Revenue, trade and welfare effects of the COMESA FTA on the Democratic Republic of Congo
- Authors: Ndungo, Lusenge Patrick
- Date: 2017
- Subjects: Revenue -- Congo (Democratic Republic) -- Econometric models , Welfare economics Congo (Democratic Republic) -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/14256 , vital:27493
- Description: The present research attempts to assess the likely revenue, trade and welfare implications of the Common Market for Eastern and Southern Africa (COMESA) Free Trade Agreement (FTA) on the Democratic Republic of Congo (DRC). The study adopts a partial equilibrium model based on the World Integrated Trade Solution 2010 database and the Software for Market Analysis and Restrictions on Trade (WITS-SMART) as the methodological approach. The findings of the research reveal that the COMESA FTA will be beneficial to the DRC in terms of an increase in exports of US$371.57 million and consumer welfare gain amounting to US$28.49 million. Moreover, The WITS-SMART simulation results indicate that around US$322.10 million of trade will be created in the DRC as a result of the COMESA FTA. Notwithstanding the fact that trade creation will have a positive effect on welfare, as the Congolese consumers would benefit from lower prices, some local industries in the DRC may be threaten of closure due to the lack of competitiveness. In addition, the simultation results show that the country will experience a huge fiscal revenue loss amounting to US$107.01 million due to the implementation of zero per cent tarrif rate on imports duty from the COMESA trading partners. Finally, the simultation results indicate that an equivalent value of US$49.47 million of trade will be diverted from more efficient and low cost non-member states to high cost suppliers from the COMESA region. In light of these results, the research recommends that the DRC’s government needs to come up with a strategic plan in order to protect the national industry that would be negatively affected by the trade-creation effect. In order to mitigate the expected revenue loss, the implementation of the COMESA FTA in the DRC should be accompanied by fiscal reforms to improve the tax-collection system from sales or value-added taxes (VAT) and domestic excise. Regarding the trade-diversion effect, the inefficient producers from the COMESA region could be displaced through building new capacities in short, medium and long term based on comparative advantage in order to address supply constraints in these sectors affected by trade diversion.
- Full Text:
- Date Issued: 2017
- Authors: Ndungo, Lusenge Patrick
- Date: 2017
- Subjects: Revenue -- Congo (Democratic Republic) -- Econometric models , Welfare economics Congo (Democratic Republic) -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/14256 , vital:27493
- Description: The present research attempts to assess the likely revenue, trade and welfare implications of the Common Market for Eastern and Southern Africa (COMESA) Free Trade Agreement (FTA) on the Democratic Republic of Congo (DRC). The study adopts a partial equilibrium model based on the World Integrated Trade Solution 2010 database and the Software for Market Analysis and Restrictions on Trade (WITS-SMART) as the methodological approach. The findings of the research reveal that the COMESA FTA will be beneficial to the DRC in terms of an increase in exports of US$371.57 million and consumer welfare gain amounting to US$28.49 million. Moreover, The WITS-SMART simulation results indicate that around US$322.10 million of trade will be created in the DRC as a result of the COMESA FTA. Notwithstanding the fact that trade creation will have a positive effect on welfare, as the Congolese consumers would benefit from lower prices, some local industries in the DRC may be threaten of closure due to the lack of competitiveness. In addition, the simultation results show that the country will experience a huge fiscal revenue loss amounting to US$107.01 million due to the implementation of zero per cent tarrif rate on imports duty from the COMESA trading partners. Finally, the simultation results indicate that an equivalent value of US$49.47 million of trade will be diverted from more efficient and low cost non-member states to high cost suppliers from the COMESA region. In light of these results, the research recommends that the DRC’s government needs to come up with a strategic plan in order to protect the national industry that would be negatively affected by the trade-creation effect. In order to mitigate the expected revenue loss, the implementation of the COMESA FTA in the DRC should be accompanied by fiscal reforms to improve the tax-collection system from sales or value-added taxes (VAT) and domestic excise. Regarding the trade-diversion effect, the inefficient producers from the COMESA region could be displaced through building new capacities in short, medium and long term based on comparative advantage in order to address supply constraints in these sectors affected by trade diversion.
- Full Text:
- Date Issued: 2017
Revising the distribution of mangrove forests in South Africa and changes in growth of mangrove species along a latitudinal gradient
- Authors: Bolosha, Uviwe
- Date: 2017
- Subjects: Mangrove ecology -- South Africa , Mangrove forests -- South Africa , Mangrove plants -- South Africa -- Effect of temperature on
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7544 , vital:21271
- Description: Mangrove forests are a diverse assemblage of trees and shrubs that are adapted to a saline and tidally inundated environment. The global spread of mangrove species is affected by climate, with most confined to areas that are warmer and moist. At a global scale, temperature limits the distribution of mangrove forests but on a regional scale and local scale, rainfall, river flow and tidal exchange have a strong effect on the distribution and biomass of mangrove forests. Other factors that play a role in limiting growth and distribution of mangroves include accessibility of suitable habitats for growth and also conditions that are suitable for propagule dispersal. The objectives of this study were to review the distribution of mangroves in South Africa and determine the number of extreme temperature events that may limit further distribution and secondly to measure growth rates of mangrove species at Mngazana and Nahoon Estuary and the nutrient pools in the sediment of these forests. In 1982, Ward and Steinke published a list of estuaries where mangroves were present. The current study sampled the population structure, microclimate and level of expansion in two estuaries within and outside of the published range. The minimum, maximum temperature and number of extreme temperature events were measured using iButtons. Mangrove expansion will be limited by minimum temperatures (1.1 ° C) and an increase in extreme temperature events (830) (<5 ° C and 5- 10 ° C) at the latitudinal limits. Expansion of A. marina at Kwelera and Tyolomnqa Estuary was evident but sapling survival was low. Mangroves have expanded within and outside the range proposed by Ward and Steinke (1982), but are limited by physical factors, restricted by the presence of saltmarsh and other estuarine macrophytes and natural disturbance regimes. An increase in population growth was recorded over the years at both Mngazana and Nahoon Estuary. Nutrients, (ammonium, nitrates + nitrites and soluble reactive phosphorus) varied amongst sites and were related to seasonality. Nitrogen in both estuaries was available in the form of ammonium (NH4) and its concentration was generally higher (1.3-76.2 pm) than other forms of nitrogen (0.07-6.3 µm). Soluble reactive phosphorus (SRP) was higher during the wet seasons in both estuaries. An increase in porewater salinity since 2007 (41.3 practical salinity unit (PSU)) was measured at Mngazana and this is a result of freshwater abstraction and low rainfall. A. marina saplings and adults grew significantly faster at Nahoon Estuary (the distributional limit) (11.1 ± 1.1 cm year-¹) compared to Mngazana Estuary (5.3 ± 1.8 cm year-¹). Different mangrove species and forests respond differently to environmental factors and changes in mangrove distribution is expected in South Africa but changes are expected to happen slowly and opportunistically.
- Full Text:
- Date Issued: 2017
- Authors: Bolosha, Uviwe
- Date: 2017
- Subjects: Mangrove ecology -- South Africa , Mangrove forests -- South Africa , Mangrove plants -- South Africa -- Effect of temperature on
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7544 , vital:21271
- Description: Mangrove forests are a diverse assemblage of trees and shrubs that are adapted to a saline and tidally inundated environment. The global spread of mangrove species is affected by climate, with most confined to areas that are warmer and moist. At a global scale, temperature limits the distribution of mangrove forests but on a regional scale and local scale, rainfall, river flow and tidal exchange have a strong effect on the distribution and biomass of mangrove forests. Other factors that play a role in limiting growth and distribution of mangroves include accessibility of suitable habitats for growth and also conditions that are suitable for propagule dispersal. The objectives of this study were to review the distribution of mangroves in South Africa and determine the number of extreme temperature events that may limit further distribution and secondly to measure growth rates of mangrove species at Mngazana and Nahoon Estuary and the nutrient pools in the sediment of these forests. In 1982, Ward and Steinke published a list of estuaries where mangroves were present. The current study sampled the population structure, microclimate and level of expansion in two estuaries within and outside of the published range. The minimum, maximum temperature and number of extreme temperature events were measured using iButtons. Mangrove expansion will be limited by minimum temperatures (1.1 ° C) and an increase in extreme temperature events (830) (<5 ° C and 5- 10 ° C) at the latitudinal limits. Expansion of A. marina at Kwelera and Tyolomnqa Estuary was evident but sapling survival was low. Mangroves have expanded within and outside the range proposed by Ward and Steinke (1982), but are limited by physical factors, restricted by the presence of saltmarsh and other estuarine macrophytes and natural disturbance regimes. An increase in population growth was recorded over the years at both Mngazana and Nahoon Estuary. Nutrients, (ammonium, nitrates + nitrites and soluble reactive phosphorus) varied amongst sites and were related to seasonality. Nitrogen in both estuaries was available in the form of ammonium (NH4) and its concentration was generally higher (1.3-76.2 pm) than other forms of nitrogen (0.07-6.3 µm). Soluble reactive phosphorus (SRP) was higher during the wet seasons in both estuaries. An increase in porewater salinity since 2007 (41.3 practical salinity unit (PSU)) was measured at Mngazana and this is a result of freshwater abstraction and low rainfall. A. marina saplings and adults grew significantly faster at Nahoon Estuary (the distributional limit) (11.1 ± 1.1 cm year-¹) compared to Mngazana Estuary (5.3 ± 1.8 cm year-¹). Different mangrove species and forests respond differently to environmental factors and changes in mangrove distribution is expected in South Africa but changes are expected to happen slowly and opportunistically.
- Full Text:
- Date Issued: 2017
Revitalisation of the informal township economy in Mdantsane
- Authors: Dyantyi, Unathi Sisikelelwe
- Date: 2017
- Subjects: Informal sector (Economics) -- South Africa -- Mdantsane Economic development -- South Africa -- Mdantsane
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/15611 , vital:28276
- Description: The main focus of this study was to perform an assessment of viable and sustainable means of creating a vibrant and sustainable economy in the Mdantsane Township. In order to perform the assessment objectives were formulated which aimed at assessing whether the informal small business sector of Mdantsane was generating wealth and livelihoods for the people running them. The study also looked at whether the informal business sector is a preferred option by most South Africans or people in the townships would rather seek employment. A number of data collection methods were used in completing this study such as literature reviews and a semi-structured questionnaire. The study revealed that Local Economic development can be implemented in the townships in order to assist in stimulating a vibrant local township economy. The study also revealed that the central focus of Local Economic Development is to support the development, growth and retention of private or co-operative enterprises. The survey conducted in the study further revealed that most businesses in the township are driven by necessity in order for them to start their businesses mainly due to unemployment. These businesses all agreed on the significant role that Local Economic Development can play in assisting township entrepreneurs and communities to grow and prosper.
- Full Text:
- Date Issued: 2017
- Authors: Dyantyi, Unathi Sisikelelwe
- Date: 2017
- Subjects: Informal sector (Economics) -- South Africa -- Mdantsane Economic development -- South Africa -- Mdantsane
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/15611 , vital:28276
- Description: The main focus of this study was to perform an assessment of viable and sustainable means of creating a vibrant and sustainable economy in the Mdantsane Township. In order to perform the assessment objectives were formulated which aimed at assessing whether the informal small business sector of Mdantsane was generating wealth and livelihoods for the people running them. The study also looked at whether the informal business sector is a preferred option by most South Africans or people in the townships would rather seek employment. A number of data collection methods were used in completing this study such as literature reviews and a semi-structured questionnaire. The study revealed that Local Economic development can be implemented in the townships in order to assist in stimulating a vibrant local township economy. The study also revealed that the central focus of Local Economic Development is to support the development, growth and retention of private or co-operative enterprises. The survey conducted in the study further revealed that most businesses in the township are driven by necessity in order for them to start their businesses mainly due to unemployment. These businesses all agreed on the significant role that Local Economic Development can play in assisting township entrepreneurs and communities to grow and prosper.
- Full Text:
- Date Issued: 2017
Rhenium complexes of benzazole derivatives
- Authors: Van Niekerk, Xandri
- Date: 2017
- Subjects: Rhenium Benzimidazoles
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/21252 , vital:29467
- Description: A series of rhenium(I) complexes with monodentate benzazole ligands containing the fac-[Re(CO)3]+ was synthesized. The rhenium(I) compound [ReCl(Hmbt)2(CO)3] was prepared from the reaction of [Re(CO)5Cl] and 2-aminobenzothiazole (Hmbt) in toluene. The ligand coordinates in a monodentate manner via the thiazole nitrogen atom. A similar reaction between [Re(CO)5Cl] and N-(1,3-benzothiazol-2-yl)-2- chloroacetamide (Hbct) resulted in the formation of [ReCl(Hbct)(CO)3(NCMe)], where only one ligand binds per rhenium in a monodentate fashion. The reaction of ligands 2-mercaptobenzimidazole (Hmbi) (dibenzothiazol-2-yl)tetraazathiapentalene (Hdbt) with rhenium(I) gave [ReCl(Hmbi)2(CO)3] and [ReCl(Hdbt)2(CO)3] respectively. The study on the coordination behaviour between ethyl-(1H-benzimidazol-2-yl-sulfanyl) acetate (Hbsa) and [Re(CO)5Cl] surprisingly gave the dimeric species (μ-Cl)2[Re(Hbsa)(CO)3]2, where the two rhenium atoms are bridged by two chloro ligands. The coordination of Hbsa occurs through the imidazole nitrogen, leaving the ethoxy tail free on each Hbsa ligand. The coordination behaviour of benzimidazole and benzothiazole derivatives gave rhenium complexes in oxidation states I, III and V, where all the ligands coordinate as bidentate N,N-chelating ligands. The study on 2-(2-aminophenyl)-1-benzothiazole (Hapt) and 2-(2-aminophenyl)-1-benzimidazole (H2apz) with [ReVOCl3(PPh3)2] resulted in the formation of [ReVOCl2(apt)(OPPh3)] and [ReVCl2(apz)(PPh3)2](ReO4), respectively. 1,2-Bis(2-benzimidazole)-1,2-ethanediol (Hbed) and 2,6-bis(2- benzimidazol-2-yl)pyridine (H2bip) were studied towards rhenium(I) and rheniumV) respectively. The former gave a dimeric species (μ-bbi)[Re(CO)4]2 (H2bbi – bisbenzimidazole) by reaction with [Re(CO)5Cl], whereas H2bip produced the rhenium(III) cationic salt [ReCl3(H3bip)(PPh3)]Cl, where the ligand coordinates as a cationic H3bip+ with protonation of an uncoordinated imidazole nitrogen atom. The pyridine derivatives 2-hydrazino-pyridinyl-2-benzothiazole (Hhpt) and (E)-1-benzo[d]thiazol-2-yl)-2- (pyridin-2-ylmethylene)hydrazine (btp) were reacted with [Re(CO)5Cl]. The neutral complex [ReCl(Hhpt)(CO)3] was isolated upon reaction with Hhpt, where Hhpt coordinates as a neutral bidentate ligand. The reaction of [Re(CO)5Cl] with btp gave two different complexes when using different solvents. In methanol, [ReCl(btp)(CO)3] was isolated, whereas in toluene, the conjugate of btp (btp1) was formed which resulted in the formation of [ReCl(btp1)(CO)3]. The study on potentially bidentate thiourea derivatives containing a benzothiazole moiety towards [ReI(CO)3]+ and [ReVO]3+ cores gave rise to a wide variety of complexes. The reaction of [Re(CO)5Cl] with N-phenyl-N-(2-benzothiazole)thiourea (Hpbt) produced the rhenium(I) complex [Re(Hpbt)(pbt)(CO)3]. Hpbt coordinates both as a monodentate neutral ligand and as a bidentate monoanionic chelate. The study of the reaction between trans-[ReOCl3(PPh3)2] and Hpbt gave the rhenium(V) product [ReOCl2(pbt)(PPh3)], with pbt acting as a bidentate ligand. The reaction of 1-(1,3- benzothiazol-2-yl)-3-benzoylthiourea (Hbbt) with [Re(CO)5Cl] led to the isolation of [ReCl(Hbbt)(CO)3]. Similar reaction of Hbbt with trans-[ReOCl3(PPh3)2] gave the unique compound [ReOCl2(Hbnt)(PPh3)], where the ligand coordinates via the ketonic oxygen and a methine carbon. The complex [Re(Hmby)(mby)(CO)3] was isolated upon reacting [Re(CO)5Cl] with methylbenzothiazol-2-ylidenecarbamodithioate (Hmby), with Hmby coordinating as a monodentate neutral ligand and mby as a bidentate monoanionic chelate. The coordination behaviour of N-(benzothiazol-2-yl)-S,S’- dimethyldithiocarboimine (Hbdc) towards rhenium(I) led to the formation of [ReCl(Hbdc)(CO)3]. The reactivity of 1-(benzothiozol-2-yl)-3,3-dimethylthiourea (Hbdm), a derivative of Hmby, was studied with trans-[ReOCl3(PPh3)2] and trans- [ReO(OEt)I2(PPh3)2] producing the square pyramidal compound [ReOCl(bdm)2] and the salt [Re(bdm)2(MeCN)2]I3, respectively. Pyrazole derivatives containing a benzothiazole ring were studied towards rhenium in oxidation states +I and +V. The reaction between 2-(3,5-dimethylpyrazol-1-yl)benzothiazole (Hdmp) and [Re(CO)5Cl] gave the neutral rhenium complex [ReCl(Hdmp)(CO)3], whereas its reaction with [ReOCl3(PPh3)2] surprisingly results in the formation of a dimeric complex (μ-O)[ReOCl2(Hdmp)]2. The study on the reactivity of 1-(benzo[d]thiazol-2-yl)-4-methyl-1H-pyrrol-2-ol (Hbtm) with [Re(CO)5Cl] gave the unexpected trimer [Re(btm)(CO)3]3 containing the fac-[Re(CO)3]+ core. The ligand btm forms a bridge between each rhenium metal, serving as a bidentate ligand to one rhenium, and a monodentate ligand to another rhenium atom. The study on the coordination chemistry between trans-[ReOCl3(PPh3)2] and Hbtm gave two different complexes when using different solvents. In ethanol, [ReOCl(btm)(btm1)] formed, whereas [ReOCl(btm1)(btz)] (Hbtz = 1-(benzo[d]thiazol-2-yl)-4-(1-iminoethyl)-3- methyl-1H-pyrazol-5-ol) was isolated in acetonitrile. The reaction of cis-[ReO2I(PPh3)2] also gave two different products when using different solvents, where the respective solvents coordinate to the metal. The rhenium(V) compound [ReO(OMe)(btm)(btm1)] was formed in methanol, whereas [ReO(OEt)(btm)(btm1)] was formed in ethanol. The coordination chemistry of 2-(2-Benzothiazoleyl)-4,5,6,7-tetrahydro-2H-indazol-3-ol (Hbth) was studied towards [Re(CO)5Cl] and trans-[ReOCl3(PPh3)2]. The resulting complexes which formed are [ReCl(Hbth)(CO)3] and [ReOCl(bth)(bth1)] respectively. The reactivity of potentially tridentate Schiff base ligands towards rhenium(I) and (V) was studied. The rhenium(I) precursor [Re(CO)5Cl] was reacted with (E)-1- (benzo[d]thiazol-2-yl)-2-(phenol-2-ylmethylene)hydrazine (H3bph) to give [ReCl(CO)3(H3bph)], which contains the kinetically inert fac-[Re(CO)3]+ core coordinated to a neutral bidentate ligand. The reaction of [ReO2(py)4Cl] with H3bph gave the dimeric species (μ-O)[ReO(Hbph)(py)]2, where the ligand coordinates as a tridentate dianionic chelate. A similar complex was isolated with (E)-1- (benzo[d]thiazol-2-yl)-2-(2,4-dihydroxy-2-ylmethylene)hydrazine (H3bdh) to give (μ-O)[ReO(Hbdh)(py)]2. The reaction of trans-[ReOCl3(PPh3)2] with H3bph afforded [Re(abt)(imp)Cl2(PPh3)] (abt = 2-aminobenzothiazole, imp = 2-(iminomethyl)phenol), where the ligand broke up into two fragments, both of which coordinated without any modification. The dioxo rhenium precursor cis-[ReO2I(PPh3)2] gave [ReO(Hbdh)(imp)] upon reaction with H3bdh. Ligand imp coordinates as a bidentate monoanionic ligand via the imine nitrogen and deprotonated phenolic oxygen and ligand Hbdh coordinatesas a tridentate dianionic chelate.
- Full Text:
- Date Issued: 2017
- Authors: Van Niekerk, Xandri
- Date: 2017
- Subjects: Rhenium Benzimidazoles
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/21252 , vital:29467
- Description: A series of rhenium(I) complexes with monodentate benzazole ligands containing the fac-[Re(CO)3]+ was synthesized. The rhenium(I) compound [ReCl(Hmbt)2(CO)3] was prepared from the reaction of [Re(CO)5Cl] and 2-aminobenzothiazole (Hmbt) in toluene. The ligand coordinates in a monodentate manner via the thiazole nitrogen atom. A similar reaction between [Re(CO)5Cl] and N-(1,3-benzothiazol-2-yl)-2- chloroacetamide (Hbct) resulted in the formation of [ReCl(Hbct)(CO)3(NCMe)], where only one ligand binds per rhenium in a monodentate fashion. The reaction of ligands 2-mercaptobenzimidazole (Hmbi) (dibenzothiazol-2-yl)tetraazathiapentalene (Hdbt) with rhenium(I) gave [ReCl(Hmbi)2(CO)3] and [ReCl(Hdbt)2(CO)3] respectively. The study on the coordination behaviour between ethyl-(1H-benzimidazol-2-yl-sulfanyl) acetate (Hbsa) and [Re(CO)5Cl] surprisingly gave the dimeric species (μ-Cl)2[Re(Hbsa)(CO)3]2, where the two rhenium atoms are bridged by two chloro ligands. The coordination of Hbsa occurs through the imidazole nitrogen, leaving the ethoxy tail free on each Hbsa ligand. The coordination behaviour of benzimidazole and benzothiazole derivatives gave rhenium complexes in oxidation states I, III and V, where all the ligands coordinate as bidentate N,N-chelating ligands. The study on 2-(2-aminophenyl)-1-benzothiazole (Hapt) and 2-(2-aminophenyl)-1-benzimidazole (H2apz) with [ReVOCl3(PPh3)2] resulted in the formation of [ReVOCl2(apt)(OPPh3)] and [ReVCl2(apz)(PPh3)2](ReO4), respectively. 1,2-Bis(2-benzimidazole)-1,2-ethanediol (Hbed) and 2,6-bis(2- benzimidazol-2-yl)pyridine (H2bip) were studied towards rhenium(I) and rheniumV) respectively. The former gave a dimeric species (μ-bbi)[Re(CO)4]2 (H2bbi – bisbenzimidazole) by reaction with [Re(CO)5Cl], whereas H2bip produced the rhenium(III) cationic salt [ReCl3(H3bip)(PPh3)]Cl, where the ligand coordinates as a cationic H3bip+ with protonation of an uncoordinated imidazole nitrogen atom. The pyridine derivatives 2-hydrazino-pyridinyl-2-benzothiazole (Hhpt) and (E)-1-benzo[d]thiazol-2-yl)-2- (pyridin-2-ylmethylene)hydrazine (btp) were reacted with [Re(CO)5Cl]. The neutral complex [ReCl(Hhpt)(CO)3] was isolated upon reaction with Hhpt, where Hhpt coordinates as a neutral bidentate ligand. The reaction of [Re(CO)5Cl] with btp gave two different complexes when using different solvents. In methanol, [ReCl(btp)(CO)3] was isolated, whereas in toluene, the conjugate of btp (btp1) was formed which resulted in the formation of [ReCl(btp1)(CO)3]. The study on potentially bidentate thiourea derivatives containing a benzothiazole moiety towards [ReI(CO)3]+ and [ReVO]3+ cores gave rise to a wide variety of complexes. The reaction of [Re(CO)5Cl] with N-phenyl-N-(2-benzothiazole)thiourea (Hpbt) produced the rhenium(I) complex [Re(Hpbt)(pbt)(CO)3]. Hpbt coordinates both as a monodentate neutral ligand and as a bidentate monoanionic chelate. The study of the reaction between trans-[ReOCl3(PPh3)2] and Hpbt gave the rhenium(V) product [ReOCl2(pbt)(PPh3)], with pbt acting as a bidentate ligand. The reaction of 1-(1,3- benzothiazol-2-yl)-3-benzoylthiourea (Hbbt) with [Re(CO)5Cl] led to the isolation of [ReCl(Hbbt)(CO)3]. Similar reaction of Hbbt with trans-[ReOCl3(PPh3)2] gave the unique compound [ReOCl2(Hbnt)(PPh3)], where the ligand coordinates via the ketonic oxygen and a methine carbon. The complex [Re(Hmby)(mby)(CO)3] was isolated upon reacting [Re(CO)5Cl] with methylbenzothiazol-2-ylidenecarbamodithioate (Hmby), with Hmby coordinating as a monodentate neutral ligand and mby as a bidentate monoanionic chelate. The coordination behaviour of N-(benzothiazol-2-yl)-S,S’- dimethyldithiocarboimine (Hbdc) towards rhenium(I) led to the formation of [ReCl(Hbdc)(CO)3]. The reactivity of 1-(benzothiozol-2-yl)-3,3-dimethylthiourea (Hbdm), a derivative of Hmby, was studied with trans-[ReOCl3(PPh3)2] and trans- [ReO(OEt)I2(PPh3)2] producing the square pyramidal compound [ReOCl(bdm)2] and the salt [Re(bdm)2(MeCN)2]I3, respectively. Pyrazole derivatives containing a benzothiazole ring were studied towards rhenium in oxidation states +I and +V. The reaction between 2-(3,5-dimethylpyrazol-1-yl)benzothiazole (Hdmp) and [Re(CO)5Cl] gave the neutral rhenium complex [ReCl(Hdmp)(CO)3], whereas its reaction with [ReOCl3(PPh3)2] surprisingly results in the formation of a dimeric complex (μ-O)[ReOCl2(Hdmp)]2. The study on the reactivity of 1-(benzo[d]thiazol-2-yl)-4-methyl-1H-pyrrol-2-ol (Hbtm) with [Re(CO)5Cl] gave the unexpected trimer [Re(btm)(CO)3]3 containing the fac-[Re(CO)3]+ core. The ligand btm forms a bridge between each rhenium metal, serving as a bidentate ligand to one rhenium, and a monodentate ligand to another rhenium atom. The study on the coordination chemistry between trans-[ReOCl3(PPh3)2] and Hbtm gave two different complexes when using different solvents. In ethanol, [ReOCl(btm)(btm1)] formed, whereas [ReOCl(btm1)(btz)] (Hbtz = 1-(benzo[d]thiazol-2-yl)-4-(1-iminoethyl)-3- methyl-1H-pyrazol-5-ol) was isolated in acetonitrile. The reaction of cis-[ReO2I(PPh3)2] also gave two different products when using different solvents, where the respective solvents coordinate to the metal. The rhenium(V) compound [ReO(OMe)(btm)(btm1)] was formed in methanol, whereas [ReO(OEt)(btm)(btm1)] was formed in ethanol. The coordination chemistry of 2-(2-Benzothiazoleyl)-4,5,6,7-tetrahydro-2H-indazol-3-ol (Hbth) was studied towards [Re(CO)5Cl] and trans-[ReOCl3(PPh3)2]. The resulting complexes which formed are [ReCl(Hbth)(CO)3] and [ReOCl(bth)(bth1)] respectively. The reactivity of potentially tridentate Schiff base ligands towards rhenium(I) and (V) was studied. The rhenium(I) precursor [Re(CO)5Cl] was reacted with (E)-1- (benzo[d]thiazol-2-yl)-2-(phenol-2-ylmethylene)hydrazine (H3bph) to give [ReCl(CO)3(H3bph)], which contains the kinetically inert fac-[Re(CO)3]+ core coordinated to a neutral bidentate ligand. The reaction of [ReO2(py)4Cl] with H3bph gave the dimeric species (μ-O)[ReO(Hbph)(py)]2, where the ligand coordinates as a tridentate dianionic chelate. A similar complex was isolated with (E)-1- (benzo[d]thiazol-2-yl)-2-(2,4-dihydroxy-2-ylmethylene)hydrazine (H3bdh) to give (μ-O)[ReO(Hbdh)(py)]2. The reaction of trans-[ReOCl3(PPh3)2] with H3bph afforded [Re(abt)(imp)Cl2(PPh3)] (abt = 2-aminobenzothiazole, imp = 2-(iminomethyl)phenol), where the ligand broke up into two fragments, both of which coordinated without any modification. The dioxo rhenium precursor cis-[ReO2I(PPh3)2] gave [ReO(Hbdh)(imp)] upon reaction with H3bdh. Ligand imp coordinates as a bidentate monoanionic ligand via the imine nitrogen and deprotonated phenolic oxygen and ligand Hbdh coordinatesas a tridentate dianionic chelate.
- Full Text:
- Date Issued: 2017
Richard Charles Nicholas Branson : a psychobiographical study
- Authors: Preston, Amanda Lorraine
- Date: 2017
- Subjects: Branson, Richard Charles Nicholas, -- 1950- Businessmen -- Great Britain -- Biography Success in business
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/5543 , vital:29318
- Description: Unique individuals are fascinating as we all want to be successful. There is thus a need to understand, unpack and share the psychological development and traits that allow some people to become sui generis, and to learn from them. Psychobiographical research is a qualitative approach that can be utilised to uncover the story of such an individual life, resulting in greater understanding of the psychological concepts underpinning the person. This form of study is invaluable, and involves applying psychological theory to lives completed or unfinished, enabling the development and testing of developmental theories. Richard Branson (1950-present), an entrepreneur, adventurer, philanthropist and family man is the single psychological subject chosen in this study. Branson was selected based on interest value, his uniqueness and the lack of a specifically academic and psychologically focused case study on his life. The primary aim was to explore and describe Branson’s personality development across his life, to date. This was achieved by applying both Maslow’s (1954, 1970) theory of optimal development and Adler’s (1929, 1956) Individual Psychology theory to provide a comprehensive idiographic interpretation of the development of Branson. To achieve this, the case study utilised the systematic and consistent collection, analysis and interpretation of life history materials, highlighting three areas of development, namely Childhood, Adolescence and Adulthood. The theoretical frameworks were used to discern, transform and reconstruct his life into a coherent and illuminating narrative of his psychological movement through life. Alexander’s (1988; 1990) model of identifying salient themes was used to analyse data for analytical generalisation (Yin, 2009). The conceptual framework derived from the theoretical perspective was constructed to organize, integrate data, and guide the presentation and discussion of findings of the study in an integrative and comprehensive manner. The findings suggest both Maslow’s and Adler’s theories considered the biopsychosocial context in Branson’s personality development and, at least to some extent, supported concepts indicative of progression toward optimality through having met the needs of the ego actualisation of his self, toward transcending selfishness and attaining altruism and social interest. The study of Branson’s personality development has provided a positive demonstration of the value of Maslow’s (1970a) and Adler’s (1929, 1956) theories to understand the process of development. It has further highlighted the unique trajectory of an individual’s life, contextualized, as well as the possibility of being agents in our own lives and despite challenges, able to become our own idiosyncratic best. The study also highlights the need, at a macro level, for governments to assist those unable to satisfy basic needs such as food, shelter and safety, to set an imperative, to aid those who struggle if a country and its people are to be uplifted. In terms of Adlerian theory, the study highlights the importance of family and early experiences in supporting the earliest years of children to assist them to develop an identity that is healthy and socially useful. Finally, recommendations were made for future research utilising a psychobiographical research design to uncover, illuminate and reconstruct the lives of outstanding and interesting individuals.
- Full Text:
- Date Issued: 2017
- Authors: Preston, Amanda Lorraine
- Date: 2017
- Subjects: Branson, Richard Charles Nicholas, -- 1950- Businessmen -- Great Britain -- Biography Success in business
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/5543 , vital:29318
- Description: Unique individuals are fascinating as we all want to be successful. There is thus a need to understand, unpack and share the psychological development and traits that allow some people to become sui generis, and to learn from them. Psychobiographical research is a qualitative approach that can be utilised to uncover the story of such an individual life, resulting in greater understanding of the psychological concepts underpinning the person. This form of study is invaluable, and involves applying psychological theory to lives completed or unfinished, enabling the development and testing of developmental theories. Richard Branson (1950-present), an entrepreneur, adventurer, philanthropist and family man is the single psychological subject chosen in this study. Branson was selected based on interest value, his uniqueness and the lack of a specifically academic and psychologically focused case study on his life. The primary aim was to explore and describe Branson’s personality development across his life, to date. This was achieved by applying both Maslow’s (1954, 1970) theory of optimal development and Adler’s (1929, 1956) Individual Psychology theory to provide a comprehensive idiographic interpretation of the development of Branson. To achieve this, the case study utilised the systematic and consistent collection, analysis and interpretation of life history materials, highlighting three areas of development, namely Childhood, Adolescence and Adulthood. The theoretical frameworks were used to discern, transform and reconstruct his life into a coherent and illuminating narrative of his psychological movement through life. Alexander’s (1988; 1990) model of identifying salient themes was used to analyse data for analytical generalisation (Yin, 2009). The conceptual framework derived from the theoretical perspective was constructed to organize, integrate data, and guide the presentation and discussion of findings of the study in an integrative and comprehensive manner. The findings suggest both Maslow’s and Adler’s theories considered the biopsychosocial context in Branson’s personality development and, at least to some extent, supported concepts indicative of progression toward optimality through having met the needs of the ego actualisation of his self, toward transcending selfishness and attaining altruism and social interest. The study of Branson’s personality development has provided a positive demonstration of the value of Maslow’s (1970a) and Adler’s (1929, 1956) theories to understand the process of development. It has further highlighted the unique trajectory of an individual’s life, contextualized, as well as the possibility of being agents in our own lives and despite challenges, able to become our own idiosyncratic best. The study also highlights the need, at a macro level, for governments to assist those unable to satisfy basic needs such as food, shelter and safety, to set an imperative, to aid those who struggle if a country and its people are to be uplifted. In terms of Adlerian theory, the study highlights the importance of family and early experiences in supporting the earliest years of children to assist them to develop an identity that is healthy and socially useful. Finally, recommendations were made for future research utilising a psychobiographical research design to uncover, illuminate and reconstruct the lives of outstanding and interesting individuals.
- Full Text:
- Date Issued: 2017
Riding into myth: Manifest Destiny, Nietzschean ethics and the creation of a new western frontier mythology in Cormac McCarthy’s Blood Meridian
- Authors: Edley, Christopher
- Date: 2017
- Subjects: McCarthy, Cormac, 1933-. Blood meridian , Nietzsche, Friedrich Wilhelm, 1844-1900 -- Influence , Mythology in literature , American fiction -- 20th century -- History and criticism , West (U.S.) -- In literature
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/7334 , vital:21243
- Description: Cormac McCarthy’s Blood Meridian or the Evening Redness in the West is a provocative evocation of the American West that has attracted a wide range of critical responses. This study has three foci: the novel as epic myth, McCarthy’s critique of Manifest destiny, and the influence of Nietzschean philosophy on the judge and McCarthy’s portrayal of the human condition. These concerns conduce to an alternative reading of the conclusion of the novel. Blood Meridian is a unique textual enterprise as it both conforms to and subverts mythic conventions associated with both Classical epic and the American West. Recognition of the resonances between Blood Meridian and these mythologies helps the reader to engage with McCarthy’s ambitious creation of a powerful literary allegory in the tradition of Twain and Faulkner. Having situated McCarthy’s enterprise within these co-ordinates, the study then moves on to examine the novel’s stunning critique of Manifest Destiny, in the context of the implications that such thinking has had on American foreign policy over the past two centuries, and that continue to inspire American involvement in military conflicts well into the twenty-first century. The final area of focus is the influence of Friedrich Nietzsche’s philosophy on the character of the judge and the weltanschauung that the novel presents. McCarthy’s ultimate objective is to demonstrate that humankind’s most basic condition is an inherently violent one. The more critically accepted reading of the novel is challenged by postulating the kid’s triumph over the judge as not only in keeping with the literary tradition of Melville and others but also a logical outcome of the novel’s allegory of American military involvement in Vietnam. The study concludes that whilst McCarthy has gone on to receive critical acclaim and public praise for works published after Blood Meridian, this work remains both his artistic masterpiece and his most far-reaching engagement with issues of eschatological and political importance. It is argued that, given the contemporary escalation in geo-political tensions, Blood Meridian may well continue to provide insight into the nature of American domestic and foreign policy for decades to come.
- Full Text:
- Date Issued: 2017
- Authors: Edley, Christopher
- Date: 2017
- Subjects: McCarthy, Cormac, 1933-. Blood meridian , Nietzsche, Friedrich Wilhelm, 1844-1900 -- Influence , Mythology in literature , American fiction -- 20th century -- History and criticism , West (U.S.) -- In literature
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/7334 , vital:21243
- Description: Cormac McCarthy’s Blood Meridian or the Evening Redness in the West is a provocative evocation of the American West that has attracted a wide range of critical responses. This study has three foci: the novel as epic myth, McCarthy’s critique of Manifest destiny, and the influence of Nietzschean philosophy on the judge and McCarthy’s portrayal of the human condition. These concerns conduce to an alternative reading of the conclusion of the novel. Blood Meridian is a unique textual enterprise as it both conforms to and subverts mythic conventions associated with both Classical epic and the American West. Recognition of the resonances between Blood Meridian and these mythologies helps the reader to engage with McCarthy’s ambitious creation of a powerful literary allegory in the tradition of Twain and Faulkner. Having situated McCarthy’s enterprise within these co-ordinates, the study then moves on to examine the novel’s stunning critique of Manifest Destiny, in the context of the implications that such thinking has had on American foreign policy over the past two centuries, and that continue to inspire American involvement in military conflicts well into the twenty-first century. The final area of focus is the influence of Friedrich Nietzsche’s philosophy on the character of the judge and the weltanschauung that the novel presents. McCarthy’s ultimate objective is to demonstrate that humankind’s most basic condition is an inherently violent one. The more critically accepted reading of the novel is challenged by postulating the kid’s triumph over the judge as not only in keeping with the literary tradition of Melville and others but also a logical outcome of the novel’s allegory of American military involvement in Vietnam. The study concludes that whilst McCarthy has gone on to receive critical acclaim and public praise for works published after Blood Meridian, this work remains both his artistic masterpiece and his most far-reaching engagement with issues of eschatological and political importance. It is argued that, given the contemporary escalation in geo-political tensions, Blood Meridian may well continue to provide insight into the nature of American domestic and foreign policy for decades to come.
- Full Text:
- Date Issued: 2017
Rights as trumps in African communitarian ethics
- Authors: Nwogbo, Johnbosco
- Date: 2017
- Subjects: Communitarianism Human rights Social values
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10353/12282 , vital:39249
- Description: The notion of rights is among the most basic ideas of contemporary political philosophy on the continent and elsewhere. Although rights are common-place in political philosophy it is fair to say that the discussion around it has been nothing short of contested. On the whole, there have been two kinds of questions to which most of the discussion about rights in political philosophy have been answers, namely, (i) what are rights?, and (ii) to what do people have rights? The first has to do with the nature of rights, while the second has to the nature of that to which people may be said to have rights. This research falls neatly within the parlance of the first kind of questions (i.e., the question of what rights are). Specifically, in this research, I am concerned with the question of whether the radical and moderate African communitarian rights theses of Ifeanyi Menkiti and Kwame Gyekye measure up to what rights are commonly understood to be. I argue that if rights are trumps, which override competing societal and communal considerations, then Menkiti’s and Gyekye’s theories of rights fall short of this fairly standard and typical conception of rights.
- Full Text:
- Date Issued: 2017
- Authors: Nwogbo, Johnbosco
- Date: 2017
- Subjects: Communitarianism Human rights Social values
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10353/12282 , vital:39249
- Description: The notion of rights is among the most basic ideas of contemporary political philosophy on the continent and elsewhere. Although rights are common-place in political philosophy it is fair to say that the discussion around it has been nothing short of contested. On the whole, there have been two kinds of questions to which most of the discussion about rights in political philosophy have been answers, namely, (i) what are rights?, and (ii) to what do people have rights? The first has to do with the nature of rights, while the second has to the nature of that to which people may be said to have rights. This research falls neatly within the parlance of the first kind of questions (i.e., the question of what rights are). Specifically, in this research, I am concerned with the question of whether the radical and moderate African communitarian rights theses of Ifeanyi Menkiti and Kwame Gyekye measure up to what rights are commonly understood to be. I argue that if rights are trumps, which override competing societal and communal considerations, then Menkiti’s and Gyekye’s theories of rights fall short of this fairly standard and typical conception of rights.
- Full Text:
- Date Issued: 2017
Role of disaster management in urban sustainability: case study of Red House
- Authors: Banda, Cisomo
- Date: 2017
- Subjects: Emergency management -- South Africa -- Nelson Mandela Bay Municipality Natural disasters -- South Africa -- Nelson Mandela Bay Municipality
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/17448 , vital:28340
- Description: Disasters are inevitable events that impact negatively on humanity in South Africa and globally. Though disasters are global the most at risk populations are predominantly from developing countries and particularly poor communities experience multi-layered threats from floods, droughts, poor energy supply, inter alia. However, the urban communities have not been spared the effects of these disasters and have cause of concern. Millions of people have suffered and passed on because of disasters. These disasters cannot be prevented in certain environments but mechanisms can be put in place by the relevant officials such as government institutions or relevant stakeholders to help mitigate and reduce the effects of these disasters and further contribute to sustainable development. The Disaster Management Act in South Africa provides clear mandates, through policy and guidelines, on how to identify and reduce risk to disasters and how to prepare and respond to emergencies and disasters, structures and mechanisms, as well as the necessary systems. The local authorities such as the Disaster Management Department‘s roles and responsibility have been clearly stipulated and emphasised. It is therefore the mandate of the department to ensure that each and every community receives the adequate services that are entitled to them to help reduce the effects of the natural disasters and in turn contribute to the promotion of sustainable development. The overall aim of the Case Study in Redhouse was to investigate the effectiveness of the NMBM Disaster Management Department in urban sustainability. The research made use of the qualitative research methodology and followed the inductive approach. This was supported by a survey which was administered to willing participants chosen at random whose extensive experience is relevant to this research topic. Interviews involved direct personal contact with participants who were asked to respond to questions relating to the research study. The research sample consisted of a total number of eight participants. The Disaster Management Official was represented by two participants: the Redhouse community, which was represented by five participants, and the local NGO, which was represented by 1 participant. Current knowledge on the topic has been analysed and new knowledge with recommendations, has been generated through findings from this study.
- Full Text:
- Date Issued: 2017
- Authors: Banda, Cisomo
- Date: 2017
- Subjects: Emergency management -- South Africa -- Nelson Mandela Bay Municipality Natural disasters -- South Africa -- Nelson Mandela Bay Municipality
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/17448 , vital:28340
- Description: Disasters are inevitable events that impact negatively on humanity in South Africa and globally. Though disasters are global the most at risk populations are predominantly from developing countries and particularly poor communities experience multi-layered threats from floods, droughts, poor energy supply, inter alia. However, the urban communities have not been spared the effects of these disasters and have cause of concern. Millions of people have suffered and passed on because of disasters. These disasters cannot be prevented in certain environments but mechanisms can be put in place by the relevant officials such as government institutions or relevant stakeholders to help mitigate and reduce the effects of these disasters and further contribute to sustainable development. The Disaster Management Act in South Africa provides clear mandates, through policy and guidelines, on how to identify and reduce risk to disasters and how to prepare and respond to emergencies and disasters, structures and mechanisms, as well as the necessary systems. The local authorities such as the Disaster Management Department‘s roles and responsibility have been clearly stipulated and emphasised. It is therefore the mandate of the department to ensure that each and every community receives the adequate services that are entitled to them to help reduce the effects of the natural disasters and in turn contribute to the promotion of sustainable development. The overall aim of the Case Study in Redhouse was to investigate the effectiveness of the NMBM Disaster Management Department in urban sustainability. The research made use of the qualitative research methodology and followed the inductive approach. This was supported by a survey which was administered to willing participants chosen at random whose extensive experience is relevant to this research topic. Interviews involved direct personal contact with participants who were asked to respond to questions relating to the research study. The research sample consisted of a total number of eight participants. The Disaster Management Official was represented by two participants: the Redhouse community, which was represented by five participants, and the local NGO, which was represented by 1 participant. Current knowledge on the topic has been analysed and new knowledge with recommendations, has been generated through findings from this study.
- Full Text:
- Date Issued: 2017
Role of midwives in facilitating the choice of delivery mode for labouring women in public sector birthing units in the Nelson Mandela Bay Municipality and Sarah Baartman District
- Authors: Muthige, Noluthando
- Date: 2017
- Subjects: Midwives -- South Africa -- Eastern Cape Midwifery -- South Africa -- Eastern Cape , Delivery (Obstetrics) Infants -- Care -- South Africa -- Eastern Cape Public hospitals -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10948/19375 , vital:28860
- Description: The World Health Organization (WHO) recommends that of all the live births per year no more than 10-15% of these should be delivered by caesarean section. Despite this recommendation there has been a global increase in the percentage of caesarean section deliveries over the past few decades. In South Africa the percentage is as high as 70% in certain health care institutions which is of concern to midwives. Caesarean section deliveries are needed when the life of the baby, mother or both are at stake. However, this method of delivery bears more disadvantages than advantages to the baby and mother. Despite these disadvantages, some women request a caesarean section in their birth plans while others are influenced by health professionals to request a caesarean section. Therefore, there is a need for labouring women to be guided where possible to have vaginal birth because of its many advantages. This study sought to explore and describe the perceptions of the midwives regarding their role in facilitating the choice of delivery mode for labouring women in public hospitals and midwifery obstetric units (MOUs) of the Nelson Mandela Bay and Sarah Baartman districts. Based on the results of the study, guidelines for midwives in this role were developed. Maputle’sWoman-Centred Childbirth Model (2010) was used as the theoretical lens through which this study was viewed. The researcher selected a quantitative survey design using an explorative, descriptive and contextual research approach. The population consisted of midwives who were working in labour wards at public hospitals and midwife-led MOUs. A non-probability convenience sample was used to collect data using a structured, self-administered questionnaire. The reliability and validity of the data collection instrument were ensured by using various means including a pre-test and an expert panel. Altogether, 300 questionnaires were distributed and 288 were returned. This number excluded the pilot study. Data was collected over a period of three months using the assistance of two fieldworkers. Data was captured and analysed under the supervision of the statistician and supervisors. Analysis was done by means of descriptive analyses that involved the production of frequencies and presented using charts, figures and tables. The major findings of the study are: -The midwives perceived themselves as the main facilitators of a suitable decision by the labouring woman for a safe delivery method - The midwives emphasised the importance of the delivery position preferred by the labouring woman -The midwives indicated that a collaboration between doctors, senior midwives, midwives and midwives in management positions could assist with a decision for a suitable delivery mode option. -The midwives agreed that the culture of the labouring woman should be considered when deciding on a delivery mode and therefore midwifery curriculum should include lessons about cultural diversity. Three principal guidelines were developed, namely: 1. Create an environment that promotes acceptance of a woman’s choice of a delivery mode. 2. Create an environment promoting a collaborative health care relationship 3. Create an environment that is sensitive to cultural needs in the maternity unit Ethical considerations in this study were upheld by maintaining the principles of beneficence, maleficence, autonomy and justice.
- Full Text:
- Date Issued: 2017
- Authors: Muthige, Noluthando
- Date: 2017
- Subjects: Midwives -- South Africa -- Eastern Cape Midwifery -- South Africa -- Eastern Cape , Delivery (Obstetrics) Infants -- Care -- South Africa -- Eastern Cape Public hospitals -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10948/19375 , vital:28860
- Description: The World Health Organization (WHO) recommends that of all the live births per year no more than 10-15% of these should be delivered by caesarean section. Despite this recommendation there has been a global increase in the percentage of caesarean section deliveries over the past few decades. In South Africa the percentage is as high as 70% in certain health care institutions which is of concern to midwives. Caesarean section deliveries are needed when the life of the baby, mother or both are at stake. However, this method of delivery bears more disadvantages than advantages to the baby and mother. Despite these disadvantages, some women request a caesarean section in their birth plans while others are influenced by health professionals to request a caesarean section. Therefore, there is a need for labouring women to be guided where possible to have vaginal birth because of its many advantages. This study sought to explore and describe the perceptions of the midwives regarding their role in facilitating the choice of delivery mode for labouring women in public hospitals and midwifery obstetric units (MOUs) of the Nelson Mandela Bay and Sarah Baartman districts. Based on the results of the study, guidelines for midwives in this role were developed. Maputle’sWoman-Centred Childbirth Model (2010) was used as the theoretical lens through which this study was viewed. The researcher selected a quantitative survey design using an explorative, descriptive and contextual research approach. The population consisted of midwives who were working in labour wards at public hospitals and midwife-led MOUs. A non-probability convenience sample was used to collect data using a structured, self-administered questionnaire. The reliability and validity of the data collection instrument were ensured by using various means including a pre-test and an expert panel. Altogether, 300 questionnaires were distributed and 288 were returned. This number excluded the pilot study. Data was collected over a period of three months using the assistance of two fieldworkers. Data was captured and analysed under the supervision of the statistician and supervisors. Analysis was done by means of descriptive analyses that involved the production of frequencies and presented using charts, figures and tables. The major findings of the study are: -The midwives perceived themselves as the main facilitators of a suitable decision by the labouring woman for a safe delivery method - The midwives emphasised the importance of the delivery position preferred by the labouring woman -The midwives indicated that a collaboration between doctors, senior midwives, midwives and midwives in management positions could assist with a decision for a suitable delivery mode option. -The midwives agreed that the culture of the labouring woman should be considered when deciding on a delivery mode and therefore midwifery curriculum should include lessons about cultural diversity. Three principal guidelines were developed, namely: 1. Create an environment that promotes acceptance of a woman’s choice of a delivery mode. 2. Create an environment promoting a collaborative health care relationship 3. Create an environment that is sensitive to cultural needs in the maternity unit Ethical considerations in this study were upheld by maintaining the principles of beneficence, maleficence, autonomy and justice.
- Full Text:
- Date Issued: 2017
Rural women's participation in commercial farming in Tweespruit
- Authors: Sebolai, Bridget
- Date: 2017
- Subjects: Rural women -- South Africa -- Free State Farmers -- Women -- South Africa -- Free State , Farms, Small -- Women -- South Africa -- Free State Agriculture -- Economic aspects -- South Africa -- Free State
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/20466 , vital:29290
- Description: This study assesses the challenges confronted by rural women participating in small-scale commercial farming in Tweespruit, a rural town of the Free State Province. A qualitative, descriptive and explorative study was used for the study, and data was collected using focus group discussions during August 2015. The study found that rural women farmers are extremely challenged, as they are inadequately equipped as farmers, and they do not receive adequate aid from government or other entities, to enable them to turn their form of farming from subsistence farming to a more beneficial, commercialized form of farming. As a result, the study made the following recommendations. Firstly, the government should intensify programmes and strategies aimed at assisting rural women involved in farming activities. Secondly, it should also assist these farmers with training, especially in modern farming technologies, so as to grow their business into a commercialized form of farming. Finally, it was recommended that government facilitates these farmers to obtain funding from foreign donors to further grow their business.
- Full Text:
- Date Issued: 2017
- Authors: Sebolai, Bridget
- Date: 2017
- Subjects: Rural women -- South Africa -- Free State Farmers -- Women -- South Africa -- Free State , Farms, Small -- Women -- South Africa -- Free State Agriculture -- Economic aspects -- South Africa -- Free State
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/20466 , vital:29290
- Description: This study assesses the challenges confronted by rural women participating in small-scale commercial farming in Tweespruit, a rural town of the Free State Province. A qualitative, descriptive and explorative study was used for the study, and data was collected using focus group discussions during August 2015. The study found that rural women farmers are extremely challenged, as they are inadequately equipped as farmers, and they do not receive adequate aid from government or other entities, to enable them to turn their form of farming from subsistence farming to a more beneficial, commercialized form of farming. As a result, the study made the following recommendations. Firstly, the government should intensify programmes and strategies aimed at assisting rural women involved in farming activities. Secondly, it should also assist these farmers with training, especially in modern farming technologies, so as to grow their business into a commercialized form of farming. Finally, it was recommended that government facilitates these farmers to obtain funding from foreign donors to further grow their business.
- Full Text:
- Date Issued: 2017
Ruthenium sulphide nanoparticles derived from tri-dithiocarbamato ruthenium (III) complexes : synthesis, optical and structural studies
- Authors: Mbese, Johannes Zanoxolo
- Date: 2017
- Subjects: Nanoparticles Ruthenium compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/15420 , vital:40406
- Description: The present Thesis pioneer the application of single-source molecular precursor method for the synthesis of ruthenium sulfide nanoparticles using a series of novel self-prepared single-source molecular precursors. The preparation of precursors involved the design and synthesis of compounds containing all the desired elements required within the coordination compound. Good precursors are tailored to give reproducible, clean decomposition at moderate temperatures, leading to high quality, defect free, mono-dispersed nanoparticles. Nine (9) homonuclear tris-dithiocarbamato ruthenium(III) complexes, [Ru(S2CNR2)3] were prepared from a stoichiometric reaction of RuCl3·H2O with self-prepared dithiocarbamate ligands at room temperature in a molar ratio of Ru3+: Ligand of 1:3. Dithiocarbamate ligands were derived from a stoichiometric reaction of carbon disulfide with (aniline, N-allylmethylamine, p-toluidine, p-anisidine, N-ethyl-m-toluidine, piperidine, morpholine, di-isopropylamine, and diallylamine) in the presence of concentrated ammonia or potassium hydroxide in ice cold bath. The dithiocarbamate ligands and complexes were characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopy (FTIR), 1H- and 13C-NMR spectroscopy. Thermogravimetric analyses (TGA) was used to study the decomposition profiles of the precursor complexes. The results obtained from the TGA of precursors showed that the complexes decompose to ruthenium sulfide nanoparticles. The FTIR spectra of the ligands revealed prominent strong absorption bands ascribed to v(N-H) stretching vibrations and also confirm the bidentate coordination of the dithiocarbamate ligands. Ruthenium(III) complexes show absorption spectra in the visible region that exhibit bands attributed to n → π* electronic transitions located on the sulfur atoms located in the S–C–S and N–C–S chromophores of the bidentate dithiocarbamate ligands respectively. The absorption spectra also confirmed the geometry of ruthenium(III) complexes to be octahedral. The proposed structures of dithiocarbamate ligands and ruthenium(III) complexes were confirmed by the 1H- and 13C-NMR. The complexes were used as single-source molecular precursors for the synthesis of ruthenium sulfide nanoparticles. The structural and optical properties were studied using transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), UV-Vis absorption and photoluminescence (PL) spectra. FTIR revealed that Ru2S3 nanoparticles are capped through the interaction of the –NH2 group of hexadecylamine HDA adsorbed on the surfaces of nanoparticles and it also showed that oleic acid (OA) is acting as both coordinating stabilizing surfactant and capping agent. The XRD confirmed the successful formation of Ru2S3 nanoparticles induced by the thermal decomposition of series of [Ru(S2CNR2)3] complexes. The diffraction peaks: 2θ = 29.43, 40.54, 49.33, 51.86, 61.92, and 75.94 were assign the Miler indices (hkl) to be (111), (211), (220), (300), (222) and (330) reflections, respectively, and were found to be in agreement with a cubic crystal structure reported in database file of (JCPDS 19-1107). The particle sizes estimated from Scherer's equation were found in a range between 2.5 and 4.9 nm. EDS spectra reveal that the prepared nanoparticles are mainly composed of Ru and S, confirming the presence of Ru2S3 nanoparticles in cubic phase. The inner morphology of nanoparticles was obtained by transmission electron microscopy (TEM) and most nanoparticles had narrow particle size distribution characterized by an average diameter of 8.45 nm with a standard deviation of 1.6 nm. The optical band gap (Eg) determined from Tauc plot was found in the range (3.44 to 4.18 eV) values.
- Full Text:
- Date Issued: 2017
- Authors: Mbese, Johannes Zanoxolo
- Date: 2017
- Subjects: Nanoparticles Ruthenium compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/15420 , vital:40406
- Description: The present Thesis pioneer the application of single-source molecular precursor method for the synthesis of ruthenium sulfide nanoparticles using a series of novel self-prepared single-source molecular precursors. The preparation of precursors involved the design and synthesis of compounds containing all the desired elements required within the coordination compound. Good precursors are tailored to give reproducible, clean decomposition at moderate temperatures, leading to high quality, defect free, mono-dispersed nanoparticles. Nine (9) homonuclear tris-dithiocarbamato ruthenium(III) complexes, [Ru(S2CNR2)3] were prepared from a stoichiometric reaction of RuCl3·H2O with self-prepared dithiocarbamate ligands at room temperature in a molar ratio of Ru3+: Ligand of 1:3. Dithiocarbamate ligands were derived from a stoichiometric reaction of carbon disulfide with (aniline, N-allylmethylamine, p-toluidine, p-anisidine, N-ethyl-m-toluidine, piperidine, morpholine, di-isopropylamine, and diallylamine) in the presence of concentrated ammonia or potassium hydroxide in ice cold bath. The dithiocarbamate ligands and complexes were characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopy (FTIR), 1H- and 13C-NMR spectroscopy. Thermogravimetric analyses (TGA) was used to study the decomposition profiles of the precursor complexes. The results obtained from the TGA of precursors showed that the complexes decompose to ruthenium sulfide nanoparticles. The FTIR spectra of the ligands revealed prominent strong absorption bands ascribed to v(N-H) stretching vibrations and also confirm the bidentate coordination of the dithiocarbamate ligands. Ruthenium(III) complexes show absorption spectra in the visible region that exhibit bands attributed to n → π* electronic transitions located on the sulfur atoms located in the S–C–S and N–C–S chromophores of the bidentate dithiocarbamate ligands respectively. The absorption spectra also confirmed the geometry of ruthenium(III) complexes to be octahedral. The proposed structures of dithiocarbamate ligands and ruthenium(III) complexes were confirmed by the 1H- and 13C-NMR. The complexes were used as single-source molecular precursors for the synthesis of ruthenium sulfide nanoparticles. The structural and optical properties were studied using transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), UV-Vis absorption and photoluminescence (PL) spectra. FTIR revealed that Ru2S3 nanoparticles are capped through the interaction of the –NH2 group of hexadecylamine HDA adsorbed on the surfaces of nanoparticles and it also showed that oleic acid (OA) is acting as both coordinating stabilizing surfactant and capping agent. The XRD confirmed the successful formation of Ru2S3 nanoparticles induced by the thermal decomposition of series of [Ru(S2CNR2)3] complexes. The diffraction peaks: 2θ = 29.43, 40.54, 49.33, 51.86, 61.92, and 75.94 were assign the Miler indices (hkl) to be (111), (211), (220), (300), (222) and (330) reflections, respectively, and were found to be in agreement with a cubic crystal structure reported in database file of (JCPDS 19-1107). The particle sizes estimated from Scherer's equation were found in a range between 2.5 and 4.9 nm. EDS spectra reveal that the prepared nanoparticles are mainly composed of Ru and S, confirming the presence of Ru2S3 nanoparticles in cubic phase. The inner morphology of nanoparticles was obtained by transmission electron microscopy (TEM) and most nanoparticles had narrow particle size distribution characterized by an average diameter of 8.45 nm with a standard deviation of 1.6 nm. The optical band gap (Eg) determined from Tauc plot was found in the range (3.44 to 4.18 eV) values.
- Full Text:
- Date Issued: 2017
Safe space online: the construction of intersectional safety in a South African feminist Facebook group
- Authors: Roux, Kayla
- Date: 2017
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/8044 , vital:21338
- Description: In this thesis I investigate the construction of an intersectional ‘safe space’ in a closed South African feminist community on the social networking site Facebook. Drawing on my own experience as a group member, observations of group dynamics, focus group interviews with administrators, and interviews with past and present members, I discuss the practices and guidelines employed to ensure the safety and intersectionality of the group. This research spans a period of more than two years, and there were a number of developments in the group over this time. It is a relatively large and well-established feminist Facebook group in South Africa which enforces an intersectional approach to social justice, and it is explicitly formulated and closely monitored so that marginalised voices are privileged in group interactions. Despite the best efforts of group moderators, however, interactions between the privileged and the marginalised tend to reproduce existing power inequalities and jeopardise the safety of those the group is meant to serve. Although some interview participants feel that safe space practices such as the call-out system and exclusionary groups and posts serve to fragment the group and cause conflict, these complaints mainly originate from white women who were required to acknowledge their unearned privilege. Their presence in the group and the problem of ‘white derailment’ makes the space feel unsafe for many POC. Ultimately, a splinter group exclusively for POC was formed in order to provide a safer space for feminists of colour to find solidarity and support, discuss issues affecting them, and do the important and necessary work of selfdefinition. I conclude that while these spaces are limited - and absolute safety can never be guaranteed - these exclusive spaces are an integral starting point in the development of a transversal intersectional politics of solidarity between different actors and movements that share the same values.
- Full Text:
- Date Issued: 2017
- Authors: Roux, Kayla
- Date: 2017
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/8044 , vital:21338
- Description: In this thesis I investigate the construction of an intersectional ‘safe space’ in a closed South African feminist community on the social networking site Facebook. Drawing on my own experience as a group member, observations of group dynamics, focus group interviews with administrators, and interviews with past and present members, I discuss the practices and guidelines employed to ensure the safety and intersectionality of the group. This research spans a period of more than two years, and there were a number of developments in the group over this time. It is a relatively large and well-established feminist Facebook group in South Africa which enforces an intersectional approach to social justice, and it is explicitly formulated and closely monitored so that marginalised voices are privileged in group interactions. Despite the best efforts of group moderators, however, interactions between the privileged and the marginalised tend to reproduce existing power inequalities and jeopardise the safety of those the group is meant to serve. Although some interview participants feel that safe space practices such as the call-out system and exclusionary groups and posts serve to fragment the group and cause conflict, these complaints mainly originate from white women who were required to acknowledge their unearned privilege. Their presence in the group and the problem of ‘white derailment’ makes the space feel unsafe for many POC. Ultimately, a splinter group exclusively for POC was formed in order to provide a safer space for feminists of colour to find solidarity and support, discuss issues affecting them, and do the important and necessary work of selfdefinition. I conclude that while these spaces are limited - and absolute safety can never be guaranteed - these exclusive spaces are an integral starting point in the development of a transversal intersectional politics of solidarity between different actors and movements that share the same values.
- Full Text:
- Date Issued: 2017
Satisfaction levels of visitors at the Tsitsikamma National Park
- Authors: Maluwa, Lutendo Obed
- Date: 2017
- Subjects: Tourism -- Research -- South Africa Consumer behavior -- South Africa , Customer relations -- South Africa National parks and reserves -- South Africa
- Language: English
- Type: Thesis , Masters , MPhil
- Identifier: http://hdl.handle.net/10948/18058 , vital:28569
- Description: The literature reviews on tourist satisfaction revealed that a satisfied tourist leads to positive word of mouth recommendation to friends and family, loyalty (return visits), competitive advantage and long-term profitability and sustainability. These favourable benefits resulting from satisfaction are necessary for any destination to survive in the competitive tourism industry. South African National Parks (SANParks) manages all 21 national parks in South Africa, with the TNP being the third in terms of visitor numbers and income generated from tourism products. Data captured from visitors to the TNP was used to achieve the goal and objective of this study. This goal was achieved by conducting a questionnaire survey at Storm’s River rest camp within the TNP from 01 May to 31 July 2015. A total of 120 questionnaires were completed and included in further analysis. The aim of this research was to determine the relationship between satisfaction, service and travel motivations of the visitors to the TNP. The statistical test was used to determine whether or not visitors’ expectations were met. This was also used to determine the relationship between travel behaviour, travel motives, and service satisfaction of the visitors to the TNP. Park management can use these results as tools to ensure that the product offered guarantees visitors’ satisfaction and therefore contributes to long-term park sustainability. Therefore, park management is able to obtain the ideal tourist experience by not only focusing on the travel motives but also on the quality of service delivered at the park. The results showed that park management needs to become aware of what the visitor sees as important factors for a memorable visitor experience and they can adapt certain aspects to improve the visitor’s experience. Park management can therefore improve their services and products as well as the quality thereof by knowing what the tourists see as important when visiting a national park to obtain a memorable experience, which will lead to positive word of mouth sharing, loyalty, increased revenue and sustainability of the TNP.
- Full Text:
- Date Issued: 2017
- Authors: Maluwa, Lutendo Obed
- Date: 2017
- Subjects: Tourism -- Research -- South Africa Consumer behavior -- South Africa , Customer relations -- South Africa National parks and reserves -- South Africa
- Language: English
- Type: Thesis , Masters , MPhil
- Identifier: http://hdl.handle.net/10948/18058 , vital:28569
- Description: The literature reviews on tourist satisfaction revealed that a satisfied tourist leads to positive word of mouth recommendation to friends and family, loyalty (return visits), competitive advantage and long-term profitability and sustainability. These favourable benefits resulting from satisfaction are necessary for any destination to survive in the competitive tourism industry. South African National Parks (SANParks) manages all 21 national parks in South Africa, with the TNP being the third in terms of visitor numbers and income generated from tourism products. Data captured from visitors to the TNP was used to achieve the goal and objective of this study. This goal was achieved by conducting a questionnaire survey at Storm’s River rest camp within the TNP from 01 May to 31 July 2015. A total of 120 questionnaires were completed and included in further analysis. The aim of this research was to determine the relationship between satisfaction, service and travel motivations of the visitors to the TNP. The statistical test was used to determine whether or not visitors’ expectations were met. This was also used to determine the relationship between travel behaviour, travel motives, and service satisfaction of the visitors to the TNP. Park management can use these results as tools to ensure that the product offered guarantees visitors’ satisfaction and therefore contributes to long-term park sustainability. Therefore, park management is able to obtain the ideal tourist experience by not only focusing on the travel motives but also on the quality of service delivered at the park. The results showed that park management needs to become aware of what the visitor sees as important factors for a memorable visitor experience and they can adapt certain aspects to improve the visitor’s experience. Park management can therefore improve their services and products as well as the quality thereof by knowing what the tourists see as important when visiting a national park to obtain a memorable experience, which will lead to positive word of mouth sharing, loyalty, increased revenue and sustainability of the TNP.
- Full Text:
- Date Issued: 2017
Scanning probe force microscopy of III-V semiconductor structures
- Authors: Kameni Boumenou, Christian
- Date: 2017
- Subjects: Scanning probe microscopy -- South Africa Semiconductors -- Optical properties
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/13992 , vital:27380
- Description: In this dissertation, cross-sectional potential imaging of GaAs-based homoepitaxial, heteroepitaxial and quantum well structures, all grown by atmospheric pressure Metal-organic Vapor Phase Epitaxy (MOVPE) is investigated. Kelvin probe force microscopy (KPFM), using amplitude modulation (AM) and frequency modulation (FM) modes in air and at room temperature, is used for the potential imaging. Studies performed on n-type GaAs homoepitaxial structures have shown two different potential profiles, related to the difference in electron density between the semi-insulating (SI) substrate and the epilayers. It is shown that the contact potential difference (CPD) between the tip and sample is higher on the semi-insulating substrate side than on the n-type epilayer side. This change in CPD across the interface has been explained by means of energy band diagrams indicating the relative Fermi level positions. In addition, it has also been found that the CPD across the interface increases with electron density. This result is in qualitative agreement with theory. In addition, as known from literature, even under ambient conditions FM mode KPFM provides better lateral resolution and more realistic CPD values than AM mode KPFM. Compared to the case of AM mode analysis, where the experimental CPD values were on average of the theoretical values, the CPD values from FM mode analysis are on average of the theoretical ones. Furthermore, by using FM mode, the transition across the interface is sharper and the surface potential flattens/saturates as expected when scanning sufficiently far away from the junction. The non-neutral space charge region of the sample with an electron density of for example, is as measured by FM-KPFM, whereas for AM-KPFM, the width is even more than and the potential profiles do not saturate. For the p-type GaAs homoepitaxial structures, FM mode measurements from a sample with a dopant density of are presented. As in the case of n-type GaAs,a similar potential profile showing two main domains has been obtained. However, unlike the case of type GaAs where the potential measured on the epilayer side is higher than that on the substrate side, the potential on the epilayer side of the junction is lower in this case due to the fact that the Fermi level of p-type GaAs is below that of the substrate.
- Full Text:
- Date Issued: 2017
- Authors: Kameni Boumenou, Christian
- Date: 2017
- Subjects: Scanning probe microscopy -- South Africa Semiconductors -- Optical properties
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/13992 , vital:27380
- Description: In this dissertation, cross-sectional potential imaging of GaAs-based homoepitaxial, heteroepitaxial and quantum well structures, all grown by atmospheric pressure Metal-organic Vapor Phase Epitaxy (MOVPE) is investigated. Kelvin probe force microscopy (KPFM), using amplitude modulation (AM) and frequency modulation (FM) modes in air and at room temperature, is used for the potential imaging. Studies performed on n-type GaAs homoepitaxial structures have shown two different potential profiles, related to the difference in electron density between the semi-insulating (SI) substrate and the epilayers. It is shown that the contact potential difference (CPD) between the tip and sample is higher on the semi-insulating substrate side than on the n-type epilayer side. This change in CPD across the interface has been explained by means of energy band diagrams indicating the relative Fermi level positions. In addition, it has also been found that the CPD across the interface increases with electron density. This result is in qualitative agreement with theory. In addition, as known from literature, even under ambient conditions FM mode KPFM provides better lateral resolution and more realistic CPD values than AM mode KPFM. Compared to the case of AM mode analysis, where the experimental CPD values were on average of the theoretical values, the CPD values from FM mode analysis are on average of the theoretical ones. Furthermore, by using FM mode, the transition across the interface is sharper and the surface potential flattens/saturates as expected when scanning sufficiently far away from the junction. The non-neutral space charge region of the sample with an electron density of for example, is as measured by FM-KPFM, whereas for AM-KPFM, the width is even more than and the potential profiles do not saturate. For the p-type GaAs homoepitaxial structures, FM mode measurements from a sample with a dopant density of are presented. As in the case of n-type GaAs,a similar potential profile showing two main domains has been obtained. However, unlike the case of type GaAs where the potential measured on the epilayer side is higher than that on the substrate side, the potential on the epilayer side of the junction is lower in this case due to the fact that the Fermi level of p-type GaAs is below that of the substrate.
- Full Text:
- Date Issued: 2017
School libraries in former model c high schools – the case of the Framesby high school media centre
- Authors: Olivier, Charleine
- Date: 2017
- Subjects: School libraries -- South Africa -- Port Elizabeth Instructional materials centers -- South Africa -- Port Elizabeth , Multicultural education -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/19795 , vital:28969
- Description: The study explored the changing role of libraries/media centres at ex-Model C (now Section 21) high schools in the Nelson Mandela Metropole (NMM), focussing on a case study of the Framesby High School (FHS) media centre in Port Elizabeth. Model C schools originated in the 1990s, just before the transition to democratic rule in 1994, when White, or House of Assembly schools were given a choice of three school governing models, namely, fully-private Model A schools, Model B state schools and semi-private Model C schools. Model C schools would receive state subsidies of about 50%, with the balance raised through school fees. A major research purpose was to present a comprehensive description of the current ex- Model C school library context and how these influenced the service orientation and intended core functions of school librarians, such as teaching information literacy, providing academic support and promoting general literacy and reading. The FHS media centre service was further described with an aim of providing functional library/media centre management guidelines, applicable to high school libraries/media centres in similar ex-Model C school situations, or any libraries that could find such guidelines useful. This qualitative FHS media centre case study was based on the FHS media centre manager’s personal observation as participative action researcher and further supported by literature, an interview and questionnaire feedback from FHS educators and respondents from selected NMM ex-Model C high school libraries. By comparing historical and existing national and provincial school library issues, conclusions were reached regarding macro- and micro-school library contexts, for example, the effect of having no national policy, the support roles of school management and governing bodies, the influence of digital media and the position of school librarians. School librarian concerns, including their roles, qualifications, service conditions and professional status, especially within Section 21 schools, were considered with the high school library and librarian’s contribution towards curriculum outcomes and life-long learning. With specific reference to ex-Model C schools, the absence of a library policy also resulted in diverse levels of school management and school governing body recognition of the school library/media centre. This impacted on the school librarian’s role in curriculum support and information literacy teaching as well as the availability of funds, infrastructure and resources. It is recommended that government should address the supply of library facilities, services and posts for school librarians and assistants. Lack of governmental action is maintaining the growing divide between ex-Model C schools and disadvantaged schools, while the lack of school library services also has a negative influence on literacy and pass rates, especially in poorer regions, like the Eastern Cape. In the light of the vast difference between the results of ex-Model C schools and other schools in the Eastern Cape, these schools and their library services could provide a benchmark towards improving educational contexts in the province.
- Full Text:
- Date Issued: 2017
- Authors: Olivier, Charleine
- Date: 2017
- Subjects: School libraries -- South Africa -- Port Elizabeth Instructional materials centers -- South Africa -- Port Elizabeth , Multicultural education -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/19795 , vital:28969
- Description: The study explored the changing role of libraries/media centres at ex-Model C (now Section 21) high schools in the Nelson Mandela Metropole (NMM), focussing on a case study of the Framesby High School (FHS) media centre in Port Elizabeth. Model C schools originated in the 1990s, just before the transition to democratic rule in 1994, when White, or House of Assembly schools were given a choice of three school governing models, namely, fully-private Model A schools, Model B state schools and semi-private Model C schools. Model C schools would receive state subsidies of about 50%, with the balance raised through school fees. A major research purpose was to present a comprehensive description of the current ex- Model C school library context and how these influenced the service orientation and intended core functions of school librarians, such as teaching information literacy, providing academic support and promoting general literacy and reading. The FHS media centre service was further described with an aim of providing functional library/media centre management guidelines, applicable to high school libraries/media centres in similar ex-Model C school situations, or any libraries that could find such guidelines useful. This qualitative FHS media centre case study was based on the FHS media centre manager’s personal observation as participative action researcher and further supported by literature, an interview and questionnaire feedback from FHS educators and respondents from selected NMM ex-Model C high school libraries. By comparing historical and existing national and provincial school library issues, conclusions were reached regarding macro- and micro-school library contexts, for example, the effect of having no national policy, the support roles of school management and governing bodies, the influence of digital media and the position of school librarians. School librarian concerns, including their roles, qualifications, service conditions and professional status, especially within Section 21 schools, were considered with the high school library and librarian’s contribution towards curriculum outcomes and life-long learning. With specific reference to ex-Model C schools, the absence of a library policy also resulted in diverse levels of school management and school governing body recognition of the school library/media centre. This impacted on the school librarian’s role in curriculum support and information literacy teaching as well as the availability of funds, infrastructure and resources. It is recommended that government should address the supply of library facilities, services and posts for school librarians and assistants. Lack of governmental action is maintaining the growing divide between ex-Model C schools and disadvantaged schools, while the lack of school library services also has a negative influence on literacy and pass rates, especially in poorer regions, like the Eastern Cape. In the light of the vast difference between the results of ex-Model C schools and other schools in the Eastern Cape, these schools and their library services could provide a benchmark towards improving educational contexts in the province.
- Full Text:
- Date Issued: 2017
Screening of shark liver extracts for potential antimicrobial properties against selected pathogenic bacterial strains
- Authors: Mrwetyana, Thandolwethu
- Date: 2017
- Subjects: Fishes -- Diseases Pathogenic bacteria
- Language: English
- Type: Thesis , Masters , Microbiology
- Identifier: http://hdl.handle.net/10353/13004 , vital:39431
- Description: The growing problem of antimicrobial resistance prevents the effective treatment of bacterial infections. Traditional antibiotics such as penicillin have been rendered ineffective against most microbial pathogens. This has led to an increased need for the development of new and improved drugs. The marine environment contains a great array of organisms with unique biological properties, but still remains one of our most underutilized biological resources. The aim of this study was to screen different shark liver extracts for antimicrobial properties. After optimizing the extraction methods, the liver extracts (oil and aminosterol) of three different shark species, namely the Dogfish (Squalus acanthias), the Catshark (Scyliorhinus capensis) and the Hammerhead (Sphyrna zygaena) shark, were screened for antimicrobial properties using the Kirby-Bauer disc diffusion method against selected bacterial pathogens (Helicobacter pylori, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Bacillus cereus), after which the MIC was determined using the modified broth micro-dilution described by Vollekova et al. (2001). The most active extract was fractionated using thin layer chromatography, and TLC-direct bioautography was used to determine the antimicrobial properties of the fractionated compounds. The Folch et al and the Shinnar et al methods yielded the highest extract volumes for oil and aminosterol consecutively, and the catshark and dogfish aminosterol extract showed greater levels of bioactivity against all selected bacterial pathogens, with S. aureus showing highest susceptibility levels to both extracts. A total of 22 compounds were observed in the developed plates with two compounds (Rf 0.53 and 0.79) showing antimicrobial activity. Certain shark liver extracts possess antimicrobial properties that have the potential to be used in the development of new antimicrobial drugs.
- Full Text:
- Date Issued: 2017
- Authors: Mrwetyana, Thandolwethu
- Date: 2017
- Subjects: Fishes -- Diseases Pathogenic bacteria
- Language: English
- Type: Thesis , Masters , Microbiology
- Identifier: http://hdl.handle.net/10353/13004 , vital:39431
- Description: The growing problem of antimicrobial resistance prevents the effective treatment of bacterial infections. Traditional antibiotics such as penicillin have been rendered ineffective against most microbial pathogens. This has led to an increased need for the development of new and improved drugs. The marine environment contains a great array of organisms with unique biological properties, but still remains one of our most underutilized biological resources. The aim of this study was to screen different shark liver extracts for antimicrobial properties. After optimizing the extraction methods, the liver extracts (oil and aminosterol) of three different shark species, namely the Dogfish (Squalus acanthias), the Catshark (Scyliorhinus capensis) and the Hammerhead (Sphyrna zygaena) shark, were screened for antimicrobial properties using the Kirby-Bauer disc diffusion method against selected bacterial pathogens (Helicobacter pylori, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Bacillus cereus), after which the MIC was determined using the modified broth micro-dilution described by Vollekova et al. (2001). The most active extract was fractionated using thin layer chromatography, and TLC-direct bioautography was used to determine the antimicrobial properties of the fractionated compounds. The Folch et al and the Shinnar et al methods yielded the highest extract volumes for oil and aminosterol consecutively, and the catshark and dogfish aminosterol extract showed greater levels of bioactivity against all selected bacterial pathogens, with S. aureus showing highest susceptibility levels to both extracts. A total of 22 compounds were observed in the developed plates with two compounds (Rf 0.53 and 0.79) showing antimicrobial activity. Certain shark liver extracts possess antimicrobial properties that have the potential to be used in the development of new antimicrobial drugs.
- Full Text:
- Date Issued: 2017
Screening of shark liver extracts for potential antimicrobial properties against selected pathogenic bacterial strains
- Authors: Mrwetyana, Thandolwethu
- Date: 2017
- Subjects: Fishes -- Diseases Pathogenic bacteria Antibiotics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12982 , vital:39413
- Description: The growing problem of antimicrobial resistance prevents the effective treatment of bacterial infections. Traditional antibiotics such as penicillin have been rendered ineffective against most microbial pathogens. This has led to an increased need for the development of new and improved drugs. The marine environment contains a great array of organisms with unique biological properties, but still remains one of our most underutilized biological resources. The aim of this study was to screen different shark liver extracts for antimicrobial properties. After optimizing the extraction methods, the liver extracts (oil and aminosterol) of three different shark species, namely the Dogfish (Squalus acanthias), the Catshark (Scyliorhinus capensis) and the Hammerhead (Sphyrna zygaena) shark, were screened for antimicrobial properties using the Kirby-Bauer disc diffusion method against selected bacterial pathogens (Helicobacter pylori, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Bacillus cereus), after which the MIC was determined using the modified broth micro-dilution described by Vollekova et al. (2001). The most active extract was fractionated using thin layer chromatography, and TLC-direct bioautography was used to determine the antimicrobial properties of the fractionated compounds. The Folch et al and the Shinnar et al methods yielded the highest extract volumes for oil and aminosterol consecutively, and the catshark and dogfish aminosterol extract showed greater levels of bioactivity against all selected bacterial pathogens, with S. aureus showing highest susceptibility levels to both extracts. A total of 22 compounds were observed in the developed plates with two compounds (Rf 0.53 and 0.79) showing antimicrobial activity. Certain shark liver extracts possess antimicrobial properties that have the potential to be used in the development of new antimicrobial drugs.
- Full Text:
- Date Issued: 2017
- Authors: Mrwetyana, Thandolwethu
- Date: 2017
- Subjects: Fishes -- Diseases Pathogenic bacteria Antibiotics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12982 , vital:39413
- Description: The growing problem of antimicrobial resistance prevents the effective treatment of bacterial infections. Traditional antibiotics such as penicillin have been rendered ineffective against most microbial pathogens. This has led to an increased need for the development of new and improved drugs. The marine environment contains a great array of organisms with unique biological properties, but still remains one of our most underutilized biological resources. The aim of this study was to screen different shark liver extracts for antimicrobial properties. After optimizing the extraction methods, the liver extracts (oil and aminosterol) of three different shark species, namely the Dogfish (Squalus acanthias), the Catshark (Scyliorhinus capensis) and the Hammerhead (Sphyrna zygaena) shark, were screened for antimicrobial properties using the Kirby-Bauer disc diffusion method against selected bacterial pathogens (Helicobacter pylori, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus and Bacillus cereus), after which the MIC was determined using the modified broth micro-dilution described by Vollekova et al. (2001). The most active extract was fractionated using thin layer chromatography, and TLC-direct bioautography was used to determine the antimicrobial properties of the fractionated compounds. The Folch et al and the Shinnar et al methods yielded the highest extract volumes for oil and aminosterol consecutively, and the catshark and dogfish aminosterol extract showed greater levels of bioactivity against all selected bacterial pathogens, with S. aureus showing highest susceptibility levels to both extracts. A total of 22 compounds were observed in the developed plates with two compounds (Rf 0.53 and 0.79) showing antimicrobial activity. Certain shark liver extracts possess antimicrobial properties that have the potential to be used in the development of new antimicrobial drugs.
- Full Text:
- Date Issued: 2017
Seasonal physiological and behavioural responses of a small bird in a hot, arid habitat
- Authors: Pattinson, Nicholas Bruce
- Date: 2017
- Subjects: Birds -- Behavior Birds -- Physiology , Birds -- Ecophysiology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/19728 , vital:28948
- Description: The role that climate plays in the ecology of organisms is perhaps the most pronounced where the earth’s environments are most extreme. In arid-zones, organisms have to deal with large seasonal shifts and/or extremes in temperature and/or moisture levels. As a result, arid-zone species are sensitive to climatic changes. I assessed the physiological and behavioural adjustments of an arid-zone endemic passerine, the rufous-eared warbler (Malcorus pectoralis), to seasonal changes in the Karoo semi-desert of South Africa. Respirometry measurements in the field showed that the warblers’ basal metabolic rate was lower and set point body temperature (Tb) was higher in summer compared to winter. At high air temperatures (Ta) evaporative water loss (EWL) rate was significantly lower in summer compared to winter, while Tb showed a clear pattern of heterothermy that was similar in both seasons. Compared to winter, the warblers in summer were able to remain calm, and tolerate higher Ta’s, before their Tb’s increased to potentially detrimental levels. Behavioural observations showed that free-living warblers exhibited significant temperature-dependence in their behaviour; they increased panting behaviour, and reduced activity levels, time spent preening, and foraging effort at high Ta’s in summer. The warblers also displayed a considerable decrease in foraging success, and a shift in microsite use, at high Ta’s in summer. I hypothesise that the flexible responses the rufous-eared warblers show are aimed at increasing their heat tolerance in summer, and help them balance their energy and water demands in an arid environment that exhibits wide seasonality in Ta, in addition to high summer Ta. My findings emphasise the importance of identifying, as well as understanding, the associated costs of physiological and behavioural responses to environmental variables. This information is valuable in terms of predicting biologically meaningful responses (and hence, vulnerability) of arid-zone avian communities to climactic shifts.
- Full Text:
- Date Issued: 2017
- Authors: Pattinson, Nicholas Bruce
- Date: 2017
- Subjects: Birds -- Behavior Birds -- Physiology , Birds -- Ecophysiology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/19728 , vital:28948
- Description: The role that climate plays in the ecology of organisms is perhaps the most pronounced where the earth’s environments are most extreme. In arid-zones, organisms have to deal with large seasonal shifts and/or extremes in temperature and/or moisture levels. As a result, arid-zone species are sensitive to climatic changes. I assessed the physiological and behavioural adjustments of an arid-zone endemic passerine, the rufous-eared warbler (Malcorus pectoralis), to seasonal changes in the Karoo semi-desert of South Africa. Respirometry measurements in the field showed that the warblers’ basal metabolic rate was lower and set point body temperature (Tb) was higher in summer compared to winter. At high air temperatures (Ta) evaporative water loss (EWL) rate was significantly lower in summer compared to winter, while Tb showed a clear pattern of heterothermy that was similar in both seasons. Compared to winter, the warblers in summer were able to remain calm, and tolerate higher Ta’s, before their Tb’s increased to potentially detrimental levels. Behavioural observations showed that free-living warblers exhibited significant temperature-dependence in their behaviour; they increased panting behaviour, and reduced activity levels, time spent preening, and foraging effort at high Ta’s in summer. The warblers also displayed a considerable decrease in foraging success, and a shift in microsite use, at high Ta’s in summer. I hypothesise that the flexible responses the rufous-eared warblers show are aimed at increasing their heat tolerance in summer, and help them balance their energy and water demands in an arid environment that exhibits wide seasonality in Ta, in addition to high summer Ta. My findings emphasise the importance of identifying, as well as understanding, the associated costs of physiological and behavioural responses to environmental variables. This information is valuable in terms of predicting biologically meaningful responses (and hence, vulnerability) of arid-zone avian communities to climactic shifts.
- Full Text:
- Date Issued: 2017
Seasonal variations in tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of extensively raised Boran cows
- Authors: Ntilini, Wonga John
- Date: 2017
- Subjects: Boran cattle -- South Africa Ticks -- South Africa
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/13471 , vital:39672
- Description: This study sought to determine the seasonal variations in tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of Boran cows reared in arid rangelands of South Africa. A total of 20 Boran cows of different age groups were used in this study. Tick counts, hair length, coat score, average temperature and relative humidity readings were measured twice (beginning and end) in each season (post-rainy, cold-dry, hot-dry, hot-wet). Blood samples were taken seasonally (beginning and end of the season) for the analysis of creatine kinase (CK) activity and haematological parameters (HP). Ticks were observed and counted from different anatomical sites, namely anterior (neck, head, ears, and around eyes), ventral (belly, udder, and limbs) and posterior (back and under the tail). The tick species observed from the Boran cows were Rhipicephalus evertsi evertsi (34.58percent), Amblyomma hebreaum (43.35percent), Rhipicephalus simus (4.48percent) and Rhipicephalus (Boophilus) decoloratus (17.59percent). Significant differences were observed in tick burdens at various anatomical sites, with posterior position having the highest tick loads during the post-rainy, cold-dry and hot-dry season. While the ventral position recorded the highest tick loads during the hot-wet season. It was also observed that the cattle had significantly long hair lengths during the cold-dry season. Furthermore, coat score and hair length were observed to be negatively (P<0.05) correlated with tick counts, while coat scores were positively (P<0.05) correlated with hair length. Significant differences were observed in CK activity across season, with higher levels during the hot-dry and hot-wet seasons compared to the post-rainy and cold-dry seasons. Boran cows were exposed to a mild stress condition during the hot-dry and hot-wet season when the THI values were high (>70). Seasonal variations had an effect (P<0.05) on some HP (HB, HCT, MCV, MCH, EOS, and BAS). Neutrophils (-0.267) and basophils (0.268) were significantly correlated with THI. In conclusion, the Boran cows were more susceptible to tick loads during the hot seasons. Likewise, the levels of creatine kinase activity and temperature-humidity index were high during the hot-dry and hot-wet season. Therefore, seasonal variations had an effect on tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of extensively raised Boran cows.
- Full Text:
- Date Issued: 2017
- Authors: Ntilini, Wonga John
- Date: 2017
- Subjects: Boran cattle -- South Africa Ticks -- South Africa
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/13471 , vital:39672
- Description: This study sought to determine the seasonal variations in tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of Boran cows reared in arid rangelands of South Africa. A total of 20 Boran cows of different age groups were used in this study. Tick counts, hair length, coat score, average temperature and relative humidity readings were measured twice (beginning and end) in each season (post-rainy, cold-dry, hot-dry, hot-wet). Blood samples were taken seasonally (beginning and end of the season) for the analysis of creatine kinase (CK) activity and haematological parameters (HP). Ticks were observed and counted from different anatomical sites, namely anterior (neck, head, ears, and around eyes), ventral (belly, udder, and limbs) and posterior (back and under the tail). The tick species observed from the Boran cows were Rhipicephalus evertsi evertsi (34.58percent), Amblyomma hebreaum (43.35percent), Rhipicephalus simus (4.48percent) and Rhipicephalus (Boophilus) decoloratus (17.59percent). Significant differences were observed in tick burdens at various anatomical sites, with posterior position having the highest tick loads during the post-rainy, cold-dry and hot-dry season. While the ventral position recorded the highest tick loads during the hot-wet season. It was also observed that the cattle had significantly long hair lengths during the cold-dry season. Furthermore, coat score and hair length were observed to be negatively (P<0.05) correlated with tick counts, while coat scores were positively (P<0.05) correlated with hair length. Significant differences were observed in CK activity across season, with higher levels during the hot-dry and hot-wet seasons compared to the post-rainy and cold-dry seasons. Boran cows were exposed to a mild stress condition during the hot-dry and hot-wet season when the THI values were high (>70). Seasonal variations had an effect (P<0.05) on some HP (HB, HCT, MCV, MCH, EOS, and BAS). Neutrophils (-0.267) and basophils (0.268) were significantly correlated with THI. In conclusion, the Boran cows were more susceptible to tick loads during the hot seasons. Likewise, the levels of creatine kinase activity and temperature-humidity index were high during the hot-dry and hot-wet season. Therefore, seasonal variations had an effect on tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of extensively raised Boran cows.
- Full Text:
- Date Issued: 2017
Sedimentary, geochemical and geophysical study of the Ecca group, Karoo supergroup and its hydrocarbon potential in the Eastern Cape Province, South Africa
- Authors: Baiyegunhi, Christopher
- Date: 2017
- Subjects: Sediments (Geology) -- South Africa -- Eastern Cape Sedimentology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/4881 , vital:28658
- Description: The Ecca Group of Karoo Supergroup is a sedimentary rock sequence that deposited between the Late Carboniferous (Dwyka Group) and the Late Permian-Middle Triassic (Beaufort Group). The Ecca Group investigated in this study is situated in the Eastern Cape Province of South Africa and it comprises mainly of shales, mudstones, siltstones and sandstones. The Ecca Group sequence contains considerable carbon content and suitable thickness to make it an ideal target for shale gas exploration. Previous studies put more emphasis on the geology and stratigraphy of the Ecca Group, this study revised the stratigraphy, and put new insight on the petrography, depositional processes, sedimentary facies, provenance, paleoweathering, tectonic setting, subsidence rates and history, electrical resistivity, source rock characteristics and diagenesis of the potentially feasible sandstone and mudrock reservoir rocks of the Ecca Group. Based on the lithological features, sedimentary structures and facies characteristics, the stratigraphy of the Prince Albert, Whitehill, Collingham and Fort Brown Formations of the Ecca Group is now subdivided into two informal members each, i.e. Lower Member and Upper Member. Furthermore, the Ripon Formation is now subdivided into three informal members. Each member has been asigned a lithological name. The grain size parameters show that most of the Ecca Group sandstones are very fine to fine grained, poorly to moderately well sorted, mostly near-symmetrical and mesokurtic in grain-size distribution. The linear discriminant function analysis is dominantly indicative of turbidity current deposits under deep marine environment for Prince Albert, Whitehill and Collingham Formations, shallow marine environment for Ripon Formation, while the Fort Brown Formation is lacustrine-deltaic deposits. Modal composition analysis and petrography studies revealed that the detrital components of the sandstones are dominated by monocrystalline quartz, feldspar and lithic fragments. The sandstones are compositionally and texturally immature and can be classified as feldspathic wacke and lithic wacke. The provenance analysis revealed plutonic and metamorphic terrains as the main source rocks with minor debris derived from recycled sedimentary rocks. The detrital modal compositions of these sandstones are related to back arc to island and continental margin of tectonic setting. Based on the detailed sedimentological analyses of outcrop and borehole data, fourteen lithofacies were identified and seven facies associations (FAs) were recognised. The facies associations are: FA 1: Shale and mudstones intercalated with siltstones, FA 2: Carbonaceous shale, mudstone with subordinate chert and sandstone, FA 3: Mudstones rhythmite with thin bedded mudstone and lenticular siltstone, FA 4: Greyish medium bedded sandstone intercalated with laminated mudstone, FA 5: Dark-grey medium to thick bedded mudstone and siltstone, FA 6: Thin to medium bedded sandstone alternated with thin bedded carbonaceous mudstone, and FA 7: Varved mudstone rhythmite intercalated with siltstone and minor sandstone. Sedimentological characteristics of the identified facies associations indicate four deposition environments, namely, deep marine basin, turbidite, shallow marine and lacustrine environments, which constitute a gradually regression sequence as a result of sea-level dropping and shallowing of the basin during the developmental processes. Geochemical analysis of the Ecca mudrocks and sandstones revealed that the rocks are of quartzose sedimentary provenance, suggesting that they were derived from a cratonic interior or recycled orogen. The petrography and geochemistry of the sandstones indicated that the source areas are composed of plutonic and metamorphic rocks with a minor component from sedimentary rocks. The geochemical diagrams and indices of weathering suggested that the granitic source rocks underwent moderate to high degree of chemical weathering. The tectonic setting discrimination diagrams support passive continental margin setting of the provenance.
- Full Text:
- Date Issued: 2017
- Authors: Baiyegunhi, Christopher
- Date: 2017
- Subjects: Sediments (Geology) -- South Africa -- Eastern Cape Sedimentology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/4881 , vital:28658
- Description: The Ecca Group of Karoo Supergroup is a sedimentary rock sequence that deposited between the Late Carboniferous (Dwyka Group) and the Late Permian-Middle Triassic (Beaufort Group). The Ecca Group investigated in this study is situated in the Eastern Cape Province of South Africa and it comprises mainly of shales, mudstones, siltstones and sandstones. The Ecca Group sequence contains considerable carbon content and suitable thickness to make it an ideal target for shale gas exploration. Previous studies put more emphasis on the geology and stratigraphy of the Ecca Group, this study revised the stratigraphy, and put new insight on the petrography, depositional processes, sedimentary facies, provenance, paleoweathering, tectonic setting, subsidence rates and history, electrical resistivity, source rock characteristics and diagenesis of the potentially feasible sandstone and mudrock reservoir rocks of the Ecca Group. Based on the lithological features, sedimentary structures and facies characteristics, the stratigraphy of the Prince Albert, Whitehill, Collingham and Fort Brown Formations of the Ecca Group is now subdivided into two informal members each, i.e. Lower Member and Upper Member. Furthermore, the Ripon Formation is now subdivided into three informal members. Each member has been asigned a lithological name. The grain size parameters show that most of the Ecca Group sandstones are very fine to fine grained, poorly to moderately well sorted, mostly near-symmetrical and mesokurtic in grain-size distribution. The linear discriminant function analysis is dominantly indicative of turbidity current deposits under deep marine environment for Prince Albert, Whitehill and Collingham Formations, shallow marine environment for Ripon Formation, while the Fort Brown Formation is lacustrine-deltaic deposits. Modal composition analysis and petrography studies revealed that the detrital components of the sandstones are dominated by monocrystalline quartz, feldspar and lithic fragments. The sandstones are compositionally and texturally immature and can be classified as feldspathic wacke and lithic wacke. The provenance analysis revealed plutonic and metamorphic terrains as the main source rocks with minor debris derived from recycled sedimentary rocks. The detrital modal compositions of these sandstones are related to back arc to island and continental margin of tectonic setting. Based on the detailed sedimentological analyses of outcrop and borehole data, fourteen lithofacies were identified and seven facies associations (FAs) were recognised. The facies associations are: FA 1: Shale and mudstones intercalated with siltstones, FA 2: Carbonaceous shale, mudstone with subordinate chert and sandstone, FA 3: Mudstones rhythmite with thin bedded mudstone and lenticular siltstone, FA 4: Greyish medium bedded sandstone intercalated with laminated mudstone, FA 5: Dark-grey medium to thick bedded mudstone and siltstone, FA 6: Thin to medium bedded sandstone alternated with thin bedded carbonaceous mudstone, and FA 7: Varved mudstone rhythmite intercalated with siltstone and minor sandstone. Sedimentological characteristics of the identified facies associations indicate four deposition environments, namely, deep marine basin, turbidite, shallow marine and lacustrine environments, which constitute a gradually regression sequence as a result of sea-level dropping and shallowing of the basin during the developmental processes. Geochemical analysis of the Ecca mudrocks and sandstones revealed that the rocks are of quartzose sedimentary provenance, suggesting that they were derived from a cratonic interior or recycled orogen. The petrography and geochemistry of the sandstones indicated that the source areas are composed of plutonic and metamorphic rocks with a minor component from sedimentary rocks. The geochemical diagrams and indices of weathering suggested that the granitic source rocks underwent moderate to high degree of chemical weathering. The tectonic setting discrimination diagrams support passive continental margin setting of the provenance.
- Full Text:
- Date Issued: 2017