Large scale spatio-temporal forcing of pelagic-coastal coupling: disentangling the effects of environmental change on intertidal invertebrate recruitment
- Authors: Muñiz, Carlota Fernández
- Date: 2019
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/75317 , vital:30400
- Description: Marine systems are driven by the relationships among organisms and environmental conditions. Anthropogenic-induced changes during the past decades have started to alter climatic drivers which have the potential to alter the physical, chemical and biological environment. In coastal systems, biogeography is influenced by the temporal variability in the conditions of the water mass. In addition, many marine benthic organisms develop in the water mass and rely on the conditions that link the pelagic and benthic systems for population maintenance. Such pelagic-coastal coupling indicates that changes in the trophic system during development can be transferred to the adult populations through changes in propagule supply. Thus, changes in environmental conditions can influence benthic populations directly (e.g. through larval advection) or indirectly, through their influence on the phytoplankton community (e.g. through the development of HABs). The South African coastline shows clear alongshore patterns of faunal biomass and species richness. On the south coast, strong longitudinal patterns of recruitment of intertidal organisms exist, with areas of particularly high recruitment. HABs of unprecedented spatio-temporal magnitude have recently developed along the south coast, including the areas where benthic recruitment is most intense. The present thesis used these blooms to study changes in intertidal recruitment directly or indirectly associated with their occurrence. Using a combination of remote sensing data to study the environmental conditions of the water mass in the innermost part of the Agulhas Bank, and estimates of mussel and barnacle recruitment rates to integrate the effects of conditions in the water mass during larval development, this thesis aimed to: (1) understand the conditions that triggered the development of an HAB of the dinoflagellate Lingulodinium polyedrum during summer of 2014, (2) determine the direct or indirect effects of that bloom on recruitment of intertidal organisms, and understand the factors that affect recruitment along the coast, (3) determine if the environmental factors during bloom development produced any carryover effects on recruit growth and mortality, and (4) determine the factors that drive changes in community biomass and composition along the south coast, the long-term trends in those factors, and possible changes experienced in recent years. Water column stability during spring, before the development of the red tide, followed by alternating periods of upwelling and relaxation during summer and autumn, seemed to promote the development and persistence of L. polyedrum. Recruitment of mussels and barnacles was estimated during the reproductive season of mussels in 2014, coinciding with the red tide, and during the following year. Alongshore patterns in recruitment were found, with higher mussel recruitment in the absence of the red tide and the opposite pattern in barnacles. Alongshore patterns in SST and chlorophyll matching those of recruitment were also found, with higher SSTs and lower chlorophyll during the red tide than the following year. Growth and mortality rates in barnacles did not differ between years during the first five months after settlement. This suggests that the factors which produced differences in recruitment between years did not produce carryover effects detectable at the temporal scales studied. Further analysis of 15 years of satellite-derived environmental data showed significant cooling trends potentially driven by a long-term seasonal acceleration of the Agulhas Current in autumn around two upwelling centres on the south coast, coinciding temporally with the reproductive period of mussels and barnacles, and spatially with the areas of highest recruitment. In addition, the comparison of SST and chl-a conditions during the first and the second half of the period of study showed that seasonality of both variables has changed in large areas over the shelf, with increasing importance of shorter-term variability, which would in turn decrease environmental predictability. Thus, the conditions observed during the present study, particularly during 2015, when upwelling seemed to be more intense, may presage the potential effects of identified long-term cooling trends at the upwelling centres. Although the general trend shows cooling around those areas, conditions can vary greatly among years, favouring different taxa. Changes in the Agulhas Current System are affected by changes in distant areas in the Indian Ocean basin. Such tele-connection is unlikely to be unique to this system and indicates the importance of understanding trends in major large scale climatic drivers and their regional effects in order to make predictions about coastal systems.
- Full Text:
- Date Issued: 2019
- Authors: Muñiz, Carlota Fernández
- Date: 2019
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/75317 , vital:30400
- Description: Marine systems are driven by the relationships among organisms and environmental conditions. Anthropogenic-induced changes during the past decades have started to alter climatic drivers which have the potential to alter the physical, chemical and biological environment. In coastal systems, biogeography is influenced by the temporal variability in the conditions of the water mass. In addition, many marine benthic organisms develop in the water mass and rely on the conditions that link the pelagic and benthic systems for population maintenance. Such pelagic-coastal coupling indicates that changes in the trophic system during development can be transferred to the adult populations through changes in propagule supply. Thus, changes in environmental conditions can influence benthic populations directly (e.g. through larval advection) or indirectly, through their influence on the phytoplankton community (e.g. through the development of HABs). The South African coastline shows clear alongshore patterns of faunal biomass and species richness. On the south coast, strong longitudinal patterns of recruitment of intertidal organisms exist, with areas of particularly high recruitment. HABs of unprecedented spatio-temporal magnitude have recently developed along the south coast, including the areas where benthic recruitment is most intense. The present thesis used these blooms to study changes in intertidal recruitment directly or indirectly associated with their occurrence. Using a combination of remote sensing data to study the environmental conditions of the water mass in the innermost part of the Agulhas Bank, and estimates of mussel and barnacle recruitment rates to integrate the effects of conditions in the water mass during larval development, this thesis aimed to: (1) understand the conditions that triggered the development of an HAB of the dinoflagellate Lingulodinium polyedrum during summer of 2014, (2) determine the direct or indirect effects of that bloom on recruitment of intertidal organisms, and understand the factors that affect recruitment along the coast, (3) determine if the environmental factors during bloom development produced any carryover effects on recruit growth and mortality, and (4) determine the factors that drive changes in community biomass and composition along the south coast, the long-term trends in those factors, and possible changes experienced in recent years. Water column stability during spring, before the development of the red tide, followed by alternating periods of upwelling and relaxation during summer and autumn, seemed to promote the development and persistence of L. polyedrum. Recruitment of mussels and barnacles was estimated during the reproductive season of mussels in 2014, coinciding with the red tide, and during the following year. Alongshore patterns in recruitment were found, with higher mussel recruitment in the absence of the red tide and the opposite pattern in barnacles. Alongshore patterns in SST and chlorophyll matching those of recruitment were also found, with higher SSTs and lower chlorophyll during the red tide than the following year. Growth and mortality rates in barnacles did not differ between years during the first five months after settlement. This suggests that the factors which produced differences in recruitment between years did not produce carryover effects detectable at the temporal scales studied. Further analysis of 15 years of satellite-derived environmental data showed significant cooling trends potentially driven by a long-term seasonal acceleration of the Agulhas Current in autumn around two upwelling centres on the south coast, coinciding temporally with the reproductive period of mussels and barnacles, and spatially with the areas of highest recruitment. In addition, the comparison of SST and chl-a conditions during the first and the second half of the period of study showed that seasonality of both variables has changed in large areas over the shelf, with increasing importance of shorter-term variability, which would in turn decrease environmental predictability. Thus, the conditions observed during the present study, particularly during 2015, when upwelling seemed to be more intense, may presage the potential effects of identified long-term cooling trends at the upwelling centres. Although the general trend shows cooling around those areas, conditions can vary greatly among years, favouring different taxa. Changes in the Agulhas Current System are affected by changes in distant areas in the Indian Ocean basin. Such tele-connection is unlikely to be unique to this system and indicates the importance of understanding trends in major large scale climatic drivers and their regional effects in order to make predictions about coastal systems.
- Full Text:
- Date Issued: 2019
Large scale spatio-temporal forcing of pelagic-coastal coupling: disentangling the effects of environmental change on intertidal invertebrate recruitment
- Authors: Muñiz, Carlota Fernández
- Date: 2019
- Subjects: Dinoflagellates -- South Africa , Coastal ecology -- South Africa , Climatic changes -- South Africa , Benthic ecology -- South Africa , Agulhas Current , Ocean temperature -- Agulhas Current , Ocean temperature -- Physiological effect
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/151541 , vital:39140
- Description: Marine systems are driven by the relationships among organisms and environmental conditions. Anthropogenic-induced changes during the past decades have started to alter climatic drivers which have the potential to alter the physical, chemical and biological environment. In coastal systems, biogeography is influenced by the temporal variability in the conditions of the water mass. In addition, many marine benthic organisms develop in the water mass and rely on the conditions that link the pelagic and benthic systems for population maintenance. Such pelagic-coastal coupling indicates that changes in the trophic system during development can be transferred to the adult populations through changes in propagule supply. Thus, changes in environmental conditions can influence benthic populations directly (e.g. through larval advection) or indirectly, through their influence on the phytoplankton community (e.g. through the development of HABs). The South African coastline shows clear alongshore patterns of faunal biomass and species richness. On the south coast, strong longitudinal patterns of recruitment of intertidal organisms exist, with areas of particularly high recruitment. HABs of unprecedented spatio-temporal magnitude have recently developed along the south coast, including the areas where benthic recruitment is most intense. The present thesis used these blooms to study changes in intertidal recruitment directly or indirectly associated with their occurrence. Using a combination of remote sensing data to study the environmental conditions of the water mass in the innermost part of the Agulhas Bank, and estimates of mussel and barnacle recruitment rates to integrate the effects of conditions in the water mass during larval development, this thesis aimed to: (1) understand the conditions that triggered the development of an HAB of the dinoflagellate Lingulodinium polyedrum during summer of 2014, (2) determine the direct or indirect effects of that bloom on recruitment of intertidal organisms, and understand the factors that affect recruitment along the coast, (3) determine if the environmental factors during bloom development produced any carryover effects on recruit growth and mortality, and (4) determine the factors that drive changes in community biomass and composition along the south coast, the long-term trends in those factors, and possible changes experienced in recent years. Water column stability during spring, before the development of the red tide, followed by alternating periods of upwelling and relaxation during summer and autumn, seemed to promote the development and persistence of L. polyedrum. Recruitment of mussels and barnacles was estimated during the reproductive season of mussels in 2014, coinciding with the red tide, and during the following year. Alongshore patterns in recruitment were found, with higher mussel recruitment in the absence of the red tide and the opposite pattern in barnacles. Alongshore patterns in SST and chlorophyll matching those of recruitment were also found, with higher SSTs and lower chlorophyll during the red tide than the following year. Growth and mortality rates in barnacles did not differ between years during the first five months after settlement. This suggests that the factors which produced differences in recruitment between years did not produce carryover effects detectable at the temporal scales studied. Further analysis of 15 years of satellite-derived environmental data showed significant cooling trends potentially driven by a long-term seasonal acceleration of the Agulhas Current in autumn around two upwelling centres on the south coast, coinciding temporally with the reproductive period of mussels and barnacles, and spatially with the areas of highest recruitment. In addition, the comparison of SST and chl-a conditions during the first and the second half of the period of study showed that seasonality of both variables has changed in large areas over the shelf, with increasing importance of shorter-term variability, which would in turn decrease environmental predictability. Thus, the conditions observed during the present study, particularly during 2015, when upwelling seemed to be more intense, may presage the potential effects of identified long-term cooling trends at the upwelling centres. Although the general trend shows cooling around those areas, conditions can vary greatly among years, favouring different taxa. Changes in the Agulhas Current System are affected by changes in distant areas in the Indian Ocean basin. Such tele-connection is unlikely to be unique to this system and indicates the importance of understanding trends in major large scale climatic drivers and their regional effects in order to make predictions about coastal systems.
- Full Text:
- Date Issued: 2019
- Authors: Muñiz, Carlota Fernández
- Date: 2019
- Subjects: Dinoflagellates -- South Africa , Coastal ecology -- South Africa , Climatic changes -- South Africa , Benthic ecology -- South Africa , Agulhas Current , Ocean temperature -- Agulhas Current , Ocean temperature -- Physiological effect
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/151541 , vital:39140
- Description: Marine systems are driven by the relationships among organisms and environmental conditions. Anthropogenic-induced changes during the past decades have started to alter climatic drivers which have the potential to alter the physical, chemical and biological environment. In coastal systems, biogeography is influenced by the temporal variability in the conditions of the water mass. In addition, many marine benthic organisms develop in the water mass and rely on the conditions that link the pelagic and benthic systems for population maintenance. Such pelagic-coastal coupling indicates that changes in the trophic system during development can be transferred to the adult populations through changes in propagule supply. Thus, changes in environmental conditions can influence benthic populations directly (e.g. through larval advection) or indirectly, through their influence on the phytoplankton community (e.g. through the development of HABs). The South African coastline shows clear alongshore patterns of faunal biomass and species richness. On the south coast, strong longitudinal patterns of recruitment of intertidal organisms exist, with areas of particularly high recruitment. HABs of unprecedented spatio-temporal magnitude have recently developed along the south coast, including the areas where benthic recruitment is most intense. The present thesis used these blooms to study changes in intertidal recruitment directly or indirectly associated with their occurrence. Using a combination of remote sensing data to study the environmental conditions of the water mass in the innermost part of the Agulhas Bank, and estimates of mussel and barnacle recruitment rates to integrate the effects of conditions in the water mass during larval development, this thesis aimed to: (1) understand the conditions that triggered the development of an HAB of the dinoflagellate Lingulodinium polyedrum during summer of 2014, (2) determine the direct or indirect effects of that bloom on recruitment of intertidal organisms, and understand the factors that affect recruitment along the coast, (3) determine if the environmental factors during bloom development produced any carryover effects on recruit growth and mortality, and (4) determine the factors that drive changes in community biomass and composition along the south coast, the long-term trends in those factors, and possible changes experienced in recent years. Water column stability during spring, before the development of the red tide, followed by alternating periods of upwelling and relaxation during summer and autumn, seemed to promote the development and persistence of L. polyedrum. Recruitment of mussels and barnacles was estimated during the reproductive season of mussels in 2014, coinciding with the red tide, and during the following year. Alongshore patterns in recruitment were found, with higher mussel recruitment in the absence of the red tide and the opposite pattern in barnacles. Alongshore patterns in SST and chlorophyll matching those of recruitment were also found, with higher SSTs and lower chlorophyll during the red tide than the following year. Growth and mortality rates in barnacles did not differ between years during the first five months after settlement. This suggests that the factors which produced differences in recruitment between years did not produce carryover effects detectable at the temporal scales studied. Further analysis of 15 years of satellite-derived environmental data showed significant cooling trends potentially driven by a long-term seasonal acceleration of the Agulhas Current in autumn around two upwelling centres on the south coast, coinciding temporally with the reproductive period of mussels and barnacles, and spatially with the areas of highest recruitment. In addition, the comparison of SST and chl-a conditions during the first and the second half of the period of study showed that seasonality of both variables has changed in large areas over the shelf, with increasing importance of shorter-term variability, which would in turn decrease environmental predictability. Thus, the conditions observed during the present study, particularly during 2015, when upwelling seemed to be more intense, may presage the potential effects of identified long-term cooling trends at the upwelling centres. Although the general trend shows cooling around those areas, conditions can vary greatly among years, favouring different taxa. Changes in the Agulhas Current System are affected by changes in distant areas in the Indian Ocean basin. Such tele-connection is unlikely to be unique to this system and indicates the importance of understanding trends in major large scale climatic drivers and their regional effects in order to make predictions about coastal systems.
- Full Text:
- Date Issued: 2019
Learning to learn: a critical realist exploration into the home established learning practices of a marginalised community in Port Elizabeth
- Authors: Armstrong, Meredith
- Date: 2019
- Subjects: Minorities -- Education (Higher) -- South Africa , Readiness for school -- Social aspects -- South Africa , Inclusive education -- Social aspects -- South Africa , Marginality, Social -- South Africa , Critical realism
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/93778 , vital:30939
- Description: This study was completed as part of a project exploring social inclusion and exclusion in South African higher education. In a globalised world, the achievement of a qualification from an institution of higher education is increasingly key to finding any sort of employment. This is particularly the case in South Africa where employment amongst black citizens is inordinately high. The aim of the research reported upon in this thesis was to better understand the construct of ‘epistemological access’ (Morrow, 1992), often used in relation to the needs of black working class students entering higher education, in relation to performance data (see for example, CHE, 2016) that repeatedly shows that black students fare less well than their white peers. Following what might be termed a ‘social’ approach to understanding access, this study begins long before most students have even heard of higher education and focuses on identifying the mechanisms that come into play at much earlier level of learning and literacy development. The study outlines the development of ‘ways of being’, or social practices, surrounding learning in a marginalised community in Port Elizabeth, in the Eastern Cape, South Africa. This was achieved by means of critical ethnography and it is therefore qualitatively based. The study shows how social structures enable or constrain a child’s school readiness and how they then go on to support or impede progress in school where the language and literacy needed for educational success are further developed. The study therefore aims to allow us to explain global data indicating that the single greatest indicator of a young person’s ability to access and succeed in higher education is the level of education of caregivers in their homes of origin. Examined from a critical perspective (i.e. with a concern for social justice), this study has made use of a framework using social, psychological and linguistic theory and more, particularly, the work of sociologist Margaret Archer (1995, 1996, 2003). The study makes particular use of Archer’s ‘morphogenetic framework’ which allows for an analysis of the way structure and culture impact on a child’s development over time. As I was concerned that my own social status might impact on the understandings I developed as a critical ethnographer, the study acknowledges my own experiences of learning and the way my own family sought to enhance them as enabling. In doing this, the study aims to better contribute to understandings of social justice in South Africa.
- Full Text:
- Date Issued: 2019
- Authors: Armstrong, Meredith
- Date: 2019
- Subjects: Minorities -- Education (Higher) -- South Africa , Readiness for school -- Social aspects -- South Africa , Inclusive education -- Social aspects -- South Africa , Marginality, Social -- South Africa , Critical realism
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/93778 , vital:30939
- Description: This study was completed as part of a project exploring social inclusion and exclusion in South African higher education. In a globalised world, the achievement of a qualification from an institution of higher education is increasingly key to finding any sort of employment. This is particularly the case in South Africa where employment amongst black citizens is inordinately high. The aim of the research reported upon in this thesis was to better understand the construct of ‘epistemological access’ (Morrow, 1992), often used in relation to the needs of black working class students entering higher education, in relation to performance data (see for example, CHE, 2016) that repeatedly shows that black students fare less well than their white peers. Following what might be termed a ‘social’ approach to understanding access, this study begins long before most students have even heard of higher education and focuses on identifying the mechanisms that come into play at much earlier level of learning and literacy development. The study outlines the development of ‘ways of being’, or social practices, surrounding learning in a marginalised community in Port Elizabeth, in the Eastern Cape, South Africa. This was achieved by means of critical ethnography and it is therefore qualitatively based. The study shows how social structures enable or constrain a child’s school readiness and how they then go on to support or impede progress in school where the language and literacy needed for educational success are further developed. The study therefore aims to allow us to explain global data indicating that the single greatest indicator of a young person’s ability to access and succeed in higher education is the level of education of caregivers in their homes of origin. Examined from a critical perspective (i.e. with a concern for social justice), this study has made use of a framework using social, psychological and linguistic theory and more, particularly, the work of sociologist Margaret Archer (1995, 1996, 2003). The study makes particular use of Archer’s ‘morphogenetic framework’ which allows for an analysis of the way structure and culture impact on a child’s development over time. As I was concerned that my own social status might impact on the understandings I developed as a critical ethnographer, the study acknowledges my own experiences of learning and the way my own family sought to enhance them as enabling. In doing this, the study aims to better contribute to understandings of social justice in South Africa.
- Full Text:
- Date Issued: 2019
Livestock water productivity: towards improving rural livelihoods from livestock in semi-arid rangelands
- Authors: Gusha, Bukho
- Date: 2019
- Subjects: Livestock -- South Africa -- Eastern Cape , Livestock -- Effect of drought on -- South Africa -- Eastern Cape , Animals -- Food -- South Africa -- Eastern Cape , Livestock -- Effect of water quality on -- South Africa -- Eastern Cape , Livestock -- Water requirements -- South Africa -- Eastern Cape , Livestock productivity -- South Africa -- Eastern Cape , Stochastic analysis , Communal rangelands -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape , Animal owners -- South Africa -- Eastern Cape , Livestock improvement -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/115171 , vital:34084
- Description: Communal rangelands in South Africa mainly occur in the former homelands. The former homelands constitute 13% of the land surface area and support a quarter of the country's human population with a wide range of goods and services, among them, grazing for livestock, mostly reared on communal rangelands. These rangelands are degraded and cannot sustain maximum livestock production because of poor species composition and low standing biomass, however research has been conducted on livestock production at household level (where all livestock goods and services are valued). This provides an opportunity to conduct a study describing livestock water productivity in the north of the Eastern Cape, where livestock production is a primary source of livelihood for rural communities from which many households generate cash but where different practices and factors undermine high livestock production. Many studies have focused on understanding the water productivity of a natural rangeland system for commercially oriented crop-livestock systems, but the aim of this study is to contribute towards improving rural livelihoods from livestock in the sub-humid rangelands of the north Eastern Cape. Here, unimproved native grasslands are the major source of feed for livestock and people do not have herders to take livestock to the most productive parts of the rangelands. Households were surveyed using a questionnaire on livestock household contribution, socioeconomic characteristics of the household, livestock holdings and livestock production strategies. Rangeland productivity was measured in the field. Experimental animals for livestock grazing distribution were identified and fitted with Global Positioning Systems (GPS) collars to identify the seasonal grazing areas. These activities shed light on the biophysical attributes of the ecosystem and livestock production in a communal rangeland system. Because continuous grazing in the rangelands of the north Eastern Cape reduces the standing biomass, there is no obvious aboveground biomass to provide a visual perspective of production nor is it possible to determine production without excluding the livestock. Thus, four parallel lines of evidence were employed to measure rangeland productivity: line intercept, grazing exclosures, net photosynthesis from earth observation and disc pasture meter. Earth observation products were used to derive the amount of water used by the landscape to produce this forage (i.e. evapotranspiration or ET) and these measurements of net primary production and landscape water use were used in preparing a value of livestock water productivity (LWP) for this farming system. There has been the perception that residents of the study area lack knowledge of technical efficiencies in the large stock sector at household level. The study used stochastic frontier analysis to assess livestock production and followed with a household survey to collect information on socio-economic characteristics and information on livestock practices. The data from the household survey were used to estimate the technical efficiency of households using a stochastic frontier analysis. Productivity and inefficiency variables that increase livestock production or increase technical difficulties were identified. The focus on livestock has mostly been on the direct value of livestock to owners with a poor understanding of their value to non-livestock owners, where cultural activities, such as livestock slaughtering, were documented as the only source of protein for non-livestock owners. However, the value that is available to non-livestock owners has not been quantified. This study assessed livestockbased livelihoods of communal people to improve their livelihoods through a household survey looking at the contribution of livestock to both livestock and non-livestock owners. Earlier work on LWP has focused on systems where animals were on ‘fed, cut and carry’ and irrigated systems. However, there is a need to describe LWP in a natural grazing system and this study set out to achieve this for these communal rangelands through a household survey that determined the value of livestock goods and services given the amount of water used (ET). Lastly, livestock grazing distribution across the landscape was assessed, using GPS collars that recorded livestock behaviour every five minutes during the daylight. This approach was necessary because livestock grazing patterns in these communal rangelands is poorly controlled by people, and animals are largely free-ranging, grazing selectively, based on their own preferences, which leads to localised overgrazing. This part of the study was achieved through experimental livestock collaring and weighing (both sheep and goats) for the wet and dry seasons. The collared livestock were weighed on the day of putting on collars and the day of removing the collars. The results on livestock grazing distribution were analysed using the R package, T-LoCoH. The major finding of this study was that communal rangelands of the north Eastern Cape can improve rural livelihoods from livestock if proper interventions for both livestock and rangeland production and productivity can be implemented. One of these interventions is fencing as it was found that exclosures that were fenced during the study yielded high aboveground productivity comparable to that achieved in commercial rangelands, yielding 220 g DM m-2 yr-1. Surveys using the calibrated disc pasture meter showed the need for proper rotation and resting of the rangeland. Net photosynthesis of 880.7 g C m-2 yr-1 for unimproved grassland in good condition was comparable to commercial rangelands in the region. Using the line intercept, vegetation cover was found to be a good predictor of aboveground standing biomass; thus a positive relationship was revealed. Lastly, annual ET of 270 mm yr-1 was calculated using the Penman Monteith Palmer (PMP) equation, while 379 mm yr-1 was extracted from the MOD16 product, suggesting that PMP ET may not be accurate in these grassland systems due to the slow response of MODIS Leaf Area Index (LAI). The average household technical efficiency (TE) score was found to be 0.79 on the study sites, indicating the potential for households to improve outputs from livestock. A range of household categories were identified, based on gender and an index of wealth, and households with lower and higher TE were identified. This analysis revealed that productivity variables such as holding higher livestock numbers and providing additional feed achieved high livestock outputs, suggesting high livestock productivity. However, in terms of inefficiency variables, gender (female-headed households), dwelling type (an index of homestead wealth), kraaling livestock at night and herding livestock during the day were found to improve technical efficiency. It was revealed in this study that households keep livestock to derive different goods and services including offtake, manure, milk, wool and services such as traction. The non-livestock owning households were reported to also benefit from the abovementioned goods and services in the study site and that the value of their contribution could be quantified, thus contributing significantly to rural livelihoods. The study showed that LWP was comparable with other studies such as those conducted in Ethiopia. This study compared its results with the studies conducted outside South Africa as there were limited comparable South African studies available; however, this does not necessarily mean we can use the same model as the value of livestock outputs varies based on the preferred outputs. This study developed an LWP model for the natural rangeland system. The LWP values were measured in ZAR and later converted in USD and were divided into three different categories based on the wealth index, such as better-off, middle wealth and poor households. Lastly, this study showed that livestock (both cattle and sheep) spend a high proportion of their grazing day, during both the wet and dry seasons, in a small physical area, immediately around the homesteads. These are areas where the active green growth occurs throughout the year, suggesting the need for livestock herders to move livestock around the landscape for more effective landscape use. Herding has the potential to improve landscape use and conserve grazing resource and the ability of a household to attain best outputs from livestock. Positive daily weight gains were reported in collared livestock during the wet season. However, both sheep and cattle lost weight during the dry season. This study recommends interventions such as labour for herding, and other animal husbandry-related activities including milking, handling, and vaccinating animals. Market opportunities for communal rangeland livestock should be facilitated by informing livestock owners about livestock market specifications to improve their livelihoods. Lastly, proper grazing management planning, such as fencing, which enables rotational grazing, and herding which moves animals to the most productive parts of the rangeland, should be implemented so that rangelands can be rested for plant growth, vigour, and improved aboveground net primary productivity. Based on the recommendations made in this study, a research development approach is necessary which prioritises female empowerment in agriculture and poor farmers as female-headed households were reported by this study to be more technically efficient.
- Full Text:
- Date Issued: 2019
- Authors: Gusha, Bukho
- Date: 2019
- Subjects: Livestock -- South Africa -- Eastern Cape , Livestock -- Effect of drought on -- South Africa -- Eastern Cape , Animals -- Food -- South Africa -- Eastern Cape , Livestock -- Effect of water quality on -- South Africa -- Eastern Cape , Livestock -- Water requirements -- South Africa -- Eastern Cape , Livestock productivity -- South Africa -- Eastern Cape , Stochastic analysis , Communal rangelands -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape , Animal owners -- South Africa -- Eastern Cape , Livestock improvement -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/115171 , vital:34084
- Description: Communal rangelands in South Africa mainly occur in the former homelands. The former homelands constitute 13% of the land surface area and support a quarter of the country's human population with a wide range of goods and services, among them, grazing for livestock, mostly reared on communal rangelands. These rangelands are degraded and cannot sustain maximum livestock production because of poor species composition and low standing biomass, however research has been conducted on livestock production at household level (where all livestock goods and services are valued). This provides an opportunity to conduct a study describing livestock water productivity in the north of the Eastern Cape, where livestock production is a primary source of livelihood for rural communities from which many households generate cash but where different practices and factors undermine high livestock production. Many studies have focused on understanding the water productivity of a natural rangeland system for commercially oriented crop-livestock systems, but the aim of this study is to contribute towards improving rural livelihoods from livestock in the sub-humid rangelands of the north Eastern Cape. Here, unimproved native grasslands are the major source of feed for livestock and people do not have herders to take livestock to the most productive parts of the rangelands. Households were surveyed using a questionnaire on livestock household contribution, socioeconomic characteristics of the household, livestock holdings and livestock production strategies. Rangeland productivity was measured in the field. Experimental animals for livestock grazing distribution were identified and fitted with Global Positioning Systems (GPS) collars to identify the seasonal grazing areas. These activities shed light on the biophysical attributes of the ecosystem and livestock production in a communal rangeland system. Because continuous grazing in the rangelands of the north Eastern Cape reduces the standing biomass, there is no obvious aboveground biomass to provide a visual perspective of production nor is it possible to determine production without excluding the livestock. Thus, four parallel lines of evidence were employed to measure rangeland productivity: line intercept, grazing exclosures, net photosynthesis from earth observation and disc pasture meter. Earth observation products were used to derive the amount of water used by the landscape to produce this forage (i.e. evapotranspiration or ET) and these measurements of net primary production and landscape water use were used in preparing a value of livestock water productivity (LWP) for this farming system. There has been the perception that residents of the study area lack knowledge of technical efficiencies in the large stock sector at household level. The study used stochastic frontier analysis to assess livestock production and followed with a household survey to collect information on socio-economic characteristics and information on livestock practices. The data from the household survey were used to estimate the technical efficiency of households using a stochastic frontier analysis. Productivity and inefficiency variables that increase livestock production or increase technical difficulties were identified. The focus on livestock has mostly been on the direct value of livestock to owners with a poor understanding of their value to non-livestock owners, where cultural activities, such as livestock slaughtering, were documented as the only source of protein for non-livestock owners. However, the value that is available to non-livestock owners has not been quantified. This study assessed livestockbased livelihoods of communal people to improve their livelihoods through a household survey looking at the contribution of livestock to both livestock and non-livestock owners. Earlier work on LWP has focused on systems where animals were on ‘fed, cut and carry’ and irrigated systems. However, there is a need to describe LWP in a natural grazing system and this study set out to achieve this for these communal rangelands through a household survey that determined the value of livestock goods and services given the amount of water used (ET). Lastly, livestock grazing distribution across the landscape was assessed, using GPS collars that recorded livestock behaviour every five minutes during the daylight. This approach was necessary because livestock grazing patterns in these communal rangelands is poorly controlled by people, and animals are largely free-ranging, grazing selectively, based on their own preferences, which leads to localised overgrazing. This part of the study was achieved through experimental livestock collaring and weighing (both sheep and goats) for the wet and dry seasons. The collared livestock were weighed on the day of putting on collars and the day of removing the collars. The results on livestock grazing distribution were analysed using the R package, T-LoCoH. The major finding of this study was that communal rangelands of the north Eastern Cape can improve rural livelihoods from livestock if proper interventions for both livestock and rangeland production and productivity can be implemented. One of these interventions is fencing as it was found that exclosures that were fenced during the study yielded high aboveground productivity comparable to that achieved in commercial rangelands, yielding 220 g DM m-2 yr-1. Surveys using the calibrated disc pasture meter showed the need for proper rotation and resting of the rangeland. Net photosynthesis of 880.7 g C m-2 yr-1 for unimproved grassland in good condition was comparable to commercial rangelands in the region. Using the line intercept, vegetation cover was found to be a good predictor of aboveground standing biomass; thus a positive relationship was revealed. Lastly, annual ET of 270 mm yr-1 was calculated using the Penman Monteith Palmer (PMP) equation, while 379 mm yr-1 was extracted from the MOD16 product, suggesting that PMP ET may not be accurate in these grassland systems due to the slow response of MODIS Leaf Area Index (LAI). The average household technical efficiency (TE) score was found to be 0.79 on the study sites, indicating the potential for households to improve outputs from livestock. A range of household categories were identified, based on gender and an index of wealth, and households with lower and higher TE were identified. This analysis revealed that productivity variables such as holding higher livestock numbers and providing additional feed achieved high livestock outputs, suggesting high livestock productivity. However, in terms of inefficiency variables, gender (female-headed households), dwelling type (an index of homestead wealth), kraaling livestock at night and herding livestock during the day were found to improve technical efficiency. It was revealed in this study that households keep livestock to derive different goods and services including offtake, manure, milk, wool and services such as traction. The non-livestock owning households were reported to also benefit from the abovementioned goods and services in the study site and that the value of their contribution could be quantified, thus contributing significantly to rural livelihoods. The study showed that LWP was comparable with other studies such as those conducted in Ethiopia. This study compared its results with the studies conducted outside South Africa as there were limited comparable South African studies available; however, this does not necessarily mean we can use the same model as the value of livestock outputs varies based on the preferred outputs. This study developed an LWP model for the natural rangeland system. The LWP values were measured in ZAR and later converted in USD and were divided into three different categories based on the wealth index, such as better-off, middle wealth and poor households. Lastly, this study showed that livestock (both cattle and sheep) spend a high proportion of their grazing day, during both the wet and dry seasons, in a small physical area, immediately around the homesteads. These are areas where the active green growth occurs throughout the year, suggesting the need for livestock herders to move livestock around the landscape for more effective landscape use. Herding has the potential to improve landscape use and conserve grazing resource and the ability of a household to attain best outputs from livestock. Positive daily weight gains were reported in collared livestock during the wet season. However, both sheep and cattle lost weight during the dry season. This study recommends interventions such as labour for herding, and other animal husbandry-related activities including milking, handling, and vaccinating animals. Market opportunities for communal rangeland livestock should be facilitated by informing livestock owners about livestock market specifications to improve their livelihoods. Lastly, proper grazing management planning, such as fencing, which enables rotational grazing, and herding which moves animals to the most productive parts of the rangeland, should be implemented so that rangelands can be rested for plant growth, vigour, and improved aboveground net primary productivity. Based on the recommendations made in this study, a research development approach is necessary which prioritises female empowerment in agriculture and poor farmers as female-headed households were reported by this study to be more technically efficient.
- Full Text:
- Date Issued: 2019
L’entre-deux identitaire dans quelques oeuvres d’écrivains francophones “immigrantsˮ, “cas de Dany Laferrière, d’Alain Mabanckou, de Calixthe Beyala et de Lottin Wekapeˮ
- Kayumba, Viviane Ngoie Banza
- Authors: Kayumba, Viviane Ngoie Banza
- Date: 2019
- Subjects: African literature (French) -- History and criticism , Immigrants in literature , Mabanckou, Alain, 1966-. Black bazaar , Laferrière, Dany. Je suis un écrivain japonais , Beyala, Calixthe. Le Petit prince de Belleville , Wekape, Lottin, 1968-. J’appartiens au monde
- Language: French
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/150929 , vital:39018
- Description: This dissertation examines the theme of hybrid identities in Mabanckou, Laferrière, Beyala and Wekape’s novels : Black Bazar, Le Petit prince de Belleville, Je suis un écrivain japonais and J’appartiens au monde. Hybrid identity raises the issue of identity diversity and contemporary francophone literature is characterised by the emergence of fictional narratives increasingly numerous. This research undertaken is driven by the desire to extend the field of investigation in francophone literature by taking into account a varied corpus of Haitian, Congolese, and Cameroonian literatures. I have opted for writers who settled in a foreign country and have adopted a foreign language that they considered to be part of a foreign literary world; writers who are between two or more cultures which they depict in French. The few existing studies on hybrid identities on these four novels focused more on formal and linguistic analysis and omitted meaningful sociocritic analysis. It is clear that a full study on sociocritic approach on hybrid identity on these four authors remains to be done. The research is demonstrating how different characters created by these four postmodern immigrant French-speaking writers occasionally function similarly in their texts. This gives a clear understanding of the specific behaviour of immigrants characters, vis-à-vis their various situations in the novels, and how these immigrants seek to address the problems they encounter. As this research offers reflections related to the identities and nationalities of immigrants, Laferrière, Mabanckou, Beyala and Wekape’s texts are based on the search for social belonging and a literary membership in this modern world. Therefore, they are analysing their position in a literary field as well as in a social field. In their texts they highlight the Space real or imaginary. In which way and how this Space contribute to the evolution of francophone literature? To what extent does francophone literature takes into account this representation of the Space? These questions lead to a reflection on the position occupied by these authors in the francophone field and the source of their literary inspirations. My interest in these authors is motivated by the fact that, by living and writing in a country which is not their place of birth, they each reveal different aspects of hybrid identity. Each of them, has his or her personal and original way of tackling the problem of mixed identity. They present their characters in different situations and different contexts, showing that each has been in contact with several cultures which they have assimilated and each lived in his or her own way a particular story. My study’s focus is to understand the problems of contact of cultures and their consequences, and to explore how through the characters of the novel, immigrant French speaking writers understood their acculturation as themselves have experienced an identity crisis, resulting from the confrontation of the culture of their new homeland and the culture of their country of origin. For this reason, Bourdieu’s approach “la sociocritique” will help me to found out the origin of the author’s obsession with the question of hybrid identity. I have chosen these four immigrant speaking writers to explore the strategies implemented by the novels’ narrators to construct their identities and to find out how the narrators express the intentions of the authors. In their texts, Mabanckou, Beyala, Laferrière and Wekape have used various strategies to express the quest for identity which gives clear indications of the authors’ creativity such as humour, parody, or solemnity and gravity - and the narrative voices reveal distinctive attitudes in relation to hybrid identity. At this level, other approaches will also be called for, such as the work of Westphal, Doubrovsky, Genette, Colona, etc. Through my investigation, these works present similarities and dissimilarities. Each author tackled the questions of hybrid identities according to his own experience. From there, a different commitment emerges, depending on the degree of inquiry into questions about immigration. These authors all evoke the social precariousness of their characters or the immigrant and privilege an urban framework. The examination of these works allowed me to identify their place in Francophonie literature and to discover the importance of their texts. The four novels relate to the search for identity, an aesthetic way and a search for freedom. They possess aesthetic qualities, they have a high degree of coherence. Their romantic choice shows their creativity and their strategies engender a hybrid writing that stems from their position between several languages and place these novels within the world literature.
- Full Text:
- Date Issued: 2019
- Authors: Kayumba, Viviane Ngoie Banza
- Date: 2019
- Subjects: African literature (French) -- History and criticism , Immigrants in literature , Mabanckou, Alain, 1966-. Black bazaar , Laferrière, Dany. Je suis un écrivain japonais , Beyala, Calixthe. Le Petit prince de Belleville , Wekape, Lottin, 1968-. J’appartiens au monde
- Language: French
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/150929 , vital:39018
- Description: This dissertation examines the theme of hybrid identities in Mabanckou, Laferrière, Beyala and Wekape’s novels : Black Bazar, Le Petit prince de Belleville, Je suis un écrivain japonais and J’appartiens au monde. Hybrid identity raises the issue of identity diversity and contemporary francophone literature is characterised by the emergence of fictional narratives increasingly numerous. This research undertaken is driven by the desire to extend the field of investigation in francophone literature by taking into account a varied corpus of Haitian, Congolese, and Cameroonian literatures. I have opted for writers who settled in a foreign country and have adopted a foreign language that they considered to be part of a foreign literary world; writers who are between two or more cultures which they depict in French. The few existing studies on hybrid identities on these four novels focused more on formal and linguistic analysis and omitted meaningful sociocritic analysis. It is clear that a full study on sociocritic approach on hybrid identity on these four authors remains to be done. The research is demonstrating how different characters created by these four postmodern immigrant French-speaking writers occasionally function similarly in their texts. This gives a clear understanding of the specific behaviour of immigrants characters, vis-à-vis their various situations in the novels, and how these immigrants seek to address the problems they encounter. As this research offers reflections related to the identities and nationalities of immigrants, Laferrière, Mabanckou, Beyala and Wekape’s texts are based on the search for social belonging and a literary membership in this modern world. Therefore, they are analysing their position in a literary field as well as in a social field. In their texts they highlight the Space real or imaginary. In which way and how this Space contribute to the evolution of francophone literature? To what extent does francophone literature takes into account this representation of the Space? These questions lead to a reflection on the position occupied by these authors in the francophone field and the source of their literary inspirations. My interest in these authors is motivated by the fact that, by living and writing in a country which is not their place of birth, they each reveal different aspects of hybrid identity. Each of them, has his or her personal and original way of tackling the problem of mixed identity. They present their characters in different situations and different contexts, showing that each has been in contact with several cultures which they have assimilated and each lived in his or her own way a particular story. My study’s focus is to understand the problems of contact of cultures and their consequences, and to explore how through the characters of the novel, immigrant French speaking writers understood their acculturation as themselves have experienced an identity crisis, resulting from the confrontation of the culture of their new homeland and the culture of their country of origin. For this reason, Bourdieu’s approach “la sociocritique” will help me to found out the origin of the author’s obsession with the question of hybrid identity. I have chosen these four immigrant speaking writers to explore the strategies implemented by the novels’ narrators to construct their identities and to find out how the narrators express the intentions of the authors. In their texts, Mabanckou, Beyala, Laferrière and Wekape have used various strategies to express the quest for identity which gives clear indications of the authors’ creativity such as humour, parody, or solemnity and gravity - and the narrative voices reveal distinctive attitudes in relation to hybrid identity. At this level, other approaches will also be called for, such as the work of Westphal, Doubrovsky, Genette, Colona, etc. Through my investigation, these works present similarities and dissimilarities. Each author tackled the questions of hybrid identities according to his own experience. From there, a different commitment emerges, depending on the degree of inquiry into questions about immigration. These authors all evoke the social precariousness of their characters or the immigrant and privilege an urban framework. The examination of these works allowed me to identify their place in Francophonie literature and to discover the importance of their texts. The four novels relate to the search for identity, an aesthetic way and a search for freedom. They possess aesthetic qualities, they have a high degree of coherence. Their romantic choice shows their creativity and their strategies engender a hybrid writing that stems from their position between several languages and place these novels within the world literature.
- Full Text:
- Date Issued: 2019
Modelling storm-time TEC changes using linear and non-linear techniques
- Authors: Uwamahoro, Jean Claude
- Date: 2019
- Subjects: Magnetic storms , Astronomy -- Computer programs , Imaging systems in astronomy , Ionospheric storms , Electrons -- Measurement , Magnetosphere -- Observations
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92908 , vital:30762
- Description: Statistical models based on empirical orthogonal functions (EOF) analysis and non-linear regression analysis (NLRA) were developed for the purpose of estimating the ionospheric total electron content (TEC) during geomagnetic storms. The well-known least squares method (LSM) and Metropolis-Hastings algorithm (MHA) were used as optimization techniques to determine the unknown coefficients of the developed analytical expressions. Artificial Neural Networks (ANNs), the International Reference Ionosphere (IRI) model, and the Multi-Instrument Data Analysis System (MIDAS) tomographic inversion algorithm were also applied to storm-time TEC modelling/reconstruction for various latitudes of the African sector and surrounding areas. This work presents some of the first statistical modeling of the mid-latitude and low-latitude ionosphere during geomagnetic storms that includes solar, geomagnetic and neutral wind drivers.Development and validation of the empirical models were based on storm-time TEC data derived from the global positioning system (GPS) measurements over ground receivers within Africa and surrounding areas. The storm criterion applied was Dst 6 −50 nT and/or Kp > 4. The performance evaluation of MIDAS compared with ANNs to reconstruct storm-time TEC over the African low- and mid-latitude regions showed that MIDAS and ANNs provide comparable results. Their respective mean absolute error (MAE) values were 4.81 and 4.18 TECU. The ANN model was, however, found to perform 24.37 % better than MIDAS at estimating storm-time TEC for low latitudes, while MIDAS is 13.44 % more accurate than ANN for the mid-latitudes. When their performances are compared with the IRI model, both MIDAS and ANN model were found to provide more accurate storm-time TEC reconstructions for the African low- and mid-latitude regions. A comparative study of the performances of EOF, NLRA, ANN, and IRI models to estimate TEC during geomagnetic storm conditions over various latitudes showed that the ANN model is about 10 %, 26 %, and 58 % more accurate than EOF, NLRA, and IRI models, respectively, while EOF was found to perform 15 %, and 44 % better than NLRA and IRI, respectively. It was further found that the NLRA model is 25 % more accurate than the IRI model. We have also investigated for the first time, the role of meridional neutral winds (from the Horizontal Wind Model) to storm-time TEC modelling in the low latitude, northern and southern hemisphere mid-latitude regions of the African sector, based on ANN models. Statistics have shown that the inclusion of the meridional wind velocity in TEC modelling during geomagnetic storms leads to percentage improvements of about 5 % for the low latitude, 10 % and 5 % for the northern and southern hemisphere mid-latitude regions, respectively. High-latitude storm-induced winds and the inter-hemispheric blows of the meridional winds from summer to winter hemisphere have been suggested to be associated with these improvements.
- Full Text:
- Date Issued: 2019
- Authors: Uwamahoro, Jean Claude
- Date: 2019
- Subjects: Magnetic storms , Astronomy -- Computer programs , Imaging systems in astronomy , Ionospheric storms , Electrons -- Measurement , Magnetosphere -- Observations
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92908 , vital:30762
- Description: Statistical models based on empirical orthogonal functions (EOF) analysis and non-linear regression analysis (NLRA) were developed for the purpose of estimating the ionospheric total electron content (TEC) during geomagnetic storms. The well-known least squares method (LSM) and Metropolis-Hastings algorithm (MHA) were used as optimization techniques to determine the unknown coefficients of the developed analytical expressions. Artificial Neural Networks (ANNs), the International Reference Ionosphere (IRI) model, and the Multi-Instrument Data Analysis System (MIDAS) tomographic inversion algorithm were also applied to storm-time TEC modelling/reconstruction for various latitudes of the African sector and surrounding areas. This work presents some of the first statistical modeling of the mid-latitude and low-latitude ionosphere during geomagnetic storms that includes solar, geomagnetic and neutral wind drivers.Development and validation of the empirical models were based on storm-time TEC data derived from the global positioning system (GPS) measurements over ground receivers within Africa and surrounding areas. The storm criterion applied was Dst 6 −50 nT and/or Kp > 4. The performance evaluation of MIDAS compared with ANNs to reconstruct storm-time TEC over the African low- and mid-latitude regions showed that MIDAS and ANNs provide comparable results. Their respective mean absolute error (MAE) values were 4.81 and 4.18 TECU. The ANN model was, however, found to perform 24.37 % better than MIDAS at estimating storm-time TEC for low latitudes, while MIDAS is 13.44 % more accurate than ANN for the mid-latitudes. When their performances are compared with the IRI model, both MIDAS and ANN model were found to provide more accurate storm-time TEC reconstructions for the African low- and mid-latitude regions. A comparative study of the performances of EOF, NLRA, ANN, and IRI models to estimate TEC during geomagnetic storm conditions over various latitudes showed that the ANN model is about 10 %, 26 %, and 58 % more accurate than EOF, NLRA, and IRI models, respectively, while EOF was found to perform 15 %, and 44 % better than NLRA and IRI, respectively. It was further found that the NLRA model is 25 % more accurate than the IRI model. We have also investigated for the first time, the role of meridional neutral winds (from the Horizontal Wind Model) to storm-time TEC modelling in the low latitude, northern and southern hemisphere mid-latitude regions of the African sector, based on ANN models. Statistics have shown that the inclusion of the meridional wind velocity in TEC modelling during geomagnetic storms leads to percentage improvements of about 5 % for the low latitude, 10 % and 5 % for the northern and southern hemisphere mid-latitude regions, respectively. High-latitude storm-induced winds and the inter-hemispheric blows of the meridional winds from summer to winter hemisphere have been suggested to be associated with these improvements.
- Full Text:
- Date Issued: 2019
Nonlinear optical responses of targeted phthalocyanines when conjugated with nanomaterials or fabricated into polymer thin films
- Authors: Nwaji, Njemuwa Njoku
- Date: 2019
- Subjects: Electrochemistry , Phthalocyanines , Nanoparticles , Bioconjugates , Thin films , Polymers , Nonlinear optics , Nonlinear optical spectroscopy , Nanostructured materials , Raman effect
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/71625 , vital:29926
- Description: A number of zinc, gallium and indium metallophthalocyanines (MPcs) with diverse substituents have been synthesized and characterized using various characterization tools such as proton nuclear magnetic resonance (1HNMR), matrix assisted laser desorption time of flight (MALDI-TOF) mass spectrometry, Fourier-transformed infra-red (FT-IR), Ultraviolet-visible (Uv-vis) spectrophotometry, magnetic circular dichroism and CHNS elemental analysis. The time dependent density functional theory was employed to probe the origin of spectroscopic information in these complexes. Complexes with gallium and indium as central metal showed higher triplet quantum yield compared to the zinc derivatives. Some of the MPcs were covalently linked to nanomaterials such as CdTe, CdTeSe, CdTeSe/ZnO, graphene quantum dots (GQDs) as well as metallic gold (AuNPs) and silver (AgNPs) nanoparticles. Others were either surface assembled onto AuNPs and AgNPs or embedded into polystyrene as polymer source. The phthalocyanine-nanomaterial composites (Pc-NMCs) were characterized with FT-IR, UV-visible spectrophotometry, transmission electron microscopy (TEM), dynamic light scattering (DLS), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and X-ray diffractometry (XRD). The thickness of the thin films was determined by utilization of the knife edge attachment of the A Bruker D8 Discover X-ray diffraction. The optical limiting properties (using the open-aperture Z-scan technique) of the MPcs and the Pc-NMCs were investigated. The investigated MPcs complexes generally showed good optical limiting properties. The nonlinear optical response of the MPcs were improved in the presence of nanomaterials such as the semiconductor quantum dots (SQDs), graphene quantum dots (GQDs) as well as metallic AuNPs and AgNPs with MPc-QDs showing the best optical limiting behavior. The optical limiting properties of the MPcs were greatly enhanced in the presence of polymer thin films.
- Full Text:
- Date Issued: 2019
- Authors: Nwaji, Njemuwa Njoku
- Date: 2019
- Subjects: Electrochemistry , Phthalocyanines , Nanoparticles , Bioconjugates , Thin films , Polymers , Nonlinear optics , Nonlinear optical spectroscopy , Nanostructured materials , Raman effect
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/71625 , vital:29926
- Description: A number of zinc, gallium and indium metallophthalocyanines (MPcs) with diverse substituents have been synthesized and characterized using various characterization tools such as proton nuclear magnetic resonance (1HNMR), matrix assisted laser desorption time of flight (MALDI-TOF) mass spectrometry, Fourier-transformed infra-red (FT-IR), Ultraviolet-visible (Uv-vis) spectrophotometry, magnetic circular dichroism and CHNS elemental analysis. The time dependent density functional theory was employed to probe the origin of spectroscopic information in these complexes. Complexes with gallium and indium as central metal showed higher triplet quantum yield compared to the zinc derivatives. Some of the MPcs were covalently linked to nanomaterials such as CdTe, CdTeSe, CdTeSe/ZnO, graphene quantum dots (GQDs) as well as metallic gold (AuNPs) and silver (AgNPs) nanoparticles. Others were either surface assembled onto AuNPs and AgNPs or embedded into polystyrene as polymer source. The phthalocyanine-nanomaterial composites (Pc-NMCs) were characterized with FT-IR, UV-visible spectrophotometry, transmission electron microscopy (TEM), dynamic light scattering (DLS), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and X-ray diffractometry (XRD). The thickness of the thin films was determined by utilization of the knife edge attachment of the A Bruker D8 Discover X-ray diffraction. The optical limiting properties (using the open-aperture Z-scan technique) of the MPcs and the Pc-NMCs were investigated. The investigated MPcs complexes generally showed good optical limiting properties. The nonlinear optical response of the MPcs were improved in the presence of nanomaterials such as the semiconductor quantum dots (SQDs), graphene quantum dots (GQDs) as well as metallic AuNPs and AgNPs with MPc-QDs showing the best optical limiting behavior. The optical limiting properties of the MPcs were greatly enhanced in the presence of polymer thin films.
- Full Text:
- Date Issued: 2019
Observing cosmic reionization with PAPER: polarized foreground simulations and all sky images
- Authors: Nunhokee, Chuneeta Devi
- Date: 2019
- Subjects: Cosmic background radiation , Astronomy -- Observations , Epoch of reionization -- Research , Hydrogen -- Spectra , Radio interferometers
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/68203 , vital:29218
- Description: The Donald C. Backer Precision Array to Probe the Epoch of Reionization (PAPER, Parsons et al., 2010) was built with an aim to detect the redshifted 21 cm Hydrogen line, which is likely the best probe of thermal evolution of the intergalactic medium and reionization of neutral Hydrogen in our Universe. Observations of the 21 cm signal are challenged by bright astrophysical foregrounds and systematics that require precise modeling in order to extract the cosmological signal. In particular, the instrumental leakage of polarized foregrounds may contaminate the 21 cm power spectrum. In this work, we developed a formalism to describe the leakage due to instrumental widefield effects in visibility-based power spectra and used it to predict contaminations in observations. We find the leakage due to a population of point sources to be higher than the diffuse Galactic emission – for which we can predict minimal contaminations at k>0.3 h Mpc -¹ We also analyzed data from the last observing season of PAPER via all-sky imaging with a view to characterize the foregrounds. We generated an all-sky catalogue of 88 sources down to a flux density of 5 Jy. Moreover, we measured both polarized point source and the Galactic diffuse emission, and used these measurements to constrain our model of polarization leakage. We find the leakage due to a population of point sources to be 12% lower than the prediction from our polarized model.
- Full Text:
- Date Issued: 2019
- Authors: Nunhokee, Chuneeta Devi
- Date: 2019
- Subjects: Cosmic background radiation , Astronomy -- Observations , Epoch of reionization -- Research , Hydrogen -- Spectra , Radio interferometers
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/68203 , vital:29218
- Description: The Donald C. Backer Precision Array to Probe the Epoch of Reionization (PAPER, Parsons et al., 2010) was built with an aim to detect the redshifted 21 cm Hydrogen line, which is likely the best probe of thermal evolution of the intergalactic medium and reionization of neutral Hydrogen in our Universe. Observations of the 21 cm signal are challenged by bright astrophysical foregrounds and systematics that require precise modeling in order to extract the cosmological signal. In particular, the instrumental leakage of polarized foregrounds may contaminate the 21 cm power spectrum. In this work, we developed a formalism to describe the leakage due to instrumental widefield effects in visibility-based power spectra and used it to predict contaminations in observations. We find the leakage due to a population of point sources to be higher than the diffuse Galactic emission – for which we can predict minimal contaminations at k>0.3 h Mpc -¹ We also analyzed data from the last observing season of PAPER via all-sky imaging with a view to characterize the foregrounds. We generated an all-sky catalogue of 88 sources down to a flux density of 5 Jy. Moreover, we measured both polarized point source and the Galactic diffuse emission, and used these measurements to constrain our model of polarization leakage. We find the leakage due to a population of point sources to be 12% lower than the prediction from our polarized model.
- Full Text:
- Date Issued: 2019
Occurrence, feeding ecology, and population structure of two dolphin species, Tursiops aduncus and Delphinus delphis, off the Wild Coast of South Africa
- Authors: Caputo, Michelle Anne
- Date: 2019
- Subjects: Delphinus -- South Africa-- Kwazulu-Natal -- Ecology , Tursoops -- South Africa-- Kwazulu-Natal -- Ecology , Delphinus -- South Africa-- Kwazulu-Natal -- Feeding and feeds , Tursoops -- South Africa-- Kwazulu-Natal -- Feeding and feeds , Dolphins -- South Africa-- Kwazulu-Natal , Delphinus -- South Africa-- Kwazulu-Natal -- Behavior , Tursoops -- South Africa-- Kwazulu-Natal -- Behavior , Marine ecology -- South Africa -- Kwazulu-Natal
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/115612 , vital:34197
- Description: Dolphins are apex predators and their movements, foraging activities and population dynamics play an important role in shaping their environment. Understanding their occurrence, movement patterns, and trophic ecology is essential to their conservation, especially as they are considered sentinel species. The Wild Coast of South Africa’s Eastern Cape, is characterized by the annual sardine (Sardinops sagax) run, which serves as an important foraging event for apex predators, including Indo-Pacific bottlenose (Tursiops aduncus) and long-beaked common dolphins (Delphinus delphis). Despite the ecological significance of this event, no dedicated surveys for these species have previously been conducted in this area. The main objectives of this research were to: investigate long-term occurrence of dolphins during the sardine run to determine if there have been any changes over the past 19 years, as has been predicted from common dolphin dietary investigations and anecdotal evidence; to determine short-term occurrence and movement patterns of selected inshore delphinids within the area, which is characterized by three marine protected areas (MPAs); and to use stable isotope analyses to determine trophic relationships and population structure of bottlenose and common dolphins within the region. Long-term data consisted of 131 opportunistic aerial surveys conducted between May and July over the period 1996 to 2014. Results from these surveys indicate that common dolphins, typically associated with sardines, decreased significantly in average group size over the study period (p=0.0343). Bottlenose dolphins, demonstrated no such trend (p=0.916). For both species, greater majority (> 70% of total counts) of sightings were made inside the MPAs. Short-term boat-based surveys were conducted three times a year between June 2014 and December 2016, contributing to a total of 47 days of surveys divided into three locations: Amathole, Hluleka, and Pondoland, each containing a MPA. Density and group size data were analyzed for both species and photographic identification analysis was performed for photographs of bottlenose dolphin dorsal fins. Results indicate that animal and sighting density did not differ temporally (bottlenose dolphin: sighting density – p=0.398, individual density –p=0.781; common dolphin: sighting density –p=0.472, individual density – p=0.204). Environmental factors (sea surface temperature, depth, substrate, and distance from shore) appeared to have limited effect on individual and sighting density and group size for both species (p>0.05). Photographic identification of bottlenose dolphins resulted in 2149 individuals, with a 11.8% resighting rate, with the highest resighting rate within the Pondoland MPA (16.1%). The resighting count did not differ temporally between monthly survey based on generalized linear models (p=0.866), but did differ between study areas (p<0.0001). These results provide the first evidence of the occurrence of both species of dolphin off the Wild Coast, as they were sighted in this region in all survey months. There was no trend in density based on temporal or environmental factors, which suggests other factors are influencing their occurrence. Resightings of bottlenose dolphins within the area suggest that there is some degree of residency, though the majority of animals were only sighted on a single occasion and there was no plateau in the discovery curve. A total of 256 biopsy samples (bottlenose dolphins =128; common dolphins=128) were collected during boat-based surveys. Bottlenose dolphin samples were also collected from adjacent areas to the southwest (Algoa Bay, n=22) and northeast (KwaZulu-Natal (KZN), n=20) of the Wild Coast to investigate similarities and differences between these areas. Despite a high degree of niche overlap between the two species (41%), common dolphins fed with a broader niche (standard ellipse area probability 0.89) than bottlenose dolphins in the summer and a narrower niche in the winter (probability 0.94). There was a clear spatial variation in the diet of bottlenose dolphins along the coast, with individuals from Algoa Bay and Amathole demonstrating 0% niche overlap with individuals from KZN, but the mechanism for these differences remains unclear as other species from South African waters demonstrate a strong southwest to northeast gradient in nitrogen for the Eastern Cape coastline. This research provides valuable baseline information regarding dolphins off the Wild Coast of South Africa, which remained largely unknown. My results indicate that bottlenose dolphins may be more resident in the Wild Coast than previous predicted, and confirm that common dolphins are highly mobile in this area.
- Full Text:
- Date Issued: 2019
- Authors: Caputo, Michelle Anne
- Date: 2019
- Subjects: Delphinus -- South Africa-- Kwazulu-Natal -- Ecology , Tursoops -- South Africa-- Kwazulu-Natal -- Ecology , Delphinus -- South Africa-- Kwazulu-Natal -- Feeding and feeds , Tursoops -- South Africa-- Kwazulu-Natal -- Feeding and feeds , Dolphins -- South Africa-- Kwazulu-Natal , Delphinus -- South Africa-- Kwazulu-Natal -- Behavior , Tursoops -- South Africa-- Kwazulu-Natal -- Behavior , Marine ecology -- South Africa -- Kwazulu-Natal
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/115612 , vital:34197
- Description: Dolphins are apex predators and their movements, foraging activities and population dynamics play an important role in shaping their environment. Understanding their occurrence, movement patterns, and trophic ecology is essential to their conservation, especially as they are considered sentinel species. The Wild Coast of South Africa’s Eastern Cape, is characterized by the annual sardine (Sardinops sagax) run, which serves as an important foraging event for apex predators, including Indo-Pacific bottlenose (Tursiops aduncus) and long-beaked common dolphins (Delphinus delphis). Despite the ecological significance of this event, no dedicated surveys for these species have previously been conducted in this area. The main objectives of this research were to: investigate long-term occurrence of dolphins during the sardine run to determine if there have been any changes over the past 19 years, as has been predicted from common dolphin dietary investigations and anecdotal evidence; to determine short-term occurrence and movement patterns of selected inshore delphinids within the area, which is characterized by three marine protected areas (MPAs); and to use stable isotope analyses to determine trophic relationships and population structure of bottlenose and common dolphins within the region. Long-term data consisted of 131 opportunistic aerial surveys conducted between May and July over the period 1996 to 2014. Results from these surveys indicate that common dolphins, typically associated with sardines, decreased significantly in average group size over the study period (p=0.0343). Bottlenose dolphins, demonstrated no such trend (p=0.916). For both species, greater majority (> 70% of total counts) of sightings were made inside the MPAs. Short-term boat-based surveys were conducted three times a year between June 2014 and December 2016, contributing to a total of 47 days of surveys divided into three locations: Amathole, Hluleka, and Pondoland, each containing a MPA. Density and group size data were analyzed for both species and photographic identification analysis was performed for photographs of bottlenose dolphin dorsal fins. Results indicate that animal and sighting density did not differ temporally (bottlenose dolphin: sighting density – p=0.398, individual density –p=0.781; common dolphin: sighting density –p=0.472, individual density – p=0.204). Environmental factors (sea surface temperature, depth, substrate, and distance from shore) appeared to have limited effect on individual and sighting density and group size for both species (p>0.05). Photographic identification of bottlenose dolphins resulted in 2149 individuals, with a 11.8% resighting rate, with the highest resighting rate within the Pondoland MPA (16.1%). The resighting count did not differ temporally between monthly survey based on generalized linear models (p=0.866), but did differ between study areas (p<0.0001). These results provide the first evidence of the occurrence of both species of dolphin off the Wild Coast, as they were sighted in this region in all survey months. There was no trend in density based on temporal or environmental factors, which suggests other factors are influencing their occurrence. Resightings of bottlenose dolphins within the area suggest that there is some degree of residency, though the majority of animals were only sighted on a single occasion and there was no plateau in the discovery curve. A total of 256 biopsy samples (bottlenose dolphins =128; common dolphins=128) were collected during boat-based surveys. Bottlenose dolphin samples were also collected from adjacent areas to the southwest (Algoa Bay, n=22) and northeast (KwaZulu-Natal (KZN), n=20) of the Wild Coast to investigate similarities and differences between these areas. Despite a high degree of niche overlap between the two species (41%), common dolphins fed with a broader niche (standard ellipse area probability 0.89) than bottlenose dolphins in the summer and a narrower niche in the winter (probability 0.94). There was a clear spatial variation in the diet of bottlenose dolphins along the coast, with individuals from Algoa Bay and Amathole demonstrating 0% niche overlap with individuals from KZN, but the mechanism for these differences remains unclear as other species from South African waters demonstrate a strong southwest to northeast gradient in nitrogen for the Eastern Cape coastline. This research provides valuable baseline information regarding dolphins off the Wild Coast of South Africa, which remained largely unknown. My results indicate that bottlenose dolphins may be more resident in the Wild Coast than previous predicted, and confirm that common dolphins are highly mobile in this area.
- Full Text:
- Date Issued: 2019
Perspectives on land and water politics at Mushandike Irrigation Scheme, Masvingo, Zimbabwe
- Authors: Mafukidze, Jonathan
- Date: 2019
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76479 , vital:30573
- Description: Access to, control and ownership of land and water, amongst other natural resources in Zimbabwe, shape and affect rural lives, livelihoods, social relations and social organisation. Rural poverty has been entrenched and exacerbated by, amongst other factors, highly restricted access to these scarce resources. Historically, Zimbabwe’s rural areas (such as communal areas, smallholder irrigation schemes and resettlement areas) have existed as sites of struggles where contestations and negotiations over access to, control or ownership of these resources have taken place. Resultantly, multifaceted and dynamic social relations have been weaved and contested social spaces carved out. In rural Zimbabwe, contestations have tended to be complex, nuanced and intricate, working themselves out in different ways across time and space. In their heightened and more visible state, they have been characterised by violent physical expressions which, in the history of the country, involved two wars of liberation, the First Chimurenga (1896-1897) and the Second Chimurenga (1960s to 1980). The most recent violent manifestation was through nation-wide land invasions, politically christened the Third Chimurenga, which peaked in 2000 and continued sporadically to this day. Few studies on smallholder irrigation schemes in Zimbabwe have focused on understanding how contestations for access to scarce land and water resources are framed and negotiated at the local level. Cognisant of this lacuna, this thesis uses social constructionism in examining, as a case study, Mushandike Smallholder Irrigation Scheme in Masvingo Province in order to understand and analyse how land and water politics occur at the local level. The study deploys a qualitative research methodology approach in examining local water and land politics, which involved original irrigation beneficiaries and more recent land invaders. Findings of the thesis indicate that land and water shortages have increased considerably in the past two decades at the irrigation scheme due to the influx of land invaders into the scheme. This influx has had a negative impact on agricultural production and other livelihood strategies. Both scheme members and land invaders lay claim to land and water at Mushandike. These claims are intricately constructed and contested, and they are linked to broader issues such as partisan party-politics, policy developments, and tradition, origin, indigeneity and belonging. Though the struggles over land and water at Mushandike are firmly rooted in the concrete conditions of existence and experiences of beneficiaries and land invaders, external actors such as political leaders, state bureaucrats and traditional chiefs tend to complicate and intensify the contestations.
- Full Text:
- Date Issued: 2019
- Authors: Mafukidze, Jonathan
- Date: 2019
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76479 , vital:30573
- Description: Access to, control and ownership of land and water, amongst other natural resources in Zimbabwe, shape and affect rural lives, livelihoods, social relations and social organisation. Rural poverty has been entrenched and exacerbated by, amongst other factors, highly restricted access to these scarce resources. Historically, Zimbabwe’s rural areas (such as communal areas, smallholder irrigation schemes and resettlement areas) have existed as sites of struggles where contestations and negotiations over access to, control or ownership of these resources have taken place. Resultantly, multifaceted and dynamic social relations have been weaved and contested social spaces carved out. In rural Zimbabwe, contestations have tended to be complex, nuanced and intricate, working themselves out in different ways across time and space. In their heightened and more visible state, they have been characterised by violent physical expressions which, in the history of the country, involved two wars of liberation, the First Chimurenga (1896-1897) and the Second Chimurenga (1960s to 1980). The most recent violent manifestation was through nation-wide land invasions, politically christened the Third Chimurenga, which peaked in 2000 and continued sporadically to this day. Few studies on smallholder irrigation schemes in Zimbabwe have focused on understanding how contestations for access to scarce land and water resources are framed and negotiated at the local level. Cognisant of this lacuna, this thesis uses social constructionism in examining, as a case study, Mushandike Smallholder Irrigation Scheme in Masvingo Province in order to understand and analyse how land and water politics occur at the local level. The study deploys a qualitative research methodology approach in examining local water and land politics, which involved original irrigation beneficiaries and more recent land invaders. Findings of the thesis indicate that land and water shortages have increased considerably in the past two decades at the irrigation scheme due to the influx of land invaders into the scheme. This influx has had a negative impact on agricultural production and other livelihood strategies. Both scheme members and land invaders lay claim to land and water at Mushandike. These claims are intricately constructed and contested, and they are linked to broader issues such as partisan party-politics, policy developments, and tradition, origin, indigeneity and belonging. Though the struggles over land and water at Mushandike are firmly rooted in the concrete conditions of existence and experiences of beneficiaries and land invaders, external actors such as political leaders, state bureaucrats and traditional chiefs tend to complicate and intensify the contestations.
- Full Text:
- Date Issued: 2019
Ph-responsive liposomal systems for site-specific pulmonary delivery of anti-tubercular drugs
- Nkanga, Christian Isalomboto
- Authors: Nkanga, Christian Isalomboto
- Date: 2019
- Subjects: Tuberculosis -- Chemotherapy , Lipsomes , Drug carriers (Pharmacy) , Rifampin , Hydrogen-ion concentration , Hydrogen-ion concentration -- Physiological effect
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/125832 , vital:35822
- Description: Tuberculosis (TB) is an infectious disease that has been reported to be the ninth leading cause of death worldwide, even though mostly considered as a poverty related disease. Despite the existence of potent anti-tubercular drugs (ATBDs), such as rifampicin (RIF) and isoniazid (INH), TB remains the major killer among many microbial diseases over the last five years. Although several factors are to be blamed for this deadly status, the most crucial issues encompass both the self-defensiveness of the causative agent (Mycobacterium tuberculosis), including its intra-macrophage location that compromises ATBDs accessibility, and the widespread/off target distribution of ATBDs. The need for novel drug delivery strategies therefore arises to provide selective distribution of ATBDs at the infected site. Among the drug vehicles explored in this field, liposomes have been reported to be the most suitable drug carriers due to their rapid uptake by alveolar macrophages, where M. tuberculosis often resides. Since liposomes experience media of different pH throughout the cell uptake process (endocytosis/phagocytosis), the use of pH change as a stimulus for controlled release looks promising for enhancing intra-macrophage delivery and minimizing premature ‘off-target’ release of ATBDs. However, the costly status of liposome technology, due to the use of sophisticated procedures and expensive materials (especially for pH-dependent delivery, where special lipids are required), may preclude wider developments of liposomal products, especially for the developing world. This study aimed at investigating liposomal encapsulation of pH-sensitive and fluorescent hydrazone derivatives of INH using crude soybean lecithin, as a cost-effective option for site-specific delivery combined with potential bio-imaging features. Another objective was to explore encapsulation of INH hydrazone derivatives with and without RIF in liposomes using a simple and organic solvent-free preparation method. Initially, INH was coupled with 4-hydroxy-benzaldehyde to yield a conjugate (INH-HB) that was encapsulated in liposomes using film hydration method with acceptable encapsulation efficiency (î), about 89 %. The prepared INH-HB loaded liposomes (IHL) were characterized by means of dynamic light scattering (DLS), transmission electron microscopy (TEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The release of INH from IHL was evaluated over 12 hours in media of different pH using dialysis. As hypothesized, pH dependent release of INH from IHL was observed with 22, 69, 83 and 100 % release obtained in media of pH 7.4, 6.4, 5.4 and 4.4, respectively. From this experimental trial, further development was undertaken by conjugating INH to a hydrophobic fluorescent tag, zinc (II) phthalocyanine (PC), through hydrazone linkages. The obtained conjugate (PC-INH) was loaded into liposomes (PIL) that were characterized using various spectroscopic techniques, including UV-Vis absorption and energy dispersive X-ray spectroscopy, which suggested the presence of PC-INH within the lipid bilayers. The release study performed in different pH media revealed 22, 41, 97 and 100 % of INH, respectively released at pH 7.4, 6.4, 5.4 and 4.4. This confirmed the potential of pH-triggered drug release from liposomes loaded with hydrazone drug derivatives. In addition, successful encapsulation of PC-INH using crude soybean lecithin inspired a new opening towards development of multimodal liposomes that could achieve controlled drug release with added benefits of image-guided biological tracking. However, the hydrophobic nature of PC-INH requires an effective strategy that could improve its solubility and favour extensive development. In this context, the tetra-substituted structure of PC-INH brought up the hypothesis that cyclodextrin (CD) complexation would facilitate PC-INH encapsulation in liposomes using an organic solvent-free method, called here the “heating method” (HM). Inclusion complexes of PC-INH with various CDs were therefore investigated, with gamma-CD complex (CP) giving the best results. These complexes were prepared in both solution and solid-state and further comprehensively characterized using UV-Vis spectroscopy, magnetic circular dichroism, NMR spectroscopy, diffusion ordered spectroscopy, DSC, XRD and Fourier transform infrared spectroscopy. CP-loaded liposomes prepared using HM exhibited greater î than film hydration liposomes, about 70 % versus 56 %, respectively. The HM-liposomal system (CPL) exhibited potentially useful nano particulate characteristics (i.e. mean particle size 240 nm and Zeta potential –57 mV), which remained unchanged over 5 weeks of stability study at 4 °C, and pH-dependent INH release behaviour alike PIL. Furthermore, CP was co-encapsulated with rifampicin (RIF) in liposomes using HM to investigate the possibility for future combination therapy. 1H-NMR spectroscopy, DSC, XRD and photophysical studies were performed for molecular assessment of the cargo in CP-RIF co-loaded liposomes (CPRL). The mean particle size, Zeta potential and î of CPRL were respectively 594 nm, –50 mV, 58 % for CP and 86 % for RIF. CPRL exhibited much higher release rates for both INH and RIF at pH 6.4, compared to those tested at pH 7.4. In addition, there was no cytotoxicity on HeLa cells, but attractive lung fibroblasts and epithelial cells uptake and viability. Hence, CPRL are promising for targeted ATBD delivery to alveolar macrophages following pulmonary administration. Overall, the developed pH-responsive liposomal system holds the promise for new openings towards wider developments of multifunctional liposomes for site-specific controlled pulmonary delivery of antimicrobials drugs.
- Full Text:
- Date Issued: 2019
- Authors: Nkanga, Christian Isalomboto
- Date: 2019
- Subjects: Tuberculosis -- Chemotherapy , Lipsomes , Drug carriers (Pharmacy) , Rifampin , Hydrogen-ion concentration , Hydrogen-ion concentration -- Physiological effect
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/125832 , vital:35822
- Description: Tuberculosis (TB) is an infectious disease that has been reported to be the ninth leading cause of death worldwide, even though mostly considered as a poverty related disease. Despite the existence of potent anti-tubercular drugs (ATBDs), such as rifampicin (RIF) and isoniazid (INH), TB remains the major killer among many microbial diseases over the last five years. Although several factors are to be blamed for this deadly status, the most crucial issues encompass both the self-defensiveness of the causative agent (Mycobacterium tuberculosis), including its intra-macrophage location that compromises ATBDs accessibility, and the widespread/off target distribution of ATBDs. The need for novel drug delivery strategies therefore arises to provide selective distribution of ATBDs at the infected site. Among the drug vehicles explored in this field, liposomes have been reported to be the most suitable drug carriers due to their rapid uptake by alveolar macrophages, where M. tuberculosis often resides. Since liposomes experience media of different pH throughout the cell uptake process (endocytosis/phagocytosis), the use of pH change as a stimulus for controlled release looks promising for enhancing intra-macrophage delivery and minimizing premature ‘off-target’ release of ATBDs. However, the costly status of liposome technology, due to the use of sophisticated procedures and expensive materials (especially for pH-dependent delivery, where special lipids are required), may preclude wider developments of liposomal products, especially for the developing world. This study aimed at investigating liposomal encapsulation of pH-sensitive and fluorescent hydrazone derivatives of INH using crude soybean lecithin, as a cost-effective option for site-specific delivery combined with potential bio-imaging features. Another objective was to explore encapsulation of INH hydrazone derivatives with and without RIF in liposomes using a simple and organic solvent-free preparation method. Initially, INH was coupled with 4-hydroxy-benzaldehyde to yield a conjugate (INH-HB) that was encapsulated in liposomes using film hydration method with acceptable encapsulation efficiency (î), about 89 %. The prepared INH-HB loaded liposomes (IHL) were characterized by means of dynamic light scattering (DLS), transmission electron microscopy (TEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The release of INH from IHL was evaluated over 12 hours in media of different pH using dialysis. As hypothesized, pH dependent release of INH from IHL was observed with 22, 69, 83 and 100 % release obtained in media of pH 7.4, 6.4, 5.4 and 4.4, respectively. From this experimental trial, further development was undertaken by conjugating INH to a hydrophobic fluorescent tag, zinc (II) phthalocyanine (PC), through hydrazone linkages. The obtained conjugate (PC-INH) was loaded into liposomes (PIL) that were characterized using various spectroscopic techniques, including UV-Vis absorption and energy dispersive X-ray spectroscopy, which suggested the presence of PC-INH within the lipid bilayers. The release study performed in different pH media revealed 22, 41, 97 and 100 % of INH, respectively released at pH 7.4, 6.4, 5.4 and 4.4. This confirmed the potential of pH-triggered drug release from liposomes loaded with hydrazone drug derivatives. In addition, successful encapsulation of PC-INH using crude soybean lecithin inspired a new opening towards development of multimodal liposomes that could achieve controlled drug release with added benefits of image-guided biological tracking. However, the hydrophobic nature of PC-INH requires an effective strategy that could improve its solubility and favour extensive development. In this context, the tetra-substituted structure of PC-INH brought up the hypothesis that cyclodextrin (CD) complexation would facilitate PC-INH encapsulation in liposomes using an organic solvent-free method, called here the “heating method” (HM). Inclusion complexes of PC-INH with various CDs were therefore investigated, with gamma-CD complex (CP) giving the best results. These complexes were prepared in both solution and solid-state and further comprehensively characterized using UV-Vis spectroscopy, magnetic circular dichroism, NMR spectroscopy, diffusion ordered spectroscopy, DSC, XRD and Fourier transform infrared spectroscopy. CP-loaded liposomes prepared using HM exhibited greater î than film hydration liposomes, about 70 % versus 56 %, respectively. The HM-liposomal system (CPL) exhibited potentially useful nano particulate characteristics (i.e. mean particle size 240 nm and Zeta potential –57 mV), which remained unchanged over 5 weeks of stability study at 4 °C, and pH-dependent INH release behaviour alike PIL. Furthermore, CP was co-encapsulated with rifampicin (RIF) in liposomes using HM to investigate the possibility for future combination therapy. 1H-NMR spectroscopy, DSC, XRD and photophysical studies were performed for molecular assessment of the cargo in CP-RIF co-loaded liposomes (CPRL). The mean particle size, Zeta potential and î of CPRL were respectively 594 nm, –50 mV, 58 % for CP and 86 % for RIF. CPRL exhibited much higher release rates for both INH and RIF at pH 6.4, compared to those tested at pH 7.4. In addition, there was no cytotoxicity on HeLa cells, but attractive lung fibroblasts and epithelial cells uptake and viability. Hence, CPRL are promising for targeted ATBD delivery to alveolar macrophages following pulmonary administration. Overall, the developed pH-responsive liposomal system holds the promise for new openings towards wider developments of multifunctional liposomes for site-specific controlled pulmonary delivery of antimicrobials drugs.
- Full Text:
- Date Issued: 2019
Photophysical properties and photodynamic therapy activities of symmetrical and asymmetrical porphyrins embedded into Pluronic polymer micelles and nonlinear optical properties of an asymmetrical phthalocyanine
- Authors: Managa, Muthumuni Elizabeth
- Date: 2019
- Subjects: Porphyrins , Phthalocyanines
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/67625 , vital:29122
- Description: This work reports on the synthesis of symmetrical and asymmetrical novel porphyrins that have been incorporated into Pluronic polymers, as well as the synthesis of asymmetrical phthalocyanine. The new compounds were characterized by elemental analysis, Fourier-transform infrared spectroscopy (FT-IR), proton nuclear magnetic resonance (1H NMR), mass spectrometry and UV–Visible spectroscopy. The porphyrins that are synthesised were not water soluble but upon incorporating into Pluronic polymer micelles, they became water soluble. The polymer was also modified and linked to folic acid, to enhance selectivity for photodynamic therapy application, where MCF7 breast cancer cells were used. The singlet oxygen quantum yields were lower for the metal free porphyrins as compared to metalled ones due to the heavy atom effect of ClGa, Zn and Cl2Si in the latter which encourages intersystem crossing to the triplet state. Singlet oxygen quantum yields for water soluble derivatives increased upon being encapsulated into the micelles for all. The Stern-Volmer constant (Ksv), binding constant (Kb) and number of binding sites (n) were investigated in order to understand the interaction between the polymer micelles and the porphyrins, and it was showed that the central metals play a role in the manner which the porphyrin interacts with the micelles. The dark toxicity and photodynamic activity of the novel porphyrins upon encapsulating to Pluronic polymer micelles is also reported. There was minimal dark toxicity for all complexes with > 90% cell survival. The photodynamic activity of water insoluble porphyrins improved when encapsulated into the micelles. Novel asymmetrical phthalocyanines were also synthesised for nonlinear optics (NLO) studies in solution and thin films.
- Full Text:
- Date Issued: 2019
- Authors: Managa, Muthumuni Elizabeth
- Date: 2019
- Subjects: Porphyrins , Phthalocyanines
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/67625 , vital:29122
- Description: This work reports on the synthesis of symmetrical and asymmetrical novel porphyrins that have been incorporated into Pluronic polymers, as well as the synthesis of asymmetrical phthalocyanine. The new compounds were characterized by elemental analysis, Fourier-transform infrared spectroscopy (FT-IR), proton nuclear magnetic resonance (1H NMR), mass spectrometry and UV–Visible spectroscopy. The porphyrins that are synthesised were not water soluble but upon incorporating into Pluronic polymer micelles, they became water soluble. The polymer was also modified and linked to folic acid, to enhance selectivity for photodynamic therapy application, where MCF7 breast cancer cells were used. The singlet oxygen quantum yields were lower for the metal free porphyrins as compared to metalled ones due to the heavy atom effect of ClGa, Zn and Cl2Si in the latter which encourages intersystem crossing to the triplet state. Singlet oxygen quantum yields for water soluble derivatives increased upon being encapsulated into the micelles for all. The Stern-Volmer constant (Ksv), binding constant (Kb) and number of binding sites (n) were investigated in order to understand the interaction between the polymer micelles and the porphyrins, and it was showed that the central metals play a role in the manner which the porphyrin interacts with the micelles. The dark toxicity and photodynamic activity of the novel porphyrins upon encapsulating to Pluronic polymer micelles is also reported. There was minimal dark toxicity for all complexes with > 90% cell survival. The photodynamic activity of water insoluble porphyrins improved when encapsulated into the micelles. Novel asymmetrical phthalocyanines were also synthesised for nonlinear optics (NLO) studies in solution and thin films.
- Full Text:
- Date Issued: 2019
Physicochemical properties and photodynamic therapy activities of indium and zinc phthalocyanine-nanoparticle conjugates
- Authors: Dube, Edith
- Date: 2019
- Subjects: Indium , Zinc , Phthalocyanines , Breast -- Cancer -- Photochemotherapy , Nanoparticles
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76506 , vital:30589
- Description: The syntheses and characterization of symmetric and asymmetric Pcs functionalized at the peripheral position are reported. The Pcs contain either zinc or indium as central metals and have carboxyphenoxy, phenoxy propanoic acid, benzothiazole phenoxy, thiophine ethoxy or di-O-isopropylidene-α-D-glucopyranose as ring substituents. The Pcs were linked to NPs via an amide bond or through self-assembly. The photophysics and photochemistry of the Pcs were assessed when alone and with conjugates. All the studied Pcs showed good photophysicochemical behaviour with relatively high triplet and singlet oxygen quantum yields corresponding to their low fluorescence quantum yield. The Pcs with indium in their central cavity exhibited higher triplet and singlet oxygen quantum yields in comparison to their zinc counterparts due to the heavy–atom effect obtained from the former. Asymmetrical Pcs displayed higher triplet and singlet oxygen quantum yields than their symmetrical counterparts. The triplet quantum yield, generally increased on linkage to nanoparticles (NPs) due to the heavy–atom effect of gold and silver in NPs. The conjugates to gold nanospheres yielded higher triplet and singlet quantum yields than their gold nanotriangles counterparts due to the higher loading by the former probably encouraged by their relatively small particle size. The in vitro dark cytotoxicity and photodynamic therapy of selected Pc complexes and conjugates against MCF-7 cells was tested. All studied Pc complexes and conjugates showed minimum dark toxicity making them applicable for PDT. All complexes displayed poor phototoxicity with >50Îll viability at concentrations≤ 160μg/mL, however the conjugates showed<50% cell viabilityatconcentrations≤ 160μg/mLprobably due to the enhanced singlet oxygen quantum yield. The findings from this work show the importance of linking photosensitises such as phthalocyanines to metal nanoparticles for the enhancement ofsinglet oxygen quantum yield and ultimately the photodynamic effect.
- Full Text:
- Date Issued: 2019
- Authors: Dube, Edith
- Date: 2019
- Subjects: Indium , Zinc , Phthalocyanines , Breast -- Cancer -- Photochemotherapy , Nanoparticles
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76506 , vital:30589
- Description: The syntheses and characterization of symmetric and asymmetric Pcs functionalized at the peripheral position are reported. The Pcs contain either zinc or indium as central metals and have carboxyphenoxy, phenoxy propanoic acid, benzothiazole phenoxy, thiophine ethoxy or di-O-isopropylidene-α-D-glucopyranose as ring substituents. The Pcs were linked to NPs via an amide bond or through self-assembly. The photophysics and photochemistry of the Pcs were assessed when alone and with conjugates. All the studied Pcs showed good photophysicochemical behaviour with relatively high triplet and singlet oxygen quantum yields corresponding to their low fluorescence quantum yield. The Pcs with indium in their central cavity exhibited higher triplet and singlet oxygen quantum yields in comparison to their zinc counterparts due to the heavy–atom effect obtained from the former. Asymmetrical Pcs displayed higher triplet and singlet oxygen quantum yields than their symmetrical counterparts. The triplet quantum yield, generally increased on linkage to nanoparticles (NPs) due to the heavy–atom effect of gold and silver in NPs. The conjugates to gold nanospheres yielded higher triplet and singlet quantum yields than their gold nanotriangles counterparts due to the higher loading by the former probably encouraged by their relatively small particle size. The in vitro dark cytotoxicity and photodynamic therapy of selected Pc complexes and conjugates against MCF-7 cells was tested. All studied Pc complexes and conjugates showed minimum dark toxicity making them applicable for PDT. All complexes displayed poor phototoxicity with >50Îll viability at concentrations≤ 160μg/mL, however the conjugates showed<50% cell viabilityatconcentrations≤ 160μg/mLprobably due to the enhanced singlet oxygen quantum yield. The findings from this work show the importance of linking photosensitises such as phthalocyanines to metal nanoparticles for the enhancement ofsinglet oxygen quantum yield and ultimately the photodynamic effect.
- Full Text:
- Date Issued: 2019
Plants, people, and place: complex, mutualistic, and co-evolving global patterns through time
- Authors: Van Wijk, Yvette Ethné
- Date: 2019
- Subjects: Ethnobotany -- South Africa -- Western Cape , Khoisan (African people) -- Ethnobotany , Human-plant relationships -- South Africa -- Western Cape , Plants -- Classification -- South Africa -- Western Cape , Plant remains (Archaeology) -- South Africa -- Western Cape , Ethnoscience -- South Africa -- Western Cape , Regression analysis
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76575 , vital:30609
- Description: My thesis studies and analyses the suite of distinctive plant taxa which persist in small patches of vegetation growing in close association with archaeological habitation sites in the southern Cape, South Africa. The unexpected correlation and overlap between botanical taxa collected at 75 site complexes, and ethnobotanical data collected in collaboration with modern Khoi-San communities in the same area, is explored and interrogated. Although sparse, reports of the same suite of taxa recovered from archaeological excavations in the Cape provinces provides depth of time to the study, linking the past to the present. The three-way correlation of a suite of plants closely associated with humans and habitation sites through time, allows for triangulation of the data in order to validate and cross verify the results using more than one frame of reference. Both the plants and the knowledge about their uses have persisted in spite of historical attrition, and alienation of land and language, suffered by the Khoi-San over the past 300 years. Drawing on a large body of primary and secondary data, and using an interdisciplinary, abductive and pragmatic mixed methods approach, a pattern can be traced throughout Africa and globally. Regression analysis strongly indicates that the most ubiquitous taxa were selected for a purpose and are not randomly present in association with humans. Botanical, anthropological, and archaeological studies seldom focus on the inter-connectedness of people and plants at the sites they inhabited. Very little research into modern vegetation in close association with the sites has been undertaken, and vegetation mapping has not captured the occurrence of these site-specific small vegetation patches recorded during my surveys. The topographically, geologically, and vegetatively complex and varied southern Cape, and greater Cape area, is extremely rich in archaeological sites and history. This study suggests that the value of site-specific plant taxa to humans throughout the aeons of pre-agricultural history, persists into the present. Due to tolerance of a broad range of climatic and environmental variables, there is value in the study of these ancient and neglected useful plants in the face of climate change. That this vegetation is so closely associated with archaeological sites of cultural and historic importance confers an urgency to recognising the existence and significance of the distinctive and possibly anthropogenic vegetation surrounding the sites.
- Full Text:
- Date Issued: 2019
- Authors: Van Wijk, Yvette Ethné
- Date: 2019
- Subjects: Ethnobotany -- South Africa -- Western Cape , Khoisan (African people) -- Ethnobotany , Human-plant relationships -- South Africa -- Western Cape , Plants -- Classification -- South Africa -- Western Cape , Plant remains (Archaeology) -- South Africa -- Western Cape , Ethnoscience -- South Africa -- Western Cape , Regression analysis
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76575 , vital:30609
- Description: My thesis studies and analyses the suite of distinctive plant taxa which persist in small patches of vegetation growing in close association with archaeological habitation sites in the southern Cape, South Africa. The unexpected correlation and overlap between botanical taxa collected at 75 site complexes, and ethnobotanical data collected in collaboration with modern Khoi-San communities in the same area, is explored and interrogated. Although sparse, reports of the same suite of taxa recovered from archaeological excavations in the Cape provinces provides depth of time to the study, linking the past to the present. The three-way correlation of a suite of plants closely associated with humans and habitation sites through time, allows for triangulation of the data in order to validate and cross verify the results using more than one frame of reference. Both the plants and the knowledge about their uses have persisted in spite of historical attrition, and alienation of land and language, suffered by the Khoi-San over the past 300 years. Drawing on a large body of primary and secondary data, and using an interdisciplinary, abductive and pragmatic mixed methods approach, a pattern can be traced throughout Africa and globally. Regression analysis strongly indicates that the most ubiquitous taxa were selected for a purpose and are not randomly present in association with humans. Botanical, anthropological, and archaeological studies seldom focus on the inter-connectedness of people and plants at the sites they inhabited. Very little research into modern vegetation in close association with the sites has been undertaken, and vegetation mapping has not captured the occurrence of these site-specific small vegetation patches recorded during my surveys. The topographically, geologically, and vegetatively complex and varied southern Cape, and greater Cape area, is extremely rich in archaeological sites and history. This study suggests that the value of site-specific plant taxa to humans throughout the aeons of pre-agricultural history, persists into the present. Due to tolerance of a broad range of climatic and environmental variables, there is value in the study of these ancient and neglected useful plants in the face of climate change. That this vegetation is so closely associated with archaeological sites of cultural and historic importance confers an urgency to recognising the existence and significance of the distinctive and possibly anthropogenic vegetation surrounding the sites.
- Full Text:
- Date Issued: 2019
Pyramidal deliberative democracy
- Authors: Danielsen, James
- Date: 2019
- Subjects: Democracy , Information technology -- Political aspects , Internet in public administration , Political participation -- Computer network resources , World politics
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/74502 , vital:30309
- Description: This dissertation has two main objectives. First, to outline an ICT-facilitated model of democracy called ‘pyramidal democracy’ that reconciles deliberative democracy with mass engagement. Second, to suggest how this model of democracy might engender the democratisation of the global economy and thus the provision of a basic level of economic security for all global citizens. At the core of the model is the pyramidal deliberative network, a means of organising citizens into small online deliberative groups and linking these groups together by means of an iterative process of delegate-selection and group-formation. The pyramidal network enables citizens to aggregate their preferences in a deliberative manner, and then project social power by authorizing the delegates at the top-tier of the pyramidal network to communicate their social demands to elected officials or to other points of authority. The envisioned outcome is the democratisation of the public sphere by means of the proliferation of deliberative networks in the government, market, and civil society spheres. Transnational pyramidal networks may make it feasible to instantiate a new citizen-based schema of global governance and, thereby, facilitate the reform of the United Nations and enable a transition towards global peace, sustainability, and distributive justice. Distributive justice might be achieved by means of implementing the six components of a democratised economy: participatory budgeting, fee-and-dividend taxes, a basic income, monetary reform, workplace democracy, and the sharing economy. Taken together, these components might enable the universal provision of a social minimum – a universal basic income sufficient for basic security and real freedom. Taken to its logical conclusion, a democratised economy may also enable a transition towards a post-scarcity economic order characterised by a maximal stock of humanmade and natural capital that would not exceed the sustainable carrying capacity of the earth.
- Full Text:
- Date Issued: 2019
- Authors: Danielsen, James
- Date: 2019
- Subjects: Democracy , Information technology -- Political aspects , Internet in public administration , Political participation -- Computer network resources , World politics
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/74502 , vital:30309
- Description: This dissertation has two main objectives. First, to outline an ICT-facilitated model of democracy called ‘pyramidal democracy’ that reconciles deliberative democracy with mass engagement. Second, to suggest how this model of democracy might engender the democratisation of the global economy and thus the provision of a basic level of economic security for all global citizens. At the core of the model is the pyramidal deliberative network, a means of organising citizens into small online deliberative groups and linking these groups together by means of an iterative process of delegate-selection and group-formation. The pyramidal network enables citizens to aggregate their preferences in a deliberative manner, and then project social power by authorizing the delegates at the top-tier of the pyramidal network to communicate their social demands to elected officials or to other points of authority. The envisioned outcome is the democratisation of the public sphere by means of the proliferation of deliberative networks in the government, market, and civil society spheres. Transnational pyramidal networks may make it feasible to instantiate a new citizen-based schema of global governance and, thereby, facilitate the reform of the United Nations and enable a transition towards global peace, sustainability, and distributive justice. Distributive justice might be achieved by means of implementing the six components of a democratised economy: participatory budgeting, fee-and-dividend taxes, a basic income, monetary reform, workplace democracy, and the sharing economy. Taken together, these components might enable the universal provision of a social minimum – a universal basic income sufficient for basic security and real freedom. Taken to its logical conclusion, a democratised economy may also enable a transition towards a post-scarcity economic order characterised by a maximal stock of humanmade and natural capital that would not exceed the sustainable carrying capacity of the earth.
- Full Text:
- Date Issued: 2019
Reading to learn for secondary schooling: an interventionist action research study within a South African under-privileged setting
- Authors: Mataka, Tawanda Wallace
- Date: 2019
- Subjects: Rose, David, 1955-. Reading to learn , Reading (Secondary) , English language -- Study and teaching (Secondary) -- Foreign speakers -- South Africa , English language -- Study and teaching (Secondary) -- Foreign speakers -- South Africa -- Case studies , Literacy -- South Africa -- Makhanda
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92191 , vital:30706
- Description: The study examined the contribution that Rose’s (2005) Reading to Learn (RtL) methodology made in development of advanced literacy abilities recommended in the schooling system. RtL was influenced by Bernstein’s theory of pedagogic discourse, Bruner, Vygotsky’s social learning theory and Halliday’s systemic functional linguistics theory. The study used the same cohort of learners during Grades 11 and 12 in a black township secondary school in Grahamstown, Eastern Cape, South Africa. RtL was birthed in Australia with the intention of accelerating literacy development of learners in disadvantaged communities. Based on its success in Australia, I implemented the methodology against a backdrop of continuously declining literacy standards in South African primary and secondary schools. Researchers on literacy acknowledge that socioeconomic and geosocial circumstances cannot be divorced from poor literacy performances in South African schools. Although these two factors play a role in regressing literacy, pedagogical approaches play a role. RtL was employed as an intervention strategy with learners whose literacy abilities were found lacking in comparison to curriculum demands. Despite the focus being on learners whose performance was below expected academic levels, the able learners were motivated to further their advanced abilities. The learners whose performance was previously compromised performed to par with their able counterparts. RtL provided all learners an opportunity to apply, with less difficulty, the language approved by the schooling system. The two research questions sought to illuminate the role RtL played in developing learners’ ability to read, so that they could converse with text and put into writing practice what they had read. In this regard, creative and transactional assignments were written, and performance assessed to evaluate the RtL intervention. Secondly, the research allowed me to get an insight through interviews with learners as to how they were positively or negatively influenced through RtL in learning English as a First Additional Language. The study was a longitudinal action research study which had a life span of 22 months. It was dominantly qualitative with a thin quantitative strand. Data to evaluate effectiveness was generated from learners’ written work and interviews. The learners’ work was analysed using an RtL assessment tool adopted from Rose (2018), for the purposes of uniformity and reliability. Findings from interviews highlighted various views regarding the positive impact of RtL. What emerged from the findings is a reflection of the positive impact RtL had on literacy development. Significantly, learners’ work improved across the board, true to Rose’s assertion that learners exposed to teaching using RtL principles experience accelerated literacy development. Based on these findings, RtL implemented in a township setting in South Africa yields results similar to those in Australia and other countries.
- Full Text:
- Date Issued: 2019
- Authors: Mataka, Tawanda Wallace
- Date: 2019
- Subjects: Rose, David, 1955-. Reading to learn , Reading (Secondary) , English language -- Study and teaching (Secondary) -- Foreign speakers -- South Africa , English language -- Study and teaching (Secondary) -- Foreign speakers -- South Africa -- Case studies , Literacy -- South Africa -- Makhanda
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92191 , vital:30706
- Description: The study examined the contribution that Rose’s (2005) Reading to Learn (RtL) methodology made in development of advanced literacy abilities recommended in the schooling system. RtL was influenced by Bernstein’s theory of pedagogic discourse, Bruner, Vygotsky’s social learning theory and Halliday’s systemic functional linguistics theory. The study used the same cohort of learners during Grades 11 and 12 in a black township secondary school in Grahamstown, Eastern Cape, South Africa. RtL was birthed in Australia with the intention of accelerating literacy development of learners in disadvantaged communities. Based on its success in Australia, I implemented the methodology against a backdrop of continuously declining literacy standards in South African primary and secondary schools. Researchers on literacy acknowledge that socioeconomic and geosocial circumstances cannot be divorced from poor literacy performances in South African schools. Although these two factors play a role in regressing literacy, pedagogical approaches play a role. RtL was employed as an intervention strategy with learners whose literacy abilities were found lacking in comparison to curriculum demands. Despite the focus being on learners whose performance was below expected academic levels, the able learners were motivated to further their advanced abilities. The learners whose performance was previously compromised performed to par with their able counterparts. RtL provided all learners an opportunity to apply, with less difficulty, the language approved by the schooling system. The two research questions sought to illuminate the role RtL played in developing learners’ ability to read, so that they could converse with text and put into writing practice what they had read. In this regard, creative and transactional assignments were written, and performance assessed to evaluate the RtL intervention. Secondly, the research allowed me to get an insight through interviews with learners as to how they were positively or negatively influenced through RtL in learning English as a First Additional Language. The study was a longitudinal action research study which had a life span of 22 months. It was dominantly qualitative with a thin quantitative strand. Data to evaluate effectiveness was generated from learners’ written work and interviews. The learners’ work was analysed using an RtL assessment tool adopted from Rose (2018), for the purposes of uniformity and reliability. Findings from interviews highlighted various views regarding the positive impact of RtL. What emerged from the findings is a reflection of the positive impact RtL had on literacy development. Significantly, learners’ work improved across the board, true to Rose’s assertion that learners exposed to teaching using RtL principles experience accelerated literacy development. Based on these findings, RtL implemented in a township setting in South Africa yields results similar to those in Australia and other countries.
- Full Text:
- Date Issued: 2019
Regional thickening as game-changing: examining transnational activities of gender and women-focused civil society actors for region-building in Southern Africa
- Authors: Nedziwe, Cecilia Lwiindi
- Date: 2019
- Subjects: International relations , Southern Africa Development Community , Regionalism -- Africa, Southern , Africa, Southern -- Foreign relations -- 1994- , Women in development -- Africa, Southern , Women -- Social conditions -- Africa, Southern , Women -- Political activity -- Africa, Southern , Women in public life -- Africa, Southern , Civil society -- Africa, Southern
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/95420 , vital:31154
- Description: This thesis argues that norms, in general, have proliferated in a neo-liberalising context since the 1990s, in particular norms on gender, and how they have changed to indicate new agency and influence, amounts to game change. Despite growing transnational activities, regionalisation and the increasing interface between state and non-state regionalism in a transnational context since the advent of liberalisation and democratisation, analyses in regional International Relations (IR) studies, so far, largely maintain linear logic. The increasing non-state processes, and their connection to state processes in norm creation, norm adaptation, norm diffusion and implementation around broad questions of security including in the area of gender, amount to regional thickening. Regional thickening revealed in terms of increasing regionalisation, regionalism, and region-ness whose effect is game-changing challenges mainstream linear approaches in regional IR studies. Game-changing here, refers to, processes promoting the development of norms mentioned above in the interest of contributing to improved security across a region. This study is focused on Southern Africa, defined here, as the Southern African Development Community (SADC) region. This study’s analytical approach is informed by alternatives to mainstream approaches, emphasising processes, rather than linearity inherent in regional IR studies. By privileging the actual game-changing processes, interactions, and agency around the norm development cycle, this study examines how regional thickening in a transnational context promotes game-changing activities, promoting the development of the norm cycle, seeking to have improved security. A mixed method approach involving gathering of information from multiple primary and secondary sources are used. The study found transnational activities and regionalisation of gender and women-focused civil society actors, game-changing. These civil society actors organised in two ways. First, by way of advocacy and in seeking representation within intergovernmental policymaking structures at a regional level. Second, by way of organising around transnational communities in a transnational context in the interest of addressing gendered insecurities at localised levels. Regional thickening as game-changing here pointed to a growing recognition and participation of civil society actors in intergovernmental policymaking spaces as having created a groundswell for game change at localised levels. This led to policy development, adaptation, diffusion, and implementation by both state and non-state actors contributing to norm changes, improved social policies, and to greater security. The actual changes emerging from these actors’ activities on the ground are in terms of unlearning patriarchal behaviours, opening up development for women, and increasing their living standards, education, health, and their freedom. In assessing the transnational environment on gendered insecurity in Southern Africa, this thesis developed an innovative framework of regional thickening as game-changing. This framework plots how game-changing developed, evolved, and its importance in addressing gendered insecurity. The thesis has proposed that game-changing transnational activities and regionalisation that change, and diffuse norms to break learnt behaviour, have helped disrupt rigid institutionalisation, and are aiding to bring non-linear discourses to the fore.
- Full Text:
- Date Issued: 2019
- Authors: Nedziwe, Cecilia Lwiindi
- Date: 2019
- Subjects: International relations , Southern Africa Development Community , Regionalism -- Africa, Southern , Africa, Southern -- Foreign relations -- 1994- , Women in development -- Africa, Southern , Women -- Social conditions -- Africa, Southern , Women -- Political activity -- Africa, Southern , Women in public life -- Africa, Southern , Civil society -- Africa, Southern
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/95420 , vital:31154
- Description: This thesis argues that norms, in general, have proliferated in a neo-liberalising context since the 1990s, in particular norms on gender, and how they have changed to indicate new agency and influence, amounts to game change. Despite growing transnational activities, regionalisation and the increasing interface between state and non-state regionalism in a transnational context since the advent of liberalisation and democratisation, analyses in regional International Relations (IR) studies, so far, largely maintain linear logic. The increasing non-state processes, and their connection to state processes in norm creation, norm adaptation, norm diffusion and implementation around broad questions of security including in the area of gender, amount to regional thickening. Regional thickening revealed in terms of increasing regionalisation, regionalism, and region-ness whose effect is game-changing challenges mainstream linear approaches in regional IR studies. Game-changing here, refers to, processes promoting the development of norms mentioned above in the interest of contributing to improved security across a region. This study is focused on Southern Africa, defined here, as the Southern African Development Community (SADC) region. This study’s analytical approach is informed by alternatives to mainstream approaches, emphasising processes, rather than linearity inherent in regional IR studies. By privileging the actual game-changing processes, interactions, and agency around the norm development cycle, this study examines how regional thickening in a transnational context promotes game-changing activities, promoting the development of the norm cycle, seeking to have improved security. A mixed method approach involving gathering of information from multiple primary and secondary sources are used. The study found transnational activities and regionalisation of gender and women-focused civil society actors, game-changing. These civil society actors organised in two ways. First, by way of advocacy and in seeking representation within intergovernmental policymaking structures at a regional level. Second, by way of organising around transnational communities in a transnational context in the interest of addressing gendered insecurities at localised levels. Regional thickening as game-changing here pointed to a growing recognition and participation of civil society actors in intergovernmental policymaking spaces as having created a groundswell for game change at localised levels. This led to policy development, adaptation, diffusion, and implementation by both state and non-state actors contributing to norm changes, improved social policies, and to greater security. The actual changes emerging from these actors’ activities on the ground are in terms of unlearning patriarchal behaviours, opening up development for women, and increasing their living standards, education, health, and their freedom. In assessing the transnational environment on gendered insecurity in Southern Africa, this thesis developed an innovative framework of regional thickening as game-changing. This framework plots how game-changing developed, evolved, and its importance in addressing gendered insecurity. The thesis has proposed that game-changing transnational activities and regionalisation that change, and diffuse norms to break learnt behaviour, have helped disrupt rigid institutionalisation, and are aiding to bring non-linear discourses to the fore.
- Full Text:
- Date Issued: 2019
Responding to iconic images of risk through reflexive and narrative enquiry represented in a stratified text for environmental education readers
- Authors: Murphy, Mary
- Date: 2019
- Subjects: Sustainability -- Study and teaching , Environmental education -- Philosophy , Environmental degradation -- Study and teaching , Environmental degradation -- Philosophy , Reflection (Philosophy) , Archer, Margaret S (Margaret Scotford). Structure, agency, and the internal conversation
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/96768 , vital:31318
- Description: This thesis presents a stratified textual strategy to represent meaning developed through reflexive and narrative enquiry of environmental risk. Meaning that emerged in responses to iconic images of risk. Umberto Eco cautioned that iconic images over time become conventional taking over from that which they represent. Representations of risk become embedded through cultural coding. Semiotic theory provided access to the contextual and cultural content of environmental education as experienced during professional work as a radio presenter of “Environmental Matters”, as an environmental educator and activist. Methodological rigour was applied through the application of Margaret Archer's theory of the internal conversation and use of an online content management system. Both the reflexive tool of the internal conversation and the textual mechanism of the blog encouraged commitment to Paul Hart's criteria of trustworthiness and authenticity in the process of building the semiotic structure of the PhD. The Internal Conversation was used as a mediating tool in the PhD process and is presented in practice. Rethinking environmental risk from other species' perspectives through imagined experience was achieved through narrative enquiry. A noted anthropocentric limitation of the inability to interview animals for their experience of human-imposed risk was mitigated through representing the imagined, possible perspectives through story, which invites the reader to join the meaning-making process and open up discussions for and about environmental issues and action. This noted anthropocentrism was evident in debates among the characters about violence and non-violence as a conditioned theme and topic discussed in previous academic research about terrorism in divided societies. The story illustrates how the main character, a penguin called Polo, navigates through emerging meaning within a structure that confronts him with choices that end with a decision to become an agent for change. This story is a narrative example of the morphogenetic process. The multi-textual strategy presents possible methods for the exploration of risk (Vol. 1), reflexivity (Vol. 2) and representation (Vol. 3) for the application and contribution in/to environmental education.
- Full Text:
- Date Issued: 2019
- Authors: Murphy, Mary
- Date: 2019
- Subjects: Sustainability -- Study and teaching , Environmental education -- Philosophy , Environmental degradation -- Study and teaching , Environmental degradation -- Philosophy , Reflection (Philosophy) , Archer, Margaret S (Margaret Scotford). Structure, agency, and the internal conversation
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/96768 , vital:31318
- Description: This thesis presents a stratified textual strategy to represent meaning developed through reflexive and narrative enquiry of environmental risk. Meaning that emerged in responses to iconic images of risk. Umberto Eco cautioned that iconic images over time become conventional taking over from that which they represent. Representations of risk become embedded through cultural coding. Semiotic theory provided access to the contextual and cultural content of environmental education as experienced during professional work as a radio presenter of “Environmental Matters”, as an environmental educator and activist. Methodological rigour was applied through the application of Margaret Archer's theory of the internal conversation and use of an online content management system. Both the reflexive tool of the internal conversation and the textual mechanism of the blog encouraged commitment to Paul Hart's criteria of trustworthiness and authenticity in the process of building the semiotic structure of the PhD. The Internal Conversation was used as a mediating tool in the PhD process and is presented in practice. Rethinking environmental risk from other species' perspectives through imagined experience was achieved through narrative enquiry. A noted anthropocentric limitation of the inability to interview animals for their experience of human-imposed risk was mitigated through representing the imagined, possible perspectives through story, which invites the reader to join the meaning-making process and open up discussions for and about environmental issues and action. This noted anthropocentrism was evident in debates among the characters about violence and non-violence as a conditioned theme and topic discussed in previous academic research about terrorism in divided societies. The story illustrates how the main character, a penguin called Polo, navigates through emerging meaning within a structure that confronts him with choices that end with a decision to become an agent for change. This story is a narrative example of the morphogenetic process. The multi-textual strategy presents possible methods for the exploration of risk (Vol. 1), reflexivity (Vol. 2) and representation (Vol. 3) for the application and contribution in/to environmental education.
- Full Text:
- Date Issued: 2019
Rural food security in Mutare District, Zimbabwe, 1947-2010
- Authors: Kusena, Bernard
- Date: 2019
- Subjects: Mutare (Zimbabwe) -- History , Zimbabwe -- History , Food security -- Zimbabwe , Poverty -- Zimbabwe , Rural pooer -- Zimbabwe , Crop losses -- Zimbabwe , Food relief -- Zimbabwe
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92865 , vital:30757
- Description: By taking Mutare District as its lens to explore the dynamics of rural food security in Zimbabwe, this thesis assesses the role of the state in tackling hunger among its rural populations. It examines the impact of colonial and post-colonial food policy on efforts to combat food insecurity. The thesis explores the uneasy options pursued by rural communities in response to droughts and other threats of hunger. It identifies and ranks crop failure as the chief culprit to the district’s efforts towards food security. The thesis illustrates the contestations between the state and its rural people over which sustainable approaches to adopt in order to end hunger and how such debates continually shaped policy. It grapples with questions about the various understandings of food security advanced by scholars within the rural African context. It demonstrates, for instance, that the post-colonial state inherited an erstwhile crop production structure which shunned food crops in favour of cash crops. There was obvious bias against local preferences for a robust, home-grown food regime which did not put rural livelihoods at risk of starvation. The thesis also argues that food can be used as an instrument of war as evidenced during the liberation struggle when the vast majority of people residing in rural areas, particularly women and children, were pushed to the edges of survival. In addition, the thesis demonstrates that the infamous Marange diamonds turned out to be a curse rather than a blessing due to the state’s lack of transparency in the beneficiation chain. It concludes by a detailed examination of the political economy of food aid, demonstrating why donors have not succeeded for long to combat hunger in the district. In light of this background, the thesis provides a more nuanced analysis of the whole question of rural food security using archival material, newspapers, government and civil society reports, interviews and field observation. The thesis benefits from the use of a multi-pronged theoretical framework to capture the disparate themes that form the bedrock of this study.
- Full Text:
- Date Issued: 2019
- Authors: Kusena, Bernard
- Date: 2019
- Subjects: Mutare (Zimbabwe) -- History , Zimbabwe -- History , Food security -- Zimbabwe , Poverty -- Zimbabwe , Rural pooer -- Zimbabwe , Crop losses -- Zimbabwe , Food relief -- Zimbabwe
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92865 , vital:30757
- Description: By taking Mutare District as its lens to explore the dynamics of rural food security in Zimbabwe, this thesis assesses the role of the state in tackling hunger among its rural populations. It examines the impact of colonial and post-colonial food policy on efforts to combat food insecurity. The thesis explores the uneasy options pursued by rural communities in response to droughts and other threats of hunger. It identifies and ranks crop failure as the chief culprit to the district’s efforts towards food security. The thesis illustrates the contestations between the state and its rural people over which sustainable approaches to adopt in order to end hunger and how such debates continually shaped policy. It grapples with questions about the various understandings of food security advanced by scholars within the rural African context. It demonstrates, for instance, that the post-colonial state inherited an erstwhile crop production structure which shunned food crops in favour of cash crops. There was obvious bias against local preferences for a robust, home-grown food regime which did not put rural livelihoods at risk of starvation. The thesis also argues that food can be used as an instrument of war as evidenced during the liberation struggle when the vast majority of people residing in rural areas, particularly women and children, were pushed to the edges of survival. In addition, the thesis demonstrates that the infamous Marange diamonds turned out to be a curse rather than a blessing due to the state’s lack of transparency in the beneficiation chain. It concludes by a detailed examination of the political economy of food aid, demonstrating why donors have not succeeded for long to combat hunger in the district. In light of this background, the thesis provides a more nuanced analysis of the whole question of rural food security using archival material, newspapers, government and civil society reports, interviews and field observation. The thesis benefits from the use of a multi-pronged theoretical framework to capture the disparate themes that form the bedrock of this study.
- Full Text:
- Date Issued: 2019
Shifting contexts, shifting identities: a realist exploration of transnational mobility, change and identity construction in South African Higher Education expatriates in Abu Dhabi, UAE.
- Authors: Reid, Gillian Janet
- Date: 2019
- Subjects: College teacher mobility , College teacher mobility -- Abū Ẓaby (United Arab Emirates) , College teachers, Foreign -- Abū Ẓaby (United Arab Emirates) , College teachers -- Psychology , Expatriation -- Psychological aspects
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92898 , vital:30760
- Description: Positioned in relation to the globalization of higher education, this realist study is approached from an interest in identity and focuses on nine South African academics professional contexts in South Africa and Abu Dhabi, UAE. As the context of identity formation and emergence is always local, the intention of this research was never to generalize. Rather, in using Bhaskar’s critical realism as its underpinning philosophy, and Archer’s social realism, theories on self, personal and the development and attainment of social identity - her concept of analytical dualism and her morphogenetic framework, this qualitative case study was designed to explore how global and national powers and mechanism effected change in this sub-group of academic’s respective higher education sectors and institutions in post- 1994 South Africa and in Abu Dhabi between 2008 and 2016. The study suggests that participants perceived their academic roles and role-incumbent professional identities to have been negatively impacted by the changes that were implemented in the South African higher education sector as a result the countries reintroduction to the global stage. Their response to become transnational educators in Abu Dhabi’s presented them with conditions that allied their professional experiences of the transformation of South African’s higher education sector. This led to a continued sense of loss of academic agency and powerlessness. This effecting the emergence, through the personal power of reflectivity, combined with discourse and affinity powers and mechanisms, in a social identity that supplanted their academic identities.
- Full Text:
- Date Issued: 2019
- Authors: Reid, Gillian Janet
- Date: 2019
- Subjects: College teacher mobility , College teacher mobility -- Abū Ẓaby (United Arab Emirates) , College teachers, Foreign -- Abū Ẓaby (United Arab Emirates) , College teachers -- Psychology , Expatriation -- Psychological aspects
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/92898 , vital:30760
- Description: Positioned in relation to the globalization of higher education, this realist study is approached from an interest in identity and focuses on nine South African academics professional contexts in South Africa and Abu Dhabi, UAE. As the context of identity formation and emergence is always local, the intention of this research was never to generalize. Rather, in using Bhaskar’s critical realism as its underpinning philosophy, and Archer’s social realism, theories on self, personal and the development and attainment of social identity - her concept of analytical dualism and her morphogenetic framework, this qualitative case study was designed to explore how global and national powers and mechanism effected change in this sub-group of academic’s respective higher education sectors and institutions in post- 1994 South Africa and in Abu Dhabi between 2008 and 2016. The study suggests that participants perceived their academic roles and role-incumbent professional identities to have been negatively impacted by the changes that were implemented in the South African higher education sector as a result the countries reintroduction to the global stage. Their response to become transnational educators in Abu Dhabi’s presented them with conditions that allied their professional experiences of the transformation of South African’s higher education sector. This led to a continued sense of loss of academic agency and powerlessness. This effecting the emergence, through the personal power of reflectivity, combined with discourse and affinity powers and mechanisms, in a social identity that supplanted their academic identities.
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- Date Issued: 2019