List of Titles

Conservation biology of an apex predator in the Anthropocene : poaching, pastoralism and lions in multi-use landscapes, South-Eastern Africa

Authors: Everatt, Kristoffer T
Date: 2020
Subjects: Conservation biology -- Africa, Southern
Language: English
Type: Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10948/48290 , vital:40839
Description: Many of the world’s apex predators are experiencing catastrophic declines as a result of competition with humans. Understanding the mechanisms and ecosystem impacts of apex predator declines is a fundamental ecological question crucial to conserving the Earth’s biodiversity and functioning ecosystems. In this thesis I used the African lion Panthera leo, as a model species to investigate the impacts of anthropogenic pressures on the conservation and ecology of an apex predator. Specifically, I investigated the relative and cumulative influences of pastoralism and poaching on lion occurrence, population connectivity, ecological role, space use, prey selection and viability across a 73 000 km2 multi-use landscape in southern Africa. Using landscape occupancy spoor surveys, I tested the hypotheses that lions were most limited by either interference or by exploitative competition with humans and identified thresholds of lion tolerance to human activities. My results showed that lions occupied only a fraction of the landscape and were limited by a combination of interference and exploitative competition with humans. Interference competition with pastoralism however was the biggest driver limiting lion occupancy, creating a clear disturbance threshold for lions cumulating in their near complete loss from the landscape. I employed call-up surveys, pride monitoring and mortality analysis to investigate the numerical impacts of anthropogenic pressures on the viability of a lion sub-population. I found that persecution by pastoralists was the greatest source of lion mortalities across the landscape. However, the targeted poaching of lions for body parts had emerged as the greatest threat to lions in a nominally protected National Park where I documented a steep population decline and collapse of lion prides. I used GPS tracking and diet analysis of lions at the human-wildlands interface to test if lions foraged optimally or were constrained by competition with humans. I fount that individual lions appeared to select for prey and habitat optimally, while also showing some level of risk avoidance towards anthropogenic pressures. I then considered landscape resistances to test if sink habitats may provide connectivity between sources or act as ecological traps. I found that potential connectivity for lions between the region’s two source populations was limited by a loss of habitat and prey. Furthermore, the impacts of by-catch in snares risked transforming the few remaining potential conservation corridors into ecological traps. Finally, I examined interactions between lions and syntopic mesopredators across gradients of anthropogenic pressures to test if the functional role of lions was affected by human pressures. I found that lions showed limited suppression of mesopredators, however, anthropogenic pressures increased lion’s interactions with syntopic predators. As an apex predator, lions have evolved limited capacity to mitigate top-down competitive pressures, however, like many of the world’s apex predators, they are becoming increasingly limited by anthropogenic pressures. This study provides a predictive understanding of an apex predator’s ecological responses to top-down anthropogenic pressures which can be applied globally to the question of conservation in the Anthropocene.
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Date Issued: 2020

Conserving land for people: transformative adaptive co-management of sustainable protected areas in the eastern Democratic Republic of Congo

Authors: Kalyongo, Kujirakwinja Deo
Date: 2020
Subjects: Protected areas -- Congo (Democratic Republic) , Protected areas -- Government policy -- Congo (Democratic Republic) , Protected areas -- Management -- Congo (Democratic Republic) , Conservation of natural resources -- Congo (Democratic Republic)
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/165912 , vital:41296
Description: Conservation practices and approaches in the Democratic Republic of Congo (DRC), as in other parts of the world, have evolved from traditional to fortress and collaborative contemporary approaches such as adaptive co-management. These approaches aim to include multiple decision-makers using diversified resources and, existing formal and informal governance structures. Collaborative approaches also consider conflict resolution and external factors that can influence conservation outputs and outcomes. In the DRC context, conflicts over resources are related not only to resource access and power but also to the ineffectiveness of collaborative approaches that exclude stakeholders such as local communities. These conflicts have negatively affected protected areas and weakened the management and governance of protected areas. Therefore, evolving approaches such as adaptive co-management that consider power relations, the multi-scaled involvement of actors and learning loops to adjust strategies are seen as better options to improve the governance of protected areas and minimise the degradation of key ecosystems. My research explored the gazettement processes of three protected areas in the eastern DRC (Itombwe, Kabobo and Okapi Reserves). I focused on the influence of social-political, historical and psychological factors on the management and governance of protected areas in the DRC. In addition, the research reveals the inclusive gazettement processes of protected areas is the foundation of successful co-management approaches. I found that values and good governance practices play a key role in influencing local perceptions and support to conservation interventions. Whilst some conservation practitioners believe that economic benefits to communities are the most predominant motivating factor, I found that good conservation management practices can motivate communities to support protected area management. Bad management practices were related not only to inadequate conservation approaches and practices but also to factors such as corruption, inadequate law enforcement and the inappropriate equipment of rangers. Therefore, I suggest that long term protected area management in DRC should consider how the value of resources for communities and protected areas have been changing throughout the history of conservation, and how to best share power and responsibilities with local resource users and stakeholders. This is only possible if conservation practices and approaches, governance process and institutions are transformed at multiple levels.
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Date Issued: 2020

Consumer behaviour regarding stock market participation in South Africa

Authors: Mbewe, Wise
Date: 2020
Subjects: Financial Literacy -- South Africa , Stock ownership -- South Africa
Language: English
Type: Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10948/50328 , vital:42107
Description: South Africa (SA) has a highly sophisticated financial services sector that contributes significantly to the economy. A stock market forms a significant component of the financial sector of any economy. While the Johannesburg Stock Exchange (JSE) has managed to arouse interest of many South Africans, there appears to be apathy and inertia when it comes to actual participation in the stock market by South African consumers. Stock market non-participation is considered a “puzzle” in microeconomics and finance literature because it is not easy to explain the reason why many consumers, in spite of high stock returns, do not own listed shares. Thus, the primary objective of this study was to investigate consumer behaviour regarding stock market participation in SA by considering the antecedents and outcomes of stock market participation in SA.The study presented a theoretical literature review on the factors influencing stock market participation in SA. From the literature review, three sets of variables classified as independent variables, an intervening variable and dependent variables were identified. The independent variables (Demographic characteristics; Financial literacy; Investment risk tolerance; Communication; and Consumer trust) were identified as possibly influencing the intervening variable (Stock market participation) and ultimately the dependent variables (Client satisfaction and loyalty, Financial sustainability and Repurchase intentions). These variables were used to construct a hypothesised model and research hypotheses. The study further presented the research methodology (following a positivistic paradigm and quantitative research method), and the results of this study. In order to establish the influence of the independent variables on stock market participation, as well as ultimate influences on the dependent variables, an empirical investigation was conducted. Since it was not possible to reach all members of the target population, the population of this study was South African consumers located in four of the nine provinces, namely, Eastern Cape, Western Cape, Kwa-Zulu Natal and Gauteng. A sample of 510 respondents participated in the study.
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Date Issued: 2020

Contesting boundaries: a case of municipal demarcation disputes in Vuwani Vhembe District

Authors: Khowa, Thandeka Promise
Date: 2020
Subjects: Geographical boundaries
Language: English
Type: Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10948/50767 , vital:42670
Description: The research study in Vuwani Vhembe district sought to investigate demarcation disputes, the relationship between service delivery and demarcation disputes. The study further investigates the role of municipal demarcation board and local government adherence to sound governance principles and the causes of the demarcation dispute in Vuwani. The study additionally examines the conceptions and misconceptions, their impact on the current demarcation disputes in Vuwani. It further intended to establish the role and involvement of Vuwani stakeholders such as traditional structures/ leaders, civil unions, community members etc. in the processes of demarcating Vuwani. “What is the cause of Vuwani community member’s rejection of the re-demarcation, which is said to correct the past spatial injustices and promote municipal sizing, thus enabling better performance in service provision by municipalities?” The study employed a mixed-method involving the use of both quantitative (mini-survey) and qualitative (use of in-depth, semi structures interviews and focus group discussions). Research findings suggest that re-demarcation is a sensitive aspect/process in South Africa, mainly due to the past Apartheid era. There was forceful removal of people from their land supported by Apartheid legislation such as the Native Land Act 1913, Group Act 1950, Native Resettlement Act 1954 etc. Thus, fears of the past Apartheid system cloud any attempt to correct spatial injustices of the country. The new democratic South African government, therefore, needs to be cautious in its acts to correct the spatial injustices, thus adhering to sound governance principles. Findings reveal that several misconceptions and lack of adherence of good governance principles by the Municipal Demarcation Board and Local government have, to some extent, fueled the demarcation disputes in Vuwani. Municipal performance in the rendering of service delivery has a major impact and contributes to the community’s acceptance or rejection of demarcation/ amalgamations. The study further reveals that in Vuwani municipal performance with the establishment of the new Collins Chabane municipality has been clouded by fear of the unknown as this form of “demarcation of establishing a new municipality” altogether is relatively new. Rural land authority, the role of traditional leaders, ethnicity ties have all been found to have contributed to the disputes in Vuwani. Limpopo Province is home to three ethnic groups, namely, vaVhenda, baPedi and xiTsonga. The study findings have presented traits of tribalism as contributing to on-going demarcation disputes in Vuwani.
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Date Issued: 2020

Creating Citizen-Science for Groundwater Monitoring prior to potential Shale Gas Development in Cradock (South-Eastern Karoo, South Africa)

Authors: Dhliwayo, Nyaradzo
Date: 2020
Subjects: Natural gas -- Prospecting -- Environmental aspects -- South Africa
Language: English
Type: Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10948/48224 , vital:40526
Description: Citizen Science is an integral tool for community engagement in scientific project design, implementation, data interpretation and reporting, in the quest to promote local capacity development as well as scientific knowledge. Based on the relevance of public engagement in aspects of the natural environment and associated scientific issues associated with the risks and opportunities of potential Shale Gas Development (SGD), a Citizen-Science (CS) study was designed in the Eastern Karoo region of South Africa linked to a Shale Gas Baseline Study initiated by the Africa Earth Observatory Network (AEON). As the pilot area of the baseline study, the town of Cradock was chosen to be the study area for this research; and CS was used to facilitate the identification of the Cradock community’s abilities to monitor the effects of potential SGD in this region. The development of new knowledge, skills and support, as well as a deeper understanding of the community’s role in Citizen Science studies, was also facilitated by this process. This study demonstrates the feasibility of integrating Citizen Science into existing community structures in Africa, thereby encouraging community engagement in the developmental programmes through participatory methods. Using a collaborative Action-Research Approach, consistent community roundtable meetings and key informant interviews served as invaluable platforms for the establishment of a 7-member community working group, that played the liaison role between the researcher and the Cradock community in the CS implementation process. Coupled with this was the recruitment and the training of eight young citizens in conducting a hydro-census and groundwater sampling for six boreholes within the identified Cradock commonage farms, as well as two boreholes on the farm of an identified emergent farmer. The engagements between the researcher, AEON scientists, the community working group and the community at large, enabled the successful implementation of CS training in two groundwater monitoring aspects and the testing of eleven water quality parameters. The training process was combined with the design and the development of a customised ‘Xoras’ Online Application, which was used to capture and share the hydro-census data recorded. Experiential learning in hydro-census and groundwater sampling resulted subsequently in an increased understanding and awareness of these aspects (Figure A). Even if SGD does not materialise in the South-Eastern Karoo, CS training will enable communities in the Shale-Gas Development precincts to participate in local decision-making forums on ground water, health, or on any related regional development projects. It is anticipated that the adoption of CS will ix promote future community engagements, especially about water across this water-scarce region, allowing for greater community-voice representation in resource-policy decisions related to potential Shale-Gas and related natural resource industries in the Karoo.
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Date Issued: 2020

Data transport over optical fibre for ska using advanced modulation flexible spectrum technology

Authors: Dlamini, Phumla Patience
Date: 2020
Subjects: Fiber optics
Language: English
Type: Thesis , Doctoral , DPhil
Identifier: http://hdl.handle.net/10948/50666 , vital:42329
Description: Flexible Spectrum Dense Wavelength Division Multiplexed (DWDM) optical fibre networks are next-generation technology for handling extremely high data rates of the kind produced by MeerKAT and SKA.We optimise the flexible spectrum for real-time dynamic channel wavelength assignment, to ensure optimum network performance. We needed to identify and develop novel hardware and dynamic algorithms for these networks to function optimally to perform critical tasks. Such tasks include wavelength assignment, signal routing, network restoration and network protection. The antennas of the Square Kilometre Array (SKA) network connect to the correlator and data processor in a simple point-to-point fixed configuration. The connection of the astronomer users to the data processor, however, requires a more complex network architecture. This is because the network has users scattered around South Africa, Africa and the whole world. This calls for upgrade of the classical fixed wavelength spectrum grids, to flexible spectrum grid that has improved capacity, reliable, simple and cost-effectiveness through sharing of network infrastructure. The exponential growth of data traffic in current optical communication networks requires higher capacity for the bandwidth demands at a reduced cost per bit. All-optical signal processing is a promising technique to improve network resource utilisation and resolve wavelength contention associated with the flexible spectrum. Flexible Spectrum Dense Wavelength Division Multiplexed (DWDM) optical fibre networks are next-generation technology for handling extremely high data rates of the kind produced by MeerKAT and SKA. Each DWDM channel is capable of 10 Gbps transmission rate, which is sliceable into finer flexible grid 12.5 GHz granularity to offer the network elastic spectrum and channel spacing capable of signal routing and wavelength switching for the scalability of aggregate bandwidth. The variable-sized portions of the flexible spectrum assignment to end users at different speeds depend on bandwidth demand, allowing efficient utilisation of the spectrum resources. The entire bandwidth of dynamic optical connections must be contiguously allocated. However, there is an introduction of spectrum fragmentation due to spectrum contiguity related to the optical channels having different width. Thus large traffic demands are likely to experience blocking regardless of available bandwidth. To minimise the congestion and cost-effectively obtain high performance, the optical network must be reconfigurable, achievable by adding wavelength as an extra degree of freedom for effectiveness. This can introduce colourless, directionless and contentionless reconfigurability to route individual wavelengths from fibre to fibre across multiple nodes to avoid wavelength blocking/collisions, increasing the flexibility and capacity of a network. For these networks to function optimally, novel hardware and dynamic algorithms identification and development is a critical task. Such tasks include wavelength assignment, signal routing, network restoration and network protection. In this work, we for the first time to our knowledge proposed a spectrum defragmentation technique through reallocation of the central frequency of the optical transmitter, to increase the probability of finding a sufficient continuous spectrum. This is to improve network resource utilisation, capacity and resolve wavelength contention associated with a flexible spectrum in optical communication networks. The following chapter provides details on a flexible spectrum in optical fibre networks utilising DWDM, optimising transmitter-receivers, advanced modulation formats, coherent detection, reconfigurable optical add and drop multiplexer (ROADM) technology to implement hardware and middleware platforms which address growing bandwidth demands for scalability, flexibility and cost-efficiency. A major attribute is tunable lasers, an essential component for future flexible spectrum with application to wavelength switching, routing, wavelength conversion and ROADM for the multi-node optical network through spectrum flexibility and cost-effective sharing of fibre links, transmitters and receivers. Spectrum slicing into fine granular sub-carriers and assigning several frequency slots to accommodate diverse traffic demands is a viable approach. This work experimentally presents a spectral efficient technique for bandwidth variability, wavelength allocation, routing, defragmentation and wavelength selective switches in the nodes of a network, capable of removing the fixed grid spacing using low cost, high bandwidth, power-efficient and wavelength-tunable vertical-cavity surface-emitting laser (VCSEL) transmitter directly modulated with 10 Gbps data. This to ensure that majority of the spectrum utilisation at finer channel spacing, wastage of the spectrum resource as caused by the wavelength continuity constraint reduction and it improves bandwidth utilisation. The technique is flexible in terms of modulation formats and accommodates various formats with spectrally continuous channels, fulfilling the future bandwidth demands with transmissions beyond 100 Gbps per channel while maintaining spectral efficiency.
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Date Issued: 2020

Database and guide for Lesotho wool and mohair production and quality

Authors: Maqalika, Papali Elizabeth
Date: 2020
Subjects: Mohair -- Dissertations -- Lesotho , Wool -- Dissertations -- Lesotho Textile fabrics -- Lesotho Textile industry -- Lesotho
Language: English
Type: Thesis , Doctoral , DPhil
Identifier: http://hdl.handle.net/10948/49148 , vital:41605
Description: Lesotho produces significant quantities of Merino apparel wool and mohair, both of a quality that allows them to compete on the global market and to make a significant contribution to the economy of the country. Nevertheless, very little production and quality data and trends of these fibres have been documented. This is a serious disadvantage in terms of international trading and benchmarking as well as attempts to improve the production and quality of Lesotho wool and mohair. In the light of the aforementioned, the available production and quality data of the past 10 years have been captured and analysed for trends and also benchmarking, where considered applicable. The main focus is on fibre diameter (fineness), staple length, and yield since they largely determine fibre quality, application and price. Some quality related tests were undertaken to fill certain important gaps in the available data. In addition, prickle and medullation were evaluated on representative wool and mohair samples, respectively, because they represent important quality measures for apparel wool and mohair, respectively. It was found that Lesotho wool and mohair are of a fairly good and internationally competitive quality, with the wool having an average fibre diameter (MFD) of ≈20μm, an average staple length of about 64mm, an average VM level of about 4%, an average yield of about 57%, and the annual production being about 4 million kilograms greasy. The average staple length of the mohair was about 140mm, average MFD about 29μm and the average medullation, which unless otherwise specified, refers to the objectionable medullated fibres (kemp type) including the flat medullated fibre, relatively high at about 5.7%. The latter is certainly an area of concern which needs attention and improvement. It was found that the prickle level (Comfort Factor), of some of the wools tested was of such a level as to make the wool suitable for wearing against the skin. With respect to mohair, there is considerable scope to substantially reduce the level of objectionable medullated (kemp style) fibre level through the appropriate breeding interventions. Production of both wool and mohair has increased slightly over the ten years covered by this study. It also became apparent that Lesotho wool and mohair quality and production are greatly influenced by the farming practices and climatic conditions. Greater adoption of the merino sheep breed, sheds/barns and sheep coats are suggested as ways to reduce mortality rate (due to extremely cold temperatures), improve quality and increase yield and production. Some farming practices such as the lack of barns, supplementary feeding and veterinary care present constraints in terms of production of both wool and mohair. The districts in the Highlands region had the highest production of mostly wool, this being ascribed to better pastures, climatic and other conditions conducive to wool and mohair production. Both wool and mohair are considered to have potential for improved quality and production, which could be affected by appropriate interventions by the Small Agricultural and Development Project (SADP) and others through National Wool and Mohair Growers Association (NWMGA). Nevertheless, since the wool and mohair growers (farmers) do not form part of these and other interventions, they do not readily adopt the various strategies and decisions and do not receive the associated benefits immediately. It is therefore advised that local farmers, relevant educators and researchers be represented in policy and other decision making forums. In this way, educational campaigns will be demand driven with greater chance of adoption and success.
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Date Issued: 2020

Decision analysis to inform invasive alien plant management in the Garden Route Biosphere Reserve

Authors: Masunungure, Current
Date: 2020
Subjects: Invasive plants -- South Africa , Alien plants -- South Africa , Biodiversity -- South Africa -- Management , Ecosystem management -- South Africa
Language: English
Type: Thesis , Doctoral , DPhil
Identifier: http://hdl.handle.net/10948/49159 , vital:41606
Description: Invasive alien plants (IAP) pose significant threats to global economies and biodiversity and are often considered as wicked problems. With an increasing number of IAP and limited resources, their management and decision-making processes are becoming difficult because of uncertainty, multiple and conflicting objectives, and diverse stakeholder views, facts and values. This is particularly challenging given the complex interactions between economic, ecological, and social elements that exist in invaded areas. Consequently, it is important to incorporate new ways of thinking and novel methodologies to improve our understanding of IAP management and the decision-making processes around them, which are currently inadequate. Decision analysis can help with dealing with these challenges and support decision-making under uncertainty. Drawing on the systems thinking approach and the concepts of leverage points, transition management and transformational change, the aim of this thesis was to explore the effectiveness of IAP management and the decision-making process in the Garden Route Biosphere Reserve (GRBR). This was achieved using a mixed methods approach involving: social-ecological inventory (identifying relevant stakeholders); review of literature on the available decision support tools; key informant interviews (stakeholder perspectives on the current decision-making process); and stakeholder workshop and expert consultation (casual loop modelling). The results of this thesis provide evidence that application of the proposed principles of robust decision-making has the potential to overcome the weaknesses of the current decision-making process and as such, enables decision-makers to efficiently allocate resources towards IAS management. A novel causal loop diagram (CLD) was developed to highlight the interconnections between key variables in IAP management and decision-making. This revealed that to transcend ‘policy resistance’ and ‘quickfixes that fail’ archetypes, and improve IAP management, the stakeholders need to consider deep leverage points, for example, fostering trust and shared understanding among different stakeholder groups. These can be realistically maintained over the long-term and can cause a fundamental change in IAP management, rather than focusing on shallow leverage points that are relatively easy to implement but do not result in significant systemic change. The findings of this thesis are flexible and could guide various stakeholder groups at local, national, and international scales in improving the effectiveness of IAP management and decision-making.
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Date Issued: 2020

Derivative actions in contemporary company law: A comparative assessment from an enhanced accountability perspective

Authors: Hamadziripi , Friedrich
Date: 2020
Subjects: Judicial discretion
Language: English
Type: Thesis , Doctoral , LLD
Identifier: http://hdl.handle.net/10353/18336 , vital:42253
Description: The company is one of the most popular organisational vehicles for conducting business. The very nature of the company as a juristic person is attractive. The principle of legal personality entitles a company to act as a legal entity separate from its members. The principle was laid down in the landmark decision of Salomon v Salomon 1897 AC 22 (HL). This decision shows that a company is a full player in the legal arena. It has standing before the courts of law and is the proper plaintiff for wrongs done to it, not any of the stakeholders who may also be affected by the wrongdoing. However, it has to be noted that a company is just an artificial person. It is a fictitious being, a juristic person and a creature of statute. Therefore, even though a company has the capacity to acquire rights which can be enforced in a court of law and obligations which another legal subject can enforce against it, a company cannot in all respects be equated with a human person, for it has no physical substance. Inevitably, a director must act as its hands, brain, legs, mouth and eyes. Regardless of how financially strong a company can be, its juristic nature places all its resources and wealth at the mercy of its directors and officers. A company can neither protect itself against wrongdoing, vindicate nor enforce its rights without its representative directors and officers. If the wrongdoing faction in a company comprises of directors who are required to act in the best interests of the company, then who will enforce the company’s rights? The juristic nature of a company makes it vulnerable to abuse, especially by directors. It is important to note that internal stakeholders such as directors innocent of wrongdoing, employees and shareholders are not the only ones who stand to lose from the failure of corporate governance. External stakeholders’ interests too are vulnerable to abuse as a result of a company being abused by its leaders. There is, therefore, a need for a mechanism that controls abuse of power especially by agents of a company. Such a mechanism is critical to accountability as it protects the company from director malfeasance while promoting adherence to corporate governance principles in general. Also, successful derivative claims play a significant role in securing compensation for the company. Seeing that a company can be injured by both internal and external stakeholders, it is imperative that there be an effective and efficient mechanism that protects both the company and its owners without deterring entrepreneurship and stakeholder participation. Proceeding from an iii accountability enhancement perspective, this study undertakes a comparative assessment of the derivative action as a mechanism that created to deal effectively with the mischief revealed in the above paragraphs. For a complainant to be able to invoke the derivative action for relief, he or she must comply with certain requirements. Those requirements will be examined in greater detail with respect to the American, South African, English and Japanese laws. Empirical research has concluded that directors’ exposure to derivative claims remains largely theoretical. The critical question is whether the requirements for commencing or continuing a derivative action are too onerous. Although the remedy is available in theory, its shortcomings appear to make derivative actions almost impossible to invoke in practice. It has been argued that the greatest impediment to a derivative action by minority shareholders arises from the practical barriers to the commencement of derivative proceedings. With respect to the USA, it has further been demonstrated that there is a positive correlation between the significant decline in the importance of derivative litigation and the creation of additional legal hurdles in breach of directors’ duties cases. This study seeks to examine the various shortcomings of the remedy and suggest ways to make it less onerous as well as increase its availability to more stakeholders
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Date Issued: 2020

Design ethnography: methodological considerations for rebalancing socio-technical phenomena in CMS performativity

Authors: Jordaan, Leandra
Date: 2020
Subjects: Database management -- Social aspects , Information technology -- Social aspects , Management information systems -- Social aspects , Database management -- Philosophy , Information technology -- Philosophy , Management information systems -- Philosophy
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/164781 , vital:41164
Description: As a practitioner, I had been part of two Content Management System (CMS) Projects in a particular setting that did not deliver on the expected outcomes. The expected outcomes of the projects included streamlined processes, better access to information, functionalities to drive engagement, reduced time searching for information, and improved reusability of content. As I began to reflect on the projects, a certain discomfort developed when the social aspect was ignored in favour of the technological. I sought a better understanding, but I was unaware of the fact at first. The techno-centricity as a concept found in literature and my experience as content management (CM) practitioner – together informed my interest in rebalancing the social and the technological. Thus, I focused on conduct in performing of tasks and emphasised attention on the practices of experts who gave insight into context of CM and use. The research participants are communication practitioners who have the responsibility to communicate internally and externally on behalf of a publicly-funded university in South Africa. Guided by the abductive argument and literature, the key themes for the research focused on technology, individuals and the organisation. The focus on technology (CMS as a subfield of Information Systems) began with my involvement in two CMS Projects. What came to the fore was that the practitioner perspective, and thus their experiential knowledge are neglected in research and that it may be an over-emphasis on techno-centrism in CMS research. I sought to better balance the social and technological aspects. The second focus on individuals (communication practitioners) was to value the stakeholder who was considered representative of the worldviews of the community. I sought to support corporate communication practices in the task of relationship building with stakeholders. The findings showed that the culture of informatio sharing was low at the University. The third focus on the organisation (the University) was to prioritise the success of the communication undertaken by the University. I interrogated the role of power. I demonstrated how the role of power could be seen as productive and positive in the context of HE, the social reality of CUT, and this IS research itself. I positioned the research as interpretivistic. I used hermeneutics as a mode of analysis because as researcher-practitioner, I am part of the social reality of the research. A safeguard against my subjectivity was the use of Phronesis as an orientation to knowledge. An organisation with a shared understanding of ethics and values will balance instrumental rationality (scientific and technical reasoning) with value-rationality (moral reasoning about right and wrong actions). Phronesis is the virtue that should ensure ethical behaviour in actions, yet over time, social science research, in a quest to mimic the natural sciences, centred on episteme and techne. I constructed the lens by particularising the four value-rational questions of Flyvbjerg’s contemporary Phronesis to the performative perspective of the research. My interest in social reality, as well as socio-technical aspects, have led to design-ethnography (D-E) to emerge as the most suitable and most appropriate approach to the research. D-E asked the prescriptive ‘How’ and descriptive ‘What’ questions, whilst the Flyvbjergian Phronesis lens brought focus on the ‘Why’ question. D-E emphasised the betterment of the interaction and synergy between research conducted and practice. My status as an immersed researcher needed careful consideration, and D-E accepted that a certain level of immersion is necessary, D-E has short interventional fieldwork, and D-E has future-oriented engagement. The contemporary Phronesis used in the research is to enact D-E and not an all-encompassing guide for doing Phronesis research The key contributions to the research are predominantly methodological. The claims draw on evidence focused on the three themes technology, individuals and organisation, and the phenomena of interest which are to rebalance the social and the technological in CM practices. The first claim is that immersion in the context is possible and supported by the specific particularised approaches to the research. The second claim suggests a way to rebalance the socio-technical nature of Information Systems (IS). The third claim suggests that there is a viewpoint for power that is not focused on power’s oppressive nature which could see a diverging focus on power in IS research in future. In this viewpoint, the status quo of social reality is not questioned, nor are their emancipatory ambitions. The fourth and final claim suggests that Phronesis as a lens could enact D-E, which in turn is a method that assists in valuing the experience of the practitioner and the support of collaborative work. The research is recommended for IT/IS practitioners who prefer to value participants’ views in design. The approaches used could be of value for researchers who consider the context of their research to be of higher importance than the generalisation of outcomes. Researchers who find themselves in the position of being immersed in the context but question the correctness of active engagement in the field may discover some value from the research approaches and my experience. Also, researchers or practitioners who have an interest in the balance between social and the technological aspects of IS projects. Researchers or practitioners interested in Phronesis, and perhaps the viewpoint of a lens may also find value in this research.
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Date Issued: 2020

Designing a parental involvement programme to enhance parental engagement in the educational support programme at a disadvantaged primary school in the Nelson Mandela Bay Metropole, South Africa through participatory action research

Authors: WIlliams, Pearl Juanita Cherrol
Date: 2020
Subjects: Education -- Parent participation -- South Africa -- Nelson Mandela Bay Municipality
Language: English
Type: Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10948/47303 , vital:39841
Description: Over the past decades parental involvement in education has increased rapidly within disadvantaged schools in South Africa. This transformation is evident in the legislation of the country which celebrates a spirit of Ubuntu in a democratised society, and, education at large. The ideal of effective school-home partnership across racial boundaries are, for example, emphasised and strengthened via parental involvement at all public schools. Parents, according to the Department of Education (DoE, 1996b:11; 2000c:29; 2001b:29; 2008:23; 2009:17; 2014b:27; n.d.:6), are considered key role-players in school governance and encouraged to support equal educational opportunities for all learners. It implies that the praxis of parental involvement – especially at disadvantaged schools – is a huge benefit to learners with existing backlogs in education. In relation to this view, Stofile and Green (2007:63) emphasise the significance of parental involvement in school life as it can assist greatly in addressing the divere needs of disadvantaged learners. The dynamics associated with parental involvement are investigated in this study through two cycles of participatory action research. Initially ten parents from one of the disadvantaged primary schools within the Nelson Mandela Bay Metropole were purposively selected to participate in an in-depth qualitative research study pertaining to the design of a suitable parental involvement programme for disadvantaged learners. All the relevant information was gathered during action learning sets, individual interviews, and observations to triangulate the data and fill in possible gaps. This data was coded and categorised throughout the cyclical process via inductive participatory data analysis, as described by Patton (2015:216 & 551). Three main themes with sub-themes emerged from the study, namely (1) deficits of the academic programme: remedial education, teacher-assistants, homeworksupport, technical abilities; (2) the neglect of social wellness programmes: need for parental guidance, necessary professional assistance, upgrading of safety measures, availability of clothing bank, sustainability of a nutritional programme; and (3) voids in communication and relationships: the home environment, community, school environment. These themes and sub-themes successfully answered all the research questions. An increasing number of learners at disadvataged primary schools are neglected and/or leave school at a very young age. This scenario is often linked to poor communication and/or a lack of adequate educational support programmes to enhance better learning outcomes. The design of a PIP aimed to address the diverse needs of learners at a specific disadvantaged primary school with the full cooperation of their parents. Nested within the Ecological Model of Bronfenbrenner, the participating parents were engaged in comprehensive discussions about educational support programmes that the school could embark on with them. Numerous programmes were identified as fundamental to transforming the quality of education for many disadvantaged learners. This research therefore encouraged greater parental involvement at disadvantaged primary schools in order to sustain better learning outcomes.
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Date Issued: 2020

Determination of nonlinear optical properties of phthalocyanine regioisomers using computational models

Date: 2020
Subjects: Electrochemistry , Phthalocyanines , Nanoparticles , Nonlinear optics , Nonlinear optical spectroscopy , Refraction
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/166197 , vital:41337
Description: This work investigates the effects of the nonlinear optical properties of four different constitutional isomers (C4h, C2v, Cs, and D2h) of a series of tetrasubstituted phthalocyanines (free-base 3-4-tert-butylphenoxyether phthalocyanines, free-base 4-4-tertbutylphenoxyether phthalocyanines, SnCl2 tetra substituted 3-4-tert-butylphenoxyether phthalocyanine, and SnCl2 tetra substituted 4-4-tert-butylphenoxyether phthalocyanine). The properties investigated were the real and imaginary components of the 3rd order hyperpolarizability, as well as the excited state absorption and refraction cross sections. The investigations were performed with a z-scan over a range of laser beam intensities. This work determined the imaginary component of the 3rd order hyperpolarizability for the free-base and SnCl2 3-4-tert-butylphenoxyether phthalocyanines and 4-4-tert-butylphenoxyether phthalocyanines to be highly dependent on the excited state cross sections. The refraction caused due to the real component of the 3rd order hyperpolarizability of the phthalocyanines was also investigated, however, the values found were strongly dependent on the laser beam intensity and the cause of this was investigated. A Five-level model was developed and run on GPGPU computing devices in order to isolate the absorption and refractive cross sections. Theeffects of the regio substitution on the excited state cross sections were also investigated, and the 1st singlet excited state and 1st triplet state absorption cross sections were calculated for all constitutional isomers. It was found that the symmetry of the constitutional isomers have a disproportionately large effect on the excited state absorption when compared to the ground state absorption. The nonlinear refractive properties of all constitutional isomers were also investigated, and the values of the parametric susceptibility are reported herein. The nonlinear refraction was found to have less effect than was seen in the nonlinear absorption. The 1st singlet excited state and 1st triplet state refractive cross sections of all constitutional isomer was determined. The results indicated that if more than one excited state was present and contributing to the nonlinear refraction, then more data than was collected here would be required. However, the 1st singlet excited state cross section were successfully determined for the free-base constitutional isomers. This work concluded that the region substitution affected the excited states more than the ground state.
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Date Issued: 2020

Developing macroinvertebrate trait- and taxonomically-based approaches for biomonitoring wadeable riverine systems in the Niger delta, Nigeria

Authors: Edegbene, Ovie Augustine
Date: 2020
Subjects: Water – Pollution -- Nigeria -- Niger River Delta , Stream health -- Nigeria -- Niger River Delta , Water -- Pollution -- Measurement , Environmental monitoring -- Nigeria -- Niger River Delta , Water quality -- Nigeria -- Niger River Delta , Water quality biological assessment -- Nigeria -- Niger River Delta , Aquatic invertebrates -- Nigeria -- Niger River Delta , Stream restoration -- Nigeria -- Niger River Delta , Urban agriculture -- Nigeria -- Niger River Delta , Stream ecology -- Nigeria -- Niger River Delta
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/140660 , vital:37907
Description: Riverine systems are increasingly subjected to pollution due to rapid urbanisation, industrialisation, and agricultural activities. Increasing pollution in freshwater systems impairs water quality, causes biodiversity loss and impairs aquatic ecosystem functionality and supply of ecosystem services. Rivers in the Niger Delta region of Nigeria are particularly vulnerable to urban pollution and agricultural activities as natural forests are increasingly replaced by urbanisation and agriculture. The differential effects of these pressures on the ecological processes of these river systems are poorly explored, as is the development of appropriate biomonitoring tools for routine monitoring of river health. In this study, a physico-chemically-based approach and macroinvertebrate trait- and taxonomic- approaches were developed to better understand the effects of multiple pressures on riverine systems, while developing multimetric indices to enable sustainable management of rivers within the region. Sixty-six stations in 20 river systems within the Edo and Delta States of the Niger Delta ecoregion were monitored seasonally for a period of five (2008–2012) years. The physico-chemically based approach makes apparent the extent of degradation of rivers and streams in the Niger Delta. For each dominant land use type, river stations were classified into least impacted stations (LIS), moderately impacted stations (MIS) or heavily impacted stations (HIS). Of 11 stations within urban catchments, only two were considered least impacted, suggesting that urgent measures are necessary to revise the current trajectories of urban rivers within the region. Most of the stations designated as MIS and HIS in the urban and urban-agriculture catchments were found to be significantly correlated with increased nutrients, EC and BOD5. Characteristics of most of the MIS and HIS within rivers in urban catchments evidenced the so-called urban stream syndrome, a state of persistent degradation of urban streams. The results of the traits and ecological preferences approach showed traits sensitive to urban and urban-agriculture pollution. Traits and ecological preferences that were associated with the LIS include the possession of hardshell, moderate and high sensitivities to oxygen depletion, very large body sized individuals (>20-40mm), swimmers, flattened body shape, a preference for temporary attachment, crawling, respiration with aerial/vegetation, possession of breathing tubes, possession of strap or other apparatus for respiration, streamlined body, and a high sensitivity to oxygen depletion. Permanent attachment as an ecological preference associated with LIS was also positively correlated with increasing dissolved oxygen (DO) and was deemed a pollution sensitive ecological preference. The possession of very small body size (<5mm), associated with HIS, was deemed a pollution-tolerant trait and was negatively correlated with DO, confirming the deteriorating state of the urban and urban-agricultural rivers. The impact of urban-forestry pollution on the distribution pattern of macroinvertebrate traits and ecological preferences was also explored in the selected rivers. Traits and ecological preferences such as possession of hard-shell, large body size, and grazing as a feeding preference which were significantly positively associated with the LIS, were also either significantly positively correlated with DO, or significantly negatively correlated with increasing any two of flow velocity, water temperature, BOD5 and nutrient. These traits and ecological preferences were deemed sensitive in forested rivers receiving urban pollution. Further, burrowing, the pupa aquatic stage, and predation which were significantly positively associated with HIS on the RLQ ordination, were also significantly negatively associated with DO. These traits were deemed tolerant of forested systems receiving urban pollution. Multimetric indices (MMI) were developed, validated and applied for urban, urban-agriculture and urban-forested (MMI-urban, MMI-urban-agric and urban-forest) areas. Of the 26 metrics that satisfactorily discriminated between the LIS, the MIS, and the HIS for MMI-urban, only five metric were retained for integration into MMI-urban, they are log VeL, Hemiptera abundance, % Coleoptera + Hemiptera, % Chironomidae + Oligochaeta and Evenness index. Further, of the 18 metrics that satisfactorily discriminated between the LIS, the MIS, and the HIS for MMI-urban-agric, only 12 metrics were retained and nine proved to be redundant. The nine metrics represent different measures; two of them were retained in addition to Chironomidae/Diptera abundance, % Odonata and Oligochaeta richness. The two metrics selected in addition to the hironomidae/Diptera abundance, % Odonata and Oligochaeta richness were the Margalef index and the logarithm of relative abundance of sprawler. For the MMI-urban-forest, 14 metrics satisfactorily discriminated between the LIS, the MIS, and the HIS, and 12 metrics were retained and 11 proved to be redundant. The non-redundant metric was Trichoptera abundance. Three metrics were further selected in addition to the Trichoptera abundance which include % Chironomidae + Oligochaeta, Coleoptera + Hemiptera richness and Shannon diversity. The MMI-urban and MMI-urban-agric indices performed better for LIS designated stations compared to the MIS and HIS deignated stations. The developed indices proved effective as biomonitoring tools for assessing the ecological health of rivers in the urban and urban-agriculture catchments within the Niger Delta. Overall, the results of the macroinvertebrate traits and ecological preferences, and taxonomic approaches showed the strength in the complementarity of both approaches in developing biomonitoring tools for assessing levels of deterioration in riverine systems. The study contributes significantly to understanding the ecology of riverine systems in the Niger Delta, particularly those subject to urban stresses, agricultural activities and urban pollution in forested systems, and thus makes an important contribution to the science and practice of biomonitoring in Nigeria where such studies are sparse.
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Date Issued: 2020

Development of a UV-tolerant strain of the South African isolate of Cryptophlebia leucotreta granulovirus for use as an enhanced biopesticide for Thaumatotibia leucotreta control on citrus

Authors: Mwanza, Patrick
Date: 2020
Subjects: Baculoviruses -- South Africa , Ultraviolet astronomy
Language: English
Type: Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10948/48533 , vital:40885
Description: Baculoviruses are pathogenic to insects in the orders Diptera, Hymenoptera, and Lepidoptera. As a result of this natural relationship with insects they provide an environmentally friendly method to combat crop and forest pests. As such, a number of baculoviruses have been formulated into biopesticides. The use of baculovirus biopesticides is gaining popularity as the use of chemical pesticides has come under stringent regulatory conditions imposed by governments and continental blocks such as the European Union. Baculoviruses have a narrow host range and therefore do not harm non-pests or humans who consume the crops. One such baculovirus is Cryptophlebia leucotreta granulovirus (CrleGV), which is pathogenic to the citrus pest Thaumatotibia leucotreta, commonly referred to as the false codling moth (FCM). CrleGV has an occlusion body (OB) that encloses a single virion. Several CrleGV biopesticides have been registered in South Africa for use on citrus, avocadoes, macadamias, grapes and other crops by two commercial producers, River Bioscience (SA) and Andermatt (Switzerland). These biopesticides are used as part of the FCM integrated pest management (IPM) programme, a multifacetted approach to controlling FCM. However, baculoviruses are susceptible to the ultraviolet (UV) radiation component of sunlight and lose their activity within hours to a few days, after exposure to UV. Several substances have been tested as UV protectants to improve the persistence of baculovirus biopesticides in the field. These include optical brighteners, UV absorbers and anti-oxidants. While very promising in the laboratory, UV-protectants have not been as successful in the field. A few published reports have reported, that UV-tolerant baculoviruses could be isolated from a population by repeatedly exposing and re-exposing the virus to UV irradiation with a propagation step in insect host fourth or fifth instars between each exposure cycle. In this study, the South African isolate of Cryptophlebia leucotreta (CrleGV-SA) was exposed to UV irradiation for 5 exposure cycles in a Q-Sun Xe-3 HC test chamber (Qlab, USA) with parameters set to mimic a typical summer day in the Sundays River Valley, Eastern Cape Province, in South Africa. In between exposures the virus survivors were allowed to multiply in FCM fifth instars. Surface dose bioassays were also conducted to determine the LC50 of the virus after each exposure cycle. Samples from exposure cycle 1 and cycle 5 (UV-tolerant) irradiated for 72 h were prepared for Next Generation Sequencing (NGS) of DNA. The resultant sequence data were analysed using the Geneious R11 software (New Zealand) and compared with the unexposed CrleGV-SA sequence. In-silico restriction enzyme analsysis (REN) with several enzymes was also carried on both the cycle 1 and cycle 5 exposed samples and the resulting digestion patterns were compared with the original CrleGV-SA digestion patterns. The same samples were also analysed by transmission electron microscopy (TEM) and Attenuated Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) to evaluate the effect of UV irradiation on the structure of the CrleGV-SA OB. In addition, three UV protectants, lignin sulphate (Sappi, SA), BREAK-THRU®OE446 (OE446) (Evonik Industries, Germany) and Uvinul Easy (BASF, Germany) were prepared with CrleGV-SA to give final protectant concentrations of 0.09 %, 0.9 % and 9 %. The protectant-virus suspensions were exposed to UV for 24 h in the Q-Sun test chamber and bioassays conducted to determine the protective effect of each protectant concentration. The most successful protectants were then combined with the UV-tolerant CrleGV-SA and exposed to UV for 24 h in the Q-Sun test chamber and surface dose bioassays conducted afterwards. Samples exposed to UV in cycle 5 had lower LC50 values compared to samples in the early cycles. With each re-exposure cycle the LC50 values moved closer to that of the unexposed control. The LC50 of virus samples decreased from 2.89 x 108 OBs/ml after 24 h UV-exposure in cycle 1 to 2.16 x 105 OBs/ml after the same duration of exposure in cycle 5; and from 2.11 x 109 OBs/ml in cycle 1 after 72 h UV-exposure to 1.73 x 106 OBs/ml after the same duration of exposure. This represented a 1338-fold difference and a 1220-fold difference, respectively. When the UV-tolerant samples were sequenced seven SNPs were identified in cycle 1, which were thought to help establish UV tolerance, while a further seven SNPs were identified in cycle 5 samples; these were thought to further establish and maintain the UV-tolerance. Additionally, REN analysis with EcoR1 for both test samples yielded digestion patterns that were different from those of the original CrleGV-SA. TEM data showed that UV damages the virion as well as the crystalline structure of the OB. This is the first time visual evidence for UV damage to baculoviruses has been published. Comparison of cycle 1 and cycle 5 UV exposed OBs revealed that the cycle 5 OBs were significantly larger than the cycle 1 OBs (P<0.05). In addition, several peaks in the fingerprint region were shown to have either appeared or disapeered from the ATR-FTIR spectra after UV irradiation. However, there was no difference in the spectra of the Cycle 1 and Cycle 5 virus samples. The tests with potential UV-protectants revealed that the 0.9 % lignin, 9 % OE446 and 9 % Uvinul Easy were the most effective in protecting the virus from UV. However, there was no significant difference in their protection of UV tolerant CrleGV-SA and wild type CrleGV-SA. Going forward, it is recommended that the 0.9 % lignin, 9 % OE446 and 9 % Uvinul Easy combinations be explored further in future studies, particulary in the field. This study therefore forms an important foundation for the development of UV-tolerant baculovirus that will last longer in the field.
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Date Issued: 2020

Development of bio-based xylan composites for food packaging applications

Authors: Naidu, Darrel Sarvesh
Date: 2020
Subjects: Xylanases
Language: English
Type: Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10948/48544 , vital:40886
Description: Currently a large number of chemicals and plastics are produced from petroleum-based resources. However, due to the concerns surrounding the depletion of petroleum resources and growing carbon emissions, there is a desire to produce chemicals and plastics from renewable and carbon natural sources. Lignocellulosic biomass (biomass consisting of cellulose, lignin and hemicellulose) is the most common biomass on earth and is renewable and carbon neutral. Of the three main constituents of lignocellulosic biomass, hemicellulose is composed of a mixture of sugars which can be converted into chemicals and plastics. The most common form of hemicellulose found in nature is xylan. This study is aimed at extracting xylan from maize stalk waste residues and the development of xylan films with properties that are suitable for food packaging applications. Xylan was extracted from maize stalk waste residues using an alkaline pre-treatment method. The effects of bleaching conditions (time, temperature and bleach concentration) prior to alkaline treatment on the yield and purity of xylan extracted was studied using a Box-Behnken experimental design. It was observed that the experimental conditions tested had no effect on the yield of the xylan extracted but the bleach concentration had a significant effect on the purity of the xylan extracted. The samples with the lowest lignin content were found to be the samples treated with 3wt% bleach prior to alkaline pre-treatment. One of the main disadvantages of xylan is that it has poor film forming properties, a method of overcoming this is to combine it with another abundantly available biopolymer that has good film forming properties, such as alginate. The effect of xylan, alginate and glycerol content on the mechanical, thermal, moisture uptake and water barrier properties of the films were investigated. It was observed that with an increase in the alginate content there was an increase in the tensile strength and Young’s modulus of the films, whereas the water vapour permeability (WVP) of the films decreased. This was attributed to the greater cohesion between alginate polymer chains compared to the cohesion between xylan polymer chains. The xylanalginate films exhibited better optical and water sorption properties at higher xylan content. In order to improve the inherently poor mechanical and barrier properties of the xylan-alginate films, bentonite and halloysite were incorporated into the films. It was found that 5wt% incorporation of either bentonite or halloysite resulted in a 49% decrease of the WVP, which was attributed to water vapour impermeable nature of the silicate layers that make up both clays. The incorporation of the clays into the xylan-alginate matrix resulted in a significant
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Date Issued: 2020

Development of MOVPE-grown InAsSb for barrier diode applications

Authors: Dobson, Stephen R
Date: 2020
Subjects: Gallium arsenide semiconductors , Electronics
Language: English
Type: Thesis , Doctoral , DPhil
Identifier: http://hdl.handle.net/10948/49071 , vital:41598
Description: In this study, layers of GaSb, InAs and InAsSb are grown by metalorganic vapour phase epitaxy and characterised. Growth is conducted using the precursors of trimethylgallium, trimethylindium, trimethylantimony and tertiarybutylarsine. Focus is then placed on the characterisation of the materials, carried out by the techniques of X-ray diffraction, photoluminescence spectroscopy, Hall measurements and photocurrent spectroscopy. It is observed that V/III ratio plays a vital role in the growth of the GaSb and InAsSb layers. Epilayers of GaSb showed best crystalline quality when a V/III ratio of 1.2 was used at a growth temperature of 600 °C and a cell pressure of 600 Torr. Resultant Hall measurements indicated p-type GaSb. The Hall carrier concentrations of the p-type GaSb samples were analyzed considering electrical neutrality conditions and found to be highly compensated with evidence of band impurity conduction at low measurement temperatures. Both the donor and acceptor concentrations were determined to be of the order of 1016 cm−3 for all samples. For low temperature (< 150 K) a monovalent acceptor concentration is calculated to have an activation energy at approximately 20 meV. At high temperature (> 150 K) a divalent acceptor is extracted with an activation energy varying between samples based on compensation in a range of 90 meV to 70 meV. Photoluminescence measurements show four peaks with recombination mechanisms linked to the native acceptor identified in literature as either the gallium antisite and/or vacant gallium site. A fifth peak observed is attributed to the longitudinal phonon of the native acceptor. InAs and InAsSb epilayer are all grown at a temperature of 600 °C and cell pressure of 600 Torr. InAs is grown at a V/III ratio of 9.5 on GaAs substrate. Photoluminescence of the InAs layer shows two distinct peaks, one of which is an extrinsic band to band recombination. The other is attributed to free electron to acceptor or a donor-acceptor pair transition. An additional weak peak is also observed which is assigned to the longitudinal phonon of the band to band. InAsSb growth was conducted under a range of V/III ratios of 4.8 to 5, with a vapour phase composition of 0.4 to 0.435. Structural analysis via X-ray diffraction showed a 6 % to 12 % solid antimony content. Photoluminescence exhibited a single broad peak for all samples, with extended band tails. Temperature and power dependant analysis of luminescence indicated a convolution of extrinsic band to tail and band to band recombinations. Hall measurements indicated the InAsSb was n-type material with an apparent measured maximum mobility at 120 K of 9.5 × 103 cm2/V.s. and a room temperature apparent mobility of 7.5 × 103 cm2/V.s. Analysis of hall results using a two-layer model calculated a true bulk mobility of the epilayer at room temperature with an increased value of 15.4 × 103 cm2/V.s. The two-layer model details the effects of the surface conduction. From photoconductivity measurements and further analysis a resultant effective lifetime, at room temperature, was found to be on same order of magnitude as that of InAs materials. Application of a single Einstein oscillator extrapolated 0 K energy gaps for two samples of solid Sb contents of 6 % and 12 %, of 354 meV and 332 meV, respectively. Finally consideration was given to the growth of aluminium containing compounds, particularly AlGaSb. Multiple phases were observed under scanning electron microscope showing growth of GaSb regions surrounded by amorphous solid aluminium and/or aluminium oxide phases. The failure of the aluminium to incorporate into the desired crystal structure is speculated to be due to impure precursor introducing oxygen into the films. Additionally, the effectiveness of the gallium precursor compared to the aluminium precursor in helping the removal of the methyl groups at the growth surface, could also promote a preference for GaSb growth.
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Date Issued: 2020

Development of Tio 2 nanostructure arrays for photonic extraction of hydrogen gas

Authors: Suliali, Nyasha Joseph
Date: 2020
Subjects: Nanostructures , Nanostructured materials Hydrogen
Language: English
Type: Thesis , Doctoral , DPhil
Identifier: http://hdl.handle.net/10948/49314 , vital:41620
Description: Amid the energy crisis of the 21st century, renewable energy is a thriving field of study, light harvesting materials being a central theme due to the abundance of solar energy. Nanostructured TiO2 is the most studied photocatalysis material, since the discovery of its energy harvesting properties by Fujishima and Honda in 1972. Environmentally friendly products such as hydrogen fuel, can be produced using TiO2 due to its non-toxicity, chemical stability and photocatalytic activity. The surprising aspect of this important material is that it can be prepared using cost-effective methods such as hydrothermal synthesis, solution gelation and anodic oxidation. This research focused on the three key elements required to develop TiO2 photoelectrodes i.e. the deposition of Ti films on transparent substrates, a thorough analysis of the chemistry of the anodic oxidation process and the development of the TiO2 thin films. Glass substrates that have Ti films are the base component for TiO2 photoelectrode production. Ti films with thicknesses up to 4 μm, were developed on commercial F-doped SnO2 (FTO) glass substrates using high-power impulse magnetron sputtering (HiPIMS). The sputter deposition experiments were performed in the 1 to 8 kW range at a substrate temperature of 500 °C and Ar pressure of 400 mPa. At higher powers, thicker films were deposited, resulting in increased intensity of Xray-diffraction peaks. However, on comparing the XRD patterns, the (001) peak outgrew the rest regardless of thickness of the film. The deposition process therefore favoured orientation of most of the α-Ti phase crystallites with the [001] axis perpendicular to the substrate surface. Surface roughness results were interesting, showing a non-linear dependence of the surface roughness on HiPIMS pulse energy in the 1 to 8 kW range. The surface roughness is highest at the starting deposition power of 1450 W and reduces to a minimum at 4500 W. From this minimum, it increases to its second highest value at 7900 W. From this data, the parameters required to produce Ti films of lowest surface roughness, for deposition on commercial Technistro® FTO glass, were deduced at the inflection point, where the deposition power was 4500 W. The surface roughness obtained is a critical result for the anodic production of quality TiO2 photoelectrodes, which if high, leads to uneven etching, thus irregular and inefficient photoelectrodes. Direct current magnetron sputtering was also carried out in the 1 to 5 kW range to obtain ratios of power-normalised growth rates of the Ti films. This investigation provided the Ti films on FTO glass, the transparent, conductive substrates which were used to develop TiO2 photoelectrodes. To elucidate the chemistry of anodic oxidation of Ti, a mathematical model of the anodic current density, which had not been reported at the time of its publication, was developed. The technique, a highlight of this research, is a predictive numerical computation of the instantaneous quantities of species that participate in the anodization process. From eleven chemical reactions, 14 first order ordinary differential equations were compiled using the principles of chemical reaction kinetics. The pattern, transient behaviour and response to anodization parameters of the current density signal, were successfully predicted. Strong agreement between the model and measurements was demonstrated in seven experiments. The results confirm that the current density signal is a numerical integral of the kinetics of redox reactions of water. The bulk of this research was on the development of TiO2 nanotubular arrays on Ti foil substrates and Ti films on FTO glass. TiO2 films with well-defined tubular structures were synthesised. The films were developed in anhydrous, polar organic hosts with water and etching agents in the range of 10 V to 70 V. The control of geometrical properties of the tubes such as the length, pore diameter, wall thickness, tube separation and number of nanotubes per unit area was demonstrated. Anatase only and mixed anatase-rutile phase compositions were obtained at different annealing temperatures. Nanotubes with diameters as small as 20 nm and thickness as high as 29 μm were produced. Apart from an increase in nanotube thickness, a decrease in distance between nanotubes grown in diethylene glycol was observed at longer anodization times. Studies of the effects of anodization parameters on the current density measured, morphological and crystallographic properties of the nanotube films were conducted in three main investigations. The first was the study of the effect of anodization parameters on current density. Besides the obvious increase of current density with anodic voltage, the first steady state of the growth process was found to depend on the NH4F concentration. The second investigation focused on the effect of accelerated growth of TiO2 nanotubular films. In the study, 9 μm-thick nanotube films were synthesised at twice the growth rate of a 9 μm-thick control sample. The array obtained by accelerated growth had distinguishable nanotubes, however, the morphological quality was reduced. The third investigation demonstrates the control of the number of nanotubes per unit area. By varying the etchant content, the anodic voltage and the viscosity of the electrolyte host, various distributions were obtained. The research ends with a photoelectrochemical application: measurement on photocurrents generated in a two-electrode setup. The photocurrent densities measured in the off and on conditions were 30 nA/cm2 and 2.57 μA/cm2, respectively, demonstrating photoactivity of the developed films.
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Date Issued: 2020

Diversion Programmes and Empowerment: A Case Study of Young Offenders’ Experiences in the Buffalo City Metropolitan and Amathole District Municipalities in the Eastern Cape Province of South Africa

Authors: Mangwiro, Vongai P
Date: 2020
Subjects: Social work with criminals Social work with juvenile delinquents
Language: English
Type: Thesis , Doctoral , PhD (Social Work)
Identifier: http://hdl.handle.net/10353/18031 , vital:42006
Description: Crime amongst the young in South Africa has been high since the attainment of democracy in 1994. Diversion programmes were established through the National Framework Chid Justice Act of 2008, as part of a plethora of measures to curb the ever spiralling problem of crime amongst the youth. The purpose of this thesis was to investigate the experiences of young offenders regarding their empowerment vis-à-vis diversion programmes in the Buffalo City Metropolitan and Amathole District Municipalities in the Eastern Cape Province. Underpinned by the Empowerment and Social Control Theories, the study adopted a qualitative research paradigm and used focus group discussions and in-depth interviews amongst thirty-five young offenders and five social workers, who work as probation officers at NICRO, to collect data, which was analysed using thematic analysis. The major findings indicated that diversion programmes are effective in reducing the number of children who commit crimes in these two municipalities and in influencing their behavioural change, resulting in fewer chances of re-offending. The Life Skills Programme was identified as the most effective programme, in comparison to the other programmes, such as the Community pre-trial Service Programme, in changing the behaviour of the young offenders, as it helps them to discover themselves; learn respect for the self and others in the community; help with family and community reintegration; and helps them focus on who they want to be in the future. In spite of such positive attributes for the diversion programmes, the study observed that there are challenges being faced by the implementing organisation, NICRO. These include high caseloads; lack of support from the probation officers who refer young offenders; limited support from parents; paucity of financial resources; lack of transport; poor v coordination from the courts; and delays in the implementation of some accredited but not credited programmes. Overall, the study concluded that diversion programmes in the Buffalo city Metropolitan and Amathole district municipalities in the Eastern Cape suffer due to weak partnerships between different organisations and stakeholders that are supposed to complement the efforts of the judiciary. From the research findings above, it is recommended that the Child Justice System should promote a multi-sectored approach in order to restore and reunify all the stakeholders, working with children in conflict with the law. This adds more roles and responsibilities for the various stakeholders, such as the Department of Justice and Department of Social development. Furthermore, there is a need to increase the monitoring and evaluation of diversion programmes to advance accountability and improve effectiveness; and there is a need to enhance the efficiency of accrediting authorities to timeously accredit other diversion programmes that, so far, have not yet been accredited, but may be useful in empowering young offenders. Therefore, the study proposes an extension of the framework with additions of strategies to support diversion programmes at NICRO, through a stakeholder extension to the model allocating more roles and responsibilities for stakeholders in the Child Justice system, in order for diversion programmes to effectively achieve desired goals.
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Date Issued: 2020

Dynamics of stimulated luminescence in natural quartz: Thermoluminescence and phototransferred thermoluminescence

Authors: Folley, Damilola Esther
Date: 2020
Subjects: Thermoluminescence , Quartz
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/146255 , vital:38509
Description: Natural quartz has remained an important mineral that is of topical interest in luminescence and dosimetry-related research. We investigate the dynamics of stimulated luminescence on this material through thermoluminescence (TL) and phototransferred thermoluminescence (PTTL). Measurements were made on unannealed natural quartz as well as quartz annealed at 800 and 1000̊C. The samples were annealed for 10 minutes and for 1 hour. The material, in its un- and annealed state has its main peak between 68 and 72̊C when measured at 1Cs ̃1 after a dose of 50 Gy. A study of dosimetric features and kinetic analysis was carried out on two prominent peaks, peak I and III for all the samples. The peaks show a sublinear dose response for irradiation doses between 10 and 300 Gy. Kinetic analysis shows that peak I is a first-order peak and peak III a general-order peak. Interestingly, we observe for peak I for the sample annealed at 800̊C for 1 hour an inverse thermal quenching behaviour. We demonstrate that a peak affected with an inverse thermal quenching-like behaviour can still show effect of thermal quenching when the dose the sample is irradiated to is significantly reduced. We ascribe the apparent dependence of thermal quenching on dose to competition between radiative and non-radiative transitions at the recombination centre. Peaks I, II, and III for all the samples were reproduced under phototransfer when the peaks, initially removed by preheating to a certain temperature are exposed to 470 and 525 nm light. The infuence of duration of illumination on the PTTL intensity of these peaks corresponding to various preheating temperatures is modelled using coupled first-order dfferential equations. The model is based on systems of acceptors and donors whose number and role depends on preheating temperature
Full Text:
Date Issued: 2020

Ecological assessment of a temperate river system using biomonitoring techniques: a case study of the Bloukrans River system, South Africa

Authors: Magadze, Tinotenda
Date: 2020
Subjects: Bloukrans River , Ecological assessment (Biology) -- South Africa , Stream ecology -- South Africa , Rivers -- Environmental aspects -- South Africa , Benthic animals -- Effect of human beings on -- South Africa , Water quality biological assessment -- South Africa , Diatoms -- South Africa -- Data processing
Language: English
Type: text , Thesis , Doctoral , PhD
Identifier: http://hdl.handle.net/10962/142933 , vital:38177
Description: Escalating pressures from growing human populations and environmental impacts increasingly imperil freshwater ecosystems. The Bloukrans River, which drains an urbanised and agricultural catchment in the Eastern Cape province of South Africa, is no exception. Detailed knowledge of the structure and function of the aquatic ecosystems is required in order to create models and matrices that predict, guide assessment and direct intervention on ecological integrity and water quality management in these systems. The main objectives of this research were to: examine the effects of urbanization on the benthic macroinvertebrate functional feeding guild structure among different stream orders; determine if benthic diatoms can be used as effective and reliable indicators of ionic composition and conductivity in different stream order categories and finally; to evaluate the applicability of the South African Diatom Index (SADI) and other indices in the Eastern Cape region of South Africa. Field studies were carried out to explore temporal patterns in community structure (macroinvertebrates and diatoms) and ecosystem function related to land-use patterns, instream habitat availability, and water quality parameters in the Bloukrans River system across four study periods: February (summer) and July (winter) 2016 and February (summer) and May/July (winter) 2018. The study was conducted along a gradient of impacts from less impacted agricultural headwaters to highly impacted urban sites located immediately downstream of the city of Makhanda. Macroinvertebrates were separated into functional feeding groups (FFGs) (i.e. collector-gatherer, collector-filterer, scraper, shredder, and predator) which were then used to assess the effects of selected physico-chemical variables and riparian zone condition on FFG organization. Collector-gatherers were the most abundant in the Bloukrans River and represented 71.3 % of the macroinvertebrate assemblages. Stream order 1species such as Nitzschia palea, Gomphonema parvulum, Tryblionella apiculata, Diploneis vulgaris and Staurosira elliptica. Multivariate analysis (Canonical correspondence analysis (CCA)) indicated that differences in diatom community assemblages were best explained by calcium, magnesium, pH, phosphate, nitrate, dissolved oxygen, sediment nitrate, conductivity and salinity. These results indicate that diatoms can be used as bioindicators for monitoring highly impacted river systems and to also further examine pollution gradients and impacts of specific/point pollution sources. In order to further test the application of diatom indices, nine sites with contrasting water quality were sampled along the length river system in February, May and July 2018. Diatom-based indices incorporated in OMNIDIA software were applied to assess the integrity of the water quality as indicated by diatom communities. For comparative purposes, several foreign indices (e.g. the trophic diatom index (TDI), the percentage pollution-tolerant valves (%PTV), biological diatom index (BDI)) and the South African Diatom Index (SADI) were used in the study. From the results, the Percentage Pollution-Tolerant Valves (%PTV) of most urban sites in the Bloukrans River was above the 20% limit indicating the presence of organic pollutants. Although the foreign diatom indices were applicable in the study, the SADI had significant correlations with most water quality variables (p < 0.05) compared to other indices such as Watanabe Index (WAT), Biological Index of Water Quality Trophic Index (BIWQ) and Trophic Index (TI)). These results support wider use of the SADI as an indicator of water quality conditions in South African river systems. Finally, the observed variations in diatom community structure and composition as a result of changes in water quality were broadly in agreement with the results of macroinvertebrate FFG structure indicating that the two biological indicators can, and should, be used as complementary techniques in the biomonitoring of rivers and streams in South Africa.
Full Text:
Date Issued: 2020

Showing items 81 - 100 of 3066

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Diversion Programmes and Empowerment: A Case Study of Young Offenders’ Experiences in the Buffalo City Metropolitan and Amathole District Municipalities in the Eastern Cape Province of South Africa

Dynamics of stimulated luminescence in natural quartz: Thermoluminescence and phototransferred thermoluminescence

Ecological assessment of a temperate river system using biomonitoring techniques: a case study of the Bloukrans River system, South Africa