Characterisation of surfaces modified with phthalocyanines through click chemistry for applications in electrochemical sensing
- Authors: O'Donoghue, Charles St John Nqwabuko
- Date: 2018
- Subjects: Electrodes, Carbon , Phthalocyanines , X-ray photoelectron spectroscopy , Electrochemistry , Electrochemical sensors , Hydrazine , Click chemistry
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/58046 , vital:27038
- Description: One form of surface modification was primarily investigated in this work on glassy carbon electrodes. The form of modification is comprised of a series of steps in which electrografting is first applied to the glassy carbon surface, which is then followed up with click chemistry to ultimately immobilise a phthalocyanine onto the surface. The modified glassy carbon electrodes and surfaces were characterised with a combination of scanning electrochemical microscopy, X-ray photoelectron spectroscopy and various electrochemical methods. In this work, three alkyne substituted phthalocyanines were used. Two novel phthalocyanines, with nickel and cobalt metal centres, were studied alongside a manganese phthalocyanine reported in literature. Each of the three phthalocyanines was modified at the peripheral position with a 1-hexyne group, via a glycosidic bond, yielding the terminal alkyne groups that were used for subsequent click reactions. In situ diazotisation was used to graft 4-azidoaniline groups to the surface of the glassy carbon electrode. The azide bearing 4- azidoaniline groups were thus used to anchor the tetra substituted phthalocyanines to the surface of the electrodes. This method yielded successful modification of the electrodes and lead to their application in sensing studies. The modified electrodes were primarily used to catalyse the common agricultural oxidising agent hydrazine.
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- Date Issued: 2018
Chemical weathering on selected nunataks in western Dronning Maud Land, Antarctica
- Authors: Knox, Jenna Tracy
- Date: 2018
- Subjects: Glacial climates -- Antarctica -- Queen Maud Land , Glaciology -- Antarctica -- Queen Maud Land , Chemical weathering -- Antarctica -- Queen Maud Land , Atmospheric carbon dioxide -- Environmental aspects , Climatic changes -- Antarctica -- Queen Maud Land , Nunataks -- Antarctica -- Queen Maud Land
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/61658 , vital:28046
- Description: High latitude areas are sensitive to the impacts of climate change, and it is expected that the impact of greenhouse warming will be much higher in the polar regions than in any other climatic zones, with the most highly affected area being that of the Antarctic rim (Barsch, 1993). Weathering and pedogenic processes respond to variations in climate, with models predicting that chemical weathering may increase synchronously with global carbon dioxide levels increase, due to dissolution rates and the erosional impact of hydrological cycles in warming climates (Anderson & Anderson, 2010). As liquid water becomes more available in Antarctica the potential for chemical weathering, due to a less moisture-limited environment and increased temperatures, increases (Convey et al., 2009). Weathering processes are important for soil formation and the production of fine-grained material, with chemical weathering being an active constituent of this. Increased rates of soil formation are likely to occur, with global climate changes resulting in greater chemical weathering occurring in Antarctica. Opportunistic sampling was conducted during the Austral summer of 2016/2017, whereby rock, snow and meltwater samples were taken at various sites within the western portion of Dronning Maud Land of Antarctica. Rock samples were placed in resin, and cut with a diamond saw to create thin sections. Optical microscopy and scanning transmission electron microscopy (STEM) were used to analyse mineral weight percentage with depth. Twelve soil samples were dried and weighed, sieved and statistically represented according to particle size. Inductively coupled plasma mass spectrometry (ICP-MS) determined the geochemical analysis for 10 water and snow samples. Rock hardness was inferred through the use of an Equotip, with rebound values recorded for multiple rock faces and samples. Thermal regimes of rock temperature was further recorded using a FLIR infrared camera, and documented for each rock face over a 24 hour period at 2 hourly intervals. The products of increased chemical weathering were evident from particle size analysis; samples were very poorly sorted in nature, and undergo in situ weathering, whereby products were not removed by erosional processes. Weathering rinds were found to be siliceous and ferric, depending on parent lithology. Ferric ratios increased in wt.% from the substrate rock to the external surface, creating the red, iron rich crusts noted on the hand specimens. The observable chemical weathering was found adjacent to intrusions through Precambrian dolerites. Geochemical analysis revealed thin, carbonaceous features, with impurity-rich layers, characteristic of speleothem formation. Carbonaceous layers did not follow underlying substrate features, rather deposited at the external surface, upon which, further precipitation growth could occur, creating karst features. Extensive gypsum coatings (>2mm) under BSE imagery were identified, with the abundance of gypsum salts (below surface level) and rock coatings indicating active sulphuric acid weathering, in western Dronning Maud Land, Antarctica. Were mechanical processes faster than chemical, weathering rinds and solution features on silicate rocks would be uncommon in the Antarctic, periglacial landscape. However, this is not the case as the existence of these landforms implies that chemical weathering may occur faster than mechanical weathering processes (Pope et al., 1995). In a changing world, one needs to monitor these processes at a micro-scale in order to fully understand how periglacial environments react to global climatic changes, and the subsequent impacts on these sensitive environments.
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- Date Issued: 2018
Citizen science, treatment and microbial compliance monitoring in rainwater harvesting in Namibia
- Authors: Angala, Hallo Angaleni Nameya
- Date: 2018
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62082 , vital:28105
- Description: Expected release date-April 2020
- Full Text:
- Date Issued: 2018
Classification of Distinct Fuzzy Subgroups of the Dihedral Group Dp nq for p and q distinct primes and n ∈ N
- Authors: Nxala, Baphumelele Ellen
- Date: 2018
- Subjects: Fuzzy mathematics Fuzzy sets
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/14516 , vital:39997
- Description: In this dissertation, we classify distinct fuzzy subgroups of the dihedral group Dpnq, for p and q distinct primes and n ∈ N, under a natural equivalence relation of fuzzy subgroups and a fuzzy isomorphism. We aim to present formulae for the number of maximal chains and the number of distinct fuzzy subgroups of this group. Our study will include some theory on non-abelian groups since the classification of distinct fuzzy subgroups of this group relies on the crisp characterization of maximal chains. We give the definition of a natural equivalence relation introduced by Murali and Makamba in [67] which we will use in this study. Based on this definition, we introduce two counting techniques that we will use to compute the number of distinct fuzzy subgroups of Dpnq. In this dissertation, we use the criss-cut counting technique as our primary method of enumeration, and the cross-cut method serves as a means of verifying results we obtain from our primary method. To classify distinct fuzzy subgroups of this group, we begin by investigating the dihedral groups Dpnq, for p and q distinct primes and specific values of n = 2 and 3 to observe a trend. We classify the flags of these groups using the characterization of flags introduced in [93]. From this characterization, we then present formulae for the number of distinct fuzzy subgroups attributed to the flags of Dp 2q and Dp 3q . To generalise results for Dpnq, for p and q distinct primes and n ∈ N, we characterize the flags of this group and classify them as either cyclic, mdcyclic for 1 ≤ m ≤ n, or b-cyclic. Finally, we establish a general formula for the number of distinct fuzzy subgroups obtainable from these flags. We conclude by comparing results obtained from using our general formula to those obtained by other researchers for the same group. Based on the results from this study, we give an outline of future research work
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- Date Issued: 2018
Constructing an EMF radiation Hygeia framework and model to demonstrate a public interest override
- Authors: Lech, James Chrystopher
- Date: 2018
- Subjects: Electromagnetic fields , Electromagnetic fields -- Health aspects , Electromagnetic fields -- Measurement , Public interest , Radiation -- Measurement , HYGEIA , Promotion of Access to Information Act (PAIA)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/58695 , vital:27364
- Description: Scientific views on EMF radiation dosimetry and models increasingly suggest that even a tiny increase in the incidence of diseases resulting from exposure to EMF radiation could have broad¹ implications for public health, social accounting and the economy. In South Africa (SA) there is no national EMF radiation exposure protection standard, statutory monitoring or regulations. Multinational High Court deliberations indicate the need for public interest EMF radiation exposure protection standards in South Africa. Domestic citizens, academics, as well as regulatory and legislative practitioners, are unable to effectively monitor and investigate EMF radiation exposure emissions from infrastructure sources, because industries refuse to provide the required data. Industries have, since 2003, continually obstructed access to the data and the establishment of a national EMF radiation standard, citing that it would be in conflict with their strategic economic interests. The demonstration of a public interest override (PIO) function is legislatively required to gain access to the required data. This study constructed (1) a framework and (2) a model to perform test simulations against the (3) PIO criteria to demonstrate a PIO function and tested one PIO simulation scenario. Testing the PIO scenario firstly required the construction of a public interest framework, drawing input from multiple disciplines. The framework literature review used systematic case law and scientific-technical analysis whilst the framework science sought to understand the connections, feedbacks, and trajectories that occur as a result of natural and human system processes and exchanges. The EMF radiation exposure system functions to support human wellbeing needs and to explore the benefits and losses associated with alternative futures with the goal to uncover the current and future limits thereof. In the second instance a HYGEIA² model was selected as a base investigation and forecast simulation tool. The study had to uncover the key attributes and parameters necessary to construct and to run successful EMF radiation exposure simulations. Thereafter the HYGEIA model was modified to specifically identify and evaluate EMF radiation exposure hazard conditions. Through subsequent simulation runs, the constructed framework was then tested. Requested anthroposphere information was synthesized within a systems model to forecast ecosystem services and human-use dynamics under alternative scenarios. The simulation used the model, the model references and the framework for guidelines, thus allowing multiple simulation / demonstration runs for different contexts or scenarios. The third step was the construction of a PIO checklist which guides criteria testing and provides a means of gaining pertinent information for further studies, based on this dissertation. Framework EMF radiation policy inputs into the model were intersected with identified vulnerable area facilities which were selected based on international criteria. The research output revealed potential EMF radiation violations which served as system feedback inputs in support of a demonstrated PIO function. The research recommends that the identified EMF radiation exposure violations of public health undergo a Promotion of Access to Information Act (PAIA) judicial review process to confirm the research findings. The judicial qualification of a PAIA PIO function of ‘substances released into the environment’ and ‘public safety or environmental risk’ would enable access to EMF radiation emissions data essential to future studies.
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- Date Issued: 2018
Construction company joint ventures in South Africa
- Authors: Sisilana, Owethu
- Date: 2018
- Subjects: Construction industry -- South Africa , Joint ventures Strategic alliances (Business) Project management
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/35554 , vital:33756
- Description: In the construction industry, construction joint ventures (CJVs) have become one of the major organisational forms utilised in large-scale projects. However, because of the complexity of CJVs, the management of CJVs is much more difficult than that of usual projects undertaken by a single construction firm. In South Africa the existence of a clear and effective strategy for the successful transformation of organisational culture in a CJV is not clear. Similarly, poorly organised administrative structures in a CJV can also be a barrier to organisational performance. In South Africa there seems to be no evidence of a common understanding on the CJV formation process. According to CIDB (2004) there is no standard CJV agreement document. Therefore, a need arises to establish guidelines on the formation of a CJV agreement. Secondly, there is a need to establish strategies for the successful transformation of organisational culture in CJV. The research obtains an inside view with contractors who have participated in CJV’s, therefore, utilising the qualitative research method. The choice of data collection method was semi-structured one-on-one face to face interviews. In deriving the findings of the research, the ATLAS.ti software was used throughout the research process to manage both the secondary and primary data. The main factors which cause major problems in CJV's is the preliminary agreement, the partner selection and cultural differences. There is no evidence of a collective understanding among CJV partners regarding the successful formation processes of a CJV. The concept that the industry needs a standardised CJV agreement has been welcomed by the participants, the existence of a common CJV agreement would certainly resolve many problems in the way things are done currently including the implementation of joint venture projects. There is consensus between all participants that there is no standard CJV agreement in use in the South African construction industry and exploring a common approach is an idea that is viewed reasonable and to be one of the practical solutions to the problems in the industry. There are several limitations in this study. First, the sample included emerging and established contractors who are currently registered with the CIDB under Contractor Development Program only. While the sample size is relatively small, the researcher was cautious when interpreting the results. Secondly the targeted population for this research was selected using a sample of convenience method as opposed to a random sample, then the results of the study cannot be generally applied to a larger population. Thirdly, an obvious weakness of the research is the methodological difficulties related to qualitative research which relies on the inferences that are made by the researcher based on their own understanding of the data collected. It is therefore crucial that the data gathered is credible and that the findings represent the truth and actual sentiments as they appear from the data collection process. The research is of importance to managers and supervisors of construction companies of all sizes. The findings of this study will assist in ensuring that CJV are efficiently managed irrespective of the cultural differences.
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- Date Issued: 2018
Construction management’s perceptions of health and safety
- Authors: Sigama, Takalani
- Date: 2018
- Subjects: Construction industry -- Management , Building -- Safety measures Construction industry -- Health aspects Construction industry -- Safety regulations
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/35713 , vital:33784
- Description: Projects in the construction sector are reputed for poor health and safety (H&S) performance, compared to other industries. This can be attributed to, inter alia, a relatively uncontrolled working environment, inherent operational risks, workers' behaviour in relation to H&S commitment, cultural and religious beliefs, and uncertainties inherent in projects. Hazards and risk arising from poor H&S practices result in injuries, and in some cases, fatalities. The aim of this study is to explore the perceptions of construction management regarding H&S on construction sites. This study investigates the relationship between behaviours, attitudes, perceptions, and behaviours towards H&S, and compares cultural divergences among levels of construction personnel, namely construction management, construction supervision, construction H&S personnel, and H&S representatives. The construction industry has for many years developed and maintained a very bad reputation for coping with project cost, H&S, quality, and schedule. The industry often delivers projects late, and contributes to a disproportionate rate of work-related injuries, and fatalities. Project H&S management is acknowledged as one of the techniques that could be improved on construction projects to enhance performance of construction contractors in South Africa. To answer the research question: ‘Why construction management perceive H&S as a hindrance to production?” the mixed-method research approach was used. An indepth literature review with respect to project H&S was carried out, followed by qualitative and quantitative empirical research. The study established the need for H&S training and awareness of Construction Managers, Construction Supervisors, Construction Health and Safety Managers (CHSMs), Officers (CHSOs), and H&S Representatives. The study recommends that an H&S training needs analysis is critical for all employees, since it raises H&S awareness among all stakeholders in the construction industry, and enables the development of training plans, thereby supporting the reduction of accidents and related incident.
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- Date Issued: 2018
Correlation of photovoltaics plant performance metrics
- Authors: Vumbugwa, Monphias
- Date: 2018
- Subjects: Photovoltaic cells , Perfomance -- Evaluation , Thin films
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/45657 , vital:38924
- Description: The generation of electrical energy using Photovoltaic (PV) technology has increased globally with the decrease in the cost of PV systems and the rise in electrical power demand. In South Africa, the support by the government in implementing the Renewable Energy Independent Power Producer Procurement Programme (REIPPPP) has seen a growth in PV system deployment and investment in roof and ground mounted, stand alone and grid connected PV plants. This rapid growth shows that the PV industry is becoming highly competitive as there is a shift to low carbon emissions and it is anticipated to be the most affordable source of electricity. Hence, there is need to develop maintenance and fault diagnosis expertise and capabilities in the PV industry, which can in turn improve the dependability, productiveness and lifespan of PV systems. Solar PV modules directly receive and convert solar irradiance into electricity and may not generate the expected optimum energy due to abnormalities which arise when they are exposed to harsh unfavorable environmental conditions in the field. Thermal Infrared (TIR) imaging is widely used as a fault diagnosis tool in operating PV modules and mostly in large PV power plants. Therefore, there is need to research the interpretation of the observed thermal signatures and the impact that the anomalies have on electrical output of the system so as to improve the PV maintenance systems. This research focuses on identifying performance limiting defects using an Infra-Red (I-R) camera, mounted on an Unmanned Aerial Vehicle (UAV), to understand the effect of thermal signatures on current-voltage (I-V) characteristics of PV module strings. Aerial TIR imaging using a UAV can rapidly identify abnormalities in operational PV modules strings as hotspots. Any deviation of the string I-V curve, from the expected, indicates a problem with one or more PV modules in the string. However, locating the faulty module involves measuring I-V parameters of the individual modules in a string, which is not feasible in large PV power plants. Therefore, there is a need to estimate the power loss associated with the thermal signatures in PV module strings. Visual inspection may help in identifying the exact cause of some hotspots, while other hotspots need special characterization techniques, such as Electroluminescence (EL) and UV Fluorescence (UV-F), which can indicate if a solar cell is cracked or has weak busbars or contact finger connections.
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- Date Issued: 2018
Corrosion resistance of nanocrystalline titanium zirconium nitride layers deposited on ZIRLO
- Authors: Nyembe, Hlanganani Siphelele
- Date: 2018
- Subjects: Zirconium alloys , Titanium alloys Nanocrystals Nanotechnology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34744 , vital:33435
- Description: Zirconium (Zr) alloys are used as nuclear fuel cladding in water-cooled nuclear reactors. Being in contact with steam, the Zr-alloy is oxidised and it absorbs hydrogen. The hydrogen pickup in Zr-alloys induces embrittlement of the tubes due to hydride formation. In this study, effectiveness of corrosion resistant nanocrystalline titanium zirconium nitride (nc-TiZrN) coatings on the surface of a Zr-alloy for the reduction of corrosion and hydrogen pickup is investigated. The nc-TiZrN layers were deposited onto the surface of ZIRLO® using the cathodic arc vapour deposition (CAVD) technique. The influence of nc-TiZrN coatings on the corrosion performance of ZIRLO® was investigated under the following conditions: (a) In an oxygen atmosphere at various temperatures from 400 to 900 ℃ for 30 minutes, (b) for various exposure times from 6 – 24 hours with the temperature kept constant at 500 ℃ in a tube furnace, and (c) in pure steam for 30 days at 360 ℃ and 18.7 MPa in an autoclave. The corrosion properties of the nc-TiZrN coated ZIRLO were compared to uncoated ZIRLO for all experiments. Following corrosion testing, the TiZrN coatings and oxide layers were investigated by scanning and transmission electron microscopy and energy dispersive X-ray spectroscopy. The TiZrN coating had a thickness of ~3.8 μm with a small number of Ti-rich and Nb-rich inclusions. The coating exhibited a single phase solid solution of Ti0.42Zr0.58N with a NaCl-type crystal structure and columnar nanocrystals. These columnar nanocrystals showed a strong {111} preferred orientation and the {111} planes of the TiZrN crystals are oriented parallel to the (001) planes of α-ZIRLO grains with <001> direction perpendicular to the coating/ZIRLO interface. The corrosion testing at various temperatures from 400 to 900 ℃ for 30 minutes showed that the TiZrN coating oxidises slowly and retained its microstructure, composition and crystallinity up to 600 ℃. At higher temperatures above 600 ℃, the TiZrN layer completely oxidised to a non-protective TiZr-oxide layer and resulted in rapid corrosion of the underlying ZIRLO substrate. The rapid corrosion was not observed in the uncoated ZIRLO sample for all temperatures. The results of samples subjected to annealing treatment at 500 ℃ in an oxygen atmosphere at various times up to 24 hours revealed that the TiZrN layer oxidises faster than ZIRLO. This was confirmed by sub-cubic and sub-parabolic oxide growth kinetics observed in the uncoated ZIRLO which are slower than the parabolic kinetics of TiZrN coated samples. In all coated samples, the spallation was observed near the edges of the samples. The spallation was caused by rapid corrosion of the underlying ZIRLO substrate which resulted from the penetration of oxygen ions between the TiZrN coating and ZIRLO substrate along the edges of the samples. In pure steam for 30 days at 360 ℃, a complete loss of the TiZrN layer occurred but the results show that the coating might have delayed the corrosion of ZIRLO. In summary, corrosion resistance of nc-TiZrN coated ZIRLO was lower than that of uncoated ZIRLO. The study shows that the failure of TiZrN coatings leads to rapid corrosion of the underlying ZIRLO substrate which was not observed on the uncoated ZIRLO. It is not yet understood why the presence TiZrN coatings reduced the oxidation resistance of ZIRLO.
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- Date Issued: 2018
Cost and time overruns on Mpumalanga Province infrastructure projects
- Authors: Phalanndwa, Shonisani Aaron
- Date: 2018
- Subjects: Project management -- South Africa -- Mpumalanga , Infrastructure (Economics) industrial management -- South Africa -- Mpumalanga Business enterprises -- South Africa -- Mpumalanga -- Finance
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34169 , vital:33248
- Description: Cost and time overruns in construction projects are a common issue affecting project performance, and Mpumalanga is no exception. Completion of any project within the estimated cost of a project is a basic criterion for success of any project. The success of any project highly depends on adequate availability and efficient management of various resources. Construction projects often face a lot of uncertainties, which places building construction projects at the risk of cost, time overruns as well as poor quality delivery. This study assesses the causes, effects and measures of minimising construction project cost and time overrun in the Mpumalanga Province. The data used in this study were derived from both primary and secondary sources. The primary data was collected through case study interviews with construction professionals, project owners, contractors and consultants involved in Mpumalanga construction projects. Findings from the case study revealed that clients inability to meet payment obligations on time, additional work requested by the client, proper feasibility study not done, ensuring transparency in awarding of contracts, contractors financial difficulties, late delivery of materials, contractors lack of experience, bribery and corruption involving the contractor or contractor’s team, and poor site management and consultants insufficient geotechnical investigations, insufficient/unknown information regarding site conditions during design phase, mistakes and discrepancies in design documents are the major causes of cost and time overruns that are incidental to project implementation in Mpumalanga. Furthermore the study also reveals that the major effect of cost and time overrun are: poor quality workmanship, total abandonment, and disputes, discouragement of investors, community unrest and service delivery is negatively affected. It was revealed that all stakeholders of construction parties are deeply involved in contributing to the causes of the problems, clients should bear the greatest responsibility and play the most important role in lessening the impact of cost and time overrun. Thus, interventions that could be adopted by the Mpumalanga province to achieve project delivery that is within estimated cost and time are: Government must adopt ‘financial assignment’ to deal with suppliers in order to supply materials to the contractor and have available funds for projects on time, soil investigation and testing should be conducted by clients prior to the commencement of a project; encourage whistleblowing and punish fraudsters more severely. Contractors must have enough cash before commencing of projects, v monitor financial spending of the projects and payments; consultants must review and approve design documents, shop drawings, and payments of contractor. It is recommended that training courses, seminars and workshops on project management should be made available to help improve the abilities of construction teams responsible for management and supervision of sites and client organisations should encourage whistleblowing, punish fraudsters more efficiently and pay commensurate reward to whistle-blowers in order to minimise cost and time overruns.
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- Date Issued: 2018
De-identification of personal information for use in software testing to ensure compliance with the Protection of Personal Information Act
- Authors: Mark, Stephen John
- Date: 2018
- Subjects: Data processing , Information technology -- Security measures , Computer security -- South Africa , Data protection -- Law and legislation -- South Africa , Data encryption (Computer science) , Python (Computer program language) , SQL (Computer program language) , Protection of Personal Information Act (POPI)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/63888 , vital:28503
- Description: Encryption of Personally Identifiable Information stored in a Structured Query Language Database has been difficult for a long time. This is owing to block-cipher encryption algorithms changing the length and type of the input data when encrypted, which cannot subsequently be stored in the database without altering its structure. As the enactment of the South African Protection of Personal Information Act, No 4 of 2013 (POPI), was set in motion with the appointment of the Information Regulators Office in December 2016, South African companies are intensely focused on implementing compliance strategies and processes. The legislation, promulgated in 2013, encompasses the processing and storage of personally identifiable information (PII), ensuring that corporations act responsibly when collecting, storing and using individuals’ personal data. The Act comprises eight broad conditions that will become legislation once the new Information Regulator’s office is fully equipped to carry out their duties. POPI requires that individuals’ data should be kept confidential from all but those who specifically have permission to access the data. This means that not all members of IT teams should have access to the data unless it has been de-identified. This study tests an implementation of the Fixed Feistel 1 algorithm from the National Institute of Standards and Technology (NIST) “Special Publication 800-38G: Recommendation for Block Cipher Modes of Operation : Methods for Format-Preserving Encryption” using the LibFFX Python library. The Python scripting language was used for the experiments. The research shows that it is indeed possible to encrypt data in a Structured Query Language Database without changing the database schema using the new Format-Preserving encryption technique from NIST800-38G. Quality Assurance software testers can then run their full set of tests on the encrypted database. There is no reduction of encryption strength when using the FF1 encryption technique, compared to the underlying AES-128 encryption algorithm. It further shows that the utility of the data is not lost once it is encrypted.
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- Date Issued: 2018
Deep learning applied to the semantic segmentation of tyre stockpiles
- Authors: Barfknecht, Nicholas Christopher
- Date: 2018
- Subjects: Neural networks (Computer science)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/23947 , vital:30647
- Description: The global push for manufacturing which is environmentally sustainable has disrupted standard methods of waste tyre disposal. This push is further intensified by the health and safety risks discarded tyres pose to the surrounding population. Waste tyre recycling initiatives in South Africa are on the increase; however, there is still a growing number of undocumented tyre stockpiles developing throughout the country. The plans put in place to eradicate these tyre stockpiles have been met with collection, transport and storage logistical issues caused by the remoteness and distant locales. Eastwood (2016) aimed at optimising the logistics associated with collection, by estimating the number of visible tyres from images of tyre stockpiles. This research was limited by the need for manual segmentation of each tyre stockpile located within each image. This research proposes the use of semantic segmentation to automatically segment images of tyre stockpiles. An initial review of neural network, convolutional network and semantic segmentation literature resulted in the selection of Dilated Net as the semantic segmentation architecture for this research. Dilated Net builds upon the VGG-16 classification architecture to perform semantic segmentation. This resulted in classification experiments which were evaluated using precision, recall and f1-score. The results indicated that regardless of tyre stockpile image dimension, fairly accurate levels of classification accuracy can be attained. This was followed by semantic segmentation experiments which made use of intersection over union (IoU) and pixel accuracy to evaluate the effectiveness of Dilated Net on images of tyre stockpiles. The results indicated that accurate tyre stockpile segmentation regions can be obtained and that the trained model generalises well to unseen images.
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- Date Issued: 2018
Demographic change in the Upper Tsitsa Catchment: the integration of census and land cover data for 2001 and 2011
- Authors: Hodgson, Danuta Lorina
- Date: 2018
- Subjects: Land use -- South Africa -- Eastern Cape , Watersheds -- South Africa -- Eastern Cape , Thematic maps -- South Africa -- Eastern Cape , Population density -- South Africa -- Eastern Cape , Mzimvubu River Watershed (South Africa) -- Census , Upper Tsitsa Catchment (South Africa)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/57296 , vital:26870
- Description: The purpose of this research was to determine if the integration of census and land cover data could provide evidence of spatial patterns and temporal change for the Upper Tsitsa Catchment. This thesis contributed to academic literature with regards to dasymetric mapping and provided a database for the Ntabelanga and Laleni Ecological Infrastructure Project. The study took place in the Upper Tsitsa Catchment which is located in the north-eastern region of the Eastern Cape and falls within the uMzimvubu Catchment. South Africa National Population Censuses for 2001 and 2011 and the National Land Cover data sets for 2000 and 2013/14 were used to create dasymetric maps depicting demographic changes over time for the catchment area. Spatial statistics were performed on the dasymetric and choropleth map to determine the accuracy of the data that was created. From the results, it was found that although the statistics were skewed, the method was more accurate in displaying the population densities, which was noted during the sampling process of the spatial analysis. It was found that there had been a decrease in the population density within the catchment. This affected the density of several other variables such as population race group, language and employment status statistics as decreases in these values could be due to individuals migrating out of the catchment as well as socio-economic upliftment, such as having better access to services. The use of dasymetric mapping allowed an accurate representation of the population density from the census data to be created. The results of the dasymetric mapping were more accurate as they depicted where the population within the enumeration areas were located, and recognised that some areas were populated while some areas were not. To conclude, it was found that using dasymetric mapping provided reliable and useful data about population density and enables comparison over time.
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- Date Issued: 2018
Design and development of a context sensitive rural development software application for eService provisioning
- Authors: Masikisiki, Lizo
- Date: 2018
- Subjects: Rural development Electronic commerce Computer networks
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/15332 , vital:40366
- Description: After more than a decade since South Africa realized the importance of Information and Communication Technology (ICT) and the role it can play to deliver services, the country is still confronted by a number of challenges challenges that hinder the implementation of a fully-fledged ICT-based system in a form of electronic government to better deliver services and information. While rural development remains as one of the country’s greatest concerns, ICT is among approaches and perspectives that are recognized for not only accelerating rural development but also for providing the country’s economic growth. This research was set to investigate approaches to implement ICT solutions for rural development and service provisioning in the context of electronic government. The research focused more on the technical skills to implement such ICT systems for the benefit of rural development and e-government stakeholders that have an interest in design and development of an integrated and interoperable solution to accelerate service delivery, especially in rural communities. A mixed methods approach was used throughout the research accompanied by an evolutionary prototyping to development the desired prototype. A study was then conducted to gain an understanding of the state and the needs of rural communities to date. The results of the study yielded a number of urbanized service providers that rural dwellers need to timeously visit to consume services. Scenarios to design and develop the intended prototypes were then drawn from these results. The overall implementation of the prototypes produced an integrated platform that allows multiple disparate systems to communicate, share and use information. The qualities of the prototype are what this research recommends to relevant to stakeholders in order to implement an integrated and interoperable e-government system that elevates rural development programs and service delivery.
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- Date Issued: 2018
Designing and prototyping WebRTC and IMS integration using open source tools
- Authors: Motsumi, Tebagano Valerie
- Date: 2018
- Subjects: Internet Protocol multimedia subsystem , Session Initiation Protocol (Computer network protocol) , Computer software -- Development , Web Real-time Communications (WebRTC)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/63245 , vital:28386
- Description: WebRTC, or Web Real-time Communications, is a collection of web standards that detail the mechanisms, architectures and protocols that work together to deliver real-time multimedia services to the web browser. It represents a significant shift from the historical approach of using browser plugins, which over time, have proven cumbersome and problematic. Furthermore, it adopts various Internet standards in areas such as identity management, peer-to-peer connectivity, data exchange and media encoding, to provide a system that is truly open and interoperable. Given that WebRTC enables the delivery of multimedia content to any Internet Protocol (IP)-enabled device capable of hosting a web browser, this technology could potentially be used and deployed over millions of smartphones, tablets and personal computers worldwide. This service and device convergence remains an important goal of telecommunication network operators who seek to enable it through a converged network that is based on the IP Multimedia Subsystem (IMS). IMS is an IP-based subsystem that sits at the core of a modern telecommunication network and acts as the main routing substrate for media services and applications such as those that WebRTC realises. The combination of WebRTC and IMS represents an attractive coupling, and as such, a protracted investigation could help to answer important questions around the technical challenges that are involved in their integration, and the merits of various design alternatives that present themselves. This thesis is the result of such an investigation and culminates in the presentation of a detailed architectural model that is validated with a prototypical implementation in an open source testbed. The model is built on six requirements which emerge from an analysis of the literature, including previous interventions in IMS networks and a key technical report on design alternatives. Furthermore, this thesis argues that the client architecture requires support for web-oriented signalling, identity and call handling techniques leading to a potential for IMS networks to natively support these techniques as operator networks continue to grow and develop. The proposed model advocates the use of SIP over WebSockets for signalling and DTLS-SRTP for media to enable one-to-one communication and can be extended through additional functions resulting in a modular architecture. The model was implemented using open source tools which were assembled to create an experimental network testbed, and tests were conducted demonstrating successful cross domain communications under various conditions. The thesis has a strong focus on enabling ordinary software developers to assemble a prototypical network such as the one that was assembled and aims to enable experimentation in application use cases for integrated environments.
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- Date Issued: 2018
Determining productivity, residual damage and cost of two alternative harvesting systems in pinus elliottii thinning
- Authors: Dembure, Tigere Pasca , Spinelli, Raffaele , Ramantswana, Muedanyi
- Date: 2018
- Subjects: Pinus caribaea , Forests and forestry Logging Harvesting -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/22016 , vital:29813
- Description: Pinus elliottii is the second most dominant softwood grown in the South African plantation forestry industry. It possesses desirable timber characteristics and is useful for production of solid wood products. In the silviculture of softwoods (grown for solid wood products), thinning is an important tending operation. It is necessary for stand hygiene and volume increment of residual trees through the creation of growing space. The selection of a suitable harvesting system for thinning is vital. The system of choice has to attain higher productivity, cause the least damage to residual trees and must be cost effective. From as early as 2000 the South African forestry industry witnessed a general shift towards the use of fully mechanised cut-to-length harvesting systems. This has been a result of high labour turnover, increased labour costs, increased timber demand and the effects of HIV and AIDS on forestry workers. With this recent introduction of mechanised systems, they have not been benchmarked against conventional harvesting systems. In this regard, two harvesting systems were studied side-by-side for productivity, residual damage and cost in a seventh row second thinning operation in P. elliottii stands. First thinnings generate poor financial returns since small trees are harvested and they have a relatively low financial value but have a relatively high operational cost per unit harvested. The second thinning operation is usually the thinning operation that is most likely to result in an intermediate financial return for the organisation, hence the need to benchmark these harvesting systems during the second thinning. These systems were a fully mechanised cut-to-length (CTL) and a semi-mechanised tree length (TL) system. The fully mechanised system comprised of a harvester (felling) and a forwarder (extracting) and the semi-system consisted of felling by chainsaw, tractor extraction, roadside processing by chainsaw and stacking by three-wheeled logger. Two uniform compartments planted with P. elliottii were selected for the study. A total number of 32 plots (16 plots per compartment) were marked and randomly assigned between the two treatments, each plot comprised of seven rows, with the middle row clear-cut and three rows on either side, where marked trees were selectively removed. Within each plot, the number of removal trees ranged from 80 to 105. The diameter, height and form of each removal tree were measured to determine tree volume and ultimately determine productivity. Before analysis, plot characteristics were compared to determine if conditions were equal for both treatments using the Mann-Whitney test at alpha level ˂ 0.05. There was a statistically significant difference in total operator efficiency between the two systems (p ˂ 0.0001). The fully mechanised system attained higher levels of productivity than the semi-mechanised system (15.58 m3/SMH versus 5.26 m3/SMH, for felling and 15.56 m3/SMH versus 5.29 m3/SMH, for the extraction operation). Operator productivity comparisons were restricted to the two harvester operators, and one operator achieved 16.9 m3/SMH while the other operator achieved 14.3 m3/SMH. Different operator working technique contributed to the productivity differences with one operator spending (on average) four seconds less per tree on the fell-process work element. Residual tree damage was assessed immediately after all felling and extraction had taken place. Damage size was measured as ellipse surface area. For each record of residual damage, the damage type was noted, damage position along the stem, and tree position from extraction trail. The most predominant damage type was bark peel. The motor-manual system caused five per cent damage and the fully mechanised system inflicted only three per cent damage to the residual trees. Residual tree damage from the semi-mechanised system mainly occurred at the root zone, and occurred more frequently on edge trees. The mechanised CTL system was characterised by high investment and operational costs. The mechanised system incurred 3037.75 R/SMH while the semi-mechanised system incurred 1667.10 R/SMH. The difference in total costs per year between both systems was 56.29 per cent, with the fully mechanised system being more expensive. The high capacity and the superior technology of mechanised harvesting systems may not be fully exploited in thinnings, therefore harvesting systems with lower capital costs and reasonable productivity can be competitive.
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- Date Issued: 2018
Developing a citizen technician based approach to suspended sediment monitoring in the Tsitsa River catchment, Eastern Cape, South Africa
- Authors: Bannatyne, Laura Joan
- Date: 2018
- Subjects: Sediments (Geology) -- Management , Sediments (Geology) -- South Africa -- Eastern Cape , Watersheds -- South Africa -- Eastern Cape , Suspended sediments -- South Africa -- Eastern Cape , Suspended sediments -- Monitoring -- Citizen participation , Tsitsa River
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62593 , vital:28211
- Description: Suspended sediment (SS) in channels is spatiotemporally heterogeneous and, over the long term, is known to be moved predominantly by flood flows with return periods of ~1 - 1.5 years. Flood flows in the Tsitsa catchment (Eastern Cape Province, South Africa) are unpredictable, and display a wide range of discharges. Direct, flood-focused SS sampling at sub-catchment scale was required to provide a SS baseline against which to monitor the impact on SS of catchment rehabilitation interventions, to determine the relative contributions of sub-catchments to SS loads and yields at the site of the proposed Ntabelanga Dam wall, and to verify modelled SS baselines, loads and yields. Approaches to SS sampling relying on researcher presence and/or installed equipment to adequately monitor SS through flood flows were precluded by cost, and the physical and socioeconomic conditions in the project area. A citizen technician (CT)-based flood-focused approach to direct SS sampling was developed and implemented. It was assessed in terms of its efficiency and effectiveness, the proficiency of the laboratory analysis methods, and the accuracy of the resulting SS data. A basic laboratory protocol for SSC analysis was developed, but is not the focus of this thesis. Using basic sampling equipment and smartphone-based reporting protocols, local residents at eleven points on the Tsitsa River and its major tributaries were employed as CTs. They were paid to take water samples during daylight hours at sub-daily timestep, with the emphasis on sampling through flood flows. The method was innovative in that it opted for manual sampling against a global trend towards instrumentation. Whilst the management of CTs formed a significant project component, the CTs benefitted directly through remuneration and work experience opportunities. The sampling method was evaluated at four sites from December 2015 - May 2016. The CTs were found to have efficiently and effectively sampled SS through a range of water levels, particularly in the main Tsitsa channel. An acceptable level of proficiency and accuracy was achieved, and many flood events were successfully defined by multiple data points. The method was chiefly limited by the inability of CTs to sample overnight rises and peaks occurring as a result of afternoon thunderstorms, particularly in small tributaries. The laboratory process was responsible for some losses in proficiency and accuracy. Improved laboratory quality control was therefore recommended. The CT-based approach can be adapted to other spatial and temporal scales in other areas, and to other environmental monitoring applications.
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- Date Issued: 2018
Developing and testing the congruency of selected biological indicators and an existing tool designed to assess wetland health in agricultural settings in the KZN Midlands
- Authors: Kubheka, Patrick Skhumbuzo
- Date: 2018
- Subjects: Wetland conservation -- South Africa -- KwaZulu-Natal , Wetland management -- South Africa -- KwaZulu-Natal , Wetland ecology -- South Africa -- KwaZulu-Natal , Ecosystem services -- South Africa -- KwaZulu-Natal , Environmental monitoring -- South Africa -- KwaZulu-Natal , Water quality biological assessment -- South Africa -- KwaZulu-Natal
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/58310 , vital:27211
- Description: Despite the fact that wetlands have been understood to be important for a wide range of ecosystem services, wetlands continue to be degraded globally. There has been a growing need to develop biomonitoring tools that reflect the present ecological state of wetlands, but very few attempts have been made in South Africa to achieve this, and those that have attempted this have generally achieved limited success. This study was conducted to develop and test the congruency of four selected biological indicators (dragonflies, frogs, macroinveterbrates and plants) in relation to the assessment of present ecological state using an existing method in South Africa, "WET-Health". WET-Health assessments rely primarily on transformations to a wetland that result from human impacts in both the catchment and the wetland itself. Using the tool, a health score is obtained that is consistent with the Department of Water Affairs (DWA) current "present ecological state” as applied to river health assessment. The study was conducted in agricultural settings of the Midlands of KwaZulu-Natal based on 13 wetlands. The selected wetlands were scored using WET - Health and grouped in four different ecological condition classes (A, B, C and D). Physical characteristics (wetland area, mean depth), biological characteristics (species cover/abundance, presence and species richness), and chemical characteristics (ammonia, pH, sulphate, nitrogen and phosphate) were also recorded in the selected wetlands. Nineteen different species of dragonfly were recorded in this study. The study demonstrated that dragonflies are a promising bioindicator of wetland present ecological state as the dragonfly index was found to be closely correlated with WET- Health scores. Open water bodies within the selected wetlands were the focus of dragonfly sampling, as male dragonflies are territorial and they will patrol or be found around this habitat. Emergent vegetation dominated by sedges formed the focus of macroinvertebrate sampling in this study because greater numbers of macroinvertebrate families were found in this biotope in comparison to open water areas with no emergent vegetation. A total of 47 macroinvertebrate families were recorded in this study, but SASS5 scores based on macroinvetebrates showed no correlation with WET-Health scores. A total of 10 different frog species were recorded in this study. All the species were common frog species found in most parts of the country. Frog species richness and occurrence showed no correlation with WET- Health scores. A total of twenty samples of two meter radius were measured per wetland and sampled for plant species and estimation of cover-abundance of each species per sample. Over 50 different plant species were recorded in this study, and both species accumulation and species richness showed a degree of correlation with WET-Health scores. All the wetlands in class A had generally higher species accumulation rate and species richness compared to the other wetland classes. In addition to testing the congruency of four selected biological indicators with WET- Health, water quality was measured in all the wetlands. Wetlands in class A were associated with improved water quality as the water passes through the wetland. However, wetlands in class C and D did not show consistently improved water quality between the apex and the toe of these wetlands. In some cases the water quality deteriorated as it passed through wetlands in these two classes.
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- Date Issued: 2018
Development and assessment of a smart thermosetting intranasal hydrogel for lamotrigine
- Authors: Melamane, Siyabonga
- Date: 2018
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62975 , vital:28349
- Description: Expected release date-April 2020
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- Date Issued: 2018
Development and assessment of gastroretentive sustained release captopril micro-balloons
- Authors: Oridota, Omoyosola Omolola
- Date: 2018
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/63491 , vital:28419
- Description: Expected release date-April 2020
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- Date Issued: 2018