the growth rate study on Merluccius paradoxus demonstrated long-term changes in growth over three decades as a response to fishing. However, the fish growth rate patterns, in relation to fishing effort and environmental change patterns are still not known for the many commercially important stocks in the Benguela. The specific objectives of the project were to determine the annual variability and long-term trends, in annual mean lengths-at-age, catch-at-length and fish condition of 17 commercially exploited resources, targeted and bycatch in Namibia and South Africa in relation to environmental changes (sea surface temperature). The results showed that there was a significant decrease in mean length at age 7 for Merluccius capensis (Namibian stock), a significant decrease in mean length at ages 3 to 7 for South African M. capensis and a significant increase in mean length at ages 2 to 6 for South African M. paradoxus Fishery-induced evolution may be the reason for the increase in mean length in the early stages of hake. A regime shift was detected in the mean length at age 1 for Etrumeus whiteheadi (South African stock) caused by changes in water temperatures. A decrease in mean length of the catch was observed for Namibian M. capensis and the reason for this could have been the stock being overexploited during the years of the observed trend (1968 to 1987). Historically both the Namibian Lophius vomerinus and Helicolenus dactylopterus were bycatch of the hake fishery, therefore, the decrease in their mean length of the catch may be due to increased bycatch mortalities due to increased hake catches. The improvement in the management measures of the Jasus lalandii fishery and possible favourable oxygen fluctuation might have caused the stock to increase in mean length of the catch between 1977 and 1982. Fish condition showed a significant difference in stocks between years. Fish condition of M. capensis, M. paradoxus and T. capensis were analysed. The rest of the commercial stocks were omitted because there was limited length-weight data. For Namibian M. capensis the spawning season may have caused fish to have the best condition in 1987 and while higher temperatures in 1983 may have led to the worst condition in 1983. Higher prey availability in 1979 for Namibian M. paradoxus could have been the reason for fish with best condition being found in 1979. T. capensis had the highest condition index in 1986 when cooler summer SST prevailed that may have been more favourable for T. capensis to live in. July, September and January SSTs were significantly negatively correlated with the mean length of M. capensis at age 3. This was perhaps due to upwelling intensity and plankton productivity which increases in winter and decreases in summer. A separate study of the impacts of fishery-induced changes and density-dependence on fish growth rate, as well as the effects of other environmental variables is recommended. Since data for some species was outdated, it is suggested to update biological variables and assessment for future work. This study can be used to understand the key life history characteristics of Namibian and South African exploited resources, targeted and bycatch. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
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M.M. Hala: Memoirs of an Umkhonto WeSizwe Cadre

- Hala, Mzimasi Mike

Authors: Hala, Mzimasi Mike
Date: 2022-10-14
Subjects: African National Congress , Umkhonto we Sizwe (South Africa) , Anti-apartheid movements South Africa , Anti-apartheid activists South Africa , South Africa Politics and government 1948-1994 , Hani, Chris, 1942-1993 , Holomisa, Bantu, 1955- , Bisho massacre
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/406785 , vital:70307
Description: Born in Komani (Queenstown) in 1959 and detained for Congress of South African Students (COSAS) activities while still at school, Mzimasi Mike Hala departed South Africa via Swaziland in 1981 and joined uMkhonto WeSizwe (MK). Trained in Angola, Cuba and East Germany, he commanded Cacuso camp in Angola, until redeployed to South Africa in 1987 to work underground in Venda and Cape Town. Following the unbanning of the liberation movements in 1990, he was appointed Commander of MK’s Transkei Region, where he was in charge of Chris Hani’s personal security. For reasons of space, the memoir does not proceed beyond his integration into the South African National Defence Force (SANDF) with the rank of Lieutenant-Colonel and second-in-command of SANDF Group 46 in Mthatha. Besides its value as a primary source of previously undocumented information, the thesis seeks to bridge the gap between the academic literature on MK and the lived experience of MK soldiers. Having considered both the academic literature and the published MK memoirs in Chapter One, the thesis refers back to the literature in narrative chapters Two to Five. Consolidating its findings in its conclusion, the final chapter is divided into three sections: the political culture of MK, MK gender dynamics and the consequences of the political merger of the “exiles,” including MK, and the “inziles” who subsequently came to dominate the ANC. , Thesis (MA) -- Faculty of Humanities, Institute of Social and Economic Research, 2022
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Mentoring as social learning value creation in two South African environmental organisations: a social realist analysis

- Hiestermann, Michelle

Authors: Hiestermann, Michelle
Date: 2022-10-14
Subjects: Social realism , Social learning , Mentoring , Environmental education South Africa
Language: English
Type: Academic theses , Doctoral theses , text
Identifier: http://hdl.handle.net/10962/366248 , vital:65846 , https://doi.org/10.21504/10962/366248
Description: South Africa is facing overwhelming crises of educational quality, record rates of unemployment (especially amongst youth) and environmental issues and risks, further exacerbated by the Covid-19 pandemic. Environmental education research that addresses these challenges is critical to ensuring that future generations thrive in a warming climate. South Africa needs environmental leaders; we therefore need to understand and explore the possibilities of mentoring young professionals in environmental organisations in South Africa. Several initiatives have been developed to contribute to the mentoring of young professionals in South African environmental organisations. This study drew on a critical realist ontology, social realist meta-theory and domain specific theory on mentoring and evaluation to explore mentoring as a value creating proposition in two environmental organisations in South Africa that were part of the national Groen Sebenza youth employment creation programme which had a strong focus on mentoring. To strengthen conceptual analytical tools on mentoring, I undertook an immanent critique of domain specific mentoring theory to develop a more appropriate foundation for mentoring theory in the environmental sector that was not subject to the historical influence of human capital theory only (which has tended to dominate the field’s literature). I then developed in-depth understanding of mentoring in two case study contexts, namely a non-profit environmental organisation and an environmental consulting company, using qualitative research approaches that included contextual profiling, case study research and mirror data workshops. Analytically, I considered the case data drawing on the value creation evaluation framework of Wenger-Trayner and Wenger-Trayner (2014) which itself was developing as an analytical framework as the study developed. I strengthened the analytical framework with social realist interpretations drawing on Archer (1995). This offered me a way of developing an in-depth understanding of the factors which constrain or enable the value creation possibilities of mentoring, with a view to inform human capacity development initiatives that support mentoring in the environment sector. It was possible to explain the value creation possibilities of mentoring within two case study environmental organisations through considering mentoring as a social learning process of value creation and this overcame some of the shortfalls identified in other early learning theories as well as theories of mentoring. The research revealed how mentoring can provide a value creation social learning trajectory for unemployed youth. A social realist perspective explained how young professionals expanded their primary agency, through full participation in workplace communities of practice, to find their identity as corporate agents in the workplace with their mentors. In this research, Social Realist ontology, theory and methodology was able to achieve what Human Capital Theory could not and provided an account of the interplay of structure, culture and agency over time, through emergent properties and the separation of structure and agency. Thus, it was possible to avoid conflation and the limitation of theory of the present tense, with a deeper, ontologically robust explanation of mentoring as social learning and social change and a social realist orientation to human capacity development. South Africa has a history of oppression, inequality and injustice and requires social processes that are reflexive, critical, emancipatory and transformative. Therefore, this research required theory and approaches that could explain mentoring of unemployed youth, as a common good initiative for a more just and sustainable society. As shown in this study, a Social Realist approach can uncover the underlying generative mechanisms and make the implicit more explicit in research, policy and strategy, offering a robust alternative to the tenets of Human Capital Theory that have driven much mentoring research in South Africa and elsewhere to date. , Thesis (PhD) -- Faculty of Education, Education, 2022
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Mobilising indigenous technologies of making oshikundu and uumboloto to motivate and enable sense making of the topic carbon dioxide by grade 8 rural school learners

- Nandjedi, Fredinard Nghinaounditala

Authors: Nandjedi, Fredinard Nghinaounditala
Date: 2022-10-14
Subjects: Science Study and teaching (Secondary) Social aspects Namibia , Culturally relevant pedagogy Namibia , Ethnoscience Namibia , Carbon dioxide
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/405357 , vital:70164
Description: Poor performance in Science has been noted in most rural schools and this has become a concern to education planners and implementers. Part of the failure is said to be caused by inadequate school resources, under-preparedness of teachers to teach Science, poor command of the Language of Learning and Teaching, negative attitudes that are accompanied by lack of insights into the value of Science, low self-efficacy, and poor-quality environments for learning Science. In this regard, literature has revealed that many Science teachers in Namibia do not consider learners’ local indigenous knowledge (IK) also known as indigenous technology to mediate learning. Yet, it is a requirement of the Namibian Science curriculum. I assume that this could be due in part to the fact that the Science curriculum is not explicit on how IK should be integrated into Science teaching. It is against this backdrop that this study sought to explore the opportunities IK integration into Science may offer in mediating learning and sense-making on the topic of carbon dioxide (CO2). Learners’ indigenous technological practices of making oshikundu and uumboloto were used as vehicles of learning. This qualitative case study is underpinned by the interpretive and indigenous research paradigms. Within the indigenous research paradigm, I focused on the Ubuntu perspective. This study was conducted at a rural under-resourced school in the Ohangwena region in Namibia. Thirty Grade 8 learners, one science teacher and two expert community members were involved as participants. Data were gathered using focus group interviews (sharing circles), group activities, participatory observations, and journal reflections. Data interpretation and analysis were done using Vygotsky’s sociocultural theory and Ogunniyi’s contiguity argumentative theory. A thematic approach to data analysis was adopted. That is, an inductive approach was employed whereby sub-themes were identified, and thereafter common sub-themes were combined into themes. The findings of this study revealed that the process of making oshikundu and uumboloto can be used to enable learners to make sense of the topic of CO2 and other related concepts. Furthermore, the study revealed that hands-on practical activities done with easily accessible resources which are related to learners’ indigenous technologies help learners learn Science easily. The study thus recommends that educators should use oshikundu and/or uumboloto to mediate learning of topics such as CO2. Science teachers should always try to tap into learners’ socio-cultural backgrounds in their lessons to enhance better understanding of Science concepts. , Thesis (MEd) -- Faculty of Education, Education, 2022
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Mobilising the indigenous technology of making soap to mediate learning of saponification in organic chemistry

- Neporo, Johannes Kanyetu

Authors: Neporo, Johannes Kanyetu
Date: 2022-10-14
Subjects: Chemistry Study and teaching (Secondary) Social aspects Namibia , Culturally relevant pedagogy Namibia , Ethnoscience Namibia , Saponification , Ubuntu (Philosophy) , Pedagogical content knowledge
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/405368 , vital:70165
Description: Scholars across the world are advocating for culturally responsive pedagogies that allow for the integration of indigenous knowledge (IK) in science teaching. This is in the hope of making science accessibleand relevant to learners from different social, economic and cultural backgrounds. Although the Namibian curriculum welcomes the integration of IK in teaching, it, however, does not stipulate how it should be implemented. It is against this backdrop that this interventionist study aimed to mobilise the indigenous technology of making soap to mediate the learning of saponification in organic chemistry. This study is underpinned by the interpretive and indigenous research paradigms. Within these paradigms, it employed a qualitative case study research design. The study was conducted in Walvis Bay in Namibia with four Grade 11 chemistry teachers, two expert community members and a critical friend who were purposively and conveniently sampled. Data were gathered using semi-structured interviews, semi-structured questionnaires, workshop discussions, participatory observation, stimulated recall interviews and journal reflections. Vygotsky’s Socio-Cultural Theory (SCT) and Shulman’s Pedagogical Content Knowledge (PCK) were used as theoretical frameworks. Within PCK, Mavhunga and Rollnick’s Topic-Specific Pedagogical Content Knowledge (TSPCK) served as an analytical framework. A thematic approach to data analysis was employed. That is, data were analysed inductively to come up with sub-themes. Thereafter, common sub-themes were combined to form themes. The findings of the study revealed that the Grade 11 chemistry teachers demonstrated positive attitudes toward the integration of IK in their teaching. However, they seemed not tohave pedagogical insights on how to do it. Despite this, they learnt, interacted and participated actively during the two expert community members’ presentation workshops on making soap. That subsequently enabled them to co-developan exemplar lesson plan on saponification that integrated IK. This study implies that there is a need for Chemistry teachers to be empowered on how to make science accessible and relevant to learners’ socio-cultural backgrounds. The study thus recommends that higher education institutions and educational authorities reform and amend the curriculum to cater for the integration of IK. The study further recommends that Chemistry teachers should tap into the cultural heritage of expert community members in mediating the learning of science concepts. Lastly, Chemistry teachers are encouraged to form professional learning communities to develop themselves professionally. , Thesis (MEd) -- Faculty of Education, Education, 2022
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Movement patterns of the iconic giant kingfish Caranx ignobilis from Southern Africa

- Dixon, Russell Bruce

Authors: Dixon, Russell Bruce
Date: 2022-10-14
Subjects: Caranx Africa, Southern , Caranx Migration , Underwater acoustic telemetry , Carangidae Africa, Southern , Fish tagging
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/362797 , vital:65363
Description: Giant kingfish Caranx ignobilis, the largest species in the family Carangidae, are global icons as apex marine predators. They are widespread in tropical to subtropical regions globally, where they are of high importance to ecosystems and fisheries. During summer, adults aggregate for spawning, making them vulnerable to overfishing. The world’s largest recorded C. ignobilis aggregation is in southern Mozambique. Some of these aggregating individuals (an unknown proportion) have been recorded passing into South African waters. Furthermore, a unique aggregation of adult C. ignobilis in South Africa’s Mtentu Estuary has attracted global attention but remains unexplained, hence warranting investigation. Research on C. ignobilis globally has shown relatively small home ranges. Research in southern Africa has been limited and inconclusive. Thus, the broad aim of this study is to describe the movement patterns of C. ignobilis from southern Africa. Long-term (36 years) mark-recapture data from the Oceanographic Research Institute’s Co-operative Fish Tagging Project, comprising 3 729 tagged C. ignobilis and 144 recaptures, were analysed. While 74% of recaptures were recorded < 1 km from the tagging location, long-distance movements of up to 419 km were also recorded (mean = 15 km). Although adults moved significantly (p < 0.01) greater distances than juveniles, they also displayed high levels of site fidelity. Seasonal trends included evidence of a summer migration; however, there was still considerable uncertainty regarding exact movements. Therefore, 43 C. ignobilis were acoustically tagged and subsequently monitored along the east coast for over five years with the Acoustic Tracking Array Platform’s passive receiver array. All acoustically tagged adult C. ignobilis migrated to southern Mozambique each year (with minor exceptions), from distances of up to 632 km. When not migrating, South African-based fish showed consistent inter-annual fidelity to individual home ranges. Although coastal home range length (excluding migrations) varied considerably between individuals, even the mean length (92 km) was greater than any previously recorded C. ignobilis home range, globally. In contrast to the southern Mozambique aggregation, the Mtentu Estuary aggregation seems to comprise of individuals showing fidelity to that region. The passive tracking of eight acoustically tagged individuals in the Mtentu Estuary revealed clear trends. Statistical modelling showed that estuarine presence was strongly associated with periods of cold coastal upwelling. Diel movement patterns showed that the utilisation of warm surface waters ~ 4 km upstream during the day was followed by nightly departures to the mouth or sea. Thus, it is likely that this majestic aggregation is for thermal refuge; specifically, for daily re-warming after feeding in cold waters at night. Findings from this study are of global ecological interest and have direct applications for local fisheries management and the development of sustainable eco-tourism. Protecting these vulnerable aggregations is of the utmost importance for the future of this species in southern Africa. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
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Negotiating marginalisation: A socio-economic history of the Kalanga of Mangwe, Zimbabwe, 1940-2015

- Nyathi, Innocent

Authors: Nyathi, Innocent
Date: 2022-10-14
Subjects: Marginalisation , Kalanga (African people) Race identity Zimbabwe , Ethnicity Zimbabwe , Zimbabwe Economic conditions , Zimbabwe Social conditions , Kalanga language (Botswana and Zimbabwe)
Language: English
Type: Academic theses , Doctoral theses , text
Identifier: http://hdl.handle.net/10962/408705 , vital:70518 , DOI 10.21504/10962/408705
Description: The thesis explores the relationship between ethnicity, marginalisation, and survival mechanisms amongst the Kalanga people of Mangwe (southwestern Zimbabwe) from the 1940s up until the turn of the 21st century. The study showed how the Kalanga of Mangwe have used ethnicity as a concept to not only claim access to resources but also develop alternative survival strategies that help them seek to navigate their experiences of marginalisation by both the state and the hegemonic position of the Ndebele who dominate the region politically and linguistically. Using evidence from activities such as cross border migration and the mopane economy, I showed how the Kalanga express their displeasure at being dominated through engagement, as was shown in their attempt to fight for their language, for example in the 1940s through regionalised Kalanga organisations as the Kalanga Language and Cultural Development Society (KLCDS), to disengagement such as migration and illegal informal cross border trade. Using ‘conviviality’ and ‘the everyday’, as well as borrowing from the Race Relations Theory (RRT) of Robert Ezra Park as theoretical underpinnings, I demonstrated how amongst the Kalanga of Mangwe ethnic identity can lead to competition for resources, which in turn leads to marginalisation and discrimination which influences their social, political and economic choices that may in turn reinforce ethnic identity in a cycle like scenario. Everyday economic and social activities amongst the Kalanga of Mangwe that appear mundane and ordinary to an uninterested observer, help shape the everyday discourse of the Kalanga as they navigate marginalisation. , Thesis (PhD) -- Faculty of Humanities, History, 2022
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Orthographic knowledge in isiXhosa and its relation to phonological processing, letter-sound knowledge, reading and spelling

- Daries, Mikaela Ann

Authors: Daries, Mikaela Ann
Date: 2022-10-14
Subjects: Xhosa language Orthography and spelling , Phonological awareness , Psycholinguistics , Oral reading Usage , Literacy South Africa , Reading Phonetic method
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/406703 , vital:70300
Description: Despite international research confirming its importance, writing and related metalinguistic skills have often been neglected in comparison to reading in literacy research (Cunningham et al., 2001; Castles & Coltheart, 2004; Nag, 2007; Roman et al., 2009; Zhao et al., 2017). On a national level there are very few studies that have explored the writing aspect of literacy in South Africa, and none that has investigated orthographic knowledge in a Southern Bantu language, such as isiXhosa. In an attempt to address this gap, this thesis explores orthographic knowledge and its components in isiXhosa. In particular, it seeks to investigate the unique predictors of word specific and general orthographic knowledge as well as their role for reading and spelling in isiXhosa while controlling for phonological awareness (PA), rapid automatized naming (RAN), and letter-sound knowledge. Furthermore, the thesis attempts to situate its findings within the main premises of the self-teaching hypothesis and dual route approach to orthographic processing in order to contribute to linguistic theories of reading with cross-linguistic evidence (Jorm & Share, 1983; Share & Jorm, 1987; Share, 1995; Grainger & Ziegler, 2011). A quantitative cross-sectional study was conducted with 140 isiXhosa home language third grade learners in which word specific and general orthographic knowledge tasks were specifically designed. These tasks were administered along with oral reading fluency (ORF), spelling, PA, RAN, and letter-sound knowledge. The findings revealed that letter-sound knowledge and PA contributed the largest variance towards both word specific and general orthographic knowledge. Further, word specific orthographic knowledge and letter-sound knowledge were the only significant predictors of spelling. Similarly, both word specific and letter-sound knowledge were significant predictors of reading, along with RAN and general orthographic knowledge. Quantile linear regression analyses revealed that word specific orthographic knowledge was a robust predictor of spelling and letter-sound knowledge was a robust predictor of reading across ability levels confirming the importance for word specific orthographic knowledge for spelling and letter-sound knowledge for reading in isiXhosa. In relation to the two reading theories considered in this thesis, the findings reflect similarities between the assertions of the self-teaching hypothesis and current thesis with suggestions made for further inquiry. The dual route approach to orthographic processing provides insights into the potential processing of orthographic information while reading in isiXhosa. The findings of this study confirm the importance of orthographic knowledge for reading and spelling for languages with transparent orthographies such as isiXhosa. , Thesis (MA) -- Faculty of Humanities, Linguistics and Applied Language Studies, 2022
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Oversight mechanisms and service delivery: a case study of municipal public accounts committee oversight of electricity services in Raymond Mhlaba Local Municipality

- Mpofu, Sibabalwe

Authors: Mpofu, Sibabalwe
Date: 2022-10-14
Subjects: Municipal services South Africa , Local government South Africa , Local service delivery , Public sector , Oversight , Economics Sociological aspects , Government accountability South Africa
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/408671 , vital:70515
Description: Over the last few years, there has been a notable increase in popularity in the use of cannabidiol (CBD) as a form of alternative medicinal treatment for various illnesses. CBD, a by-product of the cannabis plant, is an isolate and does not contain the psychoactive agent, tetrahydrocannabinol (THC). Endometriosis and Polycystic Ovarian Syndrome (PCOS) are chronic reproductive health sicknesses that are increasingly experienced by women. In the absence of cures, biomedical treatment for these diseases aim to manage symptoms, for example; heavy bleeding, heightened levels of pain, and insomnia. CBD offers an alternative to women who feel that biomedical interventions are no longer able to maintain their health and well-being. CBD positions itself as a natural remedy claiming to be safe and effective. This research study, mainly through qualitative data collection, focused on experiences of Zimbabwean and South African women living with endometriosis and/ or PCOS, who have turned to CBD to manage their symptoms. The importance of this study was to position itself within patients’ lived experiences. The research study found that CBD indeed has numerous benefits, including pain management, alleviating stress, and anxiety. Through the emergent themes from the data, it became clear that women are marginalised and treated unequally in the biomedical healthcare sphere. Feminist Anthropology and Structural Violence was applied to analyse the data collected to explore the patriarchal nature of the biomedical healthcare system and the experiences that women have, which has led them to turn to alternative treatments. , Thesis (MSocSci) -- Faculty of Humanities, Sociology, 2022
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Photodynamic anticancer and antimicrobial activities of π-extended BODIPY dyes and cationic mitochondria-targeted porphyrins

- Chiyumba, Choonzo Nachoobe

Authors: Chiyumba, Choonzo Nachoobe
Date: 2022-10-14
Subjects: Dyes and dyeing Chemistry , Mitochondria , Cancer Chemotherapy , Porphyrins , Molecules Models , Photochemotherapy
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/362785 , vital:65362
Description: Cancer is among the most devastating diseases and is mainly caused by gene mutation. This could be hereditary, or the mutation could be stimulated due to a lifestyle one lives, such as smoking, which induces lung cancer. The high morbidity rates of cancer are attributed to it being metastatic. The relatively poor physicochemical properties of existing drugs have caused treatment to be ineffective. Photofrin®, Foscan®, and Photogem® are some of the porphyrin-based derivatives approved by the Food and Drug Administration (FDA) for use in photodynamic therapy (PDT). Despite having such drugs, the quest to find better cancer drugs is still ongoing and 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are among the molecules that are being studied as potential photosensitisers (PS) in PDT. However, these molecules suffer from poor solubility and ineffective generation of singlet oxygen, the main ingredient in PDT treatment. Furthermore, photosensitisers used in PDT face a problem with hypoxic conditions associated with cancer cells, which causes the generation of singlet oxygen to be relatively low. The PS also suffer from the untargeted treatment, increasing their toxicity. Therefore, the main aim of this study was to improve the bioavailability of BODIPY dyes. Thus, a series of BODPIY dyes were synthesised with hydrogen bond accepting atoms and heavy atoms that enhance singlet oxygen generation. Additionally, to override hypoxia conditions, porphyrins with mitochondria targeting properties were synthesised since it has been well established that the mitochondria will always have a decent amount of oxygen in cancerous cells. When employed as PS in PDT studies, these molecules have better cytotoxic abilities than BODIPY dyes, and this potency was credited to their mitochondria targeting ability and efficient singlet oxygen generation. Finally, this study reports the synthesis of di- and mono-substituted BODIPY dyes with improved solubility and porphyrins substituted with triphenyl phosphine, a mitochondria targeting moiety. On the other hand, the work further illustrates the synthesis of β-substituted cationic porphyrin with mitochondria targeting properties. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
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Poems caught in dreams

- Jafta, Nthabiseng Rose JahRose

Authors: Jafta, Nthabiseng Rose JahRose
Date: 2022-10-14
Subjects: Creative writing (Higher education) South Africa , South African poetry (English) 21st century
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/406249 , vital:70252
Description: My thesis is a collection of Lyrical and Prose Poetry. I am strongly influenced by Marina Tsvetaeva’s observation that “The condition of creation is a condition of dreaming.” As a writer I want to contribute to human knowledge by drawing from a wide literary ancestry, participating in a community of distinct voices and styles to capture and preserve the language of dreams. I fuse inherited knowledge, visions, dreams, my own experiences and what I have discovered through listening to music, reading and my own experiments in exploring poetry in dreams, thoughts and lived experiences. I am inspired by Sindiwe Magona, how she chose to express her spirituality and personal narratives into her work, and Aimé Césaire’s vision “The ground of poetic knowledge, [is] an astonishing mobilization of all human and cosmic forces.” I particularly enjoy intense forms of expression that hold substance and provoke one to elevate in knowledge and in writing. Exploring these combination of forces from these writers affords me an opportunity to write my dreams as reality. Exploring the characters, the different scenes, symbols and colours as poems flashing super/naturally yet leave one with fathomable felt, though sometimes hazy interpretations. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2022
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Portraits

- Fredericks, Gaireyah

Authors: Fredericks, Gaireyah
Date: 2022-10-14
Subjects: Kaaps , Creative writing (Higher education) South Africa , Diaries -- Authorship , Books Reviews , Afrikaans essays 21st century , Short stories, Afrikaans 21st century
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/406238 , vital:70251
Description: Die portfolio bestaan yt reflections op my writing process during die course, my reading, my poetics essay en vier boek resensies. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2022
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Production of mannooligosaccharides from pineapple pulp and pine sawdust using Aspergillus niger derived Man26A and determination of their prebiotic effect

- Hlalukana, Nosipho Pretty

Authors: Hlalukana, Nosipho Pretty
Date: 2022-10-14
Subjects: Oligosaccharides , Prebiotics , Lignocellulose , Mannans
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/362853 , vital:65368
Description: Lignocellulosic biomass is the most abundant source of renewable biomass on earth. Lignocellulosic biomass consists of cellulose, hemicelluloses and lignin. These can be used as a source of renewable fuel as well as other value-added products . Mannans are part of the hemicellulose fraction of lignocellulosic biomass and are the major hemicellulosic polysaccharide fraction in softwoods, where they are found as galactoglucomannans and as glucomannans. Mannans are also found in hardwoods in the form of glucomannans. Mannans can be enzymatically hydrolysed using endo-mannanases to produce of short chain mannooligosaccharides (MOS). MOS have received significant attention for their prebiotic properties, as they promote the growth of probiotic bacteria, which have positively affects on gut health. This study focused on the production of prebiotic MOS from lignocellulosic biomass waste (LBW) and an evaluation of the prebiotic potential of the produced MOS. An Aspergillus niger derived endo-mannanase, Man26A, was fractionated and biochemically analysed. Purified Man26A had a fold purification of 1.25 and a yield of 41.1%. SDS-PAGE analysis of the enzyme revealed that it had a molecular weight of 46 kDa. The pH and temperature optima of Man26A were determined and the pH optimum was found to be pH 4.0 (but the enzyme displayed high activity over a broad acidic pH range, with up to 90% of the activity retained between pH 3.0 and 7.0). The temperature optimum was 50℃. The enzyme was shown to have the highest specific activity on locust bean gum (52.27 U/mg) and ivory nut mannan (57.25 U/mg), compared to guar gum (29.07 U/mg), which indicated that it was affected by the substitution pattern of the mannans. Man26A produced MOS of different diversity on model mannan substrates, where the MOS produced were mannobiose, mannotriose, and mannotetraose for ivory nut mannan, mannobiose, mannotriose, mannotetraose, and mannopentaose and MOS with a higher degree of polymerisation for locust bean gum, and mannobiose, mannotriose, mannotetraose, mannopentaose, and mannohexose and MOS with a higher degree of polymerisation for guar gum, as determined by thin layer chromatography (TLC) and high-performance liquid chromatography (HPLC). Pretreatment and characterisation of pineapple pulp (PP) and pine sawdust (PSD) was conducted, and the impact of the pretreatment procedures was analysed using Megazyme sugar kits, thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and microscopic analysis using scanning electron microscopy (SEM) and light microscopy. Compositional analysis of the carbohydrates present in both substrates revealed that they had a glucan content of 36.41 and 50.47% for untreated PP and PSD, respectively. Their respective mannan content was 6.74 and 11.59% and was deemed sufficient for the production of MOS via enzymatic hydrolysis. TGA analysis revealed that untreated and sodium chlorite-acetic acid delignified samples decomposed at approximately the same time, and had a negligible ash content at 600℃, while delignified plus phosphoric acid swollen substrates decomposed at a faster rate, but had a residual ash content at 600℃. FTIR analysis of the substrates revealed slight changes in the structures of untreated and pretreated samples. SEM analysis of PP and PSD showed a change in the morphology of the substrates with subsequent pretreatment steps. Histochemical analysis for lignin for PP and PSD showed successful delignification upon pretreatment. Untreated and sodium chlorite delignified PP and PSD released low amounts of reducing sugars compared to delignified + phosphoric acid swollen substrates. The delignified + phosphoric acid swollen substrates were used for further experiments. MOS produced from delignified and phosphoric acid swollen (Del + PAS) PP and PSD at 0.1 mg/ml enzyme loading and 80 mg/ml (8% (w/v)) substrate concentration, ran between mannose and mannobiose and between mannobiose and manotriose on TLC, with low concentrations of MOS running between mannotetraose and mannopentaose. HPLC analysis of the MOS revealed that Del + PAS PP produced mannose to mannohexose, while Del + PAS PSD produced mannose, mannobiose, and mannotetraose. The MOS were analysed using FTIR, to determine whether the MOS produced contained any acetyl groups, which were present for Del + PAS PSD at 1706 cm-1. The MOS were stable at different pHs, and at temperatures below 200℃. The MOS were also found to be stable in a simulated gastrointestinal environment, in the presence of bile salts and digestive enzymes. The prebiotic effect of the MOS derived from Del + PAS PP and PSD was evaluated. MOS had a proliferative effect on probiotic bacteria (Lactobacillus bulgaricus, Bacillus subtilis and Streptococcus thermophilus). The production of short chain fatty acids (SCFAs) was evaluated on TLC, where no SCFAs were observed on the plate. The effect of MOS on the adhesion ability of bacteria revealed that they do not positively influence the adhesion of probiotic bacteria. The antioxidant activities of 1 mg/ml MOS produced from both substrates were determined to be approximately 15% using the ABTS radical scavenging assay, compared to a radical scavenging activity of 45% for the 0.02 mg/ml gallic acid standard. This study demonstrated that biomass waste could be used to produce prebiotic MOS, which play a positive role in gut ecology and provide health benefits. , Thesis (MSc) -- Faculty of Science, Biochemistry and Microbiology, 2022
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Profiling Rhodes University students’ substance use during the Covid-19 pandemic lockdown: comparing the AUDIT and CCAPS-62 substance abuse sub-scale

- Goosen, Jeslyn Chrismaré

Authors: Goosen, Jeslyn Chrismaré
Date: 2022-10-14
Subjects: College students Substance use South Africa Makhanda , College students Alcohol use South Africa Makhanda , College students Mental health South Africa Makhanda , College students Attitudes , College students Economic conditions , COVID-19 (Disease) , Rhodes University
Language: English
Type: Academic theses , Master's theses , text
Identifier: http://hdl.handle.net/10962/405974 , vital:70224
Description: Students are vulnerable to academic distress and mental health concerns. Many struggle to effectively cope with the many demands placed on them from various factions; included but not limited to institutional demands, financial concerns, and parental expectations. With the most recent outbreak of the SARS-Co V-2 (better known as the COVID-19 pandemic) many students have struggled to effectively cope with the changes relating to the nationwide lockdown. Universities had to change the way in which they provide students with the necessary academic material, and many had to return to their familial homes. This had a deleterious effect on the way students performed their daily activities and coping. A rise in impaired mental health was noted. Many students used alcohol as a means of coping during this tumultuous and unprecedented time. Undergraduate students at Rhodes University were asked to complete a survey questionnaire via SurveyMonkey, an online survey service. Data was collected over a ten-day period during July 2020. The AUDIT and the CCAPS-62 Substance Use subscale were used to measure their alcohol intake during lockdown and results was compared. Results indicated a significant positive correlation between the CCAPS-62 substance use subscale and the AUDIT (r = 0.80, n = 930, p < 0.01). Outcomes identified that men tend to drink more than females, and white students tend to drink more than black students. Findings suggests that the CCAPS-62 a multidimensional instrument measuring general distress among students could positively contribute to the reliability and validity of the measure used in a multicultural and multilingual society such as South Africa. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
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