List of Titles

The nature of geometry instruction and observed learning-outcomes opportunities in Nigerian and South African high schools:

- Atebe, Humphrey U, Schäfer, Marc

Authors: Atebe, Humphrey U , Schäfer, Marc
Date: 2013
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/140919 , vital:37929 , DOI: 10.1080/10288457.2011.10740712
Description: The purpose of this qualitative case study involving six secondary school teachers was to obtain insight into how geometry is taught in selected Nigerian and South African high schools. It also aimed, by making use of the van Hiele model of geometry instruction, to elucidate what possible learning opportunities observed instructional methods could offer learners in the subject. The sample comprised three mathematics teachers from Nigeria and three mathematics teachers from South Africa, all of whom were selected using purposive sampling techniques. Instructional activities in six geometry classrooms were recorded on videotape. The van Hiele learning phases provided the framework for data analysis. The findings of this study indicate that observed teaching methods in geometry classrooms in the participating schools offer learners scant opportunity to learn geometry.
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The Personal Is the International

- Magadla, Siphokazi

Authors: Magadla, Siphokazi
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/298674 , vital:57726 , xlink:href="https://doi.org/10.1080/02589346.2013.856568"
Description: The article reflects on why I opted for Political Science as my career. It tells of a society where once black women could only imagine themselves either as maids, teachers or nurses—this was my mother's world. The narrative shows how a racialised and gendered history shapes both my hopes for a particular kind of international relations theory and practice, as it shapes my frustrations and anxieties about my own future in the discipline. I also locate my place in the discipline within broader global ‘disruptions’ that see previously marginalised actors moving to the centre of international life. I also attempt to demonstrate that international relations today is located in globalised peace but within localised extremes of poverty and privilege. I make the case that the challenge to International Relations (IR) theory today is to find a language, a new language, in which to articulate the contradictions of a globalised peace that exists within localised extremes of poverty and privilege.
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The photophysical and photochemical behaviour of coumarin-derivatized zinc phthalocyanine when conjugated with gold nanoparticles and electrospun into polymer fibers

- Tombe, Sekai, Antunes, Edith M, Nyokong, Tebello

Authors: Tombe, Sekai , Antunes, Edith M , Nyokong, Tebello
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/232534 , vital:50000 , xlink:href="https://doi.org/10.1039/C2NJ40984D"
Description: Polymer composite fibers doped with phthalocyanines and phthalocyanine-functionalized gold nanoparticles were developed. The phthalocyanine and phthalocyanine-functionalized gold nanoparticles have been characterized using UV/Vis, fluorescence and X-ray photoelectron spectroscopy (XPS), time correlated single photon counting (TCSPC), time-resolved emission spectra (TRES) and transmission electron microscopy (TEM). The changes in photophysical and photochemical behavior of the phthalocyanines induced by their interaction with gold nanoparticles and polystyrene were also investigated. In the presence of gold nanoparticles, the fluorescence lifetimes and quantum yields of the phthalocyanine decreased, whereas the singlet oxygen quantum yield increased. This work shows that polymer composite fibers could be used as functional fibers for a variety of applications such as gas sensing when using the advantageous properties of phthalocyanines and gold nanoparticles.
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The relationship between marital status and life satisfaction among South African adults

- Botha, Ferdi, Booysen, Frikkie

Authors: Botha, Ferdi , Booysen, Frikkie
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/396207 , vital:69158 , xlink:href="https://hdl.handle.net/10520/EJC138900"
Description: This article examines the association between marital status and reported life satisfaction in South Africa. Using the 2008 National Income Dynamics Survey, the relationship between marital status and life satisfaction is heterogeneous. In the overall sample, life satisfaction is significantly higher for married compared to widowed individuals, while the former are more satisfied than those from all other marital statuses. In the overall and female samples, married people are more satisfied compared to those from all other marital status groups. Married men are not significantly more satisfied than men from other marital statuses as a whole. Marriage is positively associated with life satisfaction among women, but not among men.
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The South African Defence Review (2012) and private military/security companies (PMSCs): heralding a shift from prohibition to regulation?

- Juma, Laurence, Tsabora, James

Authors: Juma, Laurence , Tsabora, James
Date: 2013
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/126132 , vital:35852 , https://doi.org/10.17159/1727-3781/2013/v16i4a2415
Description: This article discusses the possibility of South Africa enacting a new law regulating private military/security companies (PMSCs) beyond the Prohibition of Mercenary Activities and Regulation of Certain Activities in Country of Armed Conflict Act of 2006. It argues that such a possibility arises from the policy direction expressed in the Defence Review of 2012, and the recent developments at the international level, which indicate a shift towards accommodation of PMSCs as legitimate players in the security sector. The article surveys the current state of national and international law relating to PMSCs and illustrates how the emerging shift from prohibition to regulation has affirmed the need for legislative intervention in this field. It concludes that since the future is on the side of regulation and not prohibition, legislation that furthers the policy agenda envisioned by the Defence Review 2012 may be the best tool to unlock the inhibitions of the past and create a viable climate for reframing the debate on domestic law governing private militarism in South Africa.
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The supernatural detective: witchcraft crime narratives in the Daily Sun

- Boshoff, Priscilla A

Authors: Boshoff, Priscilla A
Date: 2013
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/143447 , vital:38247 , DOI: 10.1080/1013929X.2013.833420
Description: Reports of witchcraft crimes are a staple feature in the South African tabloid newspaper, the Daily Sun. Instead of dismissing these sensational and seemingly implausible narratives, this paper examines them as ‘fictions’ through the lens of theory developed for the analysis of detective fiction. It draws on Huhn's (1987) model of the readerly relationships established by the narrative forms of the classical detective story and the hard-boiled novel in order to show how the reportage, together with its expected reception, reveals subliminal tensions within working-class black culture. Ironically, such a reading illustrates how the brazen and emotive nature of the tabloid text, which signals for some its untrustworthiness, perhaps comes closer to telling a ‘truth’ about contemporary South African society than the most ‘objective’ reports.
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The synthesis and characterisation of magnetic nanoparticles and their interaction with a zinc phthalocyanine

- Antunes, Edith M, Rapulenyane, Nomasonto, Ledwaba, Mpho, Litwinski, Christian, Chidawanyika, Wadzanai J U, Nyokong, Tebello

Authors: Antunes, Edith M , Rapulenyane, Nomasonto , Ledwaba, Mpho , Litwinski, Christian , Chidawanyika, Wadzanai J U , Nyokong, Tebello
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/242111 , vital:51002 , xlink:href="https://doi.org/10.1016/j.inoche.2012.12.010"
Description: A variety of nanoparticles (NPs), including FePt nanoparticles with Fe as the shell (2) or Pt as the shell (3), Pt NPs (4), and FePd (5) were synthesised, characterised and their effect on a zinc phthalocyanine (1) tetra-substituted with a pyridyl-oxy substituent studied using UV/Vis and fluorescence spectroscopy (including time correlated single photon counting, TCSPC). The nanoparticles were characterised using a number of techniques including UV/Vis and inductively coupled plasma-optical emission (ICP-OES) spectroscopies, transmission electron microscopy (TEM), differential scanning calorimetry (DSC), X-ray powder diffraction (XRD) and electron paramagnetic resonance (EPR) spectroscopy. Nanocomposites (NCs, 6,7) where the ZnPc (1) was used as the stabiliser, instead of oleic acid and or oleylamine, were also synthesised and characterised.
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Think Piece : conceptions of quality and ‘Learning as Connection’: teaching for relevance

- Lotz-Sisitka, Heila

Authors: Lotz-Sisitka, Heila
Date: 2013
Subjects: Teachers -- Quality -- South Africa , Quality assurance -- South Africa , Effective teaching , Relevance , SADC Regional Environmental Education Programme
Language: English
Type: article , text
Identifier: http://hdl.handle.net/10962/59635 , vital:27633 , https://www.ajol.info/index.php/sajee/article/view/122256
Description: This think piece captures some of the thinking that emerged in and through the Southern African Development Community (SADC) Regional Environmental Education Programme research programme. This research programme emerged over a five-year period (2008–2012) and involved ten southern African teacher education institutions from eight countries (see ‘Acknowledgements’). The research programme sought to understand what contributions environment and sustainability education could make to debates on educational quality and relevance. Issues of educational quality are high on the national agendas of governments in southern Africa, as it is now well known that providing access to schooling is not a sufficient condition for achieving educational quality. Educational quality is intimately linked to the processes of teaching and learning, but the concept of educational quality is not unproblematic in and of itself. It is, as Noel Gough (2005) noted many years ago, an ‘order word’ that shapes the way people think and practise. Our enquiries during this research programme involved a number of case studies (that were reported on in the Southern African Journal of Environmental Education (SAJEE) in 2008, and are again reported on in this edition of the SAJEE), but the programme also involved theoretical engagement with the concept of educational quality and relevance. This think piece helps to make some of this thinking and theoretical deliberation visible. The author of this think piece was also the leader of the regional research programme and was tasked with synthesising the theoretical deliberations that emerged from the research design which were found to be useful for guiding interpretations and deliberation on more detailed case studies undertaken at country level.
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Think Piece, Naked Science-Avoiding Methodolatry in an Environmental Education Context

- Price, Leigh

Authors: Price, Leigh
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/387264 , vital:68220 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122255"
Description: Research methodology is significantly political and in this think piece I try to better understand the effect of this politicisation in the production of science. The main focus of the think piece is to identify the dominant methodological discourses and analyse them using techniques borrowed from post-structuralism. From this analysis, I suggest that methodological discourses are reproduced and normalised in much the same way as discourses of, for example, sexuality, and I give examples of this from my experience as a PhD student of environmental education. I also suggest that some transgressive methodologies, such as those associated with postmodernism or participatory research, despite purporting to empower, at times also disempower. Furthermore, all of the methodologies that I analyse are, in one way or another, ‘loaded’; they cloak their agendas. From this analysis, I move towards suggesting an alternative critical realist methodology for environmental education which is naked; its agendas are clearly stated, not least because this epistemology does not lend itself to deception. An important part of this critical realist conception of methodology is the idea of ‘meta-reflexivity’ in which truth is not vulgarly pragmatic or fideistic.
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Third order nonlinear optical properties of phthalocyanines in the presence nanomaterials and in polymer thin films

- Britton, Jonathan, Durmus, Mahmut, Khene, Samson M, Chauke, Vongani, Nyokong, Tebello

Authors: Britton, Jonathan , Durmus, Mahmut , Khene, Samson M , Chauke, Vongani , Nyokong, Tebello
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/241772 , vital:50968 , xlink:href="https://doi.org/10.1142/S108842461350003X"
Description: Third order nonlinear optical properties were determined for phthalocyanine complexes 1–10 containing In, Ga and Zn central metals and tetra- or octa-substituted with benzyloxyphenoxy, phenoxy, tert-butylphenoxy and amino groups at peripheral or non-peripheral positions. The phthalocyanines were embedded in poly (methyl methacrylate) polymer in the presence of CdTe quantum dots. All complexes 1–10 were studied in the presence of CdTe quantum dots and embedded in poly (methyl methacrylate) to form thin films. Complex 3 tetrasubstituted with tert-butylphenoxy groups at non-peripheral positions was also studied in the presence of CdS, CdSe quantum dots, fullerenes, single walled carbon nanotubes. Third order nonlinear optical parameters generally increase for Pcs in the presence of CdTe quantum dots.
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Towards a GPU accelerated virtual machine for massively parallel packet classification and filtering

- Nottingham, Alastair, Irwin, Barry V W

Authors: Nottingham, Alastair , Irwin, Barry V W
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/430295 , vital:72681 , https://doi.org/10.1145/2513456.2513504
Description: This paper considers the application of GPU co-processors to accelerate the analysis of packet data, particularly within extremely large packet traces spanning months or years of traffic. Discussion focuses on the construction, performance and limitations of the experimental GPF (GPU Packet Filter), which employs a prototype massively-parallel protocol-independent multi-match algorithm to rapidly compare packets against multiple arbitrary filters. The paper concludes with a consideration of mechanisms to expand the flexibility and power of the GPF algorithm to construct a fully programmable GPU packet classification virtual machine, which can perform massively parallel classification, data-mining and data-transformation to explore and analyse packet traces. This virtual machine is a component of a larger framework of capture analysis tools which together provide capture indexing, manipulation, filtering and visualisation functions.
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Transcribing the Venda tshikona reedpipe dance

- Tracey, Andrew, Gumboreshumba, Laina

Authors: Tracey, Andrew , Gumboreshumba, Laina
Date: 2013
Language: English
Type: article , text
Identifier: http://hdl.handle.net/10962/59744 , vital:27644 , http://dx.doi.org/10.21504/amj.v9i3.1909
Description: Starting with the end result, the above transcription is the conclusion I came to after sitting with Laina Gumboreshumba for many hours, watching the videos she made during her recent doctoral research on the tshikona reedpipe dance of the Venda of Limpopo Province in the extreme north of South Africa. The transcription shown in Figure 2 is a skeleton version of the full pipe sound that contains all the information needed to grasp the structure of the sound and teach it or play it. There are always seven different pipes. A full tshikona group has far more than the seven pipes (nanga) shown, because all seven pipe numbers are doubled in every octave present in a group, so there may be up to four or more Pipe 1s, Pipe 2s, etc, of different sizes. All the Pipe 1s play the same pattern together, all the Pipe 2s etc. There are usually four octaves in all, with an incomplete octave of a few higher pitched pipes at the top (phalana). A popular size for a group according to group leaders (malogwane) is twenty eight pipes, which may include some pitch duplicates. A festive performance can number well over one hundred players. The music is heptatonic as you can see from the transcription, and hear for yourself from CD track 1 accompanying this issue of African Music. A chart showing the tuning is included as Figure 1 1 at the end of this article. This article does not address the pipe names; they are simply numbered Pipes 1 to 7, in the order of entry in Mr Netshivhale’s groups. The pipes are end-blown, closed tubes made of a special bamboo, or increasingly today of electrical or other tubing.
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Two sides of the same coin: extinctions and originations across the Atlantic/Indian Ocean boundary as consequences of the same climate oscillation

- Teske, Peter R, Zardi, Gerardo I, McQuaid, Christopher D, Nicastro, Katy R

Authors: Teske, Peter R , Zardi, Gerardo I , McQuaid, Christopher D , Nicastro, Katy R
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/445547 , vital:74399 , https://doi.org/10.21425/F5FBG15591
Description: Global climate change is correlated not only with variation in extinction rates, but also with speciation rates. However, few mechanisms have been proposed to explain how climate change may have driven the emergence of new evolutionary lineages that eventually became distinct species. Here, we discuss a model of range extension followed by divergence, in which the same climate oscillations that resulted in the extinction of coastal species across the Atlantic/Indian Ocean boundary in southwestern Africa also sowed the seeds of new biodiversity. We present evidence for range extensions and evolutionary divergence from both fossil and genetic data, but also point out the many challenges to the model that need to be addressed before its validity can be accepted.
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Ultrafast Photodynamics of the Indoline Dye D149 Adsorbed to Porous ZnO in Dye‐Sensitized Solar Cells

- Rohwer, Egmont, Richter, Christoph, Heming, Nadine, Strauch, Kerstin, Litwinski, Christian, Nyokong, Tebello, Schlettwein, Derck, Schwoerer, Heinrich

Authors: Rohwer, Egmont , Richter, Christoph , Heming, Nadine , Strauch, Kerstin , Litwinski, Christian , Nyokong, Tebello , Schlettwein, Derck , Schwoerer, Heinrich
Date: 2013
Subjects: To be catalogued
Language: English
Type: text , article
Identifier: http://hdl.handle.net/10962/242153 , vital:51006 , xlink:href="https://doi.org/10.1002/cphc.201200715"
Description: We investigate the ultrafast dynamics of the photoinduced electron transfer between surface-adsorbed indoline D149 dye and porous ZnO as used in the working electrodes of dye-sensitized solar cells. Transient absorption spectroscopy was conducted on the dye in solution, on solid state samples and for the latter in contact to a I−/I3− redox electrolyte typical for dye-sensitized solar cells to elucidate the effect of each component in the observed dynamics. D149 in a solution of 1:1 acetonitrile and tert-butyl alcohol shows excited-state lifetimes of 300±50 ps. This signature is severely quenched when D149 is adsorbed to ZnO, with the fastest component of the decay trace measured at 150±20 fs due to the charge-transfer mechanism. Absorption bands of the oxidized dye molecule were investigated to determine regeneration times which are in excess of 1 ns. The addition of the redox electrolyte to the system results in faster regeneration times, of the order of 1 ns.
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