Learning about water through the African catchment game : the refinement of a role playing simulation game
- Authors: Fraenkel, Linda Anne
- Date: 2010
- Subjects: Water -- South Africa -- Management -- Simulation methods Water -- Management -- Study and teaching Rain and rainfall -- South Africa -- Simulation methods Simulation games in education Role playing
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:4842 , http://hdl.handle.net/10962/d1005518
- Description: This research has undertaken two key mandates. One was to develop modifications to the African Catchment Game (ACG), a role playing simulation game, in order to simulate rainfall and water management processes representative of the southern African context. The other was to understand what, if any, learning associated with water management issues had taken place as a result of playing the ACG. The modification process took the form of an action research process. The initial modifications were trialed with South African students as part of their undergraduate Geography course offered at Rhodes University, South Africa. Subsequent modifications were implemented over a five month period with three diverse participant groups, namely Finnish, American and South African participants. An interpretive research orientation was employed in order to analyse both the qualitative and quantitative data that was generated. Pre- and Post-Game Questionnaires were used in order to identify the learning and understanding which the participants constructed as a result of playing the ACG. The Chi-Square Test was also applied to each of the pre- and post- questions to establish statistical significance. Subsequent analysis of these questions identified and traced patters and trends associated with learning and understanding across the three game runs. This research study draws on social constructivism and experiential learning as the dominant education theory that underpins it. Results revealed that for all three game runs learning took place. Participants identified dominant themes and environmental dimensions both before and after playing the ACG. The analysis of these responses indicated a deeper awareness of water as a contributing factor for sustainable economic development while the game runs enabled the researcher to adjust the water availability within each game run until rainfall and water management processes representative of a southern African context were successfully simulated in the last game run.
- Full Text:
- Authors: Fraenkel, Linda Anne
- Date: 2010
- Subjects: Water -- South Africa -- Management -- Simulation methods Water -- Management -- Study and teaching Rain and rainfall -- South Africa -- Simulation methods Simulation games in education Role playing
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:4842 , http://hdl.handle.net/10962/d1005518
- Description: This research has undertaken two key mandates. One was to develop modifications to the African Catchment Game (ACG), a role playing simulation game, in order to simulate rainfall and water management processes representative of the southern African context. The other was to understand what, if any, learning associated with water management issues had taken place as a result of playing the ACG. The modification process took the form of an action research process. The initial modifications were trialed with South African students as part of their undergraduate Geography course offered at Rhodes University, South Africa. Subsequent modifications were implemented over a five month period with three diverse participant groups, namely Finnish, American and South African participants. An interpretive research orientation was employed in order to analyse both the qualitative and quantitative data that was generated. Pre- and Post-Game Questionnaires were used in order to identify the learning and understanding which the participants constructed as a result of playing the ACG. The Chi-Square Test was also applied to each of the pre- and post- questions to establish statistical significance. Subsequent analysis of these questions identified and traced patters and trends associated with learning and understanding across the three game runs. This research study draws on social constructivism and experiential learning as the dominant education theory that underpins it. Results revealed that for all three game runs learning took place. Participants identified dominant themes and environmental dimensions both before and after playing the ACG. The analysis of these responses indicated a deeper awareness of water as a contributing factor for sustainable economic development while the game runs enabled the researcher to adjust the water availability within each game run until rainfall and water management processes representative of a southern African context were successfully simulated in the last game run.
- Full Text:
Microbial ecology of the Buffalo River in response to water quality changes
- Authors: Zuma, Bongumusa Msizi
- Date: 2010
- Subjects: Water quality -- South Africa -- Buffalo River (Eastern Cape) , Microbial ecology -- South Africa -- Buffalo River (Eastern Cape) , River Health Programme (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:6038 , http://hdl.handle.net/10962/d1006182 , Water quality -- South Africa -- Buffalo River (Eastern Cape) , Microbial ecology -- South Africa -- Buffalo River (Eastern Cape) , River Health Programme (South Africa)
- Description: South Africa’s freshwater quality and quantity is declining and consequently impacting on the ecological health of these ecosystems, due to increased agricultural, urban and industrial developments. The River Health Programme (RHP) was designed for monitoring and assessing the ecological health of freshwater ecosystems in South Africa, in order to effectively manage these aquatic resources. The RHP utilises biological indicators such as in-stream biota as a structured and sensitive tool for assessing ecosystem health. Although the RHP has been widely implemented across South Africa, no attempts have been made to explore microbial ecology as a tool that could be included as one of the RHP indices. This study used selected microbial responses and water physico-chemical parameters to assess the current water quality status of the Buffalo River. This study showed that water quality impairments compounded in the urban regions of King William’s Town and Zwelitsha and also downstream of the Bridle Drift Dam. The results also showed that the lower and the upper catchments of the Buffalo River were not significantly different in terms of water physico-chemistry and microbiology, as indicated by low stress levels of an NMDS plot. Though similarities were recorded between impacted and reference sites, the results strongly showed that known impacted sites recorded the poorest water physico-chemistry, including the Yellowwoods River. However, the Laing Dam provided a buffer effect on contributions of the Yellowwoods River into the Buffalo River. Multivariate analysis showed that microbial cell counts were not influenced by water physico-chemical changes, whilst microbial activity from the water and biofilm habitats showed significant correlation levels to water physico-chemical changes. This study demonstrated that further investigations towards exploitation of microbial activity responses to water physico-chemical quality changes should be channelled towards the development of microbiological assessment index for inclusion in the RHP.
- Full Text:
- Authors: Zuma, Bongumusa Msizi
- Date: 2010
- Subjects: Water quality -- South Africa -- Buffalo River (Eastern Cape) , Microbial ecology -- South Africa -- Buffalo River (Eastern Cape) , River Health Programme (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:6038 , http://hdl.handle.net/10962/d1006182 , Water quality -- South Africa -- Buffalo River (Eastern Cape) , Microbial ecology -- South Africa -- Buffalo River (Eastern Cape) , River Health Programme (South Africa)
- Description: South Africa’s freshwater quality and quantity is declining and consequently impacting on the ecological health of these ecosystems, due to increased agricultural, urban and industrial developments. The River Health Programme (RHP) was designed for monitoring and assessing the ecological health of freshwater ecosystems in South Africa, in order to effectively manage these aquatic resources. The RHP utilises biological indicators such as in-stream biota as a structured and sensitive tool for assessing ecosystem health. Although the RHP has been widely implemented across South Africa, no attempts have been made to explore microbial ecology as a tool that could be included as one of the RHP indices. This study used selected microbial responses and water physico-chemical parameters to assess the current water quality status of the Buffalo River. This study showed that water quality impairments compounded in the urban regions of King William’s Town and Zwelitsha and also downstream of the Bridle Drift Dam. The results also showed that the lower and the upper catchments of the Buffalo River were not significantly different in terms of water physico-chemistry and microbiology, as indicated by low stress levels of an NMDS plot. Though similarities were recorded between impacted and reference sites, the results strongly showed that known impacted sites recorded the poorest water physico-chemistry, including the Yellowwoods River. However, the Laing Dam provided a buffer effect on contributions of the Yellowwoods River into the Buffalo River. Multivariate analysis showed that microbial cell counts were not influenced by water physico-chemical changes, whilst microbial activity from the water and biofilm habitats showed significant correlation levels to water physico-chemical changes. This study demonstrated that further investigations towards exploitation of microbial activity responses to water physico-chemical quality changes should be channelled towards the development of microbiological assessment index for inclusion in the RHP.
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Movement patterns and population dynamics of four catsharks endemic to South Africa
- Authors: Escobar-Porras, Jessica
- Date: 2010
- Subjects: Chondrichthyes -- South Africa , Fish populations -- South Africa , Fishes -- Behavior -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5303 , http://hdl.handle.net/10962/d1005148 , Chondrichthyes -- South Africa , Fish populations -- South Africa , Fishes -- Behavior -- South Africa
- Description: Sharks are particularly vulnerable to over-exploitation. Although catsharks are an important component of the near-shore marine biodiversity in South Africa and most of the species are endemic, little is known about their movement patterns, home range and population size. With an increasing number of recreational fishers this information is crucial for their conservation. The aims of this study were threefold. Firstly, to identify and analyze existing data sources on movement patterns and population dynamics for four catshark species: pyjama (Poroderma africanum), leopard (P. pantherinum), puffadder (Haploblepharus edwarsii) and brown (H. fuscus). This highlighted a number of shortcomings with existing data sets, largely because these studies had diverse objectives and were not aimed solely at catsharks. Secondly, a dedicated study was carried out for a limited area, testing a number of methods for data collection, and where appropriate the data was analyzed to determine movement patterns and population numbers. Thirdly, the most appropriate methodology for future studies (with similar objectives) was identified, and the results of the study were used to propose a number of conservation measures. All species of catsharks exhibited strong site fidelity and limited dispersal for extended periods. A few individuals did, however, travel distances in excess of 150 km. Significant trends in temporal abundance were not observed, nevertheless, there was some evidence for higher catches from September to December. Population estimates for the study area were low, with P. africanum having the smallest population size while H. fuscus had the highest population size within the restricted study area. Limited movements, high site fidelity and small population sizes emphasize their vulnerability and suggest that catsharks would benefit from no-take marine protected areas.
- Full Text:
- Authors: Escobar-Porras, Jessica
- Date: 2010
- Subjects: Chondrichthyes -- South Africa , Fish populations -- South Africa , Fishes -- Behavior -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5303 , http://hdl.handle.net/10962/d1005148 , Chondrichthyes -- South Africa , Fish populations -- South Africa , Fishes -- Behavior -- South Africa
- Description: Sharks are particularly vulnerable to over-exploitation. Although catsharks are an important component of the near-shore marine biodiversity in South Africa and most of the species are endemic, little is known about their movement patterns, home range and population size. With an increasing number of recreational fishers this information is crucial for their conservation. The aims of this study were threefold. Firstly, to identify and analyze existing data sources on movement patterns and population dynamics for four catshark species: pyjama (Poroderma africanum), leopard (P. pantherinum), puffadder (Haploblepharus edwarsii) and brown (H. fuscus). This highlighted a number of shortcomings with existing data sets, largely because these studies had diverse objectives and were not aimed solely at catsharks. Secondly, a dedicated study was carried out for a limited area, testing a number of methods for data collection, and where appropriate the data was analyzed to determine movement patterns and population numbers. Thirdly, the most appropriate methodology for future studies (with similar objectives) was identified, and the results of the study were used to propose a number of conservation measures. All species of catsharks exhibited strong site fidelity and limited dispersal for extended periods. A few individuals did, however, travel distances in excess of 150 km. Significant trends in temporal abundance were not observed, nevertheless, there was some evidence for higher catches from September to December. Population estimates for the study area were low, with P. africanum having the smallest population size while H. fuscus had the highest population size within the restricted study area. Limited movements, high site fidelity and small population sizes emphasize their vulnerability and suggest that catsharks would benefit from no-take marine protected areas.
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Negotiating sexuality in Grahamstown East: young black women's experiences of relationships in the context of HIV risk
- Authors: Clüver, Frances Rose Mannix
- Date: 2010
- Subjects: HIV infections -- South Africa -- Grahamstown Man-woman relationships -- South Africa -- Grahamstown Intimacy -- South Africa -- Grahamstown Sex -- South Africa -- Grahamstown Youth, Black -- South Africa -- Grahamstown -- Sexual behavior HIV infections -- Social aspects -- South Africa -- Grahamstown Youth, Black -- South Africa -- Grahamstown -- Attitudes Reproductive health -- South Africa -- Grahamstown Health education -- South Africa -- Grahamstown Youth, Black -- South Africa -- Grahamstown -- Health and hygiene Phenomenological psychology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2951 , http://hdl.handle.net/10962/d1002460
- Description: Adolescent sexual health has been identified as a significant health and development problem facing South Africa. Limited amounts of research on sexual interactions have been undertaken, with information on adolescents’ romantic relationships being particularly scarce. Qualitative research needs to foster an understanding of the dynamics of sexual interactions in specific settings, and with emphasis in the past on cognitive health psychology models, very little is thus known about how adolescents negotiate and make sense of their sexual experiences. This highlights the need to investigate the complexities of human sexuality in a contextual manner. In response, this study explores the lived experiences of four young black women as they negotiate their agency and sexuality in a local context. By way of in-depth qualitative interviews, which were analysed for recurrent themes using interpretative phenomenological analysis, this project examines the participants’ experiences regarding sex, relationships, communication, sexual health care, as well as HIV and pregnancy prevention. The results reveal that communication about sexuality in the participants’ homes was limited if not absent altogether. When seeking sexual health care, they found clinic nurses to be judgemental and rude. Regarding sexuality and HIV education, the participants stressed the need for outside educators to teach in more practical ways to increase efficacy. In their dating relationships, most participants revealed their boyfriends had a great deal of influence over their sexual initiation. Unwanted pregnancy surfaced as a greater fear than HIV in their accounts due to pressure to finish their education and attain well-paying jobs in the future. The participants felt unable to stop their boyfriends’ infidelity and had limited agency when facing sexual demands. Their accounts revealed that they negotiate their agency in an atmosphere of coercion and the threat of rape. However, areas of agency included their consistent condom use even when facing pressure to have unprotected sex, and their active accessing of sexual health services for hormonal contraception. These insights serve to better inform sexual and reproductive health education and intervention programmes for young women. Moreover, educators, researchers and programme developers alike may gain useful insights from the personalised accounts derived from this study.
- Full Text:
- Authors: Clüver, Frances Rose Mannix
- Date: 2010
- Subjects: HIV infections -- South Africa -- Grahamstown Man-woman relationships -- South Africa -- Grahamstown Intimacy -- South Africa -- Grahamstown Sex -- South Africa -- Grahamstown Youth, Black -- South Africa -- Grahamstown -- Sexual behavior HIV infections -- Social aspects -- South Africa -- Grahamstown Youth, Black -- South Africa -- Grahamstown -- Attitudes Reproductive health -- South Africa -- Grahamstown Health education -- South Africa -- Grahamstown Youth, Black -- South Africa -- Grahamstown -- Health and hygiene Phenomenological psychology
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2951 , http://hdl.handle.net/10962/d1002460
- Description: Adolescent sexual health has been identified as a significant health and development problem facing South Africa. Limited amounts of research on sexual interactions have been undertaken, with information on adolescents’ romantic relationships being particularly scarce. Qualitative research needs to foster an understanding of the dynamics of sexual interactions in specific settings, and with emphasis in the past on cognitive health psychology models, very little is thus known about how adolescents negotiate and make sense of their sexual experiences. This highlights the need to investigate the complexities of human sexuality in a contextual manner. In response, this study explores the lived experiences of four young black women as they negotiate their agency and sexuality in a local context. By way of in-depth qualitative interviews, which were analysed for recurrent themes using interpretative phenomenological analysis, this project examines the participants’ experiences regarding sex, relationships, communication, sexual health care, as well as HIV and pregnancy prevention. The results reveal that communication about sexuality in the participants’ homes was limited if not absent altogether. When seeking sexual health care, they found clinic nurses to be judgemental and rude. Regarding sexuality and HIV education, the participants stressed the need for outside educators to teach in more practical ways to increase efficacy. In their dating relationships, most participants revealed their boyfriends had a great deal of influence over their sexual initiation. Unwanted pregnancy surfaced as a greater fear than HIV in their accounts due to pressure to finish their education and attain well-paying jobs in the future. The participants felt unable to stop their boyfriends’ infidelity and had limited agency when facing sexual demands. Their accounts revealed that they negotiate their agency in an atmosphere of coercion and the threat of rape. However, areas of agency included their consistent condom use even when facing pressure to have unprotected sex, and their active accessing of sexual health services for hormonal contraception. These insights serve to better inform sexual and reproductive health education and intervention programmes for young women. Moreover, educators, researchers and programme developers alike may gain useful insights from the personalised accounts derived from this study.
- Full Text:
Network management for community networks
- Authors: Wells, Daniel David
- Date: 2010 , 2010-03-26
- Subjects: Computer networks -- Management , Internet -- South Africa , Internet -- Management , Broadband communication systems
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4643 , http://hdl.handle.net/10962/d1006587
- Description: Community networks (in South Africa and Africa) are often serviced by limited bandwidth network backhauls. Relative to the basic needs of the community, this is an expensive ongoing concern. In many cases the Internet connection is shared among multiple sites. Community networks may also have a lack of technical personnel to maintain a network of this nature. Hence, there is a demand for a system which will monitor and manage bandwidth use, as well as network use. The proposed solution for community networks and the focus within this dissertation, is a system of two parts. A Community Access Point (CAP) is located at each site within the community network. This provides the hosts and servers at that site with access to services on the community network and the Internet, it is the site's router. The CAP provides a web based interface (CAPgui) which allows configuration of the device and viewing of simple monitoring statistics. The Access Concentrator (AC) is the default router for the CAPs and the gateway to the Internet. It provides authenticated and encrypted communication between the network sites. The AC performs several monitoring functions, both for the individual sites and for the upstream Internet connection. The AC provides a means for centrally managing and effectively allocating Internet bandwidth by using the web based interface (ACgui). Bandwidth use can be allocated per user, per host and per site. The system is maintainable, extendable and customisable for different network architectures. The system was deployed successfully to two community networks. The Centre of Excellence (CoE) testbed network is a peri-urban network deployment whereas the Siyakhula Living Lab (SLL) network is a rural deployment. The results gathered conclude that the project was successful as the deployed system is more robust and more manageable than the previous systems.
- Full Text:
- Authors: Wells, Daniel David
- Date: 2010 , 2010-03-26
- Subjects: Computer networks -- Management , Internet -- South Africa , Internet -- Management , Broadband communication systems
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4643 , http://hdl.handle.net/10962/d1006587
- Description: Community networks (in South Africa and Africa) are often serviced by limited bandwidth network backhauls. Relative to the basic needs of the community, this is an expensive ongoing concern. In many cases the Internet connection is shared among multiple sites. Community networks may also have a lack of technical personnel to maintain a network of this nature. Hence, there is a demand for a system which will monitor and manage bandwidth use, as well as network use. The proposed solution for community networks and the focus within this dissertation, is a system of two parts. A Community Access Point (CAP) is located at each site within the community network. This provides the hosts and servers at that site with access to services on the community network and the Internet, it is the site's router. The CAP provides a web based interface (CAPgui) which allows configuration of the device and viewing of simple monitoring statistics. The Access Concentrator (AC) is the default router for the CAPs and the gateway to the Internet. It provides authenticated and encrypted communication between the network sites. The AC performs several monitoring functions, both for the individual sites and for the upstream Internet connection. The AC provides a means for centrally managing and effectively allocating Internet bandwidth by using the web based interface (ACgui). Bandwidth use can be allocated per user, per host and per site. The system is maintainable, extendable and customisable for different network architectures. The system was deployed successfully to two community networks. The Centre of Excellence (CoE) testbed network is a peri-urban network deployment whereas the Siyakhula Living Lab (SLL) network is a rural deployment. The results gathered conclude that the project was successful as the deployed system is more robust and more manageable than the previous systems.
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Participatory human development in post-apartheid South Africa: a discussion of the 2006/7 Tantyi Youth Empowerment Project
- Authors: Kulundu, Injairu M
- Date: 2010
- Subjects: Spirals Trust (South Africa) Community development -- South Africa -- Citizen participation Economic development projects -- South Africa -- Citizen participation Youth in development -- South Africa Non-governmental organizations -- South Africa Post-apartheid era -- South Africa South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2791 , http://hdl.handle.net/10962/d1003001
- Description: This thesis relates the work of a non-governmental organisation, The Spirals Trust, to discussions on human and participatory development. The focus of the study is one of The Spirals Trust’s projects, the 2006/7 Tantyi Youth Empowerment Project, which is discussed in relation to theoretical material on human development and participatory development. Collectively these perspectives are defined in this thesis as ‘participatory human development’. The 2006/7 Tantyi Youth Empowerment Project illustrates some of the challenges that face the practice of participatory human development. Workshops and focus group interviews were conducted with participants who were part of the 2006/7 Tantyi Youth Empowerment Project in order to draw out their experiences of the project. Questions were created from themes that emerged from the participants’ discussion of their experiences and these questions were then posed to members of staff of The Spirals Trust. The experiences of both the participants and the staff members are discussed in order to explore issues that emerge in the practice of participatory human development in the 2006/7 Tantyi Youth Empowerment Project. The results highlight the challenges of putting into action the tenets of participatory human development. Feedback showed that a focus on personal development can help cultivate the ethic of participation. The effort that this entailed on the part of facilitators is discussed. The importance of exposing and continually working with power dynamics that may emerge in projects of this nature is revealed and the eroding influence of bureaucratic compliance in projects like this one is explored. The study also suggests that there is a need to promote development initiatives that challenge the political status quo rather than just finding ways to incorporate the marginalised more effectively into current systems. New questions that the research poses to the practice of participatory human development are considered in conjunction with suggestions for further research.
- Full Text:
- Authors: Kulundu, Injairu M
- Date: 2010
- Subjects: Spirals Trust (South Africa) Community development -- South Africa -- Citizen participation Economic development projects -- South Africa -- Citizen participation Youth in development -- South Africa Non-governmental organizations -- South Africa Post-apartheid era -- South Africa South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2791 , http://hdl.handle.net/10962/d1003001
- Description: This thesis relates the work of a non-governmental organisation, The Spirals Trust, to discussions on human and participatory development. The focus of the study is one of The Spirals Trust’s projects, the 2006/7 Tantyi Youth Empowerment Project, which is discussed in relation to theoretical material on human development and participatory development. Collectively these perspectives are defined in this thesis as ‘participatory human development’. The 2006/7 Tantyi Youth Empowerment Project illustrates some of the challenges that face the practice of participatory human development. Workshops and focus group interviews were conducted with participants who were part of the 2006/7 Tantyi Youth Empowerment Project in order to draw out their experiences of the project. Questions were created from themes that emerged from the participants’ discussion of their experiences and these questions were then posed to members of staff of The Spirals Trust. The experiences of both the participants and the staff members are discussed in order to explore issues that emerge in the practice of participatory human development in the 2006/7 Tantyi Youth Empowerment Project. The results highlight the challenges of putting into action the tenets of participatory human development. Feedback showed that a focus on personal development can help cultivate the ethic of participation. The effort that this entailed on the part of facilitators is discussed. The importance of exposing and continually working with power dynamics that may emerge in projects of this nature is revealed and the eroding influence of bureaucratic compliance in projects like this one is explored. The study also suggests that there is a need to promote development initiatives that challenge the political status quo rather than just finding ways to incorporate the marginalised more effectively into current systems. New questions that the research poses to the practice of participatory human development are considered in conjunction with suggestions for further research.
- Full Text:
Photophysical and photoelectrochemical properties of water soluble metallophthalocyanines
- Authors: Masilela, Nkosiphile
- Date: 2010
- Subjects: Phthalocyanines , Electrochemistry , Photoelectrochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4330 , http://hdl.handle.net/10962/d1004991 , Phthalocyanines , Electrochemistry , Photoelectrochemistry
- Description: This work presents the synthesis, characterization, photophysicochemical and photoelectrochemical properties of anionic octa-caboxylated (MOCPcs), tetra-sulfonated (MTSPcs) and quaternized cationic (Q(T-2-Py)MPcs) water soluble aluminium, gallium, silicon, titanium and zinc phthalocynines. The peripherally tetra-substituted cationic (Q(T-2-Py)MPcs) and anionic (MTSPcs) were found to be aggregated in aqueous media, yet the octa-carboxylated (MOCPcs) counterparts were monomeric in solution. Cremophor EL (CEL) was used as a disaggregating agent, all the aggregated complexes disaggregated partially or completely in the presence of CEL. The photophysicochemical properties of aggregated complexes were investigated both in the presence of CEL and in aqueous media of pH 11 alone. Low triplet, singlet oxygen and fluorescence quantum yield were obtained in aqueous media (especially for the aggregated complexes) but a high improvement was achieved upon addition of CEL. The gallium complexes ((OH)GaOCPc and (OH)GaTSPc) showed good photophysicochemical properties with higher triplet and singlet oxygen quantum yields. For photoelectrochemistry the (MPcs) dyes were adsorbed to nanoporous ZnO, electrodeposited in the presence of eosin Y as structure directing agent (SDA) on FTO substrates by refluxing or soaking the films in a solution containing the dye of interest such that a full surface coverage was achieved. Quaternized cationic (Q(T-2-Py)MPc) and tetrasulfonated (MTSPcs) phthalocyanines formed strong aggregates when deposited on the surface of FTO/ZnO substrate leading. High external (IPCE) and internal (APCE) quantum efficiencies of up to 50.6% and 96.7% were achieved for the OTiOCPc complex. There was a lower overall cell efficiency for quaternized and tetrasulfonated metallophthalocyanines because of the strong aggregates when they were on the surface of the electrodes. Among the studied materials, OTiOCPc gave the highest overall cell efficiency of phthalocyanine electrodeposited on ZnO of so far = 0.48%.
- Full Text:
- Authors: Masilela, Nkosiphile
- Date: 2010
- Subjects: Phthalocyanines , Electrochemistry , Photoelectrochemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4330 , http://hdl.handle.net/10962/d1004991 , Phthalocyanines , Electrochemistry , Photoelectrochemistry
- Description: This work presents the synthesis, characterization, photophysicochemical and photoelectrochemical properties of anionic octa-caboxylated (MOCPcs), tetra-sulfonated (MTSPcs) and quaternized cationic (Q(T-2-Py)MPcs) water soluble aluminium, gallium, silicon, titanium and zinc phthalocynines. The peripherally tetra-substituted cationic (Q(T-2-Py)MPcs) and anionic (MTSPcs) were found to be aggregated in aqueous media, yet the octa-carboxylated (MOCPcs) counterparts were monomeric in solution. Cremophor EL (CEL) was used as a disaggregating agent, all the aggregated complexes disaggregated partially or completely in the presence of CEL. The photophysicochemical properties of aggregated complexes were investigated both in the presence of CEL and in aqueous media of pH 11 alone. Low triplet, singlet oxygen and fluorescence quantum yield were obtained in aqueous media (especially for the aggregated complexes) but a high improvement was achieved upon addition of CEL. The gallium complexes ((OH)GaOCPc and (OH)GaTSPc) showed good photophysicochemical properties with higher triplet and singlet oxygen quantum yields. For photoelectrochemistry the (MPcs) dyes were adsorbed to nanoporous ZnO, electrodeposited in the presence of eosin Y as structure directing agent (SDA) on FTO substrates by refluxing or soaking the films in a solution containing the dye of interest such that a full surface coverage was achieved. Quaternized cationic (Q(T-2-Py)MPc) and tetrasulfonated (MTSPcs) phthalocyanines formed strong aggregates when deposited on the surface of FTO/ZnO substrate leading. High external (IPCE) and internal (APCE) quantum efficiencies of up to 50.6% and 96.7% were achieved for the OTiOCPc complex. There was a lower overall cell efficiency for quaternized and tetrasulfonated metallophthalocyanines because of the strong aggregates when they were on the surface of the electrodes. Among the studied materials, OTiOCPc gave the highest overall cell efficiency of phthalocyanine electrodeposited on ZnO of so far = 0.48%.
- Full Text:
Photophysical studies of zinc and indium tetraaminophthalocyanines in the presence of CdTe quantum dots
- Authors: Britton, Jonathan
- Date: 2010
- Subjects: Indium , Zinc , Quantum dots , Phthalocyanines , Photochemotherapy , Nonlinear optics , Nanocrystals
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4332 , http://hdl.handle.net/10962/d1004993 , Indium , Zinc , Quantum dots , Phthalocyanines , Photochemotherapy , Nonlinear optics , Nanocrystals
- Description: CdTe QDs capped with mercaptopropionic acid (MPA) and thioglycolic acid (TGA) were covalently linked to zinc and indium tetraaminophthalocyanines (TAPcs) using N-ethyl-N(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxy succinimide (NHS) as the coupling agents. The results presented give evidence in favour of formation of an amide bond between the MTAPc and CdTe QDs. Both the linked ZnTAPc–QD complexes and the mixture of QDs and ZnTAPc (without chemical linking) showed Förster resonance energy transfer (FRET), though the linked showed less FRET, whereas the QD interactions with InTAPc yielded no evidence of FRET. Both MTAPcs quenched the QDs emission, with quenching constants of the order of 103–104M−1, binding constants of the order of 108-1010M-1 and the number of binding sites for the MTAPc upon the QD being 2. High energy transfer efficiencies were obtained (in some cases as high as 93%), due to the low donor to acceptor distances. Lastly, both MTAPc were shown to be poor optical limiters because their imaginary third-order susceptibility (Im[χ(3)]) was of the order of 10-17-10-16 (optimal range is 10-9-10-11), the hyperpolarizability (γ) of the order of 10-37-10-36 (optimal range is 10-29-10-34) and the k values were above one but below ten.
- Full Text:
- Authors: Britton, Jonathan
- Date: 2010
- Subjects: Indium , Zinc , Quantum dots , Phthalocyanines , Photochemotherapy , Nonlinear optics , Nanocrystals
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4332 , http://hdl.handle.net/10962/d1004993 , Indium , Zinc , Quantum dots , Phthalocyanines , Photochemotherapy , Nonlinear optics , Nanocrystals
- Description: CdTe QDs capped with mercaptopropionic acid (MPA) and thioglycolic acid (TGA) were covalently linked to zinc and indium tetraaminophthalocyanines (TAPcs) using N-ethyl-N(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxy succinimide (NHS) as the coupling agents. The results presented give evidence in favour of formation of an amide bond between the MTAPc and CdTe QDs. Both the linked ZnTAPc–QD complexes and the mixture of QDs and ZnTAPc (without chemical linking) showed Förster resonance energy transfer (FRET), though the linked showed less FRET, whereas the QD interactions with InTAPc yielded no evidence of FRET. Both MTAPcs quenched the QDs emission, with quenching constants of the order of 103–104M−1, binding constants of the order of 108-1010M-1 and the number of binding sites for the MTAPc upon the QD being 2. High energy transfer efficiencies were obtained (in some cases as high as 93%), due to the low donor to acceptor distances. Lastly, both MTAPc were shown to be poor optical limiters because their imaginary third-order susceptibility (Im[χ(3)]) was of the order of 10-17-10-16 (optimal range is 10-9-10-11), the hyperpolarizability (γ) of the order of 10-37-10-36 (optimal range is 10-29-10-34) and the k values were above one but below ten.
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Prohibition & resistance: a socio-political exploration of the changing dynamics of the southern African cannabis trade, c. 1850 - the present
- Authors: Paterson, Craig J
- Date: 2010
- Subjects: Cannabis -- Government policy -- Africa, Southern -- History -- 19th century Cannabis -- Government policy -- Africa, Southern -- History -- 20th century Cannabis -- Law and legislation -- Africa, Southern -- History -- 20th century Drugs -- Government policy -- Africa, Southern -- History -- 19th century Drugs -- Government policy -- Africa, Southern -- History -- 20th century Drugs -- Law and legislation -- Africa, Southern -- History -- 19th century Drugs -- Law and legislation -- Africa, Southern -- History -- 20th century Drug traffic -- Africa, Southern -- History -- 19th century Drug traffic -- Africa, Southern -- History -- 20th century Substance abuse -- Social aspects -- Africa, Southern
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2551 , http://hdl.handle.net/10962/d1002403
- Description: Looking primarily at the social and political trends in South Africa over the course of the last century and a half, this thesis explores how these trends have contributed to the establishment of the southern Africa cannabis complex. Through an examination of the influence which the colonial paradigm based on Social Darwinian thinking had on the understanding of the cannabis plant in southern Africa, it is argued that cannabis prohibition and apartheid laws rested on the same ideological foundation. This thesis goes on to argue that the dynamics of cannabis production and trade can be understood in terms of the interplay between the two themes of ‘prohibition’ and ‘resistance’. Prohibition is not only understood to refer to cannabis laws, but also to the proscription of inter-racial contact and segregation dictated by the apartheid regime. Resistance, then, refers to both resistance to apartheid and resistance to cannabis laws in this thesis. Including discussions on the hippie movement and development of the world trade, the anti-apartheid movement, the successful implementation of import substitution strategies in Europe and North America from the 1980’s, and South Africa’s incorporation into the global trade, this thesis illustrates how the apartheid system (and its collapse) influenced the region’s cannabis trade.
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- Authors: Paterson, Craig J
- Date: 2010
- Subjects: Cannabis -- Government policy -- Africa, Southern -- History -- 19th century Cannabis -- Government policy -- Africa, Southern -- History -- 20th century Cannabis -- Law and legislation -- Africa, Southern -- History -- 20th century Drugs -- Government policy -- Africa, Southern -- History -- 19th century Drugs -- Government policy -- Africa, Southern -- History -- 20th century Drugs -- Law and legislation -- Africa, Southern -- History -- 19th century Drugs -- Law and legislation -- Africa, Southern -- History -- 20th century Drug traffic -- Africa, Southern -- History -- 19th century Drug traffic -- Africa, Southern -- History -- 20th century Substance abuse -- Social aspects -- Africa, Southern
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2551 , http://hdl.handle.net/10962/d1002403
- Description: Looking primarily at the social and political trends in South Africa over the course of the last century and a half, this thesis explores how these trends have contributed to the establishment of the southern Africa cannabis complex. Through an examination of the influence which the colonial paradigm based on Social Darwinian thinking had on the understanding of the cannabis plant in southern Africa, it is argued that cannabis prohibition and apartheid laws rested on the same ideological foundation. This thesis goes on to argue that the dynamics of cannabis production and trade can be understood in terms of the interplay between the two themes of ‘prohibition’ and ‘resistance’. Prohibition is not only understood to refer to cannabis laws, but also to the proscription of inter-racial contact and segregation dictated by the apartheid regime. Resistance, then, refers to both resistance to apartheid and resistance to cannabis laws in this thesis. Including discussions on the hippie movement and development of the world trade, the anti-apartheid movement, the successful implementation of import substitution strategies in Europe and North America from the 1980’s, and South Africa’s incorporation into the global trade, this thesis illustrates how the apartheid system (and its collapse) influenced the region’s cannabis trade.
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Revolt as a strategy of de-reification in contemporary performance practice
- Authors: Smit, Sonja
- Date: 2010
- Subjects: Mantero, Vera Bouwer, Jaco, 1973- Performance art -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2147 , http://hdl.handle.net/10962/d1002379
- Description: This thesis investigates the concepts of revolt and de-reification and how these can be perceived and implemented within the context of performance. The argument focuses on the ability of revolt to question and unsettle processes of reification which in turn manifest a strategy of de-reification. I investigate the potential in contemporary performance practice to challenge prevailing modes of perception and restore the production of desire to the spectator through strategies of de-reification. This research is approached through a qualitative process which entails a reading and application of critical texts to the analysis. This reading/application is engaged in a dialogue with the interpretative and experiential aspects of the two works selected for analysis. Chapter One functions as an introduction to the concept of reification and the necessity of a process geared towards de-reification through revolt. I argue that revolt is already embedded in avant-garde artistic practices through an experimental and questioning approach to artistic practice and the production of meaning. Chapter Two is an analysis of Vera Mantero’s solo work, one mysterious Thing said e.e cummings* (1996). This is structured around two identifiable elements, one being the resistance to signification (designification), which is argued as a strategy of revolt within the piece. The second is the notion of abjection, which works doubly to aid the resistance to signification as well as working as a strategy of revolt by its implication in the work. Chapter Three analyses Jaco Bouwer’s Untitled (2008), specifically dealing with the notion of absence as a strategy of revolt and de-reification. The discussion is focused on the potential complication of desire through absence as enacting a larger project of revolt. As in Chapter Two, this is similarly related to the fragmentation of signs through designification which emphasises the strategy of absence. This thesis concludes with the idea that meaning-making in performance can be considered a process. Instead, the lack or failure of meaning within these selected performance practices enables a return to the individual (performer and spectator) as the agent of desire.
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- Authors: Smit, Sonja
- Date: 2010
- Subjects: Mantero, Vera Bouwer, Jaco, 1973- Performance art -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2147 , http://hdl.handle.net/10962/d1002379
- Description: This thesis investigates the concepts of revolt and de-reification and how these can be perceived and implemented within the context of performance. The argument focuses on the ability of revolt to question and unsettle processes of reification which in turn manifest a strategy of de-reification. I investigate the potential in contemporary performance practice to challenge prevailing modes of perception and restore the production of desire to the spectator through strategies of de-reification. This research is approached through a qualitative process which entails a reading and application of critical texts to the analysis. This reading/application is engaged in a dialogue with the interpretative and experiential aspects of the two works selected for analysis. Chapter One functions as an introduction to the concept of reification and the necessity of a process geared towards de-reification through revolt. I argue that revolt is already embedded in avant-garde artistic practices through an experimental and questioning approach to artistic practice and the production of meaning. Chapter Two is an analysis of Vera Mantero’s solo work, one mysterious Thing said e.e cummings* (1996). This is structured around two identifiable elements, one being the resistance to signification (designification), which is argued as a strategy of revolt within the piece. The second is the notion of abjection, which works doubly to aid the resistance to signification as well as working as a strategy of revolt by its implication in the work. Chapter Three analyses Jaco Bouwer’s Untitled (2008), specifically dealing with the notion of absence as a strategy of revolt and de-reification. The discussion is focused on the potential complication of desire through absence as enacting a larger project of revolt. As in Chapter Two, this is similarly related to the fragmentation of signs through designification which emphasises the strategy of absence. This thesis concludes with the idea that meaning-making in performance can be considered a process. Instead, the lack or failure of meaning within these selected performance practices enables a return to the individual (performer and spectator) as the agent of desire.
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Robert Herrick's self-presentation in Hesperides and his Noble numbers
- Authors: Faull, Lionel Peter
- Date: 2010
- Subjects: Herrick, Robert, 1591-1674 Criticism and interpretation Herrick, Robert, 1591-1674. Hesperides Herrick, Robert, 1591-1674. Noble numbers English poetry -- Early modern, 1500-1700 -- History and criticism
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2207 , http://hdl.handle.net/10962/d1002250
- Description: Literature has tended to be cut from the moorings of its authorial origins under the influential literary criticism of the past forty years. This thesis is an attempt to re-moor a work of literature to its authorial origins; particularly a work of literature in which the author-poet‘s self-referential markers are so overtly and persistently present as is the case in Hesperides and His Noble Numbers. Although there is a significant overlap between the real-life Herrick and the Hesperidean Herrick, the two figures cannot be regarded as identical. Instead, Herrick‘s deployment of specific genres and not of others, his chosen conventions for ordering a collection of miscellaneous poems, and his adoption of certain conventional poetic stances provide him with a semi-fictionalised way of declaring who he understands himself to be and how he wants himself to be understood. At the same time, the rich classical mythological associations of Herrick‘s title, Hesperides, declare his status as an inheritor of the classical literary tradition, whose hallmark during the Renaissance was the melding of classical, Christian and secular associations into new and complexly polyvalent literary works. For example, Herrick‘s appropriation of the classical mythological figure of Hercules provides him with both a narrative way and an allegorical way of reconciling the so-called secular, or profane poetry of Hesperides with the so-called religious, or divine poetry of Noble Numbers. In Noble Numbers, Herrick reveals new facets of his self-presentation to the reader, whilst also making explicit the theological congruencies between the two works. Herrick‘s religious self-presentation demonstrates his expansive scholarly interests, as well his instinct to include, rather than to exclude, the religious beliefs of others within his syncretistic sense-of-self. Finally, the placement of Noble Numbers after Hesperides is not a signal that Herrick privileged the former, or took his religion less seriously than he did his love for classical poetry, but rather that in Herrick‘s understanding of his world, man‘s fleeting glimpses of God in the secular sphere give way to a fuller comprehension of Him in the divine sphere.
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- Authors: Faull, Lionel Peter
- Date: 2010
- Subjects: Herrick, Robert, 1591-1674 Criticism and interpretation Herrick, Robert, 1591-1674. Hesperides Herrick, Robert, 1591-1674. Noble numbers English poetry -- Early modern, 1500-1700 -- History and criticism
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2207 , http://hdl.handle.net/10962/d1002250
- Description: Literature has tended to be cut from the moorings of its authorial origins under the influential literary criticism of the past forty years. This thesis is an attempt to re-moor a work of literature to its authorial origins; particularly a work of literature in which the author-poet‘s self-referential markers are so overtly and persistently present as is the case in Hesperides and His Noble Numbers. Although there is a significant overlap between the real-life Herrick and the Hesperidean Herrick, the two figures cannot be regarded as identical. Instead, Herrick‘s deployment of specific genres and not of others, his chosen conventions for ordering a collection of miscellaneous poems, and his adoption of certain conventional poetic stances provide him with a semi-fictionalised way of declaring who he understands himself to be and how he wants himself to be understood. At the same time, the rich classical mythological associations of Herrick‘s title, Hesperides, declare his status as an inheritor of the classical literary tradition, whose hallmark during the Renaissance was the melding of classical, Christian and secular associations into new and complexly polyvalent literary works. For example, Herrick‘s appropriation of the classical mythological figure of Hercules provides him with both a narrative way and an allegorical way of reconciling the so-called secular, or profane poetry of Hesperides with the so-called religious, or divine poetry of Noble Numbers. In Noble Numbers, Herrick reveals new facets of his self-presentation to the reader, whilst also making explicit the theological congruencies between the two works. Herrick‘s religious self-presentation demonstrates his expansive scholarly interests, as well his instinct to include, rather than to exclude, the religious beliefs of others within his syncretistic sense-of-self. Finally, the placement of Noble Numbers after Hesperides is not a signal that Herrick privileged the former, or took his religion less seriously than he did his love for classical poetry, but rather that in Herrick‘s understanding of his world, man‘s fleeting glimpses of God in the secular sphere give way to a fuller comprehension of Him in the divine sphere.
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Rural livelihoods and food security in the aftermath of the fast track land reform in Zimbabwe
- Authors: Jowah, Eddah Vimbai
- Date: 2010
- Subjects: Land reform -- Zimbabwe Food security -- Zimbabwe Sustainable development -- Zimbabwe Right of property -- Zimbabwe Zimbabwe -- Economic conditions Rural development -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3302 , http://hdl.handle.net/10962/d1003090
- Description: Land reforms are back on the development agenda. Different types of land reforms have been adopted globally in recent years, but by far the most controversial and most radical has been the fast track land reform pursued by the Government of Zimbabwe from 2000. There is general scholarly agreement that the fast track process has been accompanied by various socio-economic and political challenges, including an increase in levels of food insecurity. This thesis examines fast track reform in specific relation to the livelihoods of smallholder households and household food security amongst land beneficiaries. It argues that the problem of food insecurity in Zimbabwe is a complex social, political and economic issue, which cannot be simplistically reduced to the failures of fast track. Understanding household food insecurity post-2000 needs to go beyond the notion that the nation‟s food security hinges on overall levels of production alone. In particular, livelihoods and food security need to be conceptualised at community and household levels. Therefore, while addressing the broad macro-level analysis and discourse around the process of fast track, the study also adopts a micro-level analysis to look at the varied impact of fast track on the actual beneficiaries. The research focuses on small-scale beneficiaries in the Goromonzi District of Zimbabwe and, through the use of the sustainable livelihoods framework, looks at how their local contexts have been influenced by the wider socio-economic and political processes, and how beneficiaries have sought ways of coping with the challenges they face.
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- Authors: Jowah, Eddah Vimbai
- Date: 2010
- Subjects: Land reform -- Zimbabwe Food security -- Zimbabwe Sustainable development -- Zimbabwe Right of property -- Zimbabwe Zimbabwe -- Economic conditions Rural development -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3302 , http://hdl.handle.net/10962/d1003090
- Description: Land reforms are back on the development agenda. Different types of land reforms have been adopted globally in recent years, but by far the most controversial and most radical has been the fast track land reform pursued by the Government of Zimbabwe from 2000. There is general scholarly agreement that the fast track process has been accompanied by various socio-economic and political challenges, including an increase in levels of food insecurity. This thesis examines fast track reform in specific relation to the livelihoods of smallholder households and household food security amongst land beneficiaries. It argues that the problem of food insecurity in Zimbabwe is a complex social, political and economic issue, which cannot be simplistically reduced to the failures of fast track. Understanding household food insecurity post-2000 needs to go beyond the notion that the nation‟s food security hinges on overall levels of production alone. In particular, livelihoods and food security need to be conceptualised at community and household levels. Therefore, while addressing the broad macro-level analysis and discourse around the process of fast track, the study also adopts a micro-level analysis to look at the varied impact of fast track on the actual beneficiaries. The research focuses on small-scale beneficiaries in the Goromonzi District of Zimbabwe and, through the use of the sustainable livelihoods framework, looks at how their local contexts have been influenced by the wider socio-economic and political processes, and how beneficiaries have sought ways of coping with the challenges they face.
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Sexy sports: a reception study of the National Broadcasting Corporation (NBC) Olympics website coverage of women's beach volleyball at the 2008 Beijing Olympics
- Authors: Tajdin, Wafa Mohamed
- Date: 2010
- Subjects: Olympics National Broadcasting Company Sports journalism Mass media and sports Volleyball for women Beach volleyball Feminism and mass media Cyberfeminism Sexism in mass media Women athletes Sports for women Sex role in mass media Women in mass media
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3486 , http://hdl.handle.net/10962/d1002941
- Description: Sexy Sports: A reception study of the National Broadcasting Corporation (NBC) Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics involves an examination of the sporting media and its reportage of the female athlete. The thesis will focus on the reception of the NBC Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics by viewing groups constituted by the researcher. The reason for this is that it would be difficult to find naturally constituted audiences for this website, but its reception is never-the-less of research interest. My hypothesis is that the nature of the images and text on the website is overdetermined by the construction of women on other popular texts such as men’s magazines etc. In focusing on the meanings obtained from the content of the website (texts and images), the study will investigate how these meanings are naturalised in specific moments of production as well as through their intertextual relationships with similar texts involved in the glamorisation of female athletes. Specifically the study explores the meanings obtained from the content of the website (texts and images) and how in turn these meanings are naturalised by the consumers of the website. The study will utilise a qualitative research design to unpack the content of the website through the use of qualitative content analysis, focus group interviews and individual in-depth interviews. The research will be informed via a theoretical framework that draws from feminist theory, sport feminism, the concept of intertextuality between media texts, ideology and Stuart Hall’s model of preferred reading. Increasingly mainstream media uses the image of a woman’s body to sell almost anything from men’s razors to margarine and in so far as the reporting of women’s sports is concerned this holds true. Through the research I intend to account for the connotative power of other texts i.e. the men’s magazines and pornography, and how this is likely to be carried through into shaping the meanings that are read off the website. Arguably the production of the NBC texts and images are overdetermined by the existence of similar texts already in transmission in the circuit of culture.
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- Authors: Tajdin, Wafa Mohamed
- Date: 2010
- Subjects: Olympics National Broadcasting Company Sports journalism Mass media and sports Volleyball for women Beach volleyball Feminism and mass media Cyberfeminism Sexism in mass media Women athletes Sports for women Sex role in mass media Women in mass media
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3486 , http://hdl.handle.net/10962/d1002941
- Description: Sexy Sports: A reception study of the National Broadcasting Corporation (NBC) Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics involves an examination of the sporting media and its reportage of the female athlete. The thesis will focus on the reception of the NBC Olympics website coverage of women’s beach volleyball at the 2008 Beijing Olympics by viewing groups constituted by the researcher. The reason for this is that it would be difficult to find naturally constituted audiences for this website, but its reception is never-the-less of research interest. My hypothesis is that the nature of the images and text on the website is overdetermined by the construction of women on other popular texts such as men’s magazines etc. In focusing on the meanings obtained from the content of the website (texts and images), the study will investigate how these meanings are naturalised in specific moments of production as well as through their intertextual relationships with similar texts involved in the glamorisation of female athletes. Specifically the study explores the meanings obtained from the content of the website (texts and images) and how in turn these meanings are naturalised by the consumers of the website. The study will utilise a qualitative research design to unpack the content of the website through the use of qualitative content analysis, focus group interviews and individual in-depth interviews. The research will be informed via a theoretical framework that draws from feminist theory, sport feminism, the concept of intertextuality between media texts, ideology and Stuart Hall’s model of preferred reading. Increasingly mainstream media uses the image of a woman’s body to sell almost anything from men’s razors to margarine and in so far as the reporting of women’s sports is concerned this holds true. Through the research I intend to account for the connotative power of other texts i.e. the men’s magazines and pornography, and how this is likely to be carried through into shaping the meanings that are read off the website. Arguably the production of the NBC texts and images are overdetermined by the existence of similar texts already in transmission in the circuit of culture.
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Social relationships and identity online and offline: a study of the interplay between offline social relationships and facebook usage by Rhodes University students from socially disadvantaged backgrounds
- Authors: Chatora, Arther Tichaona
- Date: 2010
- Subjects: Facebook (Electronic resource) Online social networks Information technology -- Social aspects Identity (Psychology) and mass media Rhodes University -- Students -- Social life and customs Rhodes University -- Students -- Social networks Rhodes University -- Students -- Social conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3421 , http://hdl.handle.net/10962/d1002874
- Description: Based on in-depth focus group and individual interviews, this thesis examines how Rhodes University students from socially disadvantaged backgrounds experience campus social life and how they subsequently use Facebook to perform, represent and negotiate their social identities. The study discusses utopian and dystopian positions and interrogates these theoretical perspectives in relation to the students‟ Facebook usage. The popularity and uptake of Facebook by students from disadvantaged backgrounds, such as those here at Rhodes University, is a growing phenomenon, provoking questions about the relationship between social experiences, social identity and social networks. Rhodes University‟s social space has been identified by previous studies as modern, liberal, “elite” and divided along race and class lines. The ways in which students experience this campus social space relates to their subject positions and identities. The study employs different perspectives of identity construction to interrogate the students‟ subject experiences in home and school contexts before coming to Rhodes University. The students‟ subjective positions are primarily embedded in tradition and their subject positions are sometimes in tension or come in conflict with the modern and liberal elements permitted by the Rhodes University context. The students also experience and adopt modern and liberal elements in their lifestyles which are permitted within the Rhodes University social space. The thesis found that Facebook offers a platform which facilitates a social connectivity that influences how students perform their identities in relation to their offline social identities and lived social experiences. This study concludes that the mediated symbolic materials for the construction and negotiation of identity provided by Facebook are sometimes in tension with the demands of traditional subjectivities experienced by these students at Rhodes University. Facebook allows the students to reinforce and affirm the validity of their traditional identities in this modern and liberal space. However, it also emerged that Facebook facilitates and allows students who experience and incorporate the modern and liberal elements permitted at Rhodes University to represent and negotiate their subjective positions online. The findings of the study indicate that participants primarily communicate with their friends, families, relatives and acquaintances - people they know personally offline, in line with the theoretical position which argues that online relationships are primarily shaped by offline relationships.
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- Authors: Chatora, Arther Tichaona
- Date: 2010
- Subjects: Facebook (Electronic resource) Online social networks Information technology -- Social aspects Identity (Psychology) and mass media Rhodes University -- Students -- Social life and customs Rhodes University -- Students -- Social networks Rhodes University -- Students -- Social conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3421 , http://hdl.handle.net/10962/d1002874
- Description: Based on in-depth focus group and individual interviews, this thesis examines how Rhodes University students from socially disadvantaged backgrounds experience campus social life and how they subsequently use Facebook to perform, represent and negotiate their social identities. The study discusses utopian and dystopian positions and interrogates these theoretical perspectives in relation to the students‟ Facebook usage. The popularity and uptake of Facebook by students from disadvantaged backgrounds, such as those here at Rhodes University, is a growing phenomenon, provoking questions about the relationship between social experiences, social identity and social networks. Rhodes University‟s social space has been identified by previous studies as modern, liberal, “elite” and divided along race and class lines. The ways in which students experience this campus social space relates to their subject positions and identities. The study employs different perspectives of identity construction to interrogate the students‟ subject experiences in home and school contexts before coming to Rhodes University. The students‟ subjective positions are primarily embedded in tradition and their subject positions are sometimes in tension or come in conflict with the modern and liberal elements permitted by the Rhodes University context. The students also experience and adopt modern and liberal elements in their lifestyles which are permitted within the Rhodes University social space. The thesis found that Facebook offers a platform which facilitates a social connectivity that influences how students perform their identities in relation to their offline social identities and lived social experiences. This study concludes that the mediated symbolic materials for the construction and negotiation of identity provided by Facebook are sometimes in tension with the demands of traditional subjectivities experienced by these students at Rhodes University. Facebook allows the students to reinforce and affirm the validity of their traditional identities in this modern and liberal space. However, it also emerged that Facebook facilitates and allows students who experience and incorporate the modern and liberal elements permitted at Rhodes University to represent and negotiate their subjective positions online. The findings of the study indicate that participants primarily communicate with their friends, families, relatives and acquaintances - people they know personally offline, in line with the theoretical position which argues that online relationships are primarily shaped by offline relationships.
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Spatial and temporal patterns in the hyperbenthic community structure in a permanently open Eastern Cape estuary, South Africa
- Authors: Heyns, Elodie R
- Date: 2010
- Subjects: Sundays Estuary -- South Africa -- Eastern Cape , Groundfishes -- South Africa -- Eatern Cape , Estuaries -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5768 , http://hdl.handle.net/10962/d1005456
- Description: The spatial and temporal (seasonal and diel) patterns in the hyperbenthic community structure (>500 μm) was investigated in the warm temperate, permanently open Kariega Estuary situated along the south-eastern coastline of South Africa. Spatial and seasonal patterns in the hyperbenthic community structure were assessed monthly at six stations along the length of the estuary over a period of twelve months. Data were collected using a modified hyperbenthic sledge, comprising two super-imposed nets. Physico-chemical data indicate the presence of a constant reverse salinity gradient, with highest salinities measured in the upper reaches and lowest at the mouth of the estuary. Strong seasonal patterns in temperature, dissolved oxygen and total chlorophyll-a (chl-a) concentrations were evident. Total average hyperbenthic densities ranged between 0.04 and 166 ind.m-3 in the lower net and between 0.12 and 225 ind.m-3 in the upper net. Hyperbenthic biomass values ranged between 0.02 and 11.9 mg.dry weight.m-3 in the lower net and between 0.02 and 17.4 mg.dry weight.m-3 in the upper net. A spatial and temporal pattern in total densities was detected with an increase in abundance over the period of September to October 2008 particularly in the middle reaches (Stations 3 and 4). Both the lower and upper nets were numerically dominated by decapods (mainly brachyuran crab zoeae) with the exception of June and July 2008 when mysids (mainly Mesopodopsis wooldridgei) dominated, making up 72.4 ± 58.14% of the total abundance in the lower net. A redundancy analysis (RDA) indicated that 99.2% of the variance in the hyperbenthic community structure could be explained by the first two canonical axes. Axis one, which accounted for 96.8% of the total variation detected in the ordination plot was highly correlated with sedimentary organic content and to a lesser extent the chl-a concentration within the Kariega Estuary. The correlations with the second canonical axis (2.4%) were less obvious, however, salinity and seston concentration were weakly correlated with this axis. Diel variability in the hyperbenthic community structure was assessed during March 2009. Samples were collected during the day and night (n = 6 for each period) using sampling gear described above. Total average hyperbenthic densities during the day (497.9 ± 254.1 ind.m-3) were significantly higher than night-time estimates (129.9 ± 38.5 ind.m-3; p<0.05). There were no significant differences in the average dayand night-time estimates of hyperbenthic biomass (p>0.05). A hierarchical cluster analysis identified two significantly distinct groupings, designated the day and night samples. Results from the SIMPER procedure indicated that the high densities of crab zoeae recorded during the day-time accounted for the majority of the dissimilarity between the day and night groupings (44.7%). In addition, it is apparent that several benthic species, especially from the cumacean and isopod orders, were absent from the hyperbenthos during the day-time and emerged into the water column at night.
- Full Text:
- Authors: Heyns, Elodie R
- Date: 2010
- Subjects: Sundays Estuary -- South Africa -- Eastern Cape , Groundfishes -- South Africa -- Eatern Cape , Estuaries -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5768 , http://hdl.handle.net/10962/d1005456
- Description: The spatial and temporal (seasonal and diel) patterns in the hyperbenthic community structure (>500 μm) was investigated in the warm temperate, permanently open Kariega Estuary situated along the south-eastern coastline of South Africa. Spatial and seasonal patterns in the hyperbenthic community structure were assessed monthly at six stations along the length of the estuary over a period of twelve months. Data were collected using a modified hyperbenthic sledge, comprising two super-imposed nets. Physico-chemical data indicate the presence of a constant reverse salinity gradient, with highest salinities measured in the upper reaches and lowest at the mouth of the estuary. Strong seasonal patterns in temperature, dissolved oxygen and total chlorophyll-a (chl-a) concentrations were evident. Total average hyperbenthic densities ranged between 0.04 and 166 ind.m-3 in the lower net and between 0.12 and 225 ind.m-3 in the upper net. Hyperbenthic biomass values ranged between 0.02 and 11.9 mg.dry weight.m-3 in the lower net and between 0.02 and 17.4 mg.dry weight.m-3 in the upper net. A spatial and temporal pattern in total densities was detected with an increase in abundance over the period of September to October 2008 particularly in the middle reaches (Stations 3 and 4). Both the lower and upper nets were numerically dominated by decapods (mainly brachyuran crab zoeae) with the exception of June and July 2008 when mysids (mainly Mesopodopsis wooldridgei) dominated, making up 72.4 ± 58.14% of the total abundance in the lower net. A redundancy analysis (RDA) indicated that 99.2% of the variance in the hyperbenthic community structure could be explained by the first two canonical axes. Axis one, which accounted for 96.8% of the total variation detected in the ordination plot was highly correlated with sedimentary organic content and to a lesser extent the chl-a concentration within the Kariega Estuary. The correlations with the second canonical axis (2.4%) were less obvious, however, salinity and seston concentration were weakly correlated with this axis. Diel variability in the hyperbenthic community structure was assessed during March 2009. Samples were collected during the day and night (n = 6 for each period) using sampling gear described above. Total average hyperbenthic densities during the day (497.9 ± 254.1 ind.m-3) were significantly higher than night-time estimates (129.9 ± 38.5 ind.m-3; p<0.05). There were no significant differences in the average dayand night-time estimates of hyperbenthic biomass (p>0.05). A hierarchical cluster analysis identified two significantly distinct groupings, designated the day and night samples. Results from the SIMPER procedure indicated that the high densities of crab zoeae recorded during the day-time accounted for the majority of the dissimilarity between the day and night groupings (44.7%). In addition, it is apparent that several benthic species, especially from the cumacean and isopod orders, were absent from the hyperbenthos during the day-time and emerged into the water column at night.
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Spatio-temporal dynamics of ichthyoplankton in the Kowie estuary, South Africa
- Authors: Kruger, Michelle
- Date: 2010
- Subjects: Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5319 , http://hdl.handle.net/10962/d1005164 , Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Description: Ichthyoplankton dynamics in the permanently open Kowie Estuary, in the warm temperate region of South Africa was investigated. The composition, abundance, distribution and seasonality of larval fishes were studied over a two year period between 2004 and 2006. Additionally, tidal exchange of ichthyoplankton and the use of frontal zones in the mouth region of the estuary were also explored between 2008 and 2009. Temporal and spatial trends in occurrence of larval fishes within the estuary and associated marina were obtained from data collected seasonally using boat-based plankton netting at 14 sampling stations along the length of the estuary. A total of 11 128 larval fishes were collected, representing 23 families and 38 taxa. Clupeidae and Gobiidae were the dominant fish families, contributing 47.0 % and 24.7 % respectively to the total catch. Estuarine resident species dominated the overall catch (91 %). A notable absence of older stage larvae and early juveniles characterised the artificial channels of the marina and estuary mouth region. This was attributed to the absence of a shallow, marginal water habitat typical of successful estuarine nursery areas. Tidal exchange of larval fishes was investigated in the Kowie Estuary using a new technique. A set of drifting light traps were set repetitively on the ebb and flood tide every second night for two consecutive 14 day periods during the peak estuarine recruitment period. A total of 553 larval fishes were caught during the study, representing nine families and 26 species. Blenniidae and Clupeidae dominated the catches. Family and species occurrence changed with tide state. Species richness (d) and diversity (H’) varied with tide and was highest on flood tides. Estuary-dependent species, such as Omobranchus woodii were more dominant on flood tides, whilst larvae of marine-spawned species, such as Sardinops sagax, were dominant on the ebb tide. Light trap catches yielded a different composition in terms of development stage / size and species, when compared to towed net studies. Towed plankton nets were again used to study the shear fronts that characterise the mouth region of the canalised Kowie Estuary. It was hypothesised that the convergence zone of the front provides feeding opportunities for ichthyoplankton. Ichthyoplankton, zooplankton and phytoplankton was collected from within and immediately outside of the convergence zone during frontal conditions. Species specific distribution trends emerged from this study. Postflexion larvae and early juvenile stages of the estuary dependent Mugilidae were only present in the foam line of the convergence zones. Some known predators of ichthyoplankton were also present in slightly higher numbers in the convergence zone (isopods) while other predators such as mysid shrimps, chaetognaths and cnidarians were more abundant out of the convergence zone. It appears that these zones may provide access to temporary food patches in the lower estuary but will be accompanied by a trade-off with increased isopod predators. The Kowie Estuary is a heavily impacted system and lack of adequate freshwater supply; artificial channelling and pollution ultimately have a negative impact of the success of this system as a nursery area. Rehabilitation of marginal areas in the lower estuary and marina is suggested as remedial action to re-establish the integrity of the nursery function this system could offer.
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- Authors: Kruger, Michelle
- Date: 2010
- Subjects: Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5319 , http://hdl.handle.net/10962/d1005164 , Fishes -- Larvae -- South Africa -- Port Alfred , Estuarine fishes -- South Africa -- Port Alfred
- Description: Ichthyoplankton dynamics in the permanently open Kowie Estuary, in the warm temperate region of South Africa was investigated. The composition, abundance, distribution and seasonality of larval fishes were studied over a two year period between 2004 and 2006. Additionally, tidal exchange of ichthyoplankton and the use of frontal zones in the mouth region of the estuary were also explored between 2008 and 2009. Temporal and spatial trends in occurrence of larval fishes within the estuary and associated marina were obtained from data collected seasonally using boat-based plankton netting at 14 sampling stations along the length of the estuary. A total of 11 128 larval fishes were collected, representing 23 families and 38 taxa. Clupeidae and Gobiidae were the dominant fish families, contributing 47.0 % and 24.7 % respectively to the total catch. Estuarine resident species dominated the overall catch (91 %). A notable absence of older stage larvae and early juveniles characterised the artificial channels of the marina and estuary mouth region. This was attributed to the absence of a shallow, marginal water habitat typical of successful estuarine nursery areas. Tidal exchange of larval fishes was investigated in the Kowie Estuary using a new technique. A set of drifting light traps were set repetitively on the ebb and flood tide every second night for two consecutive 14 day periods during the peak estuarine recruitment period. A total of 553 larval fishes were caught during the study, representing nine families and 26 species. Blenniidae and Clupeidae dominated the catches. Family and species occurrence changed with tide state. Species richness (d) and diversity (H’) varied with tide and was highest on flood tides. Estuary-dependent species, such as Omobranchus woodii were more dominant on flood tides, whilst larvae of marine-spawned species, such as Sardinops sagax, were dominant on the ebb tide. Light trap catches yielded a different composition in terms of development stage / size and species, when compared to towed net studies. Towed plankton nets were again used to study the shear fronts that characterise the mouth region of the canalised Kowie Estuary. It was hypothesised that the convergence zone of the front provides feeding opportunities for ichthyoplankton. Ichthyoplankton, zooplankton and phytoplankton was collected from within and immediately outside of the convergence zone during frontal conditions. Species specific distribution trends emerged from this study. Postflexion larvae and early juvenile stages of the estuary dependent Mugilidae were only present in the foam line of the convergence zones. Some known predators of ichthyoplankton were also present in slightly higher numbers in the convergence zone (isopods) while other predators such as mysid shrimps, chaetognaths and cnidarians were more abundant out of the convergence zone. It appears that these zones may provide access to temporary food patches in the lower estuary but will be accompanied by a trade-off with increased isopod predators. The Kowie Estuary is a heavily impacted system and lack of adequate freshwater supply; artificial channelling and pollution ultimately have a negative impact of the success of this system as a nursery area. Rehabilitation of marginal areas in the lower estuary and marina is suggested as remedial action to re-establish the integrity of the nursery function this system could offer.
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Structure and functioning of fish assemblages in two South African estuaries, with emphasis on the presence and absence of aquatic macrophyte beds
- Authors: Sheppard, Jill Nicole
- Date: 2010
- Subjects: Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5321 , http://hdl.handle.net/10962/d1005166 , Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Description: Temporarily open/closed estuaries (TOCEs) are the dominant estuary type in South Africa. These systems are often characterized by extensive beds of submerged macrophytes, which form important foraging and shelter habitats for fishes, especially for estuary-dependent fish species such as the Cape stumpnose Rhabdosargus holubi and Cape moony Monodactylus falciformis that are commonly associated with them. A loss of submerged macrophytes from an estuary has been shown to affect the fish community as well as reducing overall system productivity. The TOC East Kleinemonde Estuary, situated in the warm-temperate biogeographic region of South Africa has been subject to an ongoing long-term fish monitoring project since 1995. During the period 1995 to 2002, this estuary contained large beds of the submerged macrophytes Ruppia cirrhosa and Potamogeton pectinatus. However, subsequent to a major flood event in 2003 these macrophytes have been largely absent from this system. The effect of the loss of submerged macrophytes on the East Kleinemonde fish assemblage was investigated through an analysis of seine and gill net catch data. Seine net catches for a 12 year period, encompassing six years of macrophyte presence and six years of macrophyte senescence, revealed changes in the relative abundance of certain fish species. Vegetation-associated species such as R. holubi and M. falciformis decreased in abundance whereas sediment-associated species, especially members of the family Mugilidae, increased in abundance following loss of the macrophytes in this estuary. The critically endangered pipefish Syngnathus watermeyeri was only recorded in catches during years in which macrophyte beds were present. In addition to the analysis of catch data, the importance of macrophytes as a primary energy source for selected estuarine fishes was explored through the analysis of carbon and nitrogen stable isotopes. Prior to conducting these analyses, common methodological practices to address the presence of carbonates and lipids within isotope samples were evaluated. A subset of samples were either acid washed to remove carbonates, or lipids were removed according to the method of Bligh and Dyer (1959) as both of these compounds have been shown to affect stable carbon and nitrogen isotope ratios. The suitability of the lipid normalization models of Fry (2002) and Post et al. (2007) for samples of estuarine fish muscle were also tested. Based on this evaluation both models are suitable for use with estuarine fish muscle tissue, however since neither carbonate nor lipid content of any of the samples used in this study was high all samples were left untreated in the following analysis. Carbon isotope ratios from a wide range of fish species collected from the East Kleinemonde Estuary during the macrophyte-senescent phase were compared with individuals of the same species from the neighbouring West Kleinemonde Estuary (where extensive beds of R. cirrhosa and P. pectinatus were present) and revealed the influence of submerged macrophyte material in the diet of fishes in the latter system. However, it was apparent that these plants are not directly consumed but rather contribute to the detrital pool that forms a food source for most invertebrate and some fish species. The most significant source of carbon for East Kleinemonde fishes during the macrophyte senescent phase appeared to have a more depleted origin; probably from benthic or pelagic microalgae. In conclusion, while the importance of macrophyte beds as shelter and foraging habitats for estuarine fishes are well documented, their role in terms of the structuring and functioning of fish assemblages in TOCEs remains somewhat uncertain. The findings of this study were possibly masked by the resilience of vegetation-associated species to the loss of this habitat, as well as by life history characteristics of species such as R. holubi that allow their numerical dominance despite habitat change. Nonetheless, macrophyte senescence in the East Kleinemonde Estuary resulted in the loss of at least one species and the reduced abundance of vegetation-associated species, probably reflective of reduced food resources and/or increased vulnerability to predation. As a result, beds of submerged macrophytes are an important habitat within TOCEs.
- Full Text:
- Authors: Sheppard, Jill Nicole
- Date: 2010
- Subjects: Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5321 , http://hdl.handle.net/10962/d1005166 , Estuaries -- South Africa -- Eastern Cape , Estuarine ecology -- South Africa -- Eastern Cape
- Description: Temporarily open/closed estuaries (TOCEs) are the dominant estuary type in South Africa. These systems are often characterized by extensive beds of submerged macrophytes, which form important foraging and shelter habitats for fishes, especially for estuary-dependent fish species such as the Cape stumpnose Rhabdosargus holubi and Cape moony Monodactylus falciformis that are commonly associated with them. A loss of submerged macrophytes from an estuary has been shown to affect the fish community as well as reducing overall system productivity. The TOC East Kleinemonde Estuary, situated in the warm-temperate biogeographic region of South Africa has been subject to an ongoing long-term fish monitoring project since 1995. During the period 1995 to 2002, this estuary contained large beds of the submerged macrophytes Ruppia cirrhosa and Potamogeton pectinatus. However, subsequent to a major flood event in 2003 these macrophytes have been largely absent from this system. The effect of the loss of submerged macrophytes on the East Kleinemonde fish assemblage was investigated through an analysis of seine and gill net catch data. Seine net catches for a 12 year period, encompassing six years of macrophyte presence and six years of macrophyte senescence, revealed changes in the relative abundance of certain fish species. Vegetation-associated species such as R. holubi and M. falciformis decreased in abundance whereas sediment-associated species, especially members of the family Mugilidae, increased in abundance following loss of the macrophytes in this estuary. The critically endangered pipefish Syngnathus watermeyeri was only recorded in catches during years in which macrophyte beds were present. In addition to the analysis of catch data, the importance of macrophytes as a primary energy source for selected estuarine fishes was explored through the analysis of carbon and nitrogen stable isotopes. Prior to conducting these analyses, common methodological practices to address the presence of carbonates and lipids within isotope samples were evaluated. A subset of samples were either acid washed to remove carbonates, or lipids were removed according to the method of Bligh and Dyer (1959) as both of these compounds have been shown to affect stable carbon and nitrogen isotope ratios. The suitability of the lipid normalization models of Fry (2002) and Post et al. (2007) for samples of estuarine fish muscle were also tested. Based on this evaluation both models are suitable for use with estuarine fish muscle tissue, however since neither carbonate nor lipid content of any of the samples used in this study was high all samples were left untreated in the following analysis. Carbon isotope ratios from a wide range of fish species collected from the East Kleinemonde Estuary during the macrophyte-senescent phase were compared with individuals of the same species from the neighbouring West Kleinemonde Estuary (where extensive beds of R. cirrhosa and P. pectinatus were present) and revealed the influence of submerged macrophyte material in the diet of fishes in the latter system. However, it was apparent that these plants are not directly consumed but rather contribute to the detrital pool that forms a food source for most invertebrate and some fish species. The most significant source of carbon for East Kleinemonde fishes during the macrophyte senescent phase appeared to have a more depleted origin; probably from benthic or pelagic microalgae. In conclusion, while the importance of macrophyte beds as shelter and foraging habitats for estuarine fishes are well documented, their role in terms of the structuring and functioning of fish assemblages in TOCEs remains somewhat uncertain. The findings of this study were possibly masked by the resilience of vegetation-associated species to the loss of this habitat, as well as by life history characteristics of species such as R. holubi that allow their numerical dominance despite habitat change. Nonetheless, macrophyte senescence in the East Kleinemonde Estuary resulted in the loss of at least one species and the reduced abundance of vegetation-associated species, probably reflective of reduced food resources and/or increased vulnerability to predation. As a result, beds of submerged macrophytes are an important habitat within TOCEs.
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Studies towards the development of novel HIV-1 integrase inhibitors
- Authors: Lee, Yi-Chen
- Date: 2010
- Subjects: HIV infections -- Treatment , HIV (Viruses) , AIDS (Disease) -- Treatment , Nuclear magnetic resonance , Heterocyclic compounds -- Derivatives , Enzyme inhibitors , Chemical inhibitors , Quinoline
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4357 , http://hdl.handle.net/10962/d1005022 , HIV infections -- Treatment , HIV (Viruses) , AIDS (Disease) -- Treatment , Nuclear magnetic resonance , Heterocyclic compounds -- Derivatives , Enzyme inhibitors , Chemical inhibitors , Quinoline
- Description: The project has focused on the preparation of several series of compounds designed as potential HIV-1 integrase inhibitors. Various 2-nitrobenzaldehydes have been reacted with two activated alkenes, methyl vinyl ketone (MVK) and methyl acrylate, under Baylis-Hillman conditions to afford α-methylene-β-hydroxylalkyl derivatives in moderate to excellent yields. The reactions were conducted using the tertiary amine catalysts, 1,4-diazabicyclo[2.2.2]octane(DABCO) or 3-hydroxyquinuclidine (3-HQ) with chloroform as solvent, and yields were optimised by varying the catalyst, reagent concentrations and the reaction time. Reductive cyclization of the Baylis-Hillman adducts via catalytic hydrogenation, using 10% palladiumon-carbon catalyst in ethanol, afforded quinoline and quinoline N-oxide derivatives. In some cases “acyclic” reduction products were also isolated. Reaction of the Baylis-Hillman MVK adducts with HCl, has resulted in effective nucleophilic (SN’) displacement of the hydroxyl group to afford allylic chloride derivatives. Direct substitution of these chloro derivatives by secondary or primary amines, followed by catalytic hydrogenation gave quinoline derivatives containing a 3-aminomethyl substituent. The Baylis-Hillman ester adducts obtained from reaction with methyl acrylate were treated directly with various amines to give diastereomeric conjugate addition products. Reactions with piperazine gave N,N’-disubstituted piperazine products. The piperidine derivatives have been dehydrated to give cinnamate esters in moderate yields. The products, which have all been satisfactorily characterised by elemental (HRMS) and spectroscopic (1- and 2-D NMR) analysis, constitute a “library” of compounds for in silico and in vitro studies as potential HIV integrase inhibitors.
- Full Text:
- Authors: Lee, Yi-Chen
- Date: 2010
- Subjects: HIV infections -- Treatment , HIV (Viruses) , AIDS (Disease) -- Treatment , Nuclear magnetic resonance , Heterocyclic compounds -- Derivatives , Enzyme inhibitors , Chemical inhibitors , Quinoline
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4357 , http://hdl.handle.net/10962/d1005022 , HIV infections -- Treatment , HIV (Viruses) , AIDS (Disease) -- Treatment , Nuclear magnetic resonance , Heterocyclic compounds -- Derivatives , Enzyme inhibitors , Chemical inhibitors , Quinoline
- Description: The project has focused on the preparation of several series of compounds designed as potential HIV-1 integrase inhibitors. Various 2-nitrobenzaldehydes have been reacted with two activated alkenes, methyl vinyl ketone (MVK) and methyl acrylate, under Baylis-Hillman conditions to afford α-methylene-β-hydroxylalkyl derivatives in moderate to excellent yields. The reactions were conducted using the tertiary amine catalysts, 1,4-diazabicyclo[2.2.2]octane(DABCO) or 3-hydroxyquinuclidine (3-HQ) with chloroform as solvent, and yields were optimised by varying the catalyst, reagent concentrations and the reaction time. Reductive cyclization of the Baylis-Hillman adducts via catalytic hydrogenation, using 10% palladiumon-carbon catalyst in ethanol, afforded quinoline and quinoline N-oxide derivatives. In some cases “acyclic” reduction products were also isolated. Reaction of the Baylis-Hillman MVK adducts with HCl, has resulted in effective nucleophilic (SN’) displacement of the hydroxyl group to afford allylic chloride derivatives. Direct substitution of these chloro derivatives by secondary or primary amines, followed by catalytic hydrogenation gave quinoline derivatives containing a 3-aminomethyl substituent. The Baylis-Hillman ester adducts obtained from reaction with methyl acrylate were treated directly with various amines to give diastereomeric conjugate addition products. Reactions with piperazine gave N,N’-disubstituted piperazine products. The piperidine derivatives have been dehydrated to give cinnamate esters in moderate yields. The products, which have all been satisfactorily characterised by elemental (HRMS) and spectroscopic (1- and 2-D NMR) analysis, constitute a “library” of compounds for in silico and in vitro studies as potential HIV integrase inhibitors.
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Take my word for it: a new approach to the problem of sincerity in the epistemology of testimony
- Authors: Dewhurst, Therese
- Date: 2010
- Subjects: Sincerity Philosophy Terminology Knowledge, Theory of Honesty
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2707 , http://hdl.handle.net/10962/d1002837
- Description: The epistemological problem of sincerity in testimony is often approached in the following way: We, as a matter of fact, accept utterances as sincere. We do so in the face of knowledge that people lie and deceive,and yet we still count these beliefs as good beliefs. Therefore there must be some reason or argument that we can cite in order to justify our acceptance of the sincerity of the speaker. In this thesis I will argue, contra this, that there is no reason, per se, that justifies our of a speakers sincerity: this is because recognition of the obligation to accept the sincerity is a necessary condition on the possibility of communication and interpretation. In the first three of the thesis I will argue against three of the main approaches to the problem by focusing on what I believe to be the strongest accounts of each: Elizabeth Fricker's reductionism, Tyler Burge's non-reductionism, and Paul Faulkner's trust account of testimony. In the final chapter I will put forward my positive account. I will argue that it is a constitutive rule of language that a speaker be sincere, and then make the further claim, that it is a constitutive rule of interpretation that the hearer take an utterance as sincere. On my account, successful communication does not just depend on a speaker making sincere utterances,but just as importantly,, on the hearer recognising an obligation to take those utterances as being sincere.
- Full Text:
- Authors: Dewhurst, Therese
- Date: 2010
- Subjects: Sincerity Philosophy Terminology Knowledge, Theory of Honesty
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2707 , http://hdl.handle.net/10962/d1002837
- Description: The epistemological problem of sincerity in testimony is often approached in the following way: We, as a matter of fact, accept utterances as sincere. We do so in the face of knowledge that people lie and deceive,and yet we still count these beliefs as good beliefs. Therefore there must be some reason or argument that we can cite in order to justify our acceptance of the sincerity of the speaker. In this thesis I will argue, contra this, that there is no reason, per se, that justifies our of a speakers sincerity: this is because recognition of the obligation to accept the sincerity is a necessary condition on the possibility of communication and interpretation. In the first three of the thesis I will argue against three of the main approaches to the problem by focusing on what I believe to be the strongest accounts of each: Elizabeth Fricker's reductionism, Tyler Burge's non-reductionism, and Paul Faulkner's trust account of testimony. In the final chapter I will put forward my positive account. I will argue that it is a constitutive rule of language that a speaker be sincere, and then make the further claim, that it is a constitutive rule of interpretation that the hearer take an utterance as sincere. On my account, successful communication does not just depend on a speaker making sincere utterances,but just as importantly,, on the hearer recognising an obligation to take those utterances as being sincere.
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The advent of the 'Festivore' an exploration of South African audience attendance in the performing arts at the National Arts Festival
- Authors: Antrobus, Richard Roy
- Date: 2010
- Subjects: Standard Bank National Arts Festival -- Economic aspects , Arts -- Economic aspects , Performing arts festivals -- Economic aspects -- South Africa -- Grahamstown , Arts -- South Africa -- Economic aspects , Arts -- South Africa -- Finance , Arts -- South Africa -- Political aspects , Arts audiences -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2130 , http://hdl.handle.net/10962/d1002362
- Description: In South Africa, the performing arts have contributed to enhancing national identity and distinctiveness despite coming up against weak legislation, policy and infrastructure to support their growth and proliferation (Fredericks, 2005: 9). Coupled with a decline in both government and consumer support and the contradictory disparity between valuing the arts and the funding of the arts, theatre companies can no longer rely on the comfort of external subsidies and financial support. In order to be economically viable and sustainable to ensure their survival, there is an increasing demand for theatre companies to look to novel ways of increasing audience demand for theatre and improving audience attendance. However, instead of risking artistic integrity and the performance product to satisfy the market, this research suggests that promotion and development of theatre at arts festivals provides a platform to access a wider theatre-going public, which therefore facilitates a change in the market focus toward appreciation of the product (production). It explores leading arguments pertaining to the attendance of arts and cultural events, namely, Peterson and Simkus (1992), later updated by Peterson‟s (2005)„omnivore-univore‟ argument. The argument purports cultural consumption as binary in nature: either significant and diverse or limited, if not absent altogether. Supported by a number of case-studies, including Chan and Goldthorpe (2005) and Montgomery and Robinson (2008) and Snowball et al. (2009), the investigation challenges Bourdieu‟s (1984) theory on cultural distinction as well as the homology and individualisation argument. In determining the factors that influence cultural taste and consumer behaviour, including motivators and inhibitors of attendance and a predominant emphasis on audience risk and information asymmetry, the research was placed in a local context, providing an overview of the socio-economic theatre environment in South Africa. It investigated the nature, structure and impact of local festivals (as events) in changing audience demand and theatre attendance. With specific reference to the South African National Arts Festival (NAF) the research notes the effects of Hauptfleisch‟s „eventification‟ phenomenon on univore attenders and therefore expands the omnivore-univore theory to include a new breed of attender: the “Festivore”. A case study explored the “Festivore” hypothesis through empirical research, surveys and face-to-face qualitative interviews and on-seat questionnaire responses by festival attenders. Personal interviews and communication was also carried out with leading experts in the field. The data was then analysed using SPSS 13 electronic statistical analysis programme to determine the socio-demographics and the factors that affect theatre attendance of existing, as well as potential target, theatre audiences at the National Arts Festival The study concluded that South African theatre attenders are generally omnivorous consumers and that, more importantly, there seems to be a shift towards „festivorous‟ consumption. Furthermore, evidence supports the development and proliferation of festivals as a means not only to support and promote the arts in South Africa but, more importantly, to generate new theatre audiences and entrench theatre attendance into South African culture.
- Full Text:
- Authors: Antrobus, Richard Roy
- Date: 2010
- Subjects: Standard Bank National Arts Festival -- Economic aspects , Arts -- Economic aspects , Performing arts festivals -- Economic aspects -- South Africa -- Grahamstown , Arts -- South Africa -- Economic aspects , Arts -- South Africa -- Finance , Arts -- South Africa -- Political aspects , Arts audiences -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2130 , http://hdl.handle.net/10962/d1002362
- Description: In South Africa, the performing arts have contributed to enhancing national identity and distinctiveness despite coming up against weak legislation, policy and infrastructure to support their growth and proliferation (Fredericks, 2005: 9). Coupled with a decline in both government and consumer support and the contradictory disparity between valuing the arts and the funding of the arts, theatre companies can no longer rely on the comfort of external subsidies and financial support. In order to be economically viable and sustainable to ensure their survival, there is an increasing demand for theatre companies to look to novel ways of increasing audience demand for theatre and improving audience attendance. However, instead of risking artistic integrity and the performance product to satisfy the market, this research suggests that promotion and development of theatre at arts festivals provides a platform to access a wider theatre-going public, which therefore facilitates a change in the market focus toward appreciation of the product (production). It explores leading arguments pertaining to the attendance of arts and cultural events, namely, Peterson and Simkus (1992), later updated by Peterson‟s (2005)„omnivore-univore‟ argument. The argument purports cultural consumption as binary in nature: either significant and diverse or limited, if not absent altogether. Supported by a number of case-studies, including Chan and Goldthorpe (2005) and Montgomery and Robinson (2008) and Snowball et al. (2009), the investigation challenges Bourdieu‟s (1984) theory on cultural distinction as well as the homology and individualisation argument. In determining the factors that influence cultural taste and consumer behaviour, including motivators and inhibitors of attendance and a predominant emphasis on audience risk and information asymmetry, the research was placed in a local context, providing an overview of the socio-economic theatre environment in South Africa. It investigated the nature, structure and impact of local festivals (as events) in changing audience demand and theatre attendance. With specific reference to the South African National Arts Festival (NAF) the research notes the effects of Hauptfleisch‟s „eventification‟ phenomenon on univore attenders and therefore expands the omnivore-univore theory to include a new breed of attender: the “Festivore”. A case study explored the “Festivore” hypothesis through empirical research, surveys and face-to-face qualitative interviews and on-seat questionnaire responses by festival attenders. Personal interviews and communication was also carried out with leading experts in the field. The data was then analysed using SPSS 13 electronic statistical analysis programme to determine the socio-demographics and the factors that affect theatre attendance of existing, as well as potential target, theatre audiences at the National Arts Festival The study concluded that South African theatre attenders are generally omnivorous consumers and that, more importantly, there seems to be a shift towards „festivorous‟ consumption. Furthermore, evidence supports the development and proliferation of festivals as a means not only to support and promote the arts in South Africa but, more importantly, to generate new theatre audiences and entrench theatre attendance into South African culture.
- Full Text: