The effects of changing western worldviews on morals and ethics in economics: a protestant perspective
- Authors: Appalraju, Nerusha
- Date: 2017
- Subjects: Economics -- Moral and ethical aspects , Neoclassical school of economics , Capitalism -- Religious aspects -- Protestant churches , Feminist economics , Economics -- Religious aspects , Environmental economics -- Moral and ethical aspects , Smith, Adam, 1723-1790 , Weber, Max, 1864-1920
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/32480 , vital:24050
- Description: The World Economics Association held an online conference in 2012 where they published many papers on ethics in economics. The topic of ethics in economics became more serious and popular following the 2008 financial crisis. However the case for a professional code of ethics in economics is difficult to introduce and implement due to the multidisciplinary approach of the discipline. Therefore authors such as Dow (2012), De Martino (2012), Freeman (2012) and Earl (2012) urged economists to start thinking about ethics in economics from a pluralistic view. This thesis studied the effects of changing Western worldviews on morals and ethics in economics from a Protestant perspective. Numerous authoritative sources were considered and used to create a discussion and analysis of how diverse Western worldviews impact on the type of economics which is prescribed and practiced. It was found that different Western worldviews create various standards of understanding and evaluation, which result in varying opinions on what constitutes as morally or ethically acceptable within the discipline of economics.
- Full Text:
- Authors: Appalraju, Nerusha
- Date: 2017
- Subjects: Economics -- Moral and ethical aspects , Neoclassical school of economics , Capitalism -- Religious aspects -- Protestant churches , Feminist economics , Economics -- Religious aspects , Environmental economics -- Moral and ethical aspects , Smith, Adam, 1723-1790 , Weber, Max, 1864-1920
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/32480 , vital:24050
- Description: The World Economics Association held an online conference in 2012 where they published many papers on ethics in economics. The topic of ethics in economics became more serious and popular following the 2008 financial crisis. However the case for a professional code of ethics in economics is difficult to introduce and implement due to the multidisciplinary approach of the discipline. Therefore authors such as Dow (2012), De Martino (2012), Freeman (2012) and Earl (2012) urged economists to start thinking about ethics in economics from a pluralistic view. This thesis studied the effects of changing Western worldviews on morals and ethics in economics from a Protestant perspective. Numerous authoritative sources were considered and used to create a discussion and analysis of how diverse Western worldviews impact on the type of economics which is prescribed and practiced. It was found that different Western worldviews create various standards of understanding and evaluation, which result in varying opinions on what constitutes as morally or ethically acceptable within the discipline of economics.
- Full Text:
The effects of expansive shrubs on plant species richness and soils in semi-arid communal lands, South Africa
- Sholto-Douglas, Craig, Shackleton, Charlie M, Ruwanza, Sheunesu, Dold, Tony
- Authors: Sholto-Douglas, Craig , Shackleton, Charlie M , Ruwanza, Sheunesu , Dold, Tony
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398394 , vital:69408 , xlink:href="https://doi.org/10.1002/ldr.2745"
- Description: Expansion by expansive species can have severe ecological, social and economic impacts through the reduction of ecosystem goods and services and species richness. However, expansion by expansive species may also offer benefits to ecosystems and humans, through the supply of ecosystem goods and services (such as firewood, fodder and fruits), as well as potentially offering refugia in heavily used landscapes. Here, we examine the effects of four expansive dwarf shrub species (Aspalathus subtingens, Dicerothamnus rhinocerotis, Pteronia incana and Oedera genistifolia) on plant species richness (at the point scale), vegetation cover, soil properties and whether the expansive species offer refugia to other species. Plant species richness, cover and soil properties were recorded in 1-m2 quadrats located within a mosaic of expanded and non-expanded patches for the four expansive shrub species. Plant species richness was significantly higher in the non-expanded areas compared to the expanded ones for all four expansive species. Some of the expansive shrubs provided refugia to certain plant species and limited the frequency of other species. With regard to species composition, there was little separation of expanded and non-expanded samples within sites, indicating that the site factors were stronger determinants of plant species richness and composition than expansion. Therefore, it is more likely that the reduction in species richness in expanded sites is caused by multiple drivers, including vegetation attributes cover, litter cover and soil nutrients (organic C, Zn and P) and soil compaction.
- Full Text:
- Authors: Sholto-Douglas, Craig , Shackleton, Charlie M , Ruwanza, Sheunesu , Dold, Tony
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/398394 , vital:69408 , xlink:href="https://doi.org/10.1002/ldr.2745"
- Description: Expansion by expansive species can have severe ecological, social and economic impacts through the reduction of ecosystem goods and services and species richness. However, expansion by expansive species may also offer benefits to ecosystems and humans, through the supply of ecosystem goods and services (such as firewood, fodder and fruits), as well as potentially offering refugia in heavily used landscapes. Here, we examine the effects of four expansive dwarf shrub species (Aspalathus subtingens, Dicerothamnus rhinocerotis, Pteronia incana and Oedera genistifolia) on plant species richness (at the point scale), vegetation cover, soil properties and whether the expansive species offer refugia to other species. Plant species richness, cover and soil properties were recorded in 1-m2 quadrats located within a mosaic of expanded and non-expanded patches for the four expansive shrub species. Plant species richness was significantly higher in the non-expanded areas compared to the expanded ones for all four expansive species. Some of the expansive shrubs provided refugia to certain plant species and limited the frequency of other species. With regard to species composition, there was little separation of expanded and non-expanded samples within sites, indicating that the site factors were stronger determinants of plant species richness and composition than expansion. Therefore, it is more likely that the reduction in species richness in expanded sites is caused by multiple drivers, including vegetation attributes cover, litter cover and soil nutrients (organic C, Zn and P) and soil compaction.
- Full Text:
The effects of graphene and other nanomaterials on the electrocatalytic behaviour of phthalocyanines
- Authors: Shumba, Munyaradzi
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/37952 , vital:24712
- Description: Carbon based nanomaterials, gold nanorods and metallophthalocyanine nanoconjugates have been developed for electrocatalysis. Carbon based nanomaterials used are multiwalled carbon nanotubes, pristine graphene oxide nanosheets, nitrogen, boron, sulphur, phosphorus doped graphene oxide nanosheets. Cobalt phthalocyanine (CoPc), cobalt tetra aminophenoxy phthalocyanine (CoTAPc), cobalt tetra aminophenoxy phthalocyanine (CoTAPhPc), cobalt mono carboxyphenoxy phthalocyanine (CoMCPhPc) and cobalt tetra carboxyphenoxy phthalocyanine (CoTCPhPc) are the phthalocyanines employed in this work. Metallophthalocyanines were employed either in their bulk form or in their nanosized form. Electrode modification by these nanomaterials was either done sequentially, premixed or linked nanoconjugates. In all sequential modification, phthalocyanines were employed on top of other nanomaterials. Sequentially modified electrodes gave higher detection currents than both premixed and covalently bonded nanoconjugates. The nanomaterials reported here were characterised by transmission electron microscopy, Raman spectroscopy, time of flight secondary ion mass spectrometry, and X-ray diffraction among other techniques. The modified electrodes were further characterised by scanning electron microscopy, scanning electrochemical microscopy, X-ray photoelectron spectroscopy and cyclic voltammetry, while square wave, linear scan and cyclic voltammetry, rotating disc electrode and chronoamperometry have been used to evaluate the electrocatalytic behaviour of the previously mentioned towards either oxidation or reduction of L-cysteine and/or hydrogen peroxide respectively. Generally, the nanoconjugates resulted in superior catalytic performance compared to the performance of individual nanomaterials. Zinc octacarboxy phthalocyanine (ZnOCPc) conjugated to either GONS or rGONS were employed to compare electrocatalytic detection of hydrogen peroxide to its luminescence sensing.
- Full Text:
The effects of graphene and other nanomaterials on the electrocatalytic behaviour of phthalocyanines
- Authors: Shumba, Munyaradzi
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/37952 , vital:24712
- Description: Carbon based nanomaterials, gold nanorods and metallophthalocyanine nanoconjugates have been developed for electrocatalysis. Carbon based nanomaterials used are multiwalled carbon nanotubes, pristine graphene oxide nanosheets, nitrogen, boron, sulphur, phosphorus doped graphene oxide nanosheets. Cobalt phthalocyanine (CoPc), cobalt tetra aminophenoxy phthalocyanine (CoTAPc), cobalt tetra aminophenoxy phthalocyanine (CoTAPhPc), cobalt mono carboxyphenoxy phthalocyanine (CoMCPhPc) and cobalt tetra carboxyphenoxy phthalocyanine (CoTCPhPc) are the phthalocyanines employed in this work. Metallophthalocyanines were employed either in their bulk form or in their nanosized form. Electrode modification by these nanomaterials was either done sequentially, premixed or linked nanoconjugates. In all sequential modification, phthalocyanines were employed on top of other nanomaterials. Sequentially modified electrodes gave higher detection currents than both premixed and covalently bonded nanoconjugates. The nanomaterials reported here were characterised by transmission electron microscopy, Raman spectroscopy, time of flight secondary ion mass spectrometry, and X-ray diffraction among other techniques. The modified electrodes were further characterised by scanning electron microscopy, scanning electrochemical microscopy, X-ray photoelectron spectroscopy and cyclic voltammetry, while square wave, linear scan and cyclic voltammetry, rotating disc electrode and chronoamperometry have been used to evaluate the electrocatalytic behaviour of the previously mentioned towards either oxidation or reduction of L-cysteine and/or hydrogen peroxide respectively. Generally, the nanoconjugates resulted in superior catalytic performance compared to the performance of individual nanomaterials. Zinc octacarboxy phthalocyanine (ZnOCPc) conjugated to either GONS or rGONS were employed to compare electrocatalytic detection of hydrogen peroxide to its luminescence sensing.
- Full Text:
The effects of the type of rest breaks on return-to-task performance in semi-automated tasks with varying complexities
- Authors: Hoyi, Zandile
- Date: 2017
- Subjects: Rest periods , Rest periods -- Physiological effect , Human-robot interaction , Aeronautics -- Human factors , Human engineering , Drowsiness
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/44490 , vital:25412
- Description: Automation in the aviation industry is acknowledged as a useful tool in reducing pilot workload (Hoh, Smith & Hinton, 1987; Beringer & Harris Jr., 1999). Typically, the role of the pilot (operator) shifts from active participation in a process to a task of monitoring the system with the resumption of control should the automation ‘fail’ (Byrne & Parasuraman, 1996). Unfortunately, the skills necessary to do so would likely degrade from non-use, during this process (Landry, 2012). This project investigates the “attentional demands” for the human operator during interaction with semi-automated operations of the flight. According to Dr Abbott (1996), FAA human factors specialist, one of the problems causing disharmony between crews and their automated systems is the incorrect upset recovery, owing to the human being out-of-the-loop (OOTL) from the system. Recovery, or rather return to task, is the ability of the pilot to loop back into control, once situational awareness has been decreased due to lack of alertness and a decrease in arousal. Different types of rest tasks are commonly prescribed fatigue countermeasures in the industrial setting and have been showed to elicit beneficial effects on prolonged human performance. Understanding the effects of different rest break activity and time out-of-the-loop during semi-automated flying on return to task performance has been adequately studied, thus highlighting its importance in the context of flight safety. The present study requested participants to perform a tracking task in a laboratory where they changed from activity (30 minutes) to a break (2 vs. 30 minutes) and back to the activity (20 minutes). The task varied in the complexity of the activity (pure tracking vs. tracking plus memory plus rule-based decision making), the type of break (passive rest vs. actively supervising) and the duration of the break (2 minutes vs. 30 minutes). Performance was measured as effective response time in the tracking task and number of correct responses to secondary cognitive tasks. Physiological measures included heart rate (HR), heart rate variability (HRV- time and frequency-domain), eye blink frequency and duration. The Karolinska Sleepiness Scale was used as a subjective measure. With regards to the most appropriate rest break tasks, the study concluded that active, administrative tasks, which allowed the operator to maintain some form of situational awareness by monitoring the automated system, achieved favourable effects of being more alert than the passive rest break of being disengaged from the system. In terms of the most appropriate rest break durations, the shorter duration of being out-of-the-loop from controlling the system proved to be more advantageous than the longer out-of-the-loop duration. In looking at the workload levels of arousal, the results suggest that the higher workload level is better at maintaining the alertness of operators. This study functions as a foundational framework for future investigations around the topic of human-automation interaction, looking specifically at return-to-task performance.
- Full Text:
- Authors: Hoyi, Zandile
- Date: 2017
- Subjects: Rest periods , Rest periods -- Physiological effect , Human-robot interaction , Aeronautics -- Human factors , Human engineering , Drowsiness
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/44490 , vital:25412
- Description: Automation in the aviation industry is acknowledged as a useful tool in reducing pilot workload (Hoh, Smith & Hinton, 1987; Beringer & Harris Jr., 1999). Typically, the role of the pilot (operator) shifts from active participation in a process to a task of monitoring the system with the resumption of control should the automation ‘fail’ (Byrne & Parasuraman, 1996). Unfortunately, the skills necessary to do so would likely degrade from non-use, during this process (Landry, 2012). This project investigates the “attentional demands” for the human operator during interaction with semi-automated operations of the flight. According to Dr Abbott (1996), FAA human factors specialist, one of the problems causing disharmony between crews and their automated systems is the incorrect upset recovery, owing to the human being out-of-the-loop (OOTL) from the system. Recovery, or rather return to task, is the ability of the pilot to loop back into control, once situational awareness has been decreased due to lack of alertness and a decrease in arousal. Different types of rest tasks are commonly prescribed fatigue countermeasures in the industrial setting and have been showed to elicit beneficial effects on prolonged human performance. Understanding the effects of different rest break activity and time out-of-the-loop during semi-automated flying on return to task performance has been adequately studied, thus highlighting its importance in the context of flight safety. The present study requested participants to perform a tracking task in a laboratory where they changed from activity (30 minutes) to a break (2 vs. 30 minutes) and back to the activity (20 minutes). The task varied in the complexity of the activity (pure tracking vs. tracking plus memory plus rule-based decision making), the type of break (passive rest vs. actively supervising) and the duration of the break (2 minutes vs. 30 minutes). Performance was measured as effective response time in the tracking task and number of correct responses to secondary cognitive tasks. Physiological measures included heart rate (HR), heart rate variability (HRV- time and frequency-domain), eye blink frequency and duration. The Karolinska Sleepiness Scale was used as a subjective measure. With regards to the most appropriate rest break tasks, the study concluded that active, administrative tasks, which allowed the operator to maintain some form of situational awareness by monitoring the automated system, achieved favourable effects of being more alert than the passive rest break of being disengaged from the system. In terms of the most appropriate rest break durations, the shorter duration of being out-of-the-loop from controlling the system proved to be more advantageous than the longer out-of-the-loop duration. In looking at the workload levels of arousal, the results suggest that the higher workload level is better at maintaining the alertness of operators. This study functions as a foundational framework for future investigations around the topic of human-automation interaction, looking specifically at return-to-task performance.
- Full Text:
The emergence and expression of teachers’ identities in teaching foundation phase mathematics
- Authors: Westaway, Lise
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/7000 , vital:21208
- Description: The assertion that learner performance in South African schools is in crisis may be cliched but it is certainly true. The majority of learners in the schooling system are not achieving the required outcomes, particularly in language and mathematics. I use the underperformance of learners in mathematics as the impetus for my research which seeks to understand how teachers’ identities emerge and are expressed in teaching Foundation Phase mathematics. The research contributes to an emerging scholarship that strives to explain underperformance and quality in mathematics classrooms beyond structuralist theorising. Recently research, particularly in South Africa, has begun to look more closely at who the teacher is and how the teacher is key in understanding what happens in the mathematics classroom. This emerging scholarship focuses on teacher identities. Research that foregrounds teacher identities within the field of mathematics education tends to be situated within a social constructionist orientation, which assumes that our knowledge of self and the world comes from our interactions with people and not some ‘objective’ reality (Berger & Luckman, 1966). Such a perspective appears to conflate questions of how we know something with what is. In other words, it elides structure and agency, thereby making research that seeks to examine the interplay between the two in the formation and expression of teachers’ identities, practically impossible. It is for this reason, as well as the need to move beyond the hermeneutic, that my research draws on Margaret Archer’s (1995, 1996, 2000) social realist framework. Social realism posits a relativist epistemology but a realist ontology. It is underpinned by the notion of a stratified reality with structural mechanisms giving rise to events in the world whether we experience them or not. It is only through the (inter)actions of persons that such mechanisms have the tendential power to constrain or enable the projects of persons. As such, my research seeks to identify the structural and agential mechanisms that give rise to teachers’ identities and how these identities are expressed in teaching Foundation Phase mathematics. In my research, teacher identity refers to the manner in which teachers express their social roles as teachers. In the research I use a case study methodology. I provide rich data on four isiXhosa teachers teaching in low socio-economic status schools. This data is gleaned through interviews and classroom based observations which were recorded as field notes and video transcripts. Analysis of the data occurs through the thought processes of abduction and retroduction (Danermark, Ekstrom, Jakobsen, & Karlsson, 2002). These thought process enable me to (re)describe and (re)contextualise the object of study. Through the process of asking transfactual questions I identify the structural, cultural and agential mechanisms giving rise to teachers’ identities and their expression in teaching foundation phase mathematics. There are three significant findings in my research. Firstly, research that attempts to understand the emergence and expression of teacher identities should consider their broad contextual realities. The historical, economic, social and political contexts in which the teachers are born and live, influences their sense of self, personal identities and social identities (teacher identities) and as such, influences their decision to become teachers and how they express their roles as teachers of Foundation Phase mathematics. Secondly, my research suggests that teachers’ mode of reflexivity is key to understanding the decisions that they make in the classroom and how they deal with the structures that condition the manner in which they express their roles as teachers. Thirdly, collective agency is necessary to bring about change in the way in which teachers express their roles in teaching Foundation Phase mathematics. My research produces new knowledge by examining the interplay of structure, culture and agency in the constitution of foundation phase teachers’ identities and their expression in teaching foundation phase mathematics. I use a social realist orientation to examine this interplay and provide an understanding of the mechanisms giving rise to the phenomenon under consideration. In this way I contribute to the extensive research on learner underperformance by focusing more explicitly on who the teacher is in the classroom.
- Full Text:
- Authors: Westaway, Lise
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/7000 , vital:21208
- Description: The assertion that learner performance in South African schools is in crisis may be cliched but it is certainly true. The majority of learners in the schooling system are not achieving the required outcomes, particularly in language and mathematics. I use the underperformance of learners in mathematics as the impetus for my research which seeks to understand how teachers’ identities emerge and are expressed in teaching Foundation Phase mathematics. The research contributes to an emerging scholarship that strives to explain underperformance and quality in mathematics classrooms beyond structuralist theorising. Recently research, particularly in South Africa, has begun to look more closely at who the teacher is and how the teacher is key in understanding what happens in the mathematics classroom. This emerging scholarship focuses on teacher identities. Research that foregrounds teacher identities within the field of mathematics education tends to be situated within a social constructionist orientation, which assumes that our knowledge of self and the world comes from our interactions with people and not some ‘objective’ reality (Berger & Luckman, 1966). Such a perspective appears to conflate questions of how we know something with what is. In other words, it elides structure and agency, thereby making research that seeks to examine the interplay between the two in the formation and expression of teachers’ identities, practically impossible. It is for this reason, as well as the need to move beyond the hermeneutic, that my research draws on Margaret Archer’s (1995, 1996, 2000) social realist framework. Social realism posits a relativist epistemology but a realist ontology. It is underpinned by the notion of a stratified reality with structural mechanisms giving rise to events in the world whether we experience them or not. It is only through the (inter)actions of persons that such mechanisms have the tendential power to constrain or enable the projects of persons. As such, my research seeks to identify the structural and agential mechanisms that give rise to teachers’ identities and how these identities are expressed in teaching Foundation Phase mathematics. In my research, teacher identity refers to the manner in which teachers express their social roles as teachers. In the research I use a case study methodology. I provide rich data on four isiXhosa teachers teaching in low socio-economic status schools. This data is gleaned through interviews and classroom based observations which were recorded as field notes and video transcripts. Analysis of the data occurs through the thought processes of abduction and retroduction (Danermark, Ekstrom, Jakobsen, & Karlsson, 2002). These thought process enable me to (re)describe and (re)contextualise the object of study. Through the process of asking transfactual questions I identify the structural, cultural and agential mechanisms giving rise to teachers’ identities and their expression in teaching foundation phase mathematics. There are three significant findings in my research. Firstly, research that attempts to understand the emergence and expression of teacher identities should consider their broad contextual realities. The historical, economic, social and political contexts in which the teachers are born and live, influences their sense of self, personal identities and social identities (teacher identities) and as such, influences their decision to become teachers and how they express their roles as teachers of Foundation Phase mathematics. Secondly, my research suggests that teachers’ mode of reflexivity is key to understanding the decisions that they make in the classroom and how they deal with the structures that condition the manner in which they express their roles as teachers. Thirdly, collective agency is necessary to bring about change in the way in which teachers express their roles in teaching Foundation Phase mathematics. My research produces new knowledge by examining the interplay of structure, culture and agency in the constitution of foundation phase teachers’ identities and their expression in teaching foundation phase mathematics. I use a social realist orientation to examine this interplay and provide an understanding of the mechanisms giving rise to the phenomenon under consideration. In this way I contribute to the extensive research on learner underperformance by focusing more explicitly on who the teacher is in the classroom.
- Full Text:
The emergence of youth protest music and arts as alternative media in Zimbabwe: a Gramscian analysis
- Authors: Kabwato, Chris
- Date: 2017
- Subjects: Protest songs -- Zimbabwe , Protest poetry -- Zimbabwe , Hip-hop -- Political aspects -- Zimbabwe , Radical theater -- Zimbabwe
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/51228 , vital:26072
- Description: The primary goal of the research is to examine the reasons for the emergence of - hip-hop-based youth protest music and satirical video comedy in Zimbabwe in a context where democratic and media practice has been restricted. The study examines the strategies and platforms that the young urban-based, musicians and cultural activists employ as they contest the meta-narrative of political nationalists who control the public mass media. The study recognises culture as a site of struggle and seeks to tease out the meaning of specific art forms (‘conscious’ hip-hop music and faux-news satire) in this very specific period of Zimbabwe’s history. The study proposes that the rise of these new forms of hip-hop based protest music, poetry and satirical comedy indicate how through the production and circulation of popular culture, ordinary Africans are able to debate pertinent issues that are marginalised by the official media channels. The study thus sees these artists as organic intellectuals who use alternative media to engage with different publics as they seek to counter hegemonic discourses.
- Full Text:
The emergence of youth protest music and arts as alternative media in Zimbabwe: a Gramscian analysis
- Authors: Kabwato, Chris
- Date: 2017
- Subjects: Protest songs -- Zimbabwe , Protest poetry -- Zimbabwe , Hip-hop -- Political aspects -- Zimbabwe , Radical theater -- Zimbabwe
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/51228 , vital:26072
- Description: The primary goal of the research is to examine the reasons for the emergence of - hip-hop-based youth protest music and satirical video comedy in Zimbabwe in a context where democratic and media practice has been restricted. The study examines the strategies and platforms that the young urban-based, musicians and cultural activists employ as they contest the meta-narrative of political nationalists who control the public mass media. The study recognises culture as a site of struggle and seeks to tease out the meaning of specific art forms (‘conscious’ hip-hop music and faux-news satire) in this very specific period of Zimbabwe’s history. The study proposes that the rise of these new forms of hip-hop based protest music, poetry and satirical comedy indicate how through the production and circulation of popular culture, ordinary Africans are able to debate pertinent issues that are marginalised by the official media channels. The study thus sees these artists as organic intellectuals who use alternative media to engage with different publics as they seek to counter hegemonic discourses.
- Full Text:
The epidemiology of African horse sickness in the Eastern Cape, South Africa
- Authors: Riddin, Megan Amy
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64460 , vital:28546
- Description: Expected release date-May 2019
- Full Text:
- Authors: Riddin, Megan Amy
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64460 , vital:28546
- Description: Expected release date-May 2019
- Full Text:
The Etendeka Igneous Province: magma types and their stratigraphic distribution with implications for the evolution of the Paraná-Etendeka flood basalt province
- Marsh, Julian S, Ewart, A, Milner, Simon C, Duncan, Andrew R, Miller, R McG
- Authors: Marsh, Julian S , Ewart, A , Milner, Simon C , Duncan, Andrew R , Miller, R McG
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/149762 , vital:38882 , https://doi.org/10.1007/s004450000115
- Description: Detailed geochemical and field data for the volcanic sequence and intrusions of the Etendeka Igneous Province are used to construct a stratigraphic framework for petrogenetic interpretation of the evolution of the Etendeka-Paraná continental flood volcanic event. Geochemical and petrographic characterization of over 1,000 analyzed samples allows 8 mafic and 17 silicic magma types to be recognized.
- Full Text: false
- Authors: Marsh, Julian S , Ewart, A , Milner, Simon C , Duncan, Andrew R , Miller, R McG
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/149762 , vital:38882 , https://doi.org/10.1007/s004450000115
- Description: Detailed geochemical and field data for the volcanic sequence and intrusions of the Etendeka Igneous Province are used to construct a stratigraphic framework for petrogenetic interpretation of the evolution of the Etendeka-Paraná continental flood volcanic event. Geochemical and petrographic characterization of over 1,000 analyzed samples allows 8 mafic and 17 silicic magma types to be recognized.
- Full Text: false
The evaluation and validation of copper (II) force field parameters of the Auxiliary Activity family 9 enzymes:
- Moses, Vuyani, Tastan Bishop, Özlem, Lobb, Kevin A
- Authors: Moses, Vuyani , Tastan Bishop, Özlem , Lobb, Kevin A
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148206 , vital:38719 , DOI: 10.1016/j.cplett.2017.04.022
- Description: The Auxiliary Activity family 9 (AA9) proteins are Cu2+ coordinating enzymes which are crucial for the early stages of cellulose degradation. In this study, the force field parameters for copper-containing bonds in the Type 1 AA9 protein active site were established and used in a molecular dynamics simulation on a solvated, neutralized system containing an AA9 protein, Cu2+ and a β-cellulose surface. The copper to cellulose interaction was evident during the dynamics, which could also be accelerated by the use of high Cu O van der Waals parameters. The interaction of AA9, Cu2+ and cellulose is described in detail.
- Full Text:
- Authors: Moses, Vuyani , Tastan Bishop, Özlem , Lobb, Kevin A
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148206 , vital:38719 , DOI: 10.1016/j.cplett.2017.04.022
- Description: The Auxiliary Activity family 9 (AA9) proteins are Cu2+ coordinating enzymes which are crucial for the early stages of cellulose degradation. In this study, the force field parameters for copper-containing bonds in the Type 1 AA9 protein active site were established and used in a molecular dynamics simulation on a solvated, neutralized system containing an AA9 protein, Cu2+ and a β-cellulose surface. The copper to cellulose interaction was evident during the dynamics, which could also be accelerated by the use of high Cu O van der Waals parameters. The interaction of AA9, Cu2+ and cellulose is described in detail.
- Full Text:
The FOXP2 forkhead domain binds to a variety of DNA sequences with different rates and affinities
- Webb, Helen, Steeb, Olga, Blane, Ashleigh, Rotherham, Lia, Aron, Shaun, Machanick, Philip, Dirr, Heini, Fanucchi, Sylvia
- Authors: Webb, Helen , Steeb, Olga , Blane, Ashleigh , Rotherham, Lia , Aron, Shaun , Machanick, Philip , Dirr, Heini , Fanucchi, Sylvia
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/439326 , vital:73567 , https://doi.org/10.1093/jb/mvx003
- Description: FOXP2 is a member of the P subfamily of FOX transcription factors, the DNA-binding domain of which is the winged helix forkhead domain (FHD). In this work we show that the FOXP2 FHD is able to bind to various DNA sequences, including a novel sequence identified in this work, with different affinities and rates as detected using surface plasmon resonance. Combining the experimental work with molecular docking, we show that high-affinity sequences remain bound to the protein for longer, form a greater number of interactions with the protein and induce a greater structural change in the protein than low-affinity sequences. We propose a binding model for the FOXP2 FHD that involves three types of binding sequence: low affinity sites which allow for rapid scanning of the genome by the protein in a partially unstructured state; moderate affinity sites which serve to locate the protein near target sites and high-affinity sites which secure the protein to the DNA and induce a conformational change necessary for functional binding and the possible initiation of downstream transcriptional events.
- Full Text:
- Authors: Webb, Helen , Steeb, Olga , Blane, Ashleigh , Rotherham, Lia , Aron, Shaun , Machanick, Philip , Dirr, Heini , Fanucchi, Sylvia
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/439326 , vital:73567 , https://doi.org/10.1093/jb/mvx003
- Description: FOXP2 is a member of the P subfamily of FOX transcription factors, the DNA-binding domain of which is the winged helix forkhead domain (FHD). In this work we show that the FOXP2 FHD is able to bind to various DNA sequences, including a novel sequence identified in this work, with different affinities and rates as detected using surface plasmon resonance. Combining the experimental work with molecular docking, we show that high-affinity sequences remain bound to the protein for longer, form a greater number of interactions with the protein and induce a greater structural change in the protein than low-affinity sequences. We propose a binding model for the FOXP2 FHD that involves three types of binding sequence: low affinity sites which allow for rapid scanning of the genome by the protein in a partially unstructured state; moderate affinity sites which serve to locate the protein near target sites and high-affinity sites which secure the protein to the DNA and induce a conformational change necessary for functional binding and the possible initiation of downstream transcriptional events.
- Full Text:
The global distribution and diversity of protein vaccine candidate antigens in the highly virulent Streptococcus pnuemoniae serotype:
- Cornick, Jennifer E, Tastan Bishop, Özlem, Yalcin, Feyruz, Kiran, Anmol M, Kumwenda, Benjamin, Chaguza, Chrispin, Govindpershad, Shanil, Ousmane, Sani, Senghore, Madikay, du Plessis, Mignon, Pluschke, Gerd, 1952-, Ebruke, Chinelo, McGee, Lesley, Sigaùque , Beutel, Collard, Jean-Marc, Bentley, Stephen D, Kadioglu , Aras, Antonio, Martin, von Gottberg, Anne, French, Neil, Klugman, Keith P, Heyderman, Robert S, Alderson, Mark, Everett, Dean B
- Authors: Cornick, Jennifer E , Tastan Bishop, Özlem , Yalcin, Feyruz , Kiran, Anmol M , Kumwenda, Benjamin , Chaguza, Chrispin , Govindpershad, Shanil , Ousmane, Sani , Senghore, Madikay , du Plessis, Mignon , Pluschke, Gerd, 1952- , Ebruke, Chinelo , McGee, Lesley , Sigaùque , Beutel , Collard, Jean-Marc , Bentley, Stephen D , Kadioglu , Aras , Antonio, Martin , von Gottberg, Anne , French, Neil , Klugman, Keith P , Heyderman, Robert S , Alderson, Mark , Everett, Dean B
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148318 , vital:38729 , DOI: 10.1016/j.vaccine.2016.12.037
- Description: Serotype 1 is one of the most common causes of pneumococcal disease worldwide. Pneumococcal protein vaccines are currently being developed as an alternate intervention strategy to pneumococcal conjugate vaccines. Pre-requisites for an efficacious pneumococcal protein vaccine are universal presence and minimal variation of the target antigen in the pneumococcal population, and the capability to induce a robust human immune response. We used in silico analysis to assess the prevalence of seven protein vaccine candidates (CbpA, PcpA, PhtD, PspA, SP0148, SP1912, SP2108) among 445 serotype 1 pneumococci from 26 different countries, across four continents. CbpA (76%), PspA (68%), PhtD (28%), PcpA (11%) were not universally encoded in the study population, and would not provide full coverage against serotype 1.
- Full Text:
- Authors: Cornick, Jennifer E , Tastan Bishop, Özlem , Yalcin, Feyruz , Kiran, Anmol M , Kumwenda, Benjamin , Chaguza, Chrispin , Govindpershad, Shanil , Ousmane, Sani , Senghore, Madikay , du Plessis, Mignon , Pluschke, Gerd, 1952- , Ebruke, Chinelo , McGee, Lesley , Sigaùque , Beutel , Collard, Jean-Marc , Bentley, Stephen D , Kadioglu , Aras , Antonio, Martin , von Gottberg, Anne , French, Neil , Klugman, Keith P , Heyderman, Robert S , Alderson, Mark , Everett, Dean B
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148318 , vital:38729 , DOI: 10.1016/j.vaccine.2016.12.037
- Description: Serotype 1 is one of the most common causes of pneumococcal disease worldwide. Pneumococcal protein vaccines are currently being developed as an alternate intervention strategy to pneumococcal conjugate vaccines. Pre-requisites for an efficacious pneumococcal protein vaccine are universal presence and minimal variation of the target antigen in the pneumococcal population, and the capability to induce a robust human immune response. We used in silico analysis to assess the prevalence of seven protein vaccine candidates (CbpA, PcpA, PhtD, PspA, SP0148, SP1912, SP2108) among 445 serotype 1 pneumococci from 26 different countries, across four continents. CbpA (76%), PspA (68%), PhtD (28%), PcpA (11%) were not universally encoded in the study population, and would not provide full coverage against serotype 1.
- Full Text:
The identification of key vulnerability components within Solomon Islands coastal communities
- Authors: Malherbe, Willem Stefanus
- Date: 2017
- Subjects: Solomon Islands -- Environmental conditions , Coastal ecology -- Solomon Islands , Island ecology -- Solomon Islands , Climatic changes -- Solomon Islands , Sociology, Urban -- Solomon Islands , Sociology, Rural -- Solomon Islands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21184 , http://hdl.handle.net/10962/6827
- Description: The impacts of climate change are disproportionally felt across the planet, with small island developing states some of the countries most at risk. Furthermore, climate change may compound existing problems such as over harvested resources, leading to knock-on effects on national economies. Both direct and indirect stressors may impact communities differently based on their level of exposure to stressors, their intrinsic sensitivity to these stressors, and their ability to adapt to stressors. This study aims to answer the primary research question: Why are some communities more vulnerable than others? A vulnerability assessment is used to identify both vulnerable and non-vulnerable attributes of Solomon Islands’ communities. Surveys comprised a comprehensive questionnaire to draw inference on each vulnerability category; sensitivity, exposure and adaptive capacity, along with their various components and subcomponents. An analysis of household and community livelihood strategies was conducted to compliment vulnerability scores and provide a deeper understanding of livelihood practises. As is expected of small island states, exposure presents the biggest threat to coastal communities. Within this category, environmental changes and personal exposure from shoreline erosion and safety at sea provide evidence of high vulnerability. Within the sensitivity category, the cultural importance of fishing, as well as attachment to place and fishing, renders communities more vulnerable. Simultaneously, local ecological knowledge and economic dependence on resources other than fishing proved to be resilient attributes by decreasing vulnerability. Low vulnerability scores for the adaptive capacity category were achieved by communities where physical capital, such as community infrastructure, was evident. A lack of both institutional support and bridging of social capital were attributes which contributed to community vulnerability. This study has identified key attributes that have both positive and negative effects on the vulnerability of Solomon Islands communities. Having done this, I have also attempted to determine the drivers that render some attributes more vulnerable than others. It is acknowledged that the drivers of all key attributes of vulnerability is required to determine areas where adaptation plans will be most effective. Importantly, drivers of high vulnerability should not be considered as the primary focus of adaptation planning, but also the drivers of low vulnerability, such as community cohesion, which provide resilience within communities.
- Full Text:
- Authors: Malherbe, Willem Stefanus
- Date: 2017
- Subjects: Solomon Islands -- Environmental conditions , Coastal ecology -- Solomon Islands , Island ecology -- Solomon Islands , Climatic changes -- Solomon Islands , Sociology, Urban -- Solomon Islands , Sociology, Rural -- Solomon Islands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:21184 , http://hdl.handle.net/10962/6827
- Description: The impacts of climate change are disproportionally felt across the planet, with small island developing states some of the countries most at risk. Furthermore, climate change may compound existing problems such as over harvested resources, leading to knock-on effects on national economies. Both direct and indirect stressors may impact communities differently based on their level of exposure to stressors, their intrinsic sensitivity to these stressors, and their ability to adapt to stressors. This study aims to answer the primary research question: Why are some communities more vulnerable than others? A vulnerability assessment is used to identify both vulnerable and non-vulnerable attributes of Solomon Islands’ communities. Surveys comprised a comprehensive questionnaire to draw inference on each vulnerability category; sensitivity, exposure and adaptive capacity, along with their various components and subcomponents. An analysis of household and community livelihood strategies was conducted to compliment vulnerability scores and provide a deeper understanding of livelihood practises. As is expected of small island states, exposure presents the biggest threat to coastal communities. Within this category, environmental changes and personal exposure from shoreline erosion and safety at sea provide evidence of high vulnerability. Within the sensitivity category, the cultural importance of fishing, as well as attachment to place and fishing, renders communities more vulnerable. Simultaneously, local ecological knowledge and economic dependence on resources other than fishing proved to be resilient attributes by decreasing vulnerability. Low vulnerability scores for the adaptive capacity category were achieved by communities where physical capital, such as community infrastructure, was evident. A lack of both institutional support and bridging of social capital were attributes which contributed to community vulnerability. This study has identified key attributes that have both positive and negative effects on the vulnerability of Solomon Islands communities. Having done this, I have also attempted to determine the drivers that render some attributes more vulnerable than others. It is acknowledged that the drivers of all key attributes of vulnerability is required to determine areas where adaptation plans will be most effective. Importantly, drivers of high vulnerability should not be considered as the primary focus of adaptation planning, but also the drivers of low vulnerability, such as community cohesion, which provide resilience within communities.
- Full Text:
The illegal diamond trade in South Africa and its tax consequences
- Authors: Kumm-Schmidt, Megan
- Date: 2017
- Subjects: Diamond industry and trade -- South Africa , Diamond industry and trade -- Corrupt practices -- South Africa , Diamond industry and trade -- South Africa -- Taxation , Conflict diamonds -- South Africa , Income tax -- Law and legislation -- South Africa , Tax evasion -- South Africa , South Africa. Income Tax Act, 1962 , South Africa. Prevention and Combating of Corrupt Activities Act, 2004 , South Africa. Tax Administration Act, 2011 , South Africa. ǂt Value-Added Tax Act, 1991 , Kimberley Process Certification Scheme
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/4389 , vital:20656
- Description: The object of the research was to discuss the taxability of the illegal diamond trade in South Africa and to identify the consequences of not declaring income obtained from the illegal diamond trade to the South African Revenue Services. The research was conducted by means of a critical analysis of documentary data with specific reference to the Income Tax Act, the Value-Added Tax (VAT) Act, the Tax Administration Act and relevant case law. The Income Tax Act and the Value-Added Tax Act were referred to in relation to the tax consequences of the illegal diamond trade and the Tax Administration Act was used to determine the consequences of not declaring income to the South African Revenue Services. It was established that amounts received from the sale of illegal diamonds are to be included in the taxpayer's gross income, whilst in relation to income received from diamond theft it was not as clear. The MP Finance Group case held that the nature of the receipt and the way in which the transaction occurred in each individual situation will be the deciding factor as to whether or not the stolen diamonds will be taxable in the hands of the thief. The buying and selling of "blood" or stolen diamonds can amount to a trade. As there have been no definitive case decisions in South Africa, it remains unclear whether expenses relating to an illegal trade are deductible. Assuming that expenses relating to an illegal trade are deductible, the provisions of section 11(a) will apply to expenses incurred as a result of dealing in illegal diamonds and it was concluded that qualifying expenses will be deductible. A taxpayer buying and selling "blood" or stolen diamonds is required to register for VAT if sales exceed the threshold and would be required to account for VAT on these transactions. If the taxpayer does not declare the income for income tax purposes or register for and pay VAT to the South African Revenue Services from either the sale of illegal diamonds or the theft of diamonds, this will amount to tax evasion and the dealer will be subject to penalties and even imprisonment
- Full Text:
- Authors: Kumm-Schmidt, Megan
- Date: 2017
- Subjects: Diamond industry and trade -- South Africa , Diamond industry and trade -- Corrupt practices -- South Africa , Diamond industry and trade -- South Africa -- Taxation , Conflict diamonds -- South Africa , Income tax -- Law and legislation -- South Africa , Tax evasion -- South Africa , South Africa. Income Tax Act, 1962 , South Africa. Prevention and Combating of Corrupt Activities Act, 2004 , South Africa. Tax Administration Act, 2011 , South Africa. ǂt Value-Added Tax Act, 1991 , Kimberley Process Certification Scheme
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/4389 , vital:20656
- Description: The object of the research was to discuss the taxability of the illegal diamond trade in South Africa and to identify the consequences of not declaring income obtained from the illegal diamond trade to the South African Revenue Services. The research was conducted by means of a critical analysis of documentary data with specific reference to the Income Tax Act, the Value-Added Tax (VAT) Act, the Tax Administration Act and relevant case law. The Income Tax Act and the Value-Added Tax Act were referred to in relation to the tax consequences of the illegal diamond trade and the Tax Administration Act was used to determine the consequences of not declaring income to the South African Revenue Services. It was established that amounts received from the sale of illegal diamonds are to be included in the taxpayer's gross income, whilst in relation to income received from diamond theft it was not as clear. The MP Finance Group case held that the nature of the receipt and the way in which the transaction occurred in each individual situation will be the deciding factor as to whether or not the stolen diamonds will be taxable in the hands of the thief. The buying and selling of "blood" or stolen diamonds can amount to a trade. As there have been no definitive case decisions in South Africa, it remains unclear whether expenses relating to an illegal trade are deductible. Assuming that expenses relating to an illegal trade are deductible, the provisions of section 11(a) will apply to expenses incurred as a result of dealing in illegal diamonds and it was concluded that qualifying expenses will be deductible. A taxpayer buying and selling "blood" or stolen diamonds is required to register for VAT if sales exceed the threshold and would be required to account for VAT on these transactions. If the taxpayer does not declare the income for income tax purposes or register for and pay VAT to the South African Revenue Services from either the sale of illegal diamonds or the theft of diamonds, this will amount to tax evasion and the dealer will be subject to penalties and even imprisonment
- Full Text:
The impact of good news and bad news on South Africa’s sectoral stock return volatility: an asymmetric GARCH analysis
- Authors: Muzinda, Edmond Toreva
- Date: 2017
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/6425 , vital:21108
- Description: This study explores the impact of good news and bad news on South Africa’s sectoral stock return volatility using an asymmetric GARCH analysis. Understanding the different impact of news on stock return volatility in different economic sectors has important implications for investors’ risk management practices, portfolio allocation strategies and asset pricing. The study employs data of daily closing prices for nine sectors and three benchmark indices for the period 2nd January 1997 - 17th August 2016. The data was split into sub-samples of pre-, during and post-global financial crisis, as well as the overall sample period. The incorporation of sub-samples was to help explain the outcomes of the overall sample period. To capture the different impact of good news and bad news on stock return volatility for each sector, asymmetric GARCH models namely, TGARCH and EGARCH were employed. The findings from this study revealed that volatility asymmetry was present in all sectors and benchmark indices of South African equity market. Bad news had more impact on stock return volatility for all sectors except the Oil and Gas sector, than good news of the same magnitude. In the Oil and Gas sector, good news was found to have an amplified effect on return volatility compared with bad news of the same magnitude. High volatility persistence was also found to be present in the Consumer goods, Financials, Industrials, All-share index and Mid-cap index. High differential impact of good and bad news were found in the Industrials, Financials, Basic materials, Consumer goods and the All-share index. Since the main objective of this study was to provide explanations of volatility asymmetry found in the South African sectors, the following were proposed as possible explanations of the findings. Within sectors, volatility asymmetry was explained by financial leverage, the role of the media, loss-averse investors and the behaviour of traders (overconfidence and extrapolation bias). Volatility asymmetry across sectors was explained by information flow, the uneven distribution of information by the media, investor sentiments, investor expectations and trading volumes. Overall, the results indicate that the stock return volatility of individual sectors of the South African equity market is driven mainly by bad news (except for Oil and Gas) and that leverage effects exist in all the sectors and in the benchmark indices.
- Full Text:
- Authors: Muzinda, Edmond Toreva
- Date: 2017
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/6425 , vital:21108
- Description: This study explores the impact of good news and bad news on South Africa’s sectoral stock return volatility using an asymmetric GARCH analysis. Understanding the different impact of news on stock return volatility in different economic sectors has important implications for investors’ risk management practices, portfolio allocation strategies and asset pricing. The study employs data of daily closing prices for nine sectors and three benchmark indices for the period 2nd January 1997 - 17th August 2016. The data was split into sub-samples of pre-, during and post-global financial crisis, as well as the overall sample period. The incorporation of sub-samples was to help explain the outcomes of the overall sample period. To capture the different impact of good news and bad news on stock return volatility for each sector, asymmetric GARCH models namely, TGARCH and EGARCH were employed. The findings from this study revealed that volatility asymmetry was present in all sectors and benchmark indices of South African equity market. Bad news had more impact on stock return volatility for all sectors except the Oil and Gas sector, than good news of the same magnitude. In the Oil and Gas sector, good news was found to have an amplified effect on return volatility compared with bad news of the same magnitude. High volatility persistence was also found to be present in the Consumer goods, Financials, Industrials, All-share index and Mid-cap index. High differential impact of good and bad news were found in the Industrials, Financials, Basic materials, Consumer goods and the All-share index. Since the main objective of this study was to provide explanations of volatility asymmetry found in the South African sectors, the following were proposed as possible explanations of the findings. Within sectors, volatility asymmetry was explained by financial leverage, the role of the media, loss-averse investors and the behaviour of traders (overconfidence and extrapolation bias). Volatility asymmetry across sectors was explained by information flow, the uneven distribution of information by the media, investor sentiments, investor expectations and trading volumes. Overall, the results indicate that the stock return volatility of individual sectors of the South African equity market is driven mainly by bad news (except for Oil and Gas) and that leverage effects exist in all the sectors and in the benchmark indices.
- Full Text:
The influence of dose on the kinetic parameters and dosimetric features of the main thermoluminescence glow peak in α-Al2O3: C, Mg
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119834 , vital:34787 , https://doi.org/10.1016/j.nimb.2016.12.027
- Description: The influence of dose (0.1–100 Gy) on the kinetic parameters and the dosimetric features of the main glow peak of α-Al2O3:C,Mg have been investigated. Thermoluminescence (TL) measured at 1 °C/s shows a very high intensity glow peak at 161 °C and six secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. Analysis shows that the main peak follows first order kinetics irrespective of the irradiation dose. The activation energy is found to be consistent at 1.37 eV and the frequency factor is of the order of 1014 s−1 for any dose between 0.1 and 100 Gy. Further, the analysis for thermal quenching of the main peak of 0.1 Gy irradiated sample shows that the activation energy for thermal quenching is (0.94 ± 0.04) eV.
- Full Text: false
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119834 , vital:34787 , https://doi.org/10.1016/j.nimb.2016.12.027
- Description: The influence of dose (0.1–100 Gy) on the kinetic parameters and the dosimetric features of the main glow peak of α-Al2O3:C,Mg have been investigated. Thermoluminescence (TL) measured at 1 °C/s shows a very high intensity glow peak at 161 °C and six secondary peaks at 42, 72, 193, 279, 330, 370 °C respectively. Analysis shows that the main peak follows first order kinetics irrespective of the irradiation dose. The activation energy is found to be consistent at 1.37 eV and the frequency factor is of the order of 1014 s−1 for any dose between 0.1 and 100 Gy. Further, the analysis for thermal quenching of the main peak of 0.1 Gy irradiated sample shows that the activation energy for thermal quenching is (0.94 ± 0.04) eV.
- Full Text: false
The influence of environmental variability on the catch of chokka, Loligo reynaudii, off the coast of South Africa
- Authors: Joyner, Jessica Mary
- Date: 2017
- Subjects: Loligo reynaudii , Loligo fisheries -- South Africa , Squid fisheries -- South Africa , Loligo fisheries -- Environmental aspects -- South Africa , Squid fisheries -- Environmental aspects - South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/32130 , vital:24013
- Description: Globally, cephalopod fisheries are being relied on more heavily due to the depletion of longer-lived teleost species. The South African chokka squid (Loligo reynaudii) fishery is a case in point. Although previously numerous squid were often caught as bycatch, the fishery has officially been in place since 1985. Since the inception of the chokka fishery in South Africa, several studies have investigated the relationship between environmental drivers and annual chokka squid catch, with varying degrees of success. Recently, in 2013, chokka squid catches hit a record low, prompting resurgence in the topic of the squid environment-catch relationship. This study was initiated in an attempt to provide a quantitative relationship between the chokka squid catch and environmental variability, and to build a predictive model that could be used in fisheries management strategies. Historical data were obtained from various sources and included the mean and standard deviation in ocean bottom temperature; the mean and standard deviation in sea surface temperature; the maximum and minimum as well as the variation in wind speed; the mean, predominant and standard deviation in wind direction; the mean and standard deviation in atmospheric pressure; the mean chlorophyll concentration; the number of upwelling events; the hours of easterly winds blowing per day; and two large variation-in-climate indices, namely, the oceanic Nino index and the Antarctic Oscillation index. The monthly catch data were also provided. These data were initially analysed for inter-annual and intra-annual cyclic trends and followed by analysis of the delay in response of catch to the environmental variables, anticipating some impact on the different stages of the chokka life cycle. These lagged data were incorporated into a negative binomial generalised linear model, as well as a generalised additive model, which revealed a strong relationship (r²=0.707) between the catch and environmental variability. The inclusion of all the parameters was necessary; however, the mean bottom temperature and the standard deviation in sea surface temperature were the only parameters that had a significant effect on the catch. These results were used to build a predictive model that indicated that, although the relationship was strong, the ability of the model to predict catch was weak, particularly from the year 2005 onwards.
- Full Text:
- Authors: Joyner, Jessica Mary
- Date: 2017
- Subjects: Loligo reynaudii , Loligo fisheries -- South Africa , Squid fisheries -- South Africa , Loligo fisheries -- Environmental aspects -- South Africa , Squid fisheries -- Environmental aspects - South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/32130 , vital:24013
- Description: Globally, cephalopod fisheries are being relied on more heavily due to the depletion of longer-lived teleost species. The South African chokka squid (Loligo reynaudii) fishery is a case in point. Although previously numerous squid were often caught as bycatch, the fishery has officially been in place since 1985. Since the inception of the chokka fishery in South Africa, several studies have investigated the relationship between environmental drivers and annual chokka squid catch, with varying degrees of success. Recently, in 2013, chokka squid catches hit a record low, prompting resurgence in the topic of the squid environment-catch relationship. This study was initiated in an attempt to provide a quantitative relationship between the chokka squid catch and environmental variability, and to build a predictive model that could be used in fisheries management strategies. Historical data were obtained from various sources and included the mean and standard deviation in ocean bottom temperature; the mean and standard deviation in sea surface temperature; the maximum and minimum as well as the variation in wind speed; the mean, predominant and standard deviation in wind direction; the mean and standard deviation in atmospheric pressure; the mean chlorophyll concentration; the number of upwelling events; the hours of easterly winds blowing per day; and two large variation-in-climate indices, namely, the oceanic Nino index and the Antarctic Oscillation index. The monthly catch data were also provided. These data were initially analysed for inter-annual and intra-annual cyclic trends and followed by analysis of the delay in response of catch to the environmental variables, anticipating some impact on the different stages of the chokka life cycle. These lagged data were incorporated into a negative binomial generalised linear model, as well as a generalised additive model, which revealed a strong relationship (r²=0.707) between the catch and environmental variability. The inclusion of all the parameters was necessary; however, the mean bottom temperature and the standard deviation in sea surface temperature were the only parameters that had a significant effect on the catch. These results were used to build a predictive model that indicated that, although the relationship was strong, the ability of the model to predict catch was weak, particularly from the year 2005 onwards.
- Full Text:
The influence of radiation-induced defects on thermoluminescence and optically stimulated luminescence of α-Al2O3: C
- Nyirenda, Angel N, Chithambo, Makaiko L
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119818 , vital:34786 , https://doi.org/10.1016/j.nimb.2017.02.077
- Description: It is known that when α-Al2O3:C is exposed to excessive amounts of ionising radiation, defects are induced within its matrix. We report the influence of radiation-induced defects on the thermoluminescence (TL) and optically stimulated luminescence (OSL) measured from α-Al2O3:C after irradiation to 1000 Gy. These radiation-induced defects are thermally unstable in the region 450–650 °C and result in TL peaks in this range when the TL is measured at 1 °C/s. Heating a sample to 700 °C obliterates the radiation-induced defects, that is, the TL peaks corresponding to the radiation induced defects are no longer observed in the subsequent TL measurements when moderate irradiation doses below 10 Gy are used. The charge traps associated with these radiation-induced defects are more stable than the dosimetric trap when the sample is exposed to either sunlight or 470-nm blue light from LEDs. TL glow curves measured following the defect-inducing irradiation produce a dosimetric peak that is broader and positioned at a higher temperature than observed in glow curves obtained before the heavy irradiation. In addition, sample sensitization/desensitization occurs due to the presence of these radiation-induced defects. Furthermore, both the activation energy and the kinetic order of the dosimetric peak evaluated when the radiation-induced defects are present in the sample are significantly lower in value than those obtained when these defects are absent. The radiation-induced defects also affect the shape and total light sum of the OSL signal as well as the position and width of the resultant residual phototransferred thermoluminescence main peak.
- Full Text: false
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/119818 , vital:34786 , https://doi.org/10.1016/j.nimb.2017.02.077
- Description: It is known that when α-Al2O3:C is exposed to excessive amounts of ionising radiation, defects are induced within its matrix. We report the influence of radiation-induced defects on the thermoluminescence (TL) and optically stimulated luminescence (OSL) measured from α-Al2O3:C after irradiation to 1000 Gy. These radiation-induced defects are thermally unstable in the region 450–650 °C and result in TL peaks in this range when the TL is measured at 1 °C/s. Heating a sample to 700 °C obliterates the radiation-induced defects, that is, the TL peaks corresponding to the radiation induced defects are no longer observed in the subsequent TL measurements when moderate irradiation doses below 10 Gy are used. The charge traps associated with these radiation-induced defects are more stable than the dosimetric trap when the sample is exposed to either sunlight or 470-nm blue light from LEDs. TL glow curves measured following the defect-inducing irradiation produce a dosimetric peak that is broader and positioned at a higher temperature than observed in glow curves obtained before the heavy irradiation. In addition, sample sensitization/desensitization occurs due to the presence of these radiation-induced defects. Furthermore, both the activation energy and the kinetic order of the dosimetric peak evaluated when the radiation-induced defects are present in the sample are significantly lower in value than those obtained when these defects are absent. The radiation-induced defects also affect the shape and total light sum of the OSL signal as well as the position and width of the resultant residual phototransferred thermoluminescence main peak.
- Full Text: false
The interaction of selected bacteria with tailored electrospun fibres: towards future applications in bioremediation, bacterial inactivation and electricity generation
- Authors: Mfuku, Aphiwe
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/65123 , vital:28693
- Description: Expected release date-May 2019
- Full Text:
- Authors: Mfuku, Aphiwe
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/65123 , vital:28693
- Description: Expected release date-May 2019
- Full Text:
The isolation and genetic characterisation of a novel alphabaculovirus for the microbial control of Cryptophlebia peltastica and closely related tortricid pests
- Authors: Marsberg, Tamryn
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/59292 , vital:27543
- Description: Cryptophlebia peltastica (Meyrick) (Lepidoptera: Tortricidae) is an economically damaging pest of litchis and macadamias in South Africa. Cryptophlebia peltastica causes both pre- and post-harvest damage to litchis, reducing overall yields and thus classifying the pest as a phytosanitary risk. Various control methods have been implemented against C. peltastica in an integrated pest management programme. These control methods include chemical control, cultural control and biological control. However, these methods have not yet provided satisfactory control as of yet. As a result, an alternative control option needs to be identified and implemented into the IPM programme. An alternative method of control that has proved successful in other agricultural sectors and not yet implemented in the control of C. peltastica is that of microbial control, specifically the use of baculovirus biopesticides. This study aimed to isolate and characterise a novel baculovirus from a laboratory culture of C. peltastica that could be used as a commercially available baculovirus biopesticide. In order to isolate a baculovirus a laboratory culture of C. peltastica was successfully established at Rhodes University, Grahamstown, South Africa. This is the first time a laboratory culture of C. peltastica has been established. This allowed for various biological aspects of the pest to be determined, which included: length of the life cycle, fecundity and time to oviposition, egg and larval development and percentage hatch. The results obtained from these studies found that the biology of C. peltastica was similar to that of Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae). Once the laboratory culture had reached high densities, larvae showing symptoms of baculovirus infection were observed. Symptomatic larvae were collected and examined for the presence of a baculovirus. An alphabaculovirus (NPV) was successfully isolated and morphologically identified using purified OBs that were sectioned and observed by transmission electron microscopy. This was then confirmed by amplifying the polyhedrin gene region using degenerate primers. A BLAST analysis found a 93% similarity to a partial polyhedrin gene sequence to be that of Epinotia granitalis (Butler) (Lepidoptera: Tortricidae). The alphabaculovirus was then genetically characterised by generating restriction profiles and sequencing the whole genome. Due to the novelty of the virus, no comparison could be made. The biological activity of the alphabaculovirus was then tested against C. peltastica and two closely related Tortricidae pests: T. leucotreta and Cydiapomonella (Linnaeous) (Lepidoptera: Tortricidae). The alphabaculovirus was highly virulent against all three species. The lethal concentrations (LC50 and LC90) for the virus against C. peltastica was 8.19 x 103 and 3.33 x 105 OBs/ml. The LC50 and LC90 for T. leucotreta was 2.29 x 103 and 9.97 x 104 OBs/ml, respectively and C. pomonella had a LC50 of 1.43 x 103 OBs/ml and LC90 1.26 x 104 OBs/ml. The virus was particularly virulent against T. leucotreta and C. pomonella as compared to C. peltastica. The biological activity of the alphabaculovirus was also tested against CpGV resistant European C. pomonella. From the results it was observed that the virus had the ability to overcome the resistance in C. pomonella and could potentially be used in the resistance management of C. pomonella. With the successful biological activity results obtained from this study, preliminary investigation were made into the mass production of the alphabaculovirus using both the in vivo and in vitro production methods. For in vivo production both the homologous host (C. peltastica) and a heterologous host (T leucotreta) were investigated. Preliminary studies focused on determining the biological activity in fifth instars of both hosts. Fifth instar LC50 and LC90 values for C. peltastica were 3.43 x 103 and 1.11 x 107 OBs/ml and for T. leucotreta the LC50 and LC90 values were 2.53 x 103 and 8.82 x 106 OBs/ml, respectively. The average yield of virus produced in each species was also determined. Cryptophlebia peltastica had the highest viral yield of 5.37 x 1010 OBs/larva and 2.93 x 1010 OBs/larva for T. leucotreta. The results obtained, from the preliminary investigation concluded that the virus could be produced in vivo in both C. peltastica and T. leucotreta, however further research is required into the mass production in both hosts. The in vitro production of the virus was also considered and the susceptibility of the virus was tested against the C. pomonella cell line, Cp14R. After infection of the Cp14R cells with budded virus collected from fifth instar C. peltastica larvae, OBs could be observed after three days. Thus, the alphabaculovirus is susceptible to the Cp14R cell line, thus has the potential to be produced in vitro and further characterised. This study is the first to report of the identification and characterisation of a novel alphabaculovirus isolated from a laboratory reared culture of C. peltastica and the potential for it to be commercially developed into a bipoesticide and used against Tortricidae pests.
- Full Text:
- Authors: Marsberg, Tamryn
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/59292 , vital:27543
- Description: Cryptophlebia peltastica (Meyrick) (Lepidoptera: Tortricidae) is an economically damaging pest of litchis and macadamias in South Africa. Cryptophlebia peltastica causes both pre- and post-harvest damage to litchis, reducing overall yields and thus classifying the pest as a phytosanitary risk. Various control methods have been implemented against C. peltastica in an integrated pest management programme. These control methods include chemical control, cultural control and biological control. However, these methods have not yet provided satisfactory control as of yet. As a result, an alternative control option needs to be identified and implemented into the IPM programme. An alternative method of control that has proved successful in other agricultural sectors and not yet implemented in the control of C. peltastica is that of microbial control, specifically the use of baculovirus biopesticides. This study aimed to isolate and characterise a novel baculovirus from a laboratory culture of C. peltastica that could be used as a commercially available baculovirus biopesticide. In order to isolate a baculovirus a laboratory culture of C. peltastica was successfully established at Rhodes University, Grahamstown, South Africa. This is the first time a laboratory culture of C. peltastica has been established. This allowed for various biological aspects of the pest to be determined, which included: length of the life cycle, fecundity and time to oviposition, egg and larval development and percentage hatch. The results obtained from these studies found that the biology of C. peltastica was similar to that of Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae). Once the laboratory culture had reached high densities, larvae showing symptoms of baculovirus infection were observed. Symptomatic larvae were collected and examined for the presence of a baculovirus. An alphabaculovirus (NPV) was successfully isolated and morphologically identified using purified OBs that were sectioned and observed by transmission electron microscopy. This was then confirmed by amplifying the polyhedrin gene region using degenerate primers. A BLAST analysis found a 93% similarity to a partial polyhedrin gene sequence to be that of Epinotia granitalis (Butler) (Lepidoptera: Tortricidae). The alphabaculovirus was then genetically characterised by generating restriction profiles and sequencing the whole genome. Due to the novelty of the virus, no comparison could be made. The biological activity of the alphabaculovirus was then tested against C. peltastica and two closely related Tortricidae pests: T. leucotreta and Cydiapomonella (Linnaeous) (Lepidoptera: Tortricidae). The alphabaculovirus was highly virulent against all three species. The lethal concentrations (LC50 and LC90) for the virus against C. peltastica was 8.19 x 103 and 3.33 x 105 OBs/ml. The LC50 and LC90 for T. leucotreta was 2.29 x 103 and 9.97 x 104 OBs/ml, respectively and C. pomonella had a LC50 of 1.43 x 103 OBs/ml and LC90 1.26 x 104 OBs/ml. The virus was particularly virulent against T. leucotreta and C. pomonella as compared to C. peltastica. The biological activity of the alphabaculovirus was also tested against CpGV resistant European C. pomonella. From the results it was observed that the virus had the ability to overcome the resistance in C. pomonella and could potentially be used in the resistance management of C. pomonella. With the successful biological activity results obtained from this study, preliminary investigation were made into the mass production of the alphabaculovirus using both the in vivo and in vitro production methods. For in vivo production both the homologous host (C. peltastica) and a heterologous host (T leucotreta) were investigated. Preliminary studies focused on determining the biological activity in fifth instars of both hosts. Fifth instar LC50 and LC90 values for C. peltastica were 3.43 x 103 and 1.11 x 107 OBs/ml and for T. leucotreta the LC50 and LC90 values were 2.53 x 103 and 8.82 x 106 OBs/ml, respectively. The average yield of virus produced in each species was also determined. Cryptophlebia peltastica had the highest viral yield of 5.37 x 1010 OBs/larva and 2.93 x 1010 OBs/larva for T. leucotreta. The results obtained, from the preliminary investigation concluded that the virus could be produced in vivo in both C. peltastica and T. leucotreta, however further research is required into the mass production in both hosts. The in vitro production of the virus was also considered and the susceptibility of the virus was tested against the C. pomonella cell line, Cp14R. After infection of the Cp14R cells with budded virus collected from fifth instar C. peltastica larvae, OBs could be observed after three days. Thus, the alphabaculovirus is susceptible to the Cp14R cell line, thus has the potential to be produced in vitro and further characterised. This study is the first to report of the identification and characterisation of a novel alphabaculovirus isolated from a laboratory reared culture of C. peltastica and the potential for it to be commercially developed into a bipoesticide and used against Tortricidae pests.
- Full Text:
The Kenyan banking industry: Challenges and sustainability
- Muriithi, Samuel M, Louw, Lynette
- Authors: Muriithi, Samuel M , Louw, Lynette
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/69151 , vital:29433 , https://doi.org/10.1007/978-3-319-41090-6_1
- Description: This first chapter of the book aims to provide an overview of the key factors in knowledge and innovation management processes that are influencing and are influenced by the business environment in Africa. The chapter highlights the problematic of achieving a successful and sustainable business in Africa. It therefore outlines the various study programmes of cutting-edge research within different thematic areas such as innovation; entrepreneurship; education; capacity building; human capital; investment; and banking and finance. Finally, the chapter provides an executive summary of all the chapters included in the book.
- Full Text: false
- Authors: Muriithi, Samuel M , Louw, Lynette
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/69151 , vital:29433 , https://doi.org/10.1007/978-3-319-41090-6_1
- Description: This first chapter of the book aims to provide an overview of the key factors in knowledge and innovation management processes that are influencing and are influenced by the business environment in Africa. The chapter highlights the problematic of achieving a successful and sustainable business in Africa. It therefore outlines the various study programmes of cutting-edge research within different thematic areas such as innovation; entrepreneurship; education; capacity building; human capital; investment; and banking and finance. Finally, the chapter provides an executive summary of all the chapters included in the book.
- Full Text: false