Performance of an integrated algal pond for treatment of domestic sewage: a process audit
- Authors: Dube, Anele
- Date: 2020
- Subjects: Water -- Purification , Sewage -- Purification -- Anaerobic treatment , Algae -- Biotechnology , Waste disposal -- South Africa , Integrated algae pond systems (IAPS)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/167043 , vital:41432
- Description: Integrated algae pond systems (IAPS) are energy efficient, robust, passive systems that use the principles of fermentation, photosynthesis and microbial metabolism to remediate wastewater, producing a good quality effluent with reuse potential. In addition to the treatment of wastewater, IAPS have the ability to generate two additional product streams viz. biogas and biomass. The latter adds to the attractiveness of the system. However, the implementation of this technology, like many passive systems, has remained limited at a commercial scale, and the inclination is still towards grey technologies. The aim of this research was to investigate the capabilities and potential of a demonstration-scale IAPS and use results obtained to establish a process audit framework. The aspects considered for the audit included performance efficiency, effluent water quality, biomass composition, quantity and productivity within the ponds, and cost analysis of operation and maintenance over a 9-year period. Plant performance was closely monitored during the course of the study and this led to a review of previously adopted plant management strategies. Troubleshooting exercises were also carried out when plant performance declined. Results showed that IAPS efficiently reduced standard water parameters with the exception of pH, dissolved oxygen, and nitrate whose values increased from raw influent to final effluent. The following water quality parameters were established for the final effluent: total suspended solids 55 ± 7.1 mg. L-1 (n = 28); chemical oxygen demand 94.1 ± 10.6 mg. L-1 (n = 28) (after removal of algae); pH 9.9 ± 0.01 (n = 26); ammonium nitrogen 1.7 ± 0.3 mg. L-1 (n = 25); nitrate 3.3 ± 0.6 mg. L-1 (n = 25); ortho-phosphate 1.6 ± 0.2 mg. L-1 (n = 25); electrical conductivity 98.7 ± 2.0 mS m-1 (n = 26) and faecal coliforms (per 100 mL) 1482.6 ± 636.0 (n = 24). The final effluent measured consistently high chemical oxygen demand and total suspended solids, however close analysis showed that total suspended solids could be controlled by increasing the frequency of removal of settled biomass within the settling ponds. Biomass produced contained microalgae, bacteria, metazoa, and protozoa. The biomass productivity achieved was as high as 130.6 kg ha-1 d-1; however, about 33% was lost to the final effluent due to inadequate settling. Results obtained during the course of this study and outcomes of earlier work on IAPS are taken as the baseline to determine parameters needed for the development of the process audit framework. Techniques utilised to derive the blue print process audit protocol for IAPS included a turtle diagram, a flow diagram and a checklist. Attention to plant management proved vital in determining overall performance. Cost, including operating and maintenance, of treating water using the demonstration scale system on a per person equivalent per year basis was determined as ZAR 123.87 (where, ZAR to USD = 0.07).
- Full Text:
- Date Issued: 2020
- Authors: Dube, Anele
- Date: 2020
- Subjects: Water -- Purification , Sewage -- Purification -- Anaerobic treatment , Algae -- Biotechnology , Waste disposal -- South Africa , Integrated algae pond systems (IAPS)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/167043 , vital:41432
- Description: Integrated algae pond systems (IAPS) are energy efficient, robust, passive systems that use the principles of fermentation, photosynthesis and microbial metabolism to remediate wastewater, producing a good quality effluent with reuse potential. In addition to the treatment of wastewater, IAPS have the ability to generate two additional product streams viz. biogas and biomass. The latter adds to the attractiveness of the system. However, the implementation of this technology, like many passive systems, has remained limited at a commercial scale, and the inclination is still towards grey technologies. The aim of this research was to investigate the capabilities and potential of a demonstration-scale IAPS and use results obtained to establish a process audit framework. The aspects considered for the audit included performance efficiency, effluent water quality, biomass composition, quantity and productivity within the ponds, and cost analysis of operation and maintenance over a 9-year period. Plant performance was closely monitored during the course of the study and this led to a review of previously adopted plant management strategies. Troubleshooting exercises were also carried out when plant performance declined. Results showed that IAPS efficiently reduced standard water parameters with the exception of pH, dissolved oxygen, and nitrate whose values increased from raw influent to final effluent. The following water quality parameters were established for the final effluent: total suspended solids 55 ± 7.1 mg. L-1 (n = 28); chemical oxygen demand 94.1 ± 10.6 mg. L-1 (n = 28) (after removal of algae); pH 9.9 ± 0.01 (n = 26); ammonium nitrogen 1.7 ± 0.3 mg. L-1 (n = 25); nitrate 3.3 ± 0.6 mg. L-1 (n = 25); ortho-phosphate 1.6 ± 0.2 mg. L-1 (n = 25); electrical conductivity 98.7 ± 2.0 mS m-1 (n = 26) and faecal coliforms (per 100 mL) 1482.6 ± 636.0 (n = 24). The final effluent measured consistently high chemical oxygen demand and total suspended solids, however close analysis showed that total suspended solids could be controlled by increasing the frequency of removal of settled biomass within the settling ponds. Biomass produced contained microalgae, bacteria, metazoa, and protozoa. The biomass productivity achieved was as high as 130.6 kg ha-1 d-1; however, about 33% was lost to the final effluent due to inadequate settling. Results obtained during the course of this study and outcomes of earlier work on IAPS are taken as the baseline to determine parameters needed for the development of the process audit framework. Techniques utilised to derive the blue print process audit protocol for IAPS included a turtle diagram, a flow diagram and a checklist. Attention to plant management proved vital in determining overall performance. Cost, including operating and maintenance, of treating water using the demonstration scale system on a per person equivalent per year basis was determined as ZAR 123.87 (where, ZAR to USD = 0.07).
- Full Text:
- Date Issued: 2020
Petits récits: creative perspectives of Chinese encounters in Zambia
- Authors: Mwaba, Stary
- Date: 2020
- Subjects: Personal narratives , Lyotard, Jean-François, 1924-1998 , Art and society -- Zambia , Social practice (Art) -- Zambia , Art and globalization -- Zambia , China -- Relations -- Zambia , Storytelling in art , Colonization in art
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: http://hdl.handle.net/10962/146355 , vital:38518
- Description: This mini-thesis, which supports my MFA exhibition Black Mountain, articulates on-the- ground creative perspectives of the Zambia-China discourse, through the representation of little narratives - les petits récits - connected to personal experiences. Through my creative production as an artist, I respond to perceptions of the Chinese presence in Africa. I utilize historical and contemporary personal narratives to complicate existing perceptions of Chinese presence in my home context of Zambia. “Petit récits”, or “little narratives”, in Francois Lyotard’s term, refers to personal stories of individuals that subvert dominant master-narratives and their legitimization in social-cultural structure. In the case of China’s presence in Zambia, I refer to the dichotomized narratives in the media as metanarratives which pay little attention to the people on the ground and propose the approach of “little narratives” to foreground the lived experiences of Zambians who have individual encounters with Chinese in various social spaces. By employing the narratives of my family members through installations, paintings, and drawings, I intervene in a broader China-Africa discourse that is often driven by economics and politics, and I attach importance to the little narratives. In my thesis I divide my material into three chapters; each chapter grows out of an encounter with the presence of China (and Chinese people) in Zambia in relation to the very personal narratives of family members - Zoë my daughter, my grandma, and Ngolo my cousin. The first chapter focuses on my work Chinese Cabbage as my entry point to this topic, which is based on a school experiment I did with my daughter Zoë. In this chapter I also discuss the current discourses around China’s presence. Chapter two revisits the Zambian-Chinese historical encounters in memory of my grandma’s insaka stories about the construction of TAZARA Railway, and thus my works discussed in this chapter attach importance to the individual engagements from a historical perspective. Chapter three discusses in particular the controversial issues around Black Mountain and the works inspired by my cousin Ngolo’s stories of mining in Black Mountain and dealing with the Chinese traders.
- Full Text:
- Date Issued: 2020
- Authors: Mwaba, Stary
- Date: 2020
- Subjects: Personal narratives , Lyotard, Jean-François, 1924-1998 , Art and society -- Zambia , Social practice (Art) -- Zambia , Art and globalization -- Zambia , China -- Relations -- Zambia , Storytelling in art , Colonization in art
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: http://hdl.handle.net/10962/146355 , vital:38518
- Description: This mini-thesis, which supports my MFA exhibition Black Mountain, articulates on-the- ground creative perspectives of the Zambia-China discourse, through the representation of little narratives - les petits récits - connected to personal experiences. Through my creative production as an artist, I respond to perceptions of the Chinese presence in Africa. I utilize historical and contemporary personal narratives to complicate existing perceptions of Chinese presence in my home context of Zambia. “Petit récits”, or “little narratives”, in Francois Lyotard’s term, refers to personal stories of individuals that subvert dominant master-narratives and their legitimization in social-cultural structure. In the case of China’s presence in Zambia, I refer to the dichotomized narratives in the media as metanarratives which pay little attention to the people on the ground and propose the approach of “little narratives” to foreground the lived experiences of Zambians who have individual encounters with Chinese in various social spaces. By employing the narratives of my family members through installations, paintings, and drawings, I intervene in a broader China-Africa discourse that is often driven by economics and politics, and I attach importance to the little narratives. In my thesis I divide my material into three chapters; each chapter grows out of an encounter with the presence of China (and Chinese people) in Zambia in relation to the very personal narratives of family members - Zoë my daughter, my grandma, and Ngolo my cousin. The first chapter focuses on my work Chinese Cabbage as my entry point to this topic, which is based on a school experiment I did with my daughter Zoë. In this chapter I also discuss the current discourses around China’s presence. Chapter two revisits the Zambian-Chinese historical encounters in memory of my grandma’s insaka stories about the construction of TAZARA Railway, and thus my works discussed in this chapter attach importance to the individual engagements from a historical perspective. Chapter three discusses in particular the controversial issues around Black Mountain and the works inspired by my cousin Ngolo’s stories of mining in Black Mountain and dealing with the Chinese traders.
- Full Text:
- Date Issued: 2020
Petrographic and geochemical characterisation of the hangingwall and the footwall rocks (the Dipeta and R.A.T. stratigraphic units) to the Kinsevere and Nambulwa copper ore deposits of the Lufilian Arc, southern Democratic Republic of Congo
- Authors: Nkulu, Robert Kankomba
- Date: 2020
- Subjects: Petrogenesis -- Congo (Democratic Republic) , Analytical geochemistry -- Congo (Democratic Republic) , Copper ores -- Congo (Democratic Republic) , Ore deposits -- Congo (Democratic Republic) , Katangan Sequence , Geological mapping -- Congo (Democratic Republic) , Central African Copperbelt (Congo and Zambia) , Lufilian Arc , Neoproterozoic Katangan R.A.T. (Roches Argilo Talqueuse) Subgroup , Dipeta Subgroup
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/142772 , vital:38115
- Description: The Kinsevere and Nambulwa copper deposits in the Democratic Republic of Congo (D.R.C.) are set in the eastern side of the Neoproterozoic Katanga Supergroup, forming the Lufilian Arc, resulting from a cratonic collision between the Congo and the Kalahari Cratons (ca.620-570_Ma). The Katanga Supergroup was deposited in an extensional rift setting with a sedimentary thickness succession ranging between 7 to 10 km, sub-divided into: − the Roan, the Nguba and the Kundelungu Groups. The stratigraphic column of the Roan Group consists of the R.A.T. (Roche Argilo Talqueuse), the Mines, the Dipeta and the Mwashya Subgroups. Three major deformation phases have been described characterised by complex multiphase tectonics related to a curved superposition of folded, thrust and sheared blocks. The rocks of the R.A.T., Mines and Dipeta Subgroups are recognised as blocks that occur within a stratiform to discordant and diapiritic megabreccia. The blocks were rafted upward with salt tectonics, resulting in the juxtaposition with the hangingwall and the footwall terranes. Therefore, in that context it has been found that the Dipeta may appear overlying the R.A.T. Subgroup through the unconformity decollement surface of heterogeneous breccia. The petrographic observations made of the R.A.T. and Dipeta samples indicates in both units the presence of detrital quartz and feldspar that have been altered and replaced by sericite and muscovite minerals. Gypsum is intimately associated with magnesite, showing an evaporitic environment domain, while magnesite is common as alteration phase both in the R.A.T. and Dipeta Subgroups. Pyrophyllite has been observed in the Dipeta, resulting from reaction of silica with the Kaolinite at low temperature. Accessory detrital minerals include zircon, as well as xenotime intergrown with altered Fe-Ti-oxide hematite, forming complex textures with disseminated Ti-oxides both in R.A.T. and Dipeta units. Major and trace element geochemistry indicates that the Dipeta is more dolomitic and magnesite while the R.A.T. is clay-rich. The Ti2O value of Dipeta and R.A.T samples is relatively low, ranging between 0.36 and 0.69 wt.% respectively, which suggest highly evolved felsic material in the protolith. This is consistent with interpretation based on the Al2O3/TiO2 ratio, which ranges between 18 and 23 for the R.A.T. and Dipeta respectively, indicating an intermediate to felsic granitoids as the protolith of R.A.T. and Dipeta siltstones. The Ti/Zr ratio of R.A.T. and Dipeta samples of less than 10, while, the higher La/Sc ratio of between 2.6 and 5.5 (for the R.A.T. and Dipeta respectively) indicate that both the R.A.T. and Dipeta are active continental and passive margin tectonic setting. Based on the geochemical variation with depth across the R.A.T. and Dipeta and their contact zone, a geochemical fingerprinting suggests that the ratio TiO2/Al2O3 appears to be useful and could be considered as a stratigraphic geochemical maker able to discriminate the R.A.T. and the Dipeta Subgroups during the geological mapping.
- Full Text:
- Date Issued: 2020
- Authors: Nkulu, Robert Kankomba
- Date: 2020
- Subjects: Petrogenesis -- Congo (Democratic Republic) , Analytical geochemistry -- Congo (Democratic Republic) , Copper ores -- Congo (Democratic Republic) , Ore deposits -- Congo (Democratic Republic) , Katangan Sequence , Geological mapping -- Congo (Democratic Republic) , Central African Copperbelt (Congo and Zambia) , Lufilian Arc , Neoproterozoic Katangan R.A.T. (Roches Argilo Talqueuse) Subgroup , Dipeta Subgroup
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/142772 , vital:38115
- Description: The Kinsevere and Nambulwa copper deposits in the Democratic Republic of Congo (D.R.C.) are set in the eastern side of the Neoproterozoic Katanga Supergroup, forming the Lufilian Arc, resulting from a cratonic collision between the Congo and the Kalahari Cratons (ca.620-570_Ma). The Katanga Supergroup was deposited in an extensional rift setting with a sedimentary thickness succession ranging between 7 to 10 km, sub-divided into: − the Roan, the Nguba and the Kundelungu Groups. The stratigraphic column of the Roan Group consists of the R.A.T. (Roche Argilo Talqueuse), the Mines, the Dipeta and the Mwashya Subgroups. Three major deformation phases have been described characterised by complex multiphase tectonics related to a curved superposition of folded, thrust and sheared blocks. The rocks of the R.A.T., Mines and Dipeta Subgroups are recognised as blocks that occur within a stratiform to discordant and diapiritic megabreccia. The blocks were rafted upward with salt tectonics, resulting in the juxtaposition with the hangingwall and the footwall terranes. Therefore, in that context it has been found that the Dipeta may appear overlying the R.A.T. Subgroup through the unconformity decollement surface of heterogeneous breccia. The petrographic observations made of the R.A.T. and Dipeta samples indicates in both units the presence of detrital quartz and feldspar that have been altered and replaced by sericite and muscovite minerals. Gypsum is intimately associated with magnesite, showing an evaporitic environment domain, while magnesite is common as alteration phase both in the R.A.T. and Dipeta Subgroups. Pyrophyllite has been observed in the Dipeta, resulting from reaction of silica with the Kaolinite at low temperature. Accessory detrital minerals include zircon, as well as xenotime intergrown with altered Fe-Ti-oxide hematite, forming complex textures with disseminated Ti-oxides both in R.A.T. and Dipeta units. Major and trace element geochemistry indicates that the Dipeta is more dolomitic and magnesite while the R.A.T. is clay-rich. The Ti2O value of Dipeta and R.A.T samples is relatively low, ranging between 0.36 and 0.69 wt.% respectively, which suggest highly evolved felsic material in the protolith. This is consistent with interpretation based on the Al2O3/TiO2 ratio, which ranges between 18 and 23 for the R.A.T. and Dipeta respectively, indicating an intermediate to felsic granitoids as the protolith of R.A.T. and Dipeta siltstones. The Ti/Zr ratio of R.A.T. and Dipeta samples of less than 10, while, the higher La/Sc ratio of between 2.6 and 5.5 (for the R.A.T. and Dipeta respectively) indicate that both the R.A.T. and Dipeta are active continental and passive margin tectonic setting. Based on the geochemical variation with depth across the R.A.T. and Dipeta and their contact zone, a geochemical fingerprinting suggests that the ratio TiO2/Al2O3 appears to be useful and could be considered as a stratigraphic geochemical maker able to discriminate the R.A.T. and the Dipeta Subgroups during the geological mapping.
- Full Text:
- Date Issued: 2020
Petrography, metamorphism, deformation and P-T conditions in the western arm of the Lufilian Arc - Zambezi, north-western Zambia
- Authors: Chilekwa, Mwango
- Date: 2020
- Subjects: Petrogenesis -- Zambia -- Zambezi District , Metamorphism (Geology) -- Zambia -- Zambezi District , Petrology -- Zambia -- Zambezi District , Formations (Geology) -- Zambia -- Zambezi District , Rock deformation -- Zambia -- Zambezi District , Lufilian Arc , Neoproterozoic Katangan R.A.T. (Roches Argilo Talqueuse) Subgroup
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/161971 , vital:40699
- Description: The Zambezi area in north-western Zambia is underlain by Neoproterozoic Katanga Supergroup and older, Archean to Mesoproterozoic Basement Supergroup rocks. The area lies within the Domes Region, which is a structural domain of the Lufilian Arc. The stratigraphic succession within Zambezi area is dominated by the Grand Conglomerate Formation (GC) and Mwashia Group which are the most extensive units, and the less abundant Lower and Upper Roan Groups of the Katanga Supergroup. They wrap around the domal Basement Supergroup units. The mineral assemblage of the Mwashia and the GC schists commonly contains garnet, anthophyllite and biotite. GC rocks show remnants of primary structures such as clasts and sedimentary features. Anthophyllite, garnet and biotite are the dominant Mg-Fe rich metamorphic minerals. However, these are iron rich for each mineral phase and has been attributed to iron rich protoliths. The earliest recognised deformation episode (D1) formed NE-SW S1 foliations within GC which is consistent with the regional structural trend in the western Lufilian Arc. S1 was later affected by D2 that generated downward facing F2 folds and S2 foliations. The other associated feature to D2 is garnet that grew as the result of pro-grade metamorphism. The D3 deformation fabric is not developed and did not affect much of the structural geometry of the Zambezi area. The peak assemblages of the Basement Supergroup and the Katanga Supergroup formed at mid-amphibolite facies conditions of 590 °C and 630 °C at an average pressure of 4.0 kbar. The Basement Supergroup has undergone retrograde metamorphism to greenschist facies condition indicated by presence of chlorite and also determined by biotite-anorthite isopleth in THERIAK DOMINO. At the eastern part of Zambezi area, the Katanga Supergroup rocks were retrogressed in the upper greenschist facies at about ~470°C and ~4.0 kbar due to isobaric cooling.
- Full Text:
- Date Issued: 2020
- Authors: Chilekwa, Mwango
- Date: 2020
- Subjects: Petrogenesis -- Zambia -- Zambezi District , Metamorphism (Geology) -- Zambia -- Zambezi District , Petrology -- Zambia -- Zambezi District , Formations (Geology) -- Zambia -- Zambezi District , Rock deformation -- Zambia -- Zambezi District , Lufilian Arc , Neoproterozoic Katangan R.A.T. (Roches Argilo Talqueuse) Subgroup
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/161971 , vital:40699
- Description: The Zambezi area in north-western Zambia is underlain by Neoproterozoic Katanga Supergroup and older, Archean to Mesoproterozoic Basement Supergroup rocks. The area lies within the Domes Region, which is a structural domain of the Lufilian Arc. The stratigraphic succession within Zambezi area is dominated by the Grand Conglomerate Formation (GC) and Mwashia Group which are the most extensive units, and the less abundant Lower and Upper Roan Groups of the Katanga Supergroup. They wrap around the domal Basement Supergroup units. The mineral assemblage of the Mwashia and the GC schists commonly contains garnet, anthophyllite and biotite. GC rocks show remnants of primary structures such as clasts and sedimentary features. Anthophyllite, garnet and biotite are the dominant Mg-Fe rich metamorphic minerals. However, these are iron rich for each mineral phase and has been attributed to iron rich protoliths. The earliest recognised deformation episode (D1) formed NE-SW S1 foliations within GC which is consistent with the regional structural trend in the western Lufilian Arc. S1 was later affected by D2 that generated downward facing F2 folds and S2 foliations. The other associated feature to D2 is garnet that grew as the result of pro-grade metamorphism. The D3 deformation fabric is not developed and did not affect much of the structural geometry of the Zambezi area. The peak assemblages of the Basement Supergroup and the Katanga Supergroup formed at mid-amphibolite facies conditions of 590 °C and 630 °C at an average pressure of 4.0 kbar. The Basement Supergroup has undergone retrograde metamorphism to greenschist facies condition indicated by presence of chlorite and also determined by biotite-anorthite isopleth in THERIAK DOMINO. At the eastern part of Zambezi area, the Katanga Supergroup rocks were retrogressed in the upper greenschist facies at about ~470°C and ~4.0 kbar due to isobaric cooling.
- Full Text:
- Date Issued: 2020
Photo-physicochemical characterization and in vitro Photodynamic Therapy Activity of Phthalocyanine-Graphene Quantum Dots Conjugates
- Authors: Nene, Lindokuhle Cindy
- Date: 2020
- Subjects: Photochemotherapy , Cancer -- Chemotherapy , Quantum dots , Graphene , Nanomedicine
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/140463 , vital:37891
- Description: This thesis reports on the preparation of several differently substituted Zn(II) phthalocyanine (Pc) complexes and their respective graphene quantum dots (GQDs) conjugates. In addition, Pc complexes substituted with biologically active molecules used in cancer therapeutics, namely: benzothiazole and morpholine, were also prepared and conjugated to GQDs. The photo-physicochemical properties were determined for both the complexes and their respective conjugates including the fluorescence/ triplet quantum yields and lifetimes as well as the singlet oxygen generating abilities. Upon conjugation to GQDs, the fluorescence of the Pc complexes decreased (insignificant decrease in some cases), with an increase in the triplet quantum yields. However, the singlet quantum yields of the Pcs in the conjugates did not show an increase with the increase in the triplet quantum yields. This is suspected to be due to the screening effect. The cytotoxicity of the complexes in vitro decreased upon conjugation, as a result of reduced actual number of Pc units provided in the conjugate for therapy. An increase in the efficacy upon quaternization was observed, and a relatively better performance was also observed for the cationic complex in combination with the biotin- functionalized GQDs, 7-GQDs-Biotin. Moreover, the cellular uptake of 7-GQDs-Biotin over 24 h was relatively high compared to complexes alone and other Pcs-GQDs conjugates.
- Full Text:
- Date Issued: 2020
- Authors: Nene, Lindokuhle Cindy
- Date: 2020
- Subjects: Photochemotherapy , Cancer -- Chemotherapy , Quantum dots , Graphene , Nanomedicine
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/140463 , vital:37891
- Description: This thesis reports on the preparation of several differently substituted Zn(II) phthalocyanine (Pc) complexes and their respective graphene quantum dots (GQDs) conjugates. In addition, Pc complexes substituted with biologically active molecules used in cancer therapeutics, namely: benzothiazole and morpholine, were also prepared and conjugated to GQDs. The photo-physicochemical properties were determined for both the complexes and their respective conjugates including the fluorescence/ triplet quantum yields and lifetimes as well as the singlet oxygen generating abilities. Upon conjugation to GQDs, the fluorescence of the Pc complexes decreased (insignificant decrease in some cases), with an increase in the triplet quantum yields. However, the singlet quantum yields of the Pcs in the conjugates did not show an increase with the increase in the triplet quantum yields. This is suspected to be due to the screening effect. The cytotoxicity of the complexes in vitro decreased upon conjugation, as a result of reduced actual number of Pc units provided in the conjugate for therapy. An increase in the efficacy upon quaternization was observed, and a relatively better performance was also observed for the cationic complex in combination with the biotin- functionalized GQDs, 7-GQDs-Biotin. Moreover, the cellular uptake of 7-GQDs-Biotin over 24 h was relatively high compared to complexes alone and other Pcs-GQDs conjugates.
- Full Text:
- Date Issued: 2020
Photocatalysis of 4-chloro and 4-nonylphenols using novel symmetric phthalocyanines and asymmetric porphyrin supported on polyacrylonitrite nanofibres
- Authors: Jones, Benjamin Martin
- Date: 2020
- Subjects: Nanoparticles , Phthalocyanines , Electrospinning , Porphyrins , Nanofibers , Photocatalysis , Photocatalysis -- Environmental aspects
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164770 , vital:41163
- Description: This work explores the synthesis and characterisation of novel symmetrical phthalocyanines and novel asymmetric porphyrins that have been embedded or linked respectively,and electrospun into fibres for application in the photocatalysis of environmental pollutants. The phthalocyanines contain pyrrole moieties without hetero atom linkers to maintain a rigid structure. The porphyrin contains a carboxy moiety utilized to construct an amide bond between the complex and the polymer prior to the spinning process. The new compounds were characterized by elemental analyses, proton nuclear magnetic resonance (HNMR)Fourier-transform infrared spectroscopy (FTIR), MALDI-TOF and UV-vis spectroscopy. The general trends of fluorescence, triplet and singlet oxygen quantum yields are described as well as their appropriate lifetimes. The photocatalytic activity of phthalocyanine embedded fibres were compared against those that had been dyed. Unfortunately, during the degradation process, the dyed fibres leeched compound and the studies could not be continued. It was seen that the porphyrin fibres linked to the polymer showed the most efficient photocatalytic activity against 4-cholorphenol and 4-nonylphenol due to irradiation at lower wavelengths consequently having higher frequencies and transferring more energy.
- Full Text:
- Date Issued: 2020
- Authors: Jones, Benjamin Martin
- Date: 2020
- Subjects: Nanoparticles , Phthalocyanines , Electrospinning , Porphyrins , Nanofibers , Photocatalysis , Photocatalysis -- Environmental aspects
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/164770 , vital:41163
- Description: This work explores the synthesis and characterisation of novel symmetrical phthalocyanines and novel asymmetric porphyrins that have been embedded or linked respectively,and electrospun into fibres for application in the photocatalysis of environmental pollutants. The phthalocyanines contain pyrrole moieties without hetero atom linkers to maintain a rigid structure. The porphyrin contains a carboxy moiety utilized to construct an amide bond between the complex and the polymer prior to the spinning process. The new compounds were characterized by elemental analyses, proton nuclear magnetic resonance (HNMR)Fourier-transform infrared spectroscopy (FTIR), MALDI-TOF and UV-vis spectroscopy. The general trends of fluorescence, triplet and singlet oxygen quantum yields are described as well as their appropriate lifetimes. The photocatalytic activity of phthalocyanine embedded fibres were compared against those that had been dyed. Unfortunately, during the degradation process, the dyed fibres leeched compound and the studies could not be continued. It was seen that the porphyrin fibres linked to the polymer showed the most efficient photocatalytic activity against 4-cholorphenol and 4-nonylphenol due to irradiation at lower wavelengths consequently having higher frequencies and transferring more energy.
- Full Text:
- Date Issued: 2020
Photocatalytic reduction of CO2 by cobalt doped TiO2 and ZnO micro/nanostructured materials
- Authors: Mgolombane, Mvano
- Date: 2020
- Subjects: Nanostructures , Catalysis , Nanotechnology , Chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/49171 , vital:41607
- Description: Large emissions of carbon dioxide (CO2) in the atmosphere have caused many harmful effects on humans and the environment. Carbon dioxide is a good source C and is used in a number of applications such as synthesis of fossil fuels. Redox reaction of CO2 and H2O with photocatalysts such as TiO2 and ZnO to produce solar fuels is a promising approach in reducing the environmental impacts of greenhouse gasses. This dissertation describes an in-depth synthesis of four photochemical catalysts and their photocatalytic conversion of CO2 to methanol, thereby addressing the above-mentioned problems by applying synthesised nano-based catalysts. Prior to photocatalytic reduction studies, catalysts such as TiO2, Co-doped TiO2, Co-doped TiO2/rGO, ZnO, Co-doped ZnO and Co-doped ZnO/rGO were synthesized and characterized using various spectroscopic and imaging techniques such as Powder X-Ray Diffraction (PXRD), Scanning Electron Microscopy (SEM), Transmission Electron Micrograph (TEM), X-ray Photoelectron Spectroscopy (XPS), Brunner- Emmet- Teller measurement (BET), Thermogravimetry Analysis (TGA) and UV-Vis Diffuse Reflectance Spectroscopy (UV-Vis-DRS). The conversion yield of CO2 to methanol on TiO2, Co-doped TiO2 and Co-doped TiO2/rGO reached 32.3 μmol/gcat, 730 μmol/gcat and 936 μmol/gcat, respectively, after 7 h of irradiation. Theoretical studies via Density functional theory (DFT) revealed that doping TiO2 with Co ions facilitated the formation of adsorbed carbonate or CO2•- species, as CO2 adsorbs onto Co-doped TiO2 surface with binding energy (BE) of -18.12 KJ/mol. The photocatalytic activities of ZnO-based nanomaterials found that Co-doped ZnO/rGO with high ratio of Co, reduced graphene (rGO) and large surface area (10.62 m2g-1) possessed higher CH3OH (30.1 μmol/g) in comparison with Co-doped ZnO (27.3 μmol/g) and ZnO (7.5 μmol/g). The research will deepen the understanding that TiO2 based photocatalyst show higher activity and the mole ratio (Ti/Zn:Co) influences nanocomposites performance and provide new ideas for designing efficient photocatalysts.
- Full Text:
- Date Issued: 2020
- Authors: Mgolombane, Mvano
- Date: 2020
- Subjects: Nanostructures , Catalysis , Nanotechnology , Chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/49171 , vital:41607
- Description: Large emissions of carbon dioxide (CO2) in the atmosphere have caused many harmful effects on humans and the environment. Carbon dioxide is a good source C and is used in a number of applications such as synthesis of fossil fuels. Redox reaction of CO2 and H2O with photocatalysts such as TiO2 and ZnO to produce solar fuels is a promising approach in reducing the environmental impacts of greenhouse gasses. This dissertation describes an in-depth synthesis of four photochemical catalysts and their photocatalytic conversion of CO2 to methanol, thereby addressing the above-mentioned problems by applying synthesised nano-based catalysts. Prior to photocatalytic reduction studies, catalysts such as TiO2, Co-doped TiO2, Co-doped TiO2/rGO, ZnO, Co-doped ZnO and Co-doped ZnO/rGO were synthesized and characterized using various spectroscopic and imaging techniques such as Powder X-Ray Diffraction (PXRD), Scanning Electron Microscopy (SEM), Transmission Electron Micrograph (TEM), X-ray Photoelectron Spectroscopy (XPS), Brunner- Emmet- Teller measurement (BET), Thermogravimetry Analysis (TGA) and UV-Vis Diffuse Reflectance Spectroscopy (UV-Vis-DRS). The conversion yield of CO2 to methanol on TiO2, Co-doped TiO2 and Co-doped TiO2/rGO reached 32.3 μmol/gcat, 730 μmol/gcat and 936 μmol/gcat, respectively, after 7 h of irradiation. Theoretical studies via Density functional theory (DFT) revealed that doping TiO2 with Co ions facilitated the formation of adsorbed carbonate or CO2•- species, as CO2 adsorbs onto Co-doped TiO2 surface with binding energy (BE) of -18.12 KJ/mol. The photocatalytic activities of ZnO-based nanomaterials found that Co-doped ZnO/rGO with high ratio of Co, reduced graphene (rGO) and large surface area (10.62 m2g-1) possessed higher CH3OH (30.1 μmol/g) in comparison with Co-doped ZnO (27.3 μmol/g) and ZnO (7.5 μmol/g). The research will deepen the understanding that TiO2 based photocatalyst show higher activity and the mole ratio (Ti/Zn:Co) influences nanocomposites performance and provide new ideas for designing efficient photocatalysts.
- Full Text:
- Date Issued: 2020
Physical and thermal properties of binary and ternary blends of polypropylene, crumb rubber and wood flour
- Authors: Mosia, Lefika Ellen
- Date: 2020
- Subjects: Polypropylene , Polymers Materials science
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/49193 , vital:41609
- Description: The properties of binary and ternary blends of polypropylene (PP), crumb rubber (CR) and wood flour (WF), with and without ethylene-1-butene as a compatibiliser, were studied. The design of experiment (DoE) was used to determine the proportions of each component for various composites. The components were mixed using the Haake Thermo scientific Polylab QC internal mixer and the crumbs were then moulded into different shapes using the ARBURG 221-55-250 injection moulding machine. The properties of the blends were investigated using a scanning electron microscope (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanic analysis (DMA), tensile tester, water absorption and thickness swelling tests. The morphology of the blends showed the agglomeration of fillers (CR and WF) and more voids on untreated blends but on the treated blends fewer voids as well as improved distribution and dispersion were observed. PP bonded better with WF than with CR. The incorporation of both fillers improved the thermal stability, glass transition temperature, and melt temperature as well as crystallisation temperatures of the blends. Yet these fillers reduced the tensile strength and the yield strength of PP. The addition of WF increased the elongation at break and hardness of the blends but decreased the impact strength of the blends, whereas the addition of CR improved the elongation at break and impact strength of the blends and decreased the hardness of the blends. The blends with more WF absorbed more water and swelled more than the blends containing a high amount of CR. The incorporation of compatibiliser further decreased the tensile strength but improved the thermal stability and elongation at break of the blends. The water absorption and swelling of the blends seemed to decrease with the addition of the compatibiliser whereas the hardness increased. The impact strength of the blends containing more WF, increased after the addition of compatibiliser. The ternary blends showed better results than the binary blends.
- Full Text:
- Date Issued: 2020
- Authors: Mosia, Lefika Ellen
- Date: 2020
- Subjects: Polypropylene , Polymers Materials science
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/49193 , vital:41609
- Description: The properties of binary and ternary blends of polypropylene (PP), crumb rubber (CR) and wood flour (WF), with and without ethylene-1-butene as a compatibiliser, were studied. The design of experiment (DoE) was used to determine the proportions of each component for various composites. The components were mixed using the Haake Thermo scientific Polylab QC internal mixer and the crumbs were then moulded into different shapes using the ARBURG 221-55-250 injection moulding machine. The properties of the blends were investigated using a scanning electron microscope (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanic analysis (DMA), tensile tester, water absorption and thickness swelling tests. The morphology of the blends showed the agglomeration of fillers (CR and WF) and more voids on untreated blends but on the treated blends fewer voids as well as improved distribution and dispersion were observed. PP bonded better with WF than with CR. The incorporation of both fillers improved the thermal stability, glass transition temperature, and melt temperature as well as crystallisation temperatures of the blends. Yet these fillers reduced the tensile strength and the yield strength of PP. The addition of WF increased the elongation at break and hardness of the blends but decreased the impact strength of the blends, whereas the addition of CR improved the elongation at break and impact strength of the blends and decreased the hardness of the blends. The blends with more WF absorbed more water and swelled more than the blends containing a high amount of CR. The incorporation of compatibiliser further decreased the tensile strength but improved the thermal stability and elongation at break of the blends. The water absorption and swelling of the blends seemed to decrease with the addition of the compatibiliser whereas the hardness increased. The impact strength of the blends containing more WF, increased after the addition of compatibiliser. The ternary blends showed better results than the binary blends.
- Full Text:
- Date Issued: 2020
Poor whites and the post-apartheid labour market: a study of perceptions and experiences of work among residents in a homeless shelter in Johannesburg
- Authors: Wollnik, Nadjeschda
- Date: 2020
- Subjects: Poor whites -- South Africa , Poor whites -- South Africa -- Atitudes , Shelters for the homeless -- South Africa , Unemployed -- South Africa -- Attitudes , Unemployed -- South Africa , South Africa -- Social conditions -- 1994- , South Africa -- Economic conditions -- 1991-
- Language: English
- Type: text , Thesis , Masters , MSocSci
- Identifier: http://hdl.handle.net/10962/148540 , vital:38748
- Description: Despite historical precedents, poverty among white people in South Africa remains an anomaly and a paradox. Likewise, the perceptions of work and employment among poor (under- and unemployed) whites in contemporary South Africa have received scant attention in the scholarly literature. Using the conceptual frameworks of critical whiteness studies and segmented labour market theory – as a way of combining subjective and objective considerations – this research seeks to describe and explain the perceptions and experiences of the labour market among poor whites living in a homeless shelter in Johannesburg. Eight respondents were chosen for extended, in-depth interviews in an effort to develop a fine-grained understanding of the pre-existing circumstances that affected their access to information and thus shaped their choices in the labour market, as well as to ascertain what they believed to be the barriers that they face in the labour market. The findings varied, with most of the interviewees seeing ‘being white’ as the reason for their poverty and unemployment, while others exhibited some awareness of the role of their lack of skills and qualifications in their capacity to compete in higher segments of the labour market. The findings were also varied in the sense that not all interviewees experienced poverty in the same manner, with some having been part of the middle class prior to becoming poor, while others having been poor their entire lives. It was also found that class or socio-economic status seemed to have a greater impact than race on the labour market prospects of the interviewees. It is argued that the perceptions of these poor whites, which are informed by their lack of information about the workings of the labour market, rather than their lack of qualifications or their race, most affected their prospects in the labour market. The mechanisms they rely on when seeking employment reveal a poor knowledge of the local labour market and the ways in which they think their skillsets match up to the types of jobs they desire. The lack of understanding of the South African labour market and the policies that are in place to redress the legacies of apartheid are among the factors influencing the lack of success these poor whites are experiencing in their search for work.
- Full Text:
- Date Issued: 2020
- Authors: Wollnik, Nadjeschda
- Date: 2020
- Subjects: Poor whites -- South Africa , Poor whites -- South Africa -- Atitudes , Shelters for the homeless -- South Africa , Unemployed -- South Africa -- Attitudes , Unemployed -- South Africa , South Africa -- Social conditions -- 1994- , South Africa -- Economic conditions -- 1991-
- Language: English
- Type: text , Thesis , Masters , MSocSci
- Identifier: http://hdl.handle.net/10962/148540 , vital:38748
- Description: Despite historical precedents, poverty among white people in South Africa remains an anomaly and a paradox. Likewise, the perceptions of work and employment among poor (under- and unemployed) whites in contemporary South Africa have received scant attention in the scholarly literature. Using the conceptual frameworks of critical whiteness studies and segmented labour market theory – as a way of combining subjective and objective considerations – this research seeks to describe and explain the perceptions and experiences of the labour market among poor whites living in a homeless shelter in Johannesburg. Eight respondents were chosen for extended, in-depth interviews in an effort to develop a fine-grained understanding of the pre-existing circumstances that affected their access to information and thus shaped their choices in the labour market, as well as to ascertain what they believed to be the barriers that they face in the labour market. The findings varied, with most of the interviewees seeing ‘being white’ as the reason for their poverty and unemployment, while others exhibited some awareness of the role of their lack of skills and qualifications in their capacity to compete in higher segments of the labour market. The findings were also varied in the sense that not all interviewees experienced poverty in the same manner, with some having been part of the middle class prior to becoming poor, while others having been poor their entire lives. It was also found that class or socio-economic status seemed to have a greater impact than race on the labour market prospects of the interviewees. It is argued that the perceptions of these poor whites, which are informed by their lack of information about the workings of the labour market, rather than their lack of qualifications or their race, most affected their prospects in the labour market. The mechanisms they rely on when seeking employment reveal a poor knowledge of the local labour market and the ways in which they think their skillsets match up to the types of jobs they desire. The lack of understanding of the South African labour market and the policies that are in place to redress the legacies of apartheid are among the factors influencing the lack of success these poor whites are experiencing in their search for work.
- Full Text:
- Date Issued: 2020
Possible futures for the health system of South Africa towards 2030
- Authors: Lourens, Stephanus Johannes
- Date: 2020
- Subjects: Health services administration -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/48720 , vital:41065
- Description: The South African health system is in crisis. To improve access to health services and move towards universal health coverage the South African government has decided to implement National Health Insurance (NHI). The implementation of such health reforms to the health system of SA is further complicated by the rapidly changing technological environment in the form of the fourth industrial revolution. The NHI and the fourth industrial revolution are expected to impact on the health system of the country, but what the impacts will be remain unclear. A review of the theory and practice of future studies support the notion that change management for healthcare organisations operating within the SA health system must be approached differently. The volatility introduced by the NHI within the context of the fourth industrial revolution necessitates the creation of strategic foresight using futures methodologies. The research has attempted to gain an understanding of the impact of National Health Insurance and the fourth industrial revolution on the health system of SA through the creation of possible futures for the health system, in the form of four alternative scenarios, towards 2030. The six pillars of future studies as stated by Inayatullah (2008) were used as a research methodology and assisted in the mapping, anticipation and timing of the issues facing the health system. The future was deepened using causal layered analysis and alternative futures were constructed through double-variable scenario creation methods using the worldviews identified during the causal layered analysis. From the constructed scenarios the research attempted to identify the preferred future for the health system of South Africa. The preferred future was used in the development of the Future Vision for the Health System of South Africa towards 2030. It is clear to achieve the desired health system towards 2030 the private and the public sectors must collaborate to create a hybrid health system which is supported by fourth industrial revolution technologies.
- Full Text:
- Date Issued: 2020
- Authors: Lourens, Stephanus Johannes
- Date: 2020
- Subjects: Health services administration -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/48720 , vital:41065
- Description: The South African health system is in crisis. To improve access to health services and move towards universal health coverage the South African government has decided to implement National Health Insurance (NHI). The implementation of such health reforms to the health system of SA is further complicated by the rapidly changing technological environment in the form of the fourth industrial revolution. The NHI and the fourth industrial revolution are expected to impact on the health system of the country, but what the impacts will be remain unclear. A review of the theory and practice of future studies support the notion that change management for healthcare organisations operating within the SA health system must be approached differently. The volatility introduced by the NHI within the context of the fourth industrial revolution necessitates the creation of strategic foresight using futures methodologies. The research has attempted to gain an understanding of the impact of National Health Insurance and the fourth industrial revolution on the health system of SA through the creation of possible futures for the health system, in the form of four alternative scenarios, towards 2030. The six pillars of future studies as stated by Inayatullah (2008) were used as a research methodology and assisted in the mapping, anticipation and timing of the issues facing the health system. The future was deepened using causal layered analysis and alternative futures were constructed through double-variable scenario creation methods using the worldviews identified during the causal layered analysis. From the constructed scenarios the research attempted to identify the preferred future for the health system of South Africa. The preferred future was used in the development of the Future Vision for the Health System of South Africa towards 2030. It is clear to achieve the desired health system towards 2030 the private and the public sectors must collaborate to create a hybrid health system which is supported by fourth industrial revolution technologies.
- Full Text:
- Date Issued: 2020
Power in Africa: a comparison of selected South African and Nigerian dystopian fiction
- Authors: Simelane, Smangaliso
- Date: 2020
- Subjects: Dystopias in literature , Africa -- In literature , South African fiction (English) -- History and criticism , Nigerian fiction (English) -- History and criticism , Beukes, Lauren -- Moxyland , Herne, Lily -- Deadlands , Bandele-Thomas, Biyi, 1967- The Sympathetic Undertaker and Other Dreams , Bandele-Thomas, Biyi, 1967- The Man Who Came in from the Back of Beyond
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/148171 , vital:38716
- Description: Dystopias have frequently been explored in literature to better understand the present and imagine the effects of certain elements of society if taken to a logical extreme. In this way, dystopian fiction can act as both cautionary tales and a form of social commentary. This can be explored within the context of African dystopian fiction where power is a recurring theme, highlighting the anxiety and turbulent history several countries on the continent continue to face. To demonstrate this, I compare selected South African and Nigerian Dystopian texts. With regards to South Africa, I analyse novels by South African science fiction authors Lauren Beukes and Lily Herne, namely Moxyland (2008) and Deadlands (2011) respectively, to investigate how South Africa’s past under Apartheid shapes the segregated societies presented. Nigerian dystopian texts by Biyi Bandele-Thomas, namely The Sympathetic Undertaker And Other Dreams (1993) and The Man Who Came in from the Back of Beyond (1992), are discussed with regards to the way Nigeria’s colonial past and several military juntas have contributed to the kinds of corruption that are depicted. I argue that all four texts warn of the dangers of power, albeit in ways that pertain specifically to their countries of origin. With regards to the South African texts, readers are shown the ways in which those in power can manipulate the desire to survive to keep those they subjugate dependent and, consequently, obedient through what Judith Butler terms ‘passionate attachments’. In the case of the Nigerian dystopias, I argue that Bandele-Thomas’s texts warn of tyranny and effects of the corruption that result from misused power strategies. While the dire settings of dystopian fiction may be grim enough, on their own, to motivate change in the real world, this may not be enough to prevent the texts from becoming pessimistic and fatalistic outlooks. Hence, I seek to understand how the selected novels maintain hope and, consequently, convince readers that the depicted dystopias are ones that can be avoided. Typically, dystopian literature fosters hope by setting the narratives in the future, giving readers hope that they may take steps today to protect their societies from becoming like the damned worlds described by dystopian authors. However, the selected texts are not set in the future. Hence, I explore three literary techniques that might foster hope within the selected African dystopian texts in lieu of temporal distancing. They are, namely: identification with the protagonist, defamiliarization and cognitive estrangement.
- Full Text:
- Date Issued: 2020
- Authors: Simelane, Smangaliso
- Date: 2020
- Subjects: Dystopias in literature , Africa -- In literature , South African fiction (English) -- History and criticism , Nigerian fiction (English) -- History and criticism , Beukes, Lauren -- Moxyland , Herne, Lily -- Deadlands , Bandele-Thomas, Biyi, 1967- The Sympathetic Undertaker and Other Dreams , Bandele-Thomas, Biyi, 1967- The Man Who Came in from the Back of Beyond
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/148171 , vital:38716
- Description: Dystopias have frequently been explored in literature to better understand the present and imagine the effects of certain elements of society if taken to a logical extreme. In this way, dystopian fiction can act as both cautionary tales and a form of social commentary. This can be explored within the context of African dystopian fiction where power is a recurring theme, highlighting the anxiety and turbulent history several countries on the continent continue to face. To demonstrate this, I compare selected South African and Nigerian Dystopian texts. With regards to South Africa, I analyse novels by South African science fiction authors Lauren Beukes and Lily Herne, namely Moxyland (2008) and Deadlands (2011) respectively, to investigate how South Africa’s past under Apartheid shapes the segregated societies presented. Nigerian dystopian texts by Biyi Bandele-Thomas, namely The Sympathetic Undertaker And Other Dreams (1993) and The Man Who Came in from the Back of Beyond (1992), are discussed with regards to the way Nigeria’s colonial past and several military juntas have contributed to the kinds of corruption that are depicted. I argue that all four texts warn of the dangers of power, albeit in ways that pertain specifically to their countries of origin. With regards to the South African texts, readers are shown the ways in which those in power can manipulate the desire to survive to keep those they subjugate dependent and, consequently, obedient through what Judith Butler terms ‘passionate attachments’. In the case of the Nigerian dystopias, I argue that Bandele-Thomas’s texts warn of tyranny and effects of the corruption that result from misused power strategies. While the dire settings of dystopian fiction may be grim enough, on their own, to motivate change in the real world, this may not be enough to prevent the texts from becoming pessimistic and fatalistic outlooks. Hence, I seek to understand how the selected novels maintain hope and, consequently, convince readers that the depicted dystopias are ones that can be avoided. Typically, dystopian literature fosters hope by setting the narratives in the future, giving readers hope that they may take steps today to protect their societies from becoming like the damned worlds described by dystopian authors. However, the selected texts are not set in the future. Hence, I explore three literary techniques that might foster hope within the selected African dystopian texts in lieu of temporal distancing. They are, namely: identification with the protagonist, defamiliarization and cognitive estrangement.
- Full Text:
- Date Issued: 2020
Prediction of mass spectra for natural products using an ab initio approach
- Authors: Novokoza, Yolanda
- Date: 2020
- Subjects: Molecular dynamics , Molecular dynamics -- Computer simulation , Mass spectroscopy , Electron impact ionization
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/167166 , vital:41443
- Description: Mass spectrometry (MS) is a technique that measures the fragmentation of molecules, dependent on the molecule’s chemical composition and structure, by first introducing a charge on the molecules. The instrument records the mass to charge ratio, but the energy from the ionization process causes the molecule to fragment. The resultant mass spectrum is highly indicative of not only the molecule analyzed, but also its chemical composition. MS is used in research and industry for both routine and research purposes. One such way to ionize molecules for MS is by bombarding the molecule with electrons which is the basis of electron impact mass spectrometry (EIMS). Although EIMS is widely used, prediction of electron impact mass spectra from first principles is a challenging problem due to a need to accurately determine the probability of different fragmentation pathways of a molecule. Ab initio molecular dynamics based methods are able to explore in an automatic fashion the energetically available fragmentation paths thus give reaction mechanisms in an unbiased way. The mass spectra of five molecules have been explored in work-flows leading to the prediction of mass spectra. These molecules include three natural products alpha-hispanolol, PFB oxime derivative and boronolide (for which experimental mass spectra were not available) and two compounds from the NIST database (for which experimental mass spectra were available). For each of these systems many random conformations were generated using the RDKit library. To all conformations random velocities were applied to each atom. Ab initio molecular dynamics was performed on each conformer, using these initial random velocities using CP2K software, at DFTB+ level at a variety of highly raised temperatures (to accelerate the formation of fragments) Fragmentation was monitored by iterating through all bonds, and identifying bond breakages during dynamics. Graph theoretical packages were used then to track distinct fragments generated. For each of these fragments, charges were determined from Mulliken analysis for all atoms on the fragment from the QM calculations and sum of atomic spin densities per fragment was also plotted. The fragment with the greatest charge (corresponding to the formation of a cation fragment) was taken for plotting on the mass spectrum. Finally, from the mass of the fragment and its elemental composition, the isotopic distribution for the fragment was determined, and this distribution was included by addition in to the mass spectrum. For all trajectories, the sum of all isotopic distributions determined the final mass spectrum.
- Full Text:
- Date Issued: 2020
- Authors: Novokoza, Yolanda
- Date: 2020
- Subjects: Molecular dynamics , Molecular dynamics -- Computer simulation , Mass spectroscopy , Electron impact ionization
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/167166 , vital:41443
- Description: Mass spectrometry (MS) is a technique that measures the fragmentation of molecules, dependent on the molecule’s chemical composition and structure, by first introducing a charge on the molecules. The instrument records the mass to charge ratio, but the energy from the ionization process causes the molecule to fragment. The resultant mass spectrum is highly indicative of not only the molecule analyzed, but also its chemical composition. MS is used in research and industry for both routine and research purposes. One such way to ionize molecules for MS is by bombarding the molecule with electrons which is the basis of electron impact mass spectrometry (EIMS). Although EIMS is widely used, prediction of electron impact mass spectra from first principles is a challenging problem due to a need to accurately determine the probability of different fragmentation pathways of a molecule. Ab initio molecular dynamics based methods are able to explore in an automatic fashion the energetically available fragmentation paths thus give reaction mechanisms in an unbiased way. The mass spectra of five molecules have been explored in work-flows leading to the prediction of mass spectra. These molecules include three natural products alpha-hispanolol, PFB oxime derivative and boronolide (for which experimental mass spectra were not available) and two compounds from the NIST database (for which experimental mass spectra were available). For each of these systems many random conformations were generated using the RDKit library. To all conformations random velocities were applied to each atom. Ab initio molecular dynamics was performed on each conformer, using these initial random velocities using CP2K software, at DFTB+ level at a variety of highly raised temperatures (to accelerate the formation of fragments) Fragmentation was monitored by iterating through all bonds, and identifying bond breakages during dynamics. Graph theoretical packages were used then to track distinct fragments generated. For each of these fragments, charges were determined from Mulliken analysis for all atoms on the fragment from the QM calculations and sum of atomic spin densities per fragment was also plotted. The fragment with the greatest charge (corresponding to the formation of a cation fragment) was taken for plotting on the mass spectrum. Finally, from the mass of the fragment and its elemental composition, the isotopic distribution for the fragment was determined, and this distribution was included by addition in to the mass spectrum. For all trajectories, the sum of all isotopic distributions determined the final mass spectrum.
- Full Text:
- Date Issued: 2020
Preparation and characterization of sodium alginate-based dissolvable bandages as potential wound dressings
- Authors: Ndlovu, Sindi Prescila
- Date: 2020
- Subjects: Nanostructured materials
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18800 , vital:42734
- Description: Burn wounds are among the leading causes of mortality and morbidity globally. Burn wounds are painful, cause social isolation and causes post-traumatic stress disorder (PTSD) due to prolonged hospital treatment. The challenges encountered in the treatment of burn wounds are infections resulting from the use of wound dressings that do not protect the wounds from microbial invasion. Sodium alginate-based dissolvable bandages were prepared and encapsulated with various antibiotics (ampicillin and ciprofloxacin) and nanoparticles (i.e. zinc oxide and silver). The dissolvable bandages were characterized by FTIR, SEM/EDX, TEM, XRD and TGA. Furthermore, the porosity, water uptake, biodegradation, antibacterial studies, and water vapour transmittance properties of the bandages were also studied. The prepared sodium alginate-based dissolvable bandage incorporated with varied amount of drugs (such as ampicillin, ciprofloxacin, zinc oxide and silver nanoparticle) exhibited good porosity, high water uptake, excellent WVTR with sustained drug release profiles. The loading of ZnO Nps, CLP/ZnO Nps and Ag Nps/CLP into the bandages improved the antibacterial activity of the bandages against both gram-negative and gram-positive strains of bacteria. XRD confirmed the amorphous nature of the dissolvable bandage and the absence of free drugs. FTIR revealed the successful encapsulation of the antibiotics and nanoparticle into the dissolvable bandages. The dissolvable bandages exhibited high water uptake ranging from 870-4468% with good porosity suggesting that they can absorb large amount of wound exudates. The drug release for all the bandages obeyed the Korsemeyer Peppas drug release model with n values in the range 0.1-1.0. The results obtained indicate that the bandages are potential wound dressings for burns and for patients with sensitive skins.
- Full Text:
- Date Issued: 2020
- Authors: Ndlovu, Sindi Prescila
- Date: 2020
- Subjects: Nanostructured materials
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18800 , vital:42734
- Description: Burn wounds are among the leading causes of mortality and morbidity globally. Burn wounds are painful, cause social isolation and causes post-traumatic stress disorder (PTSD) due to prolonged hospital treatment. The challenges encountered in the treatment of burn wounds are infections resulting from the use of wound dressings that do not protect the wounds from microbial invasion. Sodium alginate-based dissolvable bandages were prepared and encapsulated with various antibiotics (ampicillin and ciprofloxacin) and nanoparticles (i.e. zinc oxide and silver). The dissolvable bandages were characterized by FTIR, SEM/EDX, TEM, XRD and TGA. Furthermore, the porosity, water uptake, biodegradation, antibacterial studies, and water vapour transmittance properties of the bandages were also studied. The prepared sodium alginate-based dissolvable bandage incorporated with varied amount of drugs (such as ampicillin, ciprofloxacin, zinc oxide and silver nanoparticle) exhibited good porosity, high water uptake, excellent WVTR with sustained drug release profiles. The loading of ZnO Nps, CLP/ZnO Nps and Ag Nps/CLP into the bandages improved the antibacterial activity of the bandages against both gram-negative and gram-positive strains of bacteria. XRD confirmed the amorphous nature of the dissolvable bandage and the absence of free drugs. FTIR revealed the successful encapsulation of the antibiotics and nanoparticle into the dissolvable bandages. The dissolvable bandages exhibited high water uptake ranging from 870-4468% with good porosity suggesting that they can absorb large amount of wound exudates. The drug release for all the bandages obeyed the Korsemeyer Peppas drug release model with n values in the range 0.1-1.0. The results obtained indicate that the bandages are potential wound dressings for burns and for patients with sensitive skins.
- Full Text:
- Date Issued: 2020
Primary school teachers’ perceptions and experiences regarding the risk and protective factors impacting learner conduct
- Authors: Mxhobo, Buhle Vuyo
- Date: 2020
- Subjects: LCSH
- Language: English
- Type: Thesis , Masters , MSW
- Identifier: http://hdl.handle.net/10948/46446 , vital:39584
- Description: Learners are interconnected with their families, schools and communities and can thus be affected risk or protective factorsthat occur in the community.Such factors could relate to lack of parent-to-learner relationships, poor teacher-to-learner relationships and/or violencewitnessedfrom the community.The purpose of this study was to gain anunderstanding of primary school teachers’ perceptions andexperiences regarding the riskand protective factors impactinglearner conduct. This study utiliseda qualitative approach. An explorative, descriptive andcontextual design wasfollowed. Semi-structured individual interviews wereimplemented. Thesampling technique used was non-probability, purposive sampling. Tesch’s model (in Creswell, 2009) wasfollowed for the data analysis process.The data led to identification of three themes, namely: risk and protective factorsimpacting learner conduct. Recommendations that preventrisk factors and promoteprotective factorswere identified.The researcher implemented Guba’s model (Krefting, 1991) for data verification. This study contributes to the social work knowledgein that it provides a deeper understanding of factors affecting learner contact.
- Full Text:
- Date Issued: 2020
- Authors: Mxhobo, Buhle Vuyo
- Date: 2020
- Subjects: LCSH
- Language: English
- Type: Thesis , Masters , MSW
- Identifier: http://hdl.handle.net/10948/46446 , vital:39584
- Description: Learners are interconnected with their families, schools and communities and can thus be affected risk or protective factorsthat occur in the community.Such factors could relate to lack of parent-to-learner relationships, poor teacher-to-learner relationships and/or violencewitnessedfrom the community.The purpose of this study was to gain anunderstanding of primary school teachers’ perceptions andexperiences regarding the riskand protective factors impactinglearner conduct. This study utiliseda qualitative approach. An explorative, descriptive andcontextual design wasfollowed. Semi-structured individual interviews wereimplemented. Thesampling technique used was non-probability, purposive sampling. Tesch’s model (in Creswell, 2009) wasfollowed for the data analysis process.The data led to identification of three themes, namely: risk and protective factorsimpacting learner conduct. Recommendations that preventrisk factors and promoteprotective factorswere identified.The researcher implemented Guba’s model (Krefting, 1991) for data verification. This study contributes to the social work knowledgein that it provides a deeper understanding of factors affecting learner contact.
- Full Text:
- Date Issued: 2020
Profitable day-neutral strawberry variety and planting date combination for year-round strawberry fruit production in the Southern Cape
- Authors: Parehwa, Patience
- Date: 2020
- Subjects: Strawberries -- Fertilizers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/48599 , vital:40894
- Description: South Africa’s strawberry production is currently limited to winter and spring production. Strawberry growers have not been able to extend the growing season for year-round strawberry production primarily due to variety- and climatic limitations. Consumers world-wide, however, demand year-round supply of strawberries on their markets. Delayed planting and robust day-neutral varieties may allow growers to extend the marketing season. To investigate the most profitable variety and planting date combination for season extension in the Southern Cape, trials were conducted at Groeneweide Farm, George. Day-neutral strawberry varieties Monterey, San Andreas and Albion were planted at 30-day intervals from April to September for 3 seasons. They were planted in single layer, standard coir grow-bags at a density of 75 000/ha. Analyses of variance (ANOVA) were performed on vegetative growth stages (crown and runner formation), yield (flowering and fruit yield), fruit quality (fruit mass and total soluble solids content) and gross income. The analysis encompassed variety, month and planting month × variety interaction. ‘Monterey’ significantly outperformed ‘San Andreas’ which in turn significantly (p<0.05) outperformed ‘Albion’ for crown number, flower number, yield, fruit size and margin above cost. ‘San Andreas’ produced significantly fewer runners than ‘Monterey’ and ‘Albion’. ‘Albion’ produced significantly higher TSS followed by ‘Monterey’ and ‘San Andreas’. Over all, the three day-neutral varieties had no significant differences in yield within all planting dates. However, August and September planting dates produced significantly more runners, flowers and higher margin above cost, but significantly smaller fruit and lower total soluble solids (TSS). ‘Monterey’ planted in April and May produced the highest margin above cost and brought earliness to the production window. Together with ‘San Andreas’ planted in August, which extended the harvest season and gave similar margin above cost, it is possible to maximise profitability, extend both ends of the harvest season and also minimise hygiene costs associated with weekly runner removal. Since the strawberry price is very responsive, to quantity supplied, an oversupply out of the normal season, may however lead to lower prices affecting gross income.
- Full Text:
- Date Issued: 2020
- Authors: Parehwa, Patience
- Date: 2020
- Subjects: Strawberries -- Fertilizers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/48599 , vital:40894
- Description: South Africa’s strawberry production is currently limited to winter and spring production. Strawberry growers have not been able to extend the growing season for year-round strawberry production primarily due to variety- and climatic limitations. Consumers world-wide, however, demand year-round supply of strawberries on their markets. Delayed planting and robust day-neutral varieties may allow growers to extend the marketing season. To investigate the most profitable variety and planting date combination for season extension in the Southern Cape, trials were conducted at Groeneweide Farm, George. Day-neutral strawberry varieties Monterey, San Andreas and Albion were planted at 30-day intervals from April to September for 3 seasons. They were planted in single layer, standard coir grow-bags at a density of 75 000/ha. Analyses of variance (ANOVA) were performed on vegetative growth stages (crown and runner formation), yield (flowering and fruit yield), fruit quality (fruit mass and total soluble solids content) and gross income. The analysis encompassed variety, month and planting month × variety interaction. ‘Monterey’ significantly outperformed ‘San Andreas’ which in turn significantly (p<0.05) outperformed ‘Albion’ for crown number, flower number, yield, fruit size and margin above cost. ‘San Andreas’ produced significantly fewer runners than ‘Monterey’ and ‘Albion’. ‘Albion’ produced significantly higher TSS followed by ‘Monterey’ and ‘San Andreas’. Over all, the three day-neutral varieties had no significant differences in yield within all planting dates. However, August and September planting dates produced significantly more runners, flowers and higher margin above cost, but significantly smaller fruit and lower total soluble solids (TSS). ‘Monterey’ planted in April and May produced the highest margin above cost and brought earliness to the production window. Together with ‘San Andreas’ planted in August, which extended the harvest season and gave similar margin above cost, it is possible to maximise profitability, extend both ends of the harvest season and also minimise hygiene costs associated with weekly runner removal. Since the strawberry price is very responsive, to quantity supplied, an oversupply out of the normal season, may however lead to lower prices affecting gross income.
- Full Text:
- Date Issued: 2020
Psychological capital and work engagement of employees at a training academy
- Authors: Jacobs, Carel-Theron
- Date: 2020
- Subjects: Work environment -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/48169 , vital:40517
- Description: Having an engaged workforce gives an organisation a competitive advantage. Levels of work engagement are influenced by, amongst other factors, Psychological Capital (PsyCap). The main aim of this study is to determine the influence of PsyCap on the levels of work engagement of employees at a Technical Vocational Education and Training (TVET) college. This study employed a descriptive quantitative research approach with a cross-sectional correlational design. A composite paper-and-pencil questionnaire was distributed to all employees at the TVET college. The questionnaire consisted of the Utrecht Work Engagement Scale (UWES) and PsyCap Questionnaire (PCQ). Descriptive statistics were used to describe the sample (n =195). The relationship between the two variables was analysed using Pearson product-moment correlation coefficients, and multiple regression analysis predicted the value of engagement based on the value of PsyCap. The study confirms previous findings that indicate that PsyCap is positively related work engagement and that work engament can predict PsyCap.
- Full Text:
- Date Issued: 2020
- Authors: Jacobs, Carel-Theron
- Date: 2020
- Subjects: Work environment -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/48169 , vital:40517
- Description: Having an engaged workforce gives an organisation a competitive advantage. Levels of work engagement are influenced by, amongst other factors, Psychological Capital (PsyCap). The main aim of this study is to determine the influence of PsyCap on the levels of work engagement of employees at a Technical Vocational Education and Training (TVET) college. This study employed a descriptive quantitative research approach with a cross-sectional correlational design. A composite paper-and-pencil questionnaire was distributed to all employees at the TVET college. The questionnaire consisted of the Utrecht Work Engagement Scale (UWES) and PsyCap Questionnaire (PCQ). Descriptive statistics were used to describe the sample (n =195). The relationship between the two variables was analysed using Pearson product-moment correlation coefficients, and multiple regression analysis predicted the value of engagement based on the value of PsyCap. The study confirms previous findings that indicate that PsyCap is positively related work engagement and that work engament can predict PsyCap.
- Full Text:
- Date Issued: 2020
Psychological capital as a moderator in the relationship between occupational stress and quality of work life among healthcare practitioners in Buffalo City Metropolitan Municipality
- Umenze , Catherine Chetachukwu
- Authors: Umenze , Catherine Chetachukwu
- Date: 2020
- Subjects: Job stress Human capital -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MCom (Industrial Psychology)
- Identifier: http://hdl.handle.net/10353/12536 , vital:39285
- Description: The study investigated psychological capital as a moderator in the relationship between occupational stress and quality of work life. The study used the explanatory survey research design. The convenience and purposive types of the non-probability sampling method were used to sample 150 male and female healthcare practitioners who participated in the study. Validated questionnaires were used to elicit information from the study’s participants. Four hypotheses were stated and analysed using the inferential statistical approach. The research findings showed that there was a significant positive relationship between occupational stress and quality of work life; there was a significant positive relationship between psychological capital and quality of work life; and there was a significant moderating influence of psychological capital on the relationship between occupational stress and quality of work life. And finally, there was no significant relationship between psychological capital and occupational stress. There is need for managers to focus on the four dimensions of psychological capital to help minimise occupational stress and improve quality of work life of healthcare practitioners. Management was also advised to devise optimal methods to curb stress and strengthen the mental and physical abilities of the employees’ outcomes. Future research should endeavour to apply a longitudinal research design in investigating the extent to which psychological capital can predict occupational stress, and in understanding its influence in the quality of work life of employees. The future study can spread the investigation to other districts as this study was conducted in just one district, which is a foremost limitation of the study.
- Full Text:
- Date Issued: 2020
- Authors: Umenze , Catherine Chetachukwu
- Date: 2020
- Subjects: Job stress Human capital -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MCom (Industrial Psychology)
- Identifier: http://hdl.handle.net/10353/12536 , vital:39285
- Description: The study investigated psychological capital as a moderator in the relationship between occupational stress and quality of work life. The study used the explanatory survey research design. The convenience and purposive types of the non-probability sampling method were used to sample 150 male and female healthcare practitioners who participated in the study. Validated questionnaires were used to elicit information from the study’s participants. Four hypotheses were stated and analysed using the inferential statistical approach. The research findings showed that there was a significant positive relationship between occupational stress and quality of work life; there was a significant positive relationship between psychological capital and quality of work life; and there was a significant moderating influence of psychological capital on the relationship between occupational stress and quality of work life. And finally, there was no significant relationship between psychological capital and occupational stress. There is need for managers to focus on the four dimensions of psychological capital to help minimise occupational stress and improve quality of work life of healthcare practitioners. Management was also advised to devise optimal methods to curb stress and strengthen the mental and physical abilities of the employees’ outcomes. Future research should endeavour to apply a longitudinal research design in investigating the extent to which psychological capital can predict occupational stress, and in understanding its influence in the quality of work life of employees. The future study can spread the investigation to other districts as this study was conducted in just one district, which is a foremost limitation of the study.
- Full Text:
- Date Issued: 2020
Psychological capital as a moderator of the relationship between intrinsic motivation and employee engagement at public hospital in the Eastern Cape, a South Africa
- Authors: Skoti , Bulumko
- Date: 2020
- Subjects: Employee motivation
- Language: English
- Type: Thesis , Masters , MCom (Industrial Psychology)
- Identifier: http://hdl.handle.net/10353/18996 , vital:43006
- Description: Employee engagement is an important characteristic that all organizations would be happy to have among all their employees. This is because employee engagement is linked with many desirable organisational outcomes such as job satisfaction, productivity, and employee retention. It is therefore extremely important for organisations to know how engagement among employees can be generated or enhanced, especially in the South African public health sector that is characterised by high levels of stress and labour turnover among its employees. The main objective of the present study was accordingly to explore (i) the role of intrinsic motivation and psychological capital as individual and combined predictors of employee engagement, and (ii) the role of psychological capital as a moderator of the relationship between intrinsic motivation and employee engagement. A quantitative approach was adopted and a structured self-administered questionnaire was used in data collection. Simple Linear Regression and Hierarchical Multiple Regression were used in hypothesis testing. The results revealed a significant positive relationship between intrinsic motivation and employee engagement. Psychological capital was also found to be significantly positively related to employee engagement. Intrinsic motivation and psychological capital (combined) were found to account for a significantly higher proportion of variance in employee engagement than intrinsic motivation alone but they did not account for a significantly higher proportion of variance in employee engagement than psychological capital alone. The limitations of the study were highlighted and recommendations were made for future research directions. Recommendations were also made for the managerial and professional application of the results of the present study.
- Full Text:
- Date Issued: 2020
- Authors: Skoti , Bulumko
- Date: 2020
- Subjects: Employee motivation
- Language: English
- Type: Thesis , Masters , MCom (Industrial Psychology)
- Identifier: http://hdl.handle.net/10353/18996 , vital:43006
- Description: Employee engagement is an important characteristic that all organizations would be happy to have among all their employees. This is because employee engagement is linked with many desirable organisational outcomes such as job satisfaction, productivity, and employee retention. It is therefore extremely important for organisations to know how engagement among employees can be generated or enhanced, especially in the South African public health sector that is characterised by high levels of stress and labour turnover among its employees. The main objective of the present study was accordingly to explore (i) the role of intrinsic motivation and psychological capital as individual and combined predictors of employee engagement, and (ii) the role of psychological capital as a moderator of the relationship between intrinsic motivation and employee engagement. A quantitative approach was adopted and a structured self-administered questionnaire was used in data collection. Simple Linear Regression and Hierarchical Multiple Regression were used in hypothesis testing. The results revealed a significant positive relationship between intrinsic motivation and employee engagement. Psychological capital was also found to be significantly positively related to employee engagement. Intrinsic motivation and psychological capital (combined) were found to account for a significantly higher proportion of variance in employee engagement than intrinsic motivation alone but they did not account for a significantly higher proportion of variance in employee engagement than psychological capital alone. The limitations of the study were highlighted and recommendations were made for future research directions. Recommendations were also made for the managerial and professional application of the results of the present study.
- Full Text:
- Date Issued: 2020
Psychological capital as a moderator of the relationship between workplace conflict and organisational citizenship behaviour among administrative staff at the University of Fort Hare
- Authors: Motema, Boiketlo
- Date: 2020
- Subjects: Organizational behavior Employees -- Attitudes Organizational effectiveness
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10353/18565 , vital:42609
- Description: This study investigated psychological capital (PsyCap) as a mediator of the relationship between workplace conflict (WC) and organisational citizenship behaviour (OCB). The study was based on equity theory as well as the social exchange theory. The sample encompassed of 151 administrative staff members from the University of Fort Hare (Alice, Bhisho and East London campuses) in the Eastern Cape Province. Argentero, Cortese, and Ferretti (2008) organisational citizenship behaviour questionnaire was employed to assess OCB; the Interpersonal Conflict at Work Scale (ICAWS) was employed to assess workplace conflict; and Luthans, Avolio, Avey, and Norman’s (2007) psychological capital questionnaire by McGee (2011) was employed to assess psychological capital. In terms of data analysis, a descriptive analysis, correlational analysis together with simple linear regression analysis and multiple linear regression models were applied using the Statistical Package for Social Sciences (SPSS) version 25. The findings indicated a negative relationship between workplace conflict and organisational citizenship behaviour. Thus, for the purpose of enhancing extra-role behaviours amongst staff members, the management of the institution needs to ensure equitable compensation, rewards, and benefits amongst workers. This is vital because should the employees perceive that inequity exists, they will fight for fairness and justice, and if they are not heard, it will result in workplace conflict.
- Full Text:
- Date Issued: 2020
- Authors: Motema, Boiketlo
- Date: 2020
- Subjects: Organizational behavior Employees -- Attitudes Organizational effectiveness
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10353/18565 , vital:42609
- Description: This study investigated psychological capital (PsyCap) as a mediator of the relationship between workplace conflict (WC) and organisational citizenship behaviour (OCB). The study was based on equity theory as well as the social exchange theory. The sample encompassed of 151 administrative staff members from the University of Fort Hare (Alice, Bhisho and East London campuses) in the Eastern Cape Province. Argentero, Cortese, and Ferretti (2008) organisational citizenship behaviour questionnaire was employed to assess OCB; the Interpersonal Conflict at Work Scale (ICAWS) was employed to assess workplace conflict; and Luthans, Avolio, Avey, and Norman’s (2007) psychological capital questionnaire by McGee (2011) was employed to assess psychological capital. In terms of data analysis, a descriptive analysis, correlational analysis together with simple linear regression analysis and multiple linear regression models were applied using the Statistical Package for Social Sciences (SPSS) version 25. The findings indicated a negative relationship between workplace conflict and organisational citizenship behaviour. Thus, for the purpose of enhancing extra-role behaviours amongst staff members, the management of the institution needs to ensure equitable compensation, rewards, and benefits amongst workers. This is vital because should the employees perceive that inequity exists, they will fight for fairness and justice, and if they are not heard, it will result in workplace conflict.
- Full Text:
- Date Issued: 2020
Psychologists’ perceptions of cultural competence in working with clients from diverse cultures in psychotherapy within the Nelson Mandela Bay area
- Authors: Sdinane, Thembeka Gloria
- Date: 2020
- Subjects: Cultural competence
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/46453 , vital:39597
- Description: There has beenanincreasedacknowledgement of the need for current psychological interventions to meet the needs of the diverse cultural contexts reflective of the SouthAfrican clients. As such, researchers began exploring, enhancing,and evaluating modelsof psychotherapy, applicable to the cultures of the diverse clients. To address disparities caused by Eurocentricepistemologies that fail to recognise the impact of culture on clients, the concept of cultural competence was introduced.While there is international literature available on cultural competence in psychotherapy, there is still a significant gap in South African literature.Consequently, this study explored psychologists’ perceptions of cultural competence when working with diverse clients in psychotherapy. A general exploratory qualitative approach informed this study. The qualitative data was collected using semi-structured interviews. Using a purposive sampling strategy, registered clinical and counselling psychologists who are in private practice were selected. A total of 6 participants were interviewed.The interviews were transcribed verbatim, and the thematic analysis method was used to analyse data with aid from the Atlas.ti coding Software. Findings of this study are presented using the four identified themes i) Complexities of working with diverse cultures, ii) knowledge limitation hinders complete cultural competence, iii) Actions towards cultural competence and iv) The geographical context. The findings of this study suggest that the idea of complete cultural competence in psychological therapyis not plausible, given the nuances embedded within South African society. As such, the researcher suggests a move from cultural competence to cultural effectiveness as an alternative that could potentially create aplatform that bridges the gap between psychological science and the nuances posed by cultures.
- Full Text:
- Date Issued: 2020
- Authors: Sdinane, Thembeka Gloria
- Date: 2020
- Subjects: Cultural competence
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/46453 , vital:39597
- Description: There has beenanincreasedacknowledgement of the need for current psychological interventions to meet the needs of the diverse cultural contexts reflective of the SouthAfrican clients. As such, researchers began exploring, enhancing,and evaluating modelsof psychotherapy, applicable to the cultures of the diverse clients. To address disparities caused by Eurocentricepistemologies that fail to recognise the impact of culture on clients, the concept of cultural competence was introduced.While there is international literature available on cultural competence in psychotherapy, there is still a significant gap in South African literature.Consequently, this study explored psychologists’ perceptions of cultural competence when working with diverse clients in psychotherapy. A general exploratory qualitative approach informed this study. The qualitative data was collected using semi-structured interviews. Using a purposive sampling strategy, registered clinical and counselling psychologists who are in private practice were selected. A total of 6 participants were interviewed.The interviews were transcribed verbatim, and the thematic analysis method was used to analyse data with aid from the Atlas.ti coding Software. Findings of this study are presented using the four identified themes i) Complexities of working with diverse cultures, ii) knowledge limitation hinders complete cultural competence, iii) Actions towards cultural competence and iv) The geographical context. The findings of this study suggest that the idea of complete cultural competence in psychological therapyis not plausible, given the nuances embedded within South African society. As such, the researcher suggests a move from cultural competence to cultural effectiveness as an alternative that could potentially create aplatform that bridges the gap between psychological science and the nuances posed by cultures.
- Full Text:
- Date Issued: 2020