Enhancement of the electrocatalytic activity of phthalocyanines through the reduction in symmetry and conjugation to detonation nanodiamonds
- Authors: Ncwane, Lunathi
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424541 , vital:72162
- Description: This thesis reports on the synthesis of novel phthalocynines tetrakis[(benzo[d]thiazol-2ylthio)phthalocyaninato]cobalt(II)chloride (complex 1) and tris(2-(ethylthio)benzo[d]thiazole)2-(phthalocyanine-9-ylthio)propionate cobalt(II) chloride (complex 2). The complexes are combined with DNDs via different techniques such as π-π stacking, covalent linkage and sequential modification on glassy carbon electrode. The synthesized MPcs and conjugates were characterized using UV-visible, mass, Fourier transform infrared, and Raman spectroscopies as well as transmission electron microscopy and dynamic light scattering. Combining MPcs with DNDs sought to improve electrooxidation of hydrazine. The electrochemical studies were conducted using cyclic voltammetry, chronocoloumetry, electrochemical impedance spectroscopy and chronoamperometry. Hydrazine was utilized as an analyte of interest, due to its mutagenic and carcinogenic effects. Glassy carbon electrodes (GCE) were modified using drop and dry method. The conjugation via covalent linkage proved to be the best way of enhancing electrocatalytic properties. Since it performed better in terms of limit of detection (0.33 μM), even though catalytic rate and sensitivity are not the highest. , Thesis (MSc) -- Faculty of Science, Chemistry, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Ncwane, Lunathi
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424541 , vital:72162
- Description: This thesis reports on the synthesis of novel phthalocynines tetrakis[(benzo[d]thiazol-2ylthio)phthalocyaninato]cobalt(II)chloride (complex 1) and tris(2-(ethylthio)benzo[d]thiazole)2-(phthalocyanine-9-ylthio)propionate cobalt(II) chloride (complex 2). The complexes are combined with DNDs via different techniques such as π-π stacking, covalent linkage and sequential modification on glassy carbon electrode. The synthesized MPcs and conjugates were characterized using UV-visible, mass, Fourier transform infrared, and Raman spectroscopies as well as transmission electron microscopy and dynamic light scattering. Combining MPcs with DNDs sought to improve electrooxidation of hydrazine. The electrochemical studies were conducted using cyclic voltammetry, chronocoloumetry, electrochemical impedance spectroscopy and chronoamperometry. Hydrazine was utilized as an analyte of interest, due to its mutagenic and carcinogenic effects. Glassy carbon electrodes (GCE) were modified using drop and dry method. The conjugation via covalent linkage proved to be the best way of enhancing electrocatalytic properties. Since it performed better in terms of limit of detection (0.33 μM), even though catalytic rate and sensitivity are not the highest. , Thesis (MSc) -- Faculty of Science, Chemistry, 2023
- Full Text:
- Date Issued: 2023-10-13
Enteric microbial responses to host hyperthermia in southern African insectivorous bats: a test of thermal co-adaptation
- Authors: Hunter, Amy Alison
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424391 , vital:72149
- Description: Embargoed. Expected release date 2025. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Hunter, Amy Alison
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424391 , vital:72149
- Description: Embargoed. Expected release date 2025. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
Esibelekweni: Ingqokelela Yemibongo ngesiXhosa nangesiNgesi
- Authors: Busakwe, Yenzokuhle
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English , Xhosa
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424917 , vital:72193
- Description: My thesis is a collection of poems that is written in isiXhosa and English. It explores African spirituality, my relationship with God, heartache from romantic and platonic relationships. I make use of dual languages because some themes that I write about such as African spirituality I find words that capture their truest emotion in my Xhosa vocabulary, and I cannot find them in English. My poems use the narrative form because it allows me to tell stories through poetry without having to commit my writing to musicality or rhyming that a lyric poetry normally has. My work is shaped by writers such as Kate Beinhemer, Mangaliso Buzani, Amy Saul Zerby, Nontsizi Mgqwethio, Simphiwe Nolutshungu and Oiu Miaojin. Buzani makes use of images and few lines in his writing but still manages to capture a story with brevity. Saul-Zerby makes use of text lingo in some of her poems, and I make use of it to close a gap that I have identified with the books that I was reading that are all written in a formal and serious format. Mgqwetho’s poems explore Christianity and African Spirituality which is one of the subjects that my work is exploring too but in a manner that differs. I talk about how they have been my guidance instead of praising their powers like Nontsizi normally does in her poems. Simphiwe Nolutshungu’s poems has influenced the structure of my poems. Fairy tales written by writers like Kate helps my writing to bring to life issues that sound too dreamy to be true but have manifested as visions and memories that I cannot wipe out from my conscience. Oiu Miaojin’s novel “Last words from Montmantre” I am fascinated by how the writer detail emotions such as vulnerability and heartbreak in his storytelling. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Busakwe, Yenzokuhle
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English , Xhosa
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424917 , vital:72193
- Description: My thesis is a collection of poems that is written in isiXhosa and English. It explores African spirituality, my relationship with God, heartache from romantic and platonic relationships. I make use of dual languages because some themes that I write about such as African spirituality I find words that capture their truest emotion in my Xhosa vocabulary, and I cannot find them in English. My poems use the narrative form because it allows me to tell stories through poetry without having to commit my writing to musicality or rhyming that a lyric poetry normally has. My work is shaped by writers such as Kate Beinhemer, Mangaliso Buzani, Amy Saul Zerby, Nontsizi Mgqwethio, Simphiwe Nolutshungu and Oiu Miaojin. Buzani makes use of images and few lines in his writing but still manages to capture a story with brevity. Saul-Zerby makes use of text lingo in some of her poems, and I make use of it to close a gap that I have identified with the books that I was reading that are all written in a formal and serious format. Mgqwetho’s poems explore Christianity and African Spirituality which is one of the subjects that my work is exploring too but in a manner that differs. I talk about how they have been my guidance instead of praising their powers like Nontsizi normally does in her poems. Simphiwe Nolutshungu’s poems has influenced the structure of my poems. Fairy tales written by writers like Kate helps my writing to bring to life issues that sound too dreamy to be true but have manifested as visions and memories that I cannot wipe out from my conscience. Oiu Miaojin’s novel “Last words from Montmantre” I am fascinated by how the writer detail emotions such as vulnerability and heartbreak in his storytelling. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
- Date Issued: 2023-10-13
Evaluating the potential effects of microplastics at environmentally realistic concentrations in South African freshwater systems
- Authors: Mtintsilana, Zintle
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424160 , vital:72129
- Description: Microplastic pollution is spatially broad, microplastics can be found in various habitats including freshwater systems. Microplastic exposure to aquatic organisms has been associated with several physical impacts on aquatic organisms from multiple trophic levels such as; increased immune response, a decrease in food intake, excessive loss of weight, reduced growth rate, reduced energy and adverse effects on successive generations. However, these significant effects of microplastics exposure have been observed mostly in studies that use concentrations of microplastics that exceed environmental concentrations. Therefore, there is an overall lack of research on the effects of microplastics on freshwater organisms using environmentally realistic concentrations, especially in the Southern Hemisphere. A series of toxicity tests were used to expose a range of taxa including Tilapia sparrmanii, Caridina nilotica, and Melanoides tuberculata to different environmentally realistic concentrations of microplastics of different polymers. The study results show that the environmentally realistic concentrations had no statistically significant effects on most of the chosen test organisms and selected study endpoints, except for T. sparrmanii microplastic particle egestion and growth in polyethylene exposures which produced significant results. Although this study showed that at environmentally realistic concentrations and 21 days of exposure, minute effects on the test taxa were detected, various studies have proven that with longer exposure to microplastics, significant effects on freshwater organisms can be detected. Additionally, studies using concentrations higher than the current environmental concentrations have recorded significant effects on organisms and therefore, with increasing concentrations in the environment, more significant effects may be observed. Therefore, plastic pollution in the environment should be reduced as microplastics are in continuous production and circulation, and microplastic concentrations in freshwater environments are predicted to increase. , Thesis (MSc) -- Faculty of Science, Institute for Water Research, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Mtintsilana, Zintle
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424160 , vital:72129
- Description: Microplastic pollution is spatially broad, microplastics can be found in various habitats including freshwater systems. Microplastic exposure to aquatic organisms has been associated with several physical impacts on aquatic organisms from multiple trophic levels such as; increased immune response, a decrease in food intake, excessive loss of weight, reduced growth rate, reduced energy and adverse effects on successive generations. However, these significant effects of microplastics exposure have been observed mostly in studies that use concentrations of microplastics that exceed environmental concentrations. Therefore, there is an overall lack of research on the effects of microplastics on freshwater organisms using environmentally realistic concentrations, especially in the Southern Hemisphere. A series of toxicity tests were used to expose a range of taxa including Tilapia sparrmanii, Caridina nilotica, and Melanoides tuberculata to different environmentally realistic concentrations of microplastics of different polymers. The study results show that the environmentally realistic concentrations had no statistically significant effects on most of the chosen test organisms and selected study endpoints, except for T. sparrmanii microplastic particle egestion and growth in polyethylene exposures which produced significant results. Although this study showed that at environmentally realistic concentrations and 21 days of exposure, minute effects on the test taxa were detected, various studies have proven that with longer exposure to microplastics, significant effects on freshwater organisms can be detected. Additionally, studies using concentrations higher than the current environmental concentrations have recorded significant effects on organisms and therefore, with increasing concentrations in the environment, more significant effects may be observed. Therefore, plastic pollution in the environment should be reduced as microplastics are in continuous production and circulation, and microplastic concentrations in freshwater environments are predicted to increase. , Thesis (MSc) -- Faculty of Science, Institute for Water Research, 2023
- Full Text:
- Date Issued: 2023-10-13
Evaluation of potential oviposition deterrents for false codling moth, Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae)
- Authors: Dambuza, Khalipha
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424479 , vital:72157
- Description: There has been extensive research on the use of semiochemicals as deterrents or true repellents in insect pest management, particularly in push-pull strategies. Much of this research has focused on pests of medical and veterinary importance and has been limited for agricultural pests. This means there is an opportunity to study use of deterrents to manage pests of agricultural importance. No study has been conducted on deterrents for false codling moth (FCM), Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae), a key phytosanitary pest in citrus orchards across South Africa. This study assessed FCM oviposition deterrence in botanicals (plants (n = 11) and essential oils (n = 15)), and some commercial pesticides (n = 7) used for FCM control in South Africa. All tested botanicals were selected based on an extensive literature review of plant compounds that have been reported to deter or repel lepidopteran pests. Choice and no-choice oviposition bioassays were conducted in complete darkness in a controlled environment room. Oranges treated with solutions/suspensions of potential oviposition deterrents were placed into a cage with gravid FCM females for four hours, with oviposition being recorded every hour. Of the 33 tested compounds, only eight significantly reduced FCM oviposition (P < 0.05) compared to the control in oviposition bioassays i.e. two essential oils (lavender and peppermint), two plant crude extracts (garlic and marigold), one fruit (Mango), and three commercial FCM insecticides (Delegate, Coragen, and Warlock). All identified oviposition deterrents, except for Mango, were further investigated for their ovicidal properties in concentration response bioassays, where all botanicals were identified to have dual action (both deterrent and ovicidal properties), as they significantly (P < 0.05) reduced FCM oviposition and egg hatch. Garlic was the most efficacious botanical whilst Warlock was the only commercial insecticide that did not show ovicidal activity (F = 41.17, P = 0.0622). Larval penetration of the host fruit was less than egg hatch for all tested compounds in concentration response bioassays. Oviposition, egg hatch, and larval penetration were all affected by concentration, with the higher concentrations being the most effective. The efficacy of these deterrent compounds should be further tested in semi-field and/or field trials, and they may have potential in FCM management as allomone dispensers or sprays. They can also be implemented in push-pull strategies where they can be used in conjunction with FCM attractants. Lastly, repellence studies should be conducted in absentia of the host fruit to determine whether oviposition deterrence was a result of true repellence or odour masking. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Dambuza, Khalipha
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424479 , vital:72157
- Description: There has been extensive research on the use of semiochemicals as deterrents or true repellents in insect pest management, particularly in push-pull strategies. Much of this research has focused on pests of medical and veterinary importance and has been limited for agricultural pests. This means there is an opportunity to study use of deterrents to manage pests of agricultural importance. No study has been conducted on deterrents for false codling moth (FCM), Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae), a key phytosanitary pest in citrus orchards across South Africa. This study assessed FCM oviposition deterrence in botanicals (plants (n = 11) and essential oils (n = 15)), and some commercial pesticides (n = 7) used for FCM control in South Africa. All tested botanicals were selected based on an extensive literature review of plant compounds that have been reported to deter or repel lepidopteran pests. Choice and no-choice oviposition bioassays were conducted in complete darkness in a controlled environment room. Oranges treated with solutions/suspensions of potential oviposition deterrents were placed into a cage with gravid FCM females for four hours, with oviposition being recorded every hour. Of the 33 tested compounds, only eight significantly reduced FCM oviposition (P < 0.05) compared to the control in oviposition bioassays i.e. two essential oils (lavender and peppermint), two plant crude extracts (garlic and marigold), one fruit (Mango), and three commercial FCM insecticides (Delegate, Coragen, and Warlock). All identified oviposition deterrents, except for Mango, were further investigated for their ovicidal properties in concentration response bioassays, where all botanicals were identified to have dual action (both deterrent and ovicidal properties), as they significantly (P < 0.05) reduced FCM oviposition and egg hatch. Garlic was the most efficacious botanical whilst Warlock was the only commercial insecticide that did not show ovicidal activity (F = 41.17, P = 0.0622). Larval penetration of the host fruit was less than egg hatch for all tested compounds in concentration response bioassays. Oviposition, egg hatch, and larval penetration were all affected by concentration, with the higher concentrations being the most effective. The efficacy of these deterrent compounds should be further tested in semi-field and/or field trials, and they may have potential in FCM management as allomone dispensers or sprays. They can also be implemented in push-pull strategies where they can be used in conjunction with FCM attractants. Lastly, repellence studies should be conducted in absentia of the host fruit to determine whether oviposition deterrence was a result of true repellence or odour masking. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
Examining teachers’ pedagogical strategies for fostering critical thinking skills in English as a Second Language (ESL) classrooms: a case study of selected Namibian secondary school teachers
- Authors: Rittmann, Heinrich Heinz
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424097 , vital:72123
- Description: Thesis embargoed. Expected release date 2025. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Rittmann, Heinrich Heinz
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424097 , vital:72123
- Description: Thesis embargoed. Expected release date 2025. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
Exploring ESL teachers’ self-developed pedagogical practices for teaching reading comprehension in Namibian primary schools
- Authors: Alumbungu, Marta Ndakalako
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419714 , vital:71669
- Description: Embargoed. Possible release date 2026 pending publication. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Alumbungu, Marta Ndakalako
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419714 , vital:71669
- Description: Embargoed. Possible release date 2026 pending publication. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
Exploring grade 8 teachers’ code-switching in teaching orthographic drawing in the Khomas Educational Region, Namibia
- Authors: Iita, Gabriel
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424041 , vital:72118
- Description: Studies in learner English proficiency in Namibia have shown that a considerable number of learners in primary and high schools have low proficiency. Naturally, this will be problematic for both learners and teachers who operate under a policy that dictates that from Grade 4 upwards, English is the medium of instruction in government schools. Literature has shown a general bias towards English as a medium of instruction from both the Namibian government and Namibian parents, despite the broader level of low English proficiency among learners. Research reviewed within this study has outlined the multiple benefits of code-switching for both learners and teachers. In fact, a recent study on the perceptions of code-switching in classrooms among Namibian learners indicated a positive attitude towards code-switching as a learning tool. Grade 8 Technical Drawing classes tend to be challenging due to the complexity and novelty of some of the concepts and terminologies used when teaching the subject. This makes it particularly difficult for learners whose first language is not English. Learners struggle to understand and make meaning of the concepts and objects used in Orthographic Drawing. Code-switching has been seen as a beneficial pedagogical tool. The study was therefore conducted to explore the Grade 8 teachers’ code-switching when teaching Orthographic Drawing in the Khomas educational region, Namibia. The study used the Matrix Language Frame Model by Myers-Scotton as the theoretical framework which focuses on two crucial language aspects of participating in code-switching and the matrix and embedded language, which guided this study. The qualitative approach employed a case study design which was used to gain first-hand experience in the Technical Drawing classrooms. Semi-structured interviews and an observation checklist were the research instruments that were used to generate data on the use of code-switching in Orthographic Drawing. Two schools, two Technical Drawing classes with 40 learners and two teachers in the Khomas region, Namibia were conveniently and purposively sampled. The data were analysed using coding, descriptive statistics and thematic data analysis. The primary and secondary results indicate that code-switching occurrence has constructive effects. Consequently, recommendations have been made on the effective use of code-switching along with other pedagogical tools based on the research insights into code-switching when teaching and learning Orthographic Drawing. , Thesis (MEd) -- Faculty of Humanities, Study of Englishes of Africa, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Iita, Gabriel
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424041 , vital:72118
- Description: Studies in learner English proficiency in Namibia have shown that a considerable number of learners in primary and high schools have low proficiency. Naturally, this will be problematic for both learners and teachers who operate under a policy that dictates that from Grade 4 upwards, English is the medium of instruction in government schools. Literature has shown a general bias towards English as a medium of instruction from both the Namibian government and Namibian parents, despite the broader level of low English proficiency among learners. Research reviewed within this study has outlined the multiple benefits of code-switching for both learners and teachers. In fact, a recent study on the perceptions of code-switching in classrooms among Namibian learners indicated a positive attitude towards code-switching as a learning tool. Grade 8 Technical Drawing classes tend to be challenging due to the complexity and novelty of some of the concepts and terminologies used when teaching the subject. This makes it particularly difficult for learners whose first language is not English. Learners struggle to understand and make meaning of the concepts and objects used in Orthographic Drawing. Code-switching has been seen as a beneficial pedagogical tool. The study was therefore conducted to explore the Grade 8 teachers’ code-switching when teaching Orthographic Drawing in the Khomas educational region, Namibia. The study used the Matrix Language Frame Model by Myers-Scotton as the theoretical framework which focuses on two crucial language aspects of participating in code-switching and the matrix and embedded language, which guided this study. The qualitative approach employed a case study design which was used to gain first-hand experience in the Technical Drawing classrooms. Semi-structured interviews and an observation checklist were the research instruments that were used to generate data on the use of code-switching in Orthographic Drawing. Two schools, two Technical Drawing classes with 40 learners and two teachers in the Khomas region, Namibia were conveniently and purposively sampled. The data were analysed using coding, descriptive statistics and thematic data analysis. The primary and secondary results indicate that code-switching occurrence has constructive effects. Consequently, recommendations have been made on the effective use of code-switching along with other pedagogical tools based on the research insights into code-switching when teaching and learning Orthographic Drawing. , Thesis (MEd) -- Faculty of Humanities, Study of Englishes of Africa, 2023
- Full Text:
- Date Issued: 2023-10-13
Exploring how Grade 11 Chemistry teachers mediate learning of the topic redox reactions in their classrooms in Namibia
- Iindombo, Junilla Inamudhimbwa
- Authors: Iindombo, Junilla Inamudhimbwa
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424030 , vital:72117
- Description: The Namibian Chemistry ordinary level syllabus requires learners to study the topic of redox reactions. This topic has proven to be one of the most difficult for Namibian learners as reflected by their poor responses to questions in the Grade 11 and 12 Namibian Senior Secondary Certificate ‘O’ examinations. Teaching abstract concepts such as redox reactions requires higher cognitive thinking skills and thus presents a challenge. Against this background, this study sought to explore how teachers mediate learning of redox reactions in their classrooms. The focus was on conceptual understanding through linking content to the context of the learners. The study was underpinned by an interpretivist paradigm, within which a qualitative case study approach was adopted. Two Grade 11 Chemistry teachers from the Ohangwena and Oshana regions in Namibia were the research participants. I used semi-structured interviews, lesson observations and stimulated recall interviews to collect data. I used Shulman’s Pedagogical Content Knowledge as a theoretical framework in this study and the data sets were analysed using the Topic-Specific Pedagogical Content Knowledge components. Qualitative data were analysed inductively-deductively. The study’s findings revealed that teachers used various mediation tools such as analogies and prior knowledge. The results further illuminated that teachers should develop strong subject content knowledge and pedagogical content knowledge to have the best strategies in place to mediate learning of this topic. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Iindombo, Junilla Inamudhimbwa
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424030 , vital:72117
- Description: The Namibian Chemistry ordinary level syllabus requires learners to study the topic of redox reactions. This topic has proven to be one of the most difficult for Namibian learners as reflected by their poor responses to questions in the Grade 11 and 12 Namibian Senior Secondary Certificate ‘O’ examinations. Teaching abstract concepts such as redox reactions requires higher cognitive thinking skills and thus presents a challenge. Against this background, this study sought to explore how teachers mediate learning of redox reactions in their classrooms. The focus was on conceptual understanding through linking content to the context of the learners. The study was underpinned by an interpretivist paradigm, within which a qualitative case study approach was adopted. Two Grade 11 Chemistry teachers from the Ohangwena and Oshana regions in Namibia were the research participants. I used semi-structured interviews, lesson observations and stimulated recall interviews to collect data. I used Shulman’s Pedagogical Content Knowledge as a theoretical framework in this study and the data sets were analysed using the Topic-Specific Pedagogical Content Knowledge components. Qualitative data were analysed inductively-deductively. The study’s findings revealed that teachers used various mediation tools such as analogies and prior knowledge. The results further illuminated that teachers should develop strong subject content knowledge and pedagogical content knowledge to have the best strategies in place to mediate learning of this topic. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
Exploring rural youth livelihood opportunities: a case study of a youth centre in Bizana
- Authors: Mtwa, Zikhona Asanda
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/431485 , vital:72776
- Description: Throughout South Africa, youth that are not in Education, Employment, or Training (NEET) continue to face many socio-economic challenges, including unemployment. Bizana, a small rural town in the Eastern Cape, is no exception. This study explores rural youth livelihood opportunities for youth NEET in Bizana. There is limited research done to understand the role of youth centres in providing accessing to rural youth livelihood opportunities. As a result, this study sought to understand the role of youth centres in re-integrating youth NEET into the labour market, as well as into education and training institutions. It utilizes the case study of the Bizana Love Life youth centre by looking at the programmes they offer, and whether they enhance livelihood opportunities for youth NEET. The Sustainable Livelihoods Approach (SLA) was used as a theoretical lens in understanding rural youth livelihood opportunities for youth NEET in Bizana, by identifying the challenges they face and the assets they use to enhance their livelihoods. Against this backdrop, the study adopted a qualitative research approach and an explorative case study design and was supplemented by purposive and snowball sampling methods. Data was obtained using semi-structured interviews with twelve youth NEET participants who are part of the programmes of the youth centre, and two staff members of the youth centre. Findings were analysed using open coding and thematic analysis in line with the objectives of the study. The findings of the study revealed that in attempting to gain employment, extended family support, parenthood, financial reasons, household chores, poor academic performance and lack of work experience were some of the challenges facing rural youth NEET in Bizana. The findings indicate that a combination of human and social capital can be used to support youth NEET in gaining confidence and in preparing them for the workplace. With these findings, the study indicates the need to strengthen existing youth programmes that cater for youth NEET, who are the most vulnerable in the labour market, through skills development and broadening of their social networks. As a policy recommendation, the national and provincial government must work with youth centres and other stakeholders to establish policies that cater for the development of youth NEET. , Thesis (MSocSci) -- Faculty of Humanities, Sociology, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Mtwa, Zikhona Asanda
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/431485 , vital:72776
- Description: Throughout South Africa, youth that are not in Education, Employment, or Training (NEET) continue to face many socio-economic challenges, including unemployment. Bizana, a small rural town in the Eastern Cape, is no exception. This study explores rural youth livelihood opportunities for youth NEET in Bizana. There is limited research done to understand the role of youth centres in providing accessing to rural youth livelihood opportunities. As a result, this study sought to understand the role of youth centres in re-integrating youth NEET into the labour market, as well as into education and training institutions. It utilizes the case study of the Bizana Love Life youth centre by looking at the programmes they offer, and whether they enhance livelihood opportunities for youth NEET. The Sustainable Livelihoods Approach (SLA) was used as a theoretical lens in understanding rural youth livelihood opportunities for youth NEET in Bizana, by identifying the challenges they face and the assets they use to enhance their livelihoods. Against this backdrop, the study adopted a qualitative research approach and an explorative case study design and was supplemented by purposive and snowball sampling methods. Data was obtained using semi-structured interviews with twelve youth NEET participants who are part of the programmes of the youth centre, and two staff members of the youth centre. Findings were analysed using open coding and thematic analysis in line with the objectives of the study. The findings of the study revealed that in attempting to gain employment, extended family support, parenthood, financial reasons, household chores, poor academic performance and lack of work experience were some of the challenges facing rural youth NEET in Bizana. The findings indicate that a combination of human and social capital can be used to support youth NEET in gaining confidence and in preparing them for the workplace. With these findings, the study indicates the need to strengthen existing youth programmes that cater for youth NEET, who are the most vulnerable in the labour market, through skills development and broadening of their social networks. As a policy recommendation, the national and provincial government must work with youth centres and other stakeholders to establish policies that cater for the development of youth NEET. , Thesis (MSocSci) -- Faculty of Humanities, Sociology, 2023
- Full Text:
- Date Issued: 2023-10-13
Exploring the strategies for teaching reading comprehension to non-readers in upper primary phase: a case study of Namibian Grade 5 ESL experienced teachers
- Authors: Mavambe, Tsitsi
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424086 , vital:72122
- Description: Thesis embargoed. Expected release date 2025. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Mavambe, Tsitsi
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424086 , vital:72122
- Description: Thesis embargoed. Expected release date 2025. , Thesis (MEd) -- Faculty of Education, Secondary and Post-School Education, 2023
- Full Text:
- Date Issued: 2023-10-13
Fabrication of nanocatalysts as nanozymes-based biosensors for the detection of glucose and ascorbic acid
- Authors: Chavalala, Ridge Nhlamulo
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424501 , vital:72159
- Description: Embargoed. Expected release in 2025. , Thesis (MSc) -- Faculty of Science, Chemistry, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Chavalala, Ridge Nhlamulo
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424501 , vital:72159
- Description: Embargoed. Expected release in 2025. , Thesis (MSc) -- Faculty of Science, Chemistry, 2023
- Full Text:
- Date Issued: 2023-10-13
faces, disappearing
- Authors: Mbhele, Mbekezeli
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424952 , vital:72196
- Description: My thesis explores township life through the eyes of a young boy, Sengwayo, whose life changes when a strange man arrives unexpectedly to stay with his family. The man is introduced as his uncle but nothing further is said about him. Sengwayo soon begins to experience visions and decides to find out who this man really is. His search for truth soon becomes obsessive and culminates in tragedy. As we follow Sengwayo in his quest of uncovering the truth it becomes difficult to differentiate between Sengwayo’s imagination and reality. This thesis collapses the distance between what is and what could be. It does this by alternating short sentences mostly used in the poetry of maskanda lyrics, and in the stream of consciousness found in jazz improvisation. In literary terms, the thesis draws influence from the rants and rhyme schemes of Lesego Rampolokeng, the tone and pace of Sony Labou Tansi and the surrealism in Mangaliso Buzani’s work. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Mbhele, Mbekezeli
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424952 , vital:72196
- Description: My thesis explores township life through the eyes of a young boy, Sengwayo, whose life changes when a strange man arrives unexpectedly to stay with his family. The man is introduced as his uncle but nothing further is said about him. Sengwayo soon begins to experience visions and decides to find out who this man really is. His search for truth soon becomes obsessive and culminates in tragedy. As we follow Sengwayo in his quest of uncovering the truth it becomes difficult to differentiate between Sengwayo’s imagination and reality. This thesis collapses the distance between what is and what could be. It does this by alternating short sentences mostly used in the poetry of maskanda lyrics, and in the stream of consciousness found in jazz improvisation. In literary terms, the thesis draws influence from the rants and rhyme schemes of Lesego Rampolokeng, the tone and pace of Sony Labou Tansi and the surrealism in Mangaliso Buzani’s work. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2023
- Full Text:
- Date Issued: 2023-10-13
Fire disaster management in South Africa: modelling and data analysis at national and local level of government
- Authors: Madondo, Rennifer
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419577 , vital:71656
- Description: Embargoed. Possible release in 2026 pending publication. , Thesis (MSC Pharm) -- Faculty of Pharmacy, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Madondo, Rennifer
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/419577 , vital:71656
- Description: Embargoed. Possible release in 2026 pending publication. , Thesis (MSC Pharm) -- Faculty of Pharmacy, 2023
- Full Text:
- Date Issued: 2023-10-13
Framing VBS: a textual analysis of Daily Maverick’s coverage of the VBS Mutual Bank heist in the years 2018-2020
- Authors: Nyulu, Siyamthanda Natascha
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/425256 , vital:72223
- Description: This study investigates how Daily Maverick framed the VBS Mutual Bank scandal for its readers in the years 2018-2020. It utilises framing theory as the guiding theoretical framework in trying to understand how Daily Maverick portrayed the corruption case for its readers. This study also leans on social responsibility and normative theories of the press to analyse whether Daily Maverick fulfilled its role of facilitating dialogue between the elite and ordinary citizens of Limpopo affected by the corruption at the bank. Using a qualitative textual analysis, the thesis discusses how elite sources were quoted more than ordinary citizens who are affected the most by the corruption scandal. This allowed the elite to turn the VBS matter into a political spectacle whereas, because it is an example of failure in the financial sector, the heist caused further failures in municipalities already failing in Limpopo, North-West and Gauteng. , Thesis (MA) -- Faculty of Humanities, Journalism and Media Studies, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Nyulu, Siyamthanda Natascha
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/425256 , vital:72223
- Description: This study investigates how Daily Maverick framed the VBS Mutual Bank scandal for its readers in the years 2018-2020. It utilises framing theory as the guiding theoretical framework in trying to understand how Daily Maverick portrayed the corruption case for its readers. This study also leans on social responsibility and normative theories of the press to analyse whether Daily Maverick fulfilled its role of facilitating dialogue between the elite and ordinary citizens of Limpopo affected by the corruption at the bank. Using a qualitative textual analysis, the thesis discusses how elite sources were quoted more than ordinary citizens who are affected the most by the corruption scandal. This allowed the elite to turn the VBS matter into a political spectacle whereas, because it is an example of failure in the financial sector, the heist caused further failures in municipalities already failing in Limpopo, North-West and Gauteng. , Thesis (MA) -- Faculty of Humanities, Journalism and Media Studies, 2023
- Full Text:
- Date Issued: 2023-10-13
Freshwater invasive alien crayfish species in South Africa: testing eDNA assessment and DNA barcoding
- Mdidimba, Nonkazimulo Dorothea
- Authors: Mdidimba, Nonkazimulo Dorothea
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424413 , vital:72151
- Description: The expansion of the wild populations of the two invasive alien crayfish species, i.e., Cherax quadricarinatus and Procambarus clarkii in South Africa is of high concern. Given this, innovative and improved monitoring methods are required to be explored in order to effectively detect and manage their spread. Environmental DNA (eDNA) has shown promising and reliable results to detect and monitor alien crayfish in freshwater systems even at low densities. This research study aimed to field-test the application of eDNA for detecting and monitoring invasive alien freshwater crayfish species (IAFCs) in South African freshwater systems (Chapter 2). Further, this study also aimed to confirm the true taxonomic identity of the IAFCs in South African freshwater systems by using DNA barcoding to avoid potential misidentifications with morphological identification alone (Chapter 3). Also, ectocommensal temnocephalans and leeches attached to the crayfishes were also identified with DNA barcoding. The mitochondrial COI gene fragment of the crayfishes and the ectocommensal temnocephalans and leeches was amplified, sequenced, and used for species identification. For eDNA monitoring of C. cainii, C. quadricarinatus and P. clarkii, water samples were collected from Eastern Cape, Free State and KwaZulu Natal sites that are known to house these species. The current study did not detect the eDNA of the wild populations of both C. quadricarinatus and P. clarkii. This failure was encountered despite employing several methods, such as, end-point polymerase chain reaction (PCR), quantitative PCR (qPCR) and next-generation sequencing (NGS). The eDNA assessment to detect IAFCs in the wild populations is discussed in detail, and corrective measures suggested (Chapter 2). However, only C. cainii was able to be detected by eDNA. Cherax cainii is housed/farmed in an aquaculture facility (Vaughn Bursey’s Stock Farm in Eastern Cape) with large number of individuals per pond. For this, NGS was able to detect C. cainii but the other two methods, end-point PCR and qPCR were not able to detect the species. Based on the results, refinement of eDNA monitoring methods for the South African freshwater systems is recommended. Evaluation of different DNA collection methods, preservation, DNA extraction kits and primer design to obtain effective eDNA detection is discussed as possible sources of error. Interestingly, the newly established population of P. clarkii in Mimosa Dam in Free State was infested with alien leeches, that were confirmed by DNA barcoding to be Helobdella europaea and Helobdella octatestica. Consequently, this study reports for the first time in South Africa the presence of this alien freshwater leeches. The presence of alien leeches and P. clarkii suggests a double invasion in Mimosa Dam, P. clarkii seems to continue expanding its range in the country. However, the long-established population of P. clarkii in Driehoek Farm in Mpumalanga, which has been in the country for over 30 years did not have any leech or temnocephalan infestation. This could suggest several interesting ecological phenomena, including environmental filtering over time of the co-invaders, differential source populations, and post-introduction adaptation. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Mdidimba, Nonkazimulo Dorothea
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424413 , vital:72151
- Description: The expansion of the wild populations of the two invasive alien crayfish species, i.e., Cherax quadricarinatus and Procambarus clarkii in South Africa is of high concern. Given this, innovative and improved monitoring methods are required to be explored in order to effectively detect and manage their spread. Environmental DNA (eDNA) has shown promising and reliable results to detect and monitor alien crayfish in freshwater systems even at low densities. This research study aimed to field-test the application of eDNA for detecting and monitoring invasive alien freshwater crayfish species (IAFCs) in South African freshwater systems (Chapter 2). Further, this study also aimed to confirm the true taxonomic identity of the IAFCs in South African freshwater systems by using DNA barcoding to avoid potential misidentifications with morphological identification alone (Chapter 3). Also, ectocommensal temnocephalans and leeches attached to the crayfishes were also identified with DNA barcoding. The mitochondrial COI gene fragment of the crayfishes and the ectocommensal temnocephalans and leeches was amplified, sequenced, and used for species identification. For eDNA monitoring of C. cainii, C. quadricarinatus and P. clarkii, water samples were collected from Eastern Cape, Free State and KwaZulu Natal sites that are known to house these species. The current study did not detect the eDNA of the wild populations of both C. quadricarinatus and P. clarkii. This failure was encountered despite employing several methods, such as, end-point polymerase chain reaction (PCR), quantitative PCR (qPCR) and next-generation sequencing (NGS). The eDNA assessment to detect IAFCs in the wild populations is discussed in detail, and corrective measures suggested (Chapter 2). However, only C. cainii was able to be detected by eDNA. Cherax cainii is housed/farmed in an aquaculture facility (Vaughn Bursey’s Stock Farm in Eastern Cape) with large number of individuals per pond. For this, NGS was able to detect C. cainii but the other two methods, end-point PCR and qPCR were not able to detect the species. Based on the results, refinement of eDNA monitoring methods for the South African freshwater systems is recommended. Evaluation of different DNA collection methods, preservation, DNA extraction kits and primer design to obtain effective eDNA detection is discussed as possible sources of error. Interestingly, the newly established population of P. clarkii in Mimosa Dam in Free State was infested with alien leeches, that were confirmed by DNA barcoding to be Helobdella europaea and Helobdella octatestica. Consequently, this study reports for the first time in South Africa the presence of this alien freshwater leeches. The presence of alien leeches and P. clarkii suggests a double invasion in Mimosa Dam, P. clarkii seems to continue expanding its range in the country. However, the long-established population of P. clarkii in Driehoek Farm in Mpumalanga, which has been in the country for over 30 years did not have any leech or temnocephalan infestation. This could suggest several interesting ecological phenomena, including environmental filtering over time of the co-invaders, differential source populations, and post-introduction adaptation. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2023
- Full Text:
- Date Issued: 2023-10-13
Gender, informality and urban livelihoods: eamining the livelihood strategies adopted by Black female street vendors in Makhanda, Eastern Cape
- Authors: Khoele, Lineo
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/431474 , vital:72775
- Description: This study sought to examine livelihood strategies adopted by black female street vendors in Makhanda, Eastern Cape. The street vending activities that were undertaken by the research participants included selling: cooked foods, fresh fruit and vegetables, eggs, and beauty products. This study used the Sustainable Livelihood Approach (SLA) to examine the livelihood strategies of black female street vendors in Makhanda. The SL approach was chosen as an ideal framework for a study of this nature as it holistically and traditionally focuses on vulnerable population groups around the world. More importantly, the SLA gives agency to these vulnerable groups, as it prioritizes their innovative techniques in mobilizing diverse assets at their disposal in order to survive. The study is, therefore, ideal as it also gives agency to selected black female street vendors by examining how they utilized diverse assets at their disposal to sustain their livelihoods. This study seeks to contribute to the ongoing debate on urban livelihoods and the informal economy in South Africa, focusing particularly on the different methods or strategies employed by black female street vendors to enhance the sustainability of street vending as a livelihood. Due to the nature of this study, which seeks to capture the lived experiences of the selected black female street vendors in Makhanda, qualitative research methodologies were used to collect and analyse data. This study proved street vending to be a survival strategy that is used by black unskilled women in pursuit of livelihoods. It argues that, faced with the socio-economic realities associated with high unemployment, street vending can be used by many to best support their households. When it comes to livelihood strategies, this study found that, livelihood diversification is the most common livelihood strategy adopted by street vendors in Makhanda, with the only difference being the type of diversification adopted. Two forms of livelihood diversification strategies were identified in this study, and these included: product diversification and income diversification. The conclusion drawn from the findings argues that the selected street vendors in Makhanda strategically used different assets accessible to them to enhance and sustain their livelihoods. The study found that despite the different structural challenges faced by street vendors in Makhanda, the selected black female street vendors are able to meet their livelihood outcomes and support their families through engaging in street vending. , Thesis (MSocSci) -- Faculty of Humanities, Sociology, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Khoele, Lineo
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/431474 , vital:72775
- Description: This study sought to examine livelihood strategies adopted by black female street vendors in Makhanda, Eastern Cape. The street vending activities that were undertaken by the research participants included selling: cooked foods, fresh fruit and vegetables, eggs, and beauty products. This study used the Sustainable Livelihood Approach (SLA) to examine the livelihood strategies of black female street vendors in Makhanda. The SL approach was chosen as an ideal framework for a study of this nature as it holistically and traditionally focuses on vulnerable population groups around the world. More importantly, the SLA gives agency to these vulnerable groups, as it prioritizes their innovative techniques in mobilizing diverse assets at their disposal in order to survive. The study is, therefore, ideal as it also gives agency to selected black female street vendors by examining how they utilized diverse assets at their disposal to sustain their livelihoods. This study seeks to contribute to the ongoing debate on urban livelihoods and the informal economy in South Africa, focusing particularly on the different methods or strategies employed by black female street vendors to enhance the sustainability of street vending as a livelihood. Due to the nature of this study, which seeks to capture the lived experiences of the selected black female street vendors in Makhanda, qualitative research methodologies were used to collect and analyse data. This study proved street vending to be a survival strategy that is used by black unskilled women in pursuit of livelihoods. It argues that, faced with the socio-economic realities associated with high unemployment, street vending can be used by many to best support their households. When it comes to livelihood strategies, this study found that, livelihood diversification is the most common livelihood strategy adopted by street vendors in Makhanda, with the only difference being the type of diversification adopted. Two forms of livelihood diversification strategies were identified in this study, and these included: product diversification and income diversification. The conclusion drawn from the findings argues that the selected street vendors in Makhanda strategically used different assets accessible to them to enhance and sustain their livelihoods. The study found that despite the different structural challenges faced by street vendors in Makhanda, the selected black female street vendors are able to meet their livelihood outcomes and support their families through engaging in street vending. , Thesis (MSocSci) -- Faculty of Humanities, Sociology, 2023
- Full Text:
- Date Issued: 2023-10-13
Giving a voice and holding to account: a critical civic and democratic discourse analysis of The Big Debate South Africa TV show’s opportunities for ‘Political Listening’
- Authors: Mgqoboka, Banathi
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/425245 , vital:72222
- Description: The television studio debate genre was initially inspired by the 1960s television news coverage that captured the zeitgeist of American political campaigns and elections, which featured prominent political figures. The genre has since been adapted by broadcast networks around the world to facilitate politically-charged public discussions that allow ordinary people to pose significant questions and express their concerns or cynicism to the political elites in power. The Big Debate South Africa is a popular televised town hall debate show that began airing in 2009 on eMedia Investment’s eNCA and later on the SABC. During its ninth-season run, the show attracted an audience of up to 12 million. The programme is formatted to give South African citizens a voice to hold state leaders to account. Anthea Garman and Herman Wasserman’s (2014) research on citizenship and media in a democratic society, asserts that the media’s contribution to citizenship is often a way to encourage citizens to exercise their influence over political decisions and dialogue in an overt manner. Through observations and qualitative in-depth interviews, this tightly focused study analysed the third episode of The Big Debate South Africa’s ninth season, hosted by journalist and broadcaster Redi Tlhabi. It explored the show’s format and discourse to investigate how it creates opportunities for the practice of Susan Bickford’s (1996) conception of ‘political listening’ within the confines of hierarchical binary oppositions (‘Us and Them’ and ‘lay’/‘expert’). By deconstructing how civil society organisations, activists and citizens (‘lay’) interact with the political elites (‘experts’), this study chronicled how the show mediates these binary oppositions with an anticipation for them to collectively hear each other out. In examining the show’s structure as a participative civic political broadcast talk platform that promotes democratic deliberation, this study ultimately demonstrated the capacity of The Big Debate South Africa to pluralise democratic life in its practice of ‘political listening’. While the show advances equality and amplifies marginalised voices, this research also found that these significant practices seemingly only held temporary effects once the cameras shut down. , Thesis (MA) -- Faculty of Humanities, Journalism and Media Studies, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Mgqoboka, Banathi
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/425245 , vital:72222
- Description: The television studio debate genre was initially inspired by the 1960s television news coverage that captured the zeitgeist of American political campaigns and elections, which featured prominent political figures. The genre has since been adapted by broadcast networks around the world to facilitate politically-charged public discussions that allow ordinary people to pose significant questions and express their concerns or cynicism to the political elites in power. The Big Debate South Africa is a popular televised town hall debate show that began airing in 2009 on eMedia Investment’s eNCA and later on the SABC. During its ninth-season run, the show attracted an audience of up to 12 million. The programme is formatted to give South African citizens a voice to hold state leaders to account. Anthea Garman and Herman Wasserman’s (2014) research on citizenship and media in a democratic society, asserts that the media’s contribution to citizenship is often a way to encourage citizens to exercise their influence over political decisions and dialogue in an overt manner. Through observations and qualitative in-depth interviews, this tightly focused study analysed the third episode of The Big Debate South Africa’s ninth season, hosted by journalist and broadcaster Redi Tlhabi. It explored the show’s format and discourse to investigate how it creates opportunities for the practice of Susan Bickford’s (1996) conception of ‘political listening’ within the confines of hierarchical binary oppositions (‘Us and Them’ and ‘lay’/‘expert’). By deconstructing how civil society organisations, activists and citizens (‘lay’) interact with the political elites (‘experts’), this study chronicled how the show mediates these binary oppositions with an anticipation for them to collectively hear each other out. In examining the show’s structure as a participative civic political broadcast talk platform that promotes democratic deliberation, this study ultimately demonstrated the capacity of The Big Debate South Africa to pluralise democratic life in its practice of ‘political listening’. While the show advances equality and amplifies marginalised voices, this research also found that these significant practices seemingly only held temporary effects once the cameras shut down. , Thesis (MA) -- Faculty of Humanities, Journalism and Media Studies, 2023
- Full Text:
- Date Issued: 2023-10-13
Halogenated Aza-BODIPY dyes for photodynamic anticancer and antimicrobial activity studies
- Magwaza, Temlandvo Matshidiso
- Authors: Magwaza, Temlandvo Matshidiso
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424514 , vital:72160
- Description: This thesis reports on the synthesis and characterisation of differently substituted aza-BODIPY dyes for use in photodynamic antimicrobial chemotherapy (PACT) and photodynamic therapy (PDT) activity studies. The aza-BODIPY dyes were synthesised by adding phenyl and naphthyl rings at the 3,5-positions of the aza-BODIPY core, with methylthiolphenyl (9a and 9b, respectively) or thien-2-yl rings (9c and 9d, respectively) at the 1,7-positions. 9a-c were iodinated at the 2-position to form 10a-c, respectively, while 9d was diiodinated at the 2,6-positions to form 10d. The methylthiolphenyl-substituted dyes (10a and 10b) were successfully conjugated to gold nanoparticles (AuNPs) to form nanoparticles conjugates (10a-AuNPs and 10b-AuNPs), while attempts to conjugate the thien-2-yl-substituted dyes were unsuccessful. The photophysicochemical properties of 9a-d, 10a-d and nanoconjugates 10a-AuNPs and 10b-AuNPs were investigated to determine their suitability for use in the applications. Adding heavy atoms such as iodine at the 2,6-positions of the aza-BODIPY led to enhanced singlet oxygen generation since these dyes displayed moderate to high singlet oxygen quantum yields. None of the dyes exhibited any fluorescence. The PACT activity studies for 9c-d, 10a-d, and the 10a-AuNPs and 10b-AuNPs were carried out against Staphylococcus aureus and Escherichia coli with a Thorlabs M660L3 light-emitting diode (LED) with an irradiance of 280 mW/cm2 for all dyes other than 10d. A Thorlabs M730L4 LED with an irradiance of 160 mW/cm2 was used for 10d. Time dependence studies were only carried out against Staphylococcus aureus, so very low log reductions were observed against Escherichia coli in initial concentration studies. The 10a-AuNP and 10b-AuNP nanoconjugates exhibited high antimicrobial activity with a log reduction of 9.41 and 0.00% viable colonies, while the iodinated aza-BODIPY had a log reduction of 8.94. The in vitro photodynamic therapy activities and dark cytotoxicity were investigated against human MCF-7 breast cancer cells for dyes 9c-d and 10c-d with a Thorlabs M660L3 LED (280 mW/cm2) for all dyes. The dark cytotoxicity was minimal in each case with IC50 > 50. Iodinated dyes 10c and 10d had IC50 values of 11.6 and 8.2 μM, respectively, and non-iodinated dyes 9c and 9d had IC50 values of 12.5 and 19.2 μM. The heavy atom effect associated with the iodine atoms increases the singlet oxygen quantum yield and enhances the suitability of the dyes for photodynamic therapy. , Thesis (MSc) -- Faculty of Science, Chemistry, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Magwaza, Temlandvo Matshidiso
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/424514 , vital:72160
- Description: This thesis reports on the synthesis and characterisation of differently substituted aza-BODIPY dyes for use in photodynamic antimicrobial chemotherapy (PACT) and photodynamic therapy (PDT) activity studies. The aza-BODIPY dyes were synthesised by adding phenyl and naphthyl rings at the 3,5-positions of the aza-BODIPY core, with methylthiolphenyl (9a and 9b, respectively) or thien-2-yl rings (9c and 9d, respectively) at the 1,7-positions. 9a-c were iodinated at the 2-position to form 10a-c, respectively, while 9d was diiodinated at the 2,6-positions to form 10d. The methylthiolphenyl-substituted dyes (10a and 10b) were successfully conjugated to gold nanoparticles (AuNPs) to form nanoparticles conjugates (10a-AuNPs and 10b-AuNPs), while attempts to conjugate the thien-2-yl-substituted dyes were unsuccessful. The photophysicochemical properties of 9a-d, 10a-d and nanoconjugates 10a-AuNPs and 10b-AuNPs were investigated to determine their suitability for use in the applications. Adding heavy atoms such as iodine at the 2,6-positions of the aza-BODIPY led to enhanced singlet oxygen generation since these dyes displayed moderate to high singlet oxygen quantum yields. None of the dyes exhibited any fluorescence. The PACT activity studies for 9c-d, 10a-d, and the 10a-AuNPs and 10b-AuNPs were carried out against Staphylococcus aureus and Escherichia coli with a Thorlabs M660L3 light-emitting diode (LED) with an irradiance of 280 mW/cm2 for all dyes other than 10d. A Thorlabs M730L4 LED with an irradiance of 160 mW/cm2 was used for 10d. Time dependence studies were only carried out against Staphylococcus aureus, so very low log reductions were observed against Escherichia coli in initial concentration studies. The 10a-AuNP and 10b-AuNP nanoconjugates exhibited high antimicrobial activity with a log reduction of 9.41 and 0.00% viable colonies, while the iodinated aza-BODIPY had a log reduction of 8.94. The in vitro photodynamic therapy activities and dark cytotoxicity were investigated against human MCF-7 breast cancer cells for dyes 9c-d and 10c-d with a Thorlabs M660L3 LED (280 mW/cm2) for all dyes. The dark cytotoxicity was minimal in each case with IC50 > 50. Iodinated dyes 10c and 10d had IC50 values of 11.6 and 8.2 μM, respectively, and non-iodinated dyes 9c and 9d had IC50 values of 12.5 and 19.2 μM. The heavy atom effect associated with the iodine atoms increases the singlet oxygen quantum yield and enhances the suitability of the dyes for photodynamic therapy. , Thesis (MSc) -- Faculty of Science, Chemistry, 2023
- Full Text:
- Date Issued: 2023-10-13
HI View of the Norma Galaxy Cluster with MeerKAT
- Authors: Mophahlane, Koketso Vincent
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/432530 , vital:72878
- Description: Studies reveal that galaxies assemble into clusters as gas-rich, active star-forming disks and eventually settle in the virialized core as quenched early-type galaxies with depleted gas. To examine environmental effects responsible for the quenched population in the cluster core, we exploit the higher sensitivity of the MeerKAT telescope to probe Hi properties of galaxies in the Norma cluster. The Norma cluster is an ideal laboratory for this study since it is a rich and massive cluster of nearby galaxies. The Hi data cube used covers a velocity range of 483 − 11, 113 km/s, with a noise rms sensitivity of 0.09 mJy/beam and an angular resolution of ∼ 14.65′′ × 9.28′′. A total of 25 reliable Hi sources were detected over the entire velocity range. The Hi detections reveal two major galaxy overdensities located at vrad ∼ 2096 − 7646 km/s and vrad ∼ 10, 000 km/s. The first is associated with the Norma cluster gravitational potential and indicates a substructure in its velocity distribution; the other is a population of background galaxies. In this work, the Norma cluster has 13 cluster members detected in Hi and 130 galaxies from optical surveys. The spatial distribution of cluster members covers a field that is 2/3 × RA, where RA = 2.02 Mpc at cz = 4871 km/s. From the spatial distribution, optical galaxies are densely populated in the central regions, while most galaxies in Hi were detected on the outskirts. From the phase-space diagram, 6 galaxies detected in Hi are found in the virialised region, while the rest of the detections are infalling for the first time. Hi detections that are not yet virialised have asymmetrical morphologies, while virialised detections have truncated gas disks. Most cluster members that were found to have asymmetrical gas disks are also Hi deficient by 0.8 − 1.2 dex but show excess SFR efficiency for the amount of Hi detected. The results demonstrate that the initial phase of galaxy-ICM interactions might be responsible for morphological transformation and enhancement of star formation activity. , Thesis (MSc) -- Faculty of Science, Physics and Electronics, 2023
- Full Text:
- Date Issued: 2023-10-13
- Authors: Mophahlane, Koketso Vincent
- Date: 2023-10-13
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/432530 , vital:72878
- Description: Studies reveal that galaxies assemble into clusters as gas-rich, active star-forming disks and eventually settle in the virialized core as quenched early-type galaxies with depleted gas. To examine environmental effects responsible for the quenched population in the cluster core, we exploit the higher sensitivity of the MeerKAT telescope to probe Hi properties of galaxies in the Norma cluster. The Norma cluster is an ideal laboratory for this study since it is a rich and massive cluster of nearby galaxies. The Hi data cube used covers a velocity range of 483 − 11, 113 km/s, with a noise rms sensitivity of 0.09 mJy/beam and an angular resolution of ∼ 14.65′′ × 9.28′′. A total of 25 reliable Hi sources were detected over the entire velocity range. The Hi detections reveal two major galaxy overdensities located at vrad ∼ 2096 − 7646 km/s and vrad ∼ 10, 000 km/s. The first is associated with the Norma cluster gravitational potential and indicates a substructure in its velocity distribution; the other is a population of background galaxies. In this work, the Norma cluster has 13 cluster members detected in Hi and 130 galaxies from optical surveys. The spatial distribution of cluster members covers a field that is 2/3 × RA, where RA = 2.02 Mpc at cz = 4871 km/s. From the spatial distribution, optical galaxies are densely populated in the central regions, while most galaxies in Hi were detected on the outskirts. From the phase-space diagram, 6 galaxies detected in Hi are found in the virialised region, while the rest of the detections are infalling for the first time. Hi detections that are not yet virialised have asymmetrical morphologies, while virialised detections have truncated gas disks. Most cluster members that were found to have asymmetrical gas disks are also Hi deficient by 0.8 − 1.2 dex but show excess SFR efficiency for the amount of Hi detected. The results demonstrate that the initial phase of galaxy-ICM interactions might be responsible for morphological transformation and enhancement of star formation activity. , Thesis (MSc) -- Faculty of Science, Physics and Electronics, 2023
- Full Text:
- Date Issued: 2023-10-13