Electrocatalytic studies of covalently immobilized metal tetra-amino phthalocyanines onto derivatized screen-printed gold electrodes
- Mashazi, Philani N, Nyokong, Tebello
- Authors: Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249059 , vital:51774 , xlink:href="https://doi.org/10.1007/s00604-010-0438-6"
- Description: Metal tetra-amino phthalocyanine complexes (MTAPc; where M is Co or Mn) were immobilized on screen-printed gold electrodes pre-modified with monolayers of benzylamino groups. The functionalized electrodes were then activated using benzene-1,4-dicarbaldehyde as a linker before MTAPc complexes were immobilized. The surface coverages for the modified electrodes confirmed the perpendicular orientation of the MTAPcs. The apparent electron transfer constant (kapp) for the electrodes is 2.2 × 10−5 cm.s−1 for both CoTAPc and MnTAPc modified electrodes as calculated with data from impedance measurements. The kapp values for the bare and benzylamino modified electrodes were found to be 1.2 × 10−4 cm.s−1 and 4.9 × 10−6 cm.s−1, respectively. The electrocatalysis of the modified electrodes towards detection of H2O2 gave significant peak current densities and electrocatalytic potentials at −0.28 V and −0.31 V for the MnTAPc and CoTAPc modified electrodes, respectively.
- Full Text:
- Date Issued: 2015
- Authors: Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249059 , vital:51774 , xlink:href="https://doi.org/10.1007/s00604-010-0438-6"
- Description: Metal tetra-amino phthalocyanine complexes (MTAPc; where M is Co or Mn) were immobilized on screen-printed gold electrodes pre-modified with monolayers of benzylamino groups. The functionalized electrodes were then activated using benzene-1,4-dicarbaldehyde as a linker before MTAPc complexes were immobilized. The surface coverages for the modified electrodes confirmed the perpendicular orientation of the MTAPcs. The apparent electron transfer constant (kapp) for the electrodes is 2.2 × 10−5 cm.s−1 for both CoTAPc and MnTAPc modified electrodes as calculated with data from impedance measurements. The kapp values for the bare and benzylamino modified electrodes were found to be 1.2 × 10−4 cm.s−1 and 4.9 × 10−6 cm.s−1, respectively. The electrocatalysis of the modified electrodes towards detection of H2O2 gave significant peak current densities and electrocatalytic potentials at −0.28 V and −0.31 V for the MnTAPc and CoTAPc modified electrodes, respectively.
- Full Text:
- Date Issued: 2015
Becoming African: debating post-apartheid white South African identities
- Authors: Matthews, Sally
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142409 , vital:38077 , DOI: 10.1080/14725843.2011.530440
- Description: The post-apartheid era necessitates the rethinking of white identities in South Africa. One way in which some white South Africans are seeking to redefine themselves is through describing themselves as African. However, claims by white South Africans that they too are Africans have been met with mixed responses from black South Africans. In this article I use contributions to an online university students' forum to explore ways in which some white South Africans are embracing an African identity and to consider ways in which some black South Africans are responding to white South Africans' shifting identities. I use contributions to this forum as a starting point to think about the possibilities and limitations that the embracing of an African identity has for the development of what Frankenberg calls ‘anti-racist forms of whiteness’ among white South Africans.
- Full Text:
- Date Issued: 2011
- Authors: Matthews, Sally
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142409 , vital:38077 , DOI: 10.1080/14725843.2011.530440
- Description: The post-apartheid era necessitates the rethinking of white identities in South Africa. One way in which some white South Africans are seeking to redefine themselves is through describing themselves as African. However, claims by white South Africans that they too are Africans have been met with mixed responses from black South Africans. In this article I use contributions to an online university students' forum to explore ways in which some white South Africans are embracing an African identity and to consider ways in which some black South Africans are responding to white South Africans' shifting identities. I use contributions to this forum as a starting point to think about the possibilities and limitations that the embracing of an African identity has for the development of what Frankenberg calls ‘anti-racist forms of whiteness’ among white South Africans.
- Full Text:
- Date Issued: 2011
Developing visual images for communicating information aboutantiretroviral side effects to a low-literate population:
- Dowse, Roslind, Ramela, Thato, Barford, Kirsty-Lee, Browne, Sara H
- Authors: Dowse, Roslind , Ramela, Thato , Barford, Kirsty-Lee , Browne, Sara H
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156769 , vital:40048 , https://doi.org/10.2989/16085906.2010.530172
- Description: The side effects of antiretroviral (ARV) therapy are linked to altered quality of life and adherence. Poor adherence has also been associated with low health-literacy skills, with an uninformed patient more likely to make ARV-related decisions that compromise the efficacy of the treatment. Low literacy skills disempower patients in interactions with healthcare providers and preclude the use of existing written patient information materials, which are generally written at a high reading level. Visual images or pictograms used as a counselling tool or included in patient information leaflets have been shown to improve patients’ knowledge, particularly in low-literate groups. The objective of this study was to design visuals or pictograms illustrating various ARV side effects and to evaluate them in a low-literate South African Xhosa population. Core images were generated either from a design workshop or from posed photos or images from textbooks. The research team worked closely with a graphic artist. Initial versions of the images were discussed and assessed in group discussions, and then modified and eventually evaluated quantitatively in individual interviews with 40 participants who each had a maximum of 10 years of schooling.
- Full Text:
- Date Issued: 2011
- Authors: Dowse, Roslind , Ramela, Thato , Barford, Kirsty-Lee , Browne, Sara H
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156769 , vital:40048 , https://doi.org/10.2989/16085906.2010.530172
- Description: The side effects of antiretroviral (ARV) therapy are linked to altered quality of life and adherence. Poor adherence has also been associated with low health-literacy skills, with an uninformed patient more likely to make ARV-related decisions that compromise the efficacy of the treatment. Low literacy skills disempower patients in interactions with healthcare providers and preclude the use of existing written patient information materials, which are generally written at a high reading level. Visual images or pictograms used as a counselling tool or included in patient information leaflets have been shown to improve patients’ knowledge, particularly in low-literate groups. The objective of this study was to design visuals or pictograms illustrating various ARV side effects and to evaluate them in a low-literate South African Xhosa population. Core images were generated either from a design workshop or from posed photos or images from textbooks. The research team worked closely with a graphic artist. Initial versions of the images were discussed and assessed in group discussions, and then modified and eventually evaluated quantitatively in individual interviews with 40 participants who each had a maximum of 10 years of schooling.
- Full Text:
- Date Issued: 2011
Effect of turbidity on the foraging success of Glossogobius callidus (Teleostei: Gobiidae)
- Parkinson, Matthew C, Booth, Anthony J
- Authors: Parkinson, Matthew C , Booth, Anthony J
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124375 , vital:35600 , https://doi.org/10.2989/16085914.2011.589120
- Description: Particles suspended in water attenuate the light that passes through it via absorption or scattering (Utne-Palm 2002). For example, whereas algae absorb specific wavelengths of light necessary for photosynthesis, inorganic suspensoids tend to scatter light (Radke and Gaupisch 2005). This results in lowered ambient light levels and reduces the visual acuity of aquatic organisms. From a fish’s perspective, an increase in water turbidity has the potential to alter visually-mediated reproductive behaviours (Järvenpää and Lindström 2004), predator avoidance (Meager et al. 2006) and foraging success negatively (Utne-Palm 2002, Rowe et al. 2003, Sweka and Hartman 2003, Stuart-Smith et al. 2004). The foraging success of various fish species was affected by increased turbidity through decreasing predator–prey encounter rates (Sweka and Hartman 2003) and through decreasing visual acuity whereby the distance at which prey are visually detected is reduced (Utne-Palm 2002).
- Full Text:
- Date Issued: 2011
- Authors: Parkinson, Matthew C , Booth, Anthony J
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124375 , vital:35600 , https://doi.org/10.2989/16085914.2011.589120
- Description: Particles suspended in water attenuate the light that passes through it via absorption or scattering (Utne-Palm 2002). For example, whereas algae absorb specific wavelengths of light necessary for photosynthesis, inorganic suspensoids tend to scatter light (Radke and Gaupisch 2005). This results in lowered ambient light levels and reduces the visual acuity of aquatic organisms. From a fish’s perspective, an increase in water turbidity has the potential to alter visually-mediated reproductive behaviours (Järvenpää and Lindström 2004), predator avoidance (Meager et al. 2006) and foraging success negatively (Utne-Palm 2002, Rowe et al. 2003, Sweka and Hartman 2003, Stuart-Smith et al. 2004). The foraging success of various fish species was affected by increased turbidity through decreasing predator–prey encounter rates (Sweka and Hartman 2003) and through decreasing visual acuity whereby the distance at which prey are visually detected is reduced (Utne-Palm 2002).
- Full Text:
- Date Issued: 2011
Know your rights! A basic guide for domestic workers in South Africa
- Labour Research Service (LRS)
- Authors: Labour Research Service (LRS)
- Date: 2010-06
- Subjects: Household employees -- Legal status, laws, etc. -- South Africa , Household employees -- Employment -- South Africa , Labour contract -- South Africa
- Language: English
- Type: book , text
- Identifier: http://hdl.handle.net/10962/60041 , vital:27725
- Description: The demand for domestic services has increased globally during the last two decades and today domestic workers constitute a large portion of the workforce, especially in developing countries. Yet domestic work is undervalued and poorly regulated, and many domestic workers are underpaid and unprotected. This has been recognised by international organisations, such as the International Labour Organisation (ILO). The struggle of domestic workers has lead to improvements to their rights and conditions in many countries. Yet working conditions and wages remain poor in many countries, including South Africa. This booklet sheds light on this problem. There are 888 000 domestic workers in South Africa, which accounts for 7% of total formal employment (Labour Force Survey, May 2010). The vast majority of these workers do not belong to a trade union and do not partake in collective bargaining or are unaware of their rights to bargain and to join trade unions. The South African Domestic Services and Allied Workers Union (SADSAWU) is a trade union for domestic workers in South Africa and campaigns for the improvement of rights and conditions of domestic workers. It recognises that it is not as powerful as it could be and it would have a bigger influence on the legislating authorities if there were more members which were strongly organised. There are numerous difficulties to organise domestic workers, some are related to the education level of the workers and some lies within the nature of the work (many are live-in workers and therefore have no contact with other domestic workers as a natural part of their work). However, SADSAWU has over many years built up a lot of experience and developed a solid vision to build a strong domestic workers movement, and is therefore well placed to fight these difficulties. This booklet also serves as an organising tool for domestic workers. The aim is to raise awareness of the rights of domestic workers and to encourage workers to organise.
- Full Text:
- Date Issued: 2010-06
- Authors: Labour Research Service (LRS)
- Date: 2010-06
- Subjects: Household employees -- Legal status, laws, etc. -- South Africa , Household employees -- Employment -- South Africa , Labour contract -- South Africa
- Language: English
- Type: book , text
- Identifier: http://hdl.handle.net/10962/60041 , vital:27725
- Description: The demand for domestic services has increased globally during the last two decades and today domestic workers constitute a large portion of the workforce, especially in developing countries. Yet domestic work is undervalued and poorly regulated, and many domestic workers are underpaid and unprotected. This has been recognised by international organisations, such as the International Labour Organisation (ILO). The struggle of domestic workers has lead to improvements to their rights and conditions in many countries. Yet working conditions and wages remain poor in many countries, including South Africa. This booklet sheds light on this problem. There are 888 000 domestic workers in South Africa, which accounts for 7% of total formal employment (Labour Force Survey, May 2010). The vast majority of these workers do not belong to a trade union and do not partake in collective bargaining or are unaware of their rights to bargain and to join trade unions. The South African Domestic Services and Allied Workers Union (SADSAWU) is a trade union for domestic workers in South Africa and campaigns for the improvement of rights and conditions of domestic workers. It recognises that it is not as powerful as it could be and it would have a bigger influence on the legislating authorities if there were more members which were strongly organised. There are numerous difficulties to organise domestic workers, some are related to the education level of the workers and some lies within the nature of the work (many are live-in workers and therefore have no contact with other domestic workers as a natural part of their work). However, SADSAWU has over many years built up a lot of experience and developed a solid vision to build a strong domestic workers movement, and is therefore well placed to fight these difficulties. This booklet also serves as an organising tool for domestic workers. The aim is to raise awareness of the rights of domestic workers and to encourage workers to organise.
- Full Text:
- Date Issued: 2010-06
"Fit for purpose": towards tracking the quality of university education of entry-level journalists
- Authors: Berger, Guy
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159835 , vital:40348 , DOI: 10.1080/02560054.2005.9653329
- Description: Debate about the extent to which university education should serve industry is an important consideration for institutions of higher learning in a transforming South Africa, and particularly for those teaching would-be journalists. This issue can also be profitably analysed with reference to the current framework of the South African education authorities who argue that the quality of higher education institutions should be measured in terms of their “fit for purpose” to missions aligned to stakeholder interests in the transformation of the country as a whole. This criterion for quality assessment tends to focus on the educative processes within a university, but it can be argued that it ought to extend into the examination of the output consequences of journalism teaching. This would amount to not just fitness for purpose, but also achievement of purpose – and the latter including a creative and critical impact.
- Full Text:
- Date Issued: 2010
- Authors: Berger, Guy
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159835 , vital:40348 , DOI: 10.1080/02560054.2005.9653329
- Description: Debate about the extent to which university education should serve industry is an important consideration for institutions of higher learning in a transforming South Africa, and particularly for those teaching would-be journalists. This issue can also be profitably analysed with reference to the current framework of the South African education authorities who argue that the quality of higher education institutions should be measured in terms of their “fit for purpose” to missions aligned to stakeholder interests in the transformation of the country as a whole. This criterion for quality assessment tends to focus on the educative processes within a university, but it can be argued that it ought to extend into the examination of the output consequences of journalism teaching. This would amount to not just fitness for purpose, but also achievement of purpose – and the latter including a creative and critical impact.
- Full Text:
- Date Issued: 2010
'I won't be squeezed into someone else's frame': Stories of supervisor selection
- Harrison, Liz, McKenna, Sioux, Searle, Ruth
- Authors: Harrison, Liz , McKenna, Sioux , Searle, Ruth
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187395 , vital:44629 , xlink:href="https://hdl.handle.net/10520/EJC15100"
- Description: Using a collection of stories from a group of women who belong to a PhD support group, this article tracks the issue of choosing a supervisor. These women are all academics and therefore had some claim to an "insider" status but as novice researchers they were also "outsiders". Their discussions around how and why they chose their supervisors highlight issues often underplayed or ignored in textbooks on postgraduate supervision. In particular, this article examines issues of knowledge, embodied subjectivity and power by following three questions that arise from the data : whose knowing is important; who should I be, and whose PhD is it?
- Full Text:
- Date Issued: 2010
- Authors: Harrison, Liz , McKenna, Sioux , Searle, Ruth
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187395 , vital:44629 , xlink:href="https://hdl.handle.net/10520/EJC15100"
- Description: Using a collection of stories from a group of women who belong to a PhD support group, this article tracks the issue of choosing a supervisor. These women are all academics and therefore had some claim to an "insider" status but as novice researchers they were also "outsiders". Their discussions around how and why they chose their supervisors highlight issues often underplayed or ignored in textbooks on postgraduate supervision. In particular, this article examines issues of knowledge, embodied subjectivity and power by following three questions that arise from the data : whose knowing is important; who should I be, and whose PhD is it?
- Full Text:
- Date Issued: 2010
'Rich man poor man': inter-household and community factors influencing the use of wild plant resources amongst rural households in South Africa
- Cocks, Michelle L, Bangay, Lindsey, Shackleton, Charlie M, Wiersum, K Freerk
- Authors: Cocks, Michelle L , Bangay, Lindsey , Shackleton, Charlie M , Wiersum, K Freerk
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141211 , vital:37953 , DOI: 10.3843/SusDev.15.3:3
- Description: Biodiversity is recognised as an integral part of people's daily livelihoods. This study therefore aims to understand the use of NTFPs at an intricate level by determining what role these resources fulfil in six rural villages and 1011 households' livelihoods. It examines how the use of NTFPs are influenced by intra-household variables, such as wealth and gender, and inter-community variables, such as accessibility to the natural resource. The results reveal that approximately 4453 kg of wild material is used annually per household, of which 1598 kg is used for cultural purposes. The influence of vegetation type and differences between villages are statistically more significant than inter-household variables. At an inter-household level, an increase in the financial status of households did not result in a decrease in the use of natural resources, nor in the quantity of material used.
- Full Text:
- Date Issued: 2010
- Authors: Cocks, Michelle L , Bangay, Lindsey , Shackleton, Charlie M , Wiersum, K Freerk
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141211 , vital:37953 , DOI: 10.3843/SusDev.15.3:3
- Description: Biodiversity is recognised as an integral part of people's daily livelihoods. This study therefore aims to understand the use of NTFPs at an intricate level by determining what role these resources fulfil in six rural villages and 1011 households' livelihoods. It examines how the use of NTFPs are influenced by intra-household variables, such as wealth and gender, and inter-community variables, such as accessibility to the natural resource. The results reveal that approximately 4453 kg of wild material is used annually per household, of which 1598 kg is used for cultural purposes. The influence of vegetation type and differences between villages are statistically more significant than inter-household variables. At an inter-household level, an increase in the financial status of households did not result in a decrease in the use of natural resources, nor in the quantity of material used.
- Full Text:
- Date Issued: 2010
25 years of training doctors at WSU: how have we responded to the 1983 UNITRA Council Guidelines?
- Authors: Kwizera, E N
- Date: 2010
- Subjects: Medical education -- South Africa -- Eastern Cape Clinical medical -- Teaching and learning
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/801 , vital:29826
- Description: More importantly, Mr VC, Sir, some relatively more recent improvisations have been in the roles I have played in the development, implementation, and evaluation of the Problem-based, and Community-based MB ChB curriculum at the then UNITRA (and now WSU) from 1989 to date4-33; particularly my successful introduction of ‘one tutor per tutorial group’ in our programme8,10,12,14. As I will elaborate in due course, one of the secrets of our success as a medical school has been the adaptation of ideas and practices from diverse parts of the world to make them fit in our settings; and needless to say, this has involved a lot of improvisation.
- Full Text:
- Date Issued: 2010
- Authors: Kwizera, E N
- Date: 2010
- Subjects: Medical education -- South Africa -- Eastern Cape Clinical medical -- Teaching and learning
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/801 , vital:29826
- Description: More importantly, Mr VC, Sir, some relatively more recent improvisations have been in the roles I have played in the development, implementation, and evaluation of the Problem-based, and Community-based MB ChB curriculum at the then UNITRA (and now WSU) from 1989 to date4-33; particularly my successful introduction of ‘one tutor per tutorial group’ in our programme8,10,12,14. As I will elaborate in due course, one of the secrets of our success as a medical school has been the adaptation of ideas and practices from diverse parts of the world to make them fit in our settings; and needless to say, this has involved a lot of improvisation.
- Full Text:
- Date Issued: 2010
31P NMR kinetic study of the tandem cleavage of phosphonate esters by bromotrimethylsilane
- Conibear, Anne C, Lobb, Kevin A, Kaye, Perry T
- Authors: Conibear, Anne C , Lobb, Kevin A , Kaye, Perry T
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449304 , vital:74810 , xlink:href="https://doi.org/10.1016/j.tet.2010.08.058"
- Description: 1H and 31P NMR methods have been used to access rate constants and activation parameters for each of the consecutive second-order silylation reactions involved in the overall transformation (1a→3a→4a), while computational optimisation of the rate constants obtained from the initial, linear phase of each reaction has permitted an excellent fit with the experimental data for the entire course of the reaction.
- Full Text:
- Date Issued: 2010
- Authors: Conibear, Anne C , Lobb, Kevin A , Kaye, Perry T
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449304 , vital:74810 , xlink:href="https://doi.org/10.1016/j.tet.2010.08.058"
- Description: 1H and 31P NMR methods have been used to access rate constants and activation parameters for each of the consecutive second-order silylation reactions involved in the overall transformation (1a→3a→4a), while computational optimisation of the rate constants obtained from the initial, linear phase of each reaction has permitted an excellent fit with the experimental data for the entire course of the reaction.
- Full Text:
- Date Issued: 2010
A conceptually relevant and practically sophisticated journalism syllabus for Africa
- Authors: Banda, Fackson
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454547 , vital:75354 , https://hdl.handle.net/10520/EJC139370
- Description: Over 35 African journalism educators gathered in Grahamstown, South Africa in September last year, at the invitation of the SAB Ltd-Unesco Chair of Media and Democracy, to present and discuss initial research papers aimed at defining a common vision of journalism education on the African continent. The meeting was held against the backdrop of the bid by Rhodes University, under the auspices of the School of Journalism and Media Studies, to host the 2nd World Journalism Education Congress (WJEC).
- Full Text:
- Date Issued: 2010
- Authors: Banda, Fackson
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/454547 , vital:75354 , https://hdl.handle.net/10520/EJC139370
- Description: Over 35 African journalism educators gathered in Grahamstown, South Africa in September last year, at the invitation of the SAB Ltd-Unesco Chair of Media and Democracy, to present and discuss initial research papers aimed at defining a common vision of journalism education on the African continent. The meeting was held against the backdrop of the bid by Rhodes University, under the auspices of the School of Journalism and Media Studies, to host the 2nd World Journalism Education Congress (WJEC).
- Full Text:
- Date Issued: 2010
A framework for recuperation: HIV/AIDS and the Keiskamma Altarpiece
- Authors: Schmahmann, Brenda
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147593 , vital:38652 , https://doi.org/10.1162/afar.2010.43.3.34
- Description: South Africa has the largest number of people living with HIV of any nation in the world. While various conditions and circumstances have made South Africa especially susceptible to an HIV/AIDS pandemic, its leadership has not recognized the impact of the disease or found appropriate strategies to address rising rates of infection. Thabo Mbeki's presidency (1999—2008) and the appointment of Manto Tshabalala-Msimang as his health minister were disastrous in terms of the pandemic.
- Full Text:
- Date Issued: 2010
- Authors: Schmahmann, Brenda
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147593 , vital:38652 , https://doi.org/10.1162/afar.2010.43.3.34
- Description: South Africa has the largest number of people living with HIV of any nation in the world. While various conditions and circumstances have made South Africa especially susceptible to an HIV/AIDS pandemic, its leadership has not recognized the impact of the disease or found appropriate strategies to address rising rates of infection. Thabo Mbeki's presidency (1999—2008) and the appointment of Manto Tshabalala-Msimang as his health minister were disastrous in terms of the pandemic.
- Full Text:
- Date Issued: 2010
A Game Theoretic Framework for Cooperative Benefits in South Africa’s land redistribution process: a case of Northern Kwa-Zulu Natal Sugarcane Farmland Transfers (No. 308-2016-5118)
- Mbatha, Cyril N, Antrobus, Geoffrey G
- Authors: Mbatha, Cyril N , Antrobus, Geoffrey G
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142958 , vital:38180 , https://ageconsearch.umn.edu/record/96156/
- Description: A good indicator of successful farm redistribution cases has to be the continuation of viable productivity rates in their post transfer periods. Continued productivity benefits all the stakeholders that are involved in the process. Unfortunately negative productivity levels have been reported in numerous South African land redistribution transfers in recent years. A game theoretic perspective is adopted to argue that cooperation among key stakeholders, which could be enforced through long term contracts between a land buyer, sellers and new owners, would lead to higher productivity levels and other benefits. Additional benefits would, for example, include market related prices paid by a buyer.
- Full Text:
- Date Issued: 2010
- Authors: Mbatha, Cyril N , Antrobus, Geoffrey G
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142958 , vital:38180 , https://ageconsearch.umn.edu/record/96156/
- Description: A good indicator of successful farm redistribution cases has to be the continuation of viable productivity rates in their post transfer periods. Continued productivity benefits all the stakeholders that are involved in the process. Unfortunately negative productivity levels have been reported in numerous South African land redistribution transfers in recent years. A game theoretic perspective is adopted to argue that cooperation among key stakeholders, which could be enforced through long term contracts between a land buyer, sellers and new owners, would lead to higher productivity levels and other benefits. Additional benefits would, for example, include market related prices paid by a buyer.
- Full Text:
- Date Issued: 2010
A histological description of ovarian recrudescence in two Labeo victorianus populations
- Booth, Anthony J, Hecht, Thomas
- Authors: Booth, Anthony J , Hecht, Thomas
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123564 , vital:35455 , https://doi.org/10.2989/16085910409503813
- Description: The ovaries of Labeo victorianus are paired organs situated in the peritoneal cavity and suspended on either side of the midline by a mesovarium. A capsule, composed of dense, regularly-arranged collagen and elastic fibres mixed with a few smooth muscle cells, enclosed the ovaries and gave off connective tissue septa, forming the ovigerous lamellae, which contained germ and follicle cells. Eight discrete stages of recrudescence were identified: oogonia, chromatin nucleolar oocytes, perinucleolar oocytes, primary yolk vesicle oocytes, secondary yolk vesicle oocytes, tertiary yolk vesicle oocytes, post-ovulatory follicles and atretic oocytes. Ovulation seemed to be synchronised with the onset of rainfall, with some deviations in the Sio River population. Gonadosomatic index variation followed a bimodal pattern, with maxima between January–February and between September–October for both populations. The same pattern was exhibited for both rainfall and water levels at the two study sites. Successful ovulation was followed by the formation of post-ovulatory follicles and Type I atresia, while failed spawning was characterised by Type II atresia. Clearance of post-ovulatory follicles was by phagocytosis and formation of melanomacrophage centres. There were variations in post-ovulatory changes between the two populations. Reproductive patterns in the Kagera River population conformed to the ‘norm’ in African labeines of the synchronisation of spawning with rainfall. Slight deviations from this pattern were, however, observed in the Sio River population where spawning occurred prior to the onset of rainfall.
- Full Text:
- Date Issued: 2010
- Authors: Booth, Anthony J , Hecht, Thomas
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123564 , vital:35455 , https://doi.org/10.2989/16085910409503813
- Description: The ovaries of Labeo victorianus are paired organs situated in the peritoneal cavity and suspended on either side of the midline by a mesovarium. A capsule, composed of dense, regularly-arranged collagen and elastic fibres mixed with a few smooth muscle cells, enclosed the ovaries and gave off connective tissue septa, forming the ovigerous lamellae, which contained germ and follicle cells. Eight discrete stages of recrudescence were identified: oogonia, chromatin nucleolar oocytes, perinucleolar oocytes, primary yolk vesicle oocytes, secondary yolk vesicle oocytes, tertiary yolk vesicle oocytes, post-ovulatory follicles and atretic oocytes. Ovulation seemed to be synchronised with the onset of rainfall, with some deviations in the Sio River population. Gonadosomatic index variation followed a bimodal pattern, with maxima between January–February and between September–October for both populations. The same pattern was exhibited for both rainfall and water levels at the two study sites. Successful ovulation was followed by the formation of post-ovulatory follicles and Type I atresia, while failed spawning was characterised by Type II atresia. Clearance of post-ovulatory follicles was by phagocytosis and formation of melanomacrophage centres. There were variations in post-ovulatory changes between the two populations. Reproductive patterns in the Kagera River population conformed to the ‘norm’ in African labeines of the synchronisation of spawning with rainfall. Slight deviations from this pattern were, however, observed in the Sio River population where spawning occurred prior to the onset of rainfall.
- Full Text:
- Date Issued: 2010
A Landscape of Insects and Other Invertebrates, D.N. MacFadyen: book review
- Authors: Villet, Martin H
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451583 , vital:75061 , https://hdl.handle.net/10520/EJC32856
- Description: Despite their generally small sizes, southern African insects consistently attract public attention. Rarely is it positive attention, but when it is, it is often from notable champions. Let me explain.
- Full Text:
- Date Issued: 2010
- Authors: Villet, Martin H
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/451583 , vital:75061 , https://hdl.handle.net/10520/EJC32856
- Description: Despite their generally small sizes, southern African insects consistently attract public attention. Rarely is it positive attention, but when it is, it is often from notable champions. Let me explain.
- Full Text:
- Date Issued: 2010
A Proxy Approach for Interoperability and Common Control of Networked Digital Audio Devices
- Igumbor, Osedum P, Foss, Richard
- Authors: Igumbor, Osedum P , Foss, Richard
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427099 , vital:72414 , https://www.aes.org/e-lib/browse.cfm?elib=15338
- Description: This paper highlights the challenge that results from the availability of a large number of control protocols within the context of digital audio networks. Devices that conform to different protocols are unable to communicate with one another, even though they might be utilizing the same networking technology (Ethernet, IEEE 1394 serial bus, USB). This paper describes the use of a proxy that allows for high-level device interaction (by sending protocol messages) between networked devices. Furthermore, the proxy allows for a common controller to control the disparate networked devices.
- Full Text:
- Date Issued: 2010
- Authors: Igumbor, Osedum P , Foss, Richard
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427099 , vital:72414 , https://www.aes.org/e-lib/browse.cfm?elib=15338
- Description: This paper highlights the challenge that results from the availability of a large number of control protocols within the context of digital audio networks. Devices that conform to different protocols are unable to communicate with one another, even though they might be utilizing the same networking technology (Ethernet, IEEE 1394 serial bus, USB). This paper describes the use of a proxy that allows for high-level device interaction (by sending protocol messages) between networked devices. Furthermore, the proxy allows for a common controller to control the disparate networked devices.
- Full Text:
- Date Issued: 2010
A South African response to ethics in legal education
- Authors: Kruuse, Helen
- Date: 2010
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54201 , vital:26403 , https://www.lehmanns.de/shop/recht-steuern/17056480-9780195985818-the-law-of-persons-in-south-africa?PHPSESSID=ogicv1k4dkbpi03lq53elurqh2
- Description: This book reflects the legislative change and consequent changes in common law that fundamentally affect the law of persons, in particular the Children's Act of 2007 and the application of the constitution.
- Full Text: false
- Date Issued: 2010
- Authors: Kruuse, Helen
- Date: 2010
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54201 , vital:26403 , https://www.lehmanns.de/shop/recht-steuern/17056480-9780195985818-the-law-of-persons-in-south-africa?PHPSESSID=ogicv1k4dkbpi03lq53elurqh2
- Description: This book reflects the legislative change and consequent changes in common law that fundamentally affect the law of persons, in particular the Children's Act of 2007 and the application of the constitution.
- Full Text: false
- Date Issued: 2010
A tale of 2 investigations:
- Authors: Amner, Roderick J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159438 , vital:40297 , https://hdl.handle.net/10520/EJC139354
- Description: This is a tale of two in-depth stories, both produced by one Daily Dispatch journalist, Gcina Nstaluba, in 2009. One was wildly successful - it helped change the face of the government's housing policy and won Ntsaluba SA Story of the Year at the 2010 Mondi Shanduka Newspaper Awards. The other was deemed a dismal failure by Ntsaluba himself. Why? And what can these stories teach us and our students about doing journalism in South Africa?
- Full Text:
- Date Issued: 2010
- Authors: Amner, Roderick J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159438 , vital:40297 , https://hdl.handle.net/10520/EJC139354
- Description: This is a tale of two in-depth stories, both produced by one Daily Dispatch journalist, Gcina Nstaluba, in 2009. One was wildly successful - it helped change the face of the government's housing policy and won Ntsaluba SA Story of the Year at the 2010 Mondi Shanduka Newspaper Awards. The other was deemed a dismal failure by Ntsaluba himself. Why? And what can these stories teach us and our students about doing journalism in South Africa?
- Full Text:
- Date Issued: 2010
A watershed study on genetic diversity phylogenetic analysis of the Platypleura plumosa (Hemiptera Cicadidae) complex reveals catchment-specific lineages
- Price, Benjamin W, Barker, Nigel P, Villet, Martin H
- Authors: Price, Benjamin W , Barker, Nigel P , Villet, Martin H
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/441711 , vital:73909 , https://doi.org/10.1016/j.ympev.2009.10.011
- Description: Historical biogeography studies have at their disposal a small suite of vicariance models to explain genetic differentiation within and between species. One of these processes involves the role of river catchments and their associated watersheds, in driving diversification and is applicable to both aquatic and terrestrial organisms. Although the idea of catchments structuring the genetic history of aquatic organisms is reasonably well understood, their effect on terrestrial organisms has largely been overlooked, with relevant studies being limited in scope. South Africa presents a perfect test-bed for elucidating this mechanism of diversification due to its rich biodiversity, range of climatic environments and many large river catchments. Here we use the cicadas of the Platypleura plumosa complex to highlight the importance of catchments and their associated watersheds in driving diversification of terrestrial invertebrates that lack an aquatic life-stage. Population structure was found to correspond to primary and in some cases secondary catchments; highlighting the need to include information on catchment structure when formulating hypotheses of population diversification. Recognizing that climate change in the near future is likely to alter the environment, and particularly precipitation patterns, insight into recent patterns of population change related to catchments may be useful in a conservation context.
- Full Text:
- Date Issued: 2010
- Authors: Price, Benjamin W , Barker, Nigel P , Villet, Martin H
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/441711 , vital:73909 , https://doi.org/10.1016/j.ympev.2009.10.011
- Description: Historical biogeography studies have at their disposal a small suite of vicariance models to explain genetic differentiation within and between species. One of these processes involves the role of river catchments and their associated watersheds, in driving diversification and is applicable to both aquatic and terrestrial organisms. Although the idea of catchments structuring the genetic history of aquatic organisms is reasonably well understood, their effect on terrestrial organisms has largely been overlooked, with relevant studies being limited in scope. South Africa presents a perfect test-bed for elucidating this mechanism of diversification due to its rich biodiversity, range of climatic environments and many large river catchments. Here we use the cicadas of the Platypleura plumosa complex to highlight the importance of catchments and their associated watersheds in driving diversification of terrestrial invertebrates that lack an aquatic life-stage. Population structure was found to correspond to primary and in some cases secondary catchments; highlighting the need to include information on catchment structure when formulating hypotheses of population diversification. Recognizing that climate change in the near future is likely to alter the environment, and particularly precipitation patterns, insight into recent patterns of population change related to catchments may be useful in a conservation context.
- Full Text:
- Date Issued: 2010
Adoption of IT Systems by HR professionals in order to enhance efficacy at the University of Fort Hare
- Authors: Ngqubekile, Nolufefe
- Date: 2010
- Subjects: Management information systems , Personnel management , Public administration
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27176 , vital:66326
- Description: This study seeks to address the adoption of Integrated Tertiary Software (ITS), ease of use of ITS and continuous usage in Human Resources Departments. The focus of this research project is User Acceptance and Continued Use of ITS within the HR Department - the case of Fort Hare University. The University is a multi - campus operation and the use of paper systems is extremely difficult. The University made a decision to invest in ITS with the objective of improving effectiveness and efficiency of services. The nature of the problem is that ITS is partially used and it is necessary to further explore the specific influence of technological and environmental factors that may change the user’s acceptance and use of this IT System. The nature of this study is Qualitative and follows an Interpretive Approach. The Research Instrument used is an in-depth questionnaire distributed and responded to by all HR Professionals at the UFH. Recommendations based on findings will be used to design the Critical Success Factors (CSFs) for the Adoption of IT Systems by HR Professionals in order to enhance efficacy at the University of Fort Hare. The CSFs can be generalized to other settings and were identified for the UFH HR Department to include. , Thesis (MCom) -- Faculty of Management and Commerce , 2010
- Full Text:
- Date Issued: 2010
- Authors: Ngqubekile, Nolufefe
- Date: 2010
- Subjects: Management information systems , Personnel management , Public administration
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27176 , vital:66326
- Description: This study seeks to address the adoption of Integrated Tertiary Software (ITS), ease of use of ITS and continuous usage in Human Resources Departments. The focus of this research project is User Acceptance and Continued Use of ITS within the HR Department - the case of Fort Hare University. The University is a multi - campus operation and the use of paper systems is extremely difficult. The University made a decision to invest in ITS with the objective of improving effectiveness and efficiency of services. The nature of the problem is that ITS is partially used and it is necessary to further explore the specific influence of technological and environmental factors that may change the user’s acceptance and use of this IT System. The nature of this study is Qualitative and follows an Interpretive Approach. The Research Instrument used is an in-depth questionnaire distributed and responded to by all HR Professionals at the UFH. Recommendations based on findings will be used to design the Critical Success Factors (CSFs) for the Adoption of IT Systems by HR Professionals in order to enhance efficacy at the University of Fort Hare. The CSFs can be generalized to other settings and were identified for the UFH HR Department to include. , Thesis (MCom) -- Faculty of Management and Commerce , 2010
- Full Text:
- Date Issued: 2010