Geomorphological connectivity and sensitivity examined in a recently degraded gravel-bed stream: implications for river-floodplain rehabilitation
- Authors: Powell, Rebecca
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/53722 , vital:26313
- Description: The study of river complexity and sensitivity to future human land-use activities and climate change is a fast growing field within the discipline of fluvial geomorphology. Associated with this is a need to improve river rehabilitation and catchment management approach, design and effectiveness. This study aimed to investigate drivers of the recent geomorphological sensitivity of the Baviaanskloof River-floodplain, an upland system in South Africa, by integrating the concepts of geomorphological connectivity and Panarchy. The understanding generated was used to evaluate the approach of the State agency, Working for Wetlands (WfWet), to river-floodplain rehabilitation in the catchment.The concepts of geomorphological connectivity and Panarchy provide useful frameworks for understanding interactions between geomorphological processes and structure across scales of space and time. Geomorphological connectivity explains the degree to which water and sediment is linked in a river landscape, determined by the distribution of erosional and depositional landforms (Brierley et al. 2006; Fryirs et al. 2007a; Fryirs et al. 2007b). Panarchy attempts to explain lagged response to disturbances, non-linear interactions, and sudden shifts in system state, and has been applied largely to ecological systems. Panarchy theory, when combined with the concept of geomorphological connectivity, provides a guiding framework for understanding river complexity in greater depth. The first results chapter of this study investigated river long-term and recent geomorphological history, towards understanding the nature and timing of river geomorphological cycling between erosion and deposition. Optically Stimulated Luminescence dating of alluvial fan and floodplain sedimentary units was conducted, for analysis of river-floodplain long-term history (100s to 1 000s of years). Interviews with 11 local landowners, combined with analysis of historic aerial imagery and river-floodplain topographic surveys, provided a means of describing recent (last few decades) geomorphological dynamics. The results indicated that the Baviaanskloof is naturally a cut- and-fill landscape over scales of several hundred to thousands of years, characterized by the alternation between phases of high fluvial energy and alluvial fan expansion, and low energy conditions associated with floodplain accretion. Recent and widespread river-floodplain degradation was compressed into a short period of approximately 30 years, suggesting that one or more drivers have pushed the system beyond a threshold, resulting in increased water and sediment connectivity. The second results chapter investigated the role of human land-use activities and flooding frequency and magnitude, as drivers of recent river-floodplain degradation. Human impacts were investigated by describing land-use activities for the preceding 80 years, and relating these activities to changes in river-floodplain form and behavior. Temporal trends in flood events of different frequency and magnitude were investigated by analyzing rainfall data, integrated with landowner reports of flood-inducing rainfall magnitudes. The findings indicated that human land-use activities have been an important driver of recent river- floodplain degradation, through the enhancement of water and sediment connectivity across spatial scales of the catchment. Episodic and high magnitude floods synergized with human driven increased connectivity, precipitating stream power and geomorphological threshold breaches, resulting in a shift in river behaviour. The third results chapter investigated the influence of tributary-junction streams and fans on the geomorphological form, behavior and sensitivity of the Baviaanskloof River. Local- scale topographic impacts of tributary fans and streams were described using topographic surveys and geomorphological mapping techniques. Tributary streams form a major control on the behaviour of the river, by influencing the degree of coarse sediment connectivity with the main channel. Although tributary fans buffer the river from disturbances occurring in the wider catchment, they initiate topographic variations along the floodplain, influencing local-scale patterns of deposition and erosion along the river. The main river responds to water and sediment inputs from tributary junction streams by locally adjusting longitudinal slope, maintaining an overall constant slope of 0.0066 m/m. The response of the Baviaanskloof River to tributary junction fans and streams is however variable, and is fashioned by complex interactions between geomorphological and anthropogenic factors. The final two chapters of the thesis evaluate the findings of the study within the context of river-floodplain rehabilitation approaches in South Africa, and within the theoretical, philosophical and methodological context of the research. The first of these two chapters evaluates the approach of the WfWet programme to river-floodplain rehabilitation in the Baviaanskloof. The chapter indicates that the present practice of WfWet is to reinstate a pre-degradation state, which is not suited to the Baviaanskloof River-floodplain, since the river-floodplain has passed a geomorphological threshold, resulting in a new set of interacting processes and landforms. The author presents a conceptual model illustrating the existence of geomorphological adaptive cycles interacting across spatial and temporal scales, thereby attempting to explain a river Panarchy specific to the Baviaanskloof. From this conceptual model, a hierarchical rehabilitation framework, targeting geomorphological processes and structure situated at different spatial and temporal scales of the landscape is suggested. The final chapter discusses the implications of integrating the concepts of geomorphological connectivity and river Panarchy theory in studies of river complexity and sensitivity to geomorphological change. The author suggests that there is scope for further investigation of the application of the two concepts within the discipline of fluvial geomorphology, particularly with regard to developing quantitative approaches to measuring and describing connectivity and Panarchy.
- Full Text:
- Date Issued: 2017
- Authors: Powell, Rebecca
- Date: 2017
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/53722 , vital:26313
- Description: The study of river complexity and sensitivity to future human land-use activities and climate change is a fast growing field within the discipline of fluvial geomorphology. Associated with this is a need to improve river rehabilitation and catchment management approach, design and effectiveness. This study aimed to investigate drivers of the recent geomorphological sensitivity of the Baviaanskloof River-floodplain, an upland system in South Africa, by integrating the concepts of geomorphological connectivity and Panarchy. The understanding generated was used to evaluate the approach of the State agency, Working for Wetlands (WfWet), to river-floodplain rehabilitation in the catchment.The concepts of geomorphological connectivity and Panarchy provide useful frameworks for understanding interactions between geomorphological processes and structure across scales of space and time. Geomorphological connectivity explains the degree to which water and sediment is linked in a river landscape, determined by the distribution of erosional and depositional landforms (Brierley et al. 2006; Fryirs et al. 2007a; Fryirs et al. 2007b). Panarchy attempts to explain lagged response to disturbances, non-linear interactions, and sudden shifts in system state, and has been applied largely to ecological systems. Panarchy theory, when combined with the concept of geomorphological connectivity, provides a guiding framework for understanding river complexity in greater depth. The first results chapter of this study investigated river long-term and recent geomorphological history, towards understanding the nature and timing of river geomorphological cycling between erosion and deposition. Optically Stimulated Luminescence dating of alluvial fan and floodplain sedimentary units was conducted, for analysis of river-floodplain long-term history (100s to 1 000s of years). Interviews with 11 local landowners, combined with analysis of historic aerial imagery and river-floodplain topographic surveys, provided a means of describing recent (last few decades) geomorphological dynamics. The results indicated that the Baviaanskloof is naturally a cut- and-fill landscape over scales of several hundred to thousands of years, characterized by the alternation between phases of high fluvial energy and alluvial fan expansion, and low energy conditions associated with floodplain accretion. Recent and widespread river-floodplain degradation was compressed into a short period of approximately 30 years, suggesting that one or more drivers have pushed the system beyond a threshold, resulting in increased water and sediment connectivity. The second results chapter investigated the role of human land-use activities and flooding frequency and magnitude, as drivers of recent river-floodplain degradation. Human impacts were investigated by describing land-use activities for the preceding 80 years, and relating these activities to changes in river-floodplain form and behavior. Temporal trends in flood events of different frequency and magnitude were investigated by analyzing rainfall data, integrated with landowner reports of flood-inducing rainfall magnitudes. The findings indicated that human land-use activities have been an important driver of recent river- floodplain degradation, through the enhancement of water and sediment connectivity across spatial scales of the catchment. Episodic and high magnitude floods synergized with human driven increased connectivity, precipitating stream power and geomorphological threshold breaches, resulting in a shift in river behaviour. The third results chapter investigated the influence of tributary-junction streams and fans on the geomorphological form, behavior and sensitivity of the Baviaanskloof River. Local- scale topographic impacts of tributary fans and streams were described using topographic surveys and geomorphological mapping techniques. Tributary streams form a major control on the behaviour of the river, by influencing the degree of coarse sediment connectivity with the main channel. Although tributary fans buffer the river from disturbances occurring in the wider catchment, they initiate topographic variations along the floodplain, influencing local-scale patterns of deposition and erosion along the river. The main river responds to water and sediment inputs from tributary junction streams by locally adjusting longitudinal slope, maintaining an overall constant slope of 0.0066 m/m. The response of the Baviaanskloof River to tributary junction fans and streams is however variable, and is fashioned by complex interactions between geomorphological and anthropogenic factors. The final two chapters of the thesis evaluate the findings of the study within the context of river-floodplain rehabilitation approaches in South Africa, and within the theoretical, philosophical and methodological context of the research. The first of these two chapters evaluates the approach of the WfWet programme to river-floodplain rehabilitation in the Baviaanskloof. The chapter indicates that the present practice of WfWet is to reinstate a pre-degradation state, which is not suited to the Baviaanskloof River-floodplain, since the river-floodplain has passed a geomorphological threshold, resulting in a new set of interacting processes and landforms. The author presents a conceptual model illustrating the existence of geomorphological adaptive cycles interacting across spatial and temporal scales, thereby attempting to explain a river Panarchy specific to the Baviaanskloof. From this conceptual model, a hierarchical rehabilitation framework, targeting geomorphological processes and structure situated at different spatial and temporal scales of the landscape is suggested. The final chapter discusses the implications of integrating the concepts of geomorphological connectivity and river Panarchy theory in studies of river complexity and sensitivity to geomorphological change. The author suggests that there is scope for further investigation of the application of the two concepts within the discipline of fluvial geomorphology, particularly with regard to developing quantitative approaches to measuring and describing connectivity and Panarchy.
- Full Text:
- Date Issued: 2017
Germinating in the cracks: the identity of contemporary Zambian art
- Authors: Mulenga, Andrew
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/146222 , vital:38506 , ISBN 9783863883065
- Description: Culture is the heritage of us all. Some may be more interested than others in the treasures of the past, but no one can fail to take pride in his country's participation in the story of mankind as represented in carvings, sculpture, music, painting, and the other arts (Simon Mwansa Kapwepwe 1964). After gaining independence in 1964, the next move for Zambia, like most newly-born African states at the time, was nation-building.
- Full Text:
- Date Issued: 2017
- Authors: Mulenga, Andrew
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/146222 , vital:38506 , ISBN 9783863883065
- Description: Culture is the heritage of us all. Some may be more interested than others in the treasures of the past, but no one can fail to take pride in his country's participation in the story of mankind as represented in carvings, sculpture, music, painting, and the other arts (Simon Mwansa Kapwepwe 1964). After gaining independence in 1964, the next move for Zambia, like most newly-born African states at the time, was nation-building.
- Full Text:
- Date Issued: 2017
Germinating in the cracks: the identity of contemporary Zambian art
- Authors: Mulenga, Andrew
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146734 , vital:38552 , http://www.nationalgallery.co.zw/icac/
- Description: The theme of the 2017 conference is Mapping the Future. We hope to gather art and culture professionals, academics, writers, critics and others in order to map out the future of art, culture and heritage from Africa. It will provide various players with an opportunity to interrogate the future of art institutions in the face of the current socio-economic challenges. Today the situation has changed since the first ICAC and the challenges that were there in the sixties, seventies and eighties are not the same today. ICAC comes at a time when art institutions around the world need urgent attention from both the local authorities, corporations and their governments.
- Full Text:
- Date Issued: 2017
- Authors: Mulenga, Andrew
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146734 , vital:38552 , http://www.nationalgallery.co.zw/icac/
- Description: The theme of the 2017 conference is Mapping the Future. We hope to gather art and culture professionals, academics, writers, critics and others in order to map out the future of art, culture and heritage from Africa. It will provide various players with an opportunity to interrogate the future of art institutions in the face of the current socio-economic challenges. Today the situation has changed since the first ICAC and the challenges that were there in the sixties, seventies and eighties are not the same today. ICAC comes at a time when art institutions around the world need urgent attention from both the local authorities, corporations and their governments.
- Full Text:
- Date Issued: 2017
Girl-child education in marginalised rural communities : a critical study of threats and opportunities to access quality secondary education in Binga District, Zimbabwe
- Authors: Nyamanhare, Eurita
- Date: 2017
- Subjects: Gender identity in education -- Zimbabwe Sex discrimination in education -- Zimbabwe Girls -- Education -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , Education
- Identifier: http://hdl.handle.net/10353/9213 , vital:34306
- Description: Despite the high ratings of the Zimbabwe’s education system in Africa, the state of secondary education in Binga District epitomises ‘a neglected backyard’ serving to perpetuate secondary education attainment inequalities, with the girl-child fixed at the bottom of the ladder at secondary school level. The prevailing deplorable learning conditions that characterise marginalised rural communities, mainly dominated by minority ethnic groups in Zimbabwe, depict similar conditions under which a girl-child strives to attain quality secondary education in some underdeveloped and developing African countries. Girl-Child Education in Marginalised Rural Communities: A Critical Study of Threats and Opportunities to Access Quality Secondary Education in Binga district, Zimbabwe, adopted a qualitative approach underpinned by a transformative paradigm. Pierre Bourdieu’s cultural capital and Kimberle Crenshaw’s intersectionality theoretical concepts complemented each other providing the theoretical lens that assisted in the unpacking of the whole study. Thus, the adopted theoretical framework helped the researcher to critique the seemingly ‘legitimised’ intergenerational multiple inequalities perpetuated through the education system and the intersecting systems of power (ethnicity, gender, social class) that consequently led to the unpacking of issues that surrounded the girl-child’s access to quality secondary education in Binga District. Intensive literature discussion covered the main themes derived from the study’s research questions, providing the ground from which new knowledge was nourished. With a sufficiently complex phenomenological-emergent research design embedded within critical studies, thick descriptions of lived experiences were gathered from 18 in-depth individual interviews and 6 Focus Group Discussions that involved the girls themselves; all considered to be ‘leaders of opinion’ in this study because of the various social positions and roles they played. Observations, visual materials in the form of photographs, as well as documents and records completed the list of data gathering tools that led to robust trustworthy credible findings from which the main themes of the study emerged. For the girl-child in Binga District, access to quality secondary education was found to be marginalised due to questionable gender responsiveness emanating from the social and infrastructure environments, the girl-child’s negative notions of secondary education underpinned by intersecting barriers, opportunities that are overshadowed by unmatched commitment by the girl-child seemingly underpinned by intersecting unresolved threats exacerbated by distant transitional prospects beyond secondary education. As put by one of the participants, thus, an analogy of ‘an incubator that ceases to work before the eggs hatch’ could be used to describe the state of secondary educational environment under which a girl-child strived to access quality secondary education in Binga District. Thus, using Binga District in Zimbabwe to mirror the state of secondary education in the ‘backyards’ of most of the sub-Saharan African countries, this study urges all African governments to take responsibility as they revise and enforce existing policies in line with the 2015 United Nations Sustainable Development Goals for girl-child secondary education is endowed with unlimited socio-economic benefits to all individual nations, and globally.
- Full Text:
- Date Issued: 2017
- Authors: Nyamanhare, Eurita
- Date: 2017
- Subjects: Gender identity in education -- Zimbabwe Sex discrimination in education -- Zimbabwe Girls -- Education -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , Education
- Identifier: http://hdl.handle.net/10353/9213 , vital:34306
- Description: Despite the high ratings of the Zimbabwe’s education system in Africa, the state of secondary education in Binga District epitomises ‘a neglected backyard’ serving to perpetuate secondary education attainment inequalities, with the girl-child fixed at the bottom of the ladder at secondary school level. The prevailing deplorable learning conditions that characterise marginalised rural communities, mainly dominated by minority ethnic groups in Zimbabwe, depict similar conditions under which a girl-child strives to attain quality secondary education in some underdeveloped and developing African countries. Girl-Child Education in Marginalised Rural Communities: A Critical Study of Threats and Opportunities to Access Quality Secondary Education in Binga district, Zimbabwe, adopted a qualitative approach underpinned by a transformative paradigm. Pierre Bourdieu’s cultural capital and Kimberle Crenshaw’s intersectionality theoretical concepts complemented each other providing the theoretical lens that assisted in the unpacking of the whole study. Thus, the adopted theoretical framework helped the researcher to critique the seemingly ‘legitimised’ intergenerational multiple inequalities perpetuated through the education system and the intersecting systems of power (ethnicity, gender, social class) that consequently led to the unpacking of issues that surrounded the girl-child’s access to quality secondary education in Binga District. Intensive literature discussion covered the main themes derived from the study’s research questions, providing the ground from which new knowledge was nourished. With a sufficiently complex phenomenological-emergent research design embedded within critical studies, thick descriptions of lived experiences were gathered from 18 in-depth individual interviews and 6 Focus Group Discussions that involved the girls themselves; all considered to be ‘leaders of opinion’ in this study because of the various social positions and roles they played. Observations, visual materials in the form of photographs, as well as documents and records completed the list of data gathering tools that led to robust trustworthy credible findings from which the main themes of the study emerged. For the girl-child in Binga District, access to quality secondary education was found to be marginalised due to questionable gender responsiveness emanating from the social and infrastructure environments, the girl-child’s negative notions of secondary education underpinned by intersecting barriers, opportunities that are overshadowed by unmatched commitment by the girl-child seemingly underpinned by intersecting unresolved threats exacerbated by distant transitional prospects beyond secondary education. As put by one of the participants, thus, an analogy of ‘an incubator that ceases to work before the eggs hatch’ could be used to describe the state of secondary educational environment under which a girl-child strived to access quality secondary education in Binga District. Thus, using Binga District in Zimbabwe to mirror the state of secondary education in the ‘backyards’ of most of the sub-Saharan African countries, this study urges all African governments to take responsibility as they revise and enforce existing policies in line with the 2015 United Nations Sustainable Development Goals for girl-child secondary education is endowed with unlimited socio-economic benefits to all individual nations, and globally.
- Full Text:
- Date Issued: 2017
Governing information security within the context of "bring your own device" in small, medium and micro enterprises
- Authors: Fani, Noluvuyo
- Date: 2017
- Subjects: Data protection , Computer security -- Management , Computer networks -- Security measures
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/7626 , vital:22114
- Description: Throughout history, information has been core to the communication, processing and storage of most tasks in the organisation, in this case in Small-Medium and Micro Enterprises (SMMEs). The implementation of these tasks relies on Information and Communication Technology (ICT). ICT is constantly evolving, and with each developed ICT, it becomes important that organisations adapt to the changing environment. Organisations need to adapt to the changing environment by incorporating innovative ICT that allows employees to perform their tasks with ease anywhere and anytime, whilst reducing the costs affiliated with the ICT. In this modern, performing tasks with ease anywhere and anytime requires that the employee is mobile whilst using the ICT. As a result, a relatively new phenomenon called “Bring Your Own Device” (BYOD) is currently infiltrating most organisations, where personally-owned mobile devices are used to access organisational information that will be used to conduct the various tasks of the organisation. The use of BYOD in organisations breeds the previously mentioned benefits such as performing organisational tasks anywhere and anytime. However, with the benefits highlighted for BYOD, organisations should be aware that there are risks to the implementation of BYOD. Therefore, the implementation of BYOD deems that organisations should implement BYOD with proper management thereof.
- Full Text:
- Date Issued: 2017
- Authors: Fani, Noluvuyo
- Date: 2017
- Subjects: Data protection , Computer security -- Management , Computer networks -- Security measures
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/7626 , vital:22114
- Description: Throughout history, information has been core to the communication, processing and storage of most tasks in the organisation, in this case in Small-Medium and Micro Enterprises (SMMEs). The implementation of these tasks relies on Information and Communication Technology (ICT). ICT is constantly evolving, and with each developed ICT, it becomes important that organisations adapt to the changing environment. Organisations need to adapt to the changing environment by incorporating innovative ICT that allows employees to perform their tasks with ease anywhere and anytime, whilst reducing the costs affiliated with the ICT. In this modern, performing tasks with ease anywhere and anytime requires that the employee is mobile whilst using the ICT. As a result, a relatively new phenomenon called “Bring Your Own Device” (BYOD) is currently infiltrating most organisations, where personally-owned mobile devices are used to access organisational information that will be used to conduct the various tasks of the organisation. The use of BYOD in organisations breeds the previously mentioned benefits such as performing organisational tasks anywhere and anytime. However, with the benefits highlighted for BYOD, organisations should be aware that there are risks to the implementation of BYOD. Therefore, the implementation of BYOD deems that organisations should implement BYOD with proper management thereof.
- Full Text:
- Date Issued: 2017
Graphene quantum dot-phthalocyanine polystyrene conjugate embedded in asymmetric polymer membranes for photocatalytic oxidation of 4-chlorophenol
- Mafukidze, Donovan M, Nyokong, Tebello
- Authors: Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189189 , vital:44825 , xlink:href="https://doi.org/10.1080/00958972.2017.1400664"
- Description: The feasibility of using π–π stacking as a means of fixing unsubstituted Zn phthalocyanine (ZnPc) to a support prior to formation of photoactive polymer asymmetric membranes was explored. Stable ZnPc–graphene quantum dot-polystyrene conjugates (6.15 μmol/g ZnPc loading) were synthesized and embedded in polystyrene membranes which proved to be photoactive with a singlet oxygen quantum yield of 0.43 in ethanol and 0.37 in water. The membranes also proved to be active in the photocatalytic oxidation of 4-chlorophenol in water where the reaction followed second-order kinetics. At 3.24 × 10−4 mol L−1, the photo-oxidation of 4-chlorophenol was observed with a kobs of 35.9 L mol−1 min−1 and a half-life of 86 min.
- Full Text:
- Date Issued: 2017
- Authors: Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189189 , vital:44825 , xlink:href="https://doi.org/10.1080/00958972.2017.1400664"
- Description: The feasibility of using π–π stacking as a means of fixing unsubstituted Zn phthalocyanine (ZnPc) to a support prior to formation of photoactive polymer asymmetric membranes was explored. Stable ZnPc–graphene quantum dot-polystyrene conjugates (6.15 μmol/g ZnPc loading) were synthesized and embedded in polystyrene membranes which proved to be photoactive with a singlet oxygen quantum yield of 0.43 in ethanol and 0.37 in water. The membranes also proved to be active in the photocatalytic oxidation of 4-chlorophenol in water where the reaction followed second-order kinetics. At 3.24 × 10−4 mol L−1, the photo-oxidation of 4-chlorophenol was observed with a kobs of 35.9 L mol−1 min−1 and a half-life of 86 min.
- Full Text:
- Date Issued: 2017
Graphene quantum dots anchored onto mercaptopyridine-substituted zinc phthalocyanine-Au@ Ag nanoparticle hybrid: Application as fluorescence “off-on-off” sensor for Hg2+ and biothiols
- Achadu, Ojodomo John, Nyokong, Tebello
- Authors: Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188194 , vital:44731 , xlink:href="https://doi.org/10.1016/j.dyepig.2017.06.002"
- Description: Novel supramolecular hybrid containing polyethyleneimine-functionalized graphene quantum dots (PEI-GQDs) and mercaptopyridine-substituted zinc phthalocyanine (Pc)-Au@Ag nano-alloys is presented in this study. The designed hybrid was employed as a dual fluorescence nanoprobe for Hg2+ and biothiol detection in aqueous solution using PEI-GQDs as the fluorescence switching signal probe. The dual sensing platform for the analytes detection is firstly, based on the quenching (turn “OFF”) of the PEI-GQDs fluorescence upon π-π interaction or electrostatic attraction with Pc-Au@Ag conjugate. The quenched fluorescence can be switched back to the “ON” mode in the presence of Hg2+ and switched “OFF” again when biothiols are introduced to capture the Hg2+ ion via the formation of the strong metal-thiol bond (Hg-S). The “off-on-off” processes were modulated by different amounts of Hg2+ and biothiols. The nanoprobes were found to be highly stable and selective towards the target analytes in the presence of other amino acids and metal ions. Also, the probes were successfully deployed in the assay of the test analytes in spiked samples.
- Full Text:
- Date Issued: 2017
- Authors: Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188194 , vital:44731 , xlink:href="https://doi.org/10.1016/j.dyepig.2017.06.002"
- Description: Novel supramolecular hybrid containing polyethyleneimine-functionalized graphene quantum dots (PEI-GQDs) and mercaptopyridine-substituted zinc phthalocyanine (Pc)-Au@Ag nano-alloys is presented in this study. The designed hybrid was employed as a dual fluorescence nanoprobe for Hg2+ and biothiol detection in aqueous solution using PEI-GQDs as the fluorescence switching signal probe. The dual sensing platform for the analytes detection is firstly, based on the quenching (turn “OFF”) of the PEI-GQDs fluorescence upon π-π interaction or electrostatic attraction with Pc-Au@Ag conjugate. The quenched fluorescence can be switched back to the “ON” mode in the presence of Hg2+ and switched “OFF” again when biothiols are introduced to capture the Hg2+ ion via the formation of the strong metal-thiol bond (Hg-S). The “off-on-off” processes were modulated by different amounts of Hg2+ and biothiols. The nanoprobes were found to be highly stable and selective towards the target analytes in the presence of other amino acids and metal ions. Also, the probes were successfully deployed in the assay of the test analytes in spiked samples.
- Full Text:
- Date Issued: 2017
Graphene quantum dots coordinated to mercaptopyridine-substituted phthalocyanines: Characterization and application as fluorescence “turn ON” nanoprobes
- Achadu, Ojodomo John, Nyokong, Tebello
- Authors: Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188293 , vital:44742 , xlink:href="https://doi.org/10.1016/j.saa.2016.11.043"
- Description: This study reports on the design of novel nanoconjugates of graphene quantum dots (GQDs) and tetra or octa-mercaptopyridine-substituted zinc and aluminium phthalocyanines (Pcs) deployed as fluorescence “turn ON” nanoprobes. The phthalocyanines were separately adsorbed onto the planar structure of graphene quantum dots (GQDs) via π-π stacking interaction to form GQDs-mercaptopyridine Pcs nanoconjugates. The quaternized Pc complexes could also interact with the GQDs through electrostatic attraction due to the positive charges on the Pcs ring substituents and the negative charges on the surface of GQDs. The fluorescence emission of the GQDs was quenched upon coordination to the respective Pcs. However, the fluorescence emission was “turned ON” in the presence of Hg2 + employed as a test analyte. The mechanism of the “turn ON” of the GQDs emission in the nanoconjugates is ascribed to the strong affinity of Hg2 + to bind with the bridging sulfur on the Pcs periphery thereby disrupting the π-π stacking interaction between the GQDs and the Pcs with a consequent “turn ON” of the coordinated GQDs' fluorescence.
- Full Text:
- Date Issued: 2017
- Authors: Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188293 , vital:44742 , xlink:href="https://doi.org/10.1016/j.saa.2016.11.043"
- Description: This study reports on the design of novel nanoconjugates of graphene quantum dots (GQDs) and tetra or octa-mercaptopyridine-substituted zinc and aluminium phthalocyanines (Pcs) deployed as fluorescence “turn ON” nanoprobes. The phthalocyanines were separately adsorbed onto the planar structure of graphene quantum dots (GQDs) via π-π stacking interaction to form GQDs-mercaptopyridine Pcs nanoconjugates. The quaternized Pc complexes could also interact with the GQDs through electrostatic attraction due to the positive charges on the Pcs ring substituents and the negative charges on the surface of GQDs. The fluorescence emission of the GQDs was quenched upon coordination to the respective Pcs. However, the fluorescence emission was “turned ON” in the presence of Hg2 + employed as a test analyte. The mechanism of the “turn ON” of the GQDs emission in the nanoconjugates is ascribed to the strong affinity of Hg2 + to bind with the bridging sulfur on the Pcs periphery thereby disrupting the π-π stacking interaction between the GQDs and the Pcs with a consequent “turn ON” of the coordinated GQDs' fluorescence.
- Full Text:
- Date Issued: 2017
Graphene quantum dots decorated with maleimide and zinc tetramaleimido-phthalocyanine: Application in the design of “OFF-ON” fluorescence sensors for biothiols
- Achadu, Ojodomo John, Nyokong, Tebello
- Authors: Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188282 , vital:44741 , xlink:href="https://doi.org/10.1016/j.talanta.2017.01.031"
- Description: The fabrication of maleimide-derivatized graphene quantum dots (M-GQDs) and zinc phthalocyanine (2) as novel sensor probes for the selective detection of biothiols (cysteine, homocysteine or glutathione) through the rapid and specific Michael addition reaction between biothiols and the maleimide-derivatized probes is presented in this study. GQDs directly functionalized with maleimide units (M-GQDs) were synthesized and deployed for biothiols recognition following the principle of Michael addition. M-GQDs probe was found to be highly sensitive and selective towards biothiols detection in the nanomolar range in aqueous solution and at physiological pH (7.0). On the other hand, non-covalent interaction between pristine GQDs and novel zinc tetramaleimido-derivatized phthalocyanine resulted in the quenching of the pristine GQDs fluorescence emission which was switched back to the “ON” mode by Michael addition mechanism in the presence of biothiols. Tested relevant biomolecules did not interfere in the quantitative recognition of the biothiols. The probes showed to be highly sensitive, specific and selective for biothiols sensing in simulated real samples.
- Full Text:
- Date Issued: 2017
- Authors: Achadu, Ojodomo John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188282 , vital:44741 , xlink:href="https://doi.org/10.1016/j.talanta.2017.01.031"
- Description: The fabrication of maleimide-derivatized graphene quantum dots (M-GQDs) and zinc phthalocyanine (2) as novel sensor probes for the selective detection of biothiols (cysteine, homocysteine or glutathione) through the rapid and specific Michael addition reaction between biothiols and the maleimide-derivatized probes is presented in this study. GQDs directly functionalized with maleimide units (M-GQDs) were synthesized and deployed for biothiols recognition following the principle of Michael addition. M-GQDs probe was found to be highly sensitive and selective towards biothiols detection in the nanomolar range in aqueous solution and at physiological pH (7.0). On the other hand, non-covalent interaction between pristine GQDs and novel zinc tetramaleimido-derivatized phthalocyanine resulted in the quenching of the pristine GQDs fluorescence emission which was switched back to the “ON” mode by Michael addition mechanism in the presence of biothiols. Tested relevant biomolecules did not interfere in the quantitative recognition of the biothiols. The probes showed to be highly sensitive, specific and selective for biothiols sensing in simulated real samples.
- Full Text:
- Date Issued: 2017
Group membership and collective action among small-scale farmers in Nkonkobe Local Municipality, Eastern Cape Province, South Africa
- Authors: Arwari, Margaret Kwamboka
- Date: 2017
- Subjects: Farmers -- South Africa -- Eastern Cape Farms, Small -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8144 , vital:31535
- Description: In South Africa, the organisation of farmers into groups has been a basic tenet for numerous, small and dispersed small-scale farmers to make their voices heard, address challenges and access support services from the government and other development agencies. However, the literature shows that the South African government promotes inappropriate forms of farmer collective action, i.e. collective production. The government seems to lack knowledge on what forms of collective action to implement and support. It is also noted in the literature that in South Africa, the majority of farmers do not participate in farmer organisations. There is limited research on the determinants of membership in farmer organisations, especially in terms of the role of ‘human agency’. Human agency is a concept which is interrelated with the concept of ‘empowerme nt’, whereby a person with strong agency is someone who is an agent of positive change. Therefore, the study sought to address these gaps. The broad objective of this study was to explore the phenomenon of group membership and collective action among small-scale farmers in Nkonkobe Local Municipality, Eastern Cape Province, South Africa. The study used the mixed method approach where an exploratory design was employed. A mult istage sampling technique was used which employed random, purposive and convenience sampling techniques. Quantitative and qualitative data were collected from 245 farmers using semistructured questionnaires and detailed qualitative data were elicited from 16 farmer organisat ions using interview guides. For the quantitative research, a cross-sectional survey design was employed. After discarded unusable observations, data from 228 farmers were analysed using a combination of descriptive statistics, simple inferential statistics, and econometric analysis. For the qualitative data obtained, thematic analysis was used in line with the study objectives. The study findings show that farmers undertake collective action through farmer organisations. These farmer organisations were categorised into two types, i.e. farmer cooperatives and farmer associations. However, low membership in these farmer organisations is noted and this was attributed to the following: (1) low farmer awareness of the existence of farmer organisations, (2) challenges faced by the organisations that contribute to their ineffectiveness and thus low membership, (3) the prevalence of negative perceptions of farmer organisations due to confusion as to their role, (4) the government’s farmer support approach which compels or encourages farmers to form groups. The results also showed that the following are determinants of participation in farmer organisations: farmer’s age, level of education, human agency, whether a farmer has off-farm income sources, whether a farmer is involved in government supported projects, whether a farmer accesses extension information, the number of visits from extension officers received by a farmer, and the number of adults in a household contributing family labour. The study findings also show that the farmers in farmer organisations have higher human agency compared to those not in farmer organisations. According to the study results, farmer groups offer a number of benefits. For one, farmer organisations are avenues for farmers’ voices to be heard, they lobby government for better access to support services such as credit, input supply, information, and training. In addition, farmers who belong to organisations experience the benefits of collective marketing. Despite the aforementioned benefits of farmer organisations, group challenges are observed. For example, farmer organisations face declining membership, the free rider problem and conflicts between members, have a problem of ineffective, old members and lack of commitment of some group members. It was therefore recommended that there is a need for concerted effort by the government, development agencies, non-governmental organisations, farmers, and farmer organisations to ensure the success of farmer organisations in promoting small-scale agriculture.
- Full Text:
- Date Issued: 2017
- Authors: Arwari, Margaret Kwamboka
- Date: 2017
- Subjects: Farmers -- South Africa -- Eastern Cape Farms, Small -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8144 , vital:31535
- Description: In South Africa, the organisation of farmers into groups has been a basic tenet for numerous, small and dispersed small-scale farmers to make their voices heard, address challenges and access support services from the government and other development agencies. However, the literature shows that the South African government promotes inappropriate forms of farmer collective action, i.e. collective production. The government seems to lack knowledge on what forms of collective action to implement and support. It is also noted in the literature that in South Africa, the majority of farmers do not participate in farmer organisations. There is limited research on the determinants of membership in farmer organisations, especially in terms of the role of ‘human agency’. Human agency is a concept which is interrelated with the concept of ‘empowerme nt’, whereby a person with strong agency is someone who is an agent of positive change. Therefore, the study sought to address these gaps. The broad objective of this study was to explore the phenomenon of group membership and collective action among small-scale farmers in Nkonkobe Local Municipality, Eastern Cape Province, South Africa. The study used the mixed method approach where an exploratory design was employed. A mult istage sampling technique was used which employed random, purposive and convenience sampling techniques. Quantitative and qualitative data were collected from 245 farmers using semistructured questionnaires and detailed qualitative data were elicited from 16 farmer organisat ions using interview guides. For the quantitative research, a cross-sectional survey design was employed. After discarded unusable observations, data from 228 farmers were analysed using a combination of descriptive statistics, simple inferential statistics, and econometric analysis. For the qualitative data obtained, thematic analysis was used in line with the study objectives. The study findings show that farmers undertake collective action through farmer organisations. These farmer organisations were categorised into two types, i.e. farmer cooperatives and farmer associations. However, low membership in these farmer organisations is noted and this was attributed to the following: (1) low farmer awareness of the existence of farmer organisations, (2) challenges faced by the organisations that contribute to their ineffectiveness and thus low membership, (3) the prevalence of negative perceptions of farmer organisations due to confusion as to their role, (4) the government’s farmer support approach which compels or encourages farmers to form groups. The results also showed that the following are determinants of participation in farmer organisations: farmer’s age, level of education, human agency, whether a farmer has off-farm income sources, whether a farmer is involved in government supported projects, whether a farmer accesses extension information, the number of visits from extension officers received by a farmer, and the number of adults in a household contributing family labour. The study findings also show that the farmers in farmer organisations have higher human agency compared to those not in farmer organisations. According to the study results, farmer groups offer a number of benefits. For one, farmer organisations are avenues for farmers’ voices to be heard, they lobby government for better access to support services such as credit, input supply, information, and training. In addition, farmers who belong to organisations experience the benefits of collective marketing. Despite the aforementioned benefits of farmer organisations, group challenges are observed. For example, farmer organisations face declining membership, the free rider problem and conflicts between members, have a problem of ineffective, old members and lack of commitment of some group members. It was therefore recommended that there is a need for concerted effort by the government, development agencies, non-governmental organisations, farmers, and farmer organisations to ensure the success of farmer organisations in promoting small-scale agriculture.
- Full Text:
- Date Issued: 2017
Growth strategies for black township entrepreneurs
- Authors: Boniwe, Sihlangule
- Date: 2017
- Subjects: Entrepreneurship -- South Africa , Small business -- South Africa -- Management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/14598 , vital:27800
- Description: The situation in South Africa throws up a trickier and more unconventional challenge. The country has symptoms of a spatial realm that is not fully connected with the urban systems (spatially, socially, or structurally) and is certainly disconnected from the rural economy. This is the realm of the country’s townships and informal settlements. Conceptually, they are relics of the country’s special past, but the policies of post-apartheid South Africa have inadvertently kept their contemporary reality alive. In many ways, the townships and especially the informal settlements are similar to the slums in much of the developing world, although never was a slum formed with as much central planning and purpose as were some of the larger South African townships. This paper undertakes to understand the growth strategies of black township entrepreneurs in South Africa. This paper also undertakes to investigate the perceived influence of education, government policies, access to funding, market constraints, crime and social norms on the development or perceived growth strategies for black township entrepreneurs. Propositions are made and tested through conducting interviews with individuals involved with the dynamics presented by this subject on a day to day basis. Evidence collected is interpreted into knowledge and finally recommendations are made.
- Full Text:
- Date Issued: 2017
- Authors: Boniwe, Sihlangule
- Date: 2017
- Subjects: Entrepreneurship -- South Africa , Small business -- South Africa -- Management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/14598 , vital:27800
- Description: The situation in South Africa throws up a trickier and more unconventional challenge. The country has symptoms of a spatial realm that is not fully connected with the urban systems (spatially, socially, or structurally) and is certainly disconnected from the rural economy. This is the realm of the country’s townships and informal settlements. Conceptually, they are relics of the country’s special past, but the policies of post-apartheid South Africa have inadvertently kept their contemporary reality alive. In many ways, the townships and especially the informal settlements are similar to the slums in much of the developing world, although never was a slum formed with as much central planning and purpose as were some of the larger South African townships. This paper undertakes to understand the growth strategies of black township entrepreneurs in South Africa. This paper also undertakes to investigate the perceived influence of education, government policies, access to funding, market constraints, crime and social norms on the development or perceived growth strategies for black township entrepreneurs. Propositions are made and tested through conducting interviews with individuals involved with the dynamics presented by this subject on a day to day basis. Evidence collected is interpreted into knowledge and finally recommendations are made.
- Full Text:
- Date Issued: 2017
Guidelines for cybersecurity education campaigns
- Authors: Reid, Rayne
- Date: 2017
- Subjects: Computer security Computer networks -- Security measures
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/14091 , vital:27416
- Description: In our technology- and information-infused world, cyberspace is an integral part of modern-day society. As the number of active cyberspace users increases, so too does the chances of a cyber threat finding a vulnerable target increase. All cyber users who are exposed to cyber risks need to be educated about cyber security. Human beings play a key role in the implementation and governing of an entire cybersecurity and cybersafety solution. The effectiveness of any cybersecurity and cybersafety solutions in a societal or individual context is dependent on the human beings involved in the process. If these human beings are either unaware or not knowledgeable about their roles in the security solution they become the weak link in these cybersecurity solutions. It is essential that all users be educated to combat any threats. Children are a particularly vulnerable subgroup within society. They are digital natives and make use of ICT, and online services with increasing frequency, but this does not mean they are knowledgeable about or behaving securely in their cyber activities. Children will be exposed to cyberspace throughout their lifetimes. Therefore, cybersecurity and cybersafety should be taught to children as a life-skill. There is a lack of well-known, comprehensive cybersecurity and cybersafety educational campaigns which target school children. Most existing information security and cybersecurity education campaigns limit their scope. Literature reports mainly on education campaigns focused on primary businesses, government agencies and tertiary education institutions. Additionally, most guidance for the design and implementation of security and safety campaigns: are for an organisational context, only target organisational users, and mostly provide high-level design recommendations. This thesis addressed the lack of guidance for designing and implementing cybersecurity and cybersafety educational campaigns suited to school learners as a target audience. The thesis aimed to offer guidance for designing and implementing education campaigns that educate school learners about cybersecurity and cybersafety. This was done through the implementation of an action research process over a five-year period. The action research process involved cybersecurity and cybersafety educational interventions at multiple schools. A total of 18 actionable guidelines were derived from this research to guide the design and implementation of cybersecurity and cybersafety education campaigns which aim to educate school children.
- Full Text:
- Date Issued: 2017
- Authors: Reid, Rayne
- Date: 2017
- Subjects: Computer security Computer networks -- Security measures
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/14091 , vital:27416
- Description: In our technology- and information-infused world, cyberspace is an integral part of modern-day society. As the number of active cyberspace users increases, so too does the chances of a cyber threat finding a vulnerable target increase. All cyber users who are exposed to cyber risks need to be educated about cyber security. Human beings play a key role in the implementation and governing of an entire cybersecurity and cybersafety solution. The effectiveness of any cybersecurity and cybersafety solutions in a societal or individual context is dependent on the human beings involved in the process. If these human beings are either unaware or not knowledgeable about their roles in the security solution they become the weak link in these cybersecurity solutions. It is essential that all users be educated to combat any threats. Children are a particularly vulnerable subgroup within society. They are digital natives and make use of ICT, and online services with increasing frequency, but this does not mean they are knowledgeable about or behaving securely in their cyber activities. Children will be exposed to cyberspace throughout their lifetimes. Therefore, cybersecurity and cybersafety should be taught to children as a life-skill. There is a lack of well-known, comprehensive cybersecurity and cybersafety educational campaigns which target school children. Most existing information security and cybersecurity education campaigns limit their scope. Literature reports mainly on education campaigns focused on primary businesses, government agencies and tertiary education institutions. Additionally, most guidance for the design and implementation of security and safety campaigns: are for an organisational context, only target organisational users, and mostly provide high-level design recommendations. This thesis addressed the lack of guidance for designing and implementing cybersecurity and cybersafety educational campaigns suited to school learners as a target audience. The thesis aimed to offer guidance for designing and implementing education campaigns that educate school learners about cybersecurity and cybersafety. This was done through the implementation of an action research process over a five-year period. The action research process involved cybersecurity and cybersafety educational interventions at multiple schools. A total of 18 actionable guidelines were derived from this research to guide the design and implementation of cybersecurity and cybersafety education campaigns which aim to educate school children.
- Full Text:
- Date Issued: 2017
Guidelines for secure cloud-based personal health records
- Authors: Mxoli, Ncedisa Avuya Mercia
- Date: 2017
- Subjects: Cloud computing -- Security measures , Computer security Data mining Medical records -- Data processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/14134 , vital:27433
- Description: Traditionally, health records have been stored in paper folders at the physician’s consulting rooms – or at the patient’s home. Some people stored the health records of their family members, so as to keep a running history of all the medical procedures they went through, and what medications they were given by different physicians at different stages of their lives. Technology has introduced better and safer ways of storing these records, namely, through the use of Personal Health Records (PHRs). With time, different types of PHRs have emerged, i.e. local, remote server-based, and hybrid PHRs. Web-based PHRs fall under the remote server-based PHRs; and recently, a new market in storing PHRs has emerged. Cloud computing has become a trend in storing PHRs in a more accessible and efficient manner. Despite its many benefits, cloud computing has many privacy and security concerns. As a result, the adoption rate of cloud services is not yet very high. A qualitative and exploratory research design approach was followed in this study, in order to reach the objective of proposing guidelines that could assist PHR providers in selecting a secure Cloud Service Provider (CSP) to store their customers’ health data. The research methods that were used include a literature review, systematic literature review, qualitative content analysis, reasoning, argumentation and elite interviews. A systematic literature review and qualitative content analysis were conducted to examine those risks in the cloud environment that could have a negative impact on the secure storing of PHRs. PHRs must satisfy certain dimensions, in order for them to be meaningful for use. While these were highlighted in the research, it also emerged that certain risks affect the PHR dimensions directly, thus threatening the meaningfulness and usability of cloud-based PHRs. The literature review revealed that specific control measures can be adopted to mitigate the identified risks. These control measures form part of the material used in this study to identify the guidelines for secure cloud-based PHRs. The guidelines were formulated through the use of reasoning and argumentation. After the guidelines were formulated, elite interviews were conducted, in order to validate and finalize the main research output: i.e. guidelines. The results of this study may alert PHR providers to the risks that exist in the cloud environment; so that they can make informed decisions when choosing a CSP for storing their customers’ health data.
- Full Text:
- Date Issued: 2017
- Authors: Mxoli, Ncedisa Avuya Mercia
- Date: 2017
- Subjects: Cloud computing -- Security measures , Computer security Data mining Medical records -- Data processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/14134 , vital:27433
- Description: Traditionally, health records have been stored in paper folders at the physician’s consulting rooms – or at the patient’s home. Some people stored the health records of their family members, so as to keep a running history of all the medical procedures they went through, and what medications they were given by different physicians at different stages of their lives. Technology has introduced better and safer ways of storing these records, namely, through the use of Personal Health Records (PHRs). With time, different types of PHRs have emerged, i.e. local, remote server-based, and hybrid PHRs. Web-based PHRs fall under the remote server-based PHRs; and recently, a new market in storing PHRs has emerged. Cloud computing has become a trend in storing PHRs in a more accessible and efficient manner. Despite its many benefits, cloud computing has many privacy and security concerns. As a result, the adoption rate of cloud services is not yet very high. A qualitative and exploratory research design approach was followed in this study, in order to reach the objective of proposing guidelines that could assist PHR providers in selecting a secure Cloud Service Provider (CSP) to store their customers’ health data. The research methods that were used include a literature review, systematic literature review, qualitative content analysis, reasoning, argumentation and elite interviews. A systematic literature review and qualitative content analysis were conducted to examine those risks in the cloud environment that could have a negative impact on the secure storing of PHRs. PHRs must satisfy certain dimensions, in order for them to be meaningful for use. While these were highlighted in the research, it also emerged that certain risks affect the PHR dimensions directly, thus threatening the meaningfulness and usability of cloud-based PHRs. The literature review revealed that specific control measures can be adopted to mitigate the identified risks. These control measures form part of the material used in this study to identify the guidelines for secure cloud-based PHRs. The guidelines were formulated through the use of reasoning and argumentation. After the guidelines were formulated, elite interviews were conducted, in order to validate and finalize the main research output: i.e. guidelines. The results of this study may alert PHR providers to the risks that exist in the cloud environment; so that they can make informed decisions when choosing a CSP for storing their customers’ health data.
- Full Text:
- Date Issued: 2017
Gypsum deposits associated with the Whitehill Formation (Ecca Group) in the Steytlerville-Jansenville Area, Southern Karoo, South Africa
- Authors: Almanza, Roberto Daniel
- Date: 2017
- Subjects: Gypsum -- South Africa Concretions -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/15292 , vital:28215
- Description: The Steyterville-Jansenville gypsum field is one of South Africa’s smaller deposits, yet plays host to several gypsum mines, both past and present. This study aims to deconstruct the processes involved in the precipitation of various quantities and grades of gypsum in the lower Ecca Group of the Karoo Supergroup. The calcium and sulphate ions required to form the gypsum mineral (CaSO4•2H2O) are derived from the mid- to lower-shale of the Whitehill Formation, which is carbonate- and pyrite-rich. Gypsum formation is dependent on the availability of pyrite as opposed to calcite, which is in abundance throughout the 30m thick, Early Ufimian (late Permian) Whitehill Formation. Weathered shale, which has been folded and faulted, forms the host environment in which gypsum has precipitated. Folding of the shale occurs as a series of large- and medium-scale anticlines and synclines that strike east to west. These structures, which formed during the Cape Orogeny indicate that stresses were exerted from the south-southwest towards the north-northeast. Folded calcite veins surrounded by amorphous pyrite, observed in thin section suggest that pyrite and calcite were precipitated together prior to a deformation event. Oxidation of pyrite following these deformation events results in the concentration of sulphides within the hinge zones of the folds (weakest zone) and this is where the larger gypsum deposits are found at the surface. Carbonate concretions in the Whitehill Formation up to 5m in length and 3m in width are common in the study area, and suggest a relationship with the deposition of the shale whereby calcium-rich nuclei grew in a concentric fashion during a non-depositional hiatus period. This period is also associated with a higher concentration of pyrite and could explain the occurrence of concretions together with adjacent gypsum-rich shale. Pyrite framboids observed under the Scanning Electron Microscope (SEM) provide evidence to suggest concentric growth of initially deposited microcrystals including nucleation and growth of nodules and concretions observed within the Whitehill Formation. Prerequisites for gypsum formation also include restricted drainage such as a pan, a clay layer in the drainage area and an arid climate where evaporation exceeds precipitation. The preferred surface conditions for gypsum formation would be low-lying areas which are surrounded by gently-sloping topography promoting the concentration of aqueous solutions in a calcite- and pyrite-rich area. Groundwater solution would initially dissolve the calcite and clay minerals, and pyrite and the quartz minerals would remain in the host rock. Areas with greater calcite and clay pores would accommodate more groundwater and thus promote a greater surface area for chemical reactions. This enhances the potential for the oxidation of pyrite to form sulphate ions, which can later combine with calcium ions to precipitate gypsum crystals. Alternatively, the oxidation of pyrite, which produces acidity, dissolves the carbonate host and the calcium- and sulphate-rich solution then precipitates gypsum. The combination of the structural and geomorphological processes is key to the formation of economic gypsum deposits. The potential for extensive gypsum reserves within the Steytlerville-Jansenville field remains valid, provided the target is located over a predominantly weathered Whitehill Formation outcrop, preferably in an area which has undergone extensive deformation (such as a fold hinge zone), and is favourable for the concentration of ground and surface water within a low-lying area.
- Full Text:
- Date Issued: 2017
- Authors: Almanza, Roberto Daniel
- Date: 2017
- Subjects: Gypsum -- South Africa Concretions -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/15292 , vital:28215
- Description: The Steyterville-Jansenville gypsum field is one of South Africa’s smaller deposits, yet plays host to several gypsum mines, both past and present. This study aims to deconstruct the processes involved in the precipitation of various quantities and grades of gypsum in the lower Ecca Group of the Karoo Supergroup. The calcium and sulphate ions required to form the gypsum mineral (CaSO4•2H2O) are derived from the mid- to lower-shale of the Whitehill Formation, which is carbonate- and pyrite-rich. Gypsum formation is dependent on the availability of pyrite as opposed to calcite, which is in abundance throughout the 30m thick, Early Ufimian (late Permian) Whitehill Formation. Weathered shale, which has been folded and faulted, forms the host environment in which gypsum has precipitated. Folding of the shale occurs as a series of large- and medium-scale anticlines and synclines that strike east to west. These structures, which formed during the Cape Orogeny indicate that stresses were exerted from the south-southwest towards the north-northeast. Folded calcite veins surrounded by amorphous pyrite, observed in thin section suggest that pyrite and calcite were precipitated together prior to a deformation event. Oxidation of pyrite following these deformation events results in the concentration of sulphides within the hinge zones of the folds (weakest zone) and this is where the larger gypsum deposits are found at the surface. Carbonate concretions in the Whitehill Formation up to 5m in length and 3m in width are common in the study area, and suggest a relationship with the deposition of the shale whereby calcium-rich nuclei grew in a concentric fashion during a non-depositional hiatus period. This period is also associated with a higher concentration of pyrite and could explain the occurrence of concretions together with adjacent gypsum-rich shale. Pyrite framboids observed under the Scanning Electron Microscope (SEM) provide evidence to suggest concentric growth of initially deposited microcrystals including nucleation and growth of nodules and concretions observed within the Whitehill Formation. Prerequisites for gypsum formation also include restricted drainage such as a pan, a clay layer in the drainage area and an arid climate where evaporation exceeds precipitation. The preferred surface conditions for gypsum formation would be low-lying areas which are surrounded by gently-sloping topography promoting the concentration of aqueous solutions in a calcite- and pyrite-rich area. Groundwater solution would initially dissolve the calcite and clay minerals, and pyrite and the quartz minerals would remain in the host rock. Areas with greater calcite and clay pores would accommodate more groundwater and thus promote a greater surface area for chemical reactions. This enhances the potential for the oxidation of pyrite to form sulphate ions, which can later combine with calcium ions to precipitate gypsum crystals. Alternatively, the oxidation of pyrite, which produces acidity, dissolves the carbonate host and the calcium- and sulphate-rich solution then precipitates gypsum. The combination of the structural and geomorphological processes is key to the formation of economic gypsum deposits. The potential for extensive gypsum reserves within the Steytlerville-Jansenville field remains valid, provided the target is located over a predominantly weathered Whitehill Formation outcrop, preferably in an area which has undergone extensive deformation (such as a fold hinge zone), and is favourable for the concentration of ground and surface water within a low-lying area.
- Full Text:
- Date Issued: 2017
Halogen substituted A2B type Co (III) triarylcorroles
- Niu, Yingjie, Li, Minzhi, Zhang, Qianchong, Zhu, Weihua, Mack, John, Fomo, Gertrude, Nyokong, Tebello, Liang, Xu
- Authors: Niu, Yingjie , Li, Minzhi , Zhang, Qianchong , Zhu, Weihua , Mack, John , Fomo, Gertrude , Nyokong, Tebello , Liang, Xu
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/233048 , vital:50051 , xlink:href="https://doi.org/10.1016/j.dyepig.2017.02.049"
- Description: Seven low symmetry A2B type Co(III)triarylcorroles with electron withdrawing meso-aryl substituents have been synthesized and characterized. A detailed analysis of the optical and redox properties has been carried out by comparing their optical spectroscopy, electrochemistry and spectroelectrochemistry to trends predicted in a series of DFT and TD-DFT calculations. The results demonstrate that Co(III)corroles are highly effective catalysts for hydrogen evolution reactions (HERs). Moreover, there is a marked enhancement in their homogenous catalytic ability when halogen atoms are introduced at the B position, which demonstrates that facile modifying the meso-aryl rings is a effective strategy for developing new HER catalysts. The electrochemical results demonstrate that an unusual two step modulation of HER reactions can be achieved by using singly and doubly electrochemical reduced cobalt triarylcorroles anions.
- Full Text:
- Date Issued: 2017
- Authors: Niu, Yingjie , Li, Minzhi , Zhang, Qianchong , Zhu, Weihua , Mack, John , Fomo, Gertrude , Nyokong, Tebello , Liang, Xu
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/233048 , vital:50051 , xlink:href="https://doi.org/10.1016/j.dyepig.2017.02.049"
- Description: Seven low symmetry A2B type Co(III)triarylcorroles with electron withdrawing meso-aryl substituents have been synthesized and characterized. A detailed analysis of the optical and redox properties has been carried out by comparing their optical spectroscopy, electrochemistry and spectroelectrochemistry to trends predicted in a series of DFT and TD-DFT calculations. The results demonstrate that Co(III)corroles are highly effective catalysts for hydrogen evolution reactions (HERs). Moreover, there is a marked enhancement in their homogenous catalytic ability when halogen atoms are introduced at the B position, which demonstrates that facile modifying the meso-aryl rings is a effective strategy for developing new HER catalysts. The electrochemical results demonstrate that an unusual two step modulation of HER reactions can be achieved by using singly and doubly electrochemical reduced cobalt triarylcorroles anions.
- Full Text:
- Date Issued: 2017
Happiness in the private physiotherapy sector of South Africa
- Authors: Elliot, Michael
- Date: 2017
- Subjects: Happiness Well-being , Health behavior -- Economic aspects Economics -- Sociological aspects
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/15171 , vital:28171
- Description: There is limited research pertaining to assessing the happiness levels of various disciplines within the healthcare industry. Furthermore, happiness and physiotherapy studies are two research areas that are not necessarily associated with one another on a global perspective. Hence, the happiness levels have not been adequately established for private physiotherapists. This treatise is the first attempt to evaluate the happiness levels of private physiotherapists in South Africa. A thorough literature review was conducted to determine the current climate of happiness studies pertaining to the business industry, with focus on private physiotherapy businesses in the healthcare sector. The literature review enabled the development of a hypothesised model, which was tested with quantitative techniques consisting of a questionnaire, data collection and statistical analysis. The research confirmed that influence, social relations, life balance, optimism, work and leisure are all positively associated with the happiness levels of private physiotherapists in South Africa. These variables are recommended as key focus areas for physiotherapy business owners to address, in order to positively affect happiness levels in the workplace and thereby create favourable bottom line results. In accordance with the reviewed literature and the findings of this treatise, by adequately addressing these variables the business owners of physiotherapy practices will generate a workforce that are more productive, demonstrate greater collaboration with colleagues and customers, produce happier customers, are more positively energised and are less absent and more loyal to the business. It is recommended that the proposed model is tested to provide further benefit to the industry by constructing evidence-based retention and recruitment strategies for high performing private physiotherapy staff.
- Full Text:
- Date Issued: 2017
- Authors: Elliot, Michael
- Date: 2017
- Subjects: Happiness Well-being , Health behavior -- Economic aspects Economics -- Sociological aspects
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/15171 , vital:28171
- Description: There is limited research pertaining to assessing the happiness levels of various disciplines within the healthcare industry. Furthermore, happiness and physiotherapy studies are two research areas that are not necessarily associated with one another on a global perspective. Hence, the happiness levels have not been adequately established for private physiotherapists. This treatise is the first attempt to evaluate the happiness levels of private physiotherapists in South Africa. A thorough literature review was conducted to determine the current climate of happiness studies pertaining to the business industry, with focus on private physiotherapy businesses in the healthcare sector. The literature review enabled the development of a hypothesised model, which was tested with quantitative techniques consisting of a questionnaire, data collection and statistical analysis. The research confirmed that influence, social relations, life balance, optimism, work and leisure are all positively associated with the happiness levels of private physiotherapists in South Africa. These variables are recommended as key focus areas for physiotherapy business owners to address, in order to positively affect happiness levels in the workplace and thereby create favourable bottom line results. In accordance with the reviewed literature and the findings of this treatise, by adequately addressing these variables the business owners of physiotherapy practices will generate a workforce that are more productive, demonstrate greater collaboration with colleagues and customers, produce happier customers, are more positively energised and are less absent and more loyal to the business. It is recommended that the proposed model is tested to provide further benefit to the industry by constructing evidence-based retention and recruitment strategies for high performing private physiotherapy staff.
- Full Text:
- Date Issued: 2017
Happiness is somebody’s name
- Authors: Jijana, Thabo
- Date: 2017
- Subjects: Creative writing (Higher education) South Africa , South African fiction (English) 21st century , Short stories, South African (English) 21st century
- Language: English , Xhosa
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/7268 , vital:21237
- Description: This collection of loosely interlinked short stories is a “book of imaginary beings”. It draws its influence from amaXhosa history, religion and mythology. Written in a fluid blend of isiXhosa and English, the stories make use of innovative forms and an inventive, pared-down language to create new and strange perspectives on our past, present and future. Ranging in length from brief mini-sagas to longer vignettes, the collection touches on such diverse subjects as the lore and superstitions surrounding the mythical being of tokoloshe, sorcery in the black community, and other fantastical elements of amaXhosa folklore. Literary influences include the Syrian writer Osama Olamar, whose writing about inanimate and everyday objects is both interesting and rare; Amos Tutuola, whose appropriation of Yoruba mythology I have learned much from; the Argentinian writer Julio Cortazar who has the facility to articulate the fantastical in a straightforward narrative; and Taban Lo Liyong, the Ugandan writer, whose fabulist work has served as stimulus for many of these stories.
- Full Text:
- Date Issued: 2017
- Authors: Jijana, Thabo
- Date: 2017
- Subjects: Creative writing (Higher education) South Africa , South African fiction (English) 21st century , Short stories, South African (English) 21st century
- Language: English , Xhosa
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/7268 , vital:21237
- Description: This collection of loosely interlinked short stories is a “book of imaginary beings”. It draws its influence from amaXhosa history, religion and mythology. Written in a fluid blend of isiXhosa and English, the stories make use of innovative forms and an inventive, pared-down language to create new and strange perspectives on our past, present and future. Ranging in length from brief mini-sagas to longer vignettes, the collection touches on such diverse subjects as the lore and superstitions surrounding the mythical being of tokoloshe, sorcery in the black community, and other fantastical elements of amaXhosa folklore. Literary influences include the Syrian writer Osama Olamar, whose writing about inanimate and everyday objects is both interesting and rare; Amos Tutuola, whose appropriation of Yoruba mythology I have learned much from; the Argentinian writer Julio Cortazar who has the facility to articulate the fantastical in a straightforward narrative; and Taban Lo Liyong, the Ugandan writer, whose fabulist work has served as stimulus for many of these stories.
- Full Text:
- Date Issued: 2017
Health promotion: approaches to dietary salt reduction
- Authors: Mushoriwa, Fadzai
- Date: 2017
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10962/44761 , vital:25439
- Description: Background Globally, non-communicable diseases are the leading causes of mortality and morbidity, with the majority of these occurring in low-middle income countries. The devastating consequences of non-communicable diseases could be curtailed through better management of four modifiable factors: physical inactivity; tobacco use; harmful use of alcohol; and unhealthy diets. The World Health Organisation has recommended dietary salt reduction as a cost-effective strategy in combatting the burden of NCDs. Consumer awareness and education is one of three primary strategies that have been identified by the World Health Organisation to achieve population-wide salt reduction. It involves the provision of salt reduction knowledge and the promotion of healthy salt related practices. These campaigns are a necessity in populations with high discretionary salt use such as South Africa. For these health promotion activities to succeed, they need to be developed with consideration of factors such as the environment, culture, and socio-economic standing of the intended target population. This two-phase health promotion study was conducted at St Mary’s Development and Care Centre and the Assumption Sisters Nutrition Centre. These are two community based organisations located in Grahamstown, South Africa. A needs assessment was conducted to identify the knowledge and practices of cooks and guardians from these centres on dietary salt reduction. The aim of the second phase of the study was to conduct an educational intervention and to develop a culturally appropriate and contextually specific health information intervention through a participatory process. Method: This was a qualitative study that was supported by elements of quantitative research.. The first phase of the current study was a needs assessment. The first step involved an observational phase with cooks from the centres. The aim was to observe their discretionary salt use during food preparation and to document the salt content in the processed foods available at each centre. Semi-structured interviews were then conducted, with 3 cooks and 16 guardians1 from the centres, to assess their knowledge and practices regarding salt reduction.Parents or the people responsible for the care of the children attending both centres. Guided by findings from the needs assessment phase, an educational intervention was developed. This phase involved the participatory development of three health information leaflets and a series of educational interactive sessions were conducted. Quantitative tests to assess the readability, suitability, and actionability were conducted on the leaflets. Qualitative assessment of the leaflets involved formative evaluations conducted by health care professionals, phase 1 participants, Rhodes University peer educators, an African languages and cultural expert, and a Rhodes University student wellness manager. This step was included to assess the content validity, context specificity, acceptability, and cultural appropriateness of the materials. Educational interactive sessions were guided by constructs of the Social Cognitive Theory and were conducted on three main topics: ‘Salt and my health’, ‘Reducing salt in my diet’, and ‘Reading food labels’. Results: The majority of the processed foods available at both centres contained low to medium levels of salt. Children at the centres were not provided with salt shakers on the tables during meal times. Cooks did not use measuring utensils when adding salt during meal preparation. Semistructured interviews revealed that participants lacked both declarative and procedural knowledge. In terms of declarative knowledge, they were unaware of the daily salt intake recommendations and the relationship between salt and sodium. Participants were able to identify hypertension as one of the health related consequences of high salt consumption. Most participants were responsible for purchasing groceries in their households. Their selfreported food label reading behaviours and inability to read food labels highlighted their lack of procedural knowledge. Most participants reported that they added salt during meal preparation and at mealtimes, highlighting high discretionary salt use. Some participants were also aware of cultural or religious uses of salt. The developed health information leaflets were considered to be written at a readability level appropriate for the target audience. The leaflets were also deemed to be actionable, culturally appropriate, and contextually specific and suitable materials. The educational interactive sessions were found to be interesting and informative. Conclusions: Findings from the needs assessment revealed the need for an educational intervention to address the identified gaps in the participants’ knowledge and practices regarding dietary salt reduction. The developed health information leaflets were found to be informative, culturally appropriate, and contextually specific, as planned. Interactive sessions provided an excellent platform to supply participants with concise and accurate information, increasing the possibility of improving their salt reduction related knowledge.
- Full Text:
- Date Issued: 2017
- Authors: Mushoriwa, Fadzai
- Date: 2017
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10962/44761 , vital:25439
- Description: Background Globally, non-communicable diseases are the leading causes of mortality and morbidity, with the majority of these occurring in low-middle income countries. The devastating consequences of non-communicable diseases could be curtailed through better management of four modifiable factors: physical inactivity; tobacco use; harmful use of alcohol; and unhealthy diets. The World Health Organisation has recommended dietary salt reduction as a cost-effective strategy in combatting the burden of NCDs. Consumer awareness and education is one of three primary strategies that have been identified by the World Health Organisation to achieve population-wide salt reduction. It involves the provision of salt reduction knowledge and the promotion of healthy salt related practices. These campaigns are a necessity in populations with high discretionary salt use such as South Africa. For these health promotion activities to succeed, they need to be developed with consideration of factors such as the environment, culture, and socio-economic standing of the intended target population. This two-phase health promotion study was conducted at St Mary’s Development and Care Centre and the Assumption Sisters Nutrition Centre. These are two community based organisations located in Grahamstown, South Africa. A needs assessment was conducted to identify the knowledge and practices of cooks and guardians from these centres on dietary salt reduction. The aim of the second phase of the study was to conduct an educational intervention and to develop a culturally appropriate and contextually specific health information intervention through a participatory process. Method: This was a qualitative study that was supported by elements of quantitative research.. The first phase of the current study was a needs assessment. The first step involved an observational phase with cooks from the centres. The aim was to observe their discretionary salt use during food preparation and to document the salt content in the processed foods available at each centre. Semi-structured interviews were then conducted, with 3 cooks and 16 guardians1 from the centres, to assess their knowledge and practices regarding salt reduction.Parents or the people responsible for the care of the children attending both centres. Guided by findings from the needs assessment phase, an educational intervention was developed. This phase involved the participatory development of three health information leaflets and a series of educational interactive sessions were conducted. Quantitative tests to assess the readability, suitability, and actionability were conducted on the leaflets. Qualitative assessment of the leaflets involved formative evaluations conducted by health care professionals, phase 1 participants, Rhodes University peer educators, an African languages and cultural expert, and a Rhodes University student wellness manager. This step was included to assess the content validity, context specificity, acceptability, and cultural appropriateness of the materials. Educational interactive sessions were guided by constructs of the Social Cognitive Theory and were conducted on three main topics: ‘Salt and my health’, ‘Reducing salt in my diet’, and ‘Reading food labels’. Results: The majority of the processed foods available at both centres contained low to medium levels of salt. Children at the centres were not provided with salt shakers on the tables during meal times. Cooks did not use measuring utensils when adding salt during meal preparation. Semistructured interviews revealed that participants lacked both declarative and procedural knowledge. In terms of declarative knowledge, they were unaware of the daily salt intake recommendations and the relationship between salt and sodium. Participants were able to identify hypertension as one of the health related consequences of high salt consumption. Most participants were responsible for purchasing groceries in their households. Their selfreported food label reading behaviours and inability to read food labels highlighted their lack of procedural knowledge. Most participants reported that they added salt during meal preparation and at mealtimes, highlighting high discretionary salt use. Some participants were also aware of cultural or religious uses of salt. The developed health information leaflets were considered to be written at a readability level appropriate for the target audience. The leaflets were also deemed to be actionable, culturally appropriate, and contextually specific and suitable materials. The educational interactive sessions were found to be interesting and informative. Conclusions: Findings from the needs assessment revealed the need for an educational intervention to address the identified gaps in the participants’ knowledge and practices regarding dietary salt reduction. The developed health information leaflets were found to be informative, culturally appropriate, and contextually specific, as planned. Interactive sessions provided an excellent platform to supply participants with concise and accurate information, increasing the possibility of improving their salt reduction related knowledge.
- Full Text:
- Date Issued: 2017
Hearing the citizens: inequality, access to journalists and the prospects for inclusively mediated spaces of political deliberation in South Africa
- Authors: Oelofsen, Marietjie
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/35030 , vital:24309
- Description: This study examines the extent to which material and social inequality in post-apartheid South Africa affect possibilities for poor citizens to gain access to mainstream spaces of mediated political deliberation. Access is problematized in terms of the possibilities that exist for poor citizens to ‘appear’ in these spaces as emancipated citizens with political agency. The study is motivated by a perception that South Africa’s middle-class and privileged citizens have more access to political deliberation because mainstream journalists pay more attention to their political concerns. Because mediated political deliberation provides a space for articulating the political will of citizens it is important that it reflects the multiple, and diverse range of voices that make up South Africa’s polity. If the experience of socioeconomically marginalised citizens is not registered in the same way as the experience of citizens with economic and political power, the balance of political decision-making continues to be skewed against the interests of the poor. Rather than a media-centric approach, the study centres on perceptions and views of poor citizens about their relationship with mainstream journalists. The study combines information from group interviews with citizens from Hangberg, Cape Town with 410 news reports in 18 mainstream newspapers about Hangberg citizens over a 20-year period. The interviews show that poor citizens feel largely excluded from mediated political deliberation; not because they do not appear in the news but because of how they appear in the news. The news reports confirm that mainstream journalists pay more attention to voices with political and economic power than to the voices of poor citizens. Even in news reports about Hangberg citizens, political leaders and non-governmental experts often talk about the problems in Hangberg more than the citizens of Hangberg themselves talk about these problems. Building on a relatively new scholarly interest in ‘active’ and ‘political’ listening in media studies and democratic theory (Bickford 1996, Dreher 2009, Couldry 2009, Dobson 2014, Wasserman 2013, Garman and Malila 2014), I consider listening as a constitutive element of the way in which journalists engage with poor citizens in mediated deliberative spaces. I ask whether different practices of listening can enable journalists to construct narratives that provide marginalised groups with different possibilities for equal access to, and participation in these spaces?
- Full Text:
- Date Issued: 2017
- Authors: Oelofsen, Marietjie
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/35030 , vital:24309
- Description: This study examines the extent to which material and social inequality in post-apartheid South Africa affect possibilities for poor citizens to gain access to mainstream spaces of mediated political deliberation. Access is problematized in terms of the possibilities that exist for poor citizens to ‘appear’ in these spaces as emancipated citizens with political agency. The study is motivated by a perception that South Africa’s middle-class and privileged citizens have more access to political deliberation because mainstream journalists pay more attention to their political concerns. Because mediated political deliberation provides a space for articulating the political will of citizens it is important that it reflects the multiple, and diverse range of voices that make up South Africa’s polity. If the experience of socioeconomically marginalised citizens is not registered in the same way as the experience of citizens with economic and political power, the balance of political decision-making continues to be skewed against the interests of the poor. Rather than a media-centric approach, the study centres on perceptions and views of poor citizens about their relationship with mainstream journalists. The study combines information from group interviews with citizens from Hangberg, Cape Town with 410 news reports in 18 mainstream newspapers about Hangberg citizens over a 20-year period. The interviews show that poor citizens feel largely excluded from mediated political deliberation; not because they do not appear in the news but because of how they appear in the news. The news reports confirm that mainstream journalists pay more attention to voices with political and economic power than to the voices of poor citizens. Even in news reports about Hangberg citizens, political leaders and non-governmental experts often talk about the problems in Hangberg more than the citizens of Hangberg themselves talk about these problems. Building on a relatively new scholarly interest in ‘active’ and ‘political’ listening in media studies and democratic theory (Bickford 1996, Dreher 2009, Couldry 2009, Dobson 2014, Wasserman 2013, Garman and Malila 2014), I consider listening as a constitutive element of the way in which journalists engage with poor citizens in mediated deliberative spaces. I ask whether different practices of listening can enable journalists to construct narratives that provide marginalised groups with different possibilities for equal access to, and participation in these spaces?
- Full Text:
- Date Issued: 2017
Heat shock proteins as modulators and therapeutic targets of chronic disease: an integrated perspective
- Edkins, Adrienne L, Price, John T, Pockley, A Graham, Blatch, Gregory L
- Authors: Edkins, Adrienne L , Price, John T , Pockley, A Graham , Blatch, Gregory L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164332 , vital:41109 , DOI: 10.1098/rstb.2016.0521
- Description: Many heat shock proteins (HSPs) are essential to survival as a consequence of their role as molecular chaperones, and play a critical role in maintaining cellular proteostasis by integrating the fundamental processes of protein folding and degradation. HSPs are arguably among the most prominent classes of proteins that have been broadly linked to many human disorders, with changes in their expression profile and/or intracellular/extracellular location now being described as contributing to the pathogenesis of a number of different diseases. Although the concept was initially controversial, it is now widely accepted that HSPs have additional biological functions over and above their role in proteostasis (so-called ‘protein moonlighting’).
- Full Text:
- Date Issued: 2017
- Authors: Edkins, Adrienne L , Price, John T , Pockley, A Graham , Blatch, Gregory L
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/164332 , vital:41109 , DOI: 10.1098/rstb.2016.0521
- Description: Many heat shock proteins (HSPs) are essential to survival as a consequence of their role as molecular chaperones, and play a critical role in maintaining cellular proteostasis by integrating the fundamental processes of protein folding and degradation. HSPs are arguably among the most prominent classes of proteins that have been broadly linked to many human disorders, with changes in their expression profile and/or intracellular/extracellular location now being described as contributing to the pathogenesis of a number of different diseases. Although the concept was initially controversial, it is now widely accepted that HSPs have additional biological functions over and above their role in proteostasis (so-called ‘protein moonlighting’).
- Full Text:
- Date Issued: 2017