A new continuum mapping procedure at HartRAO
- Authors: Büchner, Sarah
- Date: 2012-06-19
- Subjects: Hartebeesthoek Radio Astronomy Observatory , Radio astronomy -- Methodology , Galactic cosmic rays
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5510 , http://hdl.handle.net/10962/d1007766 , Hartebeesthoek Radio Astronomy Observatory , Radio astronomy -- Methodology , Galactic cosmic rays
- Description: A basket weaving technique for making radio continuum maps has been developed at the Hartebeesthoek Radio Astronomy Observatory (HartRAO). This data reduction technique significantly reduces scanning effects by using independent maps scanned in orthogonal directions. The observation and data analysis procedures that were developed are presented. The technique was used to map the supernova remnant MSH 15-52 at frequencies of 5000 MHz and 8500 MHz. The flux spectral index for this supernova remnant was found to be 0.83 ± 0.02 in this frequency range. Two regions (A and B) of the Galactic plane were observed at 8500 MHz with a resolution of 6'. Region A covered the 5°x5° area 47.5°< k 52.5°, Ibl < 2.5°, and region B was the 4.2°x3° area 320.4°< I <334.6°, Ibl < 1.5°. Far infrared observations at 60 !lm were used in conjunction with the radio maps to separate the thermal and non-thermal components of the radio emission. The technique can be used to map the Galactic plane at 8500 MHz using dual polarisation once the receiver at HartRAO has been upgraded. This would fulfil a need for a medium resolution, high frequency survey of the southern Galactic plane. , Adobe Acrobat Pro 9.4.6 , Adobe Acrobat 9.46 Paper Capture Plug-in
- Full Text:
- Authors: Büchner, Sarah
- Date: 2012-06-19
- Subjects: Hartebeesthoek Radio Astronomy Observatory , Radio astronomy -- Methodology , Galactic cosmic rays
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5510 , http://hdl.handle.net/10962/d1007766 , Hartebeesthoek Radio Astronomy Observatory , Radio astronomy -- Methodology , Galactic cosmic rays
- Description: A basket weaving technique for making radio continuum maps has been developed at the Hartebeesthoek Radio Astronomy Observatory (HartRAO). This data reduction technique significantly reduces scanning effects by using independent maps scanned in orthogonal directions. The observation and data analysis procedures that were developed are presented. The technique was used to map the supernova remnant MSH 15-52 at frequencies of 5000 MHz and 8500 MHz. The flux spectral index for this supernova remnant was found to be 0.83 ± 0.02 in this frequency range. Two regions (A and B) of the Galactic plane were observed at 8500 MHz with a resolution of 6'. Region A covered the 5°x5° area 47.5°< k 52.5°, Ibl < 2.5°, and region B was the 4.2°x3° area 320.4°< I <334.6°, Ibl < 1.5°. Far infrared observations at 60 !lm were used in conjunction with the radio maps to separate the thermal and non-thermal components of the radio emission. The technique can be used to map the Galactic plane at 8500 MHz using dual polarisation once the receiver at HartRAO has been upgraded. This would fulfil a need for a medium resolution, high frequency survey of the southern Galactic plane. , Adobe Acrobat Pro 9.4.6 , Adobe Acrobat 9.46 Paper Capture Plug-in
- Full Text:
A nutritional evaluation of effluent grown algae and zooplakton as feed ingredients for Xiphohorous helleri, Poecilia reticulata and Poecilia velifera (Pisces : Poeciliidae)
- Authors: Potts, Warren M
- Date: 1998
- Subjects: Poeciliidae , Poeciliidae -- Nutrition , Zooplankton , Algae , Poeciliidae -- Feeding and feeds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5306 , http://hdl.handle.net/10962/d1005151 , Poeciliidae , Poeciliidae -- Nutrition , Zooplankton , Algae , Poeciliidae -- Feeding and feeds
- Description: The aim of this study was to evaluate the nutritional value of algae and zooplankton grown in an algal integrated ponding system for poeciliids. The available information on the nutritional requirements of poeciliids was compared with a proximate analysis of the algae and zooplankton. The effluent grown algae and zooplankton had a crude protein value of 41.47 ± 0.2% and 36.84 ± 0.3%, a lipid content of 4.8 ±. 0.4% and 11.1 ± 0.8% and a carbohydrate content of 35.13 ± 0.8% and 31.06 ± 0.6% respectively. These values compared favourably with those of the known nutritional requirements of poeciliids. To test if the nutritional value of the algae and zooplankton in the AlPS was constant, the species composition of the algae and the crude protein content of the algae and zooplankton in the high rate oxidation ponds were measured monthly and bi-weekly for a year respectively. The species composition remained fairly stable for the duration of the experiment and the average protein composition of the algae and zooplankton was 43.4 ± 4.4% and 38.6 ±2.8% respectively. This indicated that the algae and zooplankton in the AlPS provided high protein biomass through the year. The quality of the effluent grown algal and zooplankton biomass was evaluated by analysing their amino acid composition and comparing it with the amino acid composition of the body tissue of X. helleri. With respect to the amino acid composition of the body tissue of X. helleri, the amino acid profile of the algae had a 69% and the zooplankton a 63% similarity. The quality of the pure algal and zooplankton protein was also tested biologically, by feeding them directly to poeciliids during a ten week growth trial. The algae and zooplankton diets did not result in adequate growth compared to poeciliids which were fed a formulated control diet. The initial growth trial also evaluated the effect of processing on the chemical composition of the algae and its biological effect on fish fed with it. There were no significant differences in the chemical composition of fresh and sun dried algae and this was reflected in the growth rates of the fish which did not differ significantly. Freeze dried algae had a lower crude protein content than fresh and sun dried algae and a poorer amino acid composition. Fish fed freeze dried algae exhibited poorer growth and survival in comparison to the other treatments. The gut transit times of X. helleri and the gastric evacuation times of poeciliids were determined using colour dyes incorporated in the diet and by sacrificing fish at predetermined intervals after feeding respectively. The gut transit time of X. helleri fed a sun dried algal diet and a formulated diet was 225 ± 8.55 minutes and 261.93 ± 10.86 minutes respectively. The gastric evacuation times of X. helleri, P. reticu/ata and P. velifera were 7, 9 and 8 hours respectively. Since the maximum amount of food in the hindgut after feeding was detemined to be 3, 5 and 3 hours in X. helleri, P. reticulata and P. velifera respectively, fish were sacrificed at these times in the digestibility study. The digestibility of sun dried algae was determined using 1 % chromic oxide as an internal marker in the algae. The apparent crude protein digestibility of sun dried effluent grown algae ranged from 65%-75% in the three poeciliid species. Based on the results of the chemical and biological analysis of the algae and zooplankton, conventional diets incorporating algae at 5% and 20% protein inclusion levels were formulated. These diets and a treatment in which zooplankton, reared in the AlPS were fed as a dietary supplement to a formulated diet were fed to poeciliids for twelve weeks. No significant differences in the growth of poeciliids fed any of the test diets were observed. It was concluded that the algae could be incorporated into poeciliid formulated diets up to level of 20% protein inclusion without any negative effect on the growth of the fish. The chemical and biological evaluation of the algae suggested that it had a similar nutritional quality to soyabean meal. Poeciliid growth was not enhanced with a zooplankton supplement, however a possible low feeding rate by poeciliids on the zooplankton as a result of their small size may have affected the result. The colour enhancement potential of effluent grown algae and zooplankton was evaluated biologically in ten and twelve week growth trials using visual observation (31 people) and by using a chromameter. While pure, sun dried algae significantly enhanced the colour of P. reticulata, no significant differences in the colour of poeciliids were observed or recorded when fish were fed diets incorporating sun dried algae up to levels of 20% protein inclusion. The effect of effluent grown algae and zooplankton on poeciliid health was also tested biologically in the ten and twelve week growth trials. The high mortalities (75%-84%) recorded for X. hel/eri when fed the pure algal and zooplankton diets were considered to be as a result of the nutritional inadequacy of the diets since there were significantly less mortalities in fish fed the formulated control diet and 63% of the fish that died during the course of the trial were emaciated. In addition, fewer mortalities (10%-40%) were recorded in X. hel/eri fed the nutritionally adequate formulated diets in the twelve week growth trial. No symptoms of disease were recorded in the twelve week growth trial and the algae was considered to have no toxicological or pathological effects on poeciliids. Centrifugation, sand filtration, sedimentation, microstraining and biological harvest were evaluated as methods of small scale algal harvest from the high rate oxidation ponds. Algae could be harvested most efficiently with little associated labour by sedimentation (without flocculating agents) and by microstraining with 60IJm mesh. Effluent grown algae can replace conventional feed ingredients up to a level of 20% protein inclusion without negatively effecting the growth, colour, health or survival of poeciliids.
- Full Text:
- Date Issued: 1998
- Authors: Potts, Warren M
- Date: 1998
- Subjects: Poeciliidae , Poeciliidae -- Nutrition , Zooplankton , Algae , Poeciliidae -- Feeding and feeds
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5306 , http://hdl.handle.net/10962/d1005151 , Poeciliidae , Poeciliidae -- Nutrition , Zooplankton , Algae , Poeciliidae -- Feeding and feeds
- Description: The aim of this study was to evaluate the nutritional value of algae and zooplankton grown in an algal integrated ponding system for poeciliids. The available information on the nutritional requirements of poeciliids was compared with a proximate analysis of the algae and zooplankton. The effluent grown algae and zooplankton had a crude protein value of 41.47 ± 0.2% and 36.84 ± 0.3%, a lipid content of 4.8 ±. 0.4% and 11.1 ± 0.8% and a carbohydrate content of 35.13 ± 0.8% and 31.06 ± 0.6% respectively. These values compared favourably with those of the known nutritional requirements of poeciliids. To test if the nutritional value of the algae and zooplankton in the AlPS was constant, the species composition of the algae and the crude protein content of the algae and zooplankton in the high rate oxidation ponds were measured monthly and bi-weekly for a year respectively. The species composition remained fairly stable for the duration of the experiment and the average protein composition of the algae and zooplankton was 43.4 ± 4.4% and 38.6 ±2.8% respectively. This indicated that the algae and zooplankton in the AlPS provided high protein biomass through the year. The quality of the effluent grown algal and zooplankton biomass was evaluated by analysing their amino acid composition and comparing it with the amino acid composition of the body tissue of X. helleri. With respect to the amino acid composition of the body tissue of X. helleri, the amino acid profile of the algae had a 69% and the zooplankton a 63% similarity. The quality of the pure algal and zooplankton protein was also tested biologically, by feeding them directly to poeciliids during a ten week growth trial. The algae and zooplankton diets did not result in adequate growth compared to poeciliids which were fed a formulated control diet. The initial growth trial also evaluated the effect of processing on the chemical composition of the algae and its biological effect on fish fed with it. There were no significant differences in the chemical composition of fresh and sun dried algae and this was reflected in the growth rates of the fish which did not differ significantly. Freeze dried algae had a lower crude protein content than fresh and sun dried algae and a poorer amino acid composition. Fish fed freeze dried algae exhibited poorer growth and survival in comparison to the other treatments. The gut transit times of X. helleri and the gastric evacuation times of poeciliids were determined using colour dyes incorporated in the diet and by sacrificing fish at predetermined intervals after feeding respectively. The gut transit time of X. helleri fed a sun dried algal diet and a formulated diet was 225 ± 8.55 minutes and 261.93 ± 10.86 minutes respectively. The gastric evacuation times of X. helleri, P. reticu/ata and P. velifera were 7, 9 and 8 hours respectively. Since the maximum amount of food in the hindgut after feeding was detemined to be 3, 5 and 3 hours in X. helleri, P. reticulata and P. velifera respectively, fish were sacrificed at these times in the digestibility study. The digestibility of sun dried algae was determined using 1 % chromic oxide as an internal marker in the algae. The apparent crude protein digestibility of sun dried effluent grown algae ranged from 65%-75% in the three poeciliid species. Based on the results of the chemical and biological analysis of the algae and zooplankton, conventional diets incorporating algae at 5% and 20% protein inclusion levels were formulated. These diets and a treatment in which zooplankton, reared in the AlPS were fed as a dietary supplement to a formulated diet were fed to poeciliids for twelve weeks. No significant differences in the growth of poeciliids fed any of the test diets were observed. It was concluded that the algae could be incorporated into poeciliid formulated diets up to level of 20% protein inclusion without any negative effect on the growth of the fish. The chemical and biological evaluation of the algae suggested that it had a similar nutritional quality to soyabean meal. Poeciliid growth was not enhanced with a zooplankton supplement, however a possible low feeding rate by poeciliids on the zooplankton as a result of their small size may have affected the result. The colour enhancement potential of effluent grown algae and zooplankton was evaluated biologically in ten and twelve week growth trials using visual observation (31 people) and by using a chromameter. While pure, sun dried algae significantly enhanced the colour of P. reticulata, no significant differences in the colour of poeciliids were observed or recorded when fish were fed diets incorporating sun dried algae up to levels of 20% protein inclusion. The effect of effluent grown algae and zooplankton on poeciliid health was also tested biologically in the ten and twelve week growth trials. The high mortalities (75%-84%) recorded for X. hel/eri when fed the pure algal and zooplankton diets were considered to be as a result of the nutritional inadequacy of the diets since there were significantly less mortalities in fish fed the formulated control diet and 63% of the fish that died during the course of the trial were emaciated. In addition, fewer mortalities (10%-40%) were recorded in X. hel/eri fed the nutritionally adequate formulated diets in the twelve week growth trial. No symptoms of disease were recorded in the twelve week growth trial and the algae was considered to have no toxicological or pathological effects on poeciliids. Centrifugation, sand filtration, sedimentation, microstraining and biological harvest were evaluated as methods of small scale algal harvest from the high rate oxidation ponds. Algae could be harvested most efficiently with little associated labour by sedimentation (without flocculating agents) and by microstraining with 60IJm mesh. Effluent grown algae can replace conventional feed ingredients up to a level of 20% protein inclusion without negatively effecting the growth, colour, health or survival of poeciliids.
- Full Text:
- Date Issued: 1998
A profile of young sex offenders in South Africa : a pilot study
- Authors: Wood, Catherine Jane
- Date: 1998
- Subjects: Sex offenders -- Psychology , Paraphilias , Sex offenders -- South Africa -- Psychology , Teenage sex offenders -- South Africa -- Psychology , Teenage sex offenders
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3089 , http://hdl.handle.net/10962/d1002598 , Sex offenders -- Psychology , Paraphilias , Sex offenders -- South Africa -- Psychology , Teenage sex offenders -- South Africa -- Psychology , Teenage sex offenders
- Description: In-depth interviews and psychometric tests were conducted with 20 young, South African male, hands-on sex offenders, between the ages of seven and 15 years. These offenders were referred by both the legal system and the welfare and health system. The data was gathered for the purpose of drawing up a descriptive profile of salient psychological and sociological characteristics of this population group, the patterns of offenses, the circumstances under which the offenses occurred and victims selected. Results showed that half the sample had committed prior sex offenses. The majority of young sex offenders had a history of consenting sexual interactions, had committed a non-sexual offense and engaged in a range of other antisocial behaviours. Half the sample reported a history of physical or sexual abuse (under-reporting of such victimization experiences was suspected). Typically, the young sex offender w:~s sexually naive and had not received any suitable sex education. He was usually a scholar although his school attendance was often infrequent and he was likely to have failed one or more standards. His intelligence quotient was most likely to fall in or below the borderline range of functioning. He tended to be either socially isolated and socially anxious or alternatively reported having a number of friends and appeared to have adequate social skills. His home environment was typically characterized by overcrowding, alcohol abuse and domestic violence. A significant male relative of his was likely to have committed a criminal offense. In his community environment, he regularly witnessed violence and sexual activity. The sex offenses were usually carried out with a co-perpetrator in a variety of venues. The victim was usually known and younger (mean age = seven years) than the perpetrator (mean age = 12 years). The overall results suggest that young sex offenders commit an array of sexual offenses that do not represent sexual experimentation, but rather indicate a developing pattern of sexual deviance. Comparisons between the above profile and the literature findings are explored. Finally, recommendations for structural changes, assessment procedures, additional future research pessibilities and guidelines for the development of appropriate - treatment programmes are outlined.
- Full Text:
- Date Issued: 1998
- Authors: Wood, Catherine Jane
- Date: 1998
- Subjects: Sex offenders -- Psychology , Paraphilias , Sex offenders -- South Africa -- Psychology , Teenage sex offenders -- South Africa -- Psychology , Teenage sex offenders
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3089 , http://hdl.handle.net/10962/d1002598 , Sex offenders -- Psychology , Paraphilias , Sex offenders -- South Africa -- Psychology , Teenage sex offenders -- South Africa -- Psychology , Teenage sex offenders
- Description: In-depth interviews and psychometric tests were conducted with 20 young, South African male, hands-on sex offenders, between the ages of seven and 15 years. These offenders were referred by both the legal system and the welfare and health system. The data was gathered for the purpose of drawing up a descriptive profile of salient psychological and sociological characteristics of this population group, the patterns of offenses, the circumstances under which the offenses occurred and victims selected. Results showed that half the sample had committed prior sex offenses. The majority of young sex offenders had a history of consenting sexual interactions, had committed a non-sexual offense and engaged in a range of other antisocial behaviours. Half the sample reported a history of physical or sexual abuse (under-reporting of such victimization experiences was suspected). Typically, the young sex offender w:~s sexually naive and had not received any suitable sex education. He was usually a scholar although his school attendance was often infrequent and he was likely to have failed one or more standards. His intelligence quotient was most likely to fall in or below the borderline range of functioning. He tended to be either socially isolated and socially anxious or alternatively reported having a number of friends and appeared to have adequate social skills. His home environment was typically characterized by overcrowding, alcohol abuse and domestic violence. A significant male relative of his was likely to have committed a criminal offense. In his community environment, he regularly witnessed violence and sexual activity. The sex offenses were usually carried out with a co-perpetrator in a variety of venues. The victim was usually known and younger (mean age = seven years) than the perpetrator (mean age = 12 years). The overall results suggest that young sex offenders commit an array of sexual offenses that do not represent sexual experimentation, but rather indicate a developing pattern of sexual deviance. Comparisons between the above profile and the literature findings are explored. Finally, recommendations for structural changes, assessment procedures, additional future research pessibilities and guidelines for the development of appropriate - treatment programmes are outlined.
- Full Text:
- Date Issued: 1998
A study of the transdermal drug diffusion properties of rooperol tetra-acetate
- Authors: Pefile, Sibongile C.
- Date: 1998 , 2013-08-29
- Subjects: Transdermal medication , Skin absorption , Dermatologic agents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3838 , http://hdl.handle.net/10962/d1007649 , Transdermal medication , Skin absorption , Dermatologic agents
- Description: The rapidly growing interest in the potential use of topical drug delivery formulations has resulted in increased use of the skin as a vital port for drug delivery. Extensive research has been conducted in designing vehicles capable of delivering a desired amount of drug to a specific site, to produce the desired pharmacological response. Rooperol tetra-acetate is a lipophilic, cytotoxic drug with the potential for use in the treatment of solar keratosis. For effective pharmacological action, delivery of the drug to the epidermal/dermal junction of the skin is required. A study of the topical penetration properties of rooperol tetra-acetate from different topical bases, each possessing different physico-chemical properties, was performed. The assessment involved a comparison of the diffusion properties under occlusive and non occlusive conditions when the drug was formulated into a gel, Cetomacrogol Cream B.P. (oil-inwater), Simple Ointment B.P. and an extemporaneously prepared water-in-oil topical cream. The in vitro experiments were conducted using polydimethylsiloxane and rat membrane mounted in a Franz diffusion cell. The topical permeation kinetics of rooperol tetra-acetate were determined by exploring the release characteristics of the active ingredient from the vehicles formulated and the permeability properties of the drug through the membranes employed. Further studies involved investigating the utilization of supersaturated systems intended to increase the thermodynamic activity of the drug when formulated into a propylene glycol/water vehicle (with and without polymer). To measure the release of rooperol tetra-acetate into the skin from a topical base it was necessary to, firstly, develop a suitable quantitative method for the analysis of the active drug in the aqueous receptor phase of in vitro diffusion cells. The second stage of product development was the design of an effective delivery system to facilitate the release of the diffusant from its base. A high performance liquid chromatographic method was utilized for the identification and quantification of the active drug. As validation is an important aspect in the development and subsequent utilization of an analytical procedure, the developed HPLC technique was validated by determining the precision, accuracy, range, limit of quantitation and sensitivity of the system. Lastly, the stability of rooperol tetra-acetate at elevated temperatures was assessed and a stability profile of the drug was generated for the three-month period of analysis. The results obtained following chromatographic analysis of the receptor phase sampled during the diffusion experiments indicate that the gel and oil-in-water formulations most effectively promoted the diffusion of rooperol tetra-acetate across polydimethylsiloxane membrane. The water-in-oil system exhibited lower flux rates and the ointment showed the least drug release. Occlusion of the topical vehicle increased the diffusitivity of the permeant from all formulations analysed. The permeation assessment results of the supersaturated systems showed enhanced diffusion of rooperol tetra-acetate across polydimethylsiloxane and rat membrane. The high thermodynamic activity existing in supersaturated systems most effectively increased the driving force for drug diffusion resulting in enhanced percutaneous penetration of rooperol tetra-acetate beyond the release and transport limitations of saturated solutions. These results provide the basis on which an effective topical drug delivery vehicle may be designed for this new drug entity.
- Full Text:
- Date Issued: 1998
- Authors: Pefile, Sibongile C.
- Date: 1998 , 2013-08-29
- Subjects: Transdermal medication , Skin absorption , Dermatologic agents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3838 , http://hdl.handle.net/10962/d1007649 , Transdermal medication , Skin absorption , Dermatologic agents
- Description: The rapidly growing interest in the potential use of topical drug delivery formulations has resulted in increased use of the skin as a vital port for drug delivery. Extensive research has been conducted in designing vehicles capable of delivering a desired amount of drug to a specific site, to produce the desired pharmacological response. Rooperol tetra-acetate is a lipophilic, cytotoxic drug with the potential for use in the treatment of solar keratosis. For effective pharmacological action, delivery of the drug to the epidermal/dermal junction of the skin is required. A study of the topical penetration properties of rooperol tetra-acetate from different topical bases, each possessing different physico-chemical properties, was performed. The assessment involved a comparison of the diffusion properties under occlusive and non occlusive conditions when the drug was formulated into a gel, Cetomacrogol Cream B.P. (oil-inwater), Simple Ointment B.P. and an extemporaneously prepared water-in-oil topical cream. The in vitro experiments were conducted using polydimethylsiloxane and rat membrane mounted in a Franz diffusion cell. The topical permeation kinetics of rooperol tetra-acetate were determined by exploring the release characteristics of the active ingredient from the vehicles formulated and the permeability properties of the drug through the membranes employed. Further studies involved investigating the utilization of supersaturated systems intended to increase the thermodynamic activity of the drug when formulated into a propylene glycol/water vehicle (with and without polymer). To measure the release of rooperol tetra-acetate into the skin from a topical base it was necessary to, firstly, develop a suitable quantitative method for the analysis of the active drug in the aqueous receptor phase of in vitro diffusion cells. The second stage of product development was the design of an effective delivery system to facilitate the release of the diffusant from its base. A high performance liquid chromatographic method was utilized for the identification and quantification of the active drug. As validation is an important aspect in the development and subsequent utilization of an analytical procedure, the developed HPLC technique was validated by determining the precision, accuracy, range, limit of quantitation and sensitivity of the system. Lastly, the stability of rooperol tetra-acetate at elevated temperatures was assessed and a stability profile of the drug was generated for the three-month period of analysis. The results obtained following chromatographic analysis of the receptor phase sampled during the diffusion experiments indicate that the gel and oil-in-water formulations most effectively promoted the diffusion of rooperol tetra-acetate across polydimethylsiloxane membrane. The water-in-oil system exhibited lower flux rates and the ointment showed the least drug release. Occlusion of the topical vehicle increased the diffusitivity of the permeant from all formulations analysed. The permeation assessment results of the supersaturated systems showed enhanced diffusion of rooperol tetra-acetate across polydimethylsiloxane and rat membrane. The high thermodynamic activity existing in supersaturated systems most effectively increased the driving force for drug diffusion resulting in enhanced percutaneous penetration of rooperol tetra-acetate beyond the release and transport limitations of saturated solutions. These results provide the basis on which an effective topical drug delivery vehicle may be designed for this new drug entity.
- Full Text:
- Date Issued: 1998
A survey of the development of pitch perception theories, their application to bell sounds and an investigation of perceived differences between ringing and chiming bells
- Authors: Botha, Alison
- Date: 1998
- Subjects: Music -- Acoustics and physics , Musical pitch , Change ringing , Chimes , Bells
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:2631 , http://hdl.handle.net/10962/d1002296 , Music -- Acoustics and physics , Musical pitch , Change ringing , Chimes , Bells
- Description: A brief overview of the workings of the human auditory system is followed by a review of literature concerning both the theories and experimental investigations of human pitch perception. The application of these theories to the inharmonic complex tones produced by bells is discussed, and further experiments using bell sounds are reviewed. A methodology for psychoacoustic experiments with specific reference to those investigating pitch perception of inharmonic complex tones is presented. This methodology is then implemented in an experimental investigation of pitch perception of ringing and chiming bell sounds. A pitch matching experiment using ringing and chiming sounds from four bells aimed to determine perceived pitch differences between ringing and chiming bells. This experiment was inconclusive because insufficient data was collected. Known experimental results, such as the inability of non-musicians to match the pitches of sounds with different timbres were confirmed. Spectral analyses of the stimuli were performed. The presentation of stimuli at a low level of sensation is questioned, as this might have prevented pseudo high frequency noise resulting from stronger upper partials in the ringing sound from being audible, and hence the pitch differences between ringing and chiming bells would not be observed.
- Full Text:
- Date Issued: 1998
- Authors: Botha, Alison
- Date: 1998
- Subjects: Music -- Acoustics and physics , Musical pitch , Change ringing , Chimes , Bells
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:2631 , http://hdl.handle.net/10962/d1002296 , Music -- Acoustics and physics , Musical pitch , Change ringing , Chimes , Bells
- Description: A brief overview of the workings of the human auditory system is followed by a review of literature concerning both the theories and experimental investigations of human pitch perception. The application of these theories to the inharmonic complex tones produced by bells is discussed, and further experiments using bell sounds are reviewed. A methodology for psychoacoustic experiments with specific reference to those investigating pitch perception of inharmonic complex tones is presented. This methodology is then implemented in an experimental investigation of pitch perception of ringing and chiming bell sounds. A pitch matching experiment using ringing and chiming sounds from four bells aimed to determine perceived pitch differences between ringing and chiming bells. This experiment was inconclusive because insufficient data was collected. Known experimental results, such as the inability of non-musicians to match the pitches of sounds with different timbres were confirmed. Spectral analyses of the stimuli were performed. The presentation of stimuli at a low level of sensation is questioned, as this might have prevented pseudo high frequency noise resulting from stronger upper partials in the ringing sound from being audible, and hence the pitch differences between ringing and chiming bells would not be observed.
- Full Text:
- Date Issued: 1998
A synthetic and spectrometric study of the initial phases in urea-formaldehyde resin formation
- Authors: Nocanda, Xolani Wittleton
- Date: 1998
- Subjects: Phenolic resins , Gums and resins, Synthetic
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4383 , http://hdl.handle.net/10962/d1005048 , Phenolic resins , Gums and resins, Synthetic
- Description: In a series ofpreIiminary studies of urea-formaldehyde reactions, the influence of the U:F molar ratio, the temperature and the catalyst were investigated. Subsequently, in a more rigorous evaluation of the influence of four variables on urea-formaldehyde resin formation, viz., U:F molar ratio, pH, temperature and reaction time, a set of twenty reactions were performed using a statistical approach. The results indicate that high resin viscosity is best achieved by using a high U:F molar ratio (1:2) and conducting the reaction at 90°C. Several basic components produced in urea-formaldehyde reactions have been synthesised, characterised by NMR spectroscopy, silylated using bis(trimethylsilyl)trifluoroacetamide and analysed by low resolution mass spectrometry. The use oftriazones as cross-linking agents has been investigated, and a series of 5-substituted triazones have been prepared and their mass fragmentation patterns explored using a combination of low and high resolution mass spectrometry. In order to facilitate interpretation of ¹³C NMR data obtained for U-F resins, internal rotation in various urea derivatives was investigated using variable temperature ¹H and ¹³C NMR spectroscopic study. Signal splittings observed below 247 K have been rationalised in terms of various rotameric structures.
- Full Text:
- Date Issued: 1998
- Authors: Nocanda, Xolani Wittleton
- Date: 1998
- Subjects: Phenolic resins , Gums and resins, Synthetic
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4383 , http://hdl.handle.net/10962/d1005048 , Phenolic resins , Gums and resins, Synthetic
- Description: In a series ofpreIiminary studies of urea-formaldehyde reactions, the influence of the U:F molar ratio, the temperature and the catalyst were investigated. Subsequently, in a more rigorous evaluation of the influence of four variables on urea-formaldehyde resin formation, viz., U:F molar ratio, pH, temperature and reaction time, a set of twenty reactions were performed using a statistical approach. The results indicate that high resin viscosity is best achieved by using a high U:F molar ratio (1:2) and conducting the reaction at 90°C. Several basic components produced in urea-formaldehyde reactions have been synthesised, characterised by NMR spectroscopy, silylated using bis(trimethylsilyl)trifluoroacetamide and analysed by low resolution mass spectrometry. The use oftriazones as cross-linking agents has been investigated, and a series of 5-substituted triazones have been prepared and their mass fragmentation patterns explored using a combination of low and high resolution mass spectrometry. In order to facilitate interpretation of ¹³C NMR data obtained for U-F resins, internal rotation in various urea derivatives was investigated using variable temperature ¹H and ¹³C NMR spectroscopic study. Signal splittings observed below 247 K have been rationalised in terms of various rotameric structures.
- Full Text:
- Date Issued: 1998
An assessment of the South African east coast linefishery from Kei Mouth to Stil Bay
- Authors: Brouwer, Stephen Leonard
- Date: 1998
- Subjects: Fisheries -- Research -- South Africa , Fisheries -- Environmental aspects -- Research -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5233 , http://hdl.handle.net/10962/d1005076 , Fisheries -- Research -- South Africa , Fisheries -- Environmental aspects -- Research -- South Africa
- Description: During the period April 1994 and February 1996 as part of an investigation into the national Iinefishery, the east coast shore fishery and the recreational and commercial ski-boat fisheries were surveyed, at eight sites between Kei Mouth in the East and Stil Bay in the West. Roving creel, access point and aerial surveys were used. A questionnaire was developed for each sector to gather data on catch and effort, fisher demographics, economics, fisher attitudes towards, and knowledge of, the current management regulations and assess the efficacy of the fisheries inspectorate. During the access point survey the catch of 3273 fishers was inspected and 1556 interviews were conducted. Questionnaires were conducted on 118 recreational ski-boaters and the catch of 165 boats was inspected. 96 commercial skippers were interviewed and 230 had their catch inspected. Three aerial surveys of the entire area were conducted during which a total of 1067 shore fishers were counted giving a shore fisher density of 0.39 fishers.km⁻¹. The majority (99%) of participants in all sectors of the linefishery were male. The greatest number of participants were white, shore fishery 77% recreational ski-boat 98% commercial skiboat 89%, followed by coloured, asian and black people. To a large extent this reflects the income of various racial groups. Most fishers supported the current linefish management plan. However, when tested on their knowledge of the size limits, bag limits and closed seasons of their target species many shore fishers (59%) did not know them and a high proportion of fishers in all sectors had disobeyed at least one of the regulations (shore 50%, recreational ski-boat 70%, commercial ski-boat 56%). When compared to historical data the present catch per unit effort (CPUE) in all sectors has decreased. Most interviewees in the various sectors did not accept responsibility for the decline in CPUE, but attributed it to three principal reasons vis their perceived direct competitors, trawling and pollution. Analysis of the catch revealed that all sectors were multispecies fisheries, with each sector being characterised by a small number of target species. Catch composition differed significantly between the shore and ski-boat sectors, but there was significant overlap between the two skiboat sectors. Analysis of the catch in comparison to that reported to the National Marine Linefish System (NMLS) revealed that there was a substantial degree of under-reporting. There was little seasonal difference in effort in the shore fishery while the recreational ski-boat effort was highest in the summer and the commercial ski-boat effort was high in the winter. Effort in the shore and recreational ski-boat fisheries was concentrated over weekends while the commercial ski-boat effort was highest during weekdays. Total effort for the entire area was estimated at 903 186 (±1913) fisher days per annum in the shore fishery, 24 357 (±685) recreational ski-boat fisher days and 64 266 (±1686) commercial ski-boat fisher days. Expenditure and capital investment in the various sectors was calculated, as were earnings of the participants in the commercial ski-boat sector. The linefishery in the Eastern Cape was estimated to have a minimum capital investment in excess of R210 million and more than R32 million is spent annually on running costs. The commercial ski-boat fishery directly employed an estimated 3184 people. The economic implications of changes in CPUE for the commercial ski-boat fishery are considered, as are the benefits of a recreational angling licence. Management of the linefishery is discussed in relation to the findings of this study.
- Full Text:
- Date Issued: 1998
- Authors: Brouwer, Stephen Leonard
- Date: 1998
- Subjects: Fisheries -- Research -- South Africa , Fisheries -- Environmental aspects -- Research -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5233 , http://hdl.handle.net/10962/d1005076 , Fisheries -- Research -- South Africa , Fisheries -- Environmental aspects -- Research -- South Africa
- Description: During the period April 1994 and February 1996 as part of an investigation into the national Iinefishery, the east coast shore fishery and the recreational and commercial ski-boat fisheries were surveyed, at eight sites between Kei Mouth in the East and Stil Bay in the West. Roving creel, access point and aerial surveys were used. A questionnaire was developed for each sector to gather data on catch and effort, fisher demographics, economics, fisher attitudes towards, and knowledge of, the current management regulations and assess the efficacy of the fisheries inspectorate. During the access point survey the catch of 3273 fishers was inspected and 1556 interviews were conducted. Questionnaires were conducted on 118 recreational ski-boaters and the catch of 165 boats was inspected. 96 commercial skippers were interviewed and 230 had their catch inspected. Three aerial surveys of the entire area were conducted during which a total of 1067 shore fishers were counted giving a shore fisher density of 0.39 fishers.km⁻¹. The majority (99%) of participants in all sectors of the linefishery were male. The greatest number of participants were white, shore fishery 77% recreational ski-boat 98% commercial skiboat 89%, followed by coloured, asian and black people. To a large extent this reflects the income of various racial groups. Most fishers supported the current linefish management plan. However, when tested on their knowledge of the size limits, bag limits and closed seasons of their target species many shore fishers (59%) did not know them and a high proportion of fishers in all sectors had disobeyed at least one of the regulations (shore 50%, recreational ski-boat 70%, commercial ski-boat 56%). When compared to historical data the present catch per unit effort (CPUE) in all sectors has decreased. Most interviewees in the various sectors did not accept responsibility for the decline in CPUE, but attributed it to three principal reasons vis their perceived direct competitors, trawling and pollution. Analysis of the catch revealed that all sectors were multispecies fisheries, with each sector being characterised by a small number of target species. Catch composition differed significantly between the shore and ski-boat sectors, but there was significant overlap between the two skiboat sectors. Analysis of the catch in comparison to that reported to the National Marine Linefish System (NMLS) revealed that there was a substantial degree of under-reporting. There was little seasonal difference in effort in the shore fishery while the recreational ski-boat effort was highest in the summer and the commercial ski-boat effort was high in the winter. Effort in the shore and recreational ski-boat fisheries was concentrated over weekends while the commercial ski-boat effort was highest during weekdays. Total effort for the entire area was estimated at 903 186 (±1913) fisher days per annum in the shore fishery, 24 357 (±685) recreational ski-boat fisher days and 64 266 (±1686) commercial ski-boat fisher days. Expenditure and capital investment in the various sectors was calculated, as were earnings of the participants in the commercial ski-boat sector. The linefishery in the Eastern Cape was estimated to have a minimum capital investment in excess of R210 million and more than R32 million is spent annually on running costs. The commercial ski-boat fishery directly employed an estimated 3184 people. The economic implications of changes in CPUE for the commercial ski-boat fishery are considered, as are the benefits of a recreational angling licence. Management of the linefishery is discussed in relation to the findings of this study.
- Full Text:
- Date Issued: 1998
An investigation into the antioxidative potential and regulatory aspects of liver tryptophan 2,3-dioxygenase by tryptophan and related analogues
- Authors: Antunes, Ana Paula Martins
- Date: 1998
- Subjects: Tryptophan -- Physiological effect , Antioxidants , Liver
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4010 , http://hdl.handle.net/10962/d1004070 , Tryptophan -- Physiological effect , Antioxidants , Liver
- Description: The amino acid, tryptophan, obtained through dietary means, is metabolised by the enzymes tryptophan 2,3-dioxygenase (TDO), indoleamine 2,3-dioxygenase (IDO) and tryptophan hydroxylase. All the enzymes have an effect on circulating tryptophan levels, especially TDO, since it is the major site of tryptophan catabolism in the liver and results in the production of kynurenine metabolites, viz. kynurenine, kynurenic acid, 3-hydroxyanthranilic acid and quinolinic acid. Extrahepatically, IDO is responsible for the synthesis of the kynurenine metabolites. Tryptophan 2,3-dioxygenase and IDO activity is increased by hormones or substrates such as tryptophan, and inflammation, in the case of IDO. Tryptophan availability for serotonin (5-HT) synthesis by the enzyme tryptophan hydroxylase is primarily dependent on TDO activity. A study was attempted in order to ascertain whether any of the endogenous metabolites of the kynurenine and serotonergic pathways would be able to inhibit TDO activity. Results showed that although the kynurenines had no effect, the indoleamines, except for the indoleacetic acids, were able to reduce TDO activity. 6-Methoxy-2-benzoxazolinone (6-MBOA), a structural analogue to melatonin, was the most potent inhibitor with a reduction in activity of 55 % compared with the control. The pineal gland in the rat brain has been shown to have the highest IDO activity. With induction, the kynurenine metabolite concentrations of kynurenic acid and quinolinic acid are increased. The effects of both compounds were determined on the serotonergic pathway. Although kynurenic acid produced no significant effect, quinolinic acid significantly reduced N-acetylserotonin and melatonin synthesis at concentrations of lOJLM and 100 JLM respectively. Many authors have implicated oxygen derived species as causative agents in the important neurodegenerative disorders such as Parkinson's and Huntington's disease. Increased radical generation and lipid peroxidation have been suggested to be responsible for the toxic destruction of neurons, especially in the brain because of its high lipid content and oxygen demand. The brain is therefore vulnerable to oxidative attack. During inflammatory diseases, IDO is induced with a resultant increase in kynurenines. This study was also an attempt at determining the effect of kynurenines on lipid peroxidation. All metabolites of the kynurenine pathway were able to induce lipid peroxidation significantly. The antioxidative potential of various tryptophan analogues, viz. serotonin, melatonin and 6-methoxy-2-benzoxazolinone, was determined using quinolinic acid-induced lipid peroxidation. Serotonin, melatonin and 6-MBOA were able to significantly reduce quinolinic acid-induced lipid peroxidation.
- Full Text:
- Date Issued: 1998
- Authors: Antunes, Ana Paula Martins
- Date: 1998
- Subjects: Tryptophan -- Physiological effect , Antioxidants , Liver
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4010 , http://hdl.handle.net/10962/d1004070 , Tryptophan -- Physiological effect , Antioxidants , Liver
- Description: The amino acid, tryptophan, obtained through dietary means, is metabolised by the enzymes tryptophan 2,3-dioxygenase (TDO), indoleamine 2,3-dioxygenase (IDO) and tryptophan hydroxylase. All the enzymes have an effect on circulating tryptophan levels, especially TDO, since it is the major site of tryptophan catabolism in the liver and results in the production of kynurenine metabolites, viz. kynurenine, kynurenic acid, 3-hydroxyanthranilic acid and quinolinic acid. Extrahepatically, IDO is responsible for the synthesis of the kynurenine metabolites. Tryptophan 2,3-dioxygenase and IDO activity is increased by hormones or substrates such as tryptophan, and inflammation, in the case of IDO. Tryptophan availability for serotonin (5-HT) synthesis by the enzyme tryptophan hydroxylase is primarily dependent on TDO activity. A study was attempted in order to ascertain whether any of the endogenous metabolites of the kynurenine and serotonergic pathways would be able to inhibit TDO activity. Results showed that although the kynurenines had no effect, the indoleamines, except for the indoleacetic acids, were able to reduce TDO activity. 6-Methoxy-2-benzoxazolinone (6-MBOA), a structural analogue to melatonin, was the most potent inhibitor with a reduction in activity of 55 % compared with the control. The pineal gland in the rat brain has been shown to have the highest IDO activity. With induction, the kynurenine metabolite concentrations of kynurenic acid and quinolinic acid are increased. The effects of both compounds were determined on the serotonergic pathway. Although kynurenic acid produced no significant effect, quinolinic acid significantly reduced N-acetylserotonin and melatonin synthesis at concentrations of lOJLM and 100 JLM respectively. Many authors have implicated oxygen derived species as causative agents in the important neurodegenerative disorders such as Parkinson's and Huntington's disease. Increased radical generation and lipid peroxidation have been suggested to be responsible for the toxic destruction of neurons, especially in the brain because of its high lipid content and oxygen demand. The brain is therefore vulnerable to oxidative attack. During inflammatory diseases, IDO is induced with a resultant increase in kynurenines. This study was also an attempt at determining the effect of kynurenines on lipid peroxidation. All metabolites of the kynurenine pathway were able to induce lipid peroxidation significantly. The antioxidative potential of various tryptophan analogues, viz. serotonin, melatonin and 6-methoxy-2-benzoxazolinone, was determined using quinolinic acid-induced lipid peroxidation. Serotonin, melatonin and 6-MBOA were able to significantly reduce quinolinic acid-induced lipid peroxidation.
- Full Text:
- Date Issued: 1998
Aspects of renormalisation in some quantum field theories
- Authors: Roy, Alan A
- Date: 1998
- Subjects: Quantum field theory , Renormalization group
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5400 , http://hdl.handle.net/10962/d1005214 , Quantum field theory , Renormalization group
- Description: Renormalisation is an important aspect of Quantum Field Theory. It is used to create physically meaningful theories and some major developments took place in the 1970's and onwards. We consider Renormalisation in its application to the theories of ψ⁴ , Quantum Electrodynamics, Quantum Chromodynamics and the Background Field Method. Feynman diagrams are used to illustrate many of the concepts.
- Full Text:
- Date Issued: 1998
- Authors: Roy, Alan A
- Date: 1998
- Subjects: Quantum field theory , Renormalization group
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5400 , http://hdl.handle.net/10962/d1005214 , Quantum field theory , Renormalization group
- Description: Renormalisation is an important aspect of Quantum Field Theory. It is used to create physically meaningful theories and some major developments took place in the 1970's and onwards. We consider Renormalisation in its application to the theories of ψ⁴ , Quantum Electrodynamics, Quantum Chromodynamics and the Background Field Method. Feynman diagrams are used to illustrate many of the concepts.
- Full Text:
- Date Issued: 1998
Aspects of the biology of the doublesash butterflyfish, Chaetodon marleyi (Pisces: Chaetodontidae)
- Authors: Vine, Niall Gordon
- Date: 1998
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21103 , http://hdl.handle.net/10962/6396
- Description: The doublesash butterflyfish, Chaetodon marleyi, indigenous to South Africa, is popular amongst marine aquarists. To provide a basis for the management of the species and assess its suitability for aquaculture, aspects of its biology were investigated. Specimens were collected between February 1996 and November 1997 from localities along the eastern Cape coastline of South Africa and from specimens in the RUSI fish collection. The dentition of C.marleyi is typical of non-coraline, benthic invertebrate feeding chaetodontids. The teeth are long, inwardly hooked and spatulate which allow easy grasping and manipulation of the prey. Stomach content analysis showed that the species fed predominantly on the tentacles of terebellid polychaetes with other polychaetes, crustaceans, hydro ids and ascideans contributing to the remainder of the diet. Juveniles had a larger volume of terebellid tentacles compared to adults which preyed more upon other polychaetes. The proximate composition (64.25% protein, 4.76% fat, 4.84% carbohydrate and 24.3 kJ/g total energy content) of the terebellid tentacles was determined suggesting a high energetic requirement of the fish or maximisation of feeding profit rates.
- Full Text:
- Date Issued: 1998
- Authors: Vine, Niall Gordon
- Date: 1998
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21103 , http://hdl.handle.net/10962/6396
- Description: The doublesash butterflyfish, Chaetodon marleyi, indigenous to South Africa, is popular amongst marine aquarists. To provide a basis for the management of the species and assess its suitability for aquaculture, aspects of its biology were investigated. Specimens were collected between February 1996 and November 1997 from localities along the eastern Cape coastline of South Africa and from specimens in the RUSI fish collection. The dentition of C.marleyi is typical of non-coraline, benthic invertebrate feeding chaetodontids. The teeth are long, inwardly hooked and spatulate which allow easy grasping and manipulation of the prey. Stomach content analysis showed that the species fed predominantly on the tentacles of terebellid polychaetes with other polychaetes, crustaceans, hydro ids and ascideans contributing to the remainder of the diet. Juveniles had a larger volume of terebellid tentacles compared to adults which preyed more upon other polychaetes. The proximate composition (64.25% protein, 4.76% fat, 4.84% carbohydrate and 24.3 kJ/g total energy content) of the terebellid tentacles was determined suggesting a high energetic requirement of the fish or maximisation of feeding profit rates.
- Full Text:
- Date Issued: 1998
Aspects of the ecology and reproductive biology of three cichlid fish species of Southern Lake Malombe (Malawi)
- Authors: Jambo, Collins Mayeso
- Date: 1998
- Subjects: Cichlids -- Africa, East -- Lake Malombe , Cichlids -- Ecology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5224 , http://hdl.handle.net/10962/d1005067 , Cichlids -- Africa, East -- Lake Malombe , Cichlids -- Ecology
- Description: The three major species Lethrinops ''pinkhead'', Otopharynx argyrosoma "red" and Copadichromis. cf virginalis which used to dominate the catches (by weight) of Lake Malombe in the past decade were investigated. In order to make rational recommendations regarding size and boundary of the existing sanctuary area (lightly fished), distribution and abundance, population structure and reproductive biology of the three species were related to habitat types of the southern part of the lake (south western side and south eastern side). Analysis of catch composition showed that species richness was higher in the south eastern side than in the south western side of the lake. Rare species such as Labeo mesops and Opsaridium microiepis were observed in the south eastern side and there was visual absence of such species in the south western side of the lake. The overall fish abundance was significantly greater in the south eastern side than in the south western side of the lake. In the south eastern side, the catch per unit effort (CPUE) was twice that of the south western side (P< 0.05). Seasonal fluctuations in CPUE were also prominent, with the highest peak occurring during September-October period. However, there was an indication of weak relationship among CPUE, phytoplankton biomass, temperature and water depth. The length-weight relationships revealed that growth of the three species closely followed the cubic law for isometric growth in both sides of the lake. Differences in regression coefficients between sides were not significant (ttest, P>0.05). The length-frequency distribution analysis revealed that the three species had the same growth rate regardless of habitat type. However, females grew faster than males. An investigation of reproductive biology showed that the three species have low fecundity and they are asynchronous spawners, with a breeding peak during August and September period. Furthermore, the length-fecundity relationships for L. ''pinkhead'', and 0. argyrosoma "red" indicated that fecundity was more closely related to length in the south eastern side than in the south western side. Based on the above characteristics of L. ''pinkhead'', 0. argyrosoma "red" and C. cf virginalis, and the substrate types, it was strongly suggested that the existing sanctuary (lightly fished) in the south eastern side of the lake could immediately be enlarged to conserve the fish stocks, favourable substratum and aquatic animals that may be of tourists concern.
- Full Text:
- Date Issued: 1998
- Authors: Jambo, Collins Mayeso
- Date: 1998
- Subjects: Cichlids -- Africa, East -- Lake Malombe , Cichlids -- Ecology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5224 , http://hdl.handle.net/10962/d1005067 , Cichlids -- Africa, East -- Lake Malombe , Cichlids -- Ecology
- Description: The three major species Lethrinops ''pinkhead'', Otopharynx argyrosoma "red" and Copadichromis. cf virginalis which used to dominate the catches (by weight) of Lake Malombe in the past decade were investigated. In order to make rational recommendations regarding size and boundary of the existing sanctuary area (lightly fished), distribution and abundance, population structure and reproductive biology of the three species were related to habitat types of the southern part of the lake (south western side and south eastern side). Analysis of catch composition showed that species richness was higher in the south eastern side than in the south western side of the lake. Rare species such as Labeo mesops and Opsaridium microiepis were observed in the south eastern side and there was visual absence of such species in the south western side of the lake. The overall fish abundance was significantly greater in the south eastern side than in the south western side of the lake. In the south eastern side, the catch per unit effort (CPUE) was twice that of the south western side (P< 0.05). Seasonal fluctuations in CPUE were also prominent, with the highest peak occurring during September-October period. However, there was an indication of weak relationship among CPUE, phytoplankton biomass, temperature and water depth. The length-weight relationships revealed that growth of the three species closely followed the cubic law for isometric growth in both sides of the lake. Differences in regression coefficients between sides were not significant (ttest, P>0.05). The length-frequency distribution analysis revealed that the three species had the same growth rate regardless of habitat type. However, females grew faster than males. An investigation of reproductive biology showed that the three species have low fecundity and they are asynchronous spawners, with a breeding peak during August and September period. Furthermore, the length-fecundity relationships for L. ''pinkhead'', and 0. argyrosoma "red" indicated that fecundity was more closely related to length in the south eastern side than in the south western side. Based on the above characteristics of L. ''pinkhead'', 0. argyrosoma "red" and C. cf virginalis, and the substrate types, it was strongly suggested that the existing sanctuary (lightly fished) in the south eastern side of the lake could immediately be enlarged to conserve the fish stocks, favourable substratum and aquatic animals that may be of tourists concern.
- Full Text:
- Date Issued: 1998
Biology and management of the Cape gurnard, Chelidonichthys capensis (Order Scorpaeniformes, Family Triglidae) in South Africa
- Authors: McPhail, Amanda Sue
- Date: 1998
- Subjects: Scorpaeniformes
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5236 , http://hdl.handle.net/10962/d1005079 , Scorpaeniformes
- Description: The South African demersal trawl fishery, as with most trawl-directed fisheries worldwide, has a substantial bycatch component. With increasing commercial emphasis being placed on retained bycatch, an urgent need has arisen to investigate these species. In the past the bycatch component has received little research or management attention. Members of the gurnard family Triglidae make up up to 2.4 % of the South African hake-directed demersal catch and are thus considered an important bycatch species. The catch history and biology, including population structure, reproduction, feeding, age, growth and mortality, of the Cape gurnard, Chelidonichthys capensis, sampled from the Agulhas Bank, South Africa, were thus investigated. Males (mean TL = 366mm) were significantly smaller than females (mean TL = 411mm). The sex ratio was close to parity, males being more dominant in commercial trawls and less dominant in research trawls. Gonad maturation and gonadosomatic indices showed this species to have an extended spawning period with peaks in reproductive activity during September, January and April. First approximations of size at 50 % maturity were similar for females (349mm TL) and males (348mm TL) but differed significantly in terms of age (3.6 years and 4.6 years respectively). Otolith growth marks were validated as annuli using marginal zone analysis. The maximum age estimated was 16 years for a female of 675mm TL and recruitment to the commercial fishery was estimated as taking place in the fifth year of growth for both males and females. Gut content analysis showed C. capensis to be an opportunistic feeder preying preferentially on the benthic crustaceans Goneplax angulata and Mursia cristimanus. Landings from the commercial linefishery were insignificant whilst those for the commercial trawl fishery ranged from 500 tonnes to 3250 tonnes between 1984 to 1995, and indicated that this species forms an important component of the South African trawl fishery bycatch. A first approximation of fishing mortality (0.36 year⁻¹) for the inshore commercial trawl fishery was higher than that of natural mortality (0.25 year⁻¹) suggesting some fishing pressure on this species on the Agulhas Bank. However this fishing mortality value was significantly less than that for F₀·₁ (4.78 year⁻¹) that was estimated using a yield-per-recruit model.
- Full Text:
- Date Issued: 1998
- Authors: McPhail, Amanda Sue
- Date: 1998
- Subjects: Scorpaeniformes
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5236 , http://hdl.handle.net/10962/d1005079 , Scorpaeniformes
- Description: The South African demersal trawl fishery, as with most trawl-directed fisheries worldwide, has a substantial bycatch component. With increasing commercial emphasis being placed on retained bycatch, an urgent need has arisen to investigate these species. In the past the bycatch component has received little research or management attention. Members of the gurnard family Triglidae make up up to 2.4 % of the South African hake-directed demersal catch and are thus considered an important bycatch species. The catch history and biology, including population structure, reproduction, feeding, age, growth and mortality, of the Cape gurnard, Chelidonichthys capensis, sampled from the Agulhas Bank, South Africa, were thus investigated. Males (mean TL = 366mm) were significantly smaller than females (mean TL = 411mm). The sex ratio was close to parity, males being more dominant in commercial trawls and less dominant in research trawls. Gonad maturation and gonadosomatic indices showed this species to have an extended spawning period with peaks in reproductive activity during September, January and April. First approximations of size at 50 % maturity were similar for females (349mm TL) and males (348mm TL) but differed significantly in terms of age (3.6 years and 4.6 years respectively). Otolith growth marks were validated as annuli using marginal zone analysis. The maximum age estimated was 16 years for a female of 675mm TL and recruitment to the commercial fishery was estimated as taking place in the fifth year of growth for both males and females. Gut content analysis showed C. capensis to be an opportunistic feeder preying preferentially on the benthic crustaceans Goneplax angulata and Mursia cristimanus. Landings from the commercial linefishery were insignificant whilst those for the commercial trawl fishery ranged from 500 tonnes to 3250 tonnes between 1984 to 1995, and indicated that this species forms an important component of the South African trawl fishery bycatch. A first approximation of fishing mortality (0.36 year⁻¹) for the inshore commercial trawl fishery was higher than that of natural mortality (0.25 year⁻¹) suggesting some fishing pressure on this species on the Agulhas Bank. However this fishing mortality value was significantly less than that for F₀·₁ (4.78 year⁻¹) that was estimated using a yield-per-recruit model.
- Full Text:
- Date Issued: 1998
Ecological interactions on a rocky shore : the control of macroalgal distribution by intertidal grazers
- Whittington-Jones, Kevin John
- Authors: Whittington-Jones, Kevin John
- Date: 1998
- Subjects: Limpets -- South Africa , Mollusks -- Ecology , Mollusks -- Feeding and feeds , Mollusks -- South Africa , Cryptogams , Cryptogams -- South Africa , Algae -- Control , Algae -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5665 , http://hdl.handle.net/10962/d1005350 , Limpets -- South Africa , Mollusks -- Ecology , Mollusks -- Feeding and feeds , Mollusks -- South Africa , Cryptogams , Cryptogams -- South Africa , Algae -- Control , Algae -- South Africa
- Description: The aim of the present study was to determine the potential impact of intertidal grazers on the distribution of macro algae on the south coast of South Africa. Particular attention was paid to the large patellid limpet, Patella oculus, which is found thoughout the intertidal zone. Studies of gut contents revealed that Patella oculus was capable of ingesting not only the thallus of foliose (eg. Ulva spp.) and encrusting coralline macroalgae, but also spores and diatoms. The inclusion of these relatively small particles in the diet was surprising, as electron micrographs of the radula of P.oculus revealed that it is typically docoglossan in structure. Such radulae are thought to be poorly suited for collecting small food particles. Sand made up a significantly higher proportion of the gut contents than other particles at all shore heights, which suggests that P.oculus might be capable of excavating the rocky substratum, or of sweeping up sand, while searching for food. Analysis of the gut contents of other local herbivorous molluscs, was also carried out. These species included the winkles, Oxystele variegata and O.sinensis, and the small pulmonate limpets, Siphonaria concinna, S.capensis, and S.serrata. The guts of all species contained mainly spores and diatoms, although small fragments of Ulva sp. were found. The population structure of Patella oculus was investigated at two sites, Cannon Rocks and Old Woman's River. At Cannon Rocks, mean shell length of low-shore animals was significantly lower than that of both mid- and high-shore animals, while at Old Woman's River, no significant difference was found among shore heights. A regression equation for In (shell length) vs In (dry weight) was calculated, and based on length data, the biomass density (g dry mass.m⁻²) of P.oculus at Old Woman's River was estimated. Values ranged from 2.8 on the low- and midshore to 0.37 on the high-shore. A manipulative field experiment was used to determine the impact of mesograzers and macrograzers (such as Patella oculus) on the distribution of intertidal macro algae on the mid- and low-shore at Old Woman's River. Grazers were excluded using mesh cages (mesh size = 3mm), in two separate experiments, one in winter and the other in spring. Percentage cover of macroalgal species and sessile invertebrates was estimated at approximately 6 week intervals for up to 3 months. MANOV A showed that treatments did not significantly affect cover of macroalgae or barnacles during winter. However, towards the end of the spring experiment (midshore only) cover of barnacles and green foliose turfs did increase in those plots from which mesograzers and/or macro grazers were excluded. The failure of the statistical tests to detect significant differences at some time intervals may have been caused by high levels of variation among replicates. This suggests that factors other than grazing are of overriding importance in determining the distribution of local macroalgae. The existence of a possible symbiotic relationship between Patella oculus and the red foliose alga, Gelidium pristoides, was investigated. The availability of various substratum types, including rock, limpet shells, barnacles etc., and the proportion of the total cover of G.pristoides on each, was calculated. It was shown that a significantly higher proportion of the alga grew on limpet shells, although the availability of this substratum type was low. It is thought that the aggressive behaviour of P.oculus prevents all but juvenile Patella longicosta from grazing on its shell, thus providing a refuge from grazing for G.pristoides.
- Full Text:
- Date Issued: 1998
- Authors: Whittington-Jones, Kevin John
- Date: 1998
- Subjects: Limpets -- South Africa , Mollusks -- Ecology , Mollusks -- Feeding and feeds , Mollusks -- South Africa , Cryptogams , Cryptogams -- South Africa , Algae -- Control , Algae -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5665 , http://hdl.handle.net/10962/d1005350 , Limpets -- South Africa , Mollusks -- Ecology , Mollusks -- Feeding and feeds , Mollusks -- South Africa , Cryptogams , Cryptogams -- South Africa , Algae -- Control , Algae -- South Africa
- Description: The aim of the present study was to determine the potential impact of intertidal grazers on the distribution of macro algae on the south coast of South Africa. Particular attention was paid to the large patellid limpet, Patella oculus, which is found thoughout the intertidal zone. Studies of gut contents revealed that Patella oculus was capable of ingesting not only the thallus of foliose (eg. Ulva spp.) and encrusting coralline macroalgae, but also spores and diatoms. The inclusion of these relatively small particles in the diet was surprising, as electron micrographs of the radula of P.oculus revealed that it is typically docoglossan in structure. Such radulae are thought to be poorly suited for collecting small food particles. Sand made up a significantly higher proportion of the gut contents than other particles at all shore heights, which suggests that P.oculus might be capable of excavating the rocky substratum, or of sweeping up sand, while searching for food. Analysis of the gut contents of other local herbivorous molluscs, was also carried out. These species included the winkles, Oxystele variegata and O.sinensis, and the small pulmonate limpets, Siphonaria concinna, S.capensis, and S.serrata. The guts of all species contained mainly spores and diatoms, although small fragments of Ulva sp. were found. The population structure of Patella oculus was investigated at two sites, Cannon Rocks and Old Woman's River. At Cannon Rocks, mean shell length of low-shore animals was significantly lower than that of both mid- and high-shore animals, while at Old Woman's River, no significant difference was found among shore heights. A regression equation for In (shell length) vs In (dry weight) was calculated, and based on length data, the biomass density (g dry mass.m⁻²) of P.oculus at Old Woman's River was estimated. Values ranged from 2.8 on the low- and midshore to 0.37 on the high-shore. A manipulative field experiment was used to determine the impact of mesograzers and macrograzers (such as Patella oculus) on the distribution of intertidal macro algae on the mid- and low-shore at Old Woman's River. Grazers were excluded using mesh cages (mesh size = 3mm), in two separate experiments, one in winter and the other in spring. Percentage cover of macroalgal species and sessile invertebrates was estimated at approximately 6 week intervals for up to 3 months. MANOV A showed that treatments did not significantly affect cover of macroalgae or barnacles during winter. However, towards the end of the spring experiment (midshore only) cover of barnacles and green foliose turfs did increase in those plots from which mesograzers and/or macro grazers were excluded. The failure of the statistical tests to detect significant differences at some time intervals may have been caused by high levels of variation among replicates. This suggests that factors other than grazing are of overriding importance in determining the distribution of local macroalgae. The existence of a possible symbiotic relationship between Patella oculus and the red foliose alga, Gelidium pristoides, was investigated. The availability of various substratum types, including rock, limpet shells, barnacles etc., and the proportion of the total cover of G.pristoides on each, was calculated. It was shown that a significantly higher proportion of the alga grew on limpet shells, although the availability of this substratum type was low. It is thought that the aggressive behaviour of P.oculus prevents all but juvenile Patella longicosta from grazing on its shell, thus providing a refuge from grazing for G.pristoides.
- Full Text:
- Date Issued: 1998
Finite element modelling of magma convection and attendant groundwater flow
- Authors: Harrison, Keith
- Date: 1998
- Subjects: Groundwater flow , Magmas
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5467 , http://hdl.handle.net/10962/d1005252 , Groundwater flow , Magmas
- Description: This thesis describes preliminary two- and three-dimensional modelling of mass and heat transport of hot, molten magma in crustal intrusions and of the associated thermally induced flow of groundwater contained in the surrounding country rock. The aim of such modelling is to create a tool with which to predict the location of mineral deposits formed by the transport and subsequent precipitation of minerals dissolved in the convecting groundwater. The momentum equations (Navier-Stokes equations), continuity equation and energy equation are used in conjunction with specially constructed density and viscosity relationships to govern the mass and heat transport processes of magma and groundwater. Finite element methods are used to solve the equations numerically for some simple model geometries. These methods are implemented by a commercial computer software code which is manipulated with a control program constructed by the author for the purpose. The models are of simple two- or three-dimensional geometries which all have an enclosed magma chamber surrounded completely by a shell of country rock through which groundwater is free to move. Modelling begins immediately after the intrusive event when the magma (in most cases rhyolitic) is at its greatest temperature. Heat is allowed to flow from the magma into the country rock causing thermal convection of the groundwater contained therein. The effect of the country rock as a porous medium on the flow of groundwater is modelled by including a distributed resistance term in the momentum equation. The computer code that controls the modelling is such that adaptions made to the models to represent real physical intrusive systems are trivial. Results of the research at this stage allow approximate prediction of the location of mineral deposits. Enhanced predictions can be made by effecting improvements to the models such as a more detailed representation of chemical processes, adaption of the computer code to allow multiple injections of magma and the modelling of frozen magma as a porous medium which admits the flow of groundwater.
- Full Text:
- Date Issued: 1998
- Authors: Harrison, Keith
- Date: 1998
- Subjects: Groundwater flow , Magmas
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5467 , http://hdl.handle.net/10962/d1005252 , Groundwater flow , Magmas
- Description: This thesis describes preliminary two- and three-dimensional modelling of mass and heat transport of hot, molten magma in crustal intrusions and of the associated thermally induced flow of groundwater contained in the surrounding country rock. The aim of such modelling is to create a tool with which to predict the location of mineral deposits formed by the transport and subsequent precipitation of minerals dissolved in the convecting groundwater. The momentum equations (Navier-Stokes equations), continuity equation and energy equation are used in conjunction with specially constructed density and viscosity relationships to govern the mass and heat transport processes of magma and groundwater. Finite element methods are used to solve the equations numerically for some simple model geometries. These methods are implemented by a commercial computer software code which is manipulated with a control program constructed by the author for the purpose. The models are of simple two- or three-dimensional geometries which all have an enclosed magma chamber surrounded completely by a shell of country rock through which groundwater is free to move. Modelling begins immediately after the intrusive event when the magma (in most cases rhyolitic) is at its greatest temperature. Heat is allowed to flow from the magma into the country rock causing thermal convection of the groundwater contained therein. The effect of the country rock as a porous medium on the flow of groundwater is modelled by including a distributed resistance term in the momentum equation. The computer code that controls the modelling is such that adaptions made to the models to represent real physical intrusive systems are trivial. Results of the research at this stage allow approximate prediction of the location of mineral deposits. Enhanced predictions can be made by effecting improvements to the models such as a more detailed representation of chemical processes, adaption of the computer code to allow multiple injections of magma and the modelling of frozen magma as a porous medium which admits the flow of groundwater.
- Full Text:
- Date Issued: 1998
Homogenous and heterogenous catalytic activity of metallophthalocyanines towards electrochemical detection of organic compounds
- Authors: Mafatle, Tsukutlane J P
- Date: 1998
- Subjects: Electrochemistry , Organic compounds , Phenols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4316 , http://hdl.handle.net/10962/d1004974 , Electrochemistry , Organic compounds , Phenols
- Description: Cysteine plays an important role in many biological and pharmaceutical systems. Therefore, in view of its importance, it is essential to find means of detecting it at the lowest possible levels. In this regard, electrochemical techniques have been found to be capable of detecting analytes even at micro levels. However, electrochemical determination of cysteine occurs at a very high potentials. These overpotentials makes quantitative analysis or detection of cysteine difficult at most conventional carbon electrodes. On platinum electrode, the oxidation of cysteine has been reported to occur in the potential range 0.7 to 1.45 V (vs NHE). Therefore, the object of this investigative study has been to find an active complex that could replace platinum and other expensive metals as electrodes. Such a complex should also be capable of reducing the potential at which the oxidation of cysteine occurs on carbon electrodes. As a result, this manuscript gives a full report on the investigative study of electrocatalytic activity of molybdenum phthalocyanine complexes towards detection of cysteine. Molybdenum phthalocyanine, OMo(OH)Pc, and its tetrasulfonated derivative, [OMo(OH)TSPc]⁴⁻ were successfully used to reduce the potential needed to initiate the oxidation of cysteine on carbon paste electrodes (CPE). The oxidation of cysteine on CPE modified with [OMo(OH)Pc]⁴⁻ was found to occur at 0.29 V (vs Ag/AgCl), and in the presence of [OMo(OH)TSPc]⁴⁻ species in solution the oxidation occurred at 0.33 V (vs Ag/AgCl). Molybdenum, in the oxidation states of Mo(IV), Mo(V) and Mo(VI), is found in biological systems as an essential trace element, participating in a number of enzymatic reactions, where it is believed to be coordinated to sulphur-containing ligands in many molybdenum enzymes. This therefore explains why molybdenum phthalocyanines were employed in electroanalytical detection of sulphur containing amino acid, cysteine. Electrochemical methods have also been successfully used in detection of environmental pollutants such as phenolic compounds. Phenolic compounds are oxidised at readily accessible potentials. However, like cysteine, there are problems associated with the electrochemical detection of these important environmental pollutants. Their electrooxidation is known to form dimeric and/or polymeric oxidation products which adsorb onto the electrode surface, thus -videactivating it. Therefore, to address this problem, cobalt phthalocyanine (CoPc) and its tetrasulfonated derivative, [CoTSPc]⁴⁻ were employed in electrocatalytic detection of phenolic compounds. These complexes were found to increase the anodic peak currents for the oxidation of o-cresol, m-cresol, p-cresol, phenol, 2-chlorophenol and 4-chlorophenol. In addition, CoPc deposited onto the glassy carbon electrode improved the stability of the electrode, by reducing electrode poisoning caused by the electrooxidation products of the mentioned phenolic compounds. The potential at which the oxidation occurred and the current response of individual phenolic compounds depended on the degree of substitution and the type of substituent on the phenol molecule. In general, the current response was found to be lower for chlorinated phenols compared with the cresols and phenol. To establish the role of the central metal in the catalytic process, comparison of the electrocatalytic activity of some of the first row transition metal phthalocyanines, for the detection of mono-substituted phenolic compounds, showed the following trend: Co⁽¹¹⁾ > Mn⁽¹¹⁾ > Fe⁽¹¹⁾Pc > Ni⁽¹¹⁾Pc > Cu⁽¹¹⁾Pc > H₂Pc > Zn⁽¹¹⁾Pc > Bare GCE. A report is also given on electrocatalysis using [CoTSPc]⁴⁻ electrochemically deposited on the glassy carbon electrode. This was also found to enhance the anodic peak currents for the oxidation of all phenolic compounds. A report on the effects of scan rate, operating potential, analyte concentration and other variables is also given.
- Full Text:
- Date Issued: 1998
- Authors: Mafatle, Tsukutlane J P
- Date: 1998
- Subjects: Electrochemistry , Organic compounds , Phenols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4316 , http://hdl.handle.net/10962/d1004974 , Electrochemistry , Organic compounds , Phenols
- Description: Cysteine plays an important role in many biological and pharmaceutical systems. Therefore, in view of its importance, it is essential to find means of detecting it at the lowest possible levels. In this regard, electrochemical techniques have been found to be capable of detecting analytes even at micro levels. However, electrochemical determination of cysteine occurs at a very high potentials. These overpotentials makes quantitative analysis or detection of cysteine difficult at most conventional carbon electrodes. On platinum electrode, the oxidation of cysteine has been reported to occur in the potential range 0.7 to 1.45 V (vs NHE). Therefore, the object of this investigative study has been to find an active complex that could replace platinum and other expensive metals as electrodes. Such a complex should also be capable of reducing the potential at which the oxidation of cysteine occurs on carbon electrodes. As a result, this manuscript gives a full report on the investigative study of electrocatalytic activity of molybdenum phthalocyanine complexes towards detection of cysteine. Molybdenum phthalocyanine, OMo(OH)Pc, and its tetrasulfonated derivative, [OMo(OH)TSPc]⁴⁻ were successfully used to reduce the potential needed to initiate the oxidation of cysteine on carbon paste electrodes (CPE). The oxidation of cysteine on CPE modified with [OMo(OH)Pc]⁴⁻ was found to occur at 0.29 V (vs Ag/AgCl), and in the presence of [OMo(OH)TSPc]⁴⁻ species in solution the oxidation occurred at 0.33 V (vs Ag/AgCl). Molybdenum, in the oxidation states of Mo(IV), Mo(V) and Mo(VI), is found in biological systems as an essential trace element, participating in a number of enzymatic reactions, where it is believed to be coordinated to sulphur-containing ligands in many molybdenum enzymes. This therefore explains why molybdenum phthalocyanines were employed in electroanalytical detection of sulphur containing amino acid, cysteine. Electrochemical methods have also been successfully used in detection of environmental pollutants such as phenolic compounds. Phenolic compounds are oxidised at readily accessible potentials. However, like cysteine, there are problems associated with the electrochemical detection of these important environmental pollutants. Their electrooxidation is known to form dimeric and/or polymeric oxidation products which adsorb onto the electrode surface, thus -videactivating it. Therefore, to address this problem, cobalt phthalocyanine (CoPc) and its tetrasulfonated derivative, [CoTSPc]⁴⁻ were employed in electrocatalytic detection of phenolic compounds. These complexes were found to increase the anodic peak currents for the oxidation of o-cresol, m-cresol, p-cresol, phenol, 2-chlorophenol and 4-chlorophenol. In addition, CoPc deposited onto the glassy carbon electrode improved the stability of the electrode, by reducing electrode poisoning caused by the electrooxidation products of the mentioned phenolic compounds. The potential at which the oxidation occurred and the current response of individual phenolic compounds depended on the degree of substitution and the type of substituent on the phenol molecule. In general, the current response was found to be lower for chlorinated phenols compared with the cresols and phenol. To establish the role of the central metal in the catalytic process, comparison of the electrocatalytic activity of some of the first row transition metal phthalocyanines, for the detection of mono-substituted phenolic compounds, showed the following trend: Co⁽¹¹⁾ > Mn⁽¹¹⁾ > Fe⁽¹¹⁾Pc > Ni⁽¹¹⁾Pc > Cu⁽¹¹⁾Pc > H₂Pc > Zn⁽¹¹⁾Pc > Bare GCE. A report is also given on electrocatalysis using [CoTSPc]⁴⁻ electrochemically deposited on the glassy carbon electrode. This was also found to enhance the anodic peak currents for the oxidation of all phenolic compounds. A report on the effects of scan rate, operating potential, analyte concentration and other variables is also given.
- Full Text:
- Date Issued: 1998
Improvement of fertility and hatchability of artificially incubated ostrich eggs in the little Karoo
- Van Schalkwyk, Salmon Jacobus
- Authors: Van Schalkwyk, Salmon Jacobus
- Date: 1998
- Subjects: Ostrich farming -- South Africa , Eggs -- Hatchability , Eggs -- Incubation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5713 , http://hdl.handle.net/10962/d1005399
- Description: Ostriches are an important commercial species in South Africa and are becoming increasingly so in other parts of the world. Fertility and hatchability of artificially incubated ostrich eggs, however, is generally regarded as low compared to other poultry species and to ostriches in the wild. Investigation into specific farming practices at present indicated scope for an overall improvement in productivity through a sound breeding strategy. This thesis investigated factors that affect egg production, fertility, and hatchability of artificially incubated eggs in the Little Karoo region of South Africa. Specific breeding pair combinations accounted for the major variations in egg weight, hatchability, chick production and offspring weight at slaughter age. An appreciable proportion of variation in reproductive traits was attributable to the repeatable nature of breeding pair performance from year to year, even from first breeding attempts, suggesting that selection of good breeding stock can be made from an early age. Artificially incubated eggs showed improved hatchability when eggs were collected two to three hours after lay rather than the following morning. Storing position of eggs did not significantly effect hatchability when eggs were stored for a maximum of one week. The critical zero temperature for ostrich eggs, below which no embryonical development takes place, was found to be ± 25°C and cooling eggs to temperatures below 20°C for complete cessation of embryonic development during storage resulted in better hatchabilities compared to eggs stored at 25°C room temperature. Hatchability decreased when incubator temperatures were raised from 36 to 37.3°C. Large temperature fluctuations and gradients, which encompass detrimental temperatures, persist within forced draught wooden incubators of the type most commonly in use in the Little Karoo region. The highest temperatures occurred at the top of these incubators and will consequently have a negative impact on hatchability. The ontogeny of ostrich egg metabolism showed an exponential increase during the first 70% of incubation followed by a decline to 75% of the peak value between days 31 and 38 of incubation. From peak levels of embryonic development it was calculated that single stage incubators needs an airflow of 54.4 1/egg.hour to maintain oxygen levels just below 21% and carbon dioxide levels below 0.5%. Lower embryonic mortalities were observed when eggs were turned twenty-four times/day in an electronic incubator compared to hand turning twice a day. Eggs rotated through increasing angles between 60 and 90° resulted in a linear improvement in hatchability. In incubators where turning angles were fixed at 60°, lower hatchabilities were overcome by incubating eggs for 2 - 3 weeks in a horizontal position before placing them vertically. No specific farming practice could be singled out as the main cause of low fertility or hatchability but rather a combination of certain practices applied wrongly.
- Full Text:
- Date Issued: 1998
Improvement of fertility and hatchability of artificially incubated ostrich eggs in the little Karoo
- Authors: Van Schalkwyk, Salmon Jacobus
- Date: 1998
- Subjects: Ostrich farming -- South Africa , Eggs -- Hatchability , Eggs -- Incubation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5713 , http://hdl.handle.net/10962/d1005399
- Description: Ostriches are an important commercial species in South Africa and are becoming increasingly so in other parts of the world. Fertility and hatchability of artificially incubated ostrich eggs, however, is generally regarded as low compared to other poultry species and to ostriches in the wild. Investigation into specific farming practices at present indicated scope for an overall improvement in productivity through a sound breeding strategy. This thesis investigated factors that affect egg production, fertility, and hatchability of artificially incubated eggs in the Little Karoo region of South Africa. Specific breeding pair combinations accounted for the major variations in egg weight, hatchability, chick production and offspring weight at slaughter age. An appreciable proportion of variation in reproductive traits was attributable to the repeatable nature of breeding pair performance from year to year, even from first breeding attempts, suggesting that selection of good breeding stock can be made from an early age. Artificially incubated eggs showed improved hatchability when eggs were collected two to three hours after lay rather than the following morning. Storing position of eggs did not significantly effect hatchability when eggs were stored for a maximum of one week. The critical zero temperature for ostrich eggs, below which no embryonical development takes place, was found to be ± 25°C and cooling eggs to temperatures below 20°C for complete cessation of embryonic development during storage resulted in better hatchabilities compared to eggs stored at 25°C room temperature. Hatchability decreased when incubator temperatures were raised from 36 to 37.3°C. Large temperature fluctuations and gradients, which encompass detrimental temperatures, persist within forced draught wooden incubators of the type most commonly in use in the Little Karoo region. The highest temperatures occurred at the top of these incubators and will consequently have a negative impact on hatchability. The ontogeny of ostrich egg metabolism showed an exponential increase during the first 70% of incubation followed by a decline to 75% of the peak value between days 31 and 38 of incubation. From peak levels of embryonic development it was calculated that single stage incubators needs an airflow of 54.4 1/egg.hour to maintain oxygen levels just below 21% and carbon dioxide levels below 0.5%. Lower embryonic mortalities were observed when eggs were turned twenty-four times/day in an electronic incubator compared to hand turning twice a day. Eggs rotated through increasing angles between 60 and 90° resulted in a linear improvement in hatchability. In incubators where turning angles were fixed at 60°, lower hatchabilities were overcome by incubating eggs for 2 - 3 weeks in a horizontal position before placing them vertically. No specific farming practice could be singled out as the main cause of low fertility or hatchability but rather a combination of certain practices applied wrongly.
- Full Text:
- Date Issued: 1998
Morphometrics and preliminary biology of the caridean shrimp Nauticaris marionis Bate, 1888, at the Prince Edward Islands (South Ocean), 37° 50'E, 46° 45'S
- Authors: Kuun, Patrick John
- Date: 1998
- Subjects: Shrimps -- Prince Edward Islands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5733 , http://hdl.handle.net/10962/d1005419 , Shrimps -- Prince Edward Islands
- Description: Carapace length, as the best measure of N. marionis body size, is precisely defined. It is shown that N. marionis is a partially protandric hermaphrodite. N. marionis appear to hatch just before April each year, with a little hatching persisting until May. The vast majority of juveniles develop into males. The majority of males transmutate into females in their third year. By April/May the transmutation is probably complete. Reproduction can occur before all male secondary characteristics have been lost. A small minority of individuals develop directly into females without passing through a male phase. At least some of these females can be initially recognized after they have developed mature ovaries by the presence of appendices internae on their first pleopods, a male copulatory structure which all juvenile N. marionis possess. Too few gravid females were recovered to make any statement on whether spawning can occur before this structure is lost. Such females may lose their first pleopod appendices internae in one moult, possibly just before spawning, which may be in late April/early May. Such individuals seem to mature into ovigerous females at a slightly smaller carapace length than do the majority of females which have had a male-phase past. A few females which have passed through a male phase seem to begin developing ovaries at about this small carapace length as well. Once the appendices internae have been lost there appears to be no way of identifying any given female's past life-history. It would seem that during the first year of life N. marionis survive in undetected localities, moult into juveniles, and then settle amongst the benthos from the plankton. Diurnal vertical migration then occurs up to an unknown larger size. It is not known whether the larvae are initially planktonic or not. It is possible that settling of small N. marionis onto the benthos only begins after November. Whether the appendices masculinae of some males only begin growing after they have settled Abstract XIX onto the benthos is unknown, but for the majority at least this begins whilst they are planktonic juveniles. Individuals older than five years are undetectable using samples of the sizes analyzed in this thesis, but they may well persist until quite an advanced age. Niche separation between smaller and larger N. marionis individuals may occur. Diel vertical migration may occur to some extent amongst large N. marionis. Itinerant euphausiids may contribute substantially to the maintenance of top predator populations at the archipelago, either through direct predation by those predators or via predation by N. marionis, which in turn are consumed by those predators. N. marionis itself is an opportunistic feeder, although the majority of its prey seem to be suspension feeders, both benthic and pelagic. In multisample situations, ageing of N. marionis cohorts is made less subjective if one utilizes the phenomenon of synchronized sexual inversion. The von Bertalanffy growth parameters for N. marionis are tentatively identified as k = 0.2353/year, L_ = 12.69mm, to = -0.2828 years and WW_ = 2.03g. The programme FiSAT is discussed, having been found to be extremely useful, but having also been found to have certain faults. Various hypotheses are proposed and are put forward as suggestions for future studies.
- Full Text:
- Date Issued: 1998
- Authors: Kuun, Patrick John
- Date: 1998
- Subjects: Shrimps -- Prince Edward Islands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5733 , http://hdl.handle.net/10962/d1005419 , Shrimps -- Prince Edward Islands
- Description: Carapace length, as the best measure of N. marionis body size, is precisely defined. It is shown that N. marionis is a partially protandric hermaphrodite. N. marionis appear to hatch just before April each year, with a little hatching persisting until May. The vast majority of juveniles develop into males. The majority of males transmutate into females in their third year. By April/May the transmutation is probably complete. Reproduction can occur before all male secondary characteristics have been lost. A small minority of individuals develop directly into females without passing through a male phase. At least some of these females can be initially recognized after they have developed mature ovaries by the presence of appendices internae on their first pleopods, a male copulatory structure which all juvenile N. marionis possess. Too few gravid females were recovered to make any statement on whether spawning can occur before this structure is lost. Such females may lose their first pleopod appendices internae in one moult, possibly just before spawning, which may be in late April/early May. Such individuals seem to mature into ovigerous females at a slightly smaller carapace length than do the majority of females which have had a male-phase past. A few females which have passed through a male phase seem to begin developing ovaries at about this small carapace length as well. Once the appendices internae have been lost there appears to be no way of identifying any given female's past life-history. It would seem that during the first year of life N. marionis survive in undetected localities, moult into juveniles, and then settle amongst the benthos from the plankton. Diurnal vertical migration then occurs up to an unknown larger size. It is not known whether the larvae are initially planktonic or not. It is possible that settling of small N. marionis onto the benthos only begins after November. Whether the appendices masculinae of some males only begin growing after they have settled Abstract XIX onto the benthos is unknown, but for the majority at least this begins whilst they are planktonic juveniles. Individuals older than five years are undetectable using samples of the sizes analyzed in this thesis, but they may well persist until quite an advanced age. Niche separation between smaller and larger N. marionis individuals may occur. Diel vertical migration may occur to some extent amongst large N. marionis. Itinerant euphausiids may contribute substantially to the maintenance of top predator populations at the archipelago, either through direct predation by those predators or via predation by N. marionis, which in turn are consumed by those predators. N. marionis itself is an opportunistic feeder, although the majority of its prey seem to be suspension feeders, both benthic and pelagic. In multisample situations, ageing of N. marionis cohorts is made less subjective if one utilizes the phenomenon of synchronized sexual inversion. The von Bertalanffy growth parameters for N. marionis are tentatively identified as k = 0.2353/year, L_ = 12.69mm, to = -0.2828 years and WW_ = 2.03g. The programme FiSAT is discussed, having been found to be extremely useful, but having also been found to have certain faults. Various hypotheses are proposed and are put forward as suggestions for future studies.
- Full Text:
- Date Issued: 1998
Natural resources and local management in the Hewu District of the Eastern Cape : limitations to achieving sustainability
- Authors: Nkansa-Dwamena, Yaw
- Date: 1998
- Subjects: Natural resources -- South Africa -- Management , Natural resources -- South Africa -- Eastern Cape -- Management
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4218 , http://hdl.handle.net/10962/d1003787 , Natural resources -- South Africa -- Management , Natural resources -- South Africa -- Eastern Cape -- Management
- Description: The Mceula Commonage Land in the Hewu district lies due northwest of Whittle sea and west of Queenstown in the Eastern Cape. This thesis has two main objectives. Firstly, to survey and analyse the condition of the natural resource. base in the Hewu district with particular reference to water, soil, vegetation and land use. Secondly, to investigate the relationship between scientific approaches to assessing land use degradation and to compare these to the results obtained using a participatory approach of the rural environment of the Hewu district of the Eastern Cape. Random quadrats (4m2) were sampled and corresponding line transects were done with increasing distances from the villages. The Braun-Blanquet method was used to find the cover and abundance of the various species of plants. Data obtained from point sampling along 100 metre line transects was used to assess the condition of the veld using Trollope's technique. Six communities were defined using TWINSP AN, and grazing capacities and veld condition scores of the respective sites were calculated. It was concluded that the six communities were distributed along a gradient of palatable to non palatable grass and grasslike species. Rangelands close to the villages had low veld condition scores and percentage plant cover as opposed to those farther away from the villages. The null hypothesis of no significant difference between the percentage plant cover and condition of the veld close to the villages and farther away from the villages was rejected. Whilst it is urgent to resolve political disputes around land through land distribution, a key issue for the future is sustainability of the natural resource base of South Africa. To attain this, the old traditional methods of research must be supplemented with the participatory method, where the local community becomes fully involved. The central theme of the participatory approach was to investigate the possibility of promoting local management of the natural resources. Workshops were conducted to involve the local community in the project. The community formed six discussion groups that met regularly to discuss environmental issues. The six groups that were formed were: Firewood or woodlot collectors, shepherds / livestock raisers, crop fanners / agriculturists, water collectors, building material / soil collectors and medicinal plant users. The results obtained from the meeting of the discussion groups were used to compare the scientific results obtained from Braun-Blanquet method. Perceptions about their environment, which came out of the results of the discussion groups showed that the local knowledge of the rural community of Mceula was sufficient to train them to manage their environment sustainably.
- Full Text:
- Date Issued: 1998
- Authors: Nkansa-Dwamena, Yaw
- Date: 1998
- Subjects: Natural resources -- South Africa -- Management , Natural resources -- South Africa -- Eastern Cape -- Management
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4218 , http://hdl.handle.net/10962/d1003787 , Natural resources -- South Africa -- Management , Natural resources -- South Africa -- Eastern Cape -- Management
- Description: The Mceula Commonage Land in the Hewu district lies due northwest of Whittle sea and west of Queenstown in the Eastern Cape. This thesis has two main objectives. Firstly, to survey and analyse the condition of the natural resource. base in the Hewu district with particular reference to water, soil, vegetation and land use. Secondly, to investigate the relationship between scientific approaches to assessing land use degradation and to compare these to the results obtained using a participatory approach of the rural environment of the Hewu district of the Eastern Cape. Random quadrats (4m2) were sampled and corresponding line transects were done with increasing distances from the villages. The Braun-Blanquet method was used to find the cover and abundance of the various species of plants. Data obtained from point sampling along 100 metre line transects was used to assess the condition of the veld using Trollope's technique. Six communities were defined using TWINSP AN, and grazing capacities and veld condition scores of the respective sites were calculated. It was concluded that the six communities were distributed along a gradient of palatable to non palatable grass and grasslike species. Rangelands close to the villages had low veld condition scores and percentage plant cover as opposed to those farther away from the villages. The null hypothesis of no significant difference between the percentage plant cover and condition of the veld close to the villages and farther away from the villages was rejected. Whilst it is urgent to resolve political disputes around land through land distribution, a key issue for the future is sustainability of the natural resource base of South Africa. To attain this, the old traditional methods of research must be supplemented with the participatory method, where the local community becomes fully involved. The central theme of the participatory approach was to investigate the possibility of promoting local management of the natural resources. Workshops were conducted to involve the local community in the project. The community formed six discussion groups that met regularly to discuss environmental issues. The six groups that were formed were: Firewood or woodlot collectors, shepherds / livestock raisers, crop fanners / agriculturists, water collectors, building material / soil collectors and medicinal plant users. The results obtained from the meeting of the discussion groups were used to compare the scientific results obtained from Braun-Blanquet method. Perceptions about their environment, which came out of the results of the discussion groups showed that the local knowledge of the rural community of Mceula was sufficient to train them to manage their environment sustainably.
- Full Text:
- Date Issued: 1998
Preliminary investigation of the molecular pathogenicity determinants of Xanthomonas campestris pv. zeae
- Authors: Downing, T G
- Date: 1998
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4066 , http://hdl.handle.net/10962/d1004922
- Description: Xanthomonas campestris pv. zeae was shown to posses a vast range of potential plant cell wall degrading enzymes including at least one protease, a carboxymethylcellulase, pectin lyase, polygalacturonase and a B-endoglucanase. Replicon stability and transfer system efficiencies were determined for a range of oriC, and oriT -tra combinations, and suitable vectors were constructed and identified for insertional inactivation by homologous recombination. Ideal suicide replicons were found to be pACYC184 and p15A, while P, Wand Q group replicons were supported by X campestris pv. zeae. Group P and group N transfer systems were shown to be highly efficient in intra-genus matings between Escherichia coli and X campestris pv. zeae, with the exception of P-tra systems in trans for the delivery of Tn5. Various cloning vectors were tested for stability and mobility. Tn5 was shown to transpose at high frequencies into the genome of the bacterial plant pathogen, and insertion was relatively random. Suitable screening assays were established to allow rapid isolation of mutants with potential virulence or pathogenic deviations, after mutagenesis. Two non-pathogenic mutants were identified, one of which was a putative hrp·, while the other was a leaky virulence. A single mutant showing 40% reduced protease activity was also shown to exhibit reduced virulence indicating a minor role for the protease in pathogenicity. The majority of virulence mutants showed altered growth in different levels of nutritional availability and complexity. Nutritional viability (the ability to acquire and use nutrients at a sufficient rate to grow fast enough to overcome host defences) was shown to be essential for virulence and possibly pathogenicity. Wild-type in-planta behaviour was analysed and growth and spread patterns typical for pathogenic response identified. Chief amongst these was the requirement for a threshold level of cells per leaf area or length, before symptoms could develop. Occlusion of vascular bundles was shown not to be the primary factor in the pathogenicity of X campestris pv. zeae. Threshold levels for lesion development indicate the absence of a diffusable lesion forming element, and possibly the requirement of cell density for induction of certain functions. , KMBT_363
- Full Text:
- Date Issued: 1998
- Authors: Downing, T G
- Date: 1998
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4066 , http://hdl.handle.net/10962/d1004922
- Description: Xanthomonas campestris pv. zeae was shown to posses a vast range of potential plant cell wall degrading enzymes including at least one protease, a carboxymethylcellulase, pectin lyase, polygalacturonase and a B-endoglucanase. Replicon stability and transfer system efficiencies were determined for a range of oriC, and oriT -tra combinations, and suitable vectors were constructed and identified for insertional inactivation by homologous recombination. Ideal suicide replicons were found to be pACYC184 and p15A, while P, Wand Q group replicons were supported by X campestris pv. zeae. Group P and group N transfer systems were shown to be highly efficient in intra-genus matings between Escherichia coli and X campestris pv. zeae, with the exception of P-tra systems in trans for the delivery of Tn5. Various cloning vectors were tested for stability and mobility. Tn5 was shown to transpose at high frequencies into the genome of the bacterial plant pathogen, and insertion was relatively random. Suitable screening assays were established to allow rapid isolation of mutants with potential virulence or pathogenic deviations, after mutagenesis. Two non-pathogenic mutants were identified, one of which was a putative hrp·, while the other was a leaky virulence. A single mutant showing 40% reduced protease activity was also shown to exhibit reduced virulence indicating a minor role for the protease in pathogenicity. The majority of virulence mutants showed altered growth in different levels of nutritional availability and complexity. Nutritional viability (the ability to acquire and use nutrients at a sufficient rate to grow fast enough to overcome host defences) was shown to be essential for virulence and possibly pathogenicity. Wild-type in-planta behaviour was analysed and growth and spread patterns typical for pathogenic response identified. Chief amongst these was the requirement for a threshold level of cells per leaf area or length, before symptoms could develop. Occlusion of vascular bundles was shown not to be the primary factor in the pathogenicity of X campestris pv. zeae. Threshold levels for lesion development indicate the absence of a diffusable lesion forming element, and possibly the requirement of cell density for induction of certain functions. , KMBT_363
- Full Text:
- Date Issued: 1998
Raptor communities in hill habitats in south-eastern Zimbabwe
- Authors: Davison, Bruce
- Date: 1998
- Subjects: Birds of prey -- Zimbabwe , Birds of prey -- Ecology -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5751 , http://hdl.handle.net/10962/d1005438 , Birds of prey -- Zimbabwe , Birds of prey -- Ecology -- Zimbabwe
- Description: The interrelationships between species composition, resource-use and availability, breeding and competition were studied in two hill habitat raptor communities in a conserved reserve and an unprotected communal land in Zimbabwe in 1995 and 1996. The conserved Lonestar Study Area (LSA) and the unprotected Communal Land Study area (CLSA) had 38 and 31 raptor species, high and normal diversities for the area sizes respectively. An estimated 147 pairs of 21 raptor species bred in 40km² in the LSA compared to only 26 pairs of 22 raptor species per 40km² in the CLSA. Six species (African Hawk Eagle Hieraaetus spilogaster, Black Eagle Aquila verreauxii, Crowned Eagle Stephanoaetus coronatus, Little Banded Goshawk Accipiter badius, Barn Owl Tyto alba,and Barred Owl Glancidium capense made up 69% of breeding raptors in the LSA, while African Hawk Eagles, Little Banded Goshawks, Barn Owls and Barred Owls made up 58% of the breeding raptors in the CLSA. The abundance of Black, Crowned and African Hawk Eagles in the LSA was linked to abundant hyrax, Heterohyrax brucei and Procavia capensis and juvenile bushbuck Tragelaphus prey, and the high reproduction rates of Natal Francolin Francolinus natalensis (0.7 per ha when not breeding). Little Banded Goshawk and Barn Owl abundances were linked to their ability to change prey preferences according to prey availability. A fairly high rate of breeding attempts by eagles in the LSA in both years (60 - 76% of all pairs per year)was probably also linked to prey abundance, Most breeding failures were predator related, and were more common in areas of relatively low nesting densities indicating lower parental vigilance there. High eagle breeding densities were associated with small mean territory sizes in the LSA (7.7 - 10.7km² for the main eagle species). Eagles in the LSA usually nested closer to another eagle species than a conspecific, resulting in regular distributions of nests and no territory overlap within species. Differences in daily flight activity of eagles in both study areas, and in the onset of breeding between LSA eagles probably reduced interspecific aggression. Interspecific competition food and nest sites amongst LSA eagles was possibly lessened by slight ditferences in resource selection. Raptor resources were mostly unaffected by human activities in either study area during the study period. Differences in the raptor communities were probably as a result of natural habitat differences. The CLSA raptors potentially face resource loss through forest clearing and hunting. An expansion of the present CAMPFIRE program will protect the CLSA raptors.
- Full Text:
- Date Issued: 1998
- Authors: Davison, Bruce
- Date: 1998
- Subjects: Birds of prey -- Zimbabwe , Birds of prey -- Ecology -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5751 , http://hdl.handle.net/10962/d1005438 , Birds of prey -- Zimbabwe , Birds of prey -- Ecology -- Zimbabwe
- Description: The interrelationships between species composition, resource-use and availability, breeding and competition were studied in two hill habitat raptor communities in a conserved reserve and an unprotected communal land in Zimbabwe in 1995 and 1996. The conserved Lonestar Study Area (LSA) and the unprotected Communal Land Study area (CLSA) had 38 and 31 raptor species, high and normal diversities for the area sizes respectively. An estimated 147 pairs of 21 raptor species bred in 40km² in the LSA compared to only 26 pairs of 22 raptor species per 40km² in the CLSA. Six species (African Hawk Eagle Hieraaetus spilogaster, Black Eagle Aquila verreauxii, Crowned Eagle Stephanoaetus coronatus, Little Banded Goshawk Accipiter badius, Barn Owl Tyto alba,and Barred Owl Glancidium capense made up 69% of breeding raptors in the LSA, while African Hawk Eagles, Little Banded Goshawks, Barn Owls and Barred Owls made up 58% of the breeding raptors in the CLSA. The abundance of Black, Crowned and African Hawk Eagles in the LSA was linked to abundant hyrax, Heterohyrax brucei and Procavia capensis and juvenile bushbuck Tragelaphus prey, and the high reproduction rates of Natal Francolin Francolinus natalensis (0.7 per ha when not breeding). Little Banded Goshawk and Barn Owl abundances were linked to their ability to change prey preferences according to prey availability. A fairly high rate of breeding attempts by eagles in the LSA in both years (60 - 76% of all pairs per year)was probably also linked to prey abundance, Most breeding failures were predator related, and were more common in areas of relatively low nesting densities indicating lower parental vigilance there. High eagle breeding densities were associated with small mean territory sizes in the LSA (7.7 - 10.7km² for the main eagle species). Eagles in the LSA usually nested closer to another eagle species than a conspecific, resulting in regular distributions of nests and no territory overlap within species. Differences in daily flight activity of eagles in both study areas, and in the onset of breeding between LSA eagles probably reduced interspecific aggression. Interspecific competition food and nest sites amongst LSA eagles was possibly lessened by slight ditferences in resource selection. Raptor resources were mostly unaffected by human activities in either study area during the study period. Differences in the raptor communities were probably as a result of natural habitat differences. The CLSA raptors potentially face resource loss through forest clearing and hunting. An expansion of the present CAMPFIRE program will protect the CLSA raptors.
- Full Text:
- Date Issued: 1998