Changes in forest cover and carbon stocks of the coastal scarp forests of the Wild Coast, South Africa
- Mangwale, Kagiso, Shackleton, Charlie M, Sigwela, Ayanda
- Authors: Mangwale, Kagiso , Shackleton, Charlie M , Sigwela, Ayanda
- Date: 2017
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/60903 , vital:27887 , https://doi.org/10.2989/20702620.2016.1255480
- Description: Land-use intensification and declines in vegetative cover are considered pervasive threats to forests and biodiversity globally. The small extent and high biodiversity of indigenous forests in South Africa make them particularly important. Yet, relatively little is known about their rates of use and change. From analysis of past aerial photos we quantified rates of forest cover change in the Matiwane forests of the Wild Coast, South Africa, between 1942 and 2007, as well as quantified above- and belowground (to 0.5 m depth) carbon stocks based on a composite allometric equation derived for the area. Rates of forest conversion were spatially variable, with some areas showing no change and others more noticeable changes. Overall, the net reduction was 5.2% (0.08% p.a.) over the 65-year period. However, the rate of reduction has accelerated with time. Some of the reduction was balanced by natural reforestation into formerly cleared areas, but basal area, biomass and carbon stocks are still low in the reforested areas. The total carbon stock was highest in intact forests (311.7 ± 23.7 Mg C ha−1), followed by degraded forests (73.5 ± 12.3 Mg C ha−1) and least in regrowth forests (51.2 ± 6.2 Mg C ha−1). The greatest contribution to total carbon stocks was soil carbon, contributing 54% in intact forests, and 78% and 68% in degraded and regrowth forests, respectively. The Matiwane forests store 4.78 Tg C, with 4.7 Tg C in intact forests, 0.06 Tg C in degraded forests and 0.02 Tg C in regrowth forests. The decrease in carbon stocks within the forests as a result of the conversion of the forest area to agricultural fields was 0.19 Tg C and approximately 0.0003 Tg C was released through harvesting of firewood and building timber.
- Full Text:
- Date Issued: 2017
- Authors: Mangwale, Kagiso , Shackleton, Charlie M , Sigwela, Ayanda
- Date: 2017
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/60903 , vital:27887 , https://doi.org/10.2989/20702620.2016.1255480
- Description: Land-use intensification and declines in vegetative cover are considered pervasive threats to forests and biodiversity globally. The small extent and high biodiversity of indigenous forests in South Africa make them particularly important. Yet, relatively little is known about their rates of use and change. From analysis of past aerial photos we quantified rates of forest cover change in the Matiwane forests of the Wild Coast, South Africa, between 1942 and 2007, as well as quantified above- and belowground (to 0.5 m depth) carbon stocks based on a composite allometric equation derived for the area. Rates of forest conversion were spatially variable, with some areas showing no change and others more noticeable changes. Overall, the net reduction was 5.2% (0.08% p.a.) over the 65-year period. However, the rate of reduction has accelerated with time. Some of the reduction was balanced by natural reforestation into formerly cleared areas, but basal area, biomass and carbon stocks are still low in the reforested areas. The total carbon stock was highest in intact forests (311.7 ± 23.7 Mg C ha−1), followed by degraded forests (73.5 ± 12.3 Mg C ha−1) and least in regrowth forests (51.2 ± 6.2 Mg C ha−1). The greatest contribution to total carbon stocks was soil carbon, contributing 54% in intact forests, and 78% and 68% in degraded and regrowth forests, respectively. The Matiwane forests store 4.78 Tg C, with 4.7 Tg C in intact forests, 0.06 Tg C in degraded forests and 0.02 Tg C in regrowth forests. The decrease in carbon stocks within the forests as a result of the conversion of the forest area to agricultural fields was 0.19 Tg C and approximately 0.0003 Tg C was released through harvesting of firewood and building timber.
- Full Text:
- Date Issued: 2017
Characterization and physicochemical studies of the conjugates of graphene quantum dots with differently charged zinc phthalocyanines
- Matshitse, Refilwe, Sekhosana, Kutloana E, Achadu, Ojodomo John, Nyokong, Tebello
- Authors: Matshitse, Refilwe , Sekhosana, Kutloana E , Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189227 , vital:44829 , xlink:href="https://doi.org/10.1080/00958972.2017.1387652"
- Description: Unsubstituted zinc phthalocyanine (ZnPc), 2,9,16,23-tetrakis[4-(N-methylpyridyloxy)]-phthalocyanine (ZnTPPcQ) and Zn tetrasulfo phthalocyanine (ZnTSPc) were non-covalently (electrostatic and/or π–π interaction) attached to graphene quantum dots (GQDs) to form GQDs-Pc nanoconjugates. Relative to Pcs alone, the presence of GQDs improved the triplet quantum yields with the following values: GQDs-ZnPc (0.73), GQDs-ZnTPPcQ (0.76) and GQDs-ZnTSPc (0.67). Respective Förster resonance energy transfer (FRET) efficiencies were calculated to be 0.81, 0.80 and 0.28. However, singlet oxygen generating abilities of the as-synthesized nanoconjugates were relatively low due to the screening effect of GQDs and quenching in water. This study shows that, the type of Pc, loading and solvent used are among the vital properties to consider when constructing GQD-nanoconjugate systems with optimal triplet quantum yield properties and investigation of their physicochemical properties.
- Full Text:
- Date Issued: 2017
- Authors: Matshitse, Refilwe , Sekhosana, Kutloana E , Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189227 , vital:44829 , xlink:href="https://doi.org/10.1080/00958972.2017.1387652"
- Description: Unsubstituted zinc phthalocyanine (ZnPc), 2,9,16,23-tetrakis[4-(N-methylpyridyloxy)]-phthalocyanine (ZnTPPcQ) and Zn tetrasulfo phthalocyanine (ZnTSPc) were non-covalently (electrostatic and/or π–π interaction) attached to graphene quantum dots (GQDs) to form GQDs-Pc nanoconjugates. Relative to Pcs alone, the presence of GQDs improved the triplet quantum yields with the following values: GQDs-ZnPc (0.73), GQDs-ZnTPPcQ (0.76) and GQDs-ZnTSPc (0.67). Respective Förster resonance energy transfer (FRET) efficiencies were calculated to be 0.81, 0.80 and 0.28. However, singlet oxygen generating abilities of the as-synthesized nanoconjugates were relatively low due to the screening effect of GQDs and quenching in water. This study shows that, the type of Pc, loading and solvent used are among the vital properties to consider when constructing GQD-nanoconjugate systems with optimal triplet quantum yield properties and investigation of their physicochemical properties.
- Full Text:
- Date Issued: 2017
Characterization of conjugates of NaYF4
- Watkins, Zane, Uddin, Imran, Britton, Jonathan, Nyokong, Tebello
- Authors: Watkins, Zane , Uddin, Imran , Britton, Jonathan , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/238132 , vital:50589 , xlink:href="https://doi.org/10.1016/j.molstruc.2016.10.011"
- Description: NaYF4:Er/Yb/Gd upconversion nanoparticles (UCNP) capped with amino groups were covalently attached to chloro aluminium tetrasulphonated phthalocyanine (ClAlTSPc) and chloro aluminium tetracarboxy phthalocyanine (ClAlTCPc). The conjugates were characterized using different techniques such as infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). There was a decrease in the intensity of fluorescence emission spectra of the UCNPs at 658 nm in the presence of the phthalocyanines. This decrease indicates an energy transfer between the donor UCNP and conjugated accepting phthalocyanine (Pc), due to Förster resonance energy transfer (FRET). FRET efficiencies of 18% and 21% for ClAlTSPc and ClAlTCPc, respectively, were obtained. Oxygen generation by ClAlTSPc following FRET was proved.
- Full Text:
- Date Issued: 2017
- Authors: Watkins, Zane , Uddin, Imran , Britton, Jonathan , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/238132 , vital:50589 , xlink:href="https://doi.org/10.1016/j.molstruc.2016.10.011"
- Description: NaYF4:Er/Yb/Gd upconversion nanoparticles (UCNP) capped with amino groups were covalently attached to chloro aluminium tetrasulphonated phthalocyanine (ClAlTSPc) and chloro aluminium tetracarboxy phthalocyanine (ClAlTCPc). The conjugates were characterized using different techniques such as infrared spectroscopy (IR), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). There was a decrease in the intensity of fluorescence emission spectra of the UCNPs at 658 nm in the presence of the phthalocyanines. This decrease indicates an energy transfer between the donor UCNP and conjugated accepting phthalocyanine (Pc), due to Förster resonance energy transfer (FRET). FRET efficiencies of 18% and 21% for ClAlTSPc and ClAlTCPc, respectively, were obtained. Oxygen generation by ClAlTSPc following FRET was proved.
- Full Text:
- Date Issued: 2017
Characterization of phthalocyanine functionalized quantum dots by dynamic light scattering, laser Doppler, and capillary electrophoresis
- Ramírez-García, Gonzalo, Oluwole, David O, Nxele, Siphesihle Robin, d’Orlyé, Fanny, Nyokong, Tebello, Bedioui, Fethi, Varenne, Anne
- Authors: Ramírez-García, Gonzalo , Oluwole, David O , Nxele, Siphesihle Robin , d’Orlyé, Fanny , Nyokong, Tebello , Bedioui, Fethi , Varenne, Anne
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/238184 , vital:50595 , xlink:href="https://doi.org/10.1007/s00216-016-0120-x"
- Description: In this work, we characterized different phtalocyanine-capped core/shell/shell quantum dots (QDs) in terms of stability, ζ-potential, and size at various pH and ionic strengths, by means of capillary electrophoresis (CE), and compared these results to the ones obtained by laser Doppler electrophoresis (LDE) and dynamic light scattering (DLS). The effect of the phthalocyanine metallic center (Zn, Al, or In), the number (one or four), and nature of substituents (carboxyphenoxy- or sulfonated-) of functionalization on the phthalocyanine physicochemical properties were evaluated. Whereas QDs capped with zinc mono-carboxyphenoxy-phtalocyanine (ZnMCPPc-QDs) remained aggregated in the whole analyzed pH range, even at low ionic strength, QDs capped with zinc tetracarboxyphenoxy phtalocyanine (ZnTPPc-QDs) were easily dispersed in buffers at pH equal to or higher than 7.4. QDs capped with aluminum tetrasulfonated phthalocyanine (AlTSPPc-QDs) and indium tetracarboxyphenoxy phthalocyanines (InTCPPc-QDs) were stable in aqueous suspension only at pH higher than 9.0 due to the presence of functional groups bound to the metallic center of the phthalocyanine. The ζ-potential values determined by CE for all the samples decreased when ionic strength increased, being well correlated with the aggregation of the nanoconjugates at elevated salt concentrations. The use of electrokinetic methodologies has provided insights into the colloidal stability of the photosensitizer-functionalized QDs in physiological relevant solutions and thereby, its usefulness for improving their design and applications for photodynamic therapy.
- Full Text:
- Date Issued: 2017
- Authors: Ramírez-García, Gonzalo , Oluwole, David O , Nxele, Siphesihle Robin , d’Orlyé, Fanny , Nyokong, Tebello , Bedioui, Fethi , Varenne, Anne
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/238184 , vital:50595 , xlink:href="https://doi.org/10.1007/s00216-016-0120-x"
- Description: In this work, we characterized different phtalocyanine-capped core/shell/shell quantum dots (QDs) in terms of stability, ζ-potential, and size at various pH and ionic strengths, by means of capillary electrophoresis (CE), and compared these results to the ones obtained by laser Doppler electrophoresis (LDE) and dynamic light scattering (DLS). The effect of the phthalocyanine metallic center (Zn, Al, or In), the number (one or four), and nature of substituents (carboxyphenoxy- or sulfonated-) of functionalization on the phthalocyanine physicochemical properties were evaluated. Whereas QDs capped with zinc mono-carboxyphenoxy-phtalocyanine (ZnMCPPc-QDs) remained aggregated in the whole analyzed pH range, even at low ionic strength, QDs capped with zinc tetracarboxyphenoxy phtalocyanine (ZnTPPc-QDs) were easily dispersed in buffers at pH equal to or higher than 7.4. QDs capped with aluminum tetrasulfonated phthalocyanine (AlTSPPc-QDs) and indium tetracarboxyphenoxy phthalocyanines (InTCPPc-QDs) were stable in aqueous suspension only at pH higher than 9.0 due to the presence of functional groups bound to the metallic center of the phthalocyanine. The ζ-potential values determined by CE for all the samples decreased when ionic strength increased, being well correlated with the aggregation of the nanoconjugates at elevated salt concentrations. The use of electrokinetic methodologies has provided insights into the colloidal stability of the photosensitizer-functionalized QDs in physiological relevant solutions and thereby, its usefulness for improving their design and applications for photodynamic therapy.
- Full Text:
- Date Issued: 2017
Children and wild foods in the context of deforestation in rural Malawi
- Maseko, Heather N, Shackleton, Charlie M, Nagoli, J, Pullanikkatil, Deepa
- Authors: Maseko, Heather N , Shackleton, Charlie M , Nagoli, J , Pullanikkatil, Deepa
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182101 , vital:43800 , xlink:href="https://doi.org/10.1007/s10745-017-9956-8"
- Description: There is growing recognition of the contribution of wild foods to local diets, nutrition, and culture. Yet disaggregation of understanding of wild food use by gender and age is limited. We used a mixed methods approach to determine the types, frequencies, and perceptions of wild foods used and sold by children in four villages in southern Malawi that have different levels of deforestation. Household and individual dietary diversity scores are low at all sites. All households consume one or more wild foods. Across the four sites, children listed 119 wild foods, with a wider variety at the least deforested sites than the most deforested ones. Older children can name more wild foods than younger ones. More children from poor households sell wild foods than from well-off households. Several reasons were provided for the consumption or avoidance of wild foods (most commonly taste, contribution to health, limited alternatives, hunger, availability, local taboos).
- Full Text:
- Date Issued: 2017
- Authors: Maseko, Heather N , Shackleton, Charlie M , Nagoli, J , Pullanikkatil, Deepa
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182101 , vital:43800 , xlink:href="https://doi.org/10.1007/s10745-017-9956-8"
- Description: There is growing recognition of the contribution of wild foods to local diets, nutrition, and culture. Yet disaggregation of understanding of wild food use by gender and age is limited. We used a mixed methods approach to determine the types, frequencies, and perceptions of wild foods used and sold by children in four villages in southern Malawi that have different levels of deforestation. Household and individual dietary diversity scores are low at all sites. All households consume one or more wild foods. Across the four sites, children listed 119 wild foods, with a wider variety at the least deforested sites than the most deforested ones. Older children can name more wild foods than younger ones. More children from poor households sell wild foods than from well-off households. Several reasons were provided for the consumption or avoidance of wild foods (most commonly taste, contribution to health, limited alternatives, hunger, availability, local taboos).
- Full Text:
- Date Issued: 2017
Chinese Cabbage:
- Authors: Mwaba, Stary
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146699 , vital:38549 , https://www.ru.ac.za/artsofafrica/latestnews/rhodesparticipatesintheafrica-chinasymposiumatthegoetheinstitute.html
- Description: Stary Mwaba, an MFA candidate in the Arts of Africa and the Global South research team in the Fine Art Department, presented a paper on his installation, Chinese Cabbage, which was first displayed in his solo exhibition, Life on Mars, at the Künstlerhaus Bethanien in Germany in 2015. At the Africa–China symposium, Mwaba talked about his personal inroad into the Zambia–China debate, which draws from a family history of living along the Tazara Railway that was built by the Chinese in the 1960s, as well as the experience of his daughter attending a Chinese-run international school in Lusaka. Mwaba is currently expanding this research as part of his MFA studies at Rhodes by collecting oral narratives along the line of rail in Zambia and by addressing, through his painting practice, issues pertinent to the controversial copper slug known as Black Mountain in Kitwe.
- Full Text:
- Date Issued: 2017
- Authors: Mwaba, Stary
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146699 , vital:38549 , https://www.ru.ac.za/artsofafrica/latestnews/rhodesparticipatesintheafrica-chinasymposiumatthegoetheinstitute.html
- Description: Stary Mwaba, an MFA candidate in the Arts of Africa and the Global South research team in the Fine Art Department, presented a paper on his installation, Chinese Cabbage, which was first displayed in his solo exhibition, Life on Mars, at the Künstlerhaus Bethanien in Germany in 2015. At the Africa–China symposium, Mwaba talked about his personal inroad into the Zambia–China debate, which draws from a family history of living along the Tazara Railway that was built by the Chinese in the 1960s, as well as the experience of his daughter attending a Chinese-run international school in Lusaka. Mwaba is currently expanding this research as part of his MFA studies at Rhodes by collecting oral narratives along the line of rail in Zambia and by addressing, through his painting practice, issues pertinent to the controversial copper slug known as Black Mountain in Kitwe.
- Full Text:
- Date Issued: 2017
Collaborative research in contexts of inequality: the role of social reflexivity
- Leibowitz, Brenda, Bozalek, Vivienne, Farmer, Jean-Lee, Garraway, James, Herman, Nicoline, Jawitz, Jeff, McMillan, Wendy, Mistri, Gita, Ndebele, Clever, Nkonki, Vuyisile, Quinn, Lynn, Van Schalkwyk, Susan, Vorster, Jo-Anne E, Winberg, Chris
- Authors: Leibowitz, Brenda , Bozalek, Vivienne , Farmer, Jean-Lee , Garraway, James , Herman, Nicoline , Jawitz, Jeff , McMillan, Wendy , Mistri, Gita , Ndebele, Clever , Nkonki, Vuyisile , Quinn, Lynn , Van Schalkwyk, Susan , Vorster, Jo-Anne E , Winberg, Chris
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66634 , vital:28973 , https://doi.org/10.1007/s10734-016-0029-5
- Description: publisher version , This article reports on the role and value of social reflexivity in collaborative research in contexts of extreme inequality. Social reflexivity mediates the enablements and constraints generated by the internal and external contextual conditions impinging on the research collaboration. It fosters the ability of participants in a collaborative project to align their interests and collectively extend their agency towards a common purpose. It influences the productivity and quality of learning outcomes of the research collaboration. The article is written by fourteen members of a larger research team, which comprised 18 individuals working within the academic development environment in eight South African universities. The overarching research project investigated the participation of academics in professional development activities, and how contextual, i.e. structural and cultural, and agential conditions, influence this participation. For this sub-study on the experience of the collaboration by fourteen of the researchers, we wrote reflective pieces on our own experience of participating in the project towards the end of the third year of its duration. We discuss the structural and cultural conditions external to and internal to the project, and how the social reflexivity of the participants mediated these conditions. We conclude with the observation that policy injunctions and support from funding agencies for collaborative research, as well as support from participants’ home institutions are necessary for the flourishing of collaborative research, but that the commitment by individual participants to participate, learn and share, is also necessary.
- Full Text: false
- Date Issued: 2017
- Authors: Leibowitz, Brenda , Bozalek, Vivienne , Farmer, Jean-Lee , Garraway, James , Herman, Nicoline , Jawitz, Jeff , McMillan, Wendy , Mistri, Gita , Ndebele, Clever , Nkonki, Vuyisile , Quinn, Lynn , Van Schalkwyk, Susan , Vorster, Jo-Anne E , Winberg, Chris
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66634 , vital:28973 , https://doi.org/10.1007/s10734-016-0029-5
- Description: publisher version , This article reports on the role and value of social reflexivity in collaborative research in contexts of extreme inequality. Social reflexivity mediates the enablements and constraints generated by the internal and external contextual conditions impinging on the research collaboration. It fosters the ability of participants in a collaborative project to align their interests and collectively extend their agency towards a common purpose. It influences the productivity and quality of learning outcomes of the research collaboration. The article is written by fourteen members of a larger research team, which comprised 18 individuals working within the academic development environment in eight South African universities. The overarching research project investigated the participation of academics in professional development activities, and how contextual, i.e. structural and cultural, and agential conditions, influence this participation. For this sub-study on the experience of the collaboration by fourteen of the researchers, we wrote reflective pieces on our own experience of participating in the project towards the end of the third year of its duration. We discuss the structural and cultural conditions external to and internal to the project, and how the social reflexivity of the participants mediated these conditions. We conclude with the observation that policy injunctions and support from funding agencies for collaborative research, as well as support from participants’ home institutions are necessary for the flourishing of collaborative research, but that the commitment by individual participants to participate, learn and share, is also necessary.
- Full Text: false
- Date Issued: 2017
Colonised minds?: post-development theory and the desirability of development in Africa
- Authors: Matthews, Sally
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142213 , vital:38059 , DOI: 10.1080/01436597.2017.1279540
- Description: While post-development theory is very concerned with the ways in which development has impacted upon the countries of the Global South, there has been relatively little written on post-development theory from an African perspective. This paper identifies some of the ways in which post-development theory fails to adequately understand the African experience of development. In particular, I explore the difficulty that post-development theory confronts when faced with the continued desire on the part of many people in Africa for development.
- Full Text:
- Date Issued: 2017
- Authors: Matthews, Sally
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142213 , vital:38059 , DOI: 10.1080/01436597.2017.1279540
- Description: While post-development theory is very concerned with the ways in which development has impacted upon the countries of the Global South, there has been relatively little written on post-development theory from an African perspective. This paper identifies some of the ways in which post-development theory fails to adequately understand the African experience of development. In particular, I explore the difficulty that post-development theory confronts when faced with the continued desire on the part of many people in Africa for development.
- Full Text:
- Date Issued: 2017
Community entomology: insects, science and society
- Weaver, Kim N, Hill, Jaclyn M, Martin, Grant D, Paterson, Iain D, Coetzee, Julie A, Hill, Martin P
- Authors: Weaver, Kim N , Hill, Jaclyn M , Martin, Grant D , Paterson, Iain D , Coetzee, Julie A , Hill, Martin P
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123343 , vital:35429 , https://hdl.handle.net/10520/EJC-c859bebd5
- Description: Educative outreach programmes have been found to be effective ways in which to raise awareness around basic scientific concepts. The Biological Control Research Group (BCRG) in the Department of Zoology and Entomology at Rhodes University, South Africa, is involved in community engaged initiatives that aim to be interactive and informative around entomology, and more specifically, the use of biological control against invasive alien plants. As a higher education institution, Rhodes University has a civic responsibility to engage with local communities and work with them around local challenges. Three groups of activities undertaken by the BCRG in partnership with local schools and other community partners are described and assessed in this paper as a way of assessing them and exploring future research areas around the aims and outcomes of these programmes.
- Full Text:
- Date Issued: 2017
- Authors: Weaver, Kim N , Hill, Jaclyn M , Martin, Grant D , Paterson, Iain D , Coetzee, Julie A , Hill, Martin P
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123343 , vital:35429 , https://hdl.handle.net/10520/EJC-c859bebd5
- Description: Educative outreach programmes have been found to be effective ways in which to raise awareness around basic scientific concepts. The Biological Control Research Group (BCRG) in the Department of Zoology and Entomology at Rhodes University, South Africa, is involved in community engaged initiatives that aim to be interactive and informative around entomology, and more specifically, the use of biological control against invasive alien plants. As a higher education institution, Rhodes University has a civic responsibility to engage with local communities and work with them around local challenges. Three groups of activities undertaken by the BCRG in partnership with local schools and other community partners are described and assessed in this paper as a way of assessing them and exploring future research areas around the aims and outcomes of these programmes.
- Full Text:
- Date Issued: 2017
Community ‘Broadband Islands’ for digital government access in rural South Africa
- Terzoli, Alfredo, Siebörger, Ingrid, Gumbo, Sibukelo
- Authors: Terzoli, Alfredo , Siebörger, Ingrid , Gumbo, Sibukelo
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431248 , vital:72758 , https://www.academic-bookshop.com/ourshop/prod_6128029-ECDG-2017-PDF-Proceedings-of-the-17th-European-Conference-on-Digital-Government.html
- Description: In the developing world, one of the main obstacles to the realization of the potential of digital government in rendering services to citizens is the lack of access infrastructure. In this paper we present a model for the diffusion of Internet connectivity and access to computing infrastructure in rural communities in South Africa, through the aggregation of inde-pendent small and micro networks. The model is based on multi-year experimentation in the Siyakhula Living Lab, a long term joint venture between the Telkom Centres of Excellence hosted at Rhodes Universi-ty and the University of Fort Hare in South Africa. At the core of the model is the concept of ‘Broadband Island’, a high speed LAN realized through easy-to-deploy wireless technologies connecting groups of nearby schools. Each connected school, doubling as Digital Access Nodes for the community, hosts computing infrastructure in a serv-ers/thin clients configuration. Two schools belonging to the Broadband Island are then connected to the Internet with whatever technique makes sense within that specific geographical area: VSAT, microwave link, fibre etc. Each Broadband Island can be provisioned and support-ed by a variety of independent entities (such as Municipalities, Educa-tion Districts, NGOs, local action groups etc), possibly combined in con-sortia and in some cases using a Public Private Partnership format.
- Full Text:
- Date Issued: 2017
- Authors: Terzoli, Alfredo , Siebörger, Ingrid , Gumbo, Sibukelo
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431248 , vital:72758 , https://www.academic-bookshop.com/ourshop/prod_6128029-ECDG-2017-PDF-Proceedings-of-the-17th-European-Conference-on-Digital-Government.html
- Description: In the developing world, one of the main obstacles to the realization of the potential of digital government in rendering services to citizens is the lack of access infrastructure. In this paper we present a model for the diffusion of Internet connectivity and access to computing infrastructure in rural communities in South Africa, through the aggregation of inde-pendent small and micro networks. The model is based on multi-year experimentation in the Siyakhula Living Lab, a long term joint venture between the Telkom Centres of Excellence hosted at Rhodes Universi-ty and the University of Fort Hare in South Africa. At the core of the model is the concept of ‘Broadband Island’, a high speed LAN realized through easy-to-deploy wireless technologies connecting groups of nearby schools. Each connected school, doubling as Digital Access Nodes for the community, hosts computing infrastructure in a serv-ers/thin clients configuration. Two schools belonging to the Broadband Island are then connected to the Internet with whatever technique makes sense within that specific geographical area: VSAT, microwave link, fibre etc. Each Broadband Island can be provisioned and support-ed by a variety of independent entities (such as Municipalities, Educa-tion Districts, NGOs, local action groups etc), possibly combined in con-sortia and in some cases using a Public Private Partnership format.
- Full Text:
- Date Issued: 2017
Community-based natural resource use and management of Bigodi Wetland Sanctuary, Uganda, for livelihood benefits
- Gosling, Amanda, Shackleton, Charlie M, Gambiza, James
- Authors: Gosling, Amanda , Shackleton, Charlie M , Gambiza, James
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/60844 , vital:27839 , https://doi.org/10.1007/s11273-017-9546-y
- Description: publisher version , Conservation and sustainable management of wetlands requires participation of local stakeholders, including communities. The Bigodi Wetland is unusual because it is situated in a common property landscape but the local community has been running a successful community-based natural resource management programme (CBNRM) for the wetland for over a decade. Whilst external visitors to the wetland provide ecotourism revenues we sought to quantify community benefits through the use of wetland goods such as firewood, plant fibres, and the like, and costs associated with wild animals damaging farming activities. We interviewed 68 households living close to the wetland and valued their cash and non-cash incomes from farming and collection of non-timber forest products (NTFPs) and water. The majority of households collected a wide variety of plant and fish resources and water from the wetland for household use and livestock. Overall, 53% of total household cash and non-cash income was from collected products, mostly the wetland, 28% from arable agriculture, 12% from livestock and 7% from employment and cash transfers. Female-headed households had lower incomes than male-headed ones, and with a greater reliance on NTFPs. Annual losses due to wildlife damage were estimated at 4.2% of total gross income. Most respondents felt that the wetland was important for their livelihoods, with more than 80% identifying health, education, craft materials and firewood as key benefits. Ninety-five percent felt that the wetland was in a good condition and that most residents observed the agreed CBNRM rules regarding use of the wetland. This study confirms the success of the locally run CBNRM processes underlying the significant role that the wetland plays in local livelihoods.
- Full Text:
- Date Issued: 2017
- Authors: Gosling, Amanda , Shackleton, Charlie M , Gambiza, James
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/60844 , vital:27839 , https://doi.org/10.1007/s11273-017-9546-y
- Description: publisher version , Conservation and sustainable management of wetlands requires participation of local stakeholders, including communities. The Bigodi Wetland is unusual because it is situated in a common property landscape but the local community has been running a successful community-based natural resource management programme (CBNRM) for the wetland for over a decade. Whilst external visitors to the wetland provide ecotourism revenues we sought to quantify community benefits through the use of wetland goods such as firewood, plant fibres, and the like, and costs associated with wild animals damaging farming activities. We interviewed 68 households living close to the wetland and valued their cash and non-cash incomes from farming and collection of non-timber forest products (NTFPs) and water. The majority of households collected a wide variety of plant and fish resources and water from the wetland for household use and livestock. Overall, 53% of total household cash and non-cash income was from collected products, mostly the wetland, 28% from arable agriculture, 12% from livestock and 7% from employment and cash transfers. Female-headed households had lower incomes than male-headed ones, and with a greater reliance on NTFPs. Annual losses due to wildlife damage were estimated at 4.2% of total gross income. Most respondents felt that the wetland was important for their livelihoods, with more than 80% identifying health, education, craft materials and firewood as key benefits. Ninety-five percent felt that the wetland was in a good condition and that most residents observed the agreed CBNRM rules regarding use of the wetland. This study confirms the success of the locally run CBNRM processes underlying the significant role that the wetland plays in local livelihoods.
- Full Text:
- Date Issued: 2017
Comparative perch selection in Southern Fiscal Lanius collaris and Fiscal Flycatcher Sigelus silens at Amakhala Game Reserve, South Africa
- Daniels, Ryan J, Hulley, Patrick E, Craig, Adrian J F K
- Authors: Daniels, Ryan J , Hulley, Patrick E , Craig, Adrian J F K
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449294 , vital:74809 , https://doi.org/10.2989/00306525.2016.1264496
- Description: The Southern Fiscal Lanius collaris and the Fiscal Flycatcher Sigelus silens are common, widespread and sympatric in much of southern Africa. They are similar in plumage and ecology, which may predispose them to competition and interspecific territorial aggression but this has not been tested to date. Here we tested for evidence of competition for perch space. At Amakhala Private Game Reserve, Eastern Cape, South Africa we monitored the occurrence and perch use of both species along transects. The birds do co-occur locally but there is evidence of small-scale spatial separation possibly a result of interspecific territoriality. Perch selection differed in respect of perch type but not perch height. Both species perched prominently in the majority of observations. Southern Fiscals make greater use of Searsia and Gymnosporia trees, whereas the Fiscal Flycatcher makes near-equal use of Vachellia karroo, Searsia and Gymnosporia trees. This may be an example of niche partitioning, though it remains unclear whether the birds actively compete for perch space, or if the separation is a product of different perch preferences, territoriality and the local plant community.
- Full Text:
- Date Issued: 2017
- Authors: Daniels, Ryan J , Hulley, Patrick E , Craig, Adrian J F K
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449294 , vital:74809 , https://doi.org/10.2989/00306525.2016.1264496
- Description: The Southern Fiscal Lanius collaris and the Fiscal Flycatcher Sigelus silens are common, widespread and sympatric in much of southern Africa. They are similar in plumage and ecology, which may predispose them to competition and interspecific territorial aggression but this has not been tested to date. Here we tested for evidence of competition for perch space. At Amakhala Private Game Reserve, Eastern Cape, South Africa we monitored the occurrence and perch use of both species along transects. The birds do co-occur locally but there is evidence of small-scale spatial separation possibly a result of interspecific territoriality. Perch selection differed in respect of perch type but not perch height. Both species perched prominently in the majority of observations. Southern Fiscals make greater use of Searsia and Gymnosporia trees, whereas the Fiscal Flycatcher makes near-equal use of Vachellia karroo, Searsia and Gymnosporia trees. This may be an example of niche partitioning, though it remains unclear whether the birds actively compete for perch space, or if the separation is a product of different perch preferences, territoriality and the local plant community.
- Full Text:
- Date Issued: 2017
Comparing the fish assemblages and food web structures of large floodplain rivers
- Taylor, Geraldine C, Weyl, Olaf L F, Hill, Jaclyn M, Peel, Richard A, Hay, Clinton J
- Authors: Taylor, Geraldine C , Weyl, Olaf L F , Hill, Jaclyn M , Peel, Richard A , Hay, Clinton J
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68961 , vital:29343 , https://doi.org/10.1111/fwb.13032
- Description: The Upper Zambezi, Kavango and Kwando are large floodplain rivers with substantial biodiversity, providing water and ecosystem services to a large tract of southern Africa. These rivers differ in hydrological regime. The Upper Zambezi and Kavango rivers are in flood for 4 months (March, April, May, June) while, in the Kwando River, floods are later and last for 1–2 months in July and August. The Upper Zambezi River has the largest annual flood pulse, followed by the Kavango River, while the Kwando River experiences small and unreliable floods. During years of exceptional flooding of the Upper Zambezi and Kavango rivers, the rivers are interconnected at peak flows and therefore share a common ichthyofauna. This provided a natural experiment to investigate the responses of fish communities comprised of the same species to differing flood regimes by comparing the fish assemblages and food‐web structures between rivers.
- Full Text: false
- Date Issued: 2017
- Authors: Taylor, Geraldine C , Weyl, Olaf L F , Hill, Jaclyn M , Peel, Richard A , Hay, Clinton J
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68961 , vital:29343 , https://doi.org/10.1111/fwb.13032
- Description: The Upper Zambezi, Kavango and Kwando are large floodplain rivers with substantial biodiversity, providing water and ecosystem services to a large tract of southern Africa. These rivers differ in hydrological regime. The Upper Zambezi and Kavango rivers are in flood for 4 months (March, April, May, June) while, in the Kwando River, floods are later and last for 1–2 months in July and August. The Upper Zambezi River has the largest annual flood pulse, followed by the Kavango River, while the Kwando River experiences small and unreliable floods. During years of exceptional flooding of the Upper Zambezi and Kavango rivers, the rivers are interconnected at peak flows and therefore share a common ichthyofauna. This provided a natural experiment to investigate the responses of fish communities comprised of the same species to differing flood regimes by comparing the fish assemblages and food‐web structures between rivers.
- Full Text: false
- Date Issued: 2017
Comprehensive kinetic analysis of thermoluminescence peaks of α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116142 , vital:34323 , https://doi.org/10.1016/j.jlumin.2017.01.003
- Description: A comprehensive kinetic analysis of the glow peaks in α-Al2O3:C,Mg is reported. A thermoluminescence glow curve measured at 1 °C/s after beta irradiation to 1 Gy shows a high intensity peak hereafter referred to as the main peak at 161 °C and six lower intensity secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. For ease of reference, the secondary peaks are labelled as I, II, IV, V, VI and VII respectively and the main peak denoted peak III. Kinetic analysis of the glow peaks has been carried out using the initial rise, whole glow peak, peak shape, variable heating rate and glow curve deconvolution methods as well as by way of phosphorescence. Using Tm-Tstop, Tm-dose and phosphorescence analyses, the order of kinetics of the peaks has been evaluated as first order. Analysis by the peak shape, whole glow peak and deconvolution methods produce the same conclusion. The activation energy of peaks I through VII are calculated as ~0.83, 0.96, 1.37, 1.20, 1.15, 1.61 and 1.94 eV respectively. The frequency factors for all the peaks are of the order of 109 to 1014 s−1. The question of thermal quenching affecting the peaks was considered. The peaks III, IV and V, the only ones that could be conveniently studied in this regard, were found to be affected by thermal quenching. The activation energy for thermal quenching was calculated for peak III as 0.96±0.03 eV, for peak VI as 0.95±0.07 eV and for peak V as 1.26±0.08 eV. The thermal quenching phenomenon has been discussed with reference to F+ and F centres. An energy band model has been developed to discuss the luminescence mechanisms in α-Al2O3:C,Mg in light of finding in this work.
- Full Text: false
- Date Issued: 2017
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116142 , vital:34323 , https://doi.org/10.1016/j.jlumin.2017.01.003
- Description: A comprehensive kinetic analysis of the glow peaks in α-Al2O3:C,Mg is reported. A thermoluminescence glow curve measured at 1 °C/s after beta irradiation to 1 Gy shows a high intensity peak hereafter referred to as the main peak at 161 °C and six lower intensity secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. For ease of reference, the secondary peaks are labelled as I, II, IV, V, VI and VII respectively and the main peak denoted peak III. Kinetic analysis of the glow peaks has been carried out using the initial rise, whole glow peak, peak shape, variable heating rate and glow curve deconvolution methods as well as by way of phosphorescence. Using Tm-Tstop, Tm-dose and phosphorescence analyses, the order of kinetics of the peaks has been evaluated as first order. Analysis by the peak shape, whole glow peak and deconvolution methods produce the same conclusion. The activation energy of peaks I through VII are calculated as ~0.83, 0.96, 1.37, 1.20, 1.15, 1.61 and 1.94 eV respectively. The frequency factors for all the peaks are of the order of 109 to 1014 s−1. The question of thermal quenching affecting the peaks was considered. The peaks III, IV and V, the only ones that could be conveniently studied in this regard, were found to be affected by thermal quenching. The activation energy for thermal quenching was calculated for peak III as 0.96±0.03 eV, for peak VI as 0.95±0.07 eV and for peak V as 1.26±0.08 eV. The thermal quenching phenomenon has been discussed with reference to F+ and F centres. An energy band model has been developed to discuss the luminescence mechanisms in α-Al2O3:C,Mg in light of finding in this work.
- Full Text: false
- Date Issued: 2017
Conceptualising knowledge for access in the sciences: academic development from a social realist perspective
- Authors: Ellery, Karen
- Date: 2017
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59863 , vital:27671 , https://doi.org/10.1007/s10734-016-0085-x
- Description: Whilst arguing from a social realist perspective that knowledge matters in academic development (AD) curricula, this paper addresses the question of what knowledge types and practices are necessary for enabling epistemological access. It presents a single, in-depth, qualitative case study in which the curriculum of a science AD course is characterised using Legitimation Code Theory (LCT). Analysis of the course curriculum reveals legitimation of four main categories of knowledge types along a continuum of stronger to weaker epistemic relations: disciplinary knowledge, scientific literacies knowledge, general academic practices knowledge and everyday knowledge. These categories are ‘mapped’ onto an LCT(Semantics)(how meaning relates to both context and empirical referents) topological plane to reveal a curriculum that operates in three distinct but interrelated spaces by facing towards both the field of science and the practice of academia. It is argued that this empirically derived differentiated curriculum framework offers a conceptual means for considering the notion of access to ‘powerful’ knowledge in a range of AD and mainstream contexts.
- Full Text:
- Date Issued: 2017
- Authors: Ellery, Karen
- Date: 2017
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59863 , vital:27671 , https://doi.org/10.1007/s10734-016-0085-x
- Description: Whilst arguing from a social realist perspective that knowledge matters in academic development (AD) curricula, this paper addresses the question of what knowledge types and practices are necessary for enabling epistemological access. It presents a single, in-depth, qualitative case study in which the curriculum of a science AD course is characterised using Legitimation Code Theory (LCT). Analysis of the course curriculum reveals legitimation of four main categories of knowledge types along a continuum of stronger to weaker epistemic relations: disciplinary knowledge, scientific literacies knowledge, general academic practices knowledge and everyday knowledge. These categories are ‘mapped’ onto an LCT(Semantics)(how meaning relates to both context and empirical referents) topological plane to reveal a curriculum that operates in three distinct but interrelated spaces by facing towards both the field of science and the practice of academia. It is argued that this empirically derived differentiated curriculum framework offers a conceptual means for considering the notion of access to ‘powerful’ knowledge in a range of AD and mainstream contexts.
- Full Text:
- Date Issued: 2017
Cosmopolitanism and the unfollowable routines and rituals in Ishtiyaq Shukri’s The Silent Minaret:
- Authors: Dass, Minesh
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142531 , vital:38088 , DOI: 10.1080/02564718.2017.1290382
- Description: This article explores how Ishtiyaq Shukri’s The Silent Minaret critiques the limited and severely uneven forms of hospitality that characterise post-9/11 Britain. It also examines how the text gestures towards the possibility of a non-violent, inclusive cosmopolitanism. The piece begins by relating recent debates surrounding the “War on Terror”, as well as Britain’s decision to leave the European Union to the novel’s major concerns. It then turns to the novel, and summarises incidents in which the principal character, Issa Shamshuddin, is traumatised and harmed by the Islamophobia and anti-immigration policies evident in the London portrayed in the text. Next, it turns to an analysis of the strange and irreproducible rituals of Issa’s neighbour, Frances. The article concludes that that these unfollowable rituals posit how a truly cosmopolitan society would function.
- Full Text:
- Date Issued: 2017
- Authors: Dass, Minesh
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142531 , vital:38088 , DOI: 10.1080/02564718.2017.1290382
- Description: This article explores how Ishtiyaq Shukri’s The Silent Minaret critiques the limited and severely uneven forms of hospitality that characterise post-9/11 Britain. It also examines how the text gestures towards the possibility of a non-violent, inclusive cosmopolitanism. The piece begins by relating recent debates surrounding the “War on Terror”, as well as Britain’s decision to leave the European Union to the novel’s major concerns. It then turns to the novel, and summarises incidents in which the principal character, Issa Shamshuddin, is traumatised and harmed by the Islamophobia and anti-immigration policies evident in the London portrayed in the text. Next, it turns to an analysis of the strange and irreproducible rituals of Issa’s neighbour, Frances. The article concludes that that these unfollowable rituals posit how a truly cosmopolitan society would function.
- Full Text:
- Date Issued: 2017
Counting on demographic equity to transform institutional cultures at historically white South African universities?:
- Booi, Masixole, Vincent, Louise, Liccardo, Sabrina
- Authors: Booi, Masixole , Vincent, Louise , Liccardo, Sabrina
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141946 , vital:38018 , DOI: 10.1080/07294360.2017.1289155
- Description: The post-apartheid higher education transformation project is faced with the challenge of recruiting and retaining black academics and other senior staff. But when we shift the focus from participation rates to equality–inequality within historically white universities (HWUs), then the discourse changes from demographic equity and redress to institutional culture and diversity. HWUs invoke the need to maintain their position as leading higher education institutions globally, and notions of ‘quality’ and ‘excellence’ have emerged as discursive practices, which serve to perpetuate exclusion. The question then arises as to which forms of capital comprise the Gold Standard at HWUs? Several South African universities have responded to the challenge of recruiting and retaining black academics by initiating programmes for the ‘accelerated development’ of these candidates.
- Full Text:
- Date Issued: 2017
- Authors: Booi, Masixole , Vincent, Louise , Liccardo, Sabrina
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141946 , vital:38018 , DOI: 10.1080/07294360.2017.1289155
- Description: The post-apartheid higher education transformation project is faced with the challenge of recruiting and retaining black academics and other senior staff. But when we shift the focus from participation rates to equality–inequality within historically white universities (HWUs), then the discourse changes from demographic equity and redress to institutional culture and diversity. HWUs invoke the need to maintain their position as leading higher education institutions globally, and notions of ‘quality’ and ‘excellence’ have emerged as discursive practices, which serve to perpetuate exclusion. The question then arises as to which forms of capital comprise the Gold Standard at HWUs? Several South African universities have responded to the challenge of recruiting and retaining black academics by initiating programmes for the ‘accelerated development’ of these candidates.
- Full Text:
- Date Issued: 2017
Crossing conceptual thresholds in doctoral communities
- Authors: McKenna, Sioux
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66719 , vital:28986 , ISSN 1470-3300 , https://doi.org/10.1080/14703297.2016.1155471
- Description: Pre-print , The traditional apprenticeship model of supervision in which the single scholar charts her individual research path is giving way to more collaborative learning environments. Doctoral programmes, in which communities of scholars work together, have become increasingly common. This study interrogated how being part of such a community enables the conceptual depth we expect at doctoral level. It draws on the notion of conceptual threshold crossing to make sense of the learning experiences of 28 education PhD scholars. Working in a community of doctoral scholars was found to have conceptual impact (i) when the community is supportive, (ii) encourages risk-taking and facilitates conversations across different issues and disciplines, (iii) when the scholars have to regularly articulate their position and (iv) because the programme structure enhances the likelihood of fortuitous encounters with theories and concepts.
- Full Text:
- Date Issued: 2017
- Authors: McKenna, Sioux
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66719 , vital:28986 , ISSN 1470-3300 , https://doi.org/10.1080/14703297.2016.1155471
- Description: Pre-print , The traditional apprenticeship model of supervision in which the single scholar charts her individual research path is giving way to more collaborative learning environments. Doctoral programmes, in which communities of scholars work together, have become increasingly common. This study interrogated how being part of such a community enables the conceptual depth we expect at doctoral level. It draws on the notion of conceptual threshold crossing to make sense of the learning experiences of 28 education PhD scholars. Working in a community of doctoral scholars was found to have conceptual impact (i) when the community is supportive, (ii) encourages risk-taking and facilitates conversations across different issues and disciplines, (iii) when the scholars have to regularly articulate their position and (iv) because the programme structure enhances the likelihood of fortuitous encounters with theories and concepts.
- Full Text:
- Date Issued: 2017
Cu (III) triarylcorroles with asymmetric push–pull meso-substitutions
- Liang, Xu, Niu, Yingjie, Zhang, Ojanchong, Mack, John, Yi, Xiaoyi, Hlatshwayo, Zweli, Li, Minzhi, Zhu, Weihua, Nyokong, Tebello
- Authors: Liang, Xu , Niu, Yingjie , Zhang, Ojanchong , Mack, John , Yi, Xiaoyi , Hlatshwayo, Zweli , Li, Minzhi , Zhu, Weihua , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232947 , vital:50040 , xlink:href="https://doi.org/10.1039/C7DT00716G"
- Description: The synthesis of four low symmetry A2B type Cu (III)triarylcorroles with meso-aryl substituents that provide electron donating (push) and withdrawing (pull) properties is reported, along with their structural characterization by NMR spectroscopy and X-ray crystallography. An analysis of the structure–property relationships in the optical and redox properties has been carried out by comparing their optical spectroscopy, electrochemistry, and spectroelectrochemistry to trends predicted in DFT and TD-DFT calculations. The results demonstrate that A2B type Cu(III)triarylcorroles are highly efficient catalysts for electrocatalyzed hydrogen evolution reactions (HERs) and that their reactivity can be modulated by changing the nature of the B-position meso-substituent.
- Full Text:
- Date Issued: 2017
- Authors: Liang, Xu , Niu, Yingjie , Zhang, Ojanchong , Mack, John , Yi, Xiaoyi , Hlatshwayo, Zweli , Li, Minzhi , Zhu, Weihua , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232947 , vital:50040 , xlink:href="https://doi.org/10.1039/C7DT00716G"
- Description: The synthesis of four low symmetry A2B type Cu (III)triarylcorroles with meso-aryl substituents that provide electron donating (push) and withdrawing (pull) properties is reported, along with their structural characterization by NMR spectroscopy and X-ray crystallography. An analysis of the structure–property relationships in the optical and redox properties has been carried out by comparing their optical spectroscopy, electrochemistry, and spectroelectrochemistry to trends predicted in DFT and TD-DFT calculations. The results demonstrate that A2B type Cu(III)triarylcorroles are highly efficient catalysts for electrocatalyzed hydrogen evolution reactions (HERs) and that their reactivity can be modulated by changing the nature of the B-position meso-substituent.
- Full Text:
- Date Issued: 2017
Customary management as TURFs: social challenges and opportunities
- Authors: Aswani, Shankar
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145403 , vital:38435 , DOI: 10.5343/bms.2015.1084
- Description: There is a growing interest in working with customary management (CM) systems to effectively manage benthic resources and small-scale fisheries. The underlying notion is that CM institution as territorial use rights in fisheries (TURFs) can be sufficiently adaptive and dynamic to create the local incentives that are necessary for promoting sustainable fishing practices and marine conservation more generally in a given region. This paper reviews the social opportunities and challenges of working with CM systems as a form of TURF, particularly in Oceania. A key conclusion is that policy makers and managers not only need to recognize natural interconnectivity in any one marine space, but also consider the social interconnectivity of stakeholders that covers customary TURFs. Only by recognizing and working with the existing social networks that overlay any given marine territory can the operational principles of CM (as reviewed in this paper) be effectively deployed for achieving some kind of bioeconomic efficiency and creating an equitable rights-based fisheries management system.
- Full Text:
- Date Issued: 2017
- Authors: Aswani, Shankar
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145403 , vital:38435 , DOI: 10.5343/bms.2015.1084
- Description: There is a growing interest in working with customary management (CM) systems to effectively manage benthic resources and small-scale fisheries. The underlying notion is that CM institution as territorial use rights in fisheries (TURFs) can be sufficiently adaptive and dynamic to create the local incentives that are necessary for promoting sustainable fishing practices and marine conservation more generally in a given region. This paper reviews the social opportunities and challenges of working with CM systems as a form of TURF, particularly in Oceania. A key conclusion is that policy makers and managers not only need to recognize natural interconnectivity in any one marine space, but also consider the social interconnectivity of stakeholders that covers customary TURFs. Only by recognizing and working with the existing social networks that overlay any given marine territory can the operational principles of CM (as reviewed in this paper) be effectively deployed for achieving some kind of bioeconomic efficiency and creating an equitable rights-based fisheries management system.
- Full Text:
- Date Issued: 2017